At Least Six Carbon Atoms Patents (Class 526/348.2)
  • Patent number: 7566761
    Abstract: The present invention provides an olefin polymer having a narrow molecular weight distribution and a specific molecular weight, an olefin polymer having a functional group introduced at the terminal, a tapered polymer containing a segment wherein monomer composition continuously changes in the polymer chain, an olefin polymer having different segments which are bonded to each other, and a process for preparing these polymers. The olefin polymers of the invention are polymers of olefins of 2 to 20 carbon atoms and have a number-average molecular weight of not less than 500 and Mw/Mn of not more than 1.5.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: July 28, 2009
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Makoto Mitani, Yasunori Yoshida, Junichi Mohri, Kazutaka Tsuru, Seiichi Ishii, Shinichi Kojoh, Tomoaki Matsugi, Junji Saito, Naoto Matsukawa, Shigekazu Matsui, Takashi Nakano, Hidetsugu Tanaka, Norio Kashiwa, Terunori Fujita
  • Patent number: 7560524
    Abstract: The instant invention is a high-density polyethylene composition, and method of making the same. The high-density polyethylene composition of the instant invention includes an ethylene alpha-olefin copolymer having a density in the range of 0.935 to 0.952 g/cm3, a melt index (I2) in the range of 30 to 75 g/10 minutes, an I21/I2 ratio in the range of 13-35, a Mw/Mn ratio in the range of 3.5-8. The high-density polyethylene composition has a brittleness temperature of at least less than ?20° C. The process for producing a high-density polyethylene composition according to instant invention includes the following steps: (1) introducing ethylene, and an alpha-olefin comonomer into a reactor; (2) copolymerizing the ethylene with the alpha-olefin comonomer in the reactor; and (3) thereby producing the high-density polyethylene composition, wherein the high-density polyethylene composition having a density in the range of 0.935 to 0.
    Type: Grant
    Filed: October 15, 2008
    Date of Patent: July 14, 2009
    Assignee: Dow Global Technologies, Inc.
    Inventors: William J. Michie, Jr., Debra R. Wilson, Stephanie M. Whited, Michael A. Kinnan
  • Patent number: 7550528
    Abstract: This invention relates to a composition comprising a functionalized C3 to C40 olefin polymer comprising at least 50 mol % of one or more C3 to C40 olefins, and where the olefin polymer, prior to functionalization, has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) an Mw of 10,000 to 100,000; and c) a branching index (g?) of 0.98 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 60,000, or a branching index (g?) of 0.95 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 100,000; and where the C3 to C40 olefin polymer comprises at least 0.001 weight % of an functional group, preferably maleic anhydride. This invention further relates to blends of such functionalized polymers with other polymers including non-functionalized C3 to C40 olefin polymers as described above.
    Type: Grant
    Filed: April 15, 2004
    Date of Patent: June 23, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Ramin Abhari, Charles Lewis Sims, Mun Fu Tse, Patrick Brant, Peijun Jiang, David Raymond Johnsrud
  • Publication number: 20090156729
    Abstract: An adhesive blend is described that can include a semi-crystalline copolymer of propylene and at least one comonomer selected from the group consisting of ethylene and at least one C4 to C20 ?-olefin, the copolymer having a weight average molecular weight (Mw) from about 15,000 to about 200,000; an melt index (MI) from about 7 dg/min to about 3000 dg/min as measured by ASTM D 1238(B), and a (Mw/Mn) of approximately 2. Various production processes are also described. Also described are adhesive compositions and methods for making adhesive compositions having polymers or polymer blends with melt flow rates (MFRs) equal to and above 250 dg/min. at 230 NC. Certain specific embodiments of the invention involve the use of a free radical initiator, e.g., a peroxide.
    Type: Application
    Filed: February 24, 2009
    Publication date: June 18, 2009
    Inventors: Anthony G. Karandinos, Keith A. Nelson, Jean M. Tancrede, Kenneth Lewtas, Sudhin Datta, Charles Cozewith, Bruce A. Harrington, David J. Lohse, Olivier J.F. Georjon
  • Publication number: 20090156772
    Abstract: In accordance with an aspect of the invention, methods of forming medical articles are provided, which comprise (a) preparing a melt phase that comprises a molten polymer and a supercritical fluid, (b) forming a polymeric region from the melt phase, and (c) cooling the polymeric region. In certain embodiments, the supercritical fluid is formed from chemical species (e.g., CO2, propane, etc.) that are gases at room temperature (25° C.) and atmospheric pressure (1 atm). According to another aspect of the present invention, medical articles are provided which comprise melt-processed polymeric materials. The polymeric materials have a composition that cannot be melt processed without the use of melt-viscosity reducing additives due to thermal degradation, and yet the polymeric material does not contain such additives.
    Type: Application
    Filed: December 12, 2007
    Publication date: June 18, 2009
    Applicant: Boston Scientific Scimed, Inc.
