Mixed With A Reactant Containing More Than One 1,2-epoxy Group Per Mole Or Polymer Derived Therefrom Patents (Class 525/524)
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Patent number: 11851603Abstract: A highly thermally conductive composition is provided, such composition comprising: (A) An organopolysiloxane composition; (B) a filler treating agent; (C) a thermal stabilizer; and (D) thermally conductive filler mixture, comprising: (D-1) a small-particulate thermally conductive filler having a mean size of up to 3 ?m, (D-2) spherical aluminum nitride having a mean size of from 50 to 150 ?m, (D-3) boron nitride having a mean size of from 20 to 200 ?m.Type: GrantFiled: November 7, 2018Date of Patent: December 26, 2023Assignees: DOW SILICONES CORPORATION, DOW GLOBAL TECHNOLOGIES LLC (DGTL)Inventors: Xiaolian Hu, Jiguang Zhang, Yan Zheng, Hongyu Chen, Chen Chen, Dorab Bhagwagar, Darren Hansen
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Patent number: 11390783Abstract: An adhesive comprising a getter material and optionally a solvent comprising a catalyst activatable by means of an external stimulus for the reaction of the getter material with a permeate can tolerate brief contact with permeates such as moisture in particular before user application, without any significant impairment of getter capacity.Type: GrantFiled: June 3, 2019Date of Patent: July 19, 2022Assignee: TESA SEInventors: Christian Schuh, Klaus Keite-Telgenbüscher, Chris Gäbert
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Patent number: 11274245Abstract: To provide a curable composition which can easily form an optical film with good fluorescence efficiency and includes quantum dots (B), a film made of a cured product of the curable composition, an optical film for a light-emitting display element made of the film, a light-emitting display element panel including the optical film, and a light-emitting display equipped with the light-emitting display element panel. A film is formed by curing a curable composition which includes an epoxy compound (A) having two or more epoxy groups and including a cyclic structure other than an oxirane ring, quantum dots (B), and an acid generator (C).Type: GrantFiled: December 7, 2018Date of Patent: March 15, 2022Assignee: TOKYO OHKA KOGYO CO., LTD.Inventors: Hiroki Chisaka, Kunihiro Noda, Dai Shiota
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Patent number: 10947428Abstract: Disclosed herein are compositions including (a) a first component comprising (1) an epoxy-adduct that is the reaction product of reactants comprising a first epoxy compound, a polyol, and an anhydride and/or a diacid and (2) a second epoxy compound; (b) rubber particles having a core/shell structure and/or graphenic carbon particles; and (c) a second component that chemically reacts with the first component at ambient or slightly thermal conditions. Also disclosed herein are compositions including (a) an epoxy-capped flexibilizer; (b) a heat-activated latent curing agent; and optionally (c) rubber particles having a core/shell structure and/or graphenic carbon particles; (d) an epoxy/CTBN adduct; and/or (e) an epoxy/dimer acid adduct. The heat-activated latent curing agent may include at least one reaction product of reactants including an epoxy compound and an amine and/or an alkaloid.Type: GrantFiled: December 7, 2015Date of Patent: March 16, 2021Assignee: PPG Industries Ohio, Inc.Inventors: Umesh C. Desai, Tien-Chieh Chao, Masayuki Nakajima, Kaliappa G. Ragunathan
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Patent number: 10363724Abstract: A resin composition including an epoxy resin (A), a curing agent (B), and vinyl polymer particles (C), in which the contained amount of epoxy resin (a1) having a molecular weight of 100-480 is 30-90 parts by mass per 100 parts by mass of the epoxy resin (A), the contained amount of epoxy resin (a2) having a molecular weight of 2,000-40,000 is 10-70 parts by mass per 100 parts by mass of the epoxy resin (A), the contained amount of the vinyl polymer particles (C) is 2-30 parts by mass per 100 parts by mass of the epoxy resin (A), and the instantaneous maximum thickening value of the vinyl polymer particles obtained by the following method is 0.3-5.0 Pa·s/° C.Type: GrantFiled: October 14, 2015Date of Patent: July 30, 2019Assignee: Mitsubishi Chemical CorporationInventors: Takuya Teranishi, Akira Oota, Masahiro Ichino, Toru Kondo
