Bridged Monomer Patents (Class 526/281)
  • Patent number: 8647730
    Abstract: A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer obtained by ring-opening polymerization of 2-norbornene. The hydrogenated norbornene ring-open polymer has a weight average molecular weight determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution of 1.5 to 10.0, and a melting point of 110 to 145° C. A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. A resin composition and a molding material.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: February 11, 2014
    Assignee: Zeon Corporation
    Inventors: Nobuhiro Kudo, Koichi Ikeda
  • Publication number: 20140034883
    Abstract: The present invention relates to a polymerizable liquid crystal compound, a liquid crystal composition including the same, and an optically anisotropic body. The polymerizable liquid crystal compound according to the present invention has not only high birefringence but also excellent coating orientation, and thus it is possible to prepare a optically anisotropic body which is thin but superior in optical properties.
    Type: Application
    Filed: June 26, 2013
    Publication date: February 6, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Kyung-Chang SEO, Sung-Ho Chun, Dai-Seung Choi, Mi-Ra Hong, Hyeong-Bin Jang
  • Publication number: 20140026340
    Abstract: An inventive composition that has utility as an article for cleaning a target surface is provided. Embodiments of the inventive composition are readily applied to a substrate to form a cleaning article or form a free-standing article; the composition upon drying forms a matrix having a coefficient of friction of greater than one, and a glass transition temperature that is between 0° C. and 40° C. The matrix is amenable to loading with various additives illustratively including re-enforcing fibers, abrasives, plasticizers, foaming agents, fragrances, and combinations thereof. Embodiments of the inventive composition operate to clean a substrate such as a vehicle and ideally return the same to the original look and feel without requiring excessive work, or requiring the removal of too much material from the surface.
    Type: Application
    Filed: July 24, 2013
    Publication date: January 30, 2014
    Applicant: HTI USA, INC.
    Inventors: Robert E. Buxbaum, Herschel S. Wright
  • Patent number: 8629226
    Abstract: A retardation film, formed by stretching a film having a norbornene-based ring-opening copolymer containing a structural unit (A) represented by the general formula (1) and a structural unit (B) represented by the general formula (2), wherein the content of structural unity (A) is not less than 5 mol % but not more than 95 mol % relative to the total amount of structural units (A) and (B).
    Type: Grant
    Filed: December 24, 2010
    Date of Patent: January 14, 2014
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Takeshi Koike, Shinichi Komatsu, Tetsuya Uesaka, Hisashi Sone, Yuji Takahashi
  • Patent number: 8609005
    Abstract: [Problems] To provide a stretched film of an addition polymer consisting of norbornene compounds favorable for use in manufacturing steps of electric insulating parts and optical parts that exhibits excellent film stability, does not suffer from coloration and has a low linear expansion coefficient. [Means for Solving Problems] A stretched film of an addition polymer consisting of norbornene compounds produced by stretching a film of the addition polymer consisting of norbornene compounds and having a linear expansion coefficient of at most 50 ppm/° C. The draw ratio is preferably from 1.2 times to 10 times. The stretched film is preferably a non-crosslinked film. A method for producing the stretched film comprises stretching a film of the addition polymer consisting of norbornene compounds at least in one direction in an inert gas atmosphere within a temperature range of the glass transition temperature (Tg) thereof ±50° C.
    Type: Grant
    Filed: May 15, 2007
    Date of Patent: December 17, 2013
    Assignee: Zeon Corporation
    Inventors: Yoshihisa Takeyama, Atsushi Ishiguro
  • Patent number: 8609574
    Abstract: Embodiments in accordance with the present invention encompass methods of forming in situ olefin polymerization catalyst systems, catalysts encompassed by such systems and polymers made using such systems. For such in situ olefin polymerization catalyst systems, a hydrocarbyl magnesium halide is generally contacted with a halohydrocarbyl compound to form a halohydrocarbyl Grignard and such Grignard is generally contacted with a Group 10 metal compound to form an olefin polymerization catalyst which is contacted with one or more olefin monomers to form a polymer therefrom.
    Type: Grant
    Filed: April 23, 2009
    Date of Patent: December 17, 2013
    Assignee: Promerus LLC
    Inventors: Larry F. Rhodes, Luis Francisco Martin, Andrew Bell
  • Patent number: 8603728
    Abstract: A copolymer comprises the polymerized product of a base-soluble monomer of formula (I): wherein Ra is H, F, C1-10 alkyl, or C1-10 fluoroalkyl, L1 is an m valent C2-30 alkylene, C3-30 cycloalkylene, C6-30 arylene, C7-30 aralkylene group, X1 is independently a base-soluble organic group comprising ?-diketone, ?-ester-ketone, ?-di-ester, or a combination comprising at least one of the foregoing; and an additional monomer copolymerizable with the base-soluble monomer of formula (I).
