Wherein Unsaturated Reactant Is A Carboxylic Acid Or Derivative Or Polymer Derived Therefrom Patents (Class 525/530)
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Patent number: 12173766Abstract: A highly durable spring of the present invention includes a single-layer coating film with a thickness of 450 ?m or less, in which the coating film contains an epoxy resin, a phenolic resin, and zinc. The coating film has high corrosion resistance and chipping resistance even if it is a one thin layer with a thickness of 450 ?m or less. A method of coating a highly durable spring of the present invention includes an application process in which an epoxy resin-based powder coating material which contains an epoxy resin, a phenolic resin, and zinc and is produced by a melt kneading method is applied to a surface of a spring on which a coating-film is formed and a baking process in which the applied epoxy resin-based powder coating material is baked.Type: GrantFiled: March 8, 2017Date of Patent: December 24, 2024Assignees: CHUO HATSUJO KABUSHIKI KAISHA, SHINTO PAINT CO., LTD.Inventors: Takayuki Okamoto, Yasuhiko Kunita, Shota Otsuka, Masaki Kannami
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Patent number: 11958938Abstract: Provided is a curative part usable in a two-part curable composition. The curative part includes a liquid amine; a heterogeneous dispersant; and core-shell rubber particles having an elastomeric core and a (meth)acrylic shell. The core-shell rubber particles and the heterogeneous dispersant can be collectively shear-dispersed in the liquid amine such that the core-shell rubber particles are substantially non-aggregated and the curative part is phase-stable over a period of at least 3 months at ambient temperature. Advantageously, large amounts of core-shell rubber particles can thus be incorporated into a cured resin matrix, which can afford significantly enhanced impact performance.Type: GrantFiled: April 9, 2021Date of Patent: April 16, 2024Assignee: 3M Innovative Properties CompanyInventors: Lianzhou Chen, Sohaib Elgimiabi, Dmitriy Salnikov, Jay S. Schlechte, Yaoyao Chen
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Patent number: 11738585Abstract: The present invention relates to a method for applying an image onto the recording medium, the method including the step of applying a primer composition comprising a stoichiometric polyelectrolyte complex to a recording medium. The present invention further relates to a printing apparatus for carrying out said method.Type: GrantFiled: March 23, 2021Date of Patent: August 29, 2023Assignee: CANON PRODUCTION PRINTING HOLDING B.V.Inventors: Thomas F. Van Dijkman, Daniel H. Turkenburg
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Patent number: 10184034Abstract: The carbon fiber forming raw material is a carbon fiber forming raw material (Z) as a prepreg including sizing agent-coated carbon fibers and a thermosetting resin or a carbon fiber forming raw material (Y) as a forming material that includes sizing agent-coated carbon fibers and has a woven fabric form or a braid form. The sizing agent includes components (A) and (B). The component (A) is an epoxy compound having two or more epoxy groups or two or more types of functional groups. The component (B) is one or more compounds selected from the group consisting of a tertiary amine compound, a tertiary amine salt, a quaternary ammonium salt, a quaternary phosphonium salt, and a phosphine compound. The component (B) is contained in an amount of 0.1 to 25 parts by mass relative to 100 parts by mass of the component (A).Type: GrantFiled: November 12, 2012Date of Patent: January 22, 2019Assignee: TORAY INDUSTRIES, INC.Inventors: Yoshifumi Nakayama, Toshiya Kamae, Daigo Kobayashi, Makoto Endo
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Patent number: 9908953Abstract: Controlled thermal crosslinking in a polyacrylate-based composition is accomplished by a crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups, comprising at least one substance comprising at least one epoxide group (crosslinker) and at least one substance of the general formula (I) R1R2N—CR3R4—CR5R6—(CR7R8)n—NR9R10??(I) wherein the radicals R1, R2, R9 and R10 independently of one another are a hydrogen atom or a substituted or unsubstituted alkyl or cycloalkyl radical having 1 to 8 carbon atoms or an alkylene group bonded to the main chain and having 1 to 8 carbon atoms, where at least one of the radicals R1, R2, R9 and R10 is not a hydrogen atom; the radicals R3, R4, R5, R6, R7 and R8 independently of one another are a hydrogen atom or an alkyl group having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; and n is an integer from 0 to 4 (accelerator).Type: GrantFiled: January 18, 2013Date of Patent: March 6, 2018Assignee: TESA SEInventors: Alexander Prenzel, Sarah Bamberg, Jennifer Beschmann, Marten Papenbroock
