Abstract: Dye mixtures comprising at least one dye of formula ##STR1## and at least one dye of formula ##STR2## wherein the substituents are as defined in claim 1, have good allround fastness properties and are suitable for dyeing cellulosic fibre materials.
Abstract: Dye mixtures containing from 50 to 95% by weight, of a 4-chloro-2-nitrophenylazohydroxypyridone dye and from 5 to 50% by weight of a chlorinated quinophthalone dye and/or from 5 to 20% by weight of an unsubstituted quinophthalone dye, dye formulations containing the novel dye mixtures and the use of dye mixtures for dyeing polyesters or printing them by the direct printing method.
Type:
Grant
Filed:
March 29, 1993
Date of Patent:
June 7, 1994
Assignee:
BASF Aktiengesellschaft
Inventors:
Arno Lange, Gert Motzkus, Helmut Degen, Volker Walther
Abstract: A process for dyeing a mixed fibre substrate with at least one disperse dye and at least one metal complex dye selected from direct dyes and reactive dyes characterized in that dyeing is carried out in the presence of a compound of formula I ##STR1## in which X is --S--, --O--, or --NH--;R.sub.1 is hydrogen, --OH or C.sub.1-4 alkyl; andR.sub.2 is hydrogen, NH.sub.4 or an alkali metal (such as Na or K).
Abstract: The invention relates to dye mixtures which contain dyes of the formulae ##STR1## and to dyes of the formula ##STR2## in which A.sub.1, A.sub.2, A.sub.3, B, B.sub.1, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, Z.sub.1, Z.sub.2, X.sub.1, X.sub.2 and X.sub.3 are as defined in claim 1. The dyes and dye mixtures are distinguished by generally good properties and produce dyeings and prints having good wet and light fastness properties.
Abstract: Mixtures of different oligomer compounds of formula (1) are suitable for use as direct dyes for dyeing and printing a wide range of materials, especially cellulose fibers, to give dyeings and prints of good all-round fastness properties: ##STR1## wherein R.sub.1 is hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aryl or aralkyl, R independently has the meaning of R.sub.1 or is an unsubstituted or substituted heteroaryl radical or a radical of formula ##STR2## wherein R.sub.4 is unsubstituted or substituted alkyl, cycloalkyl, aryl, aralkyl or heteroaryl, A is an unsubstituted or substituted alkylene, cycloalkylene, arylene or aralkylene radical, X is --O--, --S-- or --N(R.sub.5)--, wherein R.sub.5 is hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aryl or aralkyl, or wherein the group ##STR3## is an unsubstituted or substituted heterocyclic radical, Y is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, sulfo, carboxy, carbamoyl, N-mono- or N,N-di-C.sub.1 -C.sub.
Abstract: The invention relates to reactive dye mixtures comprising the reactive dyes of the formulae ##STR1## in which X.sub.1, X.sub.2 and X.sub.3 are reactive radicals bonded via a diaminoalkylene bridge and the other substituents are as defined in claim 1.The reactive dye mixtures are suitable for dyeing and printing cellulosic fibre materials and give wet- and light-fast dyeings in luminous blue shades.
Type:
Grant
Filed:
November 5, 1991
Date of Patent:
May 4, 1993
Assignee:
Ciba-Geigy Corporation
Inventors:
Peter Aeschlimann, Paul Herzig, Athanassios Tzikas
Abstract: Dyestuff mixtures containing one or more dyestuffs of the formula ##STR1## and one or more dyestuffs of the formula ##STR2## in which the substituents have the meanings given in the description are highly suitable for producing green cotton dyeings.
Abstract: Denim cotton warp yarns are rope-dyed with a benzoquinone dye of formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.1 ', R.sub.2 ' and R.sub.3 ' commonly or independently represent a hydrogen atom, a halogen atom, alkyl, cycloalkyl, alkenyl, aryl, aralkyl, alkoxyl or alkoxyalkyl alone or in combination with a red .DELTA..sup.2,3' -biindolin-3,2'-dione dye and/or a blue indigoid dye or sequentially with the latter dye.
