With Specified Material Patents (Class 525/485)
  • Patent number: 4596840
    Abstract: Mixture for the production of acid-resistant sealing materials or acid-resistant impregnating materials based on epoxy resins, resols, hardening catalysts and further customary additives, which are in the form of a cement or impregnating solution and contain, as essential constituents, (A) at least one bifunctional, low-molecular epoxy resin having an epoxide equivalent weight between 87 and 1,000, (B) at least one resol formed from at least one trifunctional phenol and formaldehyde in a molar ratio of 1:1 to 1:3, having a viscosity between 50 and 2,500 mPa.s at 20.degree. C. and having a solids content of at least 50% by weight, and (C) hardening catalysts, cements also containing (D) fillers, in addition, and a process for the preparation of hardening products from the compounds. Thus, for example, cements or impervious, initially porous shaped articles which are resistant to solvents and weak acids and which have a low shrinkage after processing, are obtained.
    Type: Grant
    Filed: March 29, 1985
    Date of Patent: June 24, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wolfgang Hesse, Klaus Rauhut
  • Patent number: 4594291
    Abstract: Relatively high molecular weight epoxy resins cured with conventional curing agents are disclosed wherein the relatively high molecular weight epoxy resin is prepared in the presence of the curing agents. The resultant cured epoxy resin has an improvement in Tg or toughness and the mixture prior to reaction and curing is much easier to apply as a coating or in the preparation of castings, laminates and the like as compared to applications of mixtures of relatively high molecular weight epoxy resins and the curing agents.
    Type: Grant
    Filed: March 25, 1985
    Date of Patent: June 10, 1986
    Assignee: The Dow Chemical Company
    Inventors: James L. Bertram, Louis L. Walker, Jody R. Berman, James A. Clarke
  • Patent number: 4568727
    Abstract: Storage stable, heat curable mixtures obtained from epoxy resins as a binder system containing latent hardening agents as well as fillers and additive materials which have outstanding mechanical and electrical properties and which are obtained as epoxy resin components of an adduct of a high molecular solid epoxy resin and 4,4'-diaminodiarylalkane in a molecular ratio of 1:0.01 to 0.05. The preferred economical curing agent is a phenol formaldehyde condensation product.
    Type: Grant
    Filed: March 12, 1985
    Date of Patent: February 4, 1986
    Assignee: Rutgerswerke Aktiengesellschaft
    Inventors: Rolf Herzog, Dietrich Tichy, Harald Heerdegen, Rolf Kraas, Ulrich Grundke
  • Patent number: 4508765
    Abstract: A heat curable water dispersible film-forming synthetic resin useful in aqueous coating compositions for coating metal substrates, particularly cans used for food and beverages, comprises the reaction product of a water insoluble phenolic resin or a water insoluble amino resin with an epoxy resin and a phosphoric acid.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: April 2, 1985
    Assignee: International Paint public limited company
    Inventors: John Ring, David French, Michael Hickling, Michael G. Sturgess
  • Patent number: 4440914
    Abstract: Solid epoxy resin systems comprising the reaction products of a polyepoxide compound with a functionality greater than two, a diglycidyl ether of a polyhydric phenol and a polyhydric phenol; said systems being applicable for use in a variety of applications and particularly in combination with phenolic novolac hardeners for molding applications.
    Type: Grant
    Filed: September 20, 1982
    Date of Patent: April 3, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: David Helfand, Ralph F. Sellers
  • Patent number: 4374963
    Abstract: This invention relates to a heat curable composition comprising(a) a liquid, ethylenically unsaturated monomer, oligomer or prepolymer of the formula: ##STR1## wherein R is H or CH.sub.3, R.sub.1 is an organic moiety and n is at least 2,(b) an epoxy resin containing at least two ##STR2## groups, and (c) a thermal initiator member of the group consisting of(1) a substituted or unsubstituted diaryliodonium salt in combination with a free radical initiator,(2) a BF.sub.3 adduct,(3) a BF.sub.3 adduct in combination with a free radical initiator, and(4) dicyandiamide in combination with a free radical initiator.The system is stable at ordinary temperatures, but on heating the thermal initiator catalyzes the curing of the acrylate and the epoxy resin.