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Patent number: 9593444Abstract: Disclosed is a method for producing a sizing agent-coated carbon fibers, wherein at least one kind of sizing agent that is selected from the group consisting of sizing agents (a), (b) and (c) is used for coating, in each of the sizing agents a bi- or higher functional epoxy compound (A1) and/or an epoxy compound (A2) being used as a component (A), and the epoxy compound (A2) having a mono- or higher functional epoxy group and at least one functional group that is selected from among a hydroxyl group, an amide group, an imide group, a urethane group, a urea group, a sulfonyl group and a sulfo group. The sizing agent is applied to carbon fibers and the resulting is subjected to a heat treatment within the temperature range of 160-260° C. for 30-600 seconds.Type: GrantFiled: June 24, 2011Date of Patent: March 14, 2017Assignee: TORAY INDUSTRIES, INC.Inventors: Yoshifumi Nakayama, Toshiya Kamae, Daigo Kobayashi, Makoto Endo
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Patent number: 9206301Abstract: Structural, radically curable resin compositions suitable for (re)lining contain: a. 30-70 wt. % of a resin characterized by (i) a molecular weight Mn between 500 and 3000 and (ii) an acid value between 0 and 30 mg KOH/g resin, and wherein at least 80% of the total amount of resin is vinyl ester resin, b. 30-70 wt. % of at least one reactive diluent, characterized in that at least 25% of the reactive diluent is a difunctional diluent having a molecular weight Mn between 200 and 500 and the optional monofunctional diluent having a molecular weight Mn between 100 and 200, c. 0.00001-5 wt. % initiator, d. 0.00001-5 wt. % inhibitor. wherein the average molecular weight per reactive unsaturation (WPU) of the components (a) and (b) is equal or greater than 190 Dalton and that the amount of styrene in the resin composition is less than 5 wt. % (calculated as wt. % of the total weight of the components (a), (b), (c) and (d)).Type: GrantFiled: May 9, 2013Date of Patent: December 8, 2015Assignee: DSM IP ASSETS B.V.Inventors: Joanna Klein Nagelvoort, Cornelis Den Besten, Johan Franz Gradus Antonius Jansen
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Patent number: 9162431Abstract: Provided is a gas-barrier laminate film that has a layer containing a one-pack adhesive coating material layer having good adhesiveness to various substrates and containing a polyamine resin. The laminate film has at least a substrate, an adhesive coating material layer and a sealant layer laminated in this order, wherein the adhesive coating material to form the adhesive coating material layer contains a polyamine resin, the polyamine resin contains a skeletal structure represented by the following formula (1) in an amount of at least 40% by mass, and the polyamine resin contains a metal atom in an amount of from 2.Type: GrantFiled: July 26, 2011Date of Patent: October 20, 2015Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Nobuhiko Matsumoto, Eiichi Honda, Kana Okada
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Patent number: 9028970Abstract: Provided are an adhesive composition with good storage stability, heat resistance, moisture resistance reliability, and adhesion properties; and a curl- and heat-resistant adhesive film and a wiring film using the adhesive composition. The adhesive composition contains 100 parts by weight of a phenoxy resin (A) having plural alcoholic hydroxyl groups in a side chain of the molecule thereof; 2 to 60 parts by weight of a polyfunctional isocyanate compound (B) having an isocyanate group and at least one functional group selected from vinyl, acrylate, and methacrylate groups in the molecule thereof; and 5 to 30 parts by weight of a maleimide compound (C) having plural maleimide groups in the molecule thereof or/and reaction product thereof, in which a total amount of the components (B) and (C) is from 7 to 60 parts by weight.Type: GrantFiled: February 20, 2013Date of Patent: May 12, 2015Assignee: Hitachi Metals, Ltd.Inventors: Satoru Amou, Tomiya Abe, Daisuke Shanai, Hiroaki Komatsu, Kenichi Murakami
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Publication number: 20150126691Abstract: Methods are generally provided for preparing a polymeric composition that includes a grafted block copolymer. Methods are also generally provided for preparing a polymeric composition that includes a star block copolymer prepared from a central core molecule that includes a plurality of attachment moieties. Methods are also generally provided for preparing a polymeric composition that includes a linear block copolymer. Block copolymers are also generally provided. Multi-segmented linear block copolymers are also generally provided.Type: ApplicationFiled: October 17, 2014Publication date: May 7, 2015Inventors: Chuanbing Tang, Christopher G. Hardy, Alper Nese, Jeffery Hayat
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Patent number: 9005761Abstract: A halogen-free resin composition includes (A) 100 parts by weight of epoxy resin; (B) 1 to 100 parts by weight of benzoxazine resin per 100 parts by weight of (A); (C) 1 to 100 parts by weight of styrene-maleic anhydride per 100 parts by weight of (A); (D) 0.5 to 30 parts by weight of amine curing agent per 100 parts by weight of (A); and (E) 5 to 150 parts by weight of halogen-free flame retardant per 100 parts by weight of (A). The composition obtains properties of low dielectric constant, low dissipation factor, high heat resistance and flame retardancy by specific composition and ratio. Thus, a prepreg or a resin film, which can be applied to a copper clad laminate and a printed circuit board, is formed.Type: GrantFiled: December 22, 2011Date of Patent: April 14, 2015Assignee: Elite Material Co., Ltd.Inventor: Yu-Te Lin
