Abstract: The invention relates to a fluid storage tank having an interior volume and a floor and having an internal spill containment chamber comprising a vent gas scrubbing apparatus or scrubber. The chamber may be defined by a containment wall which completely separates the chamber from the tank interior volume. The containment wall may comprise an exterior portion which extends beyond the tank wall. The scrubber is disposed within the chamber and comprises a gas inlet passing through the containment wall into the tank interior volume, a gas outlet for venting scrubbed gases, and a gas scrubbing chemical storage and circulation system.

Abstract: A device for gas analysis includes a detector tube (2) and can be used in the area of explosive or combustible gases. A filter material, which consists of a granular, porous material and has an impregnation for absorbing toxic gases, is provided between the detector tube (2) and a pump (6).

Abstract: A method is provided for forming a zeolitic imidazolate framework composition using at least one reactant that is relatively insoluble in the reaction medium. Also provided herein is a material made according to the method, designated either as EMM-19 or as EMM-19*, and a method of using same to adsorb and/or separate gases, such as carbon dioxide.

Abstract: Methods for preparing metakaolin-enhanced industrial minerals. Mixing and heating kaolinite clay with an industrial mineral, such as activated carbon, that is between 750° F. and 1400° F. results in a metakaolin/activated carbon complex that provides good mercury sorbent qualities while producing a fly ash (after use as a sorbent in emissions applications) that has a lower foaming index.

Abstract: The invention relates to an air filter element of a passenger compartment for the driver's cab of agricultural and work machines, in particular with spraying and atomizing devices for pesticides and fertilizers, comprising an adsorption filter layer with activated carbon, a fine filter layer in particular for separating aerosols and a circumferential sealing for separating the raw side from the clean side during installation into a filter housing.

Abstract: A nitrous oxide room temperature purification method, apparatus and system utilizing at least partially oxidized nickel. In an embodiment, a room temperature regenerable N2O purifier includes a vessel having an inlet and outlet, an active portion being at least partially filled with a purification material comprising nickel oxide and optional elemental nickel, wherein the weight ratio between the nickel oxide and the optional elemental nickel is equal or higher than 3 and the surface area of the nickel oxide and the optional elemental nickel is equal or higher than 50 m2/g.

Abstract: Adsorbent compositions useful in adsorption, separation and purification processes are made using silicone-derived binding agents. The adsorbent compositions having enhanced adsorption rate and crush strength properties are made from agglomerated crystallite particles bound with silicone-derived binding agents. The silicone binder precursors are calcined during the manufacturing process to produce the silicone-derived binding agents. The adsorbent compositions are preferably used in air separation processes.

Abstract: The present invention relates generally to compositions useful in adsorption and reactive processes comprising an adsorbent powder, such as a zeolite, and a binder mixed to form an agglomerate having a porosity of 0.30??p?0.42 and a N2 pore diffusivity Dp?3.5×10?6 m2/s and wherein the mean particle diameter of the crystalline zeolite powder is 10 ?m or less; the mean particle diameter of the binder is 0.10 dA or less, and the binder concentration is 10% or less expressed on a dry weight basis.

Abstract: Filter media suitable for various applications and related components, systems, and methods associated therewith are described. The filter media may include a composite structure having a mixture comprising fibrillated fibers (e.g., lyocell) and functional particles. The filter media may exhibit favorable absorption and/or adsorption characteristics.

Abstract: Adsorbent compositions useful in adsorption and separation processes are made using silicone-derived binding agents. The adsorbent compositions are made from crystallite aluminosilicate particles bound with silicone-derived binding agents, and optionally small amounts of a clay binder, to form agglomerated crystallite particles and are calcined to volatilize the organic components associated with the silicone-derived binding agents. The agglomerated crystallite particles have superior pore structures and superior crush strengths at low binder concentrations and exhibit enhanced N2 adsorption rates and capacities when used in air separation processes.

Abstract: Systems and methods for producing a product gas are provided. In one embodiment, a plurality of gas separation assemblies separate adsorbable components from a gas source using a plurality of micro-pumps to create gas flow through the gas separation assemblies. Various embodiments include implementation of various pressure swing adsorbtion (PSA), vacuum swing adsorbtion (VSA), and vacuum pressure swing adsorbtion (VPSA) systems utilizing the gas separation assemblies with micro-pumps. In other embodiments, micro-pumps and micro-pump assemblies are arranged in various configurations capable of providing a range of pressures and flow rates.