Abstract: The fibre-reactive formazan dyes of the formula ##STR1## where B is an aliphatic or sulfo-free aromatic bridge member, R is .alpha.,.beta.-dihalopropionyl, .alpha.-haloacryloyl or haloacetyl, T.sub.1 is halogen, X is halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, cyano or nitro, Y is --CO-- or --SO.sub.2 --, Z is nitrogen or --C--T.sub.2, T.sub.2 is halogen, hydrogen, C.sub.1 -C.sub.4 alkylthio, cyano, formyl or C.sub.1 -C.sub.4 alkylsulfonyl, m is 1, 2 or 3, n is 0, 1 or 2, q is 0 or 1, and r and s are each either 0 or 1 but never the same as each other, produce dyeings having good fastness properties on nitrogen-containing or hydroxyl-containing fibre materials.
Abstract: A method of manufacturing a color filter for a liquid crystal cell comprises forming a plurality of patterns, each of a respective dye intermediate material, on a carrier element. The patterns of dye intermediate materials are then brought into contact with a substrate layer, supported on a glass substrate, under the application of heat and pressure. The substrate layer, such as a polyacrylonitrile layer, contains free acid groups which interact with the dye intermediate materials to form the colors of the color filter in the substrate layer. The method permits the actual formation of the colors on the substrate to be effected in a single alignment step, minimizing wastage of the relatively expensive glass substrates. Furthermore, as the dyes providing the colors of the filter are chemically part of the substrate layer, they are very resistant to leaching by the liquid crystal materials.
Type:
Grant
Filed:
January 29, 1991
Date of Patent:
May 12, 1992
Assignee:
Thorn EMI plc
Inventors:
Andrew N. Carrington, Bernard J. Green, Francis Jones, deceased
Abstract: Dye mixtures comprising(i) as a yellow component, at least one compound of the formula ##STR1## or a salt thereof, wherein R.sub.1 is hydrogen, C.sub.1-4 alkoxy, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by halo,R.sub.2 is C.sub.1-4 alkyl or --COR.sub.6,wherein R.sub.6 is C.sub.1-6 alkyl, C.sub.1-6 alkoxy or --NR.sub.7 R.sub.8,wherein each of R.sub.7 and R.sub.8 is independently hydrogen, C.sub.1-6 -alkyl or C.sub.2-6 alkyl mono-substituted by hydroxy,R.sub.4 is hydrogen, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy or --NR.sub.3 R.sub.9,R.sub.5 is c.sub.1-4 alkyl or C.sub.2-6 alkyl monosubstituted by hydroxy,R.sub.10 is hydrogen, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy or --NR.sub.3 R.sub.9, andR.sub.11 is hydrogen, halo, C.sub.1-4 alkyl or C.sub.1-4 alkoxy, whereineach R.sub.3 is independently hydrogen or C.sub.1-4 alkyl, andeach R.sub.9 is independently (C.sub.1-6 alkyl)carbonyl or (C.sub.
Abstract: A lens reduces eye strain and fatigue due to glare, after images, reflections or other visual noise incident upon an observer of a visual display terminal. The lens includes a light transmitting plastic body having a convex shaped outer surface for deflecting stray angular radiation and a body provided, in combination with, an ultraviolet absorber to block the transmission of ultraviolet radiation, a colored dye to diminish the intensity of any fluorescent light incident upon the lens and to diminish the transmission of either or both green color radiation or yellow color radiation through the lens and a grey dye to reduce the transmission of incident light.
Abstract: A process for dyeing or printing cellulosic textile fibre materials by the trichromatic technique, which process comprises dyeing or printing said materials from an aqueous liquor with at least one red or reddish brown dyeing dye of formula ##STR1## and at least one yellow or orange dyeing dye of formula ##STR2## and at least one blue dyeing dye of formula ##STR3## wherein A.sub.1, A.sub.2, (B.sub.2).sub.1-3, R.sub.1, R.sub.2, R.sub.3, (R.sub.4).sub.1-2, (X).sub.1-2, (T.sub.1).sub.1-2, (T.sub.2).sub.1-2, (Y).sub.1-3 and Z in formulae (1) to (7) are as defined in claim 1.The process of this invention is suitable for dyeing or printing cellulosic fibre materials.