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Publication number: 20150080535Abstract: The present invention relates to a process for the preparation of a hydroxy-amino polymer, comprising the steps: a) reacting an H-functional starter compound carrying at least one Zerewitinoff-active H atom with an unsaturated cyclic carboxylic acid anhydride to give a carboxyl-group-carrying prepolymer, b) reacting the carboxyl-group-carrying prepolymer with at least one epoxide compound to give a hydroxyl-group-carrying prepolymer, c) adding a primary amine and/or ammonia to the double bond of the hydroxyl-group-carrying prepolymer obtained according to step b) to give the hydroxy-amino polymer, wherein the ratio of the amount of carboxylic acid anhydride to the number of Zerewitinoff-active H atoms of the H-functional starter compound is so chosen that almost all the Zerewitinoff-active H atoms of the H-functional starter compound are reacted.Type: ApplicationFiled: December 17, 2012Publication date: March 19, 2015Inventors: Jörg Hofmann, Klaus Lorenz, Hartmut Nefzger
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Patent number: 8927677Abstract: A curable epoxy resin composition comprising (a) at least one epoxy resin; (b) at least one curing agent; and (c) at least one high molecular weight poly(propylene oxide) poiyol toughening agent; and a process for preparing the curable epoxy resin composition.Type: GrantFiled: March 22, 2011Date of Patent: January 6, 2015Assignee: Dow Global Technologies LLCInventors: Radhakrishnan Karunakaran, Rajesh Turakhia
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Patent number: 8895148Abstract: A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200° F. (93° C.). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins, toughening components, and inorganic filler particles. The catalyst part (B) includes an aliphatic or cyclic amine compound as a curing agent and inorganic filler. In another embodiment, the structural adhesive composition is based on a one-part system, which includes the components of the resinous part (A) mixed with a latent amine curing agent. The one-part system may further include an imidazole and/or an aliphatic amine.Type: GrantFiled: October 16, 2012Date of Patent: November 25, 2014Assignee: Cytec Technology Corp.Inventors: Junjie Jeffrey Sang, Dalip Kumar Kohli, Kunal Gaurang Shah
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Publication number: 20140336301Abstract: The invention provides highly functional epoxy resins that may be used themselves in coating formulations and applications but which may be further functionalized via ring-opening reactions of the epoxy groups yielding derivative resins with other useful functionalities. The highly functional epoxy resins are synthesized from the epoxidation of vegetable or seed oil esters of polyols having 4 or more hydroxyl groups/molecule. In one embodiment, the polyol is sucrose and the vegetable or seed oil is selected from corn oil, castor oil, soybean oil, safflower oil, sunflower oil, linseed oil, tall oil fatty acid, tung oil, vernonia oil, and mixtures thereof. Methods of making of the epoxy resin and each of its derivative resins are disclosed as are coating compositions and coated objects using each of the resins.Type: ApplicationFiled: February 4, 2011Publication date: November 13, 2014Inventors: Dean C. Webster, Partha Pratim Sengupta, Zhigang Chen, Xiao Pan, Adlina Paramarta
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Patent number: 8883938Abstract: The present invention provides a resin composition for a fiber-reinforced composite material, which has excellent fluidity at low temperature and which produces a cured product having excellent mechanical strength, and also provides a cured product thereof, a fiber-reinforced composite material, a fiber-reinforced resin molding having excellent heat resistance, and a process for producing a fiber-reinforced resin molding with good productivity. A resin composition for a fiber-reinforced composite material contains, as essential components, an epoxy resin (A), an acid group-containing radical polymerizable monomer (B), a radical polymerization initiator (C), and an amine-based curing agent (D) for an epoxy resin, and has a viscosity of 500 mPa·s or less at 50° C. measured with an E-type viscometer. The composition is impregnated into reinforcing fibers and cured.Type: GrantFiled: September 14, 2010Date of Patent: November 11, 2014Assignee: DIC CorporationInventors: Atsuko Kobayashi, Ichirou Ogura
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Patent number: 8790779Abstract: A thermally curable adhesive in strip or film form, having a thickness in the range of 0.1 to 5 mm, containing: a) at least one reactive epoxy prepolymer, b) at least one latent hardener for epoxies, and c) one or more elastomers that are selected from: c1) thermoplastic polyurethanes, c2) thermoplastic isocyanates, and c3) block copolymers having thermoplastic polymer blocks. Further components can additionally be contained, for example a blowing agent for foaming. The adhesive in the uncured state at 22° C. is bendable or wrappable and can be extended at least 100% before tearing. It can be laid onto a foil. It can be used, for example, for adhesive bonding of planar, tubular, or cylindrical components, preferably components made of metal, wood, ceramic, or ferrites.Type: GrantFiled: November 16, 2011Date of Patent: July 29, 2014Assignee: Henkel AG & Co. KGaAInventors: Eugen Bilcai, Emilie Barriau, Martin Renkel, Sven Wucherpfennig