Abstract: The invention relates to adsorbents for removing impurities from water-comprising gas streams, in particular for use in fuel cell systems, wherein the adsorbents comprise oxides of elements selected from the group consisting of Cu, Fe, Zn, Ni, Co, Mn, Mg, Ba, Zr, Ce, La or combinations of these elements, have a copper oxide content of at least 30% by weight and have pore volumes of less than 0.175 ml·g?1 for pores having a radius of less than 20 nm.

Abstract: This invention provides metal-organic frameworks (MOFs) having repeat units of the formula Zn4O(fumarate)3. Also provided are compositions thereof and methods use thereof, including for gas storage, gas separation, catalysis and sensing.

Abstract: An adsorbent medium for removing gaseous contaminants from air comprises a porous self-supporting filter element produced by sintering particles of polyethylene having a molecular weight greater than 400,000 g/mol as determined by ASTM-D 4020 and an adsorbent. In one embodiment, the filter element comprises a body perforated by a plurality of holes extending in the direction of fluid flow in use and having a diameter of less than 10 mm. In another embodiment, the filter element comprises a panel wherein at least the surface of the panel presented, in use, to the incoming air comprises a plurality of projections. In a further embodiment, the filter element comprises a fibrous web having particles of the adsorbent secured to the web by the sintered polyethylene.

Abstract: An improved air purification adsorbent is disclosed. The air purification adsorbent comprises titanium dioxide (TiO2) impregnated with zinc chloride (ZnCl2). The adsorbent may be used in air purification systems for removing ammonia from air streams. The nanocrystalline (amorphous) structure of the adsorbent results in a higher density of surface defects, higher surface area, and higher reactivity which, when combined with the synergistic effect of ZnCl2 and the nanocrystalline TiO2, provides a significantly longer breakthrough time of ammonia as compared with breakthrough time from unimpregnated nanocrystalline TiO2, the commercial (crystalline) TiO2 impregnated with ZnCl2, pure ZnCL2, and other commercially available adsorbents of ammonia. Other embodiments are described and claimed.

Abstract: A novel carbon absorption material is described which is formed from anaerobic digestate. The material has a hollow tubular structure and is particularly advantageous in converting hydrogen sulfide in biogas and in absorbing the converted sulfur and sulfur compounds from biogas into its structure. The material after use as a hydrogen sulfide absorbent has value as a horticultural or agricultural product or as a sulfur impregnated activated carbon. The process for producing this novel carbon absorption material is described. In an embodiment, the process described uses in particular, a humidified inert gas over a temperature range of between about 500° C. to 900° C. to convert anaerobic digestate to an active carbon absorbent. The thermal treatment is relatively mild and retains the fibrous structure of the source material while removing cellulosic and hemicellulosic components from the anaerobic digestate.

Abstract: The present invention provides the following new polymers which are useful for hydrogen storage: (i) a polymer comprising -[MN2]— as a repeating unit, wherein M is selected from the group consisting Sc, Ti, V, Cr, Mn, Fe, Co, Zr, Nb, Mo, and mixtures thereof; and (ii) a polymer comprising -[M2N3]— as a repeating unit, wherein M is selected from the group consisting Sc, Ti, V, Cr, Mn, Fe, Co, Zr, Nb, Mo, and mixtures thereof.

Abstract: The invention relates to an adsorbent zeolite-based material comprising for 100 mass % an amount different from zero of a zeolite selected from X zeolites or LSX zeolites; the balance up to 100 mass % consisting of an amount different from zero of a cation-exchanged zeolite, said cation-exchanged zeolite being selected from cation-exchanged X zeolites and cation-exchanged LSX zeolites.

Abstract: MOF (metal organic framework)-modified materials and methods of making and methods of using same. The MOFs are covalently bound to the materials. Examples of suitable materials include fibers and thin films. The MOF-modified materials can be made by forming MOFs in situ such that they are covalently bound to the materials. The MOF-modified materials can be used in methods where gases and/or toxic chemicals are absorbed.

Abstract: Methods and/or systems using magnetically assisted pressurization of a gas for the generation of useful power from heat transfer using heat sources at lower temperatures in a manner that does not require the emission of CO2.