Type:
Grant
Filed:
January 4, 1991
Date of Patent:
December 10, 1991
Assignee:
Ciba-Geigy Corporation
Inventors:
Jean P. Luttringer, Athanassios Tzikas, Pierre Galafassi
Abstract: The effect of chlorine concentration in laundry solutions on the life of the laundered fabrics is signalled by a chlorine concentration indicator swatch, in which contrastingly hued dyes, including one whose chlorine resistance is measurably stronger than the other, are combined to dye fabric test swatches an initial color. Including such fabric test swatches in chlorine-containing laundry solutions causes visually discernable changes in the hues of the swatches as the bleaching action progressively subtracts those dyes of lesser resistance. Chlorine concentration which, if excessive, seriously impairs laundered fabrics, may be determined by visually inspecting the swatches.
Abstract: Navy and black dye mixtures contain one or more thiopheneazo dyes whose diazo component comes from the 2-aminothiophene series and whose coupling component comes from the aniline series and one or more dyes F whose absorption maximum is at a wavelength of from 390 to 520 nm, the proportion of the thiopheneazo dyes being from 60 to 99% by weight, based on the total weight of the thiopheneazo dyes and the dyes F in the mixture.
Type:
Grant
Filed:
March 23, 1990
Date of Patent:
November 5, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Erwin Hahn, Guenter Hansen, Karl-Heinz Etzbach, Helmut Reichelt, Ernst Schefczik, Helmut Degen, Reinhold Krallmann, Gerhard Wagenblast
Abstract: A leuco dye of the formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, and R.sup.8 each represent a lower alkyl group; A represents ##STR2## in which R.sup.9 and R.sup.10 each represent hydrogen, provided that both R.sup.9 and R.sup.10 may not be hydrogen, --CN or --COR.sup.14 in which R.sup.14 represents a phenyl group which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms, or a halogen, a naphthyl group which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms or a halogen, or a lower alkoxyl group, ##STR3## in which ##STR4## represents a phenyl group or a naphthyl group, R.sup.11 represents hydrogen, a lower alkyl group, a halogen, an amino group, which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, or a nitro group, or ##STR5## in which R.sup.
Abstract: Dye mixtures particularly suitable for dyeing polyester material by the exhaust process containing at least two dicyanobenzanthrone compounds of the formula ##STR1## wherein R is hydrogen or a substituted or unsubstituted alkyl or aryl group and X is hydrogen or halogen located in the 6- or 7-position.
Abstract: A reactive dyestuff composition containing, as a dyestuff component, at least two different reactive dyestuffs which present similar color hue upon dyeing cellulose and have different reactive groups and different substantivities is disclosed. Preferably, the composition contains at least one reactive dyestuff having either a .beta.-sulfatoethyl-sulfone group or vinylsulfone group and at least one reactive dyestuff having a halogenated triazine group. The composition is suitable for dyeing cellulose fibers.
Abstract: Dyed denim cotton yarns capable of meeting the market demand for color jeans can be provided by immersing denim cotton yarns in a dye bath containing a dye or dye composition comprising a specific indirubin derivative(s), a specific quinophthalone derivative(s) and/or an indigo dye, squeezing and air-oxidizing the dyed yarns, and repeating a series of these steps.
Abstract: The method of providing random coloration patterns in fabric using dye impregnated pumice and tumbling with the fabric followed by the use of dye-fixing impregnated pumice and repeating the tumbling sequence. A number of different colored dye solutions can be used in a series of steps to provide a variety of shadings and random color patterns for the treated fabric.
Abstract: A method for dyeing polyester-containing fibers by using a disperse dye, wherein said dyeing is conducted under an alkaline condition in an aqueous medium in the presence of at least one amino acid member selected from the group consisting of an amino acid, an amino acid derivative having at least one hydrogen atom of its amino group replaced with an organic group, and an alkali metal salt of such an amino acid or amino acid derivative, in the dyeing bath, and a dyeing assistant useful for the method.
