From Imide- Or Lactam-containing Compound, Or From An Amino-nitrogen Containing Carboxylic Acid, Or Derivative Of An Amino-nitrogen-containing Carboxylic Acid Patents (Class 528/310)
  • Patent number: 8853324
    Abstract: A mobile telephone housing comprising a polyamide composition having excellent stiffness and low moisture absorption.
    Type: Grant
    Filed: November 15, 2007
    Date of Patent: October 7, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Georgios Topoulos
  • Patent number: 8853325
    Abstract: The present invention is directed to alkanal derivatives of water-soluble polymers such as poly(ethylene glycol), their corresponding hydrates and acetals, and to methods for preparing and using such polymer alkanals. The polymer alkanals of the invention are prepared in high purity and exhibit storage stability.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: October 7, 2014
    Assignee: Nektar Therapeutics
    Inventor: Antoni Kozlowski
  • Patent number: 8846852
    Abstract: The present invention provides a polyimide film which is both outstandingly transparent and highly heat resistance, and which can be usefully employed as a transparent electrically conductive film, a TFT substrate, a flexible printed circuit substrate, and the like.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: September 30, 2014
    Assignee: Kolon Industries, Inc.
    Inventors: Young Han Jeong, Han Moon Cho, Hyo Jun Park
  • Patent number: 8841407
    Abstract: Provided is a polyamide resin having high heat resistance, excellent moldability and excellent mechanical properties. The polyamide resin comprises a diamine unit containing 70 mol % or more of a xylylenediamine unit and a dicarboxylic acid unit containing 70 mol % or more of a straight chain aliphatic dicarboxylic acid unit, wherein the xylylenediamine unit is composed of 50 to 95 mol % of p-xylylenediamine and 50 to 5 mol % of m-xylylenediamine; the straight chain aliphatic dicarboxylic acid unit is composed of 50 to 100 mol % of adipic acid and 0 to less than 50 mol % of sebacic acid or other straight chain aliphatic dicarboxylic acids; the molar ratio of reacted diamine units to reacted dicarboxylic acid units (the number of moles of reacted diamine units/the number of moles of reacted dicarboxylic acid units) is less than 0.994; and the polyamide resin has a number average molecular weight of 10,000 to 25,000 and a melting point of 285° C. or more.
    Type: Grant
    Filed: November 8, 2011
    Date of Patent: September 23, 2014
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Hatsuki Oguro, Jun Mitadera, Hisayuki Kuwahara
  • Patent number: 8841406
    Abstract: Crosslinked polyimide-poly(alkylene oxide) copolymers capable of holding large volumes of liquid while maintaining good dimensional stability. Copolymers are derived at ambient temperatures from amine endcapped amic-acid oligomers subsequently imidized in solution at increased temperatures, followed by reaction with trifunctional compounds in the presence of various additives. Films of these copolymers hold over four times their weight at room temperature of liquids such as ionic liquids (RTIL) and/or carbonate solvents. These rod-coil polyimide copolymers are used to prepare polymeric electrolytes by adding to the copolymers various amounts of compounds such as ionic liquids (RTIL), lithium trifluoromethane-sulfonimide (LiTFSi) or other lithium salts, and alumina.
    Type: Grant
    Filed: December 22, 2008
    Date of Patent: September 23, 2014
    Assignee: The United States of America as Represented by the Administrator of National Aeronautics and Space Administration
    Inventors: Maryann B. Meador, Dean M. Tigelaar
  • Patent number: 8841382
    Abstract: The present invention provides an amphiphile of the formula (I) as described hereinafter. The invention further relates to a process for preparing the amphiphile and to a composition comprising the amphiphile and a sparingly water-soluble active ingredient. It further relates to a process for producing the composition by contacting the amphiphile and the active ingredient, and to the use of the amphiphile for solubilizing a sparingly water-soluble active ingredient in aqueous solutions. The invention also relates to the use of the amphiphile in an agrochemical formulation comprising the amphiphile and a pesticide for controlling phytopathogenic fungi and/or unwanted vegetation and/or unwanted insect or mite infestation and/or for regulating the growth of plants, and finally to plant propagation material comprising the amphiphile.