Abstract: Systems and methods for treating a fluid with a body are disclosed. Various aspects involve treating a fluid with a porous body. In select embodiments, a body comprises ash particles, and the ash particles used to form the body may be selected based on their providing one or more desired properties for a given treatment. Various bodies provide for the reaction and/or removal of a substance in a fluid, often using a porous body comprised of ash particles. Computer-operable methods for matching a source material to an application are disclosed. Certain aspects feature a porous body comprised of ash particles, the ash particles have a particle size distribution and interparticle connectivity that creates a plurality of pores having a pore size distribution and pore connectivity, and the pore size distribution and pore connectivity are such that a first fluid may substantially penetrate the pores.

Abstract: An apparatus for capture and sequestration of CO2 from fossil fuel-fired power plant flue gas includes a polymer matrix embedded with a sorbent suitable for removing CO2 from the flue gas and a spacer mated with the polymer matrix. The spacer is adapted to create channels between adjacent portions of the polymer matrix such that the flue gas flows through the channels and comes in contact with the sorbent. Further, an apparatus for the capture and sequestration of CO2 from fossil fuel-fired power plant flue gas includes a hollow fiber membrane embedded with an adsorbent or other suitable material for removing CO2 from the flue gas. The adsorbent particles may be embedded into a wall of the membrane.

Abstract: A method is provided for forming a zeolitic imidazolate framework composition using at least one reactant that is relatively insoluble in the reaction medium. Also provided herein is a material made according to the method, designated either as EMM-19 or as EMM-19*, and a method of using same to adsorb and/or separate gases, such as carbon dioxide.

Abstract: One exemplary embodiment can be an apparatus for isomerizing a hydrocarbon stream rich in a C4 hydrocarbon and/or at least one of a C5 and C6 hydrocarbon. The apparatus can include:a vessel containing a fluid including at least one reactant; a fluid transfer device receiving the fluid including at least one reactant from the vessel; at least one drier receiving the fluid including at least one reactant from the fluid transfer device; and a reactor communicating with the at least one drier to receive the fluid including at least one reactant. In addition, the at least one drier may communicate with the vessel at least by sending the fluid including at least one reactant or the regenerant through a fluid tapering device for at least one of regulating the flow and reducing the pressure of the regenerant to the vessel.

Abstract: One exemplary embodiment can be an apparatus for isomerizing a hydrocarbon stream rich in a C4 hydrocarbon and/or at least one of a C5 and C6 hydrocarbon. The apparatus can include: a first drier and a second drier adapted to receive a fluid including at least one reactant; and a reaction zone communicating with the first drier to receive the fluid including at least one reactant and with the second drier to receive the regenerant. Generally, the first drier operates at a first condition to dry the fluid including at least one reactant and the second drier operates at a second condition during regeneration with a regenerant. The regenerant can pass through a fluid tapering device for regulating the flow of the regenerant to the reaction zone.

Abstract: Embodiments of crystalline, titanium silicate molecular sieves are described having a formula representing mole ratios of oxides of nM1O:TiO2:ySiO2:zH2O:wX where M1 refers to a metal cation or mixture of metal cations; n is from about 1 to about 2; y is from about 1 to about 10; z is from 0 to about 100; X is a halide anion other than fluorine, or combination of halide anions that excludes fluorine; and w is greater than 0. The pore size of the sieves can be adjusted by ion exchanging M1 cations with a suitable amount of another species. Embodiments of the invention are useful for various adsorptive fluid separation processes, including pressure swing adsorption processes. For example, disclosed embodiments are useful for separating methane from air.

Abstract: In an apparatus for collection of waste anesthetic gases, and a method of using such an apparatus, the apparatus has a gas collection chamber with an input port to be connected to an exhaust of an anesthesia delivery system for receiving a first gas flow therefrom that contains a waste anesthetic gas component. An output port from the gas collection chamber is connected to a vacuum system for evacuation of an evacuation gas flow from the gas collection chamber. A bidirectional port leads to and from the gas collection chamber, which has an adsorbing unit connecting the gas collection chamber with an ambient environment surrounding the gas collection chamber. The apparatus provides for safe prevention of discharge of exhaled anesthetic gases into an ambient atmosphere surrounding the apparatus.

Abstract: The disclosure relates generally to a gas-separation system for separating one or more components from a multi-component gas using Zeolitic imidazolate or imidazolate-derived framework.

Abstract: Embodiments of the present disclosure provide for collection devices, methods of making collection devices, methods of collecting gases and aerosol particles, and the like.