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Patent number: 10358565Abstract: The present invention relates to a UV-curable ink composition, a method for producing a bezel pattern of a display substrate using same, and a bezel pattern produced thereby, the UV-curable ink composition comprising a colorant, an epoxy compound, an oxetane compound and a photopolymerization initiator, wherein the content ratio of the epoxy compound to the oxetane compound is 1:0.5-1:6.Type: GrantFiled: September 30, 2015Date of Patent: July 23, 2019Assignee: LG CHEM, LTD.Inventors: Sung-Eun Park, Yong-Sung Goo, Seung-A Back, Joon-Hyung Kim
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Patent number: 10329465Abstract: The present invention relates to adhesive compositions containing a prepolymer which can be obtained by reacting a reaction mixture containing: at least one epoxy resin; at least one polyetherdiamine or polyethertriamine; at least one carboxyl-terminated butadiene-acrylonitrile copolymer (CTBN); and rubber particles having a core/shell structure. The invention also relates to methods for curing said compositions, to the cured adhesive compositions thus obtained, to the use thereof for bonding components and to the components thus obtained.Type: GrantFiled: June 19, 2017Date of Patent: June 25, 2019Assignee: Henkel AG & Co. KGaAInventors: Christian Holtgrewe, Harald Kuester, Thomas Bachon, Rainer Schoenfeld
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Patent number: 10287478Abstract: Curable resin compositions comprising an epoxy resin and a hydrazide curing agent and methods for using the curable resin compositions in cementing and/or remedial operations in a subterranean formation are provided. In one embodiment, the method may comprise combining an epoxy resin and a curing agent to form a curable resin composition, wherein the curing agent comprises a hydrazide curing agent; introducing the curable resin composition into a subterranean formation; and allowing the curable resin composition to at least partially cure.Type: GrantFiled: January 16, 2015Date of Patent: May 14, 2019Assignee: Halliburton Energy Services, Inc.Inventors: Matthew Grady Kellum, Gregory Robert Hundt, Paul Joseph Jones, Jeffery Dwane Karcher
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Patent number: 10011678Abstract: The invention relates to a binder resin which is a plastified epoxide-amine adduct P comprising an adduct EA made of epoxide resins E and amines A, optionally modified by incorporation of unsaturated fatty acids F?, which adduct is plastified by incorporation of a fatty acid amide M, or a mixture M? of the said fatty acid amide M with a glyceride mixture GX which is a mixture of at least two glycerides selected from the group consisting of a triglyceride GT, a diglyceride GD, and a monoglyceride GM, to a process for its preparation, and to a method of use thereof as primer for wood, mineral, and metal substrates.Type: GrantFiled: October 21, 2014Date of Patent: July 3, 2018Assignee: ALLNEX AUSTRIA GMBHInventor: Roland Feola
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Patent number: 10010907Abstract: The present invention provides a method for color register spraying of a hub, which includes machining and turning for glossy finish after spraying a black paint on the surface of a hub, and then spraying a color transparent paint onto the hub. The method provided by the invention achieves a spraying-based color register effect through spraying of the color transparent paint, which greatly improves the production efficiency and is available for batch production.Type: GrantFiled: June 22, 2016Date of Patent: July 3, 2018Assignee: CITIC Dicastal CO., LTDInventors: Le Zhang, Shengchao Zhang, Yongning Wang, Zhihua Zhu, Changhai Li
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Patent number: 9957387Abstract: An epoxy resin composition having components (A), (B), (C), and (D), wherein the epoxy resin composition has a viscosity at 40° C. of about 1×103 to about 1×104 Pa·s, a curing start temperature of about 90 to about 110° C., and a minimum viscosity at the curing start temperature of about 2 to about 20 Pa·s, wherein the components (A), (B), (C), and (D) are as follows: (A) About 60 weight parts or more of a tetraglycidyl amine type epoxy resin per 100 weight parts of the epoxy resin blend; (B) Dicyandiamide; (C) Diaminodiphenyl sulfone and (D) Urea compound.Type: GrantFiled: November 7, 2011Date of Patent: May 1, 2018Assignee: TORAY INDUSTRIES, INC.Inventors: Nobuyuki Arai, Alfred P. Haro, Jonathan C. Hughes, Norimitsu Natsume