    Type: Grant
    Filed: August 31, 2011
    Date of Patent: September 23, 2014
    Assignee: BASF SE
    Inventors: Anna Cristadoro, Holger Türk, Michael Ishaque, Rabie Al-Hellani
  • Patent number: 8840875
    Abstract: Guanidine-based poly (amidoamine) polymers of formula (I): wherein n is an integer between 3 and 400; R1 is H, C1-6 alkyl; or taken together with the N atoms to which is bound and R2 is a piperazinic ring; R2 is C2-6 alkylen; C5-6 cycloalkylen; CH—COOH, CH—COOR, wherein R is C1-4 alkyl, phenyl or benzyl; R3 is —(CH2)p-HN—C(NH2)?NH, wherein p is an integer 1 to 6; for use as antiviral agents in the prevention and/or treatment of viral infections in a mammal, preferably a human subject.
    Type: Grant
    Filed: May 3, 2013
    Date of Patent: September 23, 2014
    Inventors: Paolo Ferruti, Elisabetta Ranucci
  • Patent number: 8835595
    Abstract: A polyamide compound containing: from 25 to 50 mol % of a diamine unit, which contains an aromatic diamine unit represented by the following formula (I), in an amount of 50 mol % or more; from 25 to 50 mol % of a dicarboxylic acid unit, which contains a linear aliphatic dicarboxylic acid unit represented by the following formula (II-1) and/or an aromatic dicarboxylic acid unit represented by the following formula (II-2), in an amount in total of 50 mol % or more; and from 0.1 to 50 mol % of a constitutional unit represented by the following formula (III): wherein n represents an integer of from 2 to 18, Ar represents an arylene group, and R represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group.
    Type: Grant
    Filed: December 24, 2010
    Date of Patent: September 16, 2014
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takafumi Oda, Ryoji Otaki, Shota Arakawa, Tsuneaki Masuda, Hiroyuki Matsushita, Ryuji Hasemi
  • Publication number: 20140256904
    Abstract: The subject of the invention is a biotechnological process for the production of ?-functionalized carboxylic acids and of ?-functionalized carboxylate esters from simple carbon sources.
    Type: Application
    Filed: August 15, 2012
    Publication date: September 11, 2014
    Applicant: Evonik Degussa GmbH
    Inventors: Steffen Schaffer, Nicole Decker, Jasmin Gielen, Harald Haeger, Thomas Haas, Markus Poetter, Hans-Georg Hennemann, Mirja Wessel, Michael Volland
  • Patent number: 8828069
    Abstract: A method of forming a surface layer that includes a hydroxyl polymer on a substrate coating on a medical device is provided.
    Type: Grant
    Filed: August 24, 2009
    Date of Patent: September 9, 2014
    Assignee: Advanced Cardiovascular Systems, Inc.
    Inventors: Lothar W. Kleiner, Jessica Reneé´ DesNoyer, Thierry Glauser, Stephen D. Pacetti, Syed Faiyaz Ahmed Hossainy
  • Patent number: 8829153
    Abstract: To provide a polyamic acid ester-containing polyimide precursor composition having a good storage stability, from which a polyimide film having a high imidization degree and excellent adhesion to an inorganic substrate can be obtained. A polyimide precursor composition comprising a polyamic acid ester, a thermal imidization accelerator and a solvent, wherein the thermal imidization accelerator is a compound which has a carboxy group and an amino group or an imino group which is deprotected by heat to show basicity, and which will not accelerate the imidization of the polyamic acid ester before the protecting group leaves, and a polyimide precursor composition containing a silane coupling agent.
    Type: Grant
    Filed: April 1, 2010
    Date of Patent: September 9, 2014
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Naoki Sakumoto, Masato Nagao, Yuho Noguchi
  • Patent number: 8822632
    Abstract: The invention concerns processes for forming a polymer comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine, and terephthaloyl dichloride, the process comprising: (a) forming a solution of oligomers having chloride end groups from one mole of paraphenylene diamine and 1.3 to 5 moles of terephthaloyl dichloride a solvent system comprising an organic solvent and an inorganic salt; and (b) adding DAPBI and terephthaloyl dichloride to the solution of oligomers to form a polymer.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: September 2, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 8822629
    Abstract: The present invention relates to a method of prepairing a heat-resistant polyamide by carrying out condensation polymerization with a monomer mixture including a diester compound and a diamine compound. The present invention provides an economical method of prepairing a heat-resistant polyamide in that a monomer, a raw material, is simply and chiefly prepared, and the polymerizing reaction time is short because it does not need solvent separately.
    Type: Grant
    Filed: April 10, 2009
    Date of Patent: September 2, 2014
    Assignee: SK Chemicals Co., Ltd.