    Type: Grant
    Filed: May 29, 2012
    Date of Patent: December 10, 2013
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Gregory P. Prokopowicz, Gerhard Polhers, Mingqi Li, Chunyi Wu, Cong Liu, Cheng-bai Xu
  • Patent number: 8604148
    Abstract: This invention relates to a polymer of a cyclic olefin and a vinyl terminated macromonomer, and processes for the production thereof.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: December 10, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Matthew W. Holtcamp, Donna J. Crowther, Caol P. Huff, Patrick Brant, Jacqueline A. Lovell
  • Publication number: 20130320326
    Abstract: A composition for forming an insulating material used in electronic devices which includes, as a polymerizable component, a monomer comprising two or more (meth)acrylic moieties and a polycyclic alicyclic structure.
    Type: Application
    Filed: February 14, 2012
    Publication date: December 5, 2013
    Inventors: Naoki Kurihara, Masatoshi Saito
  • Publication number: 20130323646
    Abstract: A polymer is obtained from copolymerization of a unit having a carboxyl and/or phenolic hydroxyl group substituted with an acid labile group with a hydroxyphenyl methacrylate unit having one acyl, acyloxy or alkoxycarbonyl group. The polymer is useful as a base resin in a positive resist composition. The resist composition comprising the polymer is improved in contrast of alkali dissolution rate before and after exposure, acid diffusion control, resolution, and profile and edge roughness of a pattern after exposure.
    Type: Application
    Filed: May 9, 2013
    Publication date: December 5, 2013
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Jun Hatakeyama, Masayoshi Sagehashi
  • Patent number: 8597769
    Abstract: There are provided an etching mask which has a superior thermal imprinting characteristic and also a good anti-etching characteristic, a base material with the etching mask, a microfabricated product to which those etching mask and base material are applied, and a production method of the microfabricated product. The etching mask formed of a thermoplastic resin containing at least one kind of skeleton expressed by a chemical formula (1) or a chemical formula (2) in a main chain wherein R1, R2, R3, R4, R5, R6, R7, R8 in the formulae (1), (2) can be different or same one another, each of which is a hydrogen atom, a deuterium atom, a hydrocarbon group having a carbon number of 1 to 15, a halogen atom, or a substituent group containing a hetero atom like oxygen or sulfur, and may form a ring structure one another and wherein m and n are integers equal to or greater than 0.
    Type: Grant
    Filed: November 13, 2008
    Date of Patent: December 3, 2013
    Assignee: Maruzen Petrochemical Co. Ltd.
    Inventors: Yoshiaki Takaya, Takuro Satsuka, Yoshihisa Hayashida, Takahisa Kusuura, Anupam Mitra
  • Patent number: 8598288
    Abstract: A catalyst for a polymerization of norbornene monomers includes a transition metal complex represented by a formula (1). A method for producing a norbornene copolymer includes copolymerizing first norbornene monomers corresponding to a first monomer unit represented by a formula (2) and second norbornene monomers corresponding to a second monomer unit represented by a formula (3) in a presence of the catalyst. The transition metal complex is preferably (?-allyl) {2-[N-(2,6-diisopropylphenyl) iminomethyl]phenolate}palladium, (?-allyl) {2-[N-(2,6-diisopropylphenyl)iminomethyl]-4-fluorophenolate}palladium, (?-allyl)[2-(N-phenyliminomethyl) phenolate]palladium or (?-allyl){2-[N-(2,6-diisopropylphenyl) iminomethyl]-6-methylphenolate}palladium.
    Type: Grant
    Filed: October 30, 2012
    Date of Patent: December 3, 2013
    Assignee: Showa Denko K.K.
    Inventors: Satoshi Fujibe, Nobuyuki Kibino, Tsuneo Tajima
  • Publication number: 20130317156
    Abstract: This invention relates to the new functional norbornanyl ester derivative and/or polymer compositions which are easily obtainable by reacting the Diels-Alder adduct of appropriate dienes and dienophiles with carboxylic acids. In particular, this invention relates to a new process for making cyclic chemical raw materials suitable for production coating, ink, adhesive, plasticizer, thermoplastic or thermosetting plastic and functional polymers.