    Inventors: Frederick H. Strickler, Barron Tenney, Mark Boden
  • Publication number: 20090149613
    Abstract: A propylene copolymer is described comprising at least 70 mol % of units derived from propylene, up to 30 mol % of units derived from a combination of ethylene, at least one alpha-olefin having from 4 to 10 carbon atoms, such that the molar ratio of ethylene-derived units to said alpha-olefin-derived units in said combination is from about 1:9 to about 9:1, and from 0 to about 3 mol % of units derived from a copolymerizable diene. The copolymer has isotactically arranged propylene derived sequences, an overall heat of fusion as determined by differential scanning calorimetry (DSC) of less than 65 J/g, a second melting point as determined by DSC of less than 100° C., less than one 1,3 insertion error per 1000 carbon atoms and a weight average molecular weight as determined by gel permeation chromatography (GPC) of from about 100,000 to about 500,000.
    Type: Application
    Filed: October 26, 2007
    Publication date: June 11, 2009
    Inventors: Periagaram Srinivasan Ravishankar, Weiguo Hu
  • Patent number: 7541412
    Abstract: Disclosed is a method of producing a polyolefin composition comprising contacting a metallocene pre-catalyst with a substoichiometric amount of a co-catalyst; adding a first olefin monomer; and polymerizing the first monomer for a time sufficient to form the polyolefin. The method allows for the use of a minimum amount of activating co-catalyst, and allows for the production of stereoregular and non-stereoregular polyolefins. The use of configurationally stable metallocene pre-catalysts allows for the production of monomodal isotactic polyolefins having narrow polydispersity. The use of configurationally unstable metallocene pre-catalysts allows for the production of monomodal atactic polyolefins having narrow polydispersity. The method of the present invention optionally further comprises contacting the polyolefin with a second amount of said co-catalyst; adding a second olefin monomer; polymerizing said second olefin monomer to form a block-polyolefin composition.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: June 2, 2009
    Assignee: University of Maryland, College Park
    Inventor: Lawrence R. Sita
  • Publication number: 20090137756
    Abstract: Disclosed herein is a gas phase polymerization process including the steps of passing a recycle stream through a fluidized bed in a gas phase fluidized bed reactor in the presence of a bulk density promoting agent, wherein the bulk density promoting agent is of a saturated hydrocarbon and/or a non-polymerizable unsaturated hydrocarbon having 6 or more carbon atoms; polymerizing at least one alpha-olefin monomer in the presence of a catalyst to produce an alpha-olefin polymer; and controlling an amount of the bulk density promoting agent in the reactor such that a bulk density of the alpha-olefin polymer discharged from the reactor is greater than or equal to about 480 kg/m3.
    Type: Application
    Filed: November 12, 2008
    Publication date: May 28, 2009
    Inventors: R. Eric Pequeno, Robert O. Hagerty, Bruce J. Savatsky
  • Patent number: 7538174
    Abstract: An isotactic 1-butene copolymer having a content up to 30% by mol of at least one alpha-olefin of formula CH2?CHZ derived units, wherein Z is a C3-C20 hydrocarbon group, having the following features: isotactic pentads (mmmm) >90%; and a percentage of soluble fraction in diethylether (% SD) and a molar content of said alpha olefins (% O) in the polymer chain meeting the following relation: % SD>2.8% O+8.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: May 26, 2009
    Assignee: Basell Polyolefine GmbH
    Inventors: Luigi Resconi, Anteo Pelliconi, Enea Garagnani
  • Patent number: 7524911
    Abstract: An adhesive composition comprises: (i) at least one ethylene/?-olefin interpolymer, (ii) at least one tackifier; and (iii) optionally at least one additive, such as a plasticizer, wax and antioxidant. Preferably, the ethylene/?-olefin interpolymer has a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship: Tm?858.91?1825.3(d)+1112.8(d)2. The composition has relatively higher SAFT temperature and can be used in hot melt adhesives pressure-sensitive adhesives, and thermoplastic marking paints.
    Type: Grant
    Filed: March 15, 2006
    Date of Patent: April 28, 2009
    Assignee: Dow Global Technologies Inc.
    Inventors: Teresa P. Karjala, Selim Yalvac, Charles F. Diehl, Yunwa W. Cheung, Cynthia L. Rickey
  • Patent number: 7521507
    Abstract: An adhesive blend is described that can include a semi-crystalline copolymer of propylene and at least one comonomer selected from the group consisting of ethylene and at least one C4 to C20 ?-olefin, the copolymer having a weight average molecular weight (Mw) from about 15,000 to about 200,000; an melt index (MI) from about 7 dg/min to about 3000 dg/min as measured by ASTM D 1238(B), and a (Mw/Mn) of approximately 2. Various production processes are also described. Also described are adhesive compositions and methods for making adhesive compositions having polymers or polymer blends with melt flow rates (MFRs) equal to and above 250 dg/min. at 230° C. Certain specific embodiments of the invention involve the use of a free radical initiator, e.g., a peroxide.
