ADVANCED INTERCONNECT WITH AIR GAP
Ultra-low-k dielectric materials used as inter-layer dielectrics in high-performance integrated circuits are prone to be structurally unstable. The Young's modulus of such materials is decreased, resulting in porosity, poor film strength, cracking, and voids. An alternative dual damascene interconnect structure incorporates air gaps into a high modulus dielectric material to maintain structural stability while reducing capacitance between adjacent nanowires. Incorporation of an air gap having k=1.0 compensates for the use of a higher modulus film having a dielectric constant greater than the typical ultra-low-k (ULK) dielectric value of about 2.2. The higher modulus film containing the air gap is used as an insulator between adjacent metal lines, while a ULK film is retained to insulate vias. The dielectric layer between two adjacent metal lines thus forms a ULK/high-modulus dielectric bi-layer.
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1. Technical Field
The present disclosure relates to the fabrication of nanowires for interconnecting integrated circuits and, in particular, to improvements in performance and reliability of inter-layer dielectrics used in a dual damascene process.
2. Description of the Related Art
There has been widespread use of damascene interconnect structures in microcircuit fabrication since the late 1990s when the semiconductor industry shifted from aluminum to copper metallization. A damascene interconnect process forms inlaid copper wiring by first etching trenches in a dielectric material, and then filling the trenches with copper, typically using a plating process such as, for example, electroplating. Through the use of a damascene process, semiconductor manufacturers can avoid etching copper. The term “dual damascene” refers to a process in which vertically adjacent metal lines and vias connecting them are formed in the same dielectric layer.
Current trends in the fabrication of dual damascene interconnect structures for integrated circuits include investigating mechanical properties of low dielectric constant (low-k) and ultra-low-k (ULK) dielectric materials used as insulation between the metal lines and the vias. Generally, it is desirable to use electrically insulating material that has a low dielectric constant, to reduce capacitance between adjacent nanowires. However, as the dielectric constant of such materials is reduced below a value of about 2.4 to achieve better electrical performance, the dielectric materials are becoming become more porous, with problematic consequences, as described below.
Illustrations of damascene structures that employ ULK inter-layer dielectrics as shown in
Another problem that tends to occur after etching ULK films is referred to as “dielectric flopover,” in which high aspect ratio structures 96 have been found to be unstable and tend to lean sideways as shown in
An advanced damascene interconnect structure for microelectronic circuits incorporates a plurality of air gaps into a high modulus insulator to reduce capacitance between adjacent nanowires while maintaining structural stability. The nanowires are formed by an array of metal lines positioned among insulating columns. The embodiments presented herein are characterized by the inclusion of a high modulus insulator above a dielectric layer, and a high aspect ratio film inlaid within the high modulus insulator, sealing the air gaps. Related embodiments by the present inventors are disclosed in U.S. patent application Ser. No. 13/731,878, filed on Dec. 31, 2012.
The dielectric constant of air is 1.0, significantly lower than that of any solid material used in semiconductor fabrication. Thus, incorporation of an air gap in a layer compensates for the use of a higher modulus insulator film having a dielectric constant greater than the typical ULK value of about 2.2, such that the resulting interconnect structure has an effective dielectric constant less than 2.0. In the embodiments presented herein, the higher modulus film containing the air gap is used as an insulator between metal-filled trenches, for example, at the same level as metal 3 or metal 4 while the ULK film is retained to insulate vias. The dielectric layer between two adjacent metal lines might include both a ULK and a high-modulus dielectric having air gaps, thus forming a bi-layer.
In one embodiment, a fabrication method to form such an advanced damascene interconnect structure includes patterning freestanding dielectric U-shaped structures having a selected width-to-spacing ratio, creating air gaps within the freestanding U-shaped structures, and creating metal trench/via columns between the U-shaped structures. Patterning the freestanding dielectric U-shaped structures can be done via a sidewall image transfer technique.