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Patent number: 8759422Abstract: An adhesive composition comprising elastomeric polymer, epoxy resin, reactive diluent, and filler, is suitable for use within the electronics industry, and in particular for wafer back side coating adhesives. The elastomeric polymer is a mixture of a vinyl elastomer and an epoxy elastomer; the reactive diluent is a combination of two or more diluents, one of which must have carbon to carbon unsaturation, providing cross-linking within the composition after cure; and the filler is a non-conductive filler.Type: GrantFiled: March 13, 2013Date of Patent: June 24, 2014Assignee: Henkel IP & Holding GmbHInventors: Eric C. Wang, Kevin Harris Becker, Qizhuo Zhuo
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Patent number: 8748536Abstract: Multi-piece, solid golf balls containing an inner core, an intermediate layer surrounding the core, and an outer cover are provided. At least one layer is made from an epoxy composition comprising a curing agent such as zinc diacrylate or zinc dimethacrylate. The epoxy composition is produced by reacting an epoxy prepolymer with a curing agent. Preferably, the epoxy composition is used to form an intermediate and/or cover layer resulting in a golf ball having high resiliency, good impact durability, and soft feel.Type: GrantFiled: October 5, 2009Date of Patent: June 10, 2014Assignee: Acushnet CompanyInventors: Brian Comeau, David A. Bulpett
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Patent number: 8716413Abstract: A method for the preparation of a photocurable resin by a reaction comprising the following steps i) reacting a mixture of a novolak type epoxy resin (A) and a dicyclopentadiene-phenol glycidylether resin (B) with ii) an advancement component (C) containing at least 2 phenolic hydroxyl groups per molecule; iii) reacting with an unsaturated monocarboxylic acid (D); and iv) esterification of the unsaturated group containing resin obtained from the steps of i) to iii) with a polycarboxylic acid anhydride or a carboxylic acid anhydride (E) is disclosed.Type: GrantFiled: June 12, 2009Date of Patent: May 6, 2014Assignee: Huntsman Advanced Materials Americas LLCInventors: Kai Dudde, Sabine Pierau, Martin Roth
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Patent number: 8618231Abstract: A reactive component suitable for use in a radiation-curable composition, which comprises an acrylated epoxy-amine oligomer represented by the formula (I): C-B-[A-B]n-A-B-C wherein: n is from 2 to 500; each A is individually a unit derived from a diglycidyl ether; each B is individually a unit derived from a difunctional secondary amine or a monofunctional primary amine; and each C is individually a unit derived from a multifunctional acrylate monomer, radiation-curable compositions, such as inks, coatings and adhesives, comprising said reactive component and methods of making said reactive component.Type: GrantFiled: October 19, 2009Date of Patent: December 31, 2013Assignee: Sun Chemical B.V.Inventors: Shaun Herlihy, Luisa Fuertes
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Patent number: 8618194Abstract: A resin mortar composition suitable for construction purposes is disclosed. The composition includes a resin component (A) curable with an aliphatic amine and a peroxide and a hardener component (H) with at least one peroxide (B) and at least one amine (C). At least one of the resin component (A) and the hardener component (H) contains at least one inorganic filler and the resin component (A) and the hardener component (H) or the resin composition (A) and the at least one peroxide (B) and the at least one amine (C) of the hardener component (H) are spatially separated from one another. The resin component (A) includes a compound (a) capable of undergoing a radical polymerization, a compound (b) capable of reacting with an amine, a transition metal compound (c), at least one inhibitor (d) to adjust the gel time and a bridging compound (e) having at least two reactive functionalities.Type: GrantFiled: February 10, 2011Date of Patent: December 31, 2013Assignee: Hilti AktiengesellschaftInventor: Armin Pfeil
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Patent number: 8597785Abstract: The present invention provides an adhesive tape comprising a flux-active compound having a carboxyl group and/or a phenolic hydroxyl group, a thermosetting resin and a film-forming resin. In the adhesive tape of the present invention, the thermosetting resin may be an epoxy resin and may contain a curing agent. The curing agent may be an imidazole compound and/or a phosphorous compound. The adhesive tape of the present invention can be used as an interlayer material for a circuit board and a multilayered flexible printed circuit board.Type: GrantFiled: September 28, 2007Date of Patent: December 3, 2013Assignee: Sumitomo Bakelite Co., Ltd.Inventors: Toshio Komiyatani, Takashi Hirano, Kenzou Maejima, Satoru Katsurayama, Tomoe Yamashiro
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Publication number: 20130299747Abstract: The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.Type: ApplicationFiled: March 11, 2013Publication date: November 14, 2013Inventor: Stephen M. Dershem
