Abstract: The adhesive strength of an aqueous binder dispersion consisting of: a halogenated copolymer which, in addition to other components, contains an alkylation-active monoalkenylaromatic alkyl halide; polyfunctional aromatic nitroso compounds; pigments; carbon black; anti-foaming agents; emulsifiers; and other additives, used for vulcanizing rubber onto substrates which are stable under the conditions of vulcanization, is improved, and the use of blocked isocyanates is avoided. This is achieved by adding, to increase the adhesive strength, homopolymers or copolymers of vinyl acetate that are also saponified to a certain extent, as well as, optionally, other customary additives.
Type:
Grant
Filed:
January 26, 1994
Date of Patent:
February 13, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Hans Scheer, Wolf-Dieter Beiersdorf, Hans-Joachim Purps
Abstract: Process for applying an antistatic finish to synthetic fibers comprising of steps ofapplying to the fibers to be treated a composition comprising at least one salt of a phosphate partial ester containing a C.sub.12 straight chain alkyl group, a lubricant, and an anionic and/or cationic emulsifier; andautoclaving the treated fibers at a temperature in the range of from about 93.degree. to 150.degree. F.
Abstract: An aqueous dispersion of amphiphilic oligomers for oiling leather or skins wherein the dispersion contains anionically modified urethane fatty oligomers containing long-chain hydrocarbon fatty groups containing from 8 to 40 carbon atoms, together with salt-forming carboxylic acid groups, sulfonic acid groups and mixtures thereof, which form urethane fatty oligomers having an at least predominantly linear basic structure of the oligomer molecule.
Type:
Grant
Filed:
February 17, 1995
Date of Patent:
February 6, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Wolfgang Ritter, Rudolf Zauns-Huber, Emil Ruscheinsky, Stefanie Ortanderl
Abstract: Water containing detergent mixtures contain an alkyl and/or alkenyl polyglycoside and an anionic or nonionic surfactant selected from the group consisting of: (a) a narrow range fatty alcohol polyglycol ether, (b) a narrow range fatty alcohol ether sulfate, (c) a fatty acid alkanolamide ether sulfate, and (d) a monoglyceryl ether sulfate are superior detergents for dishwashing formulations and for cosmetics.
Type:
Grant
Filed:
September 30, 1994
Date of Patent:
February 6, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Ansgar Behler, Brigitte Giesen, Hans-Christian Raths, Harald P. Wulff
Abstract: An improved process for oximation of carbonyl compounds, such as ketones and aldehydes by oximation with hydroxylamine including oximation processes carried out in the presence of a catalytic amount of a phase transfer catalyst comprised of a mixture of an alkyl phenol, such as nonylphenol or dodecylphenol and an organic carboxylic acid, such as 2-ethylhexanoic acid, in the presence of an alkali metal or alkaline earth metal compound. The resulting oximes are useful as metal extractants.
Abstract: Article of manufacture and method of making the same in which a metal substrate has an undercoating is made from a combination of at least one pulverulent metal and a transition metal compound and a coating thereon containing an autodeposited resin formed under autodepositing conditions.
Abstract: The coefficient of friction of aluminum can surfaces after alkaline cleaning and drying can be substantially reduced by adding to the alkaline cleaner a mobility enhancing additive, preferably a surface active quaternary ammonium salt with hydroxyethyl substituents on the quaternary nitrogen atoms. A can surface suitable for automatic conveying and high quality lacquer or printing ink adhesion can thereby be obtained, if desired without including any substantial fluoride content in any treatment stage.
Type:
Grant
Filed:
September 21, 1994
Date of Patent:
January 23, 1996
Assignee:
Henkel Corporation
Inventors:
James P. Bershas, Timm L. Kelly, Gary L. Rochfort
Abstract: A socket is provided whereby pipe ends are joined together so that a gas and water-tight connection is established between the pipes. The socket is generally in the form of a tubular shell having at least one projection extending radially from an inner face of the shell. Annular elements are provided at distal ends of the shell to both center the pipes to be joined within the socket, as well as seal the annular space formed between the outer surface of the pipes and the inner surface of the socket. Annular flanges located on either side of the projection are provided to receive the ends of the pipes to be permanently joined and seal the annular spaces.