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Patent number: 9670356Abstract: A matrix material for a carbon fiber-reinforced composite comprises a matrix resin as a resin component. The matrix resin contains both a first epoxy resin and a second epoxy resin or only the first epoxy resin, further contains a third epoxy resin, and has an average epoxy equivalent weight of 109 to 162. The first epoxy resin contains a polyfunctional glycidylamine-type epoxy resin. The second epoxy resin contains at least one of a p-aminophenol-type epoxy resin and a tetramethylbiphenol-type solid epoxy resin. The third epoxy resin contains a bisphenol A-type epoxy resin having a weight-average molecular weight of 8000.Type: GrantFiled: December 10, 2015Date of Patent: June 6, 2017Assignees: HONDA MOTOR CO., LTD., FUKUI PREFECTURAL GOVERNMENTInventors: Shuichiro Yoshida, Keiichi Kondo
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Patent number: 9598573Abstract: A curable resin composition which comprising (A), (B) and (C) as follows: (A) 100 parts by mass of polyfunctional epoxy component which contains (A1) a trifunctional epoxy compound having three glycidyl groups in a molecule and (A2) a tetrafunctional epoxy compound having four glycidyl groups in a molecule, wherein (A1):(A2) is 10:90 to 90:10 in terms of mass; (B) 25 to 200 parts by mass of a cyanic acid ester compound having two or more of cyanato groups; and (C) 0.5 to 20 parts by mass of an imidazole compound as a curing agent.Type: GrantFiled: June 7, 2013Date of Patent: March 21, 2017Assignee: Adeka CorporationInventors: Yuichiro Deguchi, Takahiro Mori, Yoshihiro Fukuda, Takeru Ohtsu
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Patent number: 9574045Abstract: The present invention provides an epoxy resin composition including an epoxy resin represented by the following formula (1) and an epoxy resin represented by the following formula (2):Type: GrantFiled: July 31, 2013Date of Patent: February 21, 2017Assignee: ASAHI KASEI E-MATERIALS CORPORATIONInventors: Teruhisa Yamada, Kenzo Onizuka, Kozo Yoshida, Seiji Yamaguchi
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Patent number: 9315704Abstract: A pressure sensitive adhesive construct comprising: (a) a backing substrate; and (b) a pressure sensitive adhesive composition disposed on the backing substrate, wherein the pressure sensitive adhesive includes a product made from at least one epoxidized vegetable oil and at least one dibasic acid or anhydride, or a combination of a dibasic acid or anhydride and a monobasic acid or anhydride.Type: GrantFiled: June 7, 2011Date of Patent: April 19, 2016Assignee: Oregon State UniversityInventors: Kaichang Li, Anlong Li
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Patent number: 9284434Abstract: A re-epoxidized polyfunctional epoxy resin composition comprising the reaction product of: (I) an epoxidized polyfunctional epoxy resin oligomeric composition comprising a polyfunctional aliphatic or cycloaliphatic epoxy resin which has been isolated from an epoxy resin product formed as a result of an epoxidation process comprising the reaction of: (i) an aliphatic or cycloaliphatic hydroxyl-containing material; (ii) an epihalohydrin, (iii) a basic-acting substance, in the presence of (iv) a non-Lewis acid catalyst; and (v) optionally, one or more solvents; (II) an epihalohydrin; (III) a basic acting substance; in the presence of (IV) a non-Lewis acid catalyst; and (V) optionally, one or more solvents. A curable epoxy resin composition of the re-epoxidized polyfunctional epoxy resin composition and a thermoset of the curable composition is also disclosed.Type: GrantFiled: September 7, 2011Date of Patent: March 15, 2016Assignee: BLUE CUBE IP LLCInventor: Robert E. Hefner, Jr.
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Patent number: 9255177Abstract: A hybrid epoxy resin adduct comprising, consisting of, or consisting essentially of the reaction product of: (A) a material selected from the group consisting of a hybrid polyfunctional aliphatic epoxy resin, a hybrid cycloaliphatic epoxy resin, and combinations thereof; wherein (A) is formed by contacting: (a) a hydroxyl-containing material selected from the group consisting of an aliphatic hydroxyl-containing material, a cycloaliphatic hydroxyl-containing material, and combinations thereof; (b) a material selected from the group consisting of a monoglycidyl ether-containing material, a diglycidyl ether-containing material, and combinations thereof wherein (b) is prepared from a different precursor than (a); (c) an epihalohydrin; (d) a basic acting substance; (e) a non-Lewis acid catalyst; and (f) optionally, a solvent and (B) at least one epoxide reactive compound comprising one or more compounds having two or more epoxide-reactive hydrogen atoms per molecule, is disclosed.Type: GrantFiled: June 14, 2012Date of Patent: February 9, 2016Assignee: Blue Cube IP LLCInventor: Robert E. Hefner, Jr.