Abstract: A process for redyeing partially bleached fabric or garments to yield sharply-etched multicolored designs comprises the steps of:(a) dyeing the fabric, or purchasing a commercial garment, with a background first color;(b) gathering selected areas of the dyed fabric with ligatures to restrict access of further reagents;(c) bleaching the gathered background dyed to remove the first color from the areas outside the gathered areas; and(d) redyeing the bleached areas with a second color,whereby sharply defined multicolored patterns are formed having from about 0.2 mm to about 2 mm of white gap between each color.
Abstract: There is disclosed a process for dyeing leather by the exhaust process, which comprises treating leather with an aqueous liquor which contains a formulation comprising an anionic dye and a pigment. The leather dyeings obtained by this process have good allround fastness properties.
Type:
Grant
Filed:
December 21, 1989
Date of Patent:
April 16, 1991
Assignee:
Ciba-Geigy Corporation
Inventors:
Bruno Martinelli, Markus Ghezzi, Gunter Streicher
Abstract: Since anthraquinonoid disperse dyes of the dark blue and navy region give only a low color strength on synthetic fibers, there was an urgent need for their coloristically advantageous substitution by high performance blue azo dyes which are suitable for being used in the carrier dyeing process.According to the invention, the systematic development of multi-component mixtures based on selected blue azo dyes from the dicyano azo series makes it possible to avoid most of the disadvantages mentioned.
Abstract: Compounds of the formula ##STR1## wherein each A, independently, is a ##STR2## wherein R.sub.1 is hydrogen, halo, C.sub.1-4 alkyl or C.sub.1-4 alkoxy,R.sub.2 is hydrogen, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, --NHCONH.sub.2 or --NHCOC.sub.1-4 alkyl,R.sub.3 is hydrogen or methoxy, andm is 0, 1 or 2,each B, independently, is a radical of a diazo or coupling component, and a and each b, independently, are 0 or 1,and metal complexes thereof, which compounds or complexes are in free acid or salt form, and mixtures thereof with a compound of the formula ##STR3## or a metal complex thereof, wherein A and b are as defined above and D is a radical of a diazo or coupling component of the benzene or 1-naphthalene series are useful for dyeing and printing hydroxy group- or nitrogen-containing organic substrates, especially cellulose fibre-containing textiles (e.g., cotton), paper and leather.
Abstract: There are disclosed solid dye formulations which comprise at least one anionic wool dye and optional additional components as well as a mixture of an anionic dispersant and an amphoteric surfactant. Such formulations are distinguished in particular by improved solubility in water.
Type:
Grant
Filed:
February 13, 1989
Date of Patent:
July 31, 1990
Assignee:
Ciba-Geigy Corporation
Inventors:
Paolo Balliello, Otto Schilling, Beat Bruttel
Abstract: Disclsoed herein is dye suitable for use in dyeing denim cotton yarns. The dye comprises at least one quinophthalone derivative represented by the following general formula (I) or (II): ##STR1## wherein X means H, Br or Cl and Y denotes H, COOR or --COOC.sub.2 H.sub.4 OR (R: alkyl), or a combination of said at least one quinophthalone derivative and an idigo dye. A dyeing process making use of the above dye and denim cotton yarns thus dyed are also disclosed.
Abstract: Trichromatic dyeings with acid dyes which exhaust from strongly acidic liquors have weaknesses with respect to wet fastness, which are due to insufficiently fast components (blue, red). It has been found, according to the invention, that by replacing the insufficiently fast acid dyes by reactive dyes of the vinylsulfonyl type and retaining the method of dyeing under strongly acidic conditions the wet fastness level of the exhaust dyeings can be improved while the levelness obtained remains as good.