    Type: Application
    Filed: May 25, 2012
    Publication date: November 28, 2013
    Applicant: New Functional Polymers LLC
    Inventor: Hui Yu
  • Patent number: 8592618
    Abstract: The present invention relates to a kind of novel carbene ligands and ruthenium catalysts, which is highly active and selective for ROMP and RCM reactions, respectively. It discloses the significant electronic and steric effect of different substituted carbene ligands on the catalytic activity and stability of corresponding carbene ruthenium complexes; some of novel ruthenium complexes in the invention can be broadly used as catalysts highly effectively and selective for ROMP and RCM reactions. The invention also relates to preparation of new ruthenium catalysts and the uses in metathesis. Moreover, the invention also provides effective methods of making various functional polymers by ROMP reaction in the presence of new ruthenium catalysts.
    Type: Grant
    Filed: January 8, 2010
    Date of Patent: November 26, 2013
    Assignee: Zannan Scitech Co., Ltd.
    Inventor: Zheng-Yun James Zhan
  • Patent number: 8586160
    Abstract: A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer obtained by ring-opening polymerization of 2-norbornene. The hydrogenated norbornene ring-open polymer has a weight average molecular weight determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution of 1.5 to 10.0, and a melting point of 110 to 145° C. A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. A resin composition and a molding material.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: November 19, 2013
    Assignee: Zeon Corporation
    Inventor: Koichi Ikeda
  • Publication number: 20130302726
    Abstract: A chemical amplification resist composition contains: (A) a polymer compound having a structure where a hydrogen atom of a phenolic hydroxyl group is replaced by a group having a non-acid-decomposable polycyclic alicyclic hydrocarbon structure; and (B) a compound capable of generating an acid upon irradiation with an actinic ray or radiation.
    Type: Application
    Filed: July 16, 2013
    Publication date: November 14, 2013
    Inventors: Tomotaka TSUCHIMURA, Tadateru YATSUO
  • Patent number: 8580477
    Abstract: Embodiments in accordance with the present invention encompass negative-tone, aqueous base developable, self-imageable polymer compositions useful for forming films that can be patterned to create structures for microelectronic devices, microelectronic packaging, microelectromechanical systems, optoelectronic devices and displays.
    Type: Grant
    Filed: September 21, 2009
    Date of Patent: November 12, 2013
    Assignee: Promerus LLC
    Inventors: Brian Knapp, Edmund Elce, Andrew Bell, Cheryl Burns, Sridevi Kaiti, Brian Kocher, Hendra Ng, Yogesh Patel, Masanobu Sakamoto, Xiaoming Wu, Linda Zhang
  • Publication number: 20130285026
    Abstract: Embodiments in accordance with the present invention relate generally to the use of polycycloolefinic polymers as a structure defining material in organic electronic devices, and more specifically to separators, insulating structures or bank structures of such devices and to organic electronic devices comprising such structures, to processes for preparing such structures and to organic electronic devices encompassing such structures.
    Type: Application
    Filed: April 24, 2013
    Publication date: October 31, 2013
    Applicants: Promerus LLC, Merck Patent GmbH
    Inventors: Pawel Miskiewicz, Tomas Backlund, Philip Edward May, Toby Cull, Larry F. Rhodes, Edmund Elce, Andrew Bell
  • Patent number: 8530583
    Abstract: A composition for film formation which can form a film suitable for use as an interlayer dielectric in a semiconductor device, etc. and having an appropriate even thickness and can give a film having excellent characteristics including permittivity and Young's modulus; and a dielectric film obtained from the film-forming composition. The composition contains a compound (X) having a functional group which is partly eliminated by heating, irradiation with light, irradiation with radiation, or a combination thereof to generate volatile matter and yield an unsaturated group in the remaining part of the functional group.
    Type: Grant
    Filed: November 10, 2009
    Date of Patent: September 10, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Kenji Wada, Katsuyuki Watanabe, Keiji Yamamoto
  • Patent number: 8530134
    Abstract: Disclosed is a process for producing a photoresist polymeric compound. The process includes the steps of polymerizing a monomer mixture containing at least one monomer selected from a monomer (a) containing a group capable of leaving with an acid to allow the polymeric compound to be soluble in an alkali, a monomer (b) having a lactone skeleton, and a monomer (c) having a hydroxyl-containing alicyclic skeleton, to give a polymer; passing a solution containing the polymer through a filter including a porous membrane having an anion-exchange group to give a polymer solution; and thereafter passing the polymer solution through a filter including a porous membrane having a cation-exchange group. The polymer solution before passing through the filter including a porous membrane having a cation-exchange group preferably has a content of metals of 1000 ppb by weight or less per the weight of the polymer.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: September 10, 2013
    Assignee: Daicel Chemical Industries, Ltd.