    Type: Grant
    Filed: November 2, 1981
    Date of Patent: February 22, 1983
    Assignee: W. R. Grace & Co.
    Inventors: Charles R. Morgan, David R. Kyle
  • Patent number: 4351928
    Abstract: A four-component composition is disclosed comprising a hydroxyl-bearing polymer; a liquid, amino- or hydroxyaromatic diluent having an atmospheric boiling point of about 150.degree. C. or greater; an aminoplast or phenolic resin capable of curing the hydroxyl-bearing polymer and a strong acid catalyst for the reaction between the first and third components. Optionally, a pigment may be added to the composition.
    Type: Grant
    Filed: October 26, 1981
    Date of Patent: September 28, 1982
    Assignee: The Dow Chemical Company
    Inventor: Harry A. Smith
  • Patent number: 4282136
    Abstract: The high temperature stability of devices encapsulated with a flame retardant epoxy molding compound is improved by including in the encapsulant as synergistic flame retardant a halogen-containing organic compound (preferably of the reactive type) and antimony pentoxide. The encapsulant may be prepared from an epoxy, a hardener preferably of the novolac or anhydride type, a catalyst, a mold release agent, preferably a filler, preferably a colorant, preferably a coupling agent, the halogen-containing organic compound (which may be part of the resin or the hardener) and antimony pentoxide. Such encapsulants, when used to encapsulate semiconductor devices, have improved high temperature compatability compared to similar molding compounds with antimony trioxide or antimony tetraoxide.
    Type: Grant
    Filed: April 9, 1979
    Date of Patent: August 4, 1981
    Inventors: Earl R. Hunt, Robert K. Rosler, James O. Peterson
  • Patent number: 4268648
    Abstract: A process for the preparation of resol resins by reacting bisphenol A with 1.2 to 1.8 moles of formaldehyde in the presence of n-butanol or isobutanol and in the presence of a tri-alkali metal phosphate as a catalyst, and their use, optionally combined with epoxy resins, for the preparation of deep-drawable, sterilizable and chemically resistant lacquer films.
    Type: Grant
    Filed: June 16, 1980
    Date of Patent: May 19, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Freitag, Wolfgang Beer, Ferdinand Senge
  • Patent number: 4256622
    Abstract: A four-component composition is disclosed comprising 100 parts of a non-aminoplast hydroxyl-bearing polymer; about 5-100 parts of a (poly)glycol monoether having an atmospheric boiling point of about 300.degree. C. or greater; an aminoplast or phenolic resin capable of curing the hydroxyl-bearing polymer and a strong acid catalyst for the reaction between the first and third components. Optionally, a pigment may be added to the composition.
    Type: Grant
    Filed: January 7, 1980
    Date of Patent: March 17, 1981
    Assignee: The Dow Chemical Company
    Inventor: Harry A. Smith
  • Patent number: 4192931
    Abstract: A process for producing a furan-epoxy powder-like binder comprising reaction of an epoxy diane resin (100 parts by weight) with a ketone of the furan series (40 to 500 parts by weight) and a modifying agent (60 to 500 parts by weight). As the ketone of the furan series use is made of monofurfurylideneacetone, difurfurylideneacetone, difurfurylidenecyclohexanone, a mixture of monofurfurylidenacetone with difurfurylidenacetone, 1,9-di-(.alpha.-furyl)-nonanetetraene-1,3,6,8-one-5, or 1,5-di-(.alpha.-furyl)-2,4-dimethylpentadiene-1,4-one-3. As the modifying agent use is made of a phenolformaldehyde resin or anhydrides of dibasic carboxylic acids. The reaction is carried out at a temperature within the range of from 130.degree. to 180.degree. C. in the presence, when required, of trifurylborate (10 to 30 parts by weight). The resulting product is cooled to a temperature of at most 30.degree. C. and disintegrated to a powder-like condition.
    Type: Grant
    Filed: August 7, 1978
    Date of Patent: March 11, 1980
    Inventors: Gennady D. Varlamov, Juldash Mamatov, Ildgam A. Bekbulatov, Shavkat Madaliev