Patents Represented by Law Firm Sprung, Felfe, Horn, Lynch & Kramer
  • Patent number: 4319024
    Abstract: A process for the preparation of a .beta.-alkoxyacrylonitrile of the formulaR'O--CH.dbd.CR--CN (C)where R is hydrogen or an alkyl moiety, among others, by contacting a compound of the formula(1/.alpha.Me) O--CH.dbd.CR--CN (A)where Me is an alkali metal or alkaline earth metal and .alpha. is 1 or 2 respectively, an elevated temperature with a halogen compound of the formulaR'Hal (B)where R' is among others a straight or branched alkyl or alkenyl moiety and Hal represents chlorine, bromine, or iodine. Also disclosed is a process for preparing a 3-amino-acrylonitrile of the formula ##STR1## where R.sup.5 and R.sup.6 represent, among others, hydrogen, alkyl or alkenyl by contacting a 3-alkoxyacrylonitrile or a metal salt of 3-hydroxyacrylonitrile with ammonia and/or amine. Also disclosed is a process for the preparation of such 3-aminoacrylonitrile by contacting a 3-alkoxyacrylonitrile of the formula ##STR2## where R' has the meaning given above and R.sup.
    Type: Grant
    Filed: March 24, 1980
    Date of Patent: March 9, 1982
    Assignee: Dynamit Nobel Aktiengesellschaft
    Inventors: Hermann Peeters, Uwe Prange, Wilhelm Vogt
  • Patent number: 4318902
    Abstract: A process for the preparation of an immunoglobulin solution containing IgM in concentrated form and suited for intravenous administration, comprising treating an IgM-containing protein fraction obtained by conventional fractionation from blood plasma or serum with .beta.-propiolactone in an amount such that the ratio of .beta.-propiolactone to a 5% solution of the IgM-containing proteins is from about 0.05 to 0.15 ml per 100 ml. Advantageously, prior to the treatment with .beta.-propiolactone the IgM-containing protein fraction is freed of lipids by treatment with colloidal silica gel and with crosslinked dextrans or diethylaminoethyl cellulose. The starting material used is a Cohn fraction III of human blood plasma which has been dissolved in physiological saline solution to a concentration of about 5% protein, the treatment with .beta.-propiolactone is carried out at about 20.degree. to 37.degree. C.
    Type: Grant
    Filed: January 7, 1980
    Date of Patent: March 9, 1982
    Assignee: Biotest-Serum-Institut GmbH
    Inventor: Wolfgang Stephan
  • Patent number: 4318773
    Abstract: Liquid solutions are evaporated to their setting points and the set material so formed is crushed in a screw machine. The phase conversion from the still viscous state to the flowable crushed solid state is carried out in a single closed housing zone of the screw machine and comprises simultaneous evaporation, setting, crushing and further concentration.
    Type: Grant
    Filed: May 2, 1978
    Date of Patent: March 9, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Ullrich, Manfred Hederich, Karl-Friedrich Jerchel
  • Patent number: 4318716
    Abstract: An improvement in a process of regenerating a hydrocarbon laden water miscible high boiling organic solvent obtained by scrubbing a hydrocarbon-containing gas with said water miscible high boiling organic solvent at normal temperature and super atmospheric pressure, wherein the laden solvent is regenerated by flashing, heating and/or stripping, cooled and recycled to the scrubbing step, the improvement comprising:A. adding liquid hydrocarbons to at least a part of said regenerated solvent and thereafter extracting the resultant mixture in the presence of water whereby to obtain a hydrocarbon rich phase and an aqueous phase containing said solvent;B. separating said aqueous phase from said hydrocarbon rich phase and recycling said aqueous phase to the regeneration step; andC. withdrawing said hydrocarbon rich phase.
    Type: Grant
    Filed: July 21, 1980
    Date of Patent: March 9, 1982
    Assignee: Metallgesellschaft, Aktiengesellschaft
    Inventors: Alexander Doerges, Manfred Kriebel, Johann Schlauer
  • Patent number: 4319015
    Abstract: New Synthetic resins useful as inert material for separating layers in ion exchanger mixed bed filters. The new synthetic resins are copolymers of(a) substituted styrenes and/or methacrylates,(b) methacrylates of polyhydric alcohols and/or aromatic polyvinyl compounds and(c) unsaturated hydrocarbons which have at least two allyl groupings in the molecule, and/or polyvinyl ethers of polyhydric alcohols, and optionally(d) styrene.
