Abstract: A method of reducing the content of NOx and N2O in gases using a gaseous reducing agent which is used in the amount required for reduction of the NOx in the presence of one or more iron-laden zeolites which have no pores or channels having a width of greater than or equal to 7 ?ngström in the crystal structure and at temperatures of less than 450° C. in the reaction zone is described. In this method, the flow rate of the gas mixture and/or the amount of catalyst is/are selected so that the desired degree of decomposition of N2O is achieved. The method can be used, in particular, in nitric acid production, in power stations and in gas turbines.

Abstract: An apparatus for producing ethylenically unsaturated aliphatic halogenic hydrocarbons by thermal cleavage of saturated aliphatic halogenic carbons using an apparatus that introduces an educt gas stream into a reactor which includes at least one supply conduit which opens into the reactor, the supply conduit feeds a heated gas formed from cleavage promotors and radicals produced by a nonthermal plasma device which permits an increased in the yield of the cleavage reaction.

Abstract: The invention relates to a method for the production of 1,2-dichloroethane by direct chlorination using chlorine and ethene in which, despite low reaction temperatures during direct chlorination, reaction heat produced is nevertheless used. According to the invention, vaporous 1,2-dichloroethane obtained in the direct chlorination reactor is compressed and the compressed 1,2-dichloroethane is transported to heat exchangers whereby heat is given off by the 1,2-dichloroethane. The invention also relates directly after the direct chlorination reactor.

Abstract: An apparatus for the provision of a block flange of a manhole aperture or the like, in particular for fluidized bed reactors for the oxychlorination of ethylene, oxygen and HCl, having a wall flange fixed in the reactor wall, is intended to provide a solution whereby all other auxiliary measures can be dispensed with and the expense associated therewith can be eliminated without the functionality of the system suffering as a result and without undesirable deposits being formed in these areas. This is achieved in that the flange surface (5) pointing inward and downward in the direction of gravity is of beveled design, at least in some areas.

Abstract: The invention relates to a method for the production of nitric acid having a concentration of between 50 and 76%, from ammonia and gas containing oxygen, under pressure, according to a single pressure method or dual pressure method. The expansion of the residual gas takes place in at least two stages in a work efficient manner. At least one device for heating the previously expanded gas to a temperature of more than 450° is disposed between every other expansion stage, using waste heat from the production process of nitric acid.

Abstract: A method of reducing the N2O content in gases is described. A selected zeolite catalyst is used in the method. This catalyst is present in the H form and/or contains exchanged iron and is characterized by the presence of nonlattice aluminum in addition to the lattice aluminum in a molar ratio of from 1:2 to 20:1. The method can be used in nitric acid production for reducing the N2O content of process gases or offgases.

Abstract: A method for cleaning coke oven gas by washing the gas, whereby a washing liquid is guided into a washing liquid circuit and impurities in the washing liquid are expelled in a desorber. According to the invention, the coke oven gas is washed with caustic soda in a counter flow. The caustic soda is regenerated in the desorber by expelling acid gas components and ammonia.

Abstract: With a synthesis furnace having a furnace chamber surrounded by a circumferential furnace wall, in which a plurality of burners disposed essentially in one plane, with burner exit direction directed downward, and a plurality of reaction tubes disposed essentially vertically and parallel to one another are disposed, whereby the reaction tubes are heated from the outside, by means of the firing burners, the heat distribution and the entire heat transfer are supposed to be improved in as simple a manner as possible, in terms of design and control technology. This is achieved in that at least the outer burners (5) disposed in the region of the furnace wall (2) have a burner exit direction (R) that is inclined relative to the vertical, leading away from the center of the furnace.

Abstract: With the help of a method for production of a gaseous diffusion electrode from a silver catalyst on PTFE-substrate, it is endeavored to achieve results which can be reproduced, by avoiding the disadvantages of the state-of-the-art technology, whereby this is achieved in that the porous system of the silver catalyst is filled with a wetted fluid; a dimension-stable solid body with a grain size above that of the silver catalyst is mixed below the silver catalyst; the thus compression-stable mass is shaped into a homogenous catalyst band in a calender; and in a second calender step, an electrically conductive conductor material is imprinted into the catalyst band.

Abstract: The invention relates to a method and a device for the optimal use of reaction heat resulting from the production of 1,2-dichloroethane from ethene and chlorine. The aim of the invention is achieved by extracting reaction heat liberated during the reaction of chlorine with ethene and the reaction heat contained in 1,2-dichloroethane. Extraction of said reaction heat from the reaction chamber occurs using at least one part of gaseous 1,2-dichloroethane (latent heat) and at least one part of liquid 1,2-dichloroethane (feelable heat) removed from the reaction chamber. Said reaction heat is used to heat two fractioning columns in order to purify 1,2-dichloroethane of impurities having a boiling point higher than 1,2-dichloroethane.

