Process Of Making Developer Composition Patents (Class 430/137.1)
  • Publication number: 20130344433
    Abstract: A method for producing dry toner particles that have similar particle size and shape characteristics as chemically produced toners. The method includes melt-mixing a toner resin with a colorant and, optionally, a wax, to form a toner; grinding the toner to form toner particles; classifying the toner particles into particles averaging 4 to 10 microns in size; blending the classified toner particles with additives in a high-speed blender; and then processing the mixture with optional additional surface additives in a conical mixer. The method produces toner particles that have high circularity and sharper particle size distribution. The surface processing of the toner particles does not affect the internal constituents of the toner particles.
    Type: Application
    Filed: June 26, 2012
    Publication date: December 26, 2013
    Applicant: XEROX CORPORATION
    Inventors: Paul CASALMIR, Bryan L. NORCOTT
  • Patent number: 8609313
    Abstract: A toner containing a resin binder and a colorant, wherein the resin binder contains a crystalline resin and an amorphous resin, the crystalline resin containing a composite resin containing: a polycondensation resin component obtained by polycondensing an alcohol component containing an aliphatic diol having 2 to 10 carbon atoms, and a carboxylic acid component containing an aromatic dicarboxylic acid compound, and a styrenic resin component, and the amorphous resin containing a polyester obtained from an alcohol component containing an aliphatic diol in an amount of 60% by mol or more, and a carboxylic acid component. The toner of the present invention is suitably used in, for example, the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.
    Type: Grant
    Filed: May 13, 2011
    Date of Patent: December 17, 2013
    Assignee: Kao Corporation
    Inventors: Akihiro Eida, Shogo Watanabe, Takashi Kubo
  • Publication number: 20130330522
    Abstract: White toner contains a binder resin, a white pigment, and a releasing agent, wherein the white pigment is coated with the releasing agent and dispersed in the binder resin.
    Type: Application
    Filed: May 31, 2013
    Publication date: December 12, 2013
    Inventors: Kazumi SUZUKI, Tatsuya MORITA, Yoshitaka YAMAUCHI, Masana SHIBA, Azumi MIYAAKE
  • Patent number: 8603721
    Abstract: Disclosed is a process for preparing toner particles which comprises: (a) selecting a carbon black; (b) measuring the surface level of sulfur of the carbon black by X-ray Photoelectron Spectroscopy to ensure that the surface level of sulfur is no more than about 0.05 atomic percent; and (c) mixing the carbon black with a resin to generate a toner composition.
    Type: Grant
    Filed: April 6, 2011
    Date of Patent: December 10, 2013
    Assignee: Xerox Corporation
    Inventors: Thomas P Debies, Timothy L Lincoln, Kevin F Marcell
  • Patent number: 8603373
    Abstract: A method for producing particles, including: bringing a compressive fluid into contact with a pressure plastic material, so as to produce a melt of the pressure plastic material; and discharging the melt of the pressure plastic material by differential pressure to a space, so as to form particles, wherein the discharging includes at least one of (A) discharging the melt of the pressure plastic material while a compressive fluid is supplied to the melt of the pressure plastic material, and (B) discharging the melt of the pressure plastic material through one or more through-holes, to which vibration is applied, so as to change the shape of the melt of the pressure plastic material from a columnar shape, through the columnar shape with constrictions, into a particle shape.
    Type: Grant
    Filed: October 31, 2011
    Date of Patent: December 10, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinji Ohtani, Chiaki Tanaka
  • Patent number: 8603719
    Abstract: A method for producing an electrophotographic toner including forming a toner base particle by emulsifying or dispersing a solution or dispersion of a toner material comprising a colorant, and any one of a binder resin and a binder resin precursor in an aqueous medium, and adding crystalline organic fine particles having an acid value of 20 mgKOH/g to 80 mgKOH/g into the aqueous medium, before, during or after the forming so as to attach the crystalline organic fine particles onto a surface of the toner base particle.
    Type: Grant
    Filed: June 20, 2011
    Date of Patent: December 10, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Yamashita, Yuichi Shirasu, Masaki Watanabe, Tomoki Murayama
  • Publication number: 20130323637
    Abstract: Provided is a toner that is excellent in terms of low-temperature fixability and hot offset resistance, has a wide fixing temperature range from a low-temperature region to a high-temperature region, and has high thermal storability. When the toner is measured with a capillary rheometer, t(1) is 60 seconds or more and t(5) is 30 seconds or less and the toner satisfies the following formulae (1) and (2) 65.0[° C.]?T(5)?90.0[° C.]??(1) 4.5?t(1)/t(5)?10.0??(2).