In the drawings, identical reference numbers identify similar elements. The sizes and relative positions of elements in the drawings are not necessarily drawn to scale.
In the following description, certain specific details are set forth in order to provide a thorough understanding of various aspects of the disclosed subject matter. However, the disclosed subject matter may be practiced without these specific details. In some instances, well-known structures and methods of semiconductor processing comprising embodiments of the subject matter disclosed herein have not been described in detail to avoid obscuring the descriptions of other aspects of the present disclosure.
Unless the context requires otherwise, throughout the specification and claims that follow, the word “comprise” and variations thereof, such as “comprises” and “comprising” are to be construed in an open, inclusive sense, that is, as “including, but not limited to.”
Reference throughout the specification to “one embodiment” or “an embodiment” means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment. Thus, the appearance of the phrases “in one embodiment” or “in an embodiment” in various places throughout the specification are not necessarily all referring to the same aspect. Furthermore, the particular features, structures, or characteristics may be combined in any suitable manner in one or more aspects of the present disclosure.
Fabrication of microcircuits generally entails performing a series of deposition and patterning operations to build integrated structures on a semiconductor substrate, one layer at a time. Each layer is formed by growing or depositing a film on the substrate, patterning a photo-sensitive mask using lithography, and transferring the mask pattern to the film by etching. Often, structures already formed on the substrate are protected by hard masks while new structures are created. Such use of hard masks adds masking layers to the fabrication process. Overall fabrication costs scale with the number of layers used and the number of mask patterning cycles needed. Lithography masks are expensive to design and to integrate into an existing fabrication process. For these reasons, it is generally advantageous to reduce the number of mask patterning cycles if alternative processing schemes can be substituted.
Reference throughout the specification to integrated circuits is generally intended to include integrated circuit components built on semiconducting substrates, whether or not the components are coupled together into a circuit or able to be interconnected. Throughout the specification, the term “layer” is used in its broadest sense to include a thin film, a cap, or the like.
Reference throughout the specification to conventional thin film deposition techniques for depositing silicon nitride, silicon dioxide, metals, or similar materials include such processes as chemical vapor deposition (CVD), low-pressure chemical vapor deposition (LPCVD), metal organic chemical vapor deposition (MOCVD), plasma-enhanced chemical vapor deposition (PECVD), plasma vapor deposition (PVD), atomic layer deposition (ALD), molecular beam epitaxy (MBE), electroplating, electro-less plating, and the like. Specific embodiments are described herein with reference to examples of such processes. However, the present disclosure and the reference to certain deposition techniques should not be limited to those described. For example, in some circumstances, a description that references CVD may alternatively be done using PVD, or a description that specifies electroplating may alternatively be accomplished using electro-less plating. Furthermore, reference to conventional techniques of thin film formation may include growing a film in-situ. For example, in some embodiments, controlled growth of an oxide to a desired thickness can be achieved by exposing a silicon surface to oxygen gas or to moisture in a heated chamber.
Reference throughout the specification to conventional photolithography techniques, known in the art of semiconductor fabrication for patterning various thin films, includes a spin-expose-develop process sequence typically followed by an etch process. Alternatively or additionally, photoresist can also be used to pattern a hard mask such as a silicon nitride hard mask, which, in turn, can be used to pattern an underlying film.
Reference throughout the specification to conventional etching techniques known in the art of semiconductor fabrication for selective removal of polysilicon, silicon nitride, silicon dioxide, metals, photoresist, polyimide, or similar materials includes such processes as wet chemical etching, reactive ion etching (RIE), washing, wet cleaning, pre-cleaning, spray cleaning, chemical-mechanical planarization (CMP) and the like. Specific embodiments are described herein with reference to examples of such processes. However, the present disclosure and the reference to certain deposition techniques should not be limited to those described. In some instances, two such techniques may be interchangeable. For example, stripping photoresist may entail immersing a sample in a wet chemical bath or, alternatively, spraying wet chemicals directly onto the sample.