Abstract: Device for injecting electromagnetic radiation into a reactor and a reactor comprising this device A device for injecting electromagnetic radiation into a reactor for carrying out free-radical gas-phase reactions and a reactor comprising such a device are described. This comprises the elements: a) a compartment which is separated from the reaction space of the reactor and is b) connected to the reaction space of the reactor via at least one opening, c) at least one feed line for introducing a flushing gas into the compartment, and also d) at least one source of electromagnetic radiation which is arranged so that e) the electromagnetic radiation passes through the compartment and the reaction space of the reactor adjoining the compartment. The device and reactor make an increase in the yield of free-radical chain reactions possible.

Abstract: A process for the catalytic epoxidation of olefins in the presence of a titanium containing zeolite catalyst and a polar solvent whereby the deactivation of the catalyst upon recycling of the solvent has been considerably reduced. In the process one or more nitrogen containing compounds are introduced at some stage, a solvent stream is recovered, treated to contain less than 50 wppm nitrogen in the form of organic nitrogen compounds and at least a part of it is recycled to the epoxidation step. Also disclosed is a process for the catalytic epoxidation of propene which integrates the treatment and recycle of the solvent into the workup of the reaction mixture.

Abstract: A process for recovering methanol from mixtures containing methanol and water, comprising multistage evaporation with heat integration, wherein the pressure is reduced from each stage to the next, and a downstream series of distillation stages with heat integration, wherein the pressure is increased from each stage to the next. The process reduces the amount of energy required for methanol recovery.

Abstract: A process for the epoxidation of olefins which includes i) reacting an olefin with hydrogen peroxide in presence of an epoxidation catalyst and an alcoholic solvent; ii) separating product olefin oxide and unreacted olefin from the reaction product of step i); iii) recovering a stream comprising the alcoholic solvent; and iv) subjecting the recovered stream of step iii) to hydrogenation.

Abstract: The invention relates to a method and a device for evacuating hot raw gases which occur in the oven chambers of a coke oven battery during coking. The oven gases are lead from the oven chambers into a hot gas collector. The pressure in the oven chambers is controlled by shut-off and throttling devices which are arranged in the hot gas streams between the raw gas outlet of the oven chambers and the hot gas collector. The positions of the devices are controlled according to the pressure that is measured in the allocated oven chamber. The gas of the hot gas collector is supplied to a steam boiler firing or a fission reactor.

Abstract: A process for producing nitric acid of a concentration in the range of 68 to 76% by weight, using the mono-pressure or the dual-pressure process in which the ammonia feedstock is combusted with the aid of compressed process air. The water vapour content of the process air used for combustion and/or stripping and imported from outside the system, is reduced in this process.

Abstract: A method is provided for operating a coke oven battery including many identical coking chambers, a raw gas receiver, and throttle devices arranged in the receiver for individually controlling the gas pressure in the chambers. Each throttle device includes an immersion bucket acted upon by water. Gas lines terminating in immersion pipes in the immersion buckets connect the chambers with the receiver. Throttle devices are employed that include an overflow that can be vertically adjusted by an actuating drive for controlling the liquid level in the immersion bucket. For a coking chamber to which a pressure control device is allotted, the setting signals for the actuating drive allocated to the time pressure curve in the process of carbonizing coal to coke are recorded as a position-time curve. The actuating drives of throttle devices that are allocated to coking chambers without pressure control devices are controlled according to the position-time curve.

Abstract: A device for controlling the gas pressure in a coke oven chamber, has an immersion cup, to which water is supplied, and with an immersion pipe which is connected to the gas space of the coke oven chamber and terminates in the, immersion cup. The immersion cup has an overflow and a closeable outflow. To control the liquid level, an outflow pipe for water is provided, the inflow-side end of which projects into the immersion pipe and contains casing-side inflow orifices for the inflow of water. Within the outflow pipe is arranged a slide which is open on both end faces and which closes the inflow orifices of the outflow pipe in the longitudinal direction according to the position of said slide and forms a vertically adjustable overflow for the water flowing into the outflow pipe.

Abstract: The invention relates to a device for lilting and removing oven doors of a coking oven that is comprised of a door removing head (1), which can be coupled to vertically extending oven doors of a horizontal chamber coking oven, of a drive device (3) for effecting adjusting movements of the door removing head (1), and of a suction hood, which can be displaced along the horizontal chamber coking oven above the oven door. According to the invention, sealing elements (5) are connected to the door removing head (1) and, on both sides of an oven door (2) to be opened, can be displaced against front contact surfaces (6) of the horizontal chamber coking oven. Said sealing elements extend essentially over the entire height of the oven door (2) and into the suction area (4) of the suction hood, and they form a suction chamber (8) for door emissions when the oven door (2) is opened.

Abstract: The invention relates to a method for filling a horizontal flue coking oven. According to the invention, spinning cells are introduced into the furnace chamber for filling, which comprise a discharge element rotating about a vertical axis. The bulk material is charged onto the spinning cells and the bulk material distributed in the furnace chamber as a result of the rotation of the discharge element. The surface of the bulk material is subjected to a subsequent raking process.