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Patent number: 8575280Abstract: Disclosed is a thermosetting resin composition including; (A) a carboxyl group-containing polyurethane prepared by using (a) a polyisocyanate compound (b) polyol compounds (c) a carboxyl group-containing dihydroxy compound as raw materials, (B) a curing agent, wherein the polyol compounds (b) are one or more kinds of polyol compound(s) selected from Group (I) and one or more kinds of polyol compound(s) selected from Group (II); Group I: polycarbonate polyol, polyether polyol, polyester polyol, and polylactone polyol, Group II: polybutadiene polyol, polysilicone having terminal hydroxyl groups, and such a polyol that has 18 to 72 carbon atoms and oxygen atoms present only in hydroxyl groups. The thermosetting resin composition can give a protection film for flexible printed circuits that has excellent long-term reliability of electric insulation, flexibility, and low warpage from curing shrinkage, and particularly low tackiness.Type: GrantFiled: December 7, 2006Date of Patent: November 5, 2013Assignee: Showa Denko K.K.Inventors: Hiroshi Uchida, Ritsuko Azuma
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Publication number: 20130230676Abstract: Compositions are disclosed that comprise at least one compound of formula IV: wherein the variable are as defined in the specification. The compositions are antimicrobial and optionally curable, and useful, inter alia, in dental, medical, and industrial applications for reinforcement and/or adhering two surfaces together.Type: ApplicationFiled: August 24, 2012Publication date: September 5, 2013Inventors: John D. Blizzard, Kirk Kimmerling, Joseph P. Rapp
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Publication number: 20130187095Abstract: The invention is based on the discovery that adhesive compositions containing certain low-viscosity, mono-ethylenically unsaturated monomers have surprisingly good cure parameters, resulting in very little weight loss upon cure. Many of these monofunctional monomers used alone or in combination with other monofunctional monomers described herein have high glass transition temperatures when cured. Moreover, since these monomers are monofunctional the crosslink density of the adhesive composition does not increase (relative to multi-functional monomers), which in turns results in lower stress, lower modulus adhesive compositions. As such, these monomers are useful in a variety of thermoset adhesive compositions, such as for example, die attach adhesive compositions.Type: ApplicationFiled: February 16, 2013Publication date: July 25, 2013Applicant: DESIGNER MOLECULES, INC.Inventor: Designer Molecules, Inc.
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Patent number: 8491749Abstract: A two-part structural adhesive composition comprising a curable epoxy resin, an amine curing agent, a toughening agent, and a reactive liquid modifier. The structural adhesive may also include secondary curatives, initiators, reactive diluents and combinations thereof. The structural adhesives may be used to replace or augment conventional joining means such as welds or mechanical fasteners in bonding parts together.Type: GrantFiled: July 22, 2009Date of Patent: July 23, 2013Assignee: 3M Innovative Properties CompanyInventors: Ilya Gorodisher, Alphonsus V. Pocius, Babu N. Gaddam
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Patent number: 8487052Abstract: The present invention provides a resin composition for a fiber-reinforced composite material, which has excellent fluidity and impregnation into a fiber base material and which produces a cured product having excellent heat resistance. A resin composition for a fiber-reinforced composite material contains, as essential components, a poly(glycidyloxyaryl) compound (A), a polymerizable monomer (B) which is an unsaturated carboxylic acid or an anhydride thereof and has a molecular weight of 160 or less, an aromatic vinyl compound or a (meth)acrylate (C), and a radical polymerization initiator (D), wherein an equivalent ratio [glycidyloxy group/acid group] of a glycidyloxy group in the component (A) to an acid group in the component (B) is 1/1 to 1/0.48, and a molar ratio [(B)/(C)] of the component (B) to the component (C) is in the range of 1/0.55 to 1/2.Type: GrantFiled: August 6, 2010Date of Patent: July 16, 2013Assignee: DIC CorporationInventors: Atsuko Kobayashi, Ichirou Ogura
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Publication number: 20130178590Abstract: An epoxy resin composition of the following chemical structure (I), where n is a number from 1 to about 3000; each m independently has a value of 0 or 1; each R0 is independently —H or —CH3; each R1 is independently —H or a C1 to C6 alkylene radical (saturated divalent aliphatic hydrocarbon radical), Ar is a divalent aryl group or heteroarylene group; and X is a cycloalkylene group, including a substituted cycloalkylene group, where the substituent group include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent group, for example, a halogen, a nitro, or a blocked isocyanate, an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.Type: ApplicationFiled: September 14, 2011Publication date: July 11, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Xin Jin, Ray E. Drumright, Bernhard Kainz, Jerry W. White, Robert E. Hefner, JR.