    Inventors: Dong-June Hwang, Jae-Bong Lim, Seung-Do Leem, Tae-Young Kim, Sung-su Bae
  • Patent number: 8822630
    Abstract: A polyamide composition containing a polyamide compound (A) and a transition metal compound (B), wherein the polyamide compound (A) contains: from 25 to 50 mol % of a diamine unit, which contains at least one diamine unit selected from the group consisting of an aromatic diamine unit represented by the following formula (I-1), an alicyclic diamine unit represented by the following formula (I-2) and a linear aliphatic diamine unit represented by the following formula (I-3), in an amount in total of 50% by mol or more; from 25 to 50 mol % of a dicarboxylic acid unit, which contains a linear aliphatic dicarboxylic acid unit represented by the following formula (II-1) and/or an aromatic dicarboxylic acid unit represented by the following formula (II-2), in an amount in total of 50% by mol or more; and from 0.
    Type: Grant
    Filed: December 20, 2011
    Date of Patent: September 2, 2014
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takafumi Oda, Ryoji Otaki, Kentaro Ishii, Shota Arakawa
  • Patent number: 8809434
    Abstract: The invention concerns processes for forming a polymer comprising residues of terephthaloyl chloride, paraphenylene diamine, and a salt of formula I wherein A? is a halogen anion, HSO4?, OH?, NO3?, C2H3O2?, or H2PO4?; the process comprising the steps of: a) forming a mixture comprising salt of formula I and paraphenylene diamine in a solvent system comprising an organic solvent and an inorganic salt; and b) adding terephthaloyl chloride to the mixture and allowing the formation of the polymer.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: August 19, 2014
    Assignee: EI du Pont de Nemours and Company
    Inventor: Kiu-Seung Lee
  • Patent number: 8802233
    Abstract: Upon producing a meta-type wholly aromatic polyamide fiber by wet spinning a polymer solution containing a meta-type wholly aromatic polyamide containing a m-phenylenediamine isophthalamide skeleton as a major component, and an amide solvent containing a salt, (1) the polymer solution is ejected into a coagulation bath containing an amide solvent and water and containing a salt at a low concentration to coagulate as a porous thread body (fibrous material), (2) which is subsequently stretched in a plastic stretching bath containing an aqueous solution of an amide solvent, (3) is rinsed with water and then subjected to a heat treatment in a saturated steam atmosphere, and (4) is then subjected to a dry heat treatment, so as to produce a novel meta-type wholly aromatic polyamide fiber that contains an extremely small amount of a solvent remaining in the fibers, contains a small amount of a volatile substance harmful in a heat treatment step at a high temperature, is capable of suppressing coloration of a fiber p
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: August 12, 2014
    Assignee: Teijin Limited
    Inventors: Kotaro Takiue, Hiroshi Fujita
  • Patent number: 8802809
    Abstract: The present invention relates to a new method of production of cast polyamides.
    Type: Grant
    Filed: October 27, 2011
    Date of Patent: August 12, 2014
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Wilhelm Laufer, Armin Eckert
  • Patent number: 8796411
    Abstract: The polyimide precursor composition of the present invention is characterized in comprising a polyimide precursor having a structure formed by reacting a diamine component (A) containing a fluorine-containing aromatic diamine (a1) represented by the following chemical formula (I) (in the formula (I), R1 and R2 are each independently selected from —H, —(CF2)n—CF3, and —O(CF2)n—CF3 (n is an integer of 0 or more and 7 or less), and at least one of R1 and R2 is a fluorine-containing group) and trans-1,4-cyclohexyldiamine (a2) with an acid dianhydride component (B) containing an aliphatic tetracarboxylic dianhydride (b1) and an aromatic tetracarboxylic dianhydride (b2). Use of the composition of the present invention provides a polyimide film and a transparent flexible film having high transparency, low thermal expansion properties, low birefringent properties, and high heat resistance.
    Type: Grant
    Filed: January 26, 2009
    Date of Patent: August 5, 2014
    Assignee: Hitachi Chemical DuPont Microsystems, Ltd.
    Inventors: Yuichi Kaneya, Yumiko Arakawa, Keiko Suzuki
  • Patent number: 8792318
    Abstract: An approach is presented for designing a polymeric layer for nanometer scale thermo-mechanical storage devices. Cross-linked polyimide oligomers are used as the recording layers in atomic force data storage device, giving significantly improved performance when compared to previously reported cross-linked and linear polymers. The cross-linking of the polyimide oligomers may be tuned to match thermal and force parameters required in read-write-erase cycles. Additionally, the cross-linked polyimide oligomers are suitable for use in nano-scale imaging.