    Type: Grant
    Filed: November 24, 2003
    Date of Patent: April 21, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Kenneth Lewtas, Sudhin Datta, Charles Cozewith, Bruce A. Harrington, David J. Lohse, Olivier J. F. Georjon, Anthony G. Karandinos, Keith A. Nelson, Jean M. Tancrede
  • Patent number: 7514517
    Abstract: Anti-blocking polymer compositions comprise at least one ethylene/?-olefin interpolymer and at least one anti-blocking agent comprising an amide. The ethylene/?-olefin interpolymers are a multi-block copolymer comprising at least one soft block and at least one hard block. The anti-blocking agent can be erucamide or other amides. The anti-blocking polymer composition has a pellet blocking strength of equal to or less than 100 lbs/ft2 (4800 Pa). When the anti-blocking polymer composition is made into a film, the film has a blocking force of less than about 100 grams, measured according to ASTM method D-3354.
    Type: Grant
    Filed: March 15, 2006
    Date of Patent: April 7, 2009
    Assignee: Dow Global Technologies Inc.
    Inventors: Stephen M. Hoenig, Yunwa W. Cheung, Daniel G. Moldovan
  • Publication number: 20090082523
    Abstract: The invention relates to a polyethylene resin having excellent slow crack growth property, in particular a resin having excellent durability in a pipe application, which has a specific (a) high-load melt flowrate (HLMFR; HLa), a specific (b) density (Da), and a specific (c) ?-olefin content (Ca) and in which (d) a breaking time (T) measured by notched Lander ESCR, the HLa, and the Ca satisfy log T??2.9×log HLa+5.1×log Ca+6.8. It further relates to a process for producing the resin and to a pipe and a joint each comprising the resin.
    Type: Application
    Filed: May 23, 2006
    Publication date: March 26, 2009
    Applicant: JAPAN POLYETHYLENE CORPORATION
    Inventors: Shigeki Saito, Yoshito Sasaki, Tetsuya Yoshikiyo, Hirofumi Nishibu
  • Patent number: 7504141
    Abstract: A shrink film comprising a polyethylene film, characterized in that said polyethylene is an ethylene copolymer mixture having a molecular weight distribution in the range 10 to 35, a density of 915 to 940 kg/m3, a weight average molecular weight of at least 100000 D and an MFR2.16 (190° C.) of 0.1 to 0.9 kg/m3, which copolymer mixture is produced by a two or more stage copolymerization of ethylene and 2 to 10% mole (relative to ethylene) of a C3-12 alpha-olefin comonomer in a series of reactors including at least one slurry loop reactor and at least one gas phase reactor using a heterogeneous Ziegler-Natta catalyst.
    Type: Grant
    Filed: July 29, 2003
    Date of Patent: March 17, 2009
    Assignee: Borealis Technology Oy
    Inventors: Ole Jan Myhre, Merete Skar, Hans Georg Daviknes, Kjetil Larsen Brove, Geir Morten Johansen
  • Patent number: 7491781
    Abstract: A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins containing magnesium, titanium, and halogen further contains an internal electron donor comprising a compound containing electron donating substituents with a structure: wherein D1 and D2 are selected individually from and R, R2, R3, R4, R5, R6, and R7 individually are hydrocarbon or substituted hydrocarbon groups containing 1 to 20 carbon atoms and R2, R3, R4, R6, and R7 may be hydrogen; R4 may be —NR2; and wherein groups R1 and R2, R2 and R3, R3 and R4, R3 and R5, and groups R6 and R7 may be joined to form a cyclic structure.
    Type: Grant
    Filed: March 1, 2006
    Date of Patent: February 17, 2009
    Assignee: INEOS USA LLC
    Inventors: Roger Uhrhammer, John P. Lalka
  • Publication number: 20090036621
    Abstract: A catalyst system suitable for the polymerisation of olefins, said system comprising (a) a transition metal compound or lanthanide metal compound (b) a cocatalyst and (c) at least one porous support material characterised in that the porous support material has been pretreated with a halogen-containing organometallic compound, in particularly with a fluorine-containing organometallic compound. The catalyst system is particularly suitable for the preparation of polymers having broad molecular weight distributions from the polymerisation of olefins in the presence of a single site catalyst.
    Type: Application
    Filed: December 20, 2006
    Publication date: February 5, 2009
    Inventors: Grant Berent Jacobsen, Sergio Mastroianni
  • Patent number: 7482418
    Abstract: Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
    Type: Grant
    Filed: December 9, 2005
    Date of Patent: January 27, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sudhin Datta, Charles Cozewith, Periagaram Ravishankar, Edmund J. Stachowski
  • Publication number: 20090017160
    Abstract: A chewing gum contains a water-insoluble gum base portion containing a polyolefin thermoplastic elastomer; a water-soluble bulk portion; and at least one flavor component, which is cud-forming and chewable at mouth temperature.