    Inventor: Tadashi Teranishi
  • Patent number: 8519073
    Abstract: A compound represented by general formula (I); and a polymeric compound including a structural unit (a1) represented by general formula (II). wherein R represents a hydrogen atom, a halogen atom, a lower alkyl group or a halogenated lower alkyl group; each of R1 to R3 independently represents an alkyl group or a fluorinated alkyl group, with the provision that no fluorine atom is bonded to a carbon atom adjacent to the tertiary carbon atom to which R1 to R3 are bonded, and at least one of R1 to R3 represents a fluorinated alkyl group; and R2 and R3 may form a ring structure.
    Type: Grant
    Filed: October 15, 2007
    Date of Patent: August 27, 2013
    Assignees: Tokyo Ohka Kogyo Co., Ltd., Daito Chemix Corporation
    Inventors: Yoshiyuki Utsumi, Hiroaki Shimizu, Kyoko Ohshita, Toshiharu Shimamaki, Kenshin Niwa, Seihin Shu
  • Publication number: 20130216951
    Abstract: A radiation-sensitive resin composition includes a polymer, an acid generating agent, and an organic solvent. The polymer includes a first structural unit derived from a compound represented by a formula (1), and a second structural unit derived from a compound represented by a formula (2). R1 represents an organic group having a valency of (a+2) that represents a ring structure having 3 to 8 carbon atoms together with the carbon atom constituting a lactone ring. R2 represents a fluorine atom, a hydroxyl group, an organic group having 1 to 20 carbon atoms or the like.
    Type: Application
    Filed: March 29, 2013
    Publication date: August 22, 2013
    Applicant: JSR CORPORATION
    Inventor: JSR Corporation
  • Patent number: 8487059
    Abstract: A one step process for making a dendritic hydrocarbon polymer, e.g., dendritic polyolefin, by metathesis insertion polymerization. The process comprises polymerizing an amount of one or more cyclic olefins and one or more multi-functional (meth)acrylates in the presence of a metathesis catalyst and under conditions sufficient to produce the dendritic hydrocarbon polymer. The one or more multi-functional (meth)acrylates have a functionality of 3 or higher. The dendritic hydrocarbon polymer can be hydrogenated to produce a substantially saturated dendritic hydrocarbon polymer. The hydrogenation can take place in the same reaction vessel as the polymerization, i.e., one pot process.
    Type: Grant
    Filed: November 22, 2011
    Date of Patent: July 16, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Yong Yang, Andy Haishung Tsou
  • Patent number: 8481166
    Abstract: A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer obtained by ring-opening polymerization of 2-norbornene. The hydrogenated norbornene ring-open polymer has a weight average molecular weight determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution of 1.5 to 10.0, and a melting point of 110 to 145° C. A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. A resin composition and a molding material.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: July 9, 2013
    Assignee: Zeon Corporation
    Inventors: Haruhiko Takahashi, Teiji Kohara, Nobuhiro Kudo, Koichi Ikeda, Tokudai Ogawa, Takeshi Hirata
  • Publication number: 20130164676
    Abstract: To provide a novel acrylic ester derivative which can form a structural unit of a polymer to be incorporated into a photoresist composition, a polymer produced through polymerization of a raw material containing the acrylic ester derivative, and a photoresist composition which contains the polymer and which, as compared with the case of conventional ones, realizes formation of a high-resolution resist pattern having improved LWR. The invention provides a carbamoyloxyadamantane derivative represented by the following formula (wherein R represents a hydrogen atom, a methyl group, or a trifluoromethyl group), a polymer produced by polymerizing a raw material containing the carbamoyloxyadamantane derivative, and a photoresist composition containing the polymer, a photoacid generator, and a solvent.
    Type: Application
    Filed: August 25, 2011
    Publication date: June 27, 2013
    Applicant: KURARAY CO., LTD.
    Inventors: Takashi Fukumoto, Manabu Yada
  • Patent number: 8470510
    Abstract: A polymer for lithographic purposes has at least a repeating structural unit represented by following General Formula (I). In Formula (I), R1, R3, R4, and R6 each independently represent hydrogen atom, a halogen atom, cyano group, an alkyl group, or a haloalkyl group; R2 and R5 each independently represent hydrogen atom, cyano group, etc.; X1 and X2 each independently represent single bond, or a substituted or unsubstituted bivalent alkylene, alkenylene, or cycloalkylene group, etc.; X3 and X4 each independently represent single bond or —CO—; R7, R8, R9, and R10 each independently represent hydrogen atom, an alkyl group, or a cycloalkyl group. The polymer for lithographic purposes shows good balance between line edge roughness (LER) and etching resistance and allows very fine and uniform patterning.