    Type: Application
    Filed: May 30, 2013
    Publication date: December 5, 2013
    Inventors: Shuntaro Watanabe, Kenji Aoki, Toshifumi Mori, Atsushi Tani, Takaaki Kaya, Yoshihiro Nakagawa, Tetsuya Kinumatsu, Takashige Kasuya
  • Publication number: 20130323638
    Abstract: An object of the present invention is to suppress the increase of coarse particles due to the fusion of powder particles and reduce a ratio of particles that have been excessively spheroidized, when the powder particles are heat-treated.
    Type: Application
    Filed: January 31, 2012
    Publication date: December 5, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Hironori Minagawa, Yuichi Mizo, Takeshi Ohtsu, Junichi Hagiwara, Yasushi Tamura
  • Patent number: 8592127
    Abstract: A method for producing a toner, comprising the step of feeding raw materials containing a resin binder and a colorant to an open-roller type kneader, and melt-kneading the raw materials, wherein the resin binder contains a crystalline polyester and an amorphous polyester, and wherein the crystalline polyester and the amorphous polyester fed to the open-roller type kneader are in a weight ratio, i.e. crystalline polyester/amorphous polyester, of from 5/95 to 30/70, and have a ratio of average particle sizes of crystalline polyester/amorphous polyester of from 1.5 to 4.0. The toner obtained according to the present invention is used in, for example, the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.
    Type: Grant
    Filed: July 28, 2009
    Date of Patent: November 26, 2013
    Assignee: Kao Corporation
    Inventor: Akihiro Eida
  • Patent number: 8574807
    Abstract: A method of manufacturing toner is provided, including discharging a toner constituents liquid from multiple nozzles to form liquid droplets and solidifying the liquid droplets into toner particles. The multiple nozzles satisfy the following formula: 2.5?p/d?7.5 wherein d represents an outlet diameter of each nozzle and p represents an interval between two nozzles.
    Type: Grant
    Filed: October 3, 2011
    Date of Patent: November 5, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Yoshihiro Norikane, Masaru Ohgaki, Andrew Mwaniki Mulwa, Yuko Sekiguchi
  • Patent number: 8568953
    Abstract: To provide an apparatus for producing a toner, including: a droplet forming unit configured to periodically discharge a toner composition liquid, which includes at least a resin and a colorant, from a plurality of nozzles so as to form droplets; a gas flow forming unit configured to form a gas flow which passes through a narrowed portion that corresponds to a nozzle formation area and that is placed on a downstream side of the nozzles with respect to a droplet discharge direction, and which advances in the droplet discharge direction; and a particle forming unit configured to form toner particles by solidifying the droplets of the toner composition liquid passed through the narrowed portion and then discharged, wherein the opening area of an opening which forms the narrowed portion decreases from an inlet side of the narrowed portion toward an outlet side of the narrowed portion.
    Type: Grant
    Filed: August 19, 2010
    Date of Patent: October 29, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Kenta Kenjoh, Tetsuya Tanaka
  • Patent number: 8563211
    Abstract: A process for making a latex emulsion suitable for use in a toner composition includes co-emulsifying a bio-based resin with an insoluble component, such as a pigment or wax, whereby the resin encapsulates the insoluble component. The resulting latex, including the insoluble component encapsulated in the resin, may then be utilized to form a toner. The insoluble component may thus be included in toner particles, which might otherwise be difficult to achieve, using emulsion aggregation processes.
    Type: Grant
    Filed: April 8, 2011
    Date of Patent: October 22, 2013
    Assignee: Xerox Corporation
    Inventors: Ke Zhou, Sonja Hadzidedic, Guerino G. Sacripante, Kimberly D. Nosella
  • Patent number: 8563206
    Abstract: A negatively chargeable developer includes: negatively chargeable toner mother particles including at least binding resin and colorant; and an external additive that is externally added to a surface of the toner mother particles, wherein the external additive includes polymethyl methacrylate that is within a range from approximately 0.4 parts by weight to approximately 0.8 parts by weight inclusive per 100 parts by weight of the toner mother particles and that has positive chargeability.
    Type: Grant
    Filed: August 30, 2011
    Date of Patent: October 22, 2013
    Assignee: Oki Data Corporation
    Inventor: Yuki Matsuura
  • Patent number: 8557497
    Abstract: A method of manufacturing toner including preparing a first liquid by dissolving or dispersing toner components including one or both of a binder resin and a precursor thereof in an organic solvent; preparing a second liquid by dispersing the first liquid in a first aqueous medium including a dispersant; producing primary particles by removing the organic solvent from the second liquid; washing the primary particles; preparing a third liquid by dispersing the washed primary particles in a second aqueous medium and heating the second aqueous medium while or after dispersing the washed primary particles therein; and producing toner particles by adding a charge controlling agent to the third liquid. This method satisfies the following inequation: 0.60?Sb/Sa?1.00 wherein Sa represents a BET specific surface area of the primary particles included in the third liquid and Sb represents that of the toner particles stored for 2 weeks at 40° C., 70% RH.