    Type: Grant
    Filed: January 9, 2012
    Date of Patent: July 29, 2014
    Assignee: International Business Machines Corporation
    Inventors: Urs T. Duerig, Jane Elizabeth Frommer, Bernd Walter Gotsmann, Erik Christopher Hagberg, James Lupton Hedrick, Armin W. Knoll, Victor Yee-Way Lee, Teddie Peregrino Magbitang, Robert Dennis Miller, Russell Clayton Pratt, Charles Gordon Wade, Johannes Windeln
  • Patent number: 8791229
    Abstract: A series of novel phosphorus-containing compounds having the following formula is provided: in which: R1-R4, A, Q and m are as defined in the specification. A process for the preparation of the compound of formula (I) is also provided. A polymer of formula (PA), and preparation process and use thereof are further provided. A polymer of formula (PI), and preparation process and use thereof are also provided.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: July 29, 2014
    Assignees: Chang Chun Plastics Co., Ltd., National Chung Hsing University
    Inventors: Ching-Hsuan Lin, Tsung Li Lin, Yu-Ting Fang, Kuen-Yuan Hwang, An-Pang Tu
  • Patent number: 8779085
    Abstract: The present invention discloses a method of producing a modified polyimide comprising a polycarbonate, which modified polyimide has excellent electric properties and adhesion as well as excellent heat resistance, flexibility, bending property, low warping, chemical resistance and storage stability; and the modified polyimide. Also disclosed are a composition comprising the modified polyimide and used thereof.
    Type: Grant
    Filed: April 30, 2010
    Date of Patent: July 15, 2014
    Assignee: PI R&D Co., Ltd.
    Inventors: Toshiyuki Goshima, Maw Soe Win, Eika Kyo
  • Patent number: 8771998
    Abstract: The present invention relates to a novel method for the fermentative production of gamma-aminobutyric acid (GABA) by cultivating a recombinant microorganism expressing an enzyme having a glutamate decarboxylase activity. The present invention also relates to corresponding recombinant hosts, recombinant vectors, expression cassettes and nucleic acids suitable for preparing such hosts as well as to a method for preparing polyamides making use of GABA as obtained fermentative production.
    Type: Grant
    Filed: February 20, 2009
    Date of Patent: July 8, 2014
    Assignee: BASF SE
    Inventors: Oskar Zelder, Weol Kyu Jeong, Corinna Klopprogge, Andrea Herold, Hartwig Schröder
  • Patent number: 8772438
    Abstract: A process for making a polyamide polymer, said process comprising heating, in one or more ionic liquid(s), one or more polyamide precursor(s) selected from: (i) one or more free dicarboxylic acid(s) or ester(s) thereof, with one or more diamine(s); or (ii) one or more salt(s) of a dicarboxylic acid with a diamine; or (iii) one or more lactam(s); or (iv) mixtures of any of the foregoing precursors (i) to (iii).
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: July 8, 2014
    Assignee: Invista North America S.är.l.
    Inventors: Keith Whiston, Charles Richard Langrick, Kenneth Richard Seddon, Alberto V. Puga
  • Patent number: 8772439
    Abstract: Solutions of a salt of a diamine and of a diacid, more particularly concentrated solutions of hexamethylene diammonium adipate salt (“nylon salt”), useful starting materials for the production of polyamides, more specifically of PA66, are prepared by mixing a diacid and a diamine, at a salt concentration by weight of from 50% to 80%, in a first stage, to provide aqueous solutions of diacid and diamine having a diacid/diamine molar ratio of greater than 1.1 and, in a second stage, adjusting the diacid/diamine molar ratio, by adding diamine, to a value of from 0.9 to 1.1, preferably from 0.99 to 1.01, and in fixing the salt concentration by weight by, optionally, adding water thereto.