    Type: Grant
    Filed: June 1, 2009
    Date of Patent: June 25, 2013
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Arimichi Okumura, Keizo Inoue, Kazuki Okamoto
  • Publication number: 20130123452
    Abstract: The present invention relates to accelerators for curing unsaturated polyester resins, vinyl ester resins, and acrylic resins in conjunction with peroxide type initiators. The accelerators are based on iron/manganese complexes of a tridentate, tetradentate, pentadentate, or hexadentate nitrogen donor ligands. Also disclosed are curable resin compositions including the forgoing accelerators and a curing process for employing these accelerators. These resin compositions show good curing properties and do not contain cobalt accelerators. The present invention further relates to gel coats and molded composites prepared from such unsaturated polyester, vinyl ester, and acrylic resins.
    Type: Application
    Filed: January 6, 2011
    Publication date: May 16, 2013
    Applicant: OMG ADDITIVES LIMITED
    Inventors: Ronald Hage, Richard Allen Reichert, JR.
  • Publication number: 20130116113
    Abstract: Provided are a catalyst composition comprising a main catalyst (A) and a promoter (B), wherein the main catalyst (A) is a complex represented by Formula (1): MLnK1xK2yK3z ??(1) (wherein M is one transition metal selected from groups 8 to 10 elements; L is a cyclopentadienyl base ligand containing; K1 to K3 are anionic or neutral ligands which are different from each other; n is an integer of 0 to 2; x, y and z each are an integer including 0, and a sum thereof is 1 to 7); and the promoter (B) is a compound (a) reacted with the main catalyst (A) to form a cationic compound, used for a high molecular weight addition copolymer of a norbornene compound having a polar group, a process for producing the copolymer using the above catalyst composition, and a film of the above copolymer.
    Type: Application
    Filed: July 25, 2011
    Publication date: May 9, 2013
    Applicant: SHOWA DENKO K.K.
    Inventors: Shojiro Kaita, Olivier Tardif
  • Patent number: 8431626
    Abstract: Dental compositions and disulfide monomers described. The disulfide monomer comprises a disulfide backbone group wherein each of the sulfur atoms are bonded to a group terminating with an ethylenically unsaturated norbornyl group; and at least one other monomer comprising at least two ethylenically unsaturated groups.
    Type: Grant
    Filed: May 18, 2011
    Date of Patent: April 30, 2013
    Assignees: 3M Innovative Properties Company, The Regents of the University of Colorado
    Inventors: Christopher N. Bowman, Hee Young Park, Christopher J. Kloxin, Ahmed S. Abuelyaman, Joel D. Oxman, Yizhong Wang
  • Publication number: 20130095339
    Abstract: The present invention provides a display panel equipped with a front plate and a display device, in each of which streak unevenness is sufficiently resolved in the periphery of a display area. The display panel equipped with a front plate of the present invention comprises: a display panel; a front plate; and a cured resin composition layer disposed between the display panel and the front plate, wherein the cured resin composition layer has a loss tangent of 2 or less at 0 to 70° C.
    Type: Application
    Filed: June 14, 2011
    Publication date: April 18, 2013
    Inventors: Akiyoshi Fujii, Tokio Taguchi, Chiaki Minari, Takashi Yoshizawa, Katsuhisa Senda, Mitsutoshi Naito, Eishi Katakami, Tsubasa Shiine
  • Patent number: 8420755
    Abstract: The present invention relates to a novel metallocene compound, a catalyst composition including the compound and an olefin polymer prepared using the same. The metallocene compound and the catalyst composition can be used for preparing the olefin polymer with high copolymerization degree and high molecular weight. Particularly, the block copolymer with high heat resistance can be prepared by using the metallocene compound, and the olefin polymer with high melting point (Tm) can be obtained, even if co-monomer is used at an increased amount in preparation of olefin polymer.
    Type: Grant
    Filed: August 17, 2010
    Date of Patent: April 16, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Young-Chul Won, Sung-Ho Chun, Dai-Seung Choi, Dong-Woo Yoo, Bun-Yeoul Lee
  • Patent number: 8415424
    Abstract: An aromatic ring-containing polymer for an underlayer of a resist, including a unit structure represented by Chemical Formula 1:
    Type: Grant
    Filed: July 2, 2012
    Date of Patent: April 9, 2013
    Assignee: Cheil Industries, Inc.