Abstract: Methods of purifying hydrogen-containing materials are described. The methods may include the steps of providing a purifier material comprising silica. The silica may be heated at temperature of about 100° C. or more in a dry atmosphere to form activated silica. The activated silica may be contacted with a starting hydrogen-containing material, where the activated silica reduces a concentration of one or more impurity from the starting hydrogen-containing material to form the purified hydrogen-containing material, and where the activated silica does not decompose the purified hydrogen-containing material.

Abstract: A new lithium material with high surface area, a method of its production, and a process of using the given material in purification of hydrogen or inert gases stream from active impurities. The material is manufactured in a form of granules of 0.2-2.5 mm in diameter with the structure of a dendritic carcass and is characterized with high sorption capacity and resistance to chemical shocks.

Abstract: A process for the industrial isolation of propene from a gas stream comprising at least propene and propane, which involves contacting of the gas stream with an adsorbent having a porous metal organic framework having at least one at least bidentate organic compound coordinated to at least one metal ion, with the adsorbent becoming laden with propane and the gas stream therefore having an increased proportion of propene, wherein the W least bidentate organic compound is an imidazolate which is unsubstituted or has one or more substituents selected independently from of halogen, C1-6-alkyl, phenyl, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, O-phenyl and O—C1-6-alkyl.

Abstract: An acid-gas sorbent comprising an amine-composite. The present composite may comprise a first component comprising an amine compound at a concentration of from about 1 wt % to about 75 wt %; a second component comprising a hydrophilic polymer and/or a pre-polymer compound at a concentration of from about 1 wt % to about 30 wt %; and a third component comprising a cross-linking agent, and/or a coupling agent at a concentration of from about 0.01 wt % to about 30 wt %.

Abstract: An air dryer cartridge is provided for a compressed air supply system, in particular a compressed air supply system of a commercial vehicle, with a drying agent box which is filled with a drying agent. The drying agent box can be coupled in an axial direction to a connecting flange of the compressed air supply system. A seal, which is designed as a non-return valve and, in the fitted state of the air dryer cartridge, acts in a sealing manner between the drying agent box and the connecting flange, is arranged on the drying agent box. A method for operating the air dryer cartridge on the compressed air supply system is also provided.

Abstract: Disclosed herein are rod-packing robust microporous metal-organic frameworks having the repeat unit Zn4(OH)2(1,2,4-BTC)2, useful for applications such as selective gas storage, selective gas sorption and/or separation, selective sensing of chemicals, and catalysis.

Abstract: A differential absorption spectrum for a reactive gas in a gas mixture can be generated for sample absorption data by subtracting background absorption data set from the sample absorption data. The background absorption data can be characteristic of absorption characteristics of the background composition in a laser light scan range that includes a target wavelength. The differential absorption spectrum can be converted to a measured concentration of the reactive gas using calibration data. A determination can be made whether the background composition has substantially changed relative to the background absorption data, and new background absorption data can be used if the background composition has substantially changed. Related systems, apparatus, methods, and/or articles are also described.

Abstract: The present invention relates to a process for the separation of gases which comprises putting a mixture of gases in contact with a zeolite of the ESV type to obtain the selective adsorption of at least one of the gases forming the gaseous mixture. The present invention also relates to particular zeolitic compositions suitable as adsorbents.

Abstract: The present invention relates to a filter unit for cleaning fluids, filter systems comprised of a plurality of said filter units, and the use of the filter unit or of the filter systems for filtering sludge and floating algae from water, or for purifying gases.

Abstract: Information used for creating an adsorption isostere of a substance to be measured in a measuring system (container) is obtained by repeating alternately a first control step of changing temperature or pressure of the measuring system by a fixed amount by adjusting a gas amount supplied to/discharged from the measuring system, and a second control step of changing pressure or temperature of the measuring system by adjusting the gas amount supplied to/discharged from the measuring system until a gas adsorption amount of the substance to be measured becomes the same as before execution of the first control step.

Abstract: Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.

Abstract: In accordance with the purpose(s) of the present disclosure, as embodied and broadly described herein, embodiments of the present disclosure, in one aspect, relate to materials that can be used for gas (e.g., CO2) capture, methods of making materials, methods of capturing gas (e.g., CO2), and the like, and the like.

Abstract: A system and method for systematically generating potential metal-organic framework (MOFs) structures given an input library of building blocks is provided herein. One or more material properties of the potential MOFs are evaluated using computational simulations. A range of material properties (surface area, pore volume, pore size distribution, powder x-ray diffraction pattern, methane adsorption capability, and the like) can be estimated, and in doing so, illuminate unidentified structure-property relationships that may only have been recognized by taking a global view of MOF structures. In addition to identifying structure-property relationships, this systematic approach to identify the MOFs of interest is used to identify one or more MOFs that may be useful for high pressure methane storage.