    Type: Grant
    Filed: May 22, 2008
    Date of Patent: July 8, 2014
    Assignee: Rhodia Operations
    Inventor: Jean-François Thierry
  • Patent number: 8765902
    Abstract: In a process for preparing a polyamide based on dicarboxylic acids and diamines in an extruder, a solid mixture comprising a monomer mixture composed of 50 mol % of dicarboxylic acid mixture composed of from 60 to 88 % by weight of terephthalic acid and from 12 to 40% by weight of isophthalic acid, in which up to 20% by weight of the dicarboxylic acid mixture may also be replaced by other dicarboxylic acids, and 50 mol % of hexamethylenediamine which may be up to 20% by weight replaced by other C2-30-diamines, in a corotatory twin-screw extruder for a residence time of from 10 seconds to 30 minutes, is heated to a temperature in the range from 150 to 400° C. while removing steam and if appropriate diamines through venting orifices.
    Type: Grant
    Filed: June 11, 2008
    Date of Patent: July 1, 2014
    Assignee: BASF SE
    Inventors: Philippe Desbois, Michael Kopietz, Ralf Neuhaus, Hagen Stawitzki, Hans-Joachim Weis, Jochen Engelmann
  • Patent number: 8765162
    Abstract: The current invention relates to poly(amide) and poly(ester-amide) polymers, coatings including the polymers, and narrow polydispersity drug delivery particles including the polymers.
    Type: Grant
    Filed: June 30, 2008
    Date of Patent: July 1, 2014
    Assignee: Abbott Cardiovascular Systems Inc.
    Inventors: Michael Huy Ngo, Mikael O. Trollsas, Thierry Glauser, Jinping Wan, Bozena Zofia Maslanka
  • Patent number: 8759476
    Abstract: The process for preparing a polyamide based on dicarboxylic acids and diamines has the following stages: 1) providing an aqueous monomer mixture of dicarboxylic acids and diamines, the molar ratio of dicarboxylic acids to diamines being adjusted such that a molar deficiency of dicarboxylic acids or diamines of from 1 to 10 mol % is present at the outlet of stage 3), based on the other component in each case, 2) transferring the aqueous mixture from stage 1) to a continuous evaporator reactor in which diamines and dicarboxylic acids are reacted at a temperature in the range from 100 to 370° C. and a pressure in the range from 1 to 50 bar, 3) transferring the mixture from stage 2) to a separator which is operated at a temperature in the range from 100 to 370° C.
    Type: Grant
    Filed: June 12, 2008
    Date of Patent: June 24, 2014
    Assignee: BASF SE
    Inventors: Philippe Desbois, Hagen Stawitzki, Ralf Neuhaus, Hans-Joachim Weis, Jurgen Weichmann, Racquel Fernandez Rodiles, Gunter Vogel
  • Patent number: 8759475
    Abstract: Polyamides, e.g., polyhexamethylene adipamide, are continuously produced via the following stages: Stage 1: into and through a reactor, polycondensing a liquid stream which contain the polyamide monomer(s) at a pressure P1 greater than atmospheric pressure, the stream of material at the outlet of the reactor including a vapor phase which contains steam and a liquid phase which at least contains the product of polycondensation; Stage 2: feeding the outlet stream of material into a chamber, evacuating at least a portion of the vapor phase therefrom and recovering at least the liquid phase which at least contains the product of polycondensation, the pressure P2 in the chamber being regulated at a set value such that it is greater than atmospheric pressure and the residence time of said liquid phase in the chamber being less than 5 minutes; and Stage 3: pressure reducing at least the liquid phase which at least contains the stream of polycondensation product recovered during Stage 2.
    Type: Grant
    Filed: March 25, 2008
    Date of Patent: June 24, 2014
    Assignee: Rhodia Operations
    Inventors: Jean-Francois Thierry, Sébastien Lomel, Vincent Mollet, Matthieu Helft, Cédric Fillon
  • Patent number: 8754187
    Abstract: The present invention relates generally to mercaptofunctional high ?? EO chromophores and EO polymers, and particularly to mercaptofunctional high ?? EO chromophores and EO polymers useful for making electro-optical devices and systems. Mercaptofunctional high ?? EO chromophores are covalently bonded to poly(imido sulfide) polymers producing high Tg, low optical loss, covalently bonded, high ?? EO chromophore containing polymers. Methods of synthesizing these EO materials using mild polymerization conditions are also described.