Specific embodiments are described herein with reference to planarized metal interconnect structures and photonic structures that have been produced; however, the present disclosure and the reference to certain materials, dimensions, and the details and ordering of processing steps are exemplary and should not be limited to those shown. The terms “planarize” and “polish” are used synonymously throughout the specification.
In the figures, identical reference numbers identify similar features or elements. The sizes and relative positions of the features in the figures are not necessarily drawn to scale.
At 112, a high-modulus insulator is patterned to form trenches of width D1 and, in one embodiment, freestanding dielectric U-shaped structures. The freestanding dielectric U-shaped structures preferably have an aspect ratio of at least 4:1. They are thus high aspect ratio structures. The regions inside the U-shaped structures will contain an air gap and be sealed with dielectric material, while the regions between the U-shaped structures will later be filled with metal. A ratio of trench width to inter-layer dielectric width might satisfy a golden ratio as explained later herein.
At 114, air gaps are created within the dielectric U-shaped structures. In one embodiment, the air gaps will be tapered, while in other embodiments, the air gaps will be generally rectangular with a sealing cap on top.
At 116, metal fills the trenches to create metal lines on top of conductive vias in the dielectric layer, between the U-shaped structures.
Details of the fabrication method 110 are presented below, with reference to
The freestanding dielectric U-shaped structures shown in
At 122, a dielectric layer 121 is deposited on top of the substrate 123. The dielectric layer 121 can be any layer in which vias can be formed during the semiconductor manufacturing process. In one embodiment, the dielectric layer 121 is a thick inter-metal dielectric layer such as a low-k or ultra-low-k (ULK) dielectric, wherein k represents a dielectric constant that characterizes the dielectric material. In the embodiment shown, the ULK dielectric layer 121 desirably has a dielectric constant less than about 2.0 and a thickness target that determines the via height, for example, in the range of about 100-200 nm. Such an inter-metal dielectric layer may be located between metals 1 and 2, metals 3 and 4, or other metal interconnect layers, for example.
At 124, a high modulus insulator 125 is formed above the ULK dielectric layer 121. The high modulus insulator 125 can be made of, for example, a silicon nitride (SiN), silicon carbide (SiC), or silicon carbide-nitride SiCxNy. It can generally be a ULK dielectric, although known ULK dielectric materials lack sufficient strength to be considered high modulus insulators. Trenches for metal interconnect layers will later be formed in the high modulus insulator 125 to be filled with metal. The thickness target of the high modulus insulator 125 is in the range of about 200-400 nm.
At 126, a hard mask layer 127 is deposited on top of the high modulus insulator 125. In one embodiment, the hard mask layer 127 is made of metal to permit etching the very thick underlying high-modulus insulator 125.
At 128, the hard mask layer 127 is patterned to form a hard mask 129. Patterning the hard mask layer 127 can be accomplished using a sidewall image transfer method, as described in a related patent application, U.S. patent application Ser. No. ______, entitled “Novel method for Asymmetric Pitch Adjustment with Sidewall Image Transfer,” hereby incorporated by reference in its entirety. In the sidewall image transfer method, a sloped mandrel and a sidewall blocking mask are used to open an array of large openings having a width D1, and an array of smaller openings having a width D2, respectively, in the hard mask layer 127. The large opening D1 defines the width of metal lines which include both trenches and vias. In one embodiment, the trenches are positioned directly above the vias, and both the trenches and vias have width D1. In other embodiments, the trench can have a large width D1 and the via a smaller width D3. The small opening D2 defines the width of a dielectric bi-layer trench that will include an air gap to electrically insulate adjacent metal lines from one another. In one embodiment, a target width-to-spacing ratio of D2/D1 is set at 0.618, which is a golden ratio that yields a preferred opening distribution and relationship. The hard mask 129 can now be used to pattern the underlying high-modulus insulator 125.
