Abstract: The invention relates to a method for cooling rising vapor (3) in a desorption column (2) by means of a condenser, which is situated at the head of the desorption column, is configured as an indirect heat exchanger and is traversed by a coolant (1). According to said method, the coolant enters at the bottom of the condenser (1) and flows upwards through conduits (8) that are arranged vertically in the condenser. The coolant is enriched with hydrogen sulphide prior to its entry into the condenser (1) and after the absorption of heat, escapes as an overflow (6) from the top of the condenser (1) through upper openings (10) of the conduits (8). The invention also relates to a desorption column (2) for carrying out said method.

Abstract: With the help of a method of selective removal of hydrogen sulphides, organic sulphur components and CO2 from crude gases, by using a first and second absorption stage (41 or 49) for separating almost pure CO2, a solution has to be found, with which, among other things, hydrogen sulphides and organic sulphur compounds can be removed in as selective a manner as possible. This is achieved as follows: the absorption agent coming out of the first absorption stage (41) and enriched with hydrogen sulphide and CO2 a.o.

Abstract: The invention relates to a gas burner for burning fuel gases with oxygen, said gas burner comprising a primary gas nozzle (6) and secondary gas nozzles (5) which are connected to a common central feed line (3). In this case, the non-horizontal openings (8), directed obliquely downwards, of the primary gas nozzle are oriented in such a way that the gas jet of said primary gas nozzle is directed towards a point of a centre line (10) between two respective secondary gas nozzles, and the centre line is defined as an imaginary line which runs parallel to the rotation axis of the primary gas nozzle and centrally between two adjacent secondary gas nozzles.

Abstract: The invention refers to a process for the production of high-purity 1,2-dichloroethane from dissolved chlorine and dissolved ethylene, which are brought into contact with each other in a circulating liquid reaction fluid, which mainly consists of 1,2-dichlorethane and a catalyst and flows through at least one vertically arranged loop-type reaction section, both legs of the loop being connected to an overhead degassing vessel from where the reaction product is withdrawn either in gaseous or in liquid state or in both gaseous and liquid state, and numerous admixing sections being arranged in the leg of the loop in which the liquid rises, and each of these admixing sections having one upstream feed point for dissolved or gaseous ethylene and one downstream feed point for dissolved chlorine and, if required, the admixing sections featuring static mixers.

Abstract: The invention relates to a gas cooling device for coke-oven gas containing condensing constituents. Said device comprises a gas conduit (6), through which the coke-oven gas flows, heat exchanger elements in said gas conduit that are traversed by a coolant and a spray device (2) located above the heat exchanger elements, the surface of the heat exchanger elements that faces the gas being wet by a liquid that is fed through the spray device (2). According to the invention, the heat exchanger elements (5) are configured as cooling plates (5), through which the coolant can flow and are combined with channel-forming spacers (7) to form at least one heat exchanger stack. The heat exchanger stacks are located in the gas conduit (6) with a vertical alignment of their cooling plates (5), the gas channels formed by the spacers (7) being sprayed from above by the liquid that emanates from the spray device (2) and being traversed by the coke-oven gas.

Abstract: Device for burning coking gas in a coking chamber of a coke oven of the “non-recovery type” or “heat-recovery type”, a multiplicity of inlet openings for primary air being arranged in the roof of each oven chamber in such a way that the coking gas produced during the coking is brought into uniform contact with the desired quantity of primary air for the partial combustion of the coking gas, these inlet openings for primary air being combined above the oven for each chamber separately by an air feed system, the air feed systems of the individual oven chambers being connected to an air feed system common to many oven chambers, and a respective control member for varying the primary air quantity over the carbonizing time being provided between the common air feed system and the air feeds of the individual oven chambers. A slight, constant positive pressure can be applied to the common air feed system.

Abstract: A synthesis furnace has a furnace chamber surrounded by a circumferential furnace wall, in which burners are disposed essentially in one plane, with burner exit direction directed downward, and reaction tubes are disposed essentially vertically and parallel to one another. The reaction tubes are heated externally by the ignited burners. To improve the heat distribution and the entire heat transfer in as simple a manner as possible, in terms of design and control technology, at least the outer burners disposed in the vicinity of the furnace wall have a burner exit direction that runs at an incline away from the center of the furnace in relation to the vertical.

Abstract: The invention relates to the use of a liquid, containing 0.1 to 100% of an amine or several amines of formula H2N—CH2(CHR2)x—(OCH2(CHR3)y)z—OR1, where R1?C1 to C6 alkyl, R2?H or CH3, R3?H or CH3, x=0 to 3, y=0 to 3, z=0 to 10 and 0 to 99.9% of any further solvent including piperazine and/or water for separating acid gas components from technical gases.

Abstract: With a method or a device for producing 1,2-dichloroethane or ethylene (di)chloride (EDC) with the use of a circulating reaction medium and a catalyst, whereby ethylene and chlorine are supplied to the reaction medium, the catalytic chlorination of ethylene is achieved in a manner that is particularly gentle to the product by introducing the ethylene or chlorine gas into the reaction medium via microporous gas diffuser elements for producing gas bubbles with a diameter of 0.3 to 3 mm.

Abstract: A process is described for reducing the NOx concentration and N2O concentration from the residual gas from nitric acid production. The process encompasses the passing of the residual gas leaving the absorption column, prior to entry into the residual gas turbine, through a combination of two stages. The first stage here reduces the NOx content and the second stage the N2O content of the gas, the NOx/N2O ratio prior to entry of the gas into the second stage being in the range from 0.001 to 0.5, and this gas being brought into contact in the second stage with a catalyst which is substantially composed of one or more iron-loaded zeolites.