    Type: Grant
    Filed: December 6, 2010
    Date of Patent: October 15, 2013
    Assignee: Ricoh Company, Limited
    Inventors: Junichi Watanabe, Kenichi Uehara, Junya Koeda, Daisuke Misawa, Keisuke Tada, Miyuki Hirata
  • Publication number: 20130260306
    Abstract: Provided is a production process for a colorant which contains a silicon phthalocyanine compound making it possible to reach a targeted particle diameter even by a conventional dispersing method and which is excellent in performances such as a color reproducibility, a light fastness, an electrostatic property, a transparency and the like, and a colorant composition, a toner, an ink for ink jet recording and a color filter which are excellent in the above performances. The above production process is a production process for a colorant containing a silicon phthalocyanine compound and a copper phthalocyanine compound and is characterized by having a preparing step of reacting raw materials of a silicon compound and phthalocyanine under the presence of a copper salt or the copper phthalocyanine compound described above to prepare the silicon phthalocyanine compound described above.
    Type: Application
    Filed: March 15, 2013
    Publication date: October 3, 2013
    Applicant: Konica Minolta Business Technologies, Inc.
    Inventors: Keiko ISHIDAI, Kimihiko OOKUBO
  • Patent number: 8546053
    Abstract: The present invention provides a method for producing a toner, the method including: preparing a wax dispersion liquid by cooling a wax solution, in which a wax is heated and dissolved or dispersed in an organic solvent, in a container so that a standard deviation ? of a temperature distribution between a center portion of the container and an inner wall of the container is 0.5 or less and the cooling rate is 2.0° C./min or more, to precipitate wax particles in the wax solution; forming toner base precursor particles by adding an aqueous phase containing resin fine particles into an oil phase containing at least the wax dispersion liquid, a colorant and a binder resin and mixing the oil phase and the aqueous phase with each other; and preparing toner base particles by removing the solvent from the toner base precursor particles.
    Type: Grant
    Filed: September 8, 2009
    Date of Patent: October 1, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Teruki Kusahara, Junichi Awamura, Tomomi Suzuki, Toshihiko Karato
  • Patent number: 8546057
    Abstract: A black toner composition comprising toner particles prepared by a chemical process of manufacture comprising carbon black pigment, a first addition polymer comprising carboxylic acid groups along the polymer backbone, and a thermoplastic second polymer binder distinct from the first polymer, wherein the first polymer has an Acid Value of from 30 to 220 and is present at a weight ratio of greater than 1:2 relative to the amount of carbon, and at a relatively lower weight percent than the second polymer.
    Type: Grant
    Filed: January 31, 2011
    Date of Patent: October 1, 2013
    Assignee: Eastman Kodak Company
    Inventors: Dinesh Tyagi, Louise Granica
  • Patent number: 8545133
    Abstract: A production apparatus and a production method of toner particles are provided which efficiently and stably reduce the water content of the wet toner particle cake obtained by separating and washing toner particles from toner particle dispersion in a production apparatus of toner particles granulated in a wet process. A wet toner particle cake 1 formed on a belt filter is aerated and dehydrated with air, and at the same time, sealing units 6 provided on the upstream and downstream sides of the aeration unit 3 can be operated to efficiently seal aeration air.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: October 1, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hidekazu Fumita, Yoshinori Tsuji, Takeshi Tsujino, Minoru Omura, Satoshi Iki, Naoto Aiko
  • Publication number: 20130252160
    Abstract: A toner for forming an electrophotographic image is provided, wherein the toner includes at least four types of binder resins, wherein the binder resins includes at least: a crystalline polyester resin (A); a non-crystalline resin (B); a non-crystalline resin (C); and a composite resin (D) which includes a condensation polymerization resin unit and an addition polymerization resin unit, wherein the non-crystalline resin (B) includes a chloroform insoluble matter, wherein the non-crystalline resin (C) has a softening temperature (T½) lower than that of the non-crystalline resin (B) by 25° C. or more, and wherein the toner has a main peak between 1,000 to 10,000 in a molecular weight distribution obtained by GPC from a tetrahydrofuran soluble matter, and the toner has a half-value width of the molecular weight distribution of 15,000 or less.