    Inventors: Min-Soo Kim, Hwan-Sung Cheon, Sung-Wook Cho, Seung-Bae Oh, Jee-Yun Song
  • Patent number: 8404792
    Abstract: Described is a cyclobutene polymer comprising: monomeric units of cyclobutene, said cyclobutene having at least one fused ring system substituted thereon, said polymer comprising not more than 10 mol percent ring-opened units of said cyclobutene; and said polymer having a molecular weight of at least 1,000; said polymer optionally copolymerized with a comonomer to form a copolymer therewith. Compositions thereof and methods of making the same are also described.
    Type: Grant
    Filed: August 30, 2011
    Date of Patent: March 26, 2013
    Assignee: North Carolina Sate University
    Inventors: Bruce M. Novak, Keitaro Seto
  • Publication number: 20130072650
    Abstract: The invention provides certain novel water-soluble and water-insoluble monomers for ring opening metathesis polymerization and novel polymers, compositions and products, and related methods thereof.
    Type: Application
    Filed: November 11, 2012
    Publication date: March 21, 2013
    Applicant: University of Massachuetts
    Inventor: University of Massachusetts
  • Patent number: 8399725
    Abstract: This invention relates to a functionalized co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94(mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)?83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a functionalized homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making functionalized homo- or co-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.
    Type: Grant
    Filed: June 19, 2009
    Date of Patent: March 19, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Patrick Brant, Donna J. Crowther
  • Publication number: 20130059993
    Abstract: A catalyst for a polymerization of norbornene monomers includes a transition metal complex represented by a formula (1). A method for producing a norbornene copolymer includes copolymerizing first norbornene monomers corresponding to a first monomer unit represented by a formula (2) and second norbornene monomers corresponding to a second monomer unit represented by a formula (3) in a presence of the catalyst. The transition metal complex is preferably (?-allyl){2-[N-(2,6-diisopropylphenyl)iminomethyl]phenolate}palladium, (?-allyl){2-[N-(2,6-diisopropylphenyl)iminomethyl]-4-fluorophenolate}palladium, (?-allyl)[2-(N-phenyliminomethyl)phenolate]palladium or (?-allyl){2-[N-(2,6-diisopropylphenyl)iminomethyl]-6-methylphenolate}palladium.
    Type: Application
    Filed: October 30, 2012
    Publication date: March 7, 2013
    Applicant: SHOWA DENKO K.K.
    Inventor: SHOWA DENKO K.K.
  • Patent number: 8383743
    Abstract: Disclosed is an ink composition for jet printer, comprising a pigment, a film forming resin and an organic solvent, the film forming resin being an acrylic copolymer containing, as a monomer unit, at least one of compounds represented by the general formulas (1) and (2): wherein R1 represents a hydrogen atom or a methyl group; R2 represents an alkylene group having 2 to 12 carbon atoms which may be linear or branched; and R3 and R4 each independently represents a hydrogen atom, an alkyl group, an alkenyl group or an aryl group, and the sum of the number of carbon atoms of R3 and R4 is from 4 to 12, or R3 and R4 form a saturated or unsaturated hydrocarbon group which is a five-membered ring formed by combination of the R3 and R4; and wherein R1 represents a hydrogen atom or a methyl group; R2 represents an alkylene group having 2 to 12 carbon atoms which may be linear or branched; and X represents a group selected from the group consisting of groups represented by the general formulas (3) to (9).
    Type: Grant
    Filed: March 30, 2006
    Date of Patent: February 26, 2013
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Akio Kumagai, Hiromichi Arakawa, Shigehiro Tanaka, Kazuhiro Kaneko, Yoshinosuke Shimamura
  • Publication number: 20130041122
    Abstract: This invention relates to a process for producing a polymer of a cyclic olefin and a linear mono-olefin, the process comprising contacting at least one C5 based cyclic olefin with at least one linear mono-olefin having from two to twenty carbon atoms in the presence of an alkene metathesis catalyst, and the polymer so produced.