At 130, the high-modulus insulator 125 is etched to form freestanding U-shaped structures 131. In one embodiment, the U-shaped structures 131 are spaced so as to have a 64-nm pitch. The etch process used is a plasma-based reactive ion etch that first removes the high modulus insulator 125 to form trenches 133 having width D1, and then removes the ULK dielectric layer 121 to form vias 135 directly underneath the trenches 133, the vias 135 also having width D1. The depth of the trenches can be approximately the same as the vias or might be up to twice the depth of the vias. While the trenches 133 and vias 135 are being etched, the high modulus insulator 125 between the trenches 133 is also etched to form the U-shaped structures 131, with the etched recesses having a width D2. Because less etchant reaches the material within recesses 137 having a small width D2, the U-shaped structures 131 etch more slowly, compared to the regions 133 and 135 separating the U-shaped structures 131. As a result, etching of the recesses 137 will usually stop before reaching the ULK dielectric layer 121, at a recess depth of about 40 nm. Whereas, etching of the trenches 133 and vias 135 between the U-shaped structures 131 continues through the entire ULK dielectric layer 121, into the substrate 123. If the substrate 123 is a thin silicon carbide-nitride SiCxNy layer, the exposed layer of the substrate 123 may be removed, leaving behind U-shaped structures 131 as shown in
The metal, when deposited into the via opening 135, will therefore be in contact with the metal layer that is below the top layer of the substrate 123. For example, if the metal layer being deposited into the trenches 133 is metal 4, then etching away the layer 123 will permit the filled via to couple the underlying metal 3 to metal 4 at those particular locations, but the two metal layers will remain electrically isolated at those locations where vias 135 are not formed.
Generally, the ULK dielectric layer 121 and the high modulus insulator 125 will be made of multiple sublayers. For example, it would be common to make ULK dielectric layer 121 having a first base layer of a type of silicon nitride on top of which is formed a nanopores or aerogel layer that includes some form of silicon dioxide or other layer. There may be two or three types of ULK dielectrics on top of each other within the main ULK dielectric layer 121. Similarly, the high modulus insulator 125 may have two or more sublayers making up the entire layer. For example, one of the sublayers may be a relatively strong layer having silicon, carbon, and nitrogen therein. It may also be a relatively strong layer having just silicon and carbon therein. Other sublayers of the high modulus insulator 125 may include silicon dioxide, silicon nitride, a ULK layer of any one of the many acceptable ULK materials or many other sublayers. In one embodiment, it is preferred to ensure that the high modulus insulator 125 has more mechanical strength than the ULK dielectric layer 121 to ensure that the air gaps to be formed at the regions D2 will be supported by structure and will not collapse. Even though the high modulus insulator 125 may be mechanically stronger, it may have a similar dielectric constant to that of the material used in the ULK dielectric layer 121 and, once the air gaps are formed, it may have a similar or even lower dielectric constant overall as a layer than that of the ULK dielectric layer 121.
At 132, the hard mask 129 is removed, using an anisotropic RIE process that can remove metal without attacking the underlying SiN or SiCxNy layers or other materials that might be part of the high modulus insulator 125 or the ULK dielectric layer 121.