Type:
Grant
Filed:
December 16, 1986
Date of Patent:
March 27, 1990
Assignee:
Hoechst Aktiengesellschaft
Inventors:
Hans-Ulrich von der Eltz, Karl-Heinz Rostermundt, Klaus Turschmann
Abstract: Navy and black dye mixtures contain one or more thiophene-azo dyes of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, X and Y each have defined meanings, and one or more dyes F whose absorption maximum is at a wavelength of from 390 to 520 nm, the proportion of thiophene-azo dyes being from 60 to 99% by weight, based on the total weight of thiophene-azo dyes and dyes F in the mixture.
Type:
Grant
Filed:
October 13, 1988
Date of Patent:
March 13, 1990
Assignee:
BASF Aktiengesellschaft
Inventors:
Erwin Hahn, Guenter Hansen, Karl-Heinz Etzbach, Helmut Reichelt, Ernst Schefczik, Helmut Degen, Reinhold Krallmann, Gerhard Wagenblast
Abstract: The invention refers to a mixture of anionic dyestuffs having a skitteriness value at pH5 of 3-4 and a combinability value at pH5 of 4-5 and to a process for dyeing a fibre material comprising wool with such a mixture of dyestuffs. These mixtures of anionic dyestuffs give surface and fibre level dyeings.
Type:
Grant
Filed:
March 3, 1988
Date of Patent:
January 16, 1990
Assignee:
Sandoz Ltd.
Inventors:
Oskar Annen, Wolfgang Beck, Josef Frauenknecht
Abstract: A process for the photochemical stabilization of polyamide fiber material or mixtures thereof with other fiber materials which comprises treating the fiber material with a mixture of (A) a water-soluble copper complex dye or a mixture of copper complex compounds, at least one component being a water-soluble copper complex dye, (B) a light stabilizer and if desired (C) an antioxidant, an agent for carrying out the process and the fiber material treated therewith are described.
Abstract: Dyeing formulations in solid or liquid form, containing one or more red disperse dyes of the general formula (1) ##STR1## where R.sub.1 denotes an alkyl group of 1 to 4 carbon atoms, and one or more red disperse dyes of the general formula (2) ##STR2## where R.sub.2 and R.sub.3 denote independently of each other the group --CH.sub.2 --CH.sub.2 --CH.sub.2 --COOCH.sub.3 or --CH.sub.2 --CH.sub.2 --CH.sub.2 --COOC.sub.2 H.sub.5 and R.sub.
Abstract: An ultraviolet screening agent can be incorporated into a preformed silicone rubber intraocular lens by bringing it into contact with a solution which contains the agent in a higher concentration than the lens material.
Abstract: The ultraviolet screening of a silicone rubber intraocular lens can be enhanced by the addition of an optical brightener. The optical brightener also serves to reduce any apparent yellow tint that may occur. The optical brightener is incorporated into the preformed silicone lens by immersing it in a solution containing the optical brightener and an ultraviolet screening agent.
Abstract: The mixture of monoazo dyestuffs which contains one or more dyestuffs of the formula I ##STR1## and one or more dyestuffs of the formula II ##STR2## wherein R.sup.1 and R.sup.2 independently of one another denote linear or branched alkyl with 1 to 6 carbon atoms and R denotes linear or branched alkyl with 1 to 3 carbon atoms, is outstandingly suitable for dyeing and printing hydrophobic materials a deep blue color.
Type:
Grant
Filed:
January 27, 1988
Date of Patent:
October 10, 1989
Assignee:
Bayer Aktiengesellschaft
Inventors:
Ulrich Buhler, Klaus Hofmann, Manfred Hahnke
Abstract: A trichromatic dye combination especially suited for the continuous dyeing of synthetic polyamide materials; the system including an acid red dye component, an acid blue dye component and an acid yellow dye component, each of said dye components being selected on the basis of minimum and compatible cold strike and compatible on tone strike rates.The trichromatic combination according to the invention dyes synthetic polyamide fibers from aqueous liquors, producing level dyeings having excellent fastness properties including good lightfastness and good ozone fastness.
Abstract: A dyestuff mixture for coloring synthetic fibers a yellow color contains as component A a dyestuff of the formula ##STR1## and as component B a different yellow disperse dyestuff species.