Abstract: The invention relates to improvements in the spraying of water-based treatment liquors onto textile materials, more particularly in the continuous treatment of web-form textile materials, the treatment liquors being sprayed in particular under the conditions of aerosol/superheated steam application. The invention is characterized in that the water-based treatment liquors used contain deaerating components free or at least substantially free from foam under the spraying conditions in dissolved, homogeneously emulsified and/or homogeneously dispersed form in such high concentrations that the textile material is thoroughly wetted almost immediately. The invention also relates to processes for simultaneously carrying out a plurality of treatment stages in a single step and to preparations suitable for these processes, for example preparations and a process for simultaneously desizing, scouring and bleaching cellulose-containing textile materials.
Type:
Grant
Filed:
November 2, 1993
Date of Patent:
January 16, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Bernd-Dieter Baehr, Hildegard von Delden, Wolfgang Lillotte
Abstract: The intention is a process for removing inorganic salts from aqueous mixtures of organic compositions capable of forming micelles. The aqueous mixture is subjected to ultrafiltration to remove the inorganic salts and recover the organic compositions in the retentate.
Abstract: Scouring powders containing abrasives and an alkyl glycoside having a degree of oligomerization of from 1.2. to 1.4. These scouring powders are low foaming in the presence of water.
Type:
Grant
Filed:
July 29, 1993
Date of Patent:
January 16, 1996
Assignee:
Henkel Kommanditgesellschft auf Aktien
Inventors:
Eva Kiewert, Lothar Pioch, Wolfgang Seiter, Winfried Wichelhaus
Abstract: The invention is a resorbable, viscous to solid wax for the mechanical staunching of blood on hard body tissue, particularly bones, based on oligomers of glycolic acid and/or lactic acid and derivatives thereof with monofunctional and/or polyfunctional alcohols and/or corresponding carboxylic acids. The new waxes are characterized by containing body-compatible salts of organic and/or inorganic acids which are formed by corresponding reaction of any free carboxyl groups present in the oligomer wax and/or are incorporated in the wax in homogeneous distribution as added salts.
Abstract: Saturated, branched C.sub.20-28 fatty acids or esters thereof esterified with C.sub.1-36 alkanols produced by the process comprising: (a) reacting unsaturated fatty acids containing 18 to 22 carbon atoms and more than one olefinic bond or esters thereof esterified with C.sub.1-36 alkanols with ethylene at a temperature of from about 50.degree. C. to about 140.degree. C. and at a pressure of from about 5 to about 60 bar in the presence of transition metal compounds selected from the group consisting of Ru, Rh, Pd, Ir, or Pt wherein the molar ratio of ethylene to fatty acid or fatty acid ester is from about 1:1 to about 3:1 to form an olefinically unsaturated adduct and, (2) hydrogenating said adduct in the presence of a hydrogenation catalyst at a temperature of from about 70.degree. C. to about 120.degree. C. and under a hydrogen pressure of from 10 to about 30 bar.
Type:
Grant
Filed:
July 24, 1992
Date of Patent:
January 2, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien TFP/Patentabteilung
Abstract: The invention relates to a process for the removal of alcohols containing up to 30 and, more particularly, between 8 and 18 carbon atoms by distillation from a mixture of alkyl glycosides and alcohols remaining unreacted in the production of these alkyl glycosides, the alcohols being removed in two stages, a falling-film evaporator being used in the first stage and a thin-layer evaporator being used in the second stage.
Type:
Grant
Filed:
July 28, 1994
Date of Patent:
January 2, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Wilhelm Johannisbauer, Hermann Koerner, Michael Nitsche
Abstract: Alkyl and/or alkenyl oligoglycosides can be obtained in short reaction times and high yields by a process in which glycose is reacted with fatty alcohols at elevated temperature in the presence of sulfomonocarboxylic acids containing 2 to 8 carbon atoms, carboxylic anhydrides thereof and/or mixed cyclic sulfonic/carboxylic anhydrides thereof as acidic catalysts, the water of reaction is removed and the reaction products are worked up.