    Type: Application
    Filed: September 14, 2012
    Publication date: September 26, 2013
    Inventors: Masashi NAGAYAMA, Mitsuo Aoki, Hisashi Nakajima, Saori Yamada, Mariko Takii
  • Publication number: 20130244168
    Abstract: A toner including a resin particle (C) is provided. The resin particle (C) includes a resin particle (B) and; a resin particle (A) or covering layer (P) that is adhered to a surface of the resin particle (B). The resin particle (B) includes a resin (b) having a polyhydroxycarboxylic acid skeleton. The resin particle (A) or covering layer (P) includes a resin (a). The resin (a) is a polyester resin having a polybasic acid unit and a polyol unit and has a weight average molecular weight within a range from 9,500 to 100,000.
    Type: Application
    Filed: February 6, 2013
    Publication date: September 19, 2013
    Inventors: Daiki YAMASHITA, Shinya Nakayama, Atsushi Yamamoto, Yukiko Nakajima, Akiyoshi Sabu, Yoshihiro Moriya, Hideyuki Santo
  • Patent number: 8535865
    Abstract: An emissive toner composition for producing an emissive image component of an image indicia on a substrate. The emissive toner composition includes a photoluminescent agent, a charge control agent, and one or more additives, each selected and present in an amount such that when the toner composition is printed to produce an image component on a substrate, the toner composition has stable spectral characteristics. In one embodiment, the emission spectra of the image component printed on the substrate, for irradiation with an excitation energy includes only dominant emission peaks corresponding to one or more emission peaks of the photoluminescent agent. In another embodiment, the image component has a photoluminescent toner stability factor of about greater than or equal to 25.
    Type: Grant
    Filed: August 20, 2008
    Date of Patent: September 17, 2013
    Assignee: Angstrom Technologies, Inc.
    Inventors: William Coyle, Anthony Stramondo
  • Patent number: 8524437
    Abstract: A particle producing method is provided including bringing a material into contact with a compressible fluid to prepare a melt of the material, and discharging the melt from a vibrated through hole to form particles of the melt. A particle producing apparatus is also provided including a discharger to discharge the melt. The discharger includes a storage to store the melt, at least one through hole disposed on the storage, and a vibrator to vibrate the through hole. The particle producing apparatus further includes a particle forming member defining a space within which the discharged melt is formed into particles and a pressure controller controlling a pressure difference between the space and an inside of the storage so that the discharged melt is formed into a columnar melt and the columnar melt is constricted and separated into particles.
    Type: Grant
    Filed: February 2, 2012
    Date of Patent: September 3, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Yoshitaka Yamauchi, Chiaki Tanaka, Taichi Nemoto, Keiko Osaka, Shinji Ohtani
  • Patent number: 8518622
    Abstract: A toner containing a binder resin, a colorant, and a releasing agent, wherein the colorant contains a mixed crystal of a C. I. PIGMENT YELLOW 185 and a C. I. PIGMENT YELLOW 139, and wherein a mass ratio of the C. I. PIGMENT YELLOW 185 to the C. I. PIGMENT YELLOW 139 (mass of the C. I. PIGMENT YELLOW 185/mass of the C. I. PIGMENT YELLOW 139) in the toner is 95/5 to 50/50.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: August 27, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Satoshi Ogawa, Daisuke Inoue, Daisuke Ito, Osamu Uchinokura, Junichi Awamura, Teruki Kusahara, Satoshi Kojima, Mamoru Hozumi, Shoko Sato
  • Patent number: 8518627
    Abstract: The present disclosure provides processes for producing toners. In embodiments, silica is added as a chelating agent during the toner production process contributing to enhanced triboelectric charging properties of the toner particles.
    Type: Grant
    Filed: January 24, 2011
    Date of Patent: August 27, 2013
    Assignee: Xerox Corporation
    Inventors: Allan K. Chen, Santiago Faucher, Shigang S. Qiu, Karen A. Moffat, Richard P. N. Veregin
  • Patent number: 8512927
    Abstract: An electrostatic image developing carrier including at least a core material and a coating resin layer which coats the surface of the core material, the resin layer comprising a thermoplastic resin having an alicyclic group, a thermal reduction in accordance with the TGA method being in the range of 0.5 weight % to 5 weight % of the whole of the carrier in the range of 100° C. to 400° C., and further an endothermic quantity of the whole of the carrier in accordance with the DTA method is in the range of 7 mJ/g to 40 mJ/g in the range of 100° C. to 400° C.
    Type: Grant
    Filed: April 4, 2007
    Date of Patent: August 20, 2013
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Akihiro Iizuka, Fusako Kiyono, Tsuyoshi Murakami
  • Patent number: 8501379
    Abstract: A toner containing base particles produced by dissolving and/or dispersing a toner material in an organic solvent so as to prepare a toner material solution, and emulsifying and/or dispersing the toner material solution in an aqueous medium, wherein the toner material contains a binder resin and a releasing agent, the binder resin contains a polyester resin, and the releasing agent is a hydrocarbon wax which is modified with a carboxylic acid or carboxylic anhydride.