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Patent number: 9157013Abstract: A solid dry to the touch at ambient temperature structural adhesive which can be cured at elevated temperature and which can be molded at an intermediate temperature is provided as well as the use of the adhesive for bonding metals.Type: GrantFiled: May 9, 2011Date of Patent: October 13, 2015Assignee: Zephyros, Inc.Inventor: Michael Czaplicki
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Patent number: 9068074Abstract: An object of the present invention is to provide a composition for the formation of a cured epoxy resin, wherein the composition can suppress a curing reaction at a low temperature to thereby enhance one-pack stability, and can also be subjected to a heating treatment to thereby effectively cure a resin. The present invention provides a composition for the formation of a cured epoxy resin, the composition comprising the following components (A), (B) and (C): (A) an epoxy resin; (B) a clathrate compound of a carboxylic acid derivative represented by formula (I): R(COOH)n??(I); and an imidazole compound represented by formula (II); and (C) a tetrakisphenol type compound represented by formula (III).Type: GrantFiled: October 15, 2010Date of Patent: June 30, 2015Assignees: NIPPON SODA CO., LTD., NISSO CHEMICAL ANALYSIS SERVICE CO., LTD.Inventors: Kazuo Ono, Natsuki Amanokura, Hitoshi Matsumoto, Emi Nakayama
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Patent number: 9040607Abstract: An adhesive composition includes a first part comprising about 15 to about 60 wt % of an epoxy compound, about 35 to about 80 wt % of an epoxy novolac, and about 5 to about 25 wt % of an epoxy-based reactive diluent based on the total weight of epoxy compound, epoxy novolac, and reactive diluent; and a second part comprising less than about 20 wt % of a hydroxyaromatic solvent, about 80 to about 99 wt % of a Mannich base, and about 1 to about 20 wt % of a tertiary amine, based on the total weight of hydroxyaromatic solvent, Mannich base, and tertiary amine, the first and second parts being present in a volume ratio of about 0.8:1 to about 1.2:1. Additives to further enhance the properties may be included. A method of forming an adhesive layer includes applying the adhesive composition to a surface.Type: GrantFiled: March 13, 2012Date of Patent: May 26, 2015Assignee: BLACK & DECKER INC.Inventor: James E. Surjan
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Publication number: 20150119500Abstract: This invention relates to an epoxy resin composition and its application in marine maintenance and repair coating with improved overcoatability.Type: ApplicationFiled: April 24, 2012Publication date: April 30, 2015Applicant: Dow Global Technologies LLCInventors: Amy Song, Hongyu Chen
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Publication number: 20150093320Abstract: A liquid carbon precursor composition including (a) at least one aromatic epoxy resin; and (b)(i) at least one aromatic co-reactive curing agent or (b)(ii) at least one catalytic curing agent, or (b)(iii) a mixture thereof; wherein the liquid composition prior to adding optional components and curing, has a neat viscosity of less than 10,000 mPa-s, at 25° C.; and wherein the liquid precursor composition has a neat viscosity of less than 10,000 mPa-s at 25° C. prior to adding optional components, prior to curing, and prior to carbonizing; and wherein the liquid precursor composition being cured has a carbon yield of at least 35 weight percent as measured in the absence of optional components; a cured liquid carbon precursor composition; a carbonized material made from the above liquid carbon precursor composition; and processes for producing the above compositions.Type: ApplicationFiled: May 17, 2013Publication date: April 2, 2015Inventors: Hamed H. Lakrout, Maurice J. Marks, Ludovic Valette
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Patent number: 8974905Abstract: A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200° F. (93° C.). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins with different functionality selected from difunctional, trifunctional, and tetrafunctional epoxy resins, certain toughening components, and inorganic filler particles as a rheology/thixotrophy modifying component. The toughening components include core-shell rubber particles with different particle sizes and at least one of an elastomeric polymer and a polyethersulfone polymer.Type: GrantFiled: October 13, 2014Date of Patent: March 10, 2015Assignee: Cytec Technology Corp.Inventors: Junjie Jeffrey Sang, Dalip Kumar Kohli, Kunal Gaurang Shah
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Publication number: 20150018456Abstract: Disclosed herein are polyglycidyl ethers of the formula: where R, m, Q, p and Z are as defined here. Also disclosed are methods of forming said polyglycidyl ethers and methods of using said polyglycidyl ethers to make epoxy resin oligomers and polymers, including powder coatings.Type: ApplicationFiled: February 22, 2013Publication date: January 15, 2015Inventors: Robert E. Hefner, JR., Erich J. Molitor
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Patent number: 8928158Abstract: An epoxy resin composition for encapsulating a semiconductor device includes a curing agent, a curing accelerator, inorganic fillers, and an epoxy resin, the epoxy resin including a first resin represented by Formula 1: wherein R1 and R2 are each independently hydrogen or a C1 to C4 linear or branched alkyl group, and n is a value from 1 to 9 on average.Type: GrantFiled: May 23, 2012Date of Patent: January 6, 2015Assignee: Cheil Industries Inc.Inventors: Seung Han, Ju Mi Kim, Sung Su Park, Eun Jung Lee