Abstract: The invention relates to a method for recovering absorbed hydrocarbon components while absorbing acid gases from technical gases, as for example a natural gas, by means of physically active absorption agents, wherein the inventive method consists in increasing the pressure of a loaded absorption agent extracted from an adsorption device, in adding said loaded absorption agent to the top of a rectification column which consist of a lower feeding stove and of one or several lateral stoves operating at a pressure slightly greater than the absorption column pressure, in adjusting an equilibrium is said rectification column in such a way that the acid gas concentration in the absorbent agent increases in the direction away from the bottom of the column and the hydrocarbon concentration decreases in said direction, in extracting a heated hydrocarbon-poor and acid gas component-rich absorption agent from the bottom of the column and in transferring said agent to an acid gas desorption device, in extracting a hydroca

Abstract: A process for reactions with or to form peroxidic compounds in a wall reactor whose reaction space has a specific material coating is described. Both higher space-time yields and increased selectivities can be achieved by means of the process.

Abstract: The invention relates to a method for the production of a gas diffusion electrode from a silver catalyst on a PTFE-substrate. The pore system of the silver catalyst is filled with a moistening filling agent. A dimensionally stable solid body having a particle size greater than the particle size of the silver catalyst is mixed with the silver catalyst. Said compression-stable mass is formed in a first calendar in order to form a homogenous catalyst band. In a second calendar, an electroconductive discharge material is embossed in the catalyst band, and heating takes places between the first and the second calendar by means of a heating device, wherein at least parts of the moistened filling agent are eliminated. The invention also relates to a gas diffusion electrode which is produced according to said method.

Abstract: Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.

Abstract: The invention relates to a method for producing electrically conducting nickel oxide surfaces made of nickel-containing material. According to said method, the nickel surface is first degreased and is then roughened for approximately ten minutes in a solution containing about one percent of hydrochloric acid, said process being accelerated by adding hydrogen peroxide solution, resulting in the electrolyte turning green. The nickel surface is briefly wetted, the nickel material is introduced into a solution of 3.5 molar lye to which about ten percent of hydrogen peroxide is added and is kept therein for ten minutes, and the resulting nickel hydroxide surface is dehydrated in a subsequent thermal process and is then further oxidized to obtain nickel oxide. The invention further relates to a conductive boundary layer that is produced according to said method, the electrodes therefrom, and the use thereof in chlorine-alkali electrolysis processes, in fuel cells and storage batteries.

Abstract: Composites comprising at least one hollow fibre of oxygen-transporting ceramic material, which is a ceramic material which conducts oxygen anions and electrons or a combination of ceramic material which conducts oxygen anions and a ceramic or nonceramic material which conducts electrons, with the outer surface of the hollow fibre being in contact with the outer surface of the same hollow fibre or another hollow fibre and the contact points being joined by sintering, are described. Further composites comprise at least one hollow fibre of oxygen-transporting ceramic material which is a ceramic material which conducts oxygen anions and electrons or a combination of ceramic material which conducts oxygen anions and ceramic or nonceramic material which conducts electrons and a connection element for the introduction or discharge of fluids at at least one end face, with hollow fibres and connection element being joined.

Abstract: Device for injecting electromagnetic radiation into a reactor and a reactor comprising this device A device for injecting electromagnetic radiation into a reactor for carrying out free-radical gas-phase reactions and a reactor comprising such a device are described. This comprises the elements: a) a compartment which is separated from the reaction space of the reactor and is b) connected to the reaction space of the reactor via at least one opening, c) at least one feed line for introducing a flushing gas into the compartment, and also d) at least one source of electromagnetic radiation which is arranged so that e) the electromagnetic radiation passes through the compartment and the reaction space of the reactor adjoining the compartment. The device and reactor make an increase in the yield of free-radical chain reactions possible.

Abstract: The method comprises passing an N2O- and NOx-containing gas over a sequence of two catalyst beds, adding reducing agents for NOx and for N2O between the catalyst beds in such an amount that not only NOx but also a predetermined proportion of N2O is reduced. The reaction conditions are set so that the N2O content of the gas is reduced by not more than 95%, based on the N2O content at the entrance of the first catalyst bed, by decomposition to nitrogen and oxygen in the first catalyst bed and that not only chemical reduction of NOx but also chemical reduction of N2O occurs in the second catalyst bed so that the N2O content of the gas is reduced by at least 50%, based on the N2O content at the entrance of the second catalyst bed.

Abstract: A process for reducing the content of NOx and N2O in gases, in particular in process gases and offgases, which comprises the measures: a) addition of at least one nitrogen-containing reducing agent to the NOx- and N2O-containing gas in at least the amount required for complete reduction of the NOx; b) addition of a hydrocarbon, of carbon monoxide, of hydrogen, or of a mixture of one or more of these gases to the NOx- and N2O-containing gas for the reduction of the N2O; and c) introduction of the gas mixture into at least one reaction zone at temperatures of up to 450° C., which contains one or more iron-laden zeolites. The process can be used, in particular, in nitric acid production, for offgases from power stations or for gas turbines.

Abstract: A process and device are disclosed for producing horizontally tamped coal cakes for coking in the oven chamber of a coking oven, the coal cakes being formed in a compression mould by stationary compression tools which work in the horizontal direction and with a stroke having a strictly limited length. The compression mould has a sliding stop wall which is moved away from the compression tools as the coal cake grows, under the effect of a suitable antagonistic braking force.