    Type: Grant
    Filed: June 9, 2008
    Date of Patent: August 6, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Tsuyoshi Sugimoto, Hiroshi Yamashita
  • Publication number: 20130196266
    Abstract: A toner produced by dissolving or dispersing toner components comprising a binder resin, a colorant, and a charge controlling agent in an organic solvent to prepare a toner components liquid, forming liquid droplets of the toner components liquid in a gas phase, and solidifying the liquid droplets into toner particles of the toner. The charge controlling agent includes a polycondensation reaction product of a phenol with an aldehyde.
    Type: Application
    Filed: March 13, 2013
    Publication date: August 1, 2013
    Inventors: Yohichiroh Watanabe, Kazumi Suzuki, Takahiro Honda, Shinji Ohtani, Yoshihiro Norikane
  • Publication number: 20130196260
    Abstract: A toner including: a binder resin containing a non-crystalline resin and a crystalline resin; a colorant; and, a releasing agent, wherein the releasing agent has a melting point of 55° C. to 80° C., and wherein the toner satisfies the following Expressions 1 and 2: (Expression 1): 20,000 Pa·s?G1?50,000 Pa·s; and (Expression 2): (G4/G2)/(G3/G1) 1.00, where G1 is a storage modulus, G2 is a loss modulus, G3 is a storage modulus and G4 is a loss modulus, and the storage modulus G1 and the loss modulus G2 are measured at 80° C. when the toner is heated from 70° C. to 150° C. and the storage modulus G3 and the loss modulus G4 are measured at 80° C. when the toner heated to 150° C. is cooled to 70° C.
    Type: Application
    Filed: December 28, 2012
    Publication date: August 1, 2013
    Inventors: Ryuuta YOSHIDA, Takahiro HONDA, Junichi AWAMURA, Osamu UCHINOKURA, Masaki WATANABE, Daisuke INOUE, Tomoki MURAYAMA, Mamoru HOZUMI
  • Patent number: 8492063
    Abstract: A method of manufacturing a toner including forming a wax liquid dispersion in which a wax is dispersed in an organic solvent (A1), mixing an organic layer including the wax liquid dispersion, a binder resin and an organic solvent (A) to form an oil phase and dispersing and emulsifying the oil phase in an aqueous medium to obtain an emulsified liquid dispersion, wherein the aspect ratio average of the wax in the wax liquid dispersion is from 0.3 to 0.7 and the toner includes toner particles satisfying the following relationship (1) in an amount of 20% by number or smaller based on all toner particles: 0.5<D2/D1, relationship (1), where D1 represents the major diameter (D1) of the toner and D2 represents the major diameter of the wax.
    Type: Grant
    Filed: November 28, 2008
    Date of Patent: July 23, 2013
    Assignee: Ricoh Company, Limited
    Inventors: Junichi Awamura, Akinori Saitoh, Masahide Yamada, Osamu Uchinokura, Tomomi Suzuki
  • Publication number: 20130183615
    Abstract: The present disclosure provides toners having a tunable gloss level, electrophotographic apparatus for suing such toners as well as processes for making such toners.
    Type: Application
    Filed: March 4, 2013
    Publication date: July 18, 2013
    Applicant: XEROX CORPORATION
    Inventor: Xerox Corporation
  • Patent number: 8486603
    Abstract: There is provided a method for producing a toner block. The method includes: preparing a toner suspension in which toner particles are dispersed in water so that the toner suspension is a dilatant fluid; preparing an aggregate of the toner particles in a form of cake by absorbing water contained in the toner suspension by a water absorptive material; and drying the aggregate.
    Type: Grant
    Filed: August 30, 2011
    Date of Patent: July 16, 2013
    Assignee: Brother Kogyo Kabushiki Kaisha
    Inventor: Jun Ikami
  • Publication number: 20130171557
    Abstract: To provide a toner containing: a binder resin containing a non-crystalline polyester resin and a crystalline polyester resin; a colorant; and wax, wherein the toner satisfies the following formula 1, and has loss tangent of 1 or smaller at 80° C. or higher, B?A<20 Formula 1 where A represents a melting point of the crystalline polyester resin and B represents a temperature at which the toner has storage modulus G? of 20,000 Pa.
    Type: Application
    Filed: September 27, 2011
    Publication date: July 4, 2013
    Inventors: Naohiro Watanabe, Tsuyoshi Sugimoto, Mamoru Hozumi, Osamu Uchinokura
  • Patent number: 8475992
    Abstract: A process for preparing a toner comprising a binder resin and a colorant, wherein the binder resin comprises a polyester resin having an acid value (AV) greater than 5 mg KOH/g, the process comprising: providing an aqueous dispersion of self-dispersed polyester resin particles and associating the polyester resin particles by means of a change in the pH of the dispersion.