    Type: Application
    Filed: August 12, 2011
    Publication date: February 14, 2013
    Inventors: Matthew W. Holtcamp, John R. Hagadorn, Caol P. Huff, Matthew S. Bedoya, Catherine Anne Faler
  • Publication number: 20130030136
    Abstract: Disclosed is an optical material including a cyclic olefin copolymer containing at least a repeating structural unit [A] represented by the general formula (1) and a repeating structural unit [B] represented by the general formula (2) and having a molar ratio [A]/[B] of from 95/5 to 1/99, wherein the absolute value of the ratio ?OB/?F is from 0.001 to 0.250 in which ?OB represents the amount of a change in the absolute value of the orientation birefringence calculated from the phase difference (nm) at a wavelength of 633 nm/film thickness (?m) in a stretched film obtained from the optical material, and ?F represents the amount of a change in the absolute value of the orientation coefficient determined from the dichroic ratio of parallel light intensity I? to perpendicular light intensity I?, each relative to the orientation direction according to Raman spectroscopy.
    Type: Application
    Filed: April 4, 2011
    Publication date: January 31, 2013
    Applicants: MITSUI CHEMICALS, INC.
    Inventors: Tadahiro Sunaga, Takashi Oda, Hirofumi Io, Keisuke Kawashima, Yasuhiro Koike
  • Patent number: 8362171
    Abstract: Norbornene monomers with epoxy groups and polymer materials thereof are disclosed. The Norbornene monomers with epoxy groups are prepared by Diels-Alder reaction. The Norbornene monomers with epoxy groups are highly active for ring-opening-metathesis polymerization (ROMP), and the molecular weight and PDI value of the obtained polymers are controllable.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: January 29, 2013
    Assignee: National Taiwan University of Science & Technology
    Inventors: Der-Jang Liaw, Ching-Cheng Huang
  • Publication number: 20130018160
    Abstract: Nonconjugated conductive polymers absorb radioactive iodine, therefore are useful for protection against nuclear radiation. These polymers have at least one double bond per repeat unit. The ratio of the number of double bonds to the total number of bonds along the polymer chain is less than half. Examples of nonconjugated conductive polymers include: cis-1,4-polyisoprene (natural rubber), trans-1,4-polyisoprene (gutta percha), polybutadiene, polydimethyl butadiene, poly(b-pinene), styrene butadiene rubber (SBR), polyalloocimene, polynorbornene and many others. Through interaction with iodine atoms the double bonds in the nonconjugated polymers transform into radical cations leading to a dark color. The iodine atoms remain (immobile) bound to the polymer chain through the charge-transfer interaction, these polymers are very inexpensive and can be easily processed into any shape, structure and size. Therefore, these are useful for protection against nuclear radiation including radioactive iodine.
    Type: Application
    Filed: July 11, 2011
    Publication date: January 17, 2013
    Inventor: Mrinal Thakur
  • Patent number: 8344083
    Abstract: The present invention relates to a transparent resin composition which comprises (a) a (meth)acrylate based unit comprising one or more (meth)acrylate based derivatives; (b) an aromatic based unit having a chain having the hydroxy group containing portion and an aromatic moiety and (c) a styrene-based unit comprising one or more styrene-based derivatives, and an optical film that is formed by using the same.
    Type: Grant
    Filed: May 4, 2009
    Date of Patent: January 1, 2013
    Assignee: LG Chem, Ltd.
    Inventors: Jun-Geun Um, Min-Hee Lee, Nam-Jeong Lee, Jong-Hun Lee, Dong-Ryul Kim, Sae-Han Cho
  • Patent number: 8329840
    Abstract: The present invention relates to a photo-reactive norbornene-based copolymer which has superior miscibility to various organic solvents or additives while exhibiting superior liquid crystal alignment property and can be preferably used to an alignment layer of liquid crystal display device, a method of preparing the same, and an alignment layer including the same.
    Type: Grant
    Filed: July 6, 2011
    Date of Patent: December 11, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Dong-Woo Yoo, Sung-Ho Chun, Young-Chul Won, Dai-Seung Choi
  • Patent number: 8324332
    Abstract: A resin for thermal imprint including a cyclic-olefin-based thermoplastic resin that contains at least one of skeletons represented by the following chemical equation 1 or the following chemical equation 2 in a main chain. The glass transition temperature Tg (° C.) and the value ([M]) of MFR at 260° C. satisfy the following equation 1, and [M]>10. The thermal imprint characteristics (transferability, mold release characteristic, and the like) are superior and the productivity (throughput) is improved. Tg (° C.
    Type: Grant
    Filed: August 25, 2006
    Date of Patent: December 4, 2012
    Assignees: Scivax Corporation, Maruzen Petrochemical Co., Ltd.