Type:
Grant
Filed:
November 30, 1987
Date of Patent:
September 20, 1988
Assignee:
Cassella Aktiengesellschaft
Inventors:
Manfred Hahnke, Ulrich Buhler, Albert Bode
Abstract: A process for dyeing a mixed fibrous substrate comprising applying to the substrate at least one disperse dye and at least one metal containing direct and/or reactive dye in the presence of a complexing agent having a stability constant K value with the metal of the direct or reactive dye of from 6 to 17 inclusive.
Abstract: A reactive blue dye composition, which comprises a phthalocyanine dye represented by a free acid of the following formula (I), ##STR1## wherein CuPc is a copper phthalocyanine nucleus, W is a C.sub.2 -C.sub.4 alkylene group or a 1,3- or 1,4-phenylene group having one or two sulfo groups, R.sub.1 and R.sub.2 are independently a hydrogen atom or a lower alkyl group, 1 is a number of 1 to 3, m is a number of 0 to 2, and n is a number of 1 to 3, provided that the total number of 1, m and n is 4 or less, and a phthalocyanine dye represented by a free acid of the following formula (II), ##STR2## wherein CuPc, 1, m and n are as defined above, Y.sub.1 and Y.sub.2 are independently a hydrogen atom or a methyl, methoxy or sulfo group, R.sub.3 is a hydrogen atom or a lower alkyl group, and Q is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.
Abstract: The invention relates to dye compositions for preparing level dyeings on carboxamide- or hydroxyl-containing fiber materials of comparatively good light fastness properties, which contain dioxazine dyes I (Ia and/or Ib) and II (one or more of IIa to IId) in a weight ratio of 90:10 to 10:90 ##STR1## where in each case independently of one another Z denotes vinyl or .beta.-sulfatoethyl,Z' denotes vinyl-SO.sub.2 or .beta.-sulfatoethyl-SO.sub.2 --,R denotes sulfo or --SO.sub.2 --NR.sup.8 R.sup.9, wherein R.sup.8 is H or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl and R.sup.9 is H, C.sub.1 -C.sub.4 -alkyl which can be substituted by sulfato, sulfo, carboxyl or phosphato, or is an arylated C.sub.1 -C.sub.4 -alkyl group which can be substituted in the aryl radical by sulfo or carboxyl,R.sup.1 denotes H or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,R.sup.2 denotes C.sub.1 -C.sub.
Abstract: A water-insoluble disperse dye composition comprising a combination of a dye represented by the following formula (I), ##STR1## wherein X is hydrogen, halogen, lower alkyl or lower alkoxy, in an amount of 95 to 20% by weight, and a dye represented by the following formula (II), ##STR2## wherein Z, Y.sub.1 and Y.sub.2 are independently hydrogen or halogen, and the ring A is a benzene or naphthalene ring unsubstituted or substituted with a carboxylic acid ester group, in an amount of 5 to 80% by weight, which is useful for dyeing polyester fiber materials to obtain dyed products having both extremely high light fastness and excellent thermal resistance.
Abstract: Disperse Blue 56 is an important blue dyestuff for dyeing PES fibers at the boil or under high-temperature conditions. This anthraquinonoid compound Disperse Blue 56, in addition to its advantages (high light fastness, pH/reduction insensitivity, purity of hue), has some technical disadvantages (poor leveling properties, pronounced staining of adjacent fiber, metameric red shift).By combining a plurality of blue disperse azo dyestuffs having selected structural features in the form of mixtures or mix-crystals it is possible to match the advantages of Disperse Blue 56 while substantially avoiding its disadvantages at the same time. These azo dyestuffs are based on coupling products of diazotized 2,6-substituted 4-nitroanilines with substituted N,N-dialkylanilines.