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Publication number: 20130082547Abstract: There are provided a sealing resin composition for a hard disk drive (HDD) motor and a HDD motor fabricated by using the same. The sealing resin composition includes 40 to 80 parts by weight of epichlorohydrin-4,4-isopropylidene diphenol resin; 5 to 20 parts by weight of acrylated ester; and 5 to 15 parts by weight of acrylated epoxy. The sealing resin composition containing a UV curable epoxy resin is used as a sealing material of the adhering part of the FPC of the HDD motor, whereby generation of outgas in the adhering part may be reduced.Type: ApplicationFiled: December 20, 2011Publication date: April 4, 2013Inventors: Kun Kim, Myung Hwa Choi, Sang Hyun Kwon, Hyung Kyu Kim
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Patent number: 8409669Abstract: A method and system for the spray application of epoxy materials is provided. The system includes a dual walled tank structure as a reservoir for containing and preheating the epoxy materials in preparation for mixing and spray application. Each component of the epoxy material is preheated before the components are mixed. After preheating, the components are then mixed together and spray applied. The method and system of the present invention provides a high quality spray applied epoxy coating while reducing equipment down time and cleaning.Type: GrantFiled: November 7, 2008Date of Patent: April 2, 2013Inventors: Danny R. Warren, David Allan Smith
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Patent number: 8389653Abstract: A urethane coating is formed by a reaction of a hydroxy-functional resin and a blocked isocyanate crosslinker. A method of catalyzing this reaction includes forming a polymeric ligand from the resin and/or the crosslinker. The method also includes incorporating a metal catalyst with the polymeric ligand to complex the metal catalyst with the polymeric ligand. The method further includes reacting resin and the crosslinker to form the urethane coating.Type: GrantFiled: March 30, 2006Date of Patent: March 5, 2013Assignee: BASF CorporationInventors: Timothy S. December, Cesar G. Ortiz, Hardy Reuter, Karl-Heinz Grosse-Brinkhaus, Guenter Ott
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Patent number: 8389630Abstract: Provided is a curable composition excellent in curability and mechanical properties as well as a cured product thereof. Specially provided is a curable composition containing a vinyl-based polymer (I) having one or more crosslinkable functional groups at a terminus on average and a nucleophilic agent (II) and a cured product obtained by curing the curable composition. Preferably, the curable composition of the invention further contains an epoxy resin (III).Type: GrantFiled: December 27, 2006Date of Patent: March 5, 2013Assignee: Kaneka CorporationInventors: Hitoshi Tamai, Kohei Ogawa, Yoshiki Nakagawa
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Epoxy resin hardener compositions and epoxy resin compositions containing such hardener compositions
Patent number: 8389652Abstract: An epoxy resin hardener composition including a reaction product of (i) a compound having at least one vicinal epoxy group, and (ii) an amino alcohol; an epoxy resin composition including the epoxy resin hardener composition and a compound having at least one vicinal epoxy group; and a powder coating composition including particles of the epoxy resin hardener composition and particles of a compound having at least one vicinal epoxy group.Type: GrantFiled: January 6, 2009Date of Patent: March 5, 2013Assignee: Dow Global Technologies LLCInventors: Joseph Gan, Matthieu M. Eckert, Carola Rosenthal, Bernhard Kainz, Emile C. Trottier -
Patent number: 8304034Abstract: The present invention relates to one-solution type thermosetting resin composition for a protective film of a color filter, and a color filter including the same. The one-solution type thermosetting resin composition includes a copolymer (A) including (meth)acrylate with an epoxy cyclic structure at the side chain, (meth)acrylate with a hydroxyl terminal, acid anhydride, and maleimide with a substituent; an epoxy resin (B); a base-generating agent (C); and an organic solvent (D). When a protective film of a color filter is prepared by using the one-solution type thermosetting resin composition according to the present invention, it has excellent storage stability as well as excellent flatness, close-contacting property, transmission properties, heat resistance, and chemical resistance.Type: GrantFiled: December 31, 2007Date of Patent: November 6, 2012Assignee: Cheil Industries Inc.Inventors: Hyun-Moo Choi, O-Bum Kwon, Sun-Yul Lee
