Abstract: Surfactant mixtures of an alkyl naphthalene sulfonate and an alkyl polyglycoside, wherein the alkyl polyglycoside is present in from 5 to 25% by weight of the surfactant mixture, and aqueous pesticide compositions containing the surfactant mixture.
Abstract: A process for phosphating a galvanized surface of a steel strip electrolytically galvanized on one side by contacting the galvanized surface of the steel strip with a phosphating solution containing 1.0 to 6 g/l zinc, 0.5 to 5.0 g/l nickel and 14 to 25 g/l phosphate at a temperature of 40.degree. to 70.degree. C. for from 2 to 20 seconds. The ungalvanized surface remains metal bright.
Type:
Grant
Filed:
April 27, 1995
Date of Patent:
May 14, 1996
Assignees:
Henkel Kommanditgesellschaft auf Aktien, Krupp Hoesch Stahl AG
Inventors:
Joerg Riesop, Raschad Mady, Dieter Geruhn, Frank Panter, Franz Ricke, Hubertus Peters, Juergen Verheien, Manfred Wessel
Abstract: The invention relates to ionic polymers obtained by reaction of carboxyfunctional fat- and oil-based starting materials with salts of polyvalent ions. They may be used as sealants, coatings, adhesives and as additives for plastic formulations and for mortars, gypsums and cements. The starting mixture may be present both in a one-component formulation and in a two-component formulation.
Type:
Grant
Filed:
September 30, 1994
Date of Patent:
May 14, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Wolfgang Klauck, Ernst-Ulrich Rust, Peter Daute, Johann Klein, Ludger Willeke
Abstract: The invention is a process for hydrophilicizing a mixture of triglycerides and glycerol by ethoxylation of the mixture followed by sulfonation with sulfur trioxide and neutralization.
Type:
Grant
Filed:
June 17, 1994
Date of Patent:
May 7, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Frank Wangemann, Hans-Christian Raths, Rudolf Zauns-Huber
Abstract: Preparation of N,N'-bis(alkylsalicylidene)ethylene or phenylene diamines, and transition metal complexes thereof, particularly copper, and their use as an additive to diesel fuel to reduce soot formation in diesel exhaust.
Abstract: Foaming shampoo compositions which contain no anionic surfactant and are mild to the skin and eyes are comprised of alkyl polyglycosides, betaines, and polymeric slip agents.
Type:
Grant
Filed:
May 8, 1995
Date of Patent:
May 7, 1996
Assignee:
Henkel Corporation
Inventors:
Barry A. Salka, Bruce W. Gesslein, Robert M. Jablonski
Abstract: The invention relates to a continuous process for the production of lower alkyl esters at temperatures of up to 100.degree. C. and under pressures of up to 10 bar by reaction of fatty acid triglycerides containing less than 1% free fatty acid with a lower alcohol in two stages in the presence of a homogeneous alkaline catalyst, the glycerol formed being removed after the first stage. To enable the process to be carried out with high yields and with lower maintenance, investment and energy costs than in the prior art, the reaction mixture is passed through a reactor and a following static separator only once in each stage, tube reactors are used as the reactors and the Reynolds number of the flow of the reaction mixture is greater than 2,300.
Type:
Grant
Filed:
February 3, 1994
Date of Patent:
May 7, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Georg Assmann, Gerhard Blasey, Bernhard Gutsche, Lutz Jeromin, Jean Rigal, Rene Armengaud, Bernard Cormary
Abstract: Described are materials based on a starch which has been thermomechanically digested at elevated temperatures and pressures and upon the addition of water and/or lower molecular weight plasticizers and which contains oxidatively cross-linkable alkyd resins having been incorporated in an intimate admixture. Preferably, these alkyd resins have been at least predominantly composed of key substances based on re-growable raw materials.The starch blends thus modified are suitable for the manufacture of shaped articles which in the presence of air will be reactively cured and thereupon are imparted with an increased strength, and especially an increased resistance to water.
Abstract: A binder mixture for stoving lacquers comprising A) at least one alkyd resin; and B) at least one poly-N-acyl alkyleneimine prepared by cationic polymerization of a monomer mixture ofa) from 10 to 90% by weight of at least one monomer corresponding to formula (I): ##STR1## in which Z is a direct bond or the group CR.sup.5 R.sup.6, R.sup.1 to R.sup.4 can be the same or different and represent H or a C.sub.1-8 alkyl group, R.sup.5 and R.sup.6 can be the same or different and represent H or a C.sub.1-2 alkyl group, R.sup.7 is a hydroxyl-containing alkyl or alkylene group of a hydroxycarboxylic acid containing 2 to 32 carbon atoms,b) from 90 to 10% by weight of at least one monomer corresponding to formula (II): ##STR2## in which Z and R.sup.1 to R.sup.6 are as defined above and R.sup.8 is the radical of an aromatic monocarboxylic acid, andc) from 0 to 80% by weight of at least one monomer corresponding formula (III): ##STR3## in which Z and R.sup.1 to R.sup.6 are as defined above, and R.sup.