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Patent number: 8921497Abstract: An adhesive for anchoring materials in or to concrete or masonry exhibits a shorter cure time than previous adhesives and comprises an epoxy compound and a curing agent of at least one aliphatic amine and at least one tertiary amine, optionally with a reactive dilent, which possesses sufficent strength to pass ICBO Heat Creep Test at 110 degrees F. and the ICBO Damp Hole Test at 75 degrees F.Type: GrantFiled: December 27, 2002Date of Patent: December 30, 2014Assignee: Illinois Tool Works Inc.Inventor: Jim Surjan
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Patent number: 8916656Abstract: A glass printing ink and a glass printing lacquer comprising at least one pigment, at least one photoinitiator, at least two resins and radicial photoinitiators. One resin is an epoxy resin having an average molecular weight based on bisphenol A, diluted in a UV hardening monomer. The other resin is a resin which contains free functional amino, hydroxy, epoxy, acid, acid anhydride and/or acrylate groups. Also, the use of the glass printing ink and glass printing lacquer when printing a glass substrate and to a method for printing a glass substrate.Type: GrantFiled: July 1, 2013Date of Patent: December 23, 2014Assignee: Marabu GmbH & Co., KGInventors: Saskia Lehmann, Wolfgang Schaefer
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Patent number: 8912295Abstract: It is an object to provide a liquid thermosetting composition that yields an epoxy resin having physical properties of the cured product such as high flexural strength along with adequate handleability as liquid, to be used in transparent sealants for optical semiconductors, such as transparent sealants for LEDs (light-emitting devices) and the like. There is provided a thermosetting composition containing an epoxy compound that a side chain between a triazinetrione ring and an epoxy group substituted on the triazinetrione ring is long (elongated).Type: GrantFiled: February 9, 2010Date of Patent: December 16, 2014Assignee: Nissan Chemical Industries, Ltd.Inventors: Toshiaki Takeyama, Takeo Moro
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Patent number: 8907025Abstract: The present invention is to provide an adhesive agent composition, including: a main agent containing a polyether polyurethane polyol and a bisphenol A-type epoxy resin; and a curing agent, wherein the polyether polyurethane polyol is obtained by reacting a polyalkylene glycol including repeating units each having a carbon number of 3 or 4 and an alkane diol monomer with an organic diisocyanate at an equivalent ratio (NCO/OH) of 0.7 or more but less than 1, a weight average molecular weight thereof is in the range of 20,000 to 70,000, and an urethane bond equivalent thereof is in the range of 320 to 600 g/eq, and wherein a number average molecular weight of the bisphenol A-type epoxy resin is in the range of 400 to 5,000, and the bisphenol A-type epoxy resin is of a solid state or a semisolid state at normal temperature.Type: GrantFiled: January 20, 2012Date of Patent: December 9, 2014Assignee: Toyo Ink SC Holdings Co., Ltd.Inventors: Hiroki Sugi, Bungo Yasui, Seiji Maeda, Katsuyuki Ueki, Kenshiro Shimada
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Patent number: 8895148Abstract: A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200° F. (93° C.). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins, toughening components, and inorganic filler particles. The catalyst part (B) includes an aliphatic or cyclic amine compound as a curing agent and inorganic filler. In another embodiment, the structural adhesive composition is based on a one-part system, which includes the components of the resinous part (A) mixed with a latent amine curing agent. The one-part system may further include an imidazole and/or an aliphatic amine.Type: GrantFiled: October 16, 2012Date of Patent: November 25, 2014Assignee: Cytec Technology Corp.Inventors: Junjie Jeffrey Sang, Dalip Kumar Kohli, Kunal Gaurang Shah
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Patent number: 8889803Abstract: To provide an epoxy polymerizable composition which exhibits low curing shrinkage and high workability and which gives a cured article having a high refraction index and high heat resistance. The epoxy polymerizable composition contains (A2) fluorene epoxy compound having the following general formula (1) or (2), (A3) epoxy compound having a softening point of 30° C. or less, and (B1) thiol compound having two or more thiol groups in one molecule.Type: GrantFiled: January 23, 2009Date of Patent: November 18, 2014Assignee: Mitsui Chemicals, Inc.Inventors: Yasushi Takamatsu, Yugo Yamamoto, Yuichi Ito
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Publication number: 20140316081Abstract: The present invention provides a cationically curable resin composition for assembling hard disk devices which comprises a resin having a cationically polymerizable functional group (a component A) and a cationic polymerization initiator (a component B), the component B being at least one selected from the group consisting of X+(SbF6)?(B1), X+(B(C6F5)4)?(B2) and X+((Rf)nPF6-n)?(B3) (in the formulae, X+ is iodonium or sulfonium, Rf is a fluorinated alkyl having 1 to 6 carbon atoms, and n is an integer of 1 to 6). The invention also provides a hard disk device manufacturing method using the composition, and a hard disk device assembled with the composition.Type: ApplicationFiled: November 20, 2012Publication date: October 23, 2014Applicant: KYORITSU CHEMICAL & CO., LTD.Inventors: Shigeki Toyama, Yoshitomo Denpou