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Publication number: 20120259039Abstract: The present invention provides a resin composition for a fiber-reinforced composite material, which has excellent fluidity at low temperature and which produces a cured product having excellent mechanical strength, and also provides a cured product thereof, a fiber-reinforced composite material, a fiber-reinforced resin molding having excellent heat resistance, and a process for producing a fiber-reinforced resin molding with good productivity. A resin composition for a fiber-reinforced composite material contains, as essential components, an epoxy resin (A), an acid group-containing radical polymerizable monomer (B), a radical polymerization initiator (C), and an amine-based curing agent (D) for an epoxy resin, and has a viscosity of 500 mPa·s or less at 50° C. measured with an E-type viscometer. The composition is impregnated into reinforcing fibers and cured.Type: ApplicationFiled: September 14, 2010Publication date: October 11, 2012Applicant: DIC CorporationInventors: Atsuko Kobayashi, Ichirou Ogura
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Publication number: 20120259042Abstract: A low viscosity toughened epoxy resin formulation including a divinylbenzene dioxide as a component in the formulation; wherein the formulation is useful for the manufacture of thermoset polymers.Type: ApplicationFiled: November 22, 2010Publication date: October 11, 2012Inventors: Stephanie L. Potisek, Mark B. Wilson
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Patent number: 8278401Abstract: This invention relates to curable sealants that provide low moisture permeability and good adhesive strength after cure. The composition comprises an aromatic compound having meta-substituted reactive groups and a cationic or radical initiator.Type: GrantFiled: March 29, 2006Date of Patent: October 2, 2012Assignee: Henkel AG & Co. KGaAInventors: Shengqian Kong, Sarah E. Grieshaber
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Patent number: 8268200Abstract: Provided is a pigment dispersing composition for a color filter including a color material, a resin, and an organic solvent which may dissolve the resin, wherein a modified pigment (D) is contained as the color material which includes, on the surface of a pigment (A), a polymer (P) obtained by polymerizing a polymer (B) containing a polymerizable unsaturated group soluble in a non-aqueous solvent and at least one type of polymerizable unsaturated monomer (C) which is soluble in the non-aqueous solvent and becomes either insoluble or poorly soluble following polymerization, alternatively wherein a modified pigment (D) is contained as the color material which is obtained, under the presence of a pigment (A), a non-aqueous solvent, and a polymer (B) containing a polymerizable unsaturated group soluble in the non-aqueous solvent, by polymerizing at least one type of polymerizable unsaturated monomer (C).Type: GrantFiled: March 23, 2009Date of Patent: September 18, 2012Assignee: DIC CorporationInventors: Hiroshi Kinoshita, Seiji Funakura, Eiichi Kiuchi, Yoshinori Katayama
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Patent number: 8268932Abstract: This invention relates to the use of resin compositions for chemical anchoring, wherein the resin composition comprises at least: a. a thiol-containing component, and b. a resin containing one or more reactive moieties selected from the group of: i. non-aromatic carbon double bond moieties, and ii. epoxide moieties, and an initiator. Preferably, the resin composition further comprises a diluent, more preferably a reactive diluent. Furthermore, the present invention also relates to the use of a multi-component, preferably a 2-component system of which one component contains a thiol group(s) containing component for chemical anchoring by means of cold curing.Type: GrantFiled: October 5, 2006Date of Patent: September 18, 2012Assignee: DSM IP Assets B.V.Inventors: Johan Franz Gradus Antonius Jansen, Michael Alphonsus Cornelis Johannes Van Dijck, Marco Marcus Matheus Driessen
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Publication number: 20120232228Abstract: Compounds are provided according to structure 1: in which R?H or methyl and R2=optionally substituted C1-C20 alkyl, optionally substituted C6-C20 aryl, part of a oligomeric or polymeric residue (>C20), which can be optionally substituted.Type: ApplicationFiled: March 13, 2012Publication date: September 13, 2012Applicant: DSM IP ASSETS B.V.Inventors: Joanna KLEIN NAGELVOORT, Cornelis DEN BESTEN, Johan Franz Gradus JANSEN
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Patent number: 8236157Abstract: A pigment dispersing resin is disclosed along with pigment dispersion, electrodepositable coating compositions using the pigment dispersing resin, and methods for applying the electrodepositable coating composition. The pigment dispersing resin consists essentially of the carboxylic acid salt of an aminated bisphenol epoxy resin and an alkoxylated styrenated phenol. Pigment dispersions made from the dispersing resin are especially useful for forming low or no volatile organic content electrocoating baths.Type: GrantFiled: December 12, 2008Date of Patent: August 7, 2012Assignee: E I du Pont de Nemours and CompanyInventor: Taddesse Gebregiorgis