Type:
Grant
Filed:
May 13, 1994
Date of Patent:
January 2, 1996
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Manfred Weuthen, Karlheinz Hill, Paul Schulz
Abstract: New contact adhesives which are designed as multifunctional contact reactive adhesives and which may be used in a multistage curing process, for example for bonding wood, plastic moldings, metals and the like, are provided. One of the functional substituents of the adhesive composition is characterized by the presence of an olefinic double bond which is accessible to radical reaction initiation. The other functional substituent is an isocyanate group which reacts off, e.g. under the effect of moisture. These different reaction mechanisms enable the reactive contact adhesive to be cured in stages, e.g. by forming contact-sensitive adhesive layers on hard surfaces in a first stage, subsequently fitting the correspondingly coated surfaces together and firmly bonding them together in a final stage, e.g. under the effect of atmospheric moisture. Also provided is a process for the production of the new reactive contact adhesives.
Type:
Grant
Filed:
June 24, 1993
Date of Patent:
December 26, 1995
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Thomas Huver, Winfried Emmerling, Michael Kux, Christian Nicolaisen, Wolfgang Klauck
Abstract: Light-colored alkyl or alkenyl oligoglucosides are obtained by a process in which glucose or aqueous starch degradation products are reacted with fatty alcohols in the presence of acidic catalysts which are obtained by partial sulfation of C.sub.4-22 fatty alcohols.
Type:
Grant
Filed:
August 10, 1994
Date of Patent:
December 26, 1995
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Patrick M. McCurry, Jr., Rainer Eskuchen, Paul Schulz
Abstract: Thermally stable textile lubricants suitable for spinning finishes based on polyol fatty acid esters, into which esters of thiocarboxylic acids corresponding to general formula (I) and/or (II):R.sup.1 --S--R.sup.2 --COOH (I)HOOC--R.sup.3 --S--R.sup.4 --COOH (II)in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may be the same or different and represent an alkyl, cycloalkyl, aryl or alkaryl group containing 1 to 22 carbon atoms, are introduced to increase thermal stability, are distinguished by excellent thermal stability.
Type:
Grant
Filed:
June 16, 1994
Date of Patent:
December 26, 1995
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Norbert Bialas, Raymond Mathis, Richard P. Crews, Elbert H. Mudge, F. Norman Tuller
Abstract: A process for reducing the content of free formaldehyde and formic acid in nonionic and anionic surfactants is provided. The process comprises adding an amine compound selected from the group consisting of a) alkanolamines, b) aminocarboxylic acids and c) oligopeptides to a surfactant comprised of a member selected from the group consisting of nonionic and anionic surfactants. The amine compound is preferably selected from the group consisting of a) an alkanolamine containing 2 to 15 carbon atoms, b) an aminocarboxylic acid containing 2 to 8 carbon atoms, and c) an oligopeptide with an average molecular weight of 500 to 5000. The nonionic and anionic surfactants preferably contain 1 to 100 ethylene oxide units in the form of at least one polyethylene glycol chain. The amine compound is preferably added in a quantity of 50 to 6000 ppm, based on active substance of said surfactant.
Type:
Grant
Filed:
September 23, 1994
Date of Patent:
December 26, 1995
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Ansgar Behler, Hermann Hensen, Uwe Ploog, Werner Seipel, Frank Clasen
Abstract: Antistatic agents and their use in processing textiles or formed plastic substrates. The antistatic agent comprises a compound having a fluorocarbon moiety and an ethoxylated quaternary ammonium moiety. The antistatic composition increases the electrolytic conductivity of treated textile or plastic materials, thereby increasing the rate of electrostatic charge dissipation thereof. The antistatic agents remain effective after exposure of the treated substrate to an aqueous environment.