    Type: Grant
    Filed: June 20, 2008
    Date of Patent: July 2, 2013
    Assignee: Fujifilm Imaging Colorants Limited
    Inventors: Daniel Patrick Morris, John Dylan Morgan, Martin Russell Edwards, Miguel Angel Rodriguez-Vazquez, Mohammed Nawaz, Zoonia Mehmood
  • Publication number: 20130164673
    Abstract: A method of manufacturing electrophotographic toner containing particles obtained by fusing aggregate particles obtained by aggregating an aqueous dispersion of a polyester resin for toner includes: mixing together at least a polyester resin, an organic solvent, and a neutralizer to obtain a mixture (Step 1); mixing the mixture obtained in the step 1 with at least water to obtain a resin dispersion (Step 2); removing an organic solvent from the resin dispersion obtained in the step 2 to obtain an aqueous dispersion of a polyester resin (Step 3); and mixing the aqueous dispersion obtained in the step 3 with a surfactant optionally (Step 4), in which the aqueous dispersion of the polyester resin for toner is obtained through the steps 1-4, the surfactant is added in a content of 70-100 weight % based on the total amount of the surfactant added in the steps 2 and/or 4.
    Type: Application
    Filed: December 27, 2012
    Publication date: June 27, 2013
    Applicant: Kao Corporation
    Inventor: Kao Corporation
  • Publication number: 20130164669
    Abstract: A toner including a binder resin containing an ester bond, and a releasing agent, wherein the releasing agent includes first C30-C50 alkyl monoester compound and second C30-C50 alkyl monoester compound, wherein the number of carbon atoms of the first C30-C50 alkyl monoester compound is different from that of the second C30-C50 alkyl monoester compound, wherein the amount of the first C30-C50 alkyl monoester compound is largest and the amount of the second C30-C50 alkyl monoester compound is second largest or same as the amount of the first C3OC50 alkyl monoester compound, wherein the amount of the first C30-C50 alkyl monoester compound is 30% by mass or more but less than 50% by mass to the releasing agent, and wherein the amount of the second C30-C50 alkyl monoester compound is 10% by mass or more but less than 50% by mass to the releasing agent.
    Type: Application
    Filed: August 18, 2011
    Publication date: June 27, 2013
    Inventors: Hiroshi Yamashita, Yuichi Shirasu, Tomoki Murayama, Masaki Watanabe
  • Publication number: 20130149643
    Abstract: The present disclosure describes a polyester that contains plural pendant adjacent carboxylic acid or acid salt side groups for use in making a toner for use in imaging devices.
    Type: Application
    Filed: December 12, 2011
    Publication date: June 13, 2013
    Inventors: Karen A. Moffat, Dragan Nikolic, Valerie M. Farrugia, Jordan Wosnick, Andriy Kovalenko, Alexander Kobryn, Sergey Gusarov
  • Publication number: 20130130165
    Abstract: Provided is a toner comprising toner particles, wherein each of the toner particles has a core-shell structure composed of a core and a shell phase formed on the core, the shell phase contains a resin (B), and the core contains a binder resin (A), a colorant and a wax, wherein the toner particles contain the resin (B) in a specific amount with respect to the core, and wherein the solubility parameter (SP value) of the binder resin (A) is denoted by SP(A), the SP value of the resin (B) is denoted by SP(B), the SP value of a repeating unit with the smallest SP value from among repeating units constituting the resin (B) is denoted by SP(C), and the SP value of the wax is denoted by SP(W), each of the SP(A), SP(B), SP(C) and SP(W) satisfy specific relationships.
    Type: Application
    Filed: January 14, 2013
    Publication date: May 23, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventor: Canon Kabushiki Kaisha
  • Publication number: 20130130168
    Abstract: Provided is a toner containing toner particles, each of which includes a binder resin containing a polyester as a main component, a colorant, and a wax, in which the binder resin includes a block polymer in which a segment capable of forming a crystalline structure and a segment incapable of forming a crystalline structure are bonded, the toner has a maximum endothermic peak from the binder resin, as determined by differential scanning calorimetry measurement, with a peak temperature in a specific range and with an endothermic quantity in a specific range, and the wax is an ester wax having a functionality of 3 or more.