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Patent number: 8217099Abstract: A thermosetting resins composite, composed of: epoxy resin which can have a total polymerization with bismaleimide, occupying 1.75%-18.0% solids weight of the composite; bismaleimide compounds, occupying 0.15%-12.5% solids weight of the composite; free radical initiator, its mole fraction of which its addition accounts for reaction monomer total is 0.01%-0.15%; inhibitor, whose amount is the half to double of the initiator; styrene-maleic anhydride copolymers, occupying 17.5%-47.0% solids weight of the composite; filler, occupying 20%-60% solids weight of the composite; solvent, occupying 30%-50% solids weight of the composite; flame retardant which can be used in CCL industries.Type: GrantFiled: May 22, 2008Date of Patent: July 10, 2012Assignees: ITEQ (Dongguan) Corporation, ITEQ CorporationInventors: Yufang He, Lijun Su
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Patent number: 8173726Abstract: A process including the polymerization of a reactive diluent, which is present in an aqueous dispersion that further includes an epoxy-amine material, is disclosed. The resulting composition is useful as a coating composition.Type: GrantFiled: October 7, 2010Date of Patent: May 8, 2012Assignee: Valspar Sourcing, Inc.Inventors: Martin Peter Joseph Heuts, Lonnie Jones
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Patent number: 8163155Abstract: A coating layer prepared from an aqueous electrodeposition coating composition comprising an electrodepositable binder, the binder comprising a sulfo or sulfamyl group-containing resin, provides corrosion protection to a metallic substrate.Type: GrantFiled: December 29, 2008Date of Patent: April 24, 2012Assignee: BASF Coatings GmbHInventors: Abdellatif Chouai, Timothy S December
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Patent number: 8158728Abstract: Materials and Methods are provided for fabricating microfluidic devices. The materials include low surface energy fluoropolymer compositions having multiple cure functional groups. The materials can include multiple photocurable and/or thermal-curable functional groups such that laminate devices can be fabricated. The materials also substantially do not swell in the presence of hydrocarbon solvents.Type: GrantFiled: August 9, 2006Date of Patent: April 17, 2012Assignee: The University of North Carolina at Chapel HillInventors: Joseph M. DeSimone, Jason P. Rolland, Ginger M. Denison Rothrock, Paul Resnick
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Publication number: 20120041102Abstract: The present invention relates to a novel epoxy resin having improved heat-resistance, thermal expansion properties and processability, and to a thermosetting resin composition comprising the same. To this end, the present invention provides an epoxy resin of Chemical Formula 1 as disclosed in the Description, an epoxy resin composition comprising the same, and a packaging, substrate and transistor formed thereof. When a composition that contains an epoxy resin with a specific side functional group according to the present invention and/or an epoxy resin with a specific core structure is cured, a filler forms a strong chemical bond with the epoxy resin, thereby maximizing filling effects of the filler for the epoxy resin. Moreover, with the specific core structure, heat resistance and heat expansion properties of a cured product are substantially improved (CTE is reduced), and enhanced glass transition properties, strength and processability are demonstrated.Type: ApplicationFiled: April 23, 2010Publication date: February 16, 2012Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGYInventors: Hyun-Aee Chun, Seung-Han Shin, Hyun-Ah Kim, Chang-Ho Oh, Yun-Ju Kim, Sang-Yong Tak, Myong-Hoon Lee, Tae-Yun Kang
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Patent number: 8114508Abstract: The present invention provides a composition of the modified maleic anhydride and the epoxy resins, including (A) one or more of the epoxy resin mixtures, (B) a modified maleic anhydride copolymer, (C) additives and (D) inorganic filler materials, wherein component (A) the epoxy resin mixture accounts for 35%˜56% by weight of the composition solids, component (B) the modified maleic anhydride copolymer accounts for 44%˜65% by weight of the composition solids, based on 100% by weight of total components (A), (B) and (C).Type: GrantFiled: October 20, 2009Date of Patent: February 14, 2012Assignee: Nan Ya Plastics CorporationInventor: Ming Jen Tzou
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Publication number: 20120022183Abstract: The disclosure relates to a composition having at least one radically polymerisable monomer M; at least one radical former, at least one epoxide resin A including an average of more than one epoxide group per molecule, and at least one compound of formula (I). Such compositions are suitable as adhesives, sealants or coatings. Shortly after the application thereof, they have a high initial strength and, after further hardening at room temperature, they reach a high level of final strength.Type: ApplicationFiled: January 14, 2011Publication date: January 26, 2012Applicant: SIKA TECHNOLOGY AGInventors: Markus Haufe, Andreas Kramer