    Inventors: Takemori Toshifumi, Yoshiaki Takaya, Takahito Mita, Tetsuya Iizuka, Yuji Hashima, Takahisa Kusuura, Mitsuru Fujii, Takuji Taguchi, Anupam Mitra
  • Patent number: 8324334
    Abstract: Olefin metathesis polymerization reactions are disclosed, and more particularly ring-opening metathesis polymerization of cyclic olefins with olefinic compounds, such as are derived from seed oils and the like, to form telechelic polymers. In one aspect, a method is provided for carrying out a catalytic ring-opening metathesis polymerization reaction, comprising contacting at least one olefinic compound with at least one cyclic olefin, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring-opening metathesis polymerization of the cyclic olefin, whereby the cyclic olefin polymer formed is terminated with the olefinic compound. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial chemistry.
    Type: Grant
    Filed: August 21, 2009
    Date of Patent: December 4, 2012
    Assignee: Materia, Inc.
    Inventors: Simon C. Jones, Farshad J. Motamedi, Li-Sheng Wang, Brian Edgecombe, Michael A. Giardello
  • Patent number: 8318876
    Abstract: The invention provides a method for producing a thermosetting resin from renewable oils, the method comprising supplying renewable oil molecules containing strained ring alkene moieties; reacting the alkene moieties with cyclic alkenes to create a polymer; and repeating the above two steps until the resin having desired characteristics are obtained. Also provided is a thermoset resin comprising functionalized renewable oil polymerized with a co-monomer.
    Type: Grant
    Filed: January 25, 2012
    Date of Patent: November 27, 2012
    Assignee: U.S. Department of Energy
    Inventors: Richard C. Larock, Phillip H. Henna, Michael R. Kessier
  • Publication number: 20120295227
    Abstract: Dental compositions and disulfide monomers described. The disulfide monomer comprises a disulfide backbone group wherein each of the sulfur atoms are bonded to a group terminating with an ethylenically unsaturated norbornyl group; and at least one other monomer comprising at least two ethylenically unsaturated groups.
    Type: Application
    Filed: May 18, 2011
    Publication date: November 22, 2012
    Inventors: Christopher N. Bowman, Hee Young Park, Christopher J. Kloxin, Ahmed S. Abuelyaman, Joel D. Oxman, Yizhong Wang
  • Publication number: 20120270155
    Abstract: There are provided a novel compound, a polymeric compound, a resist composition, an acid generator and a method of forming a resist pattern the compound represented by general formula (1-1): wherein each of R1 and R3 independently represents a single bond or a divalent linking group; A represents a divalent linking group; each of R2 and R4 independently represents a hydroxyl group, a hydrocarbon group which may have a substituent, or a group represented by general formula (1-an1), (1-an2) or (1-an3), provided that at least one of R2 and R4 represents a group represented by general formula (1-an1), (1-an2) or (1-an3); and n0 is preferably 0 or 1, and wherein Y1 represents a single bond or —SO2—; R5 represents a linear or branched monovalent hydrocarbon group of 1 to 10 carbon atoms, cyclic monovalent hydrocarbon group of 3 to 20 carbon atoms or monovalent hydrocarbon group of 3 to 20 carbon atoms having a cyclic partial structure which may be substituted with a fluorine atom; and M+ represents an organic ca
    Type: Application
    Filed: April 18, 2012
    Publication date: October 25, 2012
    Applicant: TOKYO OHKA KOGYO CO., LTD.
    Inventors: Yoshitaka Komuro, Yoshiyuki Utsumi, Akiya Kawaue, Masatoshi Arai
  • Patent number: 8293674
    Abstract: The present invention relates to a catalyst system for preparing a cyclic olefin addition polymer, a method for preparing the catalyst system and a cyclic olefin addition polymer prepared by the method, and more particularly to the method comprising the steps of contacting some content of norbornene-based monomer having a specific polar functional group with a catalyst system comprising a) a Group X transition metal compound; b) a compound comprising a neutral Group XV electron donor ligand having a cone angle of at least 160°; and c) a salt capable of offering an anion that can be weakly coordinated to the transition metal of the a) the Group X transition metal compound.
    Type: Grant
    Filed: June 16, 2011
    Date of Patent: October 23, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Sung-Ho Chung, Won-Kook Kim, Sung-Cheol Yoon, Tae-Sun Lim, Heon Kim, Kyoung-Hoon Kim
  • Patent number: 8273838
    Abstract: Embodiments of the invention provide a class of propylene/?-olefin block interpolymers. The propylene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block propylene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (“TREF”), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the propylene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.3.
    Type: Grant
    Filed: March 15, 2007
    Date of Patent: September 25, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Colin Li Pi Shan, Lonnie G. Hazlitt, Yunwa Wilson Cheung, Benjamin C. Poon, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, XiaoHua Qiu, Angela N. Taha