    Type: Application
    Filed: September 12, 2008
    Publication date: January 15, 2009
    Applicant: WM. Wrigley Jr. Company
    Inventors: Chungsea Shen, Joo H. Song, Bruno Padovani, David W. Record
  • Publication number: 20090018288
    Abstract: Crosslinked olefin polymers which are reduced in stickiness and improved in rigidity, heat resistance, light resistance, and water resistance while retaining the molding properties such as injection moldability, spinnability, film-forming properties and the physical properties such as toughness (including elongation and break strength) and tackiness; and a process for the production thereof. Crosslinked olefin polymers which are obtained by reacting an ?-olefin polymer produced by polymerization of at least one ?-olefin having 6 or more carbon atoms or polymerization of at least one ?-olefin having 6 or more carbon atoms with at least one other ?-olefin with a crosslinking agent and which satisfy the following requirements: (1) the content of units of ?-olefins having 6 or more carbon atoms is 50 mol % or more, (2) the molecular weight distribution (Mw/Mn) as determined by gel permeation chromatography (GPC) is 7.
    Type: Application
    Filed: November 7, 2005
    Publication date: January 15, 2009
    Applicant: Idemitsu Kosan Co., Ltd.
    Inventors: Ryo Aburatani, Yutaka Obata, Tomoaki Takebe, Masanori Sera, Yutaka Minami
  • Patent number: 7473745
    Abstract: Disclosed is a polyethylene composition. The composition comprises single-site multimodal resin A and single-site multimodal resin B, wherein resin A differs from resin B in molecular weight, in monomeric composition, in density, in long chain branch concentration or distribution, or in combinations thereof. Disclosed is also a method for making the polyethylene composition. The method comprises polymerizing, in the presence of two or more single-site catalysts, ethylene or its mixture with a C3-C10 ?-olefin to form a first multimodal resin and continuing the polymerization in the presence of the same catalysts but in a different hydrogen concentration, in a different monomer composition, or at a different temperature to form a second multimodal resin.
    Type: Grant
    Filed: September 2, 2005
    Date of Patent: January 6, 2009
    Assignee: Equistar Chemicals, LP
    Inventors: Venki Chandrashekar, Mark P. Mack, Charles H. Gates, Jr., Charles S. Holland, Natalia Nagy, Sandor M. Nagy, Edward S. Vargas, Jean A. Merrick-Mack
  • Publication number: 20080315066
    Abstract: A poly 4-methyl-1-pentene resin composition which includes a polymer containing 80% by mass or more of 4-methyl-1-pentene in which the resin composition has a melting point of 170 to 240° C. and a semicrystallization time of 70 to 220 seconds. Also provided are a release film having good releasibility, a mold for production of a sealed electronic element product having excellent heat resistance and releasibility and an LED mold, which are obtained by molding the resin composition.
    Type: Application
    Filed: July 28, 2005
    Publication date: December 25, 2008
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Tooru Tanaka, Toshiyuki Hirose
  • Publication number: 20080306217
    Abstract: The invention provides a comprising one or more ethylene interpolymers, and wherein the interpolymers, or the composition, has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein at least one ethylene interpolymer has an Rv from 0.3 to 0.99. The invention further provides a composition comprising at least one low molecular weight (LMW) ethylene interpolymer, and at least one high molecular weight (HMW) ethylene interpolymer, and wherein the composition has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein the sum of the Rv from the low molecular weight interpolymer and the high molecular weight interpolymer is from 0.3 to 2. The invention further provides for processes of making such compositions, processes for functionalizing the interpolymer(s) of such compositions, and articles comprising at least one component prepared from an inventive composition.
    Type: Application
    Filed: December 12, 2006
    Publication date: December 11, 2008
    Inventors: Teresa P. Karjala, Selim Yalvac, Cynthia L. Rickey, Sylvie Desjardins, Marc A. Springs
  • Patent number: 7459511
    Abstract: A process for polymerizing 1-butene comprising the step of contacting under polymerization conditions 1-butene and optionally from 0 to 20% by mol of an alpha olefin with a catalyst system obtainable by contacting a bridget metallocene compound of formula (I) wherein R1 and R2 are an hydrocarbon radical A is a carbon atom, a germanium atom or a silicon atom; m is 1, 2; M is a metal of group 4 of the Periodic Table of the Elements; X, is hydrogen, a halogen atom, or a group R, OR, OSO2CF3, OCOR, SR, NR2 or PR2, wherein the substituents R are hydrocarbon radical; L is a moiety of formula (IIa) or (IIb) wherein T is an oxigen (O) or sulphur (S) atom or a CH2 group; and R3 and R4 are hydrogen atoms or hydrocarbon radicals; one or more alumoxanes or compounds able to form an alkylmetallocene cation; and optionally an organo aluminium compound.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: December 2, 2008
    Assignee: Basell Polyolefine GmbH
    Inventor: Luigi Resconi
  • Patent number: 7456243
    Abstract: This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a supported catalyst composition. In one aspect, the present invention encompasses a catalyst composition comprising the contact product of a first metallocene compound, a second metallocene compound, at least one chemically-treated solid oxide, and at least one organoaluminum compound. The new resins were characterized by useful properties in impact, tear, adhesion, sealing, extruder motor loads and pressures at comparable melt index values, and neck-in and draw-down.