Type:
Grant
Filed:
February 13, 1995
Date of Patent:
April 30, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Ulrich Eicken, Herbert Fischer, Wolfgang Gress, Ulrich Nagorny, Norbert Stork
Abstract: A thermoplastic hot-melt adhesive based on a polymer blend of polyolefins is disclosed. An oligomer of an alpha-olefin with at least eight carbon atoms in the monomer and a molecular weight of the oligomer of up to 5,000, as well as other known additives, are added to the known mixture of a substantially amorphous poly-alpha-olefin and of a substantially crystalline poly-alpha-olefin. The impact strength, the viscosity and the flexibility at low temperatures are above all improved in this manner. These hot-melt adhesives are therefore suitable above all for gluing non-polar plastics in the automobile and electric industry.
Type:
Grant
Filed:
February 6, 1995
Date of Patent:
April 30, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Ruediger Butterbach, Siegfried Kopannia, Johannes Andres
Abstract: Described are initiator systems for initiating the polymerization of ethylenically unsaturated compounds, which systems have been based on oxygen-reactive organo-boron compounds present in combination with oxygen-resistant carriers; the initiator systems are characterized in that they contain oligoesters of lower hydroxycarboxylic acids as carriers. The invention further relates to the use of these initiator systems in adhesive systems in the technical field, but especially also in the areas of surgery and/or dentistry for curing body-resorbable or body-resistant adhesive agents, cements and/or filler compositions or for forming molded parts of synthetic materials.
Abstract: A process for removing printing inks from printed wastepaper in the presence of a deinking chemical is provided. In this process printed wastepaper is disintegrated to form a paper stock suspension and the detached printing ink particles are removed in known manner by flotation or washing in another stage. In this process, alkoxylates of blown oils are used as the deinking chemical. The deinking chemical is added during disintegration and/or before the flotation or washing step. Preferably, the printed wastepaper is disintegrated in the presence of 0.02 to 2% by weight and preferably 0.1 to 0.8% by weight, based on air-dry paper stock, of alkoxylates of blown oils. This deinking chemical also removed printing inks from paper circuit waters.
Type:
Grant
Filed:
July 29, 1994
Date of Patent:
April 30, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Peter Daute, Berthold Schreck, Klaus Hornfeck
Abstract: A process for the production of carboxyfunctional polyurethane from dihydroxyfatty acids and/or dihydroxypolyfatty acids as isocyanate-reactive compounds bearing an ionizable group is provided. The dihydroxycarboxylic acids and/or dihydroxypolyfatty acids have no shielding molecular group near the carboxy group, more particularly not in the alpha-position to the carboxy group, and thus give particularly good results when used as a structural element for the production of polyurethanes. Also provided are polyurethanes and aqueous polyurethane dispersions produced using the dihydroxyfatty acids.
Abstract: A process has been discovered for making alkyl polyglycoside which comprises reacting a fatty alcohol having from about 8 to about 22 carbon atoms with a sugar, in the presence of an acid catalyst, to form a product of alkyl polyglycoside and excess fatty alcohol. The molar ratio of fatty alcohol to sugar, respectively, is at least 2:1. The excess fatty alcohol is then separated from the alkyl polyglycoside product. Once separated, the excess fatty alcohol is then reacted with a source of boric acid to form a mixture comprised of one or more borate esters of the fatty alcohol and inert compounds. The non-hydroxylic compounds are then separated from the borate esters. The substantially pure fatty alcohol is then returned to the beginning of the process for use in the formation of alkyl polyglycoside.
Type:
Grant
Filed:
July 22, 1994
Date of Patent:
April 30, 1996
Assignee:
Henkel Corporation
Inventors:
Patrick M. McCurry, Jr., Janet R. Varvil, Carl E. Pickens
Abstract: The crude reaction products from the synthesis of alkyl glycosides are bleached by kneading the material substantially freed from the excess fatty alcohol and containing at most limited quantities of water with an oxidizing agent at such elevated temperatures that the reaction mixture lends itself to plastic processing. Temperatures of from about 50.degree. to 150.degree. C. are particularly suitable, although it is best to apply temperatures in the range from about 80.degree. to 100.degree. C. using aqueous hydrogen peroxide as the oxidizing agent. Bleaching is carried out under basic conditions, optionally by addition of an alkaline compound, such as for example 50% sodium hydroxide solution. The bleached product accumulates in the form of a solid. It is preferably mixed with typical compatible solids, more particularly typical constituents of detergents and cleaning preparations, to form a solid and preferably free-flowing alkyl glycoside compound.