    Type: Grant
    Filed: June 11, 2013
    Date of Patent: June 17, 2014
    Assignee: Corning Incorporated
    Inventors: Mingqian He, Jianguo Wang
  • Patent number: 8754186
    Abstract: An object of the present invention is to provide a polyimide precursor composition that can be cured at low temperatures (250° C. or lower), while having a low viscosity even at a high concentration, and a method of producing the same. Another object of the present invention is to provide a polyimide coating film obtained from the polyimide precursor composition and having good physical properties, and a method of producing the same. Furthermore, another object of the present invention is to provide a photosensitive resin composition containing the polyimide precursor composition, and a method of producing the same. These objects can be achieved by the polyimide precursor composition containing an imidized tetracarboxylic acid having a specific structure and a diamine having a specific structure.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: June 17, 2014
    Assignee: Kaneka Corporation
    Inventors: Kan Fujihara, Tetsuya Kogiso, Yoshihide Sekito
  • Patent number: 8748004
    Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.
    Type: Grant
    Filed: August 6, 2009
    Date of Patent: June 10, 2014
    Assignee: Arkema France
    Inventors: Thierry Briffaud, Philippe Blondel
  • Patent number: 8742059
    Abstract: A polymer precursor including a part which sequences an unsaturated bond having a ? electron orbit and a single bond alternately is disclosed. The polymer precursor has a first functional group and a second functional group which form a repeating unit constituting a polymer skeleton of an end product by an intramolecular reaction. At least a part of a conjugated state formed by the ? electron orbit in the molecule is disconnected or weakened due to a three-dimensional structure of the molecule and a transmittance with respect to an electromagnetic wave of at least one wavelength selected from the group consisting of 436 nm, 405 nm, 365 nm, 248 nm and 193 nm is improved.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: June 3, 2014
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventor: Katsuya Sakayori
  • Patent number: 8735530
    Abstract: A method for making polyamide is described. More particularly, a method for making a polyamide from at least one diacid and one diamine, that includes a step of concentrating an aqueous solution of diacid and diamine salt up to a salt weight concentration higher than 85%, and a polymerization step up to a desired polymerization degree is described.
    Type: Grant
    Filed: March 9, 2010
    Date of Patent: May 27, 2014
    Assignee: Rhodia Operations
    Inventors: Virginie Thieblemont, Jean-Francois Thierry
  • Patent number: 8722794
    Abstract: The present invention relates to a melt processable copolyetheramide made by reacting (a) one or more segments of polyamide hard blocks derived from a lactam-terminated diisocyanate and a lactam monomer, and (b) one or more segments of polyether soft blocks derived from a polyether diol. The invention further provides for methods of making said copolyetheramide, including a continuous extruder method of production.
    Type: Grant
    Filed: February 24, 2011
    Date of Patent: May 13, 2014
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Umit G. Makal, Bryce W. Steinmetz, Roger W. Day, Feina Cao
  • Patent number: 8722154
    Abstract: A method of electrostatic spraying of a polymer surface involves oxidation and treating the oxidized surface with a polyamine and an electroconductivity modifying agent which contains a mono-carboxylic acid of from one to 12 carbon atoms.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: May 13, 2014
    Assignee: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Sheng Li, Wojciech Stanislaw Gutowski, Wei Dong Yang, Andrew Simon Hastings, Mark Edward Spicer, Con Filippou
  • Patent number: 8716425
    Abstract: A method of improving the mechanical properties of polymers is described. The method involves heat treating the polymer at a temperature below the glass transition temperature in a wet or in a dry environment. Polymer articles capable of moisture uptake in humid environments, as well as polymer articles less susceptible to moisture uptake, have improved mechanical properties, particularly improved stress relaxation behavior and set properties, when treated in accord with the heat treatment method.
    Type: Grant
    Filed: July 29, 2005
    Date of Patent: May 6, 2014
    Assignee: Bay Materials, LLC
    Inventors: Ray F. Stewart, John G. Lahlouh
  • Patent number: 8710173
    Abstract: The present invention discloses a new type of polyimide membrane with high permeances and high selectivities for gas separations and particularly for CO2/CH4 and H2/CH4 separations. The polyimide membranes have CO2 permeability of 50 Barrers or higher and single-gas selectivity for CO2/CH4 of 15 or higher at 50° C. under 791 kPa for CO2/CH4 separation. The polyimide membranes have UV cross-linkable functional groups and can be used for the preparation of UV cross-linked polyimide membranes having CO2 permeability of 20 Barrers or higher and single-gas selectivity for CO2/CH4 of 35 or higher at 50° C. under 791 kPa for CO2/CH4 separation.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: April 29, 2014
    Assignee: UOP LLC
    Inventors: Chunqing Liu, Travis C. Bowen, Emily G. Harbert, Raisa Minkov, Syed A. Faheem, Zara Osman
  • Patent number: 8709205
    Abstract: Disclosed are polyimide short fibers having an extremely high heat resistance, suitable for non-woven fabrics and paper, and having many branches. Specifically, disclosed are polyimide short fibers having many branches, which are produced by beating and loosening a specific foamed polyimide material. The foamed material preferably comprises a polyimide produced using 2,3,3?,4?-biphenyltetracarboxylic acid as an aromatic tetracarboxylic acid component, preferably has a glass transition temperature of 300° C. or higher, and preferably has an expansion ratio of 20 times or more.