Abstract: A system and related method for purifying indoor air comprising: a filter bed comprising a growing medium suitable for growing plants rooted therein and configured to be capable of sustaining an airflow therethrough between a top surface thereof and a bottom surface thereof; a micro-irrigation system comprising a plurality of irrigation source outlets for delivering water to the filter bed in a substantially-uniform fashion; an active region of the filter bed comprising that region of the filter bed configured so as to substantially have the airflow flowing therethrough; and micro-irrigation system configured such that water therefrom is capable of being projected so as to reach at least 50% of a top surface area of the active region.

Abstract: The present invention provides a process for treating a natural gas stream comprising sending a natural gas stream to at least one membrane unit to produce a permeate stream containing a higher concentration of carbon dioxide and a retentate stream containing a lower concentration of carbon dioxide. Then the retentate stream is sent to an adsorbent bed to remove carbon dioxide and other impurities to produce a natural gas product stream. The regeneration gas stream is sent through the molecular sieve adsorbent bed to desorb the carbon dioxide. In one process flow scheme, the regeneration stream is combined with the permeate stream from the membrane unit. Then the combined stream is sent to an absorbent column to remove carbon dioxide from the permeate stream to produce a second natural gas product stream. In the alternative flow scheme, a second membrane unit is used to improve efficiency.

Abstract: The porous coordination polymer of the invention contains metal complexes formed by coordination bonding between a trivalent metal ion and an aromatic tricarboxylic acid represented by formula (1). The porous coordination polymer also has a pore structure formed by integration of a plurality of the metal complexes. [In formula (1), n represents an integer of 0 to 4.

Abstract: Filters including activated carbon cloth are described herein. Embodiments include a filter medium including at least one activated carbon cloth layer, at least one fibrous material layer, and at least one support layer, and filter cartridges including these filter mediums as well as methods for using these filter mediums to filter exhaust from diesel automobiles and diesel trucks.

Abstract: The invention concerns a crystalline solid designated IM-20 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO2: nGeO2: pZ2O3: qR: sF: wH2O, in which R represents one or more organic species, X represents one or more tetravalent element(s) other than germanium, Z represents at least one trivalent element and F is fluorine.

Abstract: A method includes operating a gas loading system with a source of one or more isotopes of hydrogen, a gas loading chamber containing a number of metallic nanoparticles, the metallic nanoparticles being selected to provide for a predetermined hydrogen cluster formation density, a vacuum system, and a valve system in communication with the gas loading chamber, the source of one or more isotopes of hydrogen and the vacuum system; providing the gas loading chamber with a first quantity of the one or more isotopes of hydrogen from the source of one or more isotopes of hydrogen; monitoring an operating temperature; and cycling a loading pressure of the gas loading chamber using the source of one or more isotopes of hydrogen in response to providing the gas loading chamber and monitoring the operating temperature.

Abstract: A consolidated nanofiber nonwoven comprising a plurality of roped fiber bundles having a length axis. The roped fiber bundles comprise a plurality of nanofibers having a median diameter of less than one micrometer, where at least 50% by number of the nanofibers are oriented within 45 degrees of the length axis of the roped fiber bundles. The nanofibers within the same roped fiber bundle are entangled together. The roped fiber bundles are randomly oriented within the nanofiber nonwoven and are entangled with other roped fiber bundles within the nanofiber nonwoven. At least a portion of the nanofibers are entangled with and adhered to other nanofibers within the same roped fiber bundle and at least a portion of the roped fiber bundles are entangled with and adhered to other roped fiber bundles within the consolidated nanofiber nonwoven.

Abstract: A composite media including at least one crystalline aluminosilicate material in polyacrylonitrile. A method of forming a composite media is also disclosed. The method comprises dissolving polyacrylonitrile in an organic solvent to form a matrix solution. At least one crystalline aluminosilicate material is combined with the matrix solution to form a composite media solution. The organic solvent present in the composite media solution is diluted. The composite media solution is solidified. In addition, a method of processing a fluid stream is disclosed. The method comprises providing a beads of a composite media comprising at least one crystalline aluminosilicate material dispersed in a polyacrylonitrile matrix. The beads of the composite media are contacted with a fluid stream comprising at least one constituent. The at least one constituent is substantially removed from the fluid stream.