    Type: Grant
    Filed: September 29, 2005
    Date of Patent: November 25, 2008
    Assignee: Chevron Phillips Chemical Company, LP
    Inventors: Michael D. Jensen, Max P. McDaniel, Joel L. Martin, Elizabeth A. Benham, Randy Muninger, Gary Jerdee, Ashish M. Sukhadia, Qing Yang, Matthew G. Thorn
  • Patent number: 7456244
    Abstract: The instant invention is a high-density polyethylene composition, and method of making the same. The high-density polyethylene composition of the instant invention includes an ethylene alpha-olefin copolymer having a density in the range of 0.935 to 0.952 g/cm3, a melt index (I2) in the range of 30 to 75 g/10 minutes, an I21/I2 ratio in the range of 13-35, a Mw/Mn ratio in the range of 3.5-8. The high-density polyethylene composition has a brittleness temperature of at least less than ?20° C. The process for producing a high-density polyethylene composition according to instant invention includes the following steps: (1) introducing ethylene, and an alpha-olefin comonomer into a reactor; (2) copolymerizing the ethylene with the alpha-olefin comonomer in the reactor; and (3) thereby producing the high-density polyethylene composition, wherein the high-density polyethylene composition having a density in the range of 0.935 to 0.
    Type: Grant
    Filed: May 23, 2006
    Date of Patent: November 25, 2008
    Assignee: Dow Global Technologies
    Inventors: William J. Michie, Jr., Debra R. Wilson, Stephanie M. Whited, Michael A. Kinnan
  • Publication number: 20080287634
    Abstract: The present invention pertains to a heterogeneous ethylene/?olefin copolymer having a relatively high melt index range (I2 from 1.1 to 1.6 dg/min.), low density (0.915 to 0.919 g/cc) and narrow molecular weight distribution (I10/I2 from 7.0 to 7.7), and highly separated composition distribution as determined by SCBD; a process for making such a copolymer; blends thereof with additional polymers; and fabricated articles, especially films, made there from.
    Type: Application
    Filed: October 31, 2006
    Publication date: November 20, 2008
    Inventors: Jesus Nieto, Hendrik H. Hagen
  • Patent number: 7452948
    Abstract: An improved method for the preparation of a supported polymerisation catalyst system comprises the combination of (i) a porous support (ii) a polymerisable monomer, (iii) a polymerisation catalyst, and (iv) a cocatalyst, characterised in that the polymerisable monomer is added to the porous support before addition of one or both of the polymerisation catalyst and the cocatalyst. The preferred polymerisation catalyst is a metallocene complex and the preferred porous support is silica. The resultant supported catalysts are stable over long periods of time. The supported catalyst are particularly suitable for use in the gas phase.
    Type: Grant
    Filed: August 14, 2003
    Date of Patent: November 18, 2008
    Assignee: Ineos Europe Limited
    Inventors: Grant Berent Jacobsen, Brian Stephen Kimberley, Sergio Mastroianni, Michael John Taylor
  • Publication number: 20080281037
    Abstract: An adhesive composition comprises: (i) at least one ethylene/?-olefin interpolymer, (ii) at least one tackifÊer; and (iii) optionally at least one additive, such as a plasticizer, wax and antioxidant. Preferably, the ethylene/?-olefin interpolymer has a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship: Tm?858.91?1825.3(d)+1112.8(d)2. The composition has relatively higher SAFT temperature and can be used in hot melt adhesives pressure-sensitive adhesives, and thermoplastic marking paints.
    Type: Application
    Filed: March 15, 2006
    Publication date: November 13, 2008
    Inventors: Teresa P. Karjala, Selim Yalvac, Charles F. Diehl, Yunwa W. Cheung, Cynthia L. Rickey
  • Patent number: 7449534
    Abstract: The invention provides a process for the preparation of a propylene polymer in which proplylene and a comonomer copolymerizable therewith and of greater molecular weight than propylene are polymerized in a single site catalyst catalized polymerization reaction, characterized in that said polymerization reaction is effected at least in part at a temperature of at least 70° C.