At 134, the recesses 137 of the U-shaped structures 131 are capped with a layer 139. The capping layer 139 will cap each U-shaped structure so as to include an air gap 141, thus forming a plurality of air gaps 141 that extend vertically within the recesses 137. The capping layer 139 is desirably capable of capping the recesses 137 so as to close the small openings of size D2. In one embodiment, such a capping layer 139 includes a filler material made of SiC. The dimension D2 is selected in conjunction with the conformal film which is to form the capping layer 139. In one embodiment, the capping layer 139 is a conformal layer which conforms generally to the interior of the U-shaped structure 131 having a gap distance D2 and as it conformally fills the trench the top portion will touch and create a cap after which further filling of the trench is blocked, resulting in air gaps 141. Alternatively, the distance to the air gap D2 may be relatively small compared with the coverage capabilities of the capping layer 139 resulting in the cap being formed almost immediately upon the deposition starting so that little to no material from the capping layer 139 enters the U-shaped structure 131. Therefore, the top of the U-shaped structure 131 will be essentially capped and maintain nearly the same open area as when it was originally etched. There may be some small amount of capping layer material 139 deposited on the very bottom of the U-shaped structure 131 with little deposited on the sides before the layer caps the top of the U-shaped structure 131, thus sealing it off against further deposition of material. For layers which are very conformal, the distance D2 may be somewhat smaller in order to ensure that a cap is formed to seal it off prior to completely filling the U-shaped structure 131 to ensure that the air gap 141 remains. On the other hand, if the capping layer 139 is not very conformal and tends to deposit more heavily at the corners and on the top, it may be permitted to have D2 be a somewhat larger dimension and still be assured that the top will cap off while still leaving an air gap 141 inside of the U-shaped structure 131. Accordingly, the dimension D2 is selected to ensure that adjacent capping layers 139 will touch each other at the top opening of the U-shaped structures 131 to seal off the top and form a sealing cap before the central portion of the region is fully formed to ensure that the air gap 141 remains. As previously mentioned, in some embodiments the selection of the width D2 together with the material used for the capping layer 139 will result in a cap being formed at the top portion of the trench 131 with little to no material of the capping layer 139 in the trench, thus maintaining a larger air gap and a correspondingly smaller dielectric constant. Since the dielectric constant of the air is 1.0 and it is substantially smaller than that of any other material, it is desired to have the air gap as large as practical within the constraints of the materials used and to provide sufficient structural integrity for the high modulus layer 125 after the metal is deposited therein. In one embodiment, the material for the capping layer 139 is silicon carbide which has a high physical strength and can be adjusted to be deposited to be ensured that it will build up at the top of the U-shaped structure 131 to create a cap that seals off the U-shaped structure 131 when the U-shaped structure 131 is only partially filled with the capping layer 139, thus ensuring that the air gap 141 will be present. By custom selection of the width D2 and the deposition properties of the SiC, a relatively large air gap 141 can be obtained, in some instances nearly the entire dimension of the original volume of the U-shaped structure 131.
At 136, further deposition of the high aspect ratio film as the capping layer 139 closes the small recesses 137 of width D2. In the embodiment shown, the capping layer 139 also serves as an encapsulant 143, lining sidewalls of the shallow trenches that will be filled with metal. The encapsulant 143 also lines the bottoms of the vias 135 temporarily, as shown in
In one preferred embodiment, the capping film 139 is preferably a high aspect ratio film that enters into the recess 137 which has been etched, even though the recess 137 is a narrow aperture. The benefit of having a high aspect ratio film 139 is that it fills the interior of the recess 137 as well as providing the encapsulant 143 that lines the outside surfaces of the U-Shaped structures 131 with a narrow layer, thus reinforcing the mechanical strength of the walls 144 of the U-shaped structures 131. Preferably, each wall 144 has sufficient strength that it is both self-supporting and will not collapse or be crushed under the weight of additional layers which will be deposited on top of it during subsequent steps in the semiconductor process. In some process technologies, the recess 137 will be sufficiently large and the walls 144 sufficiently small that they do not have sufficient mechanical strength to support the layers which will be deposited on the top of them during subsequent semiconductor processing steps. Accordingly, the high aspect ratio film 139 is selected as a reinforcing material. In one example, silicon carbide (SiC) is selected as the reinforcing material, because SiC has high mechanical strength and yet it can be deposited as a thin layer with a high aspect ratio. Thus, a thin film encapsulant layer 143 is provided on each side of each wall 144, providing sufficient mechanical strength and reinforcement that when subsequent layers are deposited on top of the U-shaped structure 131 it can support this weight and not be crushed even though there is an air gap present within the U-shaped structure 131. Accordingly, the air gap 141 formed during deposition of the high aspect ratio film 139 is maintained with sufficient structural integrity because both the wall 144 and the high aspect ratio film 139 act together to provide sufficient mechanical strength so that air gap 141 may remain and yet the layer overall has sufficient strength that it does not collapse after subsequent layers are put on the top thereof during further semiconductor processing steps until the chip is completed.