    Type: Grant
    Filed: October 4, 1979
    Date of Patent: March 9, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Struver, Harold Heller, Peter M. Lange
  • Patent number: 4318798
    Abstract: A process of cooling hot granular solids which are at temperatures from about 400.degree. to 1300.degree. C., which comprises maintaining solids in an agitated or trickling state in a cooling zone, causing air to rise through the cooling zone in direct contact with the solids, and utilizing at least part of the sensible heat of the solids so dissipated.
    Type: Grant
    Filed: August 25, 1980
    Date of Patent: March 9, 1982
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Johannes-Josef Albrecht, Roland Rammler, Martin Hirsch
  • Patent number: 4317877
    Abstract: Malignant and pre-malignant cells in humans are detected by contacting an antibody to oncofoetal deoxythymidine kinase with human cells and detecting the presence of cells containing oncofoetal deoxythymidine kinase antigen bound to the antibody.
    Type: Grant
    Filed: June 5, 1980
    Date of Patent: March 2, 1982
    Assignee: Sloan Kettering Institute
    Inventors: M. Earl Balis, Paul J. Higgins, Josephine S. Salser
  • Patent number: 4317834
    Abstract: Fluorine-substituted spirocarboxylic acid benzyl esters of the formula ##STR1## in which R.sup.1 represents hydrogen, cyano or alkyl, alkenyl or alkynyl, with in each case up to 4 carbon atoms,R.sup.2 represents a phenyl radical which is substituted by halogen and/or by optionally halogen-substituted phenoxy, with the proviso that the radical R.sup.2 contains in total at least one fluorine substituent, andR.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represent hydrogen, halogen or alkyl, orR.sup.3 and R.sup.4, taken together, and/or R.sup.5 and R.sup.6, taken together, represent alkanediyl (alkylene) or a fused-on benzo radical,and the C atoms of the 5-member spirocyclic ring are linked to one another either by double bonds or by single bonds, which possess arthropodicidal properties.
    Type: Grant
    Filed: November 3, 1980
    Date of Patent: March 2, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rainer Fuchs, Klaus Naumann, Ingeborg Hammann, Bernhard Homeyer, Wolfgang Behrenz, Wilhelm Stendel
  • Patent number: 4317561
    Abstract: A holder for an oxygen lance characterized by at least one actuating device comprising an operating lever which is connected to a shut off valve.
    Type: Grant
    Filed: June 19, 1980
    Date of Patent: March 2, 1982
    Inventor: Manfred Schulz
  • Patent number: 4317925
    Abstract: A process for the preparation of di-n-propylacetic acid which comprises the steps ofA. converting n-valeraldehyde-diallyl acetal into allyl-1-pentenyl ether by cleaving one mol of allyl alcohol per one mol of n-valeraldehye-diallyl acetal;B. rearranging the allyl-1-pentenyl ether thermally into 2-propyl-pent-4-en-1-al,C. partially hydrogenating the 2-propyl-pent-en-1-al catalytically to form 2-propyl valeraldehyde, andD. oxidizing the 2-propyl valeraldehyde to form dipropyl-acetic acid.
    Type: Grant
    Filed: July 25, 1979
    Date of Patent: March 2, 1982
    Assignee: Ruhrchemie Aktiengesellschaft
    Inventors: Jurgen Weber, Wolfgang Bernhagen, Helmut Springer
  • Patent number: 4317783
    Abstract: A process for the preparation of an .alpha.-oxo-.alpha.-(3-alkoxycarbonyl-2,2-dimethyl-cycloprop-1-yl)-methane -phosphonic acid ester of the formula ##STR1## in which R is alkyl or a radical customary in the alcohol component of pyrethroids, andR.sup.1 is alkyl or phenyl, or the two radicals R.sup.1 together are alkanediyl,comprising reacting .DELTA., .DELTA.-dimethyl-acrylic acid chloride of the formula ##STR2## with a phosphorous acid ester of the formulaR.sup.4 O-P(OR.sup.1).sub.2in whichR.sup.4 is alkyl,at a temperature between about 0.degree. and 100.degree. C., to produce the novel compound 1-oxo-3-methyl-2-butene-phosphonic acid of the formula ##STR3## which is then reacted with a sulphuranylidene-acetic acid ester of the formula ##STR4## in which R.sup.2 and R.sup.3 each independently is alkyl or together are alkanediyl, at a temperature between about 0.degree. and 100.degree. C.