    Type: Application
    Filed: January 14, 2013
    Publication date: May 23, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventor: Canon Kabushiki Kaisha
  • Publication number: 20130130166
    Abstract: A binder resin for a toner containing a vinyl resin (A), a non-crystalline polyester resin (SN) and a saturated crystalline polyester resin (SC), in which the content of the vinyl resin (A) is equal to or more than 65 mass % and equal to or less than 95 mass %, based on the total content of 100 mass % of (A), (SN) and (SC), (A) is composed of a carboxyl group-containing vinyl resin (C), a glycidyl group-containing vinyl resin (E) and a reaction product of the vinyl resins, the ester group concentration of (SC) is equal to or more than 10.0 mmol/g and equal to or less than 13.5 mmol/g, (SN) is dispersed in an island form in (A) and (SC) is contained in the island phase of (SN), and the metal component (M) containing at least one kind selected from the group consisting of Zn, Ca, Mg, Al and Ba (excluding metal oxide) is contained at least in (SC).
    Type: Application
    Filed: July 29, 2011
    Publication date: May 23, 2013
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Hiroshi Matsuoka, Hiroyuki Takei, Linwood Blanton Muire, III
  • Patent number: 8445171
    Abstract: A method of preparing a toner, including dripping a toner constituent liquid comprising an organic solvent; and toner constituents comprising a resin and a colorant, which are dissolved or dispersed in the organic solvent through a nozzle to form a droplet; and removing the organic solvent from the droplet, wherein the droplet is dried while contacted with a first de-solvent gas comprising steam in a pre-heated period and at least a part of a constant-rate drying period, or the droplet is dried at least in a pre-heated period and a constant-rate drying period, which include two stages including a first stage and a second stage, wherein the droplet is contacted with the first de-solvent gas including steam in the first stage and a second de-solvent gas having a dew point not greater than ?10° C. under ordinary pressure in the second stage.
    Type: Grant
    Filed: August 7, 2008
    Date of Patent: May 21, 2013
    Assignee: Ricoh Company, Limited
    Inventors: Kazumi Suzuki, Yohichiroh Watanabe
  • Patent number: 8445172
    Abstract: A method for producing a toner, containing: ultrasonically vibrating a liquid toner composition in which a toner material containing at least a binder resin and a colorant is dissolved or dispersed in a solvent; introducing the liquid toner composition to a liquid chamber, and ejecting the liquid toner composition as droplets from an ejecting plate having a plurality of holes and disposed on one surface of the liquid chamber; and drying and solidifying the droplets so as to produce a toner, wherein the ultrasonically vibrating is performed before the introducing the liquid toner composition to the liquid chamber.
    Type: Grant
    Filed: March 5, 2010
    Date of Patent: May 21, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Yasutada Shitara, Yoshihiro Norikane, Yohichiroh Watanabe, Andrew Mwaniki Mulwa
  • Publication number: 20130122418
    Abstract: A process including contacting an alkyl benzene sulfonate surfactant having an ammonium salt counter ion with a component to be emulsified or dispersed, wherein the alkyl benzene sulfonate surfactant is substantially free of sodium salt counter ions such that the sodium content of the alkyl benzene sulfonate surfactant is less than about 5,000 parts per million, and water to form a mixture; using the alkyl benzene sulfonate surfactant to emulsify the component and form an emulsion; or using the alkyl benzene sulfonate surfactant to disperse the component and form a dispersion.
    Type: Application
    Filed: November 10, 2011
    Publication date: May 16, 2013
    Applicant: Xerox Corporation
    Inventors: Kimberly D. Nosella, Shigang S. Qiu, Santiago Faucher, Allan Chen
  • Publication number: 20130122417
    Abstract: A toner is provided including toner particles A having a circularity of greater than 0.93 and not greater than 1.00 and toner particles B having a circularity of from 0.85 to 0.93, wherein the following relationships are satisfied: 70?RA?95, 5?RB?30, 0.014?SD?0.025, and 0.940?ED?0.950, wherein RA (% by number) represents a ratio of a number of the toner particles A to a total number of toner particles included in the toner, RB (% by number) represents a ratio of a number of the toner particles B to the total number of toner particles included in the toner, SD represents a standard deviation of circularity of the toner particles A, and ED represents an average envelope degree of the toner particles B.
    Type: Application
    Filed: January 9, 2013
    Publication date: May 16, 2013
    Applicants: XEIKON, RICOH COMPANY, LTD. MANUFACTURING N.V.
    Inventors: RICOH COMPANY, LTD. MANUFACTURING N.V., XEIKON
  • Patent number: 8440382
    Abstract: A method of stably producing a toner is provided. This method provides a long-term stabilization of material dispersion in a colorant-dispersed solution and inhibits segregation of the material and provides a more microfine and more uniform dispersion of the colorant in the toner, and moreover produces a toner that has a sharp toner particle diameter distribution. This method of producing toner has at least a colorant dispersion step of obtaining a colorant-dispersed solution by dispersing a pigment-containing colorant in a liquid mixture that contains the colorant and a dissolved resin solution or a polymerizable monomer, wherein the liquid mixture contains a nonionic surfactant and the nonionic surfactant has at least an oxyalkylene group and has a hydrophile-lipophile balance value (HLB value) of 9.0 or more and 17.0 or less.