The result shown in
At 138, a conformal metal liner 145 is deposited over the array of U-shaped structures 131. In those vias 135 in which contact to a lower metal layer is desired, the capping layer 139 will generally be etched from the bottom of the via in order to ensure that the metal liner 145 contacts the metal layer below. Such etching can occur during deposition of the conformal metal liner 145 by using ion bombardment to remove, anisotropically, the thin layer of encapsulant 143 at the bottom of the vias 135, while leaving the encapsulant 143 in place on the sidewalls of the trenches 133 and vias 135. The metal liner 145 thus establishes a conductive path between a metal layer below the substrate 123, if applicable, and the current metal layer. In the example of
The metal liner 145 forms a barrier, laterally, between the encapsulant 143 and the conducting trench fill material to be deposited next. In one embodiment, the conformal metal liner 145 can include two layers, for example, a bottom layer made of titanium nitride (TiN) that adheres well to the encapsulant 143, and a top layer made of tantalum nitride (TaN) that provides a barrier to subsequent deposition of a copper interconnect layer. Such a two-layer conformal metal liner 145 can have a representative total thickness of 8-10 nm. In other embodiments, the conformal metal liner 145 can be a single layer, for example, TaN, having a thickness of less than 8 nm.
At 140, the vias 135, and subsequently the trenches 133, are filled with a bulk metal 147. The bulk metal trench fill material in the embodiment shown is desirably a metal suitable for use as a nanowire interconnect material. Such bulk metals include, for example, copper, aluminum, tungsten, silver, gold, titanium, platinum, tantalum, or combinations thereof. Combinations of such metals include layered metal stacks or alloys. The bulk metal trench fill process can be a plasma deposition such as chemical vapor deposition (CVD) or plasma vapor deposition (PVD). Alternatively, the bulk metal trench fill process can be a plating process such as electroplating or electro-less plating. In one embodiment, a plating process is used that includes depositing a copper seed layer followed by a bulk copper layer. The metal fill process is preferably conformal. Because the metal CD has a large width D1, there should not be a gap fill problem.
At 142, the bulk metal 147 and the conformal metal liner 145 that remains on top of the U-shaped structures 131 are polished to stop on the high aspect ratio film 139. The CMP process used for polishing the bulk metal 147 can entail use of a slurry made from silica and hydrogen peroxide (H2O2), and a soft polish pad, for example. The CMP process can be timed based on a known polishing rate of the bulk metal and the metal liner materials. Or, the CMP process can be end-pointed to stop upon detection that the underlying high aspect ratio film 139 layer has been exposed. Additionally or alternatively, a touch CMP process can further be performed to gently remove remnants of the surplus bulk metal 147 and the thin conformal metal liner 145. The touch CMP process can be a brief surface polish in which the polish pad rotation speed and pressure are set to relatively low values to remove residual amounts of material while limiting the degree of surface abrasion. Alternatively, a touch clean can be substituted for the touch CMP process. The touch clean can use, for example, a wet clean chemistry that includes hydrofluoric acid (HF) diluted with de-ionized water (DI) in a 1000:1 ratio (DI:HF). Additionally or alternatively, the CMP process used for polishing the conformal metal liner 145 can entail use of a chemical formula that removes metal selective to the high aspect ratio film 139.