    Type: Grant
    Filed: July 21, 1980
    Date of Patent: March 2, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventor: Hellmut Hoffmann
  • Patent number: 4317856
    Abstract: The inclusion of metal particles finely and essentially statistically distributed in an insulating-material body which can be coated with a metal without use of an electric current is described wherein a solution of a reducible metal compound of a metal of Group VIII or Ib is employed. The solution can be added to a resin impregnating solution for the insulating material or to the adhesive of one or more adhesive layers in the insulating material. The solution of metal preferably contains a small amount of ammonium chloride.
    Type: Grant
    Filed: November 30, 1979
    Date of Patent: March 2, 1982
    Assignee: Dynamit Nobel AG
    Inventors: Dirk Huthwelker, Arnold Franz, Siegfried Kopnick
  • Patent number: 4317782
    Abstract: Distyryl compounds of the formula ##STR1## wherein A denotes 1,4-phenylene, 4,4'-biphenylylene, 4,4"-terphenylylene, 1,4-, 1,5- or 2,6-naphthylene, 9,10-dihydro-2,7-phenanthrenylene or 2,7-dibenzofuranylene,R.sup.1 denotes an optionally functionally modified phosphonic acid, phosphonyl or phosphinyl group,R.sup.2 denotes hydrogen, an optionally functionally modified phosphonic acid, phosphonyl or phosphinyl group, sulpho, carboxyl, alkoxycarbonyl, aryloxycarbonyl, aralkoxycarbonyl, aminocarbonyl, cyano, halogen, alkyl, aralkyl, alkenyl, hydroxyl, alkoxy, aralkoxy, cycloalkoxy, aryloxy or alkylmercapto andR.sup.3 and R.sup.
    Type: Grant
    Filed: February 22, 1979
    Date of Patent: March 2, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Udo Eckstein, Edgar Siegel
  • Patent number: 4317937
    Abstract: Bis-(1-bromo-2,3,3-trichloro-2-propenyl) ether of the formula ##STR1## is produced by reacting bis-(2,3,3-trichloro-2-propenyl) ether of the formula ##STR2## with bromine under irradiation with light. The end product as produced may be steam distilled in situ, thereby recovering 2,3,3-trichloroacrolein.
    Type: Grant
    Filed: January 7, 1980
    Date of Patent: March 2, 1982
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Junichi Saito, Toyohiko Kume
  • Patent number: 4316913
    Abstract: Substituted styrylcyclopropanecarboxylic acid esters of the formula ##STR1## in which R represents C.sub.1-4 -alkyl or an alcohol radical customary in pyrethroids,R.sup.1 represents alkoxy or alkylthio, either of which is optionally substituted by halogen andR.sup.2 represents hydrogen or alkoxy, orR.sup.1 and R.sup.2 together represent optionally halogen-substituted alkylenedioxy, andR.sup.3 represents hydrogen or chlorine,exhibit arthropodicidal activity. A novel synthesis is shown involving reaction of ##STR2## in the presence of an alkali metal cyanide to produce an end product wherein R is an .alpha.-cyano-3-phenoxybenzyl ester. ##STR3## is reacted with ##STR4## in the presence of a base to produce certain novel intermediates.
    Type: Grant
    Filed: March 31, 1980
    Date of Patent: February 23, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rainer Fuchs, Ingeborg Hammann, Wilhelm Stendel
  • Patent number: 4316747
    Abstract: A process and apparatus for the conversion of waste cellulose to glucose wherein an aqueous slurry of waste cellulose is acid hydrolyzed includes continuously feeding an aqueous slurry of waste cellulose into an inlet port with a twin screw extruder, continuously reacting the cellulose with water in the presence of an acid catalyst at elevated temperature and pressure in a reaction zone disposed in the extruder between the inlet port and an outlet port while continuously conveying same to the outlet port and at least quasi-continuously discharging the reacted cellulose from the extruder while maintaining the elevated temperature and pressure in the reaction zone by forming a dynamic seal zone at the upstream end of the reaction zone and valving the discharge downstream of the outlet port.