Type:
Grant
Filed:
October 17, 1994
Date of Patent:
April 23, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Willi Wuest, Rainer Eskuchen, Paul Schulz, Volker Bauer, Franz-Josef Carduck, Herbert Esser, Christiane Zeise, Manfred Weuthen, Josef Penninger
Abstract: A plug-type connector for electrical coaxial cables includes a hot-melt-type adhesive for filling in the interior space between an outer bushing and centrally located contact bushing, with the contact bushing being configured for receiving an inner conductor of a coaxial cable. The hot-melt-type adhesive seals, fills, and insulates the interior portions of the plug-type connector surrounding the centrally located contact bushing and inner conductor of the associated coaxial cable. The hot-melt-type adhesive consists a polyamide based on dimerized fatty acids, aliphatic amines, and modifiers, and a copolyethylene and additives.
Type:
Grant
Filed:
January 27, 1994
Date of Patent:
April 23, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Reimar Heucher, Juergen Wichelhaus, Kurt Schueller, Bettina Becker
Abstract: The invention is an aqueous autodeposition coating composition that produces a film that has a better adherence and corrosion resistance than the films formed by the prior-art coating compositions, but which does so without a rinse treatment (for example, a chromium containing solution, rinse) prior to film curing. The aqueous autodeposition coating composition has a pH of 1.6 to 5.0 and contains(i) water-dispersible or water-soluble organic film-forming resin,(ii) at least one of fluoride ions or fluoride ions and complex fluoride ions,(iii) hexavalent chromium ion or hexavalent chromium ion+trivalent chromium ion, and(iv) tungstate ion and/or molybdate ion.
Type:
Grant
Filed:
July 29, 1994
Date of Patent:
April 23, 1996
Assignee:
Henkel Corporation
Inventors:
Takumi Honda, Kazuhisa Naito, Mitsuyuki Koga
Abstract: A highly corrosion-resistant, highly alkali-resistant, and very paintable chromate film on the surface of a steel substrate coated with Zn-containing metal is formed by coating the substrate with an aqueous chromate bath and drying into place, preferably at a substrate temperature of 60.degree. to 200.degree. C., without a water rinse. The bath contains Cr.sup.6+, Cr.sup.3+, phosphate ions, water-soluble glycol ether (WSGE) and/or poly{vinyl alcohol} (PVA), and optionally silica sol, in amounts giving ratios of Cr.sup.3+ /Cr.sup.6+ =0.25 to 4.0, PO.sub.4 /total Cr=0.1 to 2.5, and (WSGE+PVA)/Cr.sup.6+ =0.1 to 0.5 in the bath.
Abstract: A method of curing an epoxy resin comprising mixing an epoxy resin with a curing agent is provided. The curing agent is selected from the group consisting of (i) a mixture consisting essentially of 1,2-diaminocyclohexane and an aliphatic polyamine (preferably at a molar ratio of 1,2-diaminocyclohexane to aliphatic polyamine of from about 1:1 to about 16:1, preferably about 2.5:1 to about 6:1 and more preferably about 3:1 to about 5:1) and (ii) the reaction product of reactants consisting essentially of an amine component consisting essentially of 1,2-diaminocyclohexane and an aliphatic polyamine and an epoxide component. The epoxide component has an epoxy functionality greater than one and is preferably a diglycidyl ether of an aromatic diol having an average degree of oligomerization of less than about 3.5., preferably less than about 1.5, and preferably derived from an alkyl bis-phenol, e.g. bisphenol A.
Abstract: Described is the use of surface-active alpha-sulfofatty acid di-salts as ecologically compatible emulsifiers of the W/O type and O/W type, respectively, in fluid and pumpable drilling fluids and other fluid drilling-hole treatment agents which comprise a continuous or a dispersed oil phase together with an aqueous phase and which are suitable for an environmentally acceptable exploitation of geological resources, for example oil or natural gas deposits. The invention further relates to inverted drilling fluids based on a continuous oil phase and, present therein, a dispersed aqueous phase which, in addition to the emulsifiers, contain further conventional auxiliary agents such as thickeners, fluid-loss additives, weighting agents, water-soluble salts and/or alkali reserves.
Type:
Grant
Filed:
April 28, 1995
Date of Patent:
April 16, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Heinz Mueller, Claus-Peter Herold, Johann F. Fues