Type:
Grant
Filed:
December 20, 1985
Date of Patent:
August 25, 1987
Assignee:
Hoechst Aktiengesellschaft
Inventors:
Manfred Hahnke, Reinhard Kuhn, Reinhard Hahnle, Rudolf Schickfluss
Abstract: The invention relates to a process for dyeing natural or synthetic polyamide fibre material levelly from an aqueous liquor, with 1:1 metal complex dyes and at least one metal free dye, all of which contain sulfo groups, in the presence of an alkali metal salt or an ammonium salt and optionally in the presence of an assistant, which comprises carrying out dyeing in the presence of an alkali metal fluoride or ammonium fluoride, or an alkali metal fluorosilicate or ammonium fluorosilicate, or of an alkali metal fluoroborate or ammonium fluoroborate, at a pH in the range from 3 to 7.The process of this invention is suitable for dyeing natural or synthetic polyamide material in level shades of good fastness properties.
Abstract: Synthetic fiber materials are effectively colored by dyeing or printing with a dyestuff mixture containing at least two separate dyestuffs (I) and (II) in a weight ratio of (I):(II) of from (20 to 99):(80 to 1) wherein:(I) is at least one dyestuff of the formula ##STR1## and (II) is at least one dyestuff of the formula ##STR2## in which X and Y are the same or different and each is independently chloro and bromo:R.sup.1 and R.sup.
Abstract: Cellulosic fibers are converted to cellulosate by immersion in an alkali metal hydroxide and then reacted with an aqueous solution of thioarylsulfonium salts to produce modified cellulosic fibers which are substantive to acid, direct, disperse, reactive and sulfur dyes. Cellulosic/synthetic and cellulosic/wool blends can also be treated to produce a fabric blend comprising modified cellulosic components that are substantive to diverse dye classes and synthetic and wool components which are substantive to a single dye class. When using a disperse dyebath of one color the entire fabric blend is dyed one color. When adding an acid, reactive or sulfur dye of a second color to the dyebath, the synthetic or wool component is dyed one color and the cellulosic component is dyed a different color.
Type:
Grant
Filed:
September 3, 1986
Date of Patent:
July 7, 1987
Assignee:
The United States of America as represented by the Secretary of Agriculture
Abstract: Novel dye mixtures which contain dyes of the general formulae I ##STR1## and II ##STR2## in the form of the alkali metal and ammonium salts, where m and n are each 0 to 4, p and q are each 1 or 2, r is 0 or 1, m+n is 2, 3 or 4, B.sup.1 and B.sup.2 are each hydrogen or chlorine, or B.sup.1 and B.sup.2 together form part of a fused benzene ring which is unsubstituted or substituted by SO.sub.3 H, R.sup.1 and R.sup.2 independently of one another are each hydrogen or unsubstituted or substituted lower alkyl or cyclohexyl, or R.sup.1 and R.sup.2 together with the nitrogen form a saturated heterocyclic structure, and Z is a reactive radical which is usually present in reactive dyes and which is bonded to the diazo or coupling component, are very useful for dyeing paper stocks.
Abstract: A method of dyeing textile materials of polycapronamide, enabling low temperature dyeing conditions and process duration times which do not exceed the art standards, is characterized by the following combined features: (a) use of at least two discrete combinations of dyestuffs, which show different kinetic behaviors from each other; (b) maintenance of an alkaline pH at tapering values, in the extreme down to neutral; (c) use of exclusively anionic dyeing aids; and (d) maintenance through the various method steps of a maximum temperature as high as 60.degree. C., preferably as 40.degree. C.Perfectly uniform dyeing is achieved through the utilization of conventional apparata and dyeing method procedures.
Abstract: A method for dyeing polyester fiber materials is disclosed, comprising conducting combination dyeing by a combination of disperse dyes each capable of making up for the color fading of other disperse dye produced upon exposure to sunlight, by the color change thereof in hue caused upon the exposure to sunlight under the same condition.
Abstract: Synthetic fiber materials are effectively colored by dyeing or printing with a dyestuff mixture containing at least two separate dyestuffs (I) and (II) in a weight ratio of (I):(II) of from (20 to 99):(80 to 1) wherein:(I) is at least one dyestuff of the formula ##STR1## and (II) is at least one dyestuff of the formula ##STR2## in which X and Y are the same or different and each is independently chloro and bromo:R.sup.1 and R.sup.