    Type: Grant
    Filed: October 5, 2006
    Date of Patent: November 11, 2008
    Assignee: Borealis Technology OY
    Inventors: Petri Lehmus, Kimmo Hakala, Päivi Pitkänen, Manfred Arnold, Andreas Meinecke, Udo Manfred Stehling
  • Patent number: 7449533
    Abstract: The metallocene compound according to the invention and the olefin polymerization catalyst containing the compound are intended to produce a catalyst capable of preparing an isotactic polymer with a high polymerization activity. The metallocene compound contains a substituted cyclopentadienyl group and a (substituted) fluorenyl group and has a structure wherein these groups are bridged by a hydrocarbon group or the like. The process for preparing a metallocene compound according to the invention is intended to selectively prepare a specific metallocene compound so as not to produce an isomer, and in this process an intermediate product is synthesized by a specific method.
    Type: Grant
    Filed: February 10, 2005
    Date of Patent: November 11, 2008
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Koji Kawai, Masahiro Yamashita, Yasushi Tohi, Nobuo Kawahara, Kenji Michiue, Hiromu Kaneyoshi, Ryoji Mori
  • Publication number: 20080269419
    Abstract: Copolymers, especially multi-block copolymer containing therein two or more segments or blocks differing in tacticity, are prepared by polymerizing propylene, 4-methyl-1-pentene, or another C4-8 ?-olefin in the presence of a composition comprising the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in tacticity from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
    Type: Application
    Filed: January 30, 2006
    Publication date: October 30, 2008
    Inventor: Phillip D. Hustad
  • Publication number: 20080262180
    Abstract: Methods for producing elastomers or elastomeric compositions are provided. One or more C4 to C7 isoolefins and one or more comonomers can be polymerized in the presence of a diluent comprising one or more hydrofluorocarbons to provide a slurry comprising polymer product, unreacted monomer and the diluent. The slurry can be extruded to separate at least a portion of the diluent from the polymer product. The separated diluent can be recycled for polymerizing the one or more C4 to C7 isoolefins.
    Type: Application
    Filed: April 20, 2007
    Publication date: October 23, 2008
    Inventors: Michael F. McDonald, Scott T. Milner, Timothy D. Shaffer, Robert N. Webb
  • Patent number: 7411023
    Abstract: A polymer pipe for hot fluids, usually hot water is described. The pipe is characterised in that it comprises a multimodal polyethylene with a high molecular weight (HMW) fraction and a low molecular weight (LMW) fraction where said HMW fraction has a density of at least 0.920 g/cm3, and that the multimodal polyethylene has a density of 0.921-0.950 g/cm3 and has a time to failure at 95° C. and 3.6 MPa of at least 165 h determined according to DIN 16 833 and a modulus of elasticity of at most 900 MPa determined according to ISO 527-2/1B. Preferably, the multimodal polyethylene is a bimodal polyethylene, the LMW fraction having a density of 0.955-0.975 g/cm3, the HMW fraction having a density of 0.920-0.940 g/cm3, and the weight ratio of the LMW fraction to the HMW fraction being from 30:70 to 55:45.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: August 12, 2008
    Assignee: Borealis Technology Oy
    Inventor: Magnus Palmlof
  • Patent number: 7407695
    Abstract: The present invention includes an end use article (i.e., an article of manufacture) and a process for making the same, wherein the end use article has a relatively high gloss and exhibits excellent processability over a wide range of processing conditions. The end use article can be formed with glossy polyethylene having an “a” parameter less than or equal to about 0.40, and the glossy polyethylene can be a Metallocene polyethylene. The end use article can have a 60° specular gloss of at least about 40%, or from about 40% to about 80%, or from about 60% to about 80%. The end use article may be pigmented or unpigmented.
    Type: Grant
    Filed: December 18, 2006
    Date of Patent: August 5, 2008
    Assignee: Fina Technology, Inc.
    Inventors: Gregory S. DeKunder, Eric Maziers, Brian B. Cole, G. Travis Meredith, Gerhard Guenther, Walter T. Jagmin
  • Publication number: 20080177242
    Abstract: This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines. The compositions of the present invention preferably comprise an elastomeric polyolefin resin and a high pressure low density type resin.
    Type: Application
    Filed: January 14, 2008
    Publication date: July 24, 2008
    Applicant: Dow Global Technologies Inc.
    Inventors: Andy C. Chang, Stephen M. Hoenig, Yunwa W. Cheung, Daniel G. Moldovan, Wenbin Liang, Charles F. Diehl
  • Patent number: 7399895
    Abstract: A catalyst composition for the preparation of oligomeric and/or polymer derivatives of olefin monomers, said composition comprising a Group 6 metal amide complex, a Group 1, 2, 12, 13, or 14 metal hydrocarbyl composition or compound, and a solid support comprising aluminum phosphate.