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Patent number: 8865143Abstract: A reversely thermo-reversible hydrogel composition comprising a water soluble block copolymer comprising at least two blocks of polyethylene oxide and at least one block of polypropylene oxide, and at least one associative gelling adjuvant having water solubility less than 0.5 g/100 ml, preferably less than 0.3 g/100 ml at 20° C., and being capable of forming water soluble inter-molecular complexes with the water soluble block copolymer in water. The hydrogel composition exhibits improved gelling efficiency, enhanced solubility and/or stability for water sparely soluble and insoluble pharmaceutical agents. The hydrogel compositions are useful in a variety of pharmaceutical and cosmetic products and applications, such as esophageal, otic, vaginal, rectal, ophthalmic, treatments of disorders and imperfections of the skin, and treating and/or preventing alopecia and restoring and/or promoting hair growth.Type: GrantFiled: March 21, 2012Date of Patent: October 21, 2014Assignee: Broda Technologies Co., Ltd.Inventors: Shao Xiang Lu, Jeffrey Lu, Letian Liu
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Patent number: 8859695Abstract: A hem-curing epoxy resin composition, that includes an epoxy resin A having more than one epoxy group per molecule on average; a curing agent B for epoxy resins, which is activated at a temperature in a range of 100° C. to 220° C.; and an activator C for epoxy resin compositions, wherein activator C is a compound of formula (I), or is a reaction product between a compound of formula (Ia) and an isocyanate or an epoxide.Type: GrantFiled: May 29, 2013Date of Patent: October 14, 2014Assignee: Sika Technology AGInventors: Karsten Frick, Ulrich Gerber, Juergen Finter, Andreas Kramer
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Publication number: 20140275343Abstract: An epoxy resin adduct comprising the reaction product of an epoxy resin comprising a diglycidyl ether of Formula 1 as defined herein, and at least one reactive compound having two or more active hydrogen atoms per molecule, wherein the active hydrogen atoms are reactive with epoxide groups are described. The diglycidyl ether contains a cycloaliphatic ring of 3-5 carbon atoms. Curable compositions, methods of curing, cured compositions, and articles comprising the epoxy resin adducts are also disclosed. The epoxy resin adduct has improved cure behavior and provides cured compositions having increased glass transition temperature, good weatherability, and a low total chlorine content.Type: ApplicationFiled: March 7, 2014Publication date: September 18, 2014Inventors: Robert E. Hefner, JR., Ray E. Drumright
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Patent number: 8815401Abstract: A prepreg for a printed wiring board, comprising a cyanate ester resin having a specific structure, a non-halogen epoxy resin, a silicone rubber powder as a rubber elasticity powder, an inorganic filler and a base material, which prepreg retains heat resistance owing to a stiff resin skeleton structure, has high-degree flame retardancy without the use of a halogen compound or a phosphorus compound as a flame retardant, and has a small thermal expansion coefficient in plane direction without using a large amount of inorganic filler, and a laminate comprising the above prepreg.Type: GrantFiled: July 11, 2008Date of Patent: August 26, 2014Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yoshihiro Kato, Takeshi Nobukuni, Masayoshi Ueno
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Publication number: 20140235792Abstract: A thermoset resin, including the reaction product of: an epoxy resin mixture including at least one cycloaliphatic epoxy resins; a cycloaliphatic anhydride hardener; and a catalyst; wherein the reaction product has a glass transition temperature greater than or equal to 210° C. Also disclosed is a process for forming a thermoset resin, including: admixing two or more epoxy resins and a cycloaliphatic anhydride hardener to form a curable composition, wherein the epoxy resins include at least one cycloaliphatic epoxy resin; thermally curing the curable composition at a temperature of at least 150° C. to result in a thermoset resin having a glass transition temperature of at least 210° C. Such curable compositions may include: 35 to 65 weight percent of an epoxy resin mixture having at least one cycloaliphatic epoxy resins; 35 to 65 weight percent of a cycloaliphatic anhydride hardener; and from greater than 0 to 10 weight percent of a catalyst.Type: ApplicationFiled: April 29, 2014Publication date: August 21, 2014Inventors: Jeffery L. Reynolds, Rajesh H. Turakhia, George C. Jacob, Marty J. Null
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Publication number: 20140213697Abstract: The present invention relates to a curable composition which comprises epoxy resin, epoxy-group-bearing reactive diluent and the hardener 2,2?,6,6?-tetramethyl-4,4?-methylenebis(cyclohexylamine), curing thereof, and the cured epoxy resin obtainable therefrom, and the use of 2,2?,6,6?-tetramethyl-4,4?-methylenebis(cyclohexylamine) as a hardener for epoxy resins in curable compositions with epoxy-group-bearing reactive diluent.Type: ApplicationFiled: January 27, 2014Publication date: July 31, 2014Applicant: BASF SEInventors: Achim KAFFEE, Miran YU, Monika CHARRAK, Kirsten DAHMEN, Veit STEGMANN, Gerd HADERLEIN, Alexander PANCHENKO