    Type: Grant
    Filed: December 16, 2010
    Date of Patent: April 29, 2014
    Assignee: UBE Industries, Ltd.
    Inventors: Hideki Ozawa, Fumio Aoki
  • Patent number: 8703879
    Abstract: A continuous process for the multistage drying and postcondensation of polyamide pellets in the solid phase comprises 1) carrying out the predrying process in a continuous drying apparatus which is operated in countercurrent mode or in crossflow mode with inert gas or steam, or with a mixture of inert gas and steam, using a pellet temperature in the range from 70 to 200° C., and 2) Carrying out the subsequent continuous postcondensation process in a separate vertical duct with moving bed at a pellet temperature in the range from 120 to 210° C., where the duct is operated in countercurrent mode with inert gas or steam, or with a mixture of inert gas and steam, the inert gas is introduced at least two sites along the duct, and from 15 to 90% of the inert gas is introduced at the base of the vertical duct and from 10 to 85% of the inert gas is introduced in the upper half below the surface of the pellets.
    Type: Grant
    Filed: June 19, 2009
    Date of Patent: April 22, 2014
    Assignee: BASF SE
    Inventors: Wolfgang Loth, Faissal-Ali El-Toufaili, Achim Stammer, Gad Kory, Achim Gerstlauer, Jens Becker
  • Patent number: 8703901
    Abstract: The present invention relates to an aqueous alkali-developable photosensitive polyimide precursor resin composition that is appropriate for highly heat-resistant transparent protection layers and insulation layers for liquid crystal display devices.
    Type: Grant
    Filed: May 30, 2012
    Date of Patent: April 22, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Dong-seok Kim, Yong-sik Ahn, Kyung-jun Kim, Mi-hie Yi
  • Publication number: 20140106217
    Abstract: In an aspect, a binder for a lithium battery electrode, a binder composition including the binder, and a lithium battery including the binder are provided.
    Type: Application
    Filed: March 14, 2013
    Publication date: April 17, 2014
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Beom-Wook Lee, Hye-Sun Jeong, Hye-Ran Lee
  • Patent number: 8686106
    Abstract: The present invention provides a carbon black-dispersed polyamic acid solution composition having a high solids content and a high carbon black content. The invention further provides an intermediate transfer belt using the polyamic acid solution composition. The carbon black-dispersed polyamic acid solution composition is obtained by uniformly dispersing carbon black in a polyamic acid solution obtained by reacting biphenyltetracarboxylic dianhydride and an aromatic diamine in an organic polar solvent. The biphenyltetracarboxylic dianhydride includes 2,3,3?,4?-biphenyltetracarboxylic dianhydride and 3,3?,4,4?-biphenyltetracarboxylic dianhydride. The aromatic diamine includes 4,4?-diaminodiphenyl ether and p-phenylenediamine. The polyamic acid solution has a solids content of 25 weight % or more.
    Type: Grant
    Filed: December 4, 2008
    Date of Patent: April 1, 2014
    Assignees: Gunze Limited, UBE Industries, Ltd.
    Inventors: Naoki Nishiura, Akira Ichino, Takashi Kuraoka, Toru Murakami, Takeshige Nakayama
  • Patent number: 8669344
    Abstract: A method of removing a residual catalyst metal compound from a polymer solution comprises the steps of: a) mixing a solution in which at least one organic nitrogen compound is dissolved in a polar solvent and the polymer solution to precipitate a chelate compound of the organic nitrogen compounds and the residual catalyst metal compound, b) adding the polar solvent to the solution mixture to dissolve a chelate compound and to precipitate a polymer, and c) filtering the precipitated polymer. After the polymer polymerization is completed, an organic nitrogen compound solution is added to perform a chelate reaction with the residual catalyst metal compound in a solution phase, and the polar solvent is added to precipitate the polymer so that only polymer precipitates are filtered while an additional filtration process in respect to the chelate compound is not performed to easily remove the residual catalyst metal compound.