    Type: Grant
    Filed: June 3, 2011
    Date of Patent: May 14, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Naoya Isono, Katsuyuki Nonaka, Yasuhiro Hashimoto, Akira Sugiyama, Yuhei Terui
  • Patent number: 8435716
    Abstract: A method for producing a toner, including: dispersing toner particles containing at least a binder resin in a first aqueous medium so as to produce an aqueous dispersion; and subjecting the aqueous dispersion to heat treatment, wherein the electric conductivity of the aqueous dispersion after the heat treatment is higher than the electric conductivity of the aqueous dispersion before the heat treatment by 50 ?S/cm or less.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: May 7, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Masaki Watanabe, Osamu Uchinokura, Tsuneyasu Nagatomo, Takahiro Honda, Ryuta Chiba
  • Patent number: 8435714
    Abstract: A process for making toner particles is provided. In embodiments, a suitable process includes melt mixing a resin in the absence of an organic solvent, optionally adding a surfactant to the resin, adding to the resin at least one colorant and other optional toner additives, adding to the resin a basic agent and water to form a mixture, and subjecting the mixture to acoustic mixing at a suitable frequency to form to form an emulsion. A phase inversion may then be performed to create a phase inversed emulsion including a disperse phase comprising molten resin and the optional ingredients of the toner composition, at which time toner-sized droplets may be solidified from the disperse phase into toner particles, which can be recovered for use.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: May 7, 2013
    Assignee: Xerox Corporation
    Inventors: Zhen Lai, Chieh-Min Cheng, Shigang Qiu, Emily L. Moore, Tie Hwee Ng
  • Patent number: 8431322
    Abstract: A method of manufacturing a toner is provided which is excellent in low temperature fixation property, whose fixable temperature width is large, as well as excellent in durability while giving consideration to the global environment conservation. The method of manufacturing a toner includes a step of producing a polyester resin by a reaction of dicarboxylic acid and diol, and a step of producing a toner base particle having the polyester resin and a colorant. The dicarboxylic acid is a biomass monomer having carboxyl groups introduced into ends of one, or two or more monocarboxylic acids selected from pimaric acid, isopimaric acid, and sandaracopimaric acid.
    Type: Grant
    Filed: January 6, 2011
    Date of Patent: April 30, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Nobuhiro Maezawa
  • Patent number: 8431316
    Abstract: A toner manufacturing method is provided. The toner manufacturing method includes a step of adhering fine resin particles whose volume average particle size is 5% or more and 17% or less of a volume average particle size of toner base particles, to surfaces of the toner base particles; and a step of plasticizing the toner base particles and the fine resin particles by adding mechanical impact thereto while spraying lower alcohol, and fusing the fine resin particles to the surfaces of the toner base particles to form a plurality of projections of the fine resin particles, on the surfaces of the toner base particles. Surface coverage of the surfaces of the toner base particles with the projections is 10% or more and 50% or less.
    Type: Grant
    Filed: November 8, 2010
    Date of Patent: April 30, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Yoshiaki Akazawa, Yoshitaka Kawase, Yoritaka Tsubaki, Yoshinori Mutoh, Keiichi Kikawa, Takashi Hara
  • Patent number: 8431319
    Abstract: A washing process using one or more ionic liquids (ILs) as a washing aid agent for toners, including toners produced using such ILs, such as, low melt toners, is provided. ILs are environmentally sound, green solvents that act to swell toner particle surfaces so that surface absorbed and adsorbed pollutants, such as, surfactants and other manufacturing reactants, can be effectively removed. The resulting toners have good charging, charge maintenance and RH sensitivity.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: April 30, 2013
    Assignee: Xerox Corporation
    Inventors: Zhen Lai, Chieh-Min Cheng, Zhaoyang Ou
  • Patent number: 8431315
    Abstract: There are provided a capsule toner, a two-component developer, and a capsule toner manufacturing method. The capsule toner in which a resin coating layer made of fine release-agent particles and fine resin particles is made on the surfaces of toner base particles, and thus excellent offset resistance without impairing blocking resistance can be obtained. The capsule toner includes toner base particles containing a binder resin and a colorant, and a resin coating layer made of fine release-agent particles and fine resin particles, for covering the surfaces of the toner base particles. The fine release-agent particles are dispersed in the resin coating layer.
    Type: Grant
    Filed: September 9, 2010
    Date of Patent: April 30, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Yoshinori Mutoh, Yoshiaki Akazawa, Yoshitaka Kawase, Yoritaka Tsubaki, Keiichi Kikawa, Takashi Hara