    Type: Grant
    Filed: February 24, 2005
    Date of Patent: July 15, 2008
    Assignee: Union Carbide Chemicals & Plastics
    Inventors: John R. Briggs, David W. Butler, Timothy T. Wenzel, William C. Brooks, Teresa L. Fortin
  • Patent number: 7396892
    Abstract: Multimodal polyolefin polymers may be prepared in series-connected polymerization reactors where a prior reactor is a slurry reactor employing light solvent as the slurry medium and hydrogen to limit polymer molecular weight, the polymer product from the prior reactor being substantially freed of hydrogen prior to entry into a subsequent polymerization reactor operating at low hydrogen pressure to produce a high molecular weight olefin. The economics and operating performance of such a series slurry reactor polyethylene process can be significantly improved through the use of an intermediate slurry transfer system and hydrogen removal apparatus that employs flash drums in series in conjunction with a warm recycle solvent slurry diluent.
    Type: Grant
    Filed: June 3, 2005
    Date of Patent: July 8, 2008
    Assignee: Equistar Chemicals L.P.
    Inventor: Patrick J. McGrath
  • Publication number: 20080146761
    Abstract: An ethylene-?-olefin copolymer comprising repeating units derived from ethylene and repeating units derived from an ?-olefin having 3 to 20 carbon atoms and having a melt flow rate (MFR) of from 0.01 to 100 g/10 min, a density (d) of from 890 to 970 kg/m3, a flow activation energy (Ea) of 50 kJ/mol or more, a molecular weight distribution (Mw/Mn) of 3 or more measured by gel permeation chromatography, and a hexane extraction rate (C) of 2.8% or less.
    Type: Application
    Filed: September 27, 2007
    Publication date: June 19, 2008
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Yasutoyo Kawashima, Katsuhiro Yamada, Yoshinobu Nozue
  • Patent number: 7339019
    Abstract: A copolymer having monomer units derived from ethylene and monomer units derived from an ?-olefin of 3 to 20 carbon atoms, a density of 906 to 970 kg/m3 and an activation energy of flow of 50 kJ/mol or more, and satisfying specific relations among a melt complex viscosity, a melt flow rate and a characteristic relaxation time.
    Type: Grant
    Filed: October 24, 2005
    Date of Patent: March 4, 2008
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Yuki Iseki, Katsuhiro Yamada, Tatsuhiro Nagamatsu
  • Patent number: 7335715
    Abstract: An ethylene-?-olefin copolymer having monomer units derived from ethylene and monomer units derived from an ?-olefin of 3 to 20 carbon atoms, a density of 906 to 970 kg/m3, an activation energy of flow of 50 kJ/mol or more and a heat quantity of fusion of a cold xylene soluble part of 30 J/g or more, and satisfying specific relations among a rate of the cold xylene soluble part in the copolymer, the density, a melt flow rate and a characteristic relaxation time.
    Type: Grant
    Filed: October 24, 2005
    Date of Patent: February 26, 2008
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Yuki Iseki, Katsuhiro Yamada, Tatsuhiro Nagamatsu
  • Patent number: 7335716
    Abstract: An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an ?-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an ?-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT)>12.9?7.15×SR; and the intrinsic viscosity ([?]) and the melt flow rate (MFR) satisfy the relation; [?]>1.85×MFR?0.192 in the case of MFR?1 and the relation; [?]>1.85×MFR?0.213 in the case of MFR?1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.
    Type: Grant
    Filed: June 16, 2000
    Date of Patent: February 26, 2008
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Mamoru Takahashi, Tetsuji Kasai, Junji Saito, Naoto Matsukawa, Kazutaka Tsuru, Makoto Mitani, Terunori Fujita, Shiro Otsuzuki, Tetsuhiro Matsumoto, Toshiyuki Tsutsui
  • Publication number: 20080032079
    Abstract: A method for extruding transparent and/or translucent article is provided. In one embodiment, the method comprises providing a propylene-based polymer comprising propylene derived units and one or more dienes, the propylene-based polymer having a triad tacticity of from 50% to 99% and a heat of fusion of less than 80 J/g, extruding the propylene-based polymer in the absence of processing oil into an article; and then crosslinking the extruded article.
    Type: Application
    Filed: July 24, 2007
    Publication date: February 7, 2008
    Inventors: Abdelhadi Sahnoune, Sunny Jacob
  • Patent number: 7323524
    Abstract: The invention provides a process for polymerising olefins to branched polyolefins in the presence of a polymerisation catalyst and a cocatalyst, wherein the cocatalyst produces 1-octene in a selectivity greater than 30%.
    Type: Grant
    Filed: December 19, 2003
    Date of Patent: January 29, 2008
    Assignee: Sasol Technology (PTY) Limited
    Inventors: Kevin Blann, Deon De Wet-Roos, John Thomas Dixon
  • Publication number: 20080021186
    Abstract: A dimensionally stable adhesive can be applied at room or ambient temperature to substrate surfaces. It comprises at least one, or two or more, polyfin(s) prepared in the presence of metallocene catalyst and having a ring & ball softening point in the range from 50 to 165° C., a needle penetration number of <50×0.1 mm, and a melt viscosity, measured at a temperature of 170° C., in the range from 20 to 40 000 mPa·s. The adhesive is water- and solvent-free and is used as a glue stick in the form of sticks, blocks, figures, spheres or cones.