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Patent number: 8785524Abstract: A spray coatable adhesive composition used for bonding silicon dies to a rigid substrate, preferable a silicon substrate is disclosed. The adhesive composition includes an epoxy based resin, a thermal acid generator, a photoacid generator and a solvent. The epoxy based resin includes a mixture of a solid bisphenol A epoxy resin and a liquid or semi-liquid hydrogenated bisphenol A epoxy resin at a weight ratio ranging from about 80:20 to about 65:35. The adhesive composition has a low viscosity which allows it to be spray coated on a rigid substrate and form thin film adhesive which allows silicon dies to be bonded with precise placement on the silicon substrate.Type: GrantFiled: June 24, 2011Date of Patent: July 22, 2014Assignee: Funai Electric Co., Ltd.Inventors: Xiaoming Wu, Paul Dryer, David Rhine, Anna Pearson, Jeanne Marie Saldanha Singh, Richard Wells, Joel Provence
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Publication number: 20140182903Abstract: An object is to provide a resin composition that has excellent dielectric properties, that yields a highly heat-resistant cured product, that provides a low viscosity when made into a varnish, and that has a high Tg and a high flame retardancy without containing halogen. The resin composition contains a polyarylene ether copolymer (A) that has an intrinsic viscosity, measured in methylene chloride at 25° C., of 0.03 to 0.12 dL/g and that has an average of 1.5 to 3 phenolic hydroxyl groups in molecular terminal position per molecule, a triphenylmethane-type epoxy resin (B) that has a softening point of 50 to 70° C., and a cure accelerator (C), wherein the content of the polyarylene ether copolymer (A) is 60 to 85 mass parts where the total of the polyarylene ether copolymer (A) and the epoxy resin (B) is 100 mass parts.Type: ApplicationFiled: July 13, 2012Publication date: July 3, 2014Applicant: PANASONIC CORPORATIONInventors: Takashi Sagara, Hidetaka Kakiuchi, Keiko Kashihara, Yuki Kitai, Hirosuke Saito, Daisuke Yokoyama, Hiroaki Fujiwara
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Patent number: 8765835Abstract: There is provided a curable composition having a low viscosity and high cationic curability. A curable composition including an epoxy compound of Formula (1): [in Formula (1), A is a monocyclic aliphatic hydrocarbon group optionally containing an epoxy group; R1, R2, R3 and R4 are independently a hydrogen atom or a C1-10 alkyl group; n1 and n2 are independently an integer of 2 to 6; n3 and n4 are individually an integer of 2; and n5 and n6 are individually an integer of 1], and an acid generator.Type: GrantFiled: July 27, 2011Date of Patent: July 1, 2014Assignee: Nissan Chemical Industries, Ltd.Inventors: Toshiaki Takeyama, Yuki Endo, Sayoko Yanagisawa
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Patent number: 8758549Abstract: The present invention relates to heat-curable compositions containing a mixture of reactive epoxy resins that contains, based on the mass of all epoxy resins, a) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with polypropylene glycol which has an epoxy equivalent weight of at least 250 g/eq, and b) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with a novolac resin which has an epoxy equivalent weight of at least 175 g/eq, and at least one latent hardener.Type: GrantFiled: November 5, 2012Date of Patent: June 24, 2014Assignee: Henkel AG & Co. KGaAInventors: Pablo Walter, Mustapha Benomar, Stefan Kreiling, Angelika Troll, Rainer Schoenfeld
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Patent number: 8759422Abstract: An adhesive composition comprising elastomeric polymer, epoxy resin, reactive diluent, and filler, is suitable for use within the electronics industry, and in particular for wafer back side coating adhesives. The elastomeric polymer is a mixture of a vinyl elastomer and an epoxy elastomer; the reactive diluent is a combination of two or more diluents, one of which must have carbon to carbon unsaturation, providing cross-linking within the composition after cure; and the filler is a non-conductive filler.Type: GrantFiled: March 13, 2013Date of Patent: June 24, 2014Assignee: Henkel IP & Holding GmbHInventors: Eric C. Wang, Kevin Harris Becker, Qizhuo Zhuo
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Publication number: 20140163180Abstract: A hybrid epoxy resin adduct comprising, consisting of, or consisting essentially of the reaction product of: (A) a material selected from the group consisting of a hybrid polyfunctional aliphatic epoxy resin, a hybrid cycloaliphatic epoxy resin, and combinations thereof; wherein (A) is formed by contacting: (a) a hydroxyl-containing material selected from the group consisting of an aliphatic hydroxyl-containing material, a cycloaliphatic hydroxyl-containing material, and combinations thereof; (b) a material selected from the group consisting of a monoglycidyl ether-containing material, a diglycidyl ether-containing material, and combinations thereof wherein (b) is prepared from a different precursor than (a); (c) an epihalohydrin; (d) a basic acting substance; (e) a non-Lewis acid catalyst; and (f) optionally, a solvent and (B) at least one epoxide reactive compound comprising one or more compounds having two or more epoxide-reactive hydrogen atoms per molecule, is disclosed.Type: ApplicationFiled: June 14, 2012Publication date: June 12, 2014Applicant: DOW GLOBAL TECHNOLOGIES LLCInventor: Robert E. Hefner, JR.