A final interconnect structure 150 shown in
Additional embodiments 250a and 250b are presented in
The interconnect structure 250a differs from the interconnect structure 150 in several respects. First, 250a includes various configurations of U-shaped structures among trenches to demonstrate that, depending on the local mask design, the U-shaped structures can alternate with the trenches 233 as shown in
The exemplary final interconnect structure 250b has features in common with the interconnect structure 250a but exhibits a regular alternating pattern of air gaps between adjacent metal lines. One advantage of the final interconnect structure 250b is that the bulk metal 147 is fully encapsulated by the high modulus insulator 125 for further protection against electromigration effects. One disadvantage is that there is a smaller volume of air trapped within the shorter air gap 241 than within the taller air gap 141.
A hybrid embodiment 350 that combines aspects of the interconnect structure 150 and the interconnect structures 250a and 250b is illustrated in
In summary, after the structure of
The various embodiments described above can be combined to provide further embodiments. All of the U.S. patents, U.S. patent application publications, U.S. patent applications, foreign patents, foreign patent applications and non-patent publications referred to in this specification and/or listed in the Application Data Sheet are incorporated herein by reference, in their entirety. Aspects of the embodiments can be modified, if necessary to employ concepts of the various patents, applications and publications to provide yet further embodiments.
It will be appreciated that, although specific embodiments of the present disclosure are described herein for purposes of illustration, various modifications may be made without departing from the spirit and scope of the present disclosure. Accordingly, the present disclosure is not limited except as by the appended claims.
These and other changes can be made to the embodiments in light of the above-detailed description. In general, in the following claims, the terms used should not be construed to limit the claims to the specific embodiments disclosed in the specification and the claims, but should be construed to include all possible embodiments along with the full scope of equivalents to which such claims are entitled. Accordingly, the claims are not limited by the disclosure.
1. An interconnect structure on a semiconductor substrate, the interconnect structure comprising:
- a dielectric layer;
- an insulating material above the dielectric layer;
- an array of metal lines formed in the insulating material; and
- a plurality of air gaps positioned among the metal lines of the array, the air gaps being sealed by a capping film.
2. The interconnect structure of claim 1 wherein the semiconductor substrate contains electronic devices.
3. The interconnect structure of claim 1 wherein the dielectric layer is an ultra-low-k dielectric layer having a dielectric constant less than 2.0.
4. The interconnect structure of claim 1 wherein the insulator is a high modulus insulator having a dielectric constant in the range of about 3.5-4.5.
5. The interconnect structure of claim 4 wherein an effective dielectric constant of the high modulus insulator integrated with the capping film sealing the plurality of air gaps is less than about 2.0.
6. The interconnect structure of claim 4 wherein the high modulus insulator includes one or more of SiN, SiC, or SiCxNy.
7. The interconnect structure of claim 4 further comprising an encapsulation layer surrounding the metal lines.
8. The interconnect structure of claim 1 wherein the air gaps are tapered such that the top of each air gap is narrower than the bottom of the air gap.
9. The interconnect structure of claim 1 wherein the capping film is used as the encapsulating layer.
10. The interconnect structure of claim 1 wherein the metal lines are formed having a width-to-spacing ratio of 0.618.
11. The interconnect structure of claim 1, further comprising a base layer below the dielectric layer, the base layer made of SiCxNy.
12. The interconnect structure of claim 1 wherein the capping film is a high aspect ratio film that includes SiC.
13. A damascene interconnect structure comprising: an array of insulating columns among metal lines, each of the insulating columns having a tapered air gap extending vertically therein.
14. The interconnect structure of claim 13 wherein the insulating columns contain a high modulus material.
15. The interconnect structure of claim 13 wherein the insulating columns have an insulating column width and the metal lines have a metal line width, the metal line width being a certain percentage of the insulating column width, according to a golden ratio.
16. A method comprising:
- forming a dielectric layer on a semiconductor substrate;
- forming a high modulus insulator film on the dielectric layer;
- patterning the high modulus insulator film using a hard mask to form trenches and vias among insulating columns;
- conformally depositing a layer that forms air gaps within