    Type: Grant
    Filed: April 6, 2007
    Date of Patent: March 11, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Hye-Young Jung, Sung-Ho Chun, Sung-Don Hong, Jung-Min Lee, Heon Kim, Dmitry Kravchuk
  • Patent number: 8664339
    Abstract: Disclosed are new organic semiconducting polymers. The polymers disclosed herein can exhibit high carrier mobility and/or efficient light absorption/emission characteristics, and can possess certain processing advantages such as solution-processability and/or good stability at ambient conditions.
    Type: Grant
    Filed: November 6, 2009
    Date of Patent: March 4, 2014
    Assignees: Polyera Corporation, BASF SE
    Inventor: Antonio Facchetti
  • Patent number: 8664350
    Abstract: The invention relates to a composition containing a particulate solid, a plastic material and a compound. The invention further relates to novel compounds, and the use of the coupling agents.
    Type: Grant
    Filed: October 23, 2007
    Date of Patent: March 4, 2014
    Assignee: Lubrizol Limited
    Inventor: Dean Thetford
  • Patent number: 8658148
    Abstract: Dendrimers comprising N-acyl urea terminal moieties are described herein. The dendrimers can be used, for example, in the treatment of arthritis.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: February 25, 2014
    Assignee: Genzyme Corporation
    Inventors: Luis Z. Avila, Robert J. Miller, Lauren Elizabeth Young, Rajesh Vasant Kamath
  • Patent number: 8658756
    Abstract: The present invention relates to a composition that can be used to manufacture an impermeable, sealing, tight envelope, to a process for manufacturing an impermeable envelope, and to a tank. The composition of the invention comprises in % by weight relative to the total weight of the composition: from 70 to 90% of a monomer (I); from 0.1 to 1% of an activator (II), in which R is chosen from the group comprising CnH2n+2, n being an integer chosen from 1 to 10; —OH; —OCnH2n+2, n being an integer chosen from 1 to 10; and —NHR? where R? is either CnH2n+2, n being an integer chosen from 1 to 10, or an amine functional group; from 2 to 6% of a catalyst (III), in which X is chosen from the group comprising MgBr, MgI, Li and Na; and from 10 to 20% of an additive (IV), with: This composition can be used, for example, to manufacture elements that are impermeable to fluids, for example impermeable envelopes, for example that can be used in the manufacture of type IV tanks or hydraulic accumulators.
    Type: Grant
    Filed: November 23, 2006
    Date of Patent: February 25, 2014
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Philippe Mazabraud, Elodie Chauvot, Laurent Delnaud, Katia Barral
  • Patent number: 8653286
    Abstract: Methods for forming maleimide functionalized polymers are provided. In one such embodiment, a maleimide functionalized polymer is prepared in a method that includes a step of carrying out a reverse Diels-Alder reaction. Intermediates useful in the methods, as well as methods for preparing the intermediates, are also provided. Also provided are polymeric reagents, methods of using polymeric reagents, compounds and conjugates.
    Type: Grant
    Filed: August 7, 2012
    Date of Patent: February 18, 2014
    Assignee: Nektar Therapeutics
    Inventors: Samuel P. McManus, Antoni Kozlowski, Tracy L. Hutchison, Brian Bray, Xiaoming Shen
  • Patent number: 8642716
    Abstract: The present invention relates to branched polyamides comprising unsaturated ends comprising: at least one unit originating from a multifunctional monomer (A) having more than two functional groups, at least sequences resulting from the condensation, in the presence of at least one unsaturated monoacid, either of at least two different lactams, or of at least one lactam, at least one dicarboxylic acid and at least one diamine, or of a lactam or of an ?,?-aminocarboxylic acid, or of a diamine and of a diacid. The invention also relates to thermofusible adhesives comprising these branched polyamides comprising unsaturated ends, and to the use of these branched polyamides comprising unsaturated ends in sheathing electrical cables.
    Type: Grant
    Filed: April 25, 2005
    Date of Patent: February 4, 2014
    Assignee: Arkema France
    Inventors: Annett Linemann, Thierry Briffaud
  • Patent number: 8637610
    Abstract: Novel, crosslinked polymers using biomass derived materials, such as aldaric acids and derivatives, are provided. The polymers can be used as hydrogels and in antimicrobial compositions.
    Type: Grant
    Filed: July 16, 2013
    Date of Patent: January 28, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Mark Allen Andrews, Garret D Figuly, Henry Keith Chenault