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Patent number: 8742018Abstract: A thermoset resin, including the reaction product of: an epoxy resin mixture including at least one cycloaliphatic epoxy resins; a cycloaliphatic anhydride hardener; and a catalyst; wherein the reaction product has a glass transition temperature greater than or equal to 210° C. Also disclosed is a process for forming a thermoset resin, including: admixing two or more epoxy resins and a cycloaliphatic anhydride hardener to form a curable composition, wherein the epoxy resins include at least one cycloaliphatic epoxy resin; thermally curing the curable composition at a temperature of at least 150° C. to result in a thermoset resin having a glass transition temperature of at least 210° C. Such curable compositions may include: 35 to 65 weight percent of an epoxy resin mixture having at least one cycloaliphatic epoxy resins; 35 to 65 weight percent of a cycloaliphatic anhydride hardener; and from greater than 0 to 10 weight percent of a catalyst.Type: GrantFiled: January 5, 2009Date of Patent: June 3, 2014Assignee: Dow Global Technologies LLCInventors: Jeffery L. Reynolds, Rajesh H. Turakhia, George Jacob, Marty J. Null
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Patent number: 8722816Abstract: A solder resist having both adequate sensitivity at photo-irradiation and alkali developability, and the solder resist forming a cured product which is excellent in dimensional stability against temperature change, does not exhibit brittleness, and further, is excellent in water resistance, electrical insulation, thermal cycle test resistance (TCT resistance) and the like is provided, and further, a dry film having a solder resist layer, a cured product and a printed wiring board are provided. The solder resist comprising an acid-modified vinyl ester synthesized from an epoxy compound, a phenol compound, an unsaturated monobasic acid and a polybasic acid anhydride, wherein the epoxy compound contains a crystalline epoxy resin having a melting point of 90° C. or more, and the phenol compound contains a compound having a bisphenol S structure.Type: GrantFiled: March 4, 2008Date of Patent: May 13, 2014Assignees: Nippon Shokubai Co., Ltd., Taiyo Holdings Co., Ltd.Inventors: Nobuaki Otsuki, Manabu Akiyama, Shouji Minegishi, Masao Arima
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Patent number: 8717130Abstract: The present invention relates to a lacquer composition, particularly an adhesive and corrosion-protective lacquer for rare earth magnets, on the basis of an epoxy resin mixture, a setting accelerator, a silane-based epoxy functional adhesion promoter and a solvent or a solvent mixture, wherein the lacquer composition includes 5 to 20 wt. %, with respect to the amount of solid resin in the base of the epoxy resin mixture, of a highly viscous epoxy resin based on bisphenol-A with an elastomer content of more than 30 wt. %.Type: GrantFiled: February 2, 2011Date of Patent: May 6, 2014Assignee: Vacuumschmeize GmbH & Co. KGInventor: Lothar Zapf
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Patent number: 8716413Abstract: A method for the preparation of a photocurable resin by a reaction comprising the following steps i) reacting a mixture of a novolak type epoxy resin (A) and a dicyclopentadiene-phenol glycidylether resin (B) with ii) an advancement component (C) containing at least 2 phenolic hydroxyl groups per molecule; iii) reacting with an unsaturated monocarboxylic acid (D); and iv) esterification of the unsaturated group containing resin obtained from the steps of i) to iii) with a polycarboxylic acid anhydride or a carboxylic acid anhydride (E) is disclosed.Type: GrantFiled: June 12, 2009Date of Patent: May 6, 2014Assignee: Huntsman Advanced Materials Americas LLCInventors: Kai Dudde, Sabine Pierau, Martin Roth
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Patent number: 8686069Abstract: The solvent resistance of epoxy resins toughened with polyethersulfone is improved by using low molecular weight polyethersulfone. The resulting thermoplastic toughened epoxy resins are useful for making prepreg for aerospace applications.Type: GrantFiled: October 12, 2010Date of Patent: April 1, 2014Assignee: Hexcel CorporationInventor: Yen-Seine Wang
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Patent number: 8673108Abstract: This invention relates to compositions useful as adhesives and more particularly to the preparation of epoxy-based adhesive composition with improved impact resistance and good adhesion to oily metal substrates.Type: GrantFiled: February 2, 2009Date of Patent: March 18, 2014Assignee: Henkel AG & Co. KGaAInventors: Jeng-Li Liang, Rajat K. Agarawal, Gregory A. Ferguson, Olaf Lammerschop, Frank Dittrich, Rainer Schoenfeld