    Type: Application
    Filed: July 17, 2007
    Publication date: January 24, 2008
    Inventor: Christian Steib
  • Patent number: 7312295
    Abstract: The present invention relates to a copolymer comprising units derived from ethylene and 1-heptene, to a composition comprising such a copolymer, and to an article prepared from or containing such a copolymer.
    Type: Grant
    Filed: March 12, 2004
    Date of Patent: December 25, 2007
    Assignee: Dow Global Technologies Inc.
    Inventors: Hendrik H. Hagen, Lambertus P. P. M. Van Der Heijden
  • Patent number: 7312283
    Abstract: Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. Methods for preparing and using such catalysts to produce polyolefins are also provided. The compositions and methods disclosed herein provide ethylene polymers having a HLMI of from about 0.5 to about 25, a polymer density of from about 0.920 to about 0.965, and a polydispersity of from about 3.0 to about 30.
    Type: Grant
    Filed: August 22, 2005
    Date of Patent: December 25, 2007
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Joel L. Martin, Matthew G. Thorn, Max P. McDaniel, Michael D. Jensen, Qing Yang, Paul J. DesLauriers, Mark E. Kertok
  • Patent number: 7307129
    Abstract: A method of preparing a latex that includes pigments copolymerized with a crystalline polymer includes: dispersing a pigment and a dispersing agent in water having an ultra-high purity to obtain a pigment dispersion; dissolving a crystalline monomer in a basic monomer mixture to obtain an organic phase; dissolving while heating the dispersing agent in water having an ultra-high purity, and then mixing the solution with the pigment dispersion to obtain an aqueous phase; mixing and agitating the organic phase and the aqueous phase to obtain a homogenized solution; agitating and heating the homogenized solution; adding a polymerization initiator to the homogenized solution to be reacted; and cooling the reaction solution to room temperature.
    Type: Grant
    Filed: January 19, 2005
    Date of Patent: December 11, 2007
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Jun-young Lee, Sang-woo Kim, Kyung-yol Yon
  • Patent number: 7307133
    Abstract: Methods of polymerizing at least one olefin include contacting the olefin with a catalyst comprising chromium and with a cocatalyst comprising a non-transition metal cyclopentadienyl (Cp) compound. The polymerization may be performed in the presence of hydrogen. Using the cocatalyst in conjunction with the catalyst increases several properties, such as the high load melt index (HLMI), the MW, and the MN, of the polymers produced by this polymerization method. Polymer compositions produced by such methods have various unique properties, including a PDI greater than about 30. Additional embodiments include articles of manufacture or end use articles formed from such polymer compositions.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: December 11, 2007
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Max P. McDaniel, Elizabeth A. Benham, Steven J. Secora, Michael D. Jensen, Kathy S. Collins
  • Patent number: 7304118
    Abstract: An ethylene-based copolymer for non-crosslinked water supply pipe is provided. The ethylene-based copolymer is prepared using a supported hybrid metallocene catalyst and has a dimodal or broad molecular weight distribution. The ethylene-based copolymer has a high density molecular structure in a low molecular weight and has a low density molecular structure with high content of a comonomer in a high molecular weight. The ethylene-based copolymer has a molecular weight distribution of 5-30 and the distribution of copolymerization of ethylene and C3-20 ?-olefin is localized in high molecular weight chains. Accordingly, the ethylene-based copolymer has superior processability, internal pressure creep resistance at high temperatures and environmental stress crack resistance.
    Type: Grant
    Filed: April 7, 2005
    Date of Patent: December 4, 2007
    Assignee: LG Chem, Ltd.
    Inventors: Ki Soo Lee, Choong Hoon Lee, Sangwoo Lee, Eunjung Lee, Soojeong Lee, Seungwoo Choi
  • Patent number: 7294681
    Abstract: This invention relates to a polymer of one or more C3 to C40 olefins, optionally one or more diolefins, and less than 15 mole % of ethylene, and polymerization processes for producing the same.
    Type: Grant
    Filed: October 15, 2003
    Date of Patent: November 13, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag Hagop Dekmezian, Jo Ann Marie Canich, Charles Lewis Sims, Ramin Abhari, Cesar Alberto Garcia-Franco, David Raymond Johnsrud
  • Patent number: 5220471
    Abstract: A thin film magnetic head comprises a slider and a reading/writing element attached to an end surface of the slider, wherein the reading/writing element is disposed at an end surface in the longitudinal direction of the slider when the longitudinal direction and the width direction are determined on the surface which faces a magnetic recording medium, of the slider, and the slider has a linear groove in the surface opposite the surface which faces the magnetic recording medium, at the intermediate portion in the width direction of the slider and along the longitudinal direction.
    Type: Grant
    Filed: June 26, 1992
    Date of Patent: June 15, 1993
    Assignee: TDK Corporation
    Inventor: Mikio Matsuzaki