    Type: Grant
    Filed: March 18, 1980
    Date of Patent: February 23, 1982
    Assignee: New York University
    Inventors: Barry A. Rugg, Walter Brenner
  • Patent number: 4316912
    Abstract: 1,1-Dimethyl-indan-4-yl N-alkyl-carbamic acid esters of the formula ##STR1## in which R.sup.1 is alkyl, andR.sup.2 and R.sup.3 each independently is hydrogen or alkyl, which possess fungicidal and arthropod development-inhibiting properties.
    Type: Grant
    Filed: February 19, 1980
    Date of Patent: February 23, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Detlef Grotkopp, Karlfried Wedemeyer, Wilhelm Brandes, Hans Scheinpflug, Peter Roessler
  • Patent number: 4316932
    Abstract: An .alpha.-azolyl-keto derivative of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl or optionally substituted phenyl,R.sup.2 represents the grouping --CX.sup.1 X.sup.2 R.sup.3 or alkoxy-carbonyl,R.sup.3 represents halogen, halogenoalkyl or optionally substituted phenyl,R.sup.4 represents the grouping --O--CO--R.sup.5, --O(S)--R.sup.6 or --O--S(O).sub.n --R.sup.7, or alkylamino, dialkylamino, optionally substituted phenylamino or halogen,R.sup.5 represents alkyl, halogenoalkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl, optionally substituted phenylalkyl, alkylamino, dialkylamino or optionally substituted phenylamino,R.sup.6 represents alkyl, alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl or optionally substituted benzyl,R.sup.7 represents alkyl, halogenoalkyl, optionally substituted phenyl or dialkylamino,n represents 1 or 2,X.sup.1 and X.sup.
    Type: Grant
    Filed: July 2, 1979
    Date of Patent: February 23, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Eckart Kranz, Wolfgang Kramer, Karl H. Buchel, Wilhelm Brandes, Paul-Ernst Frohberger
  • Patent number: 4316910
    Abstract: Substituted 2-carbamoyloximino-butanes of the formula ##STR1## in which R is alkyl or alkylthioalkyl,R.sup.1 is alkyl, alkoxyalkyl, alkenyl or alkynyl,R.sup.2 is hydrogen, alkyl or --SR.sup.3,R.sup.3 is alkyl, halogenoalkyl, optionally substituted phenyl, alkoxycarbonyl, --N(CH.sub.3)R.sup.4, or a radical identical to that to which --SR.sup.3 is bonded,R.sup.4 is alkyl, alkoxycarbonyl or optionally substituted phenylsulphonyl,X is hydrogen or halogen,Y is hydrogen or halogen,Z is halogen, andn is 0, 1 or 2,which possess arthropodicidal activity.
    Type: Grant
    Filed: August 11, 1980
    Date of Patent: February 23, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jorg Stetter, Bernhard Homeyer, Ingeborg Hammann, Hans-Ludwig Elbe
  • Patent number: 4316880
    Abstract: A process is described for producing carbon monoxide and hydrogen which comprises contacting methanol vapor at a temperature of 200.degree. to 500.degree. C. with an indirectly heated zinc containing catalyst while said methanol vapor is at a pressure in a range of 2 to 50 bars, whereby to obtain an effluent gas in which the components of carbon monoxide and hydrogen constitute at least 90% by volume of said gas, removing at least a part of the impurities from said effluent gas and separating said effluent gas into its carbon monoxide and hydrogen components by adsorption. The effluent gas can be separated into its carbon monoxide and hydrogen components by use of a plurality of adsorbers containing zeolite-type molecular sieve material where the zeolite is substantially permeable to hydrogen but sorbs carbon monoxide.
    Type: Grant
    Filed: May 6, 1980
    Date of Patent: February 23, 1982
    Assignee: Metallgesellschaft, Aktiengesellschaft
    Inventors: Heinz Jockel, Friedemann Marschner, Friedrich W. Moller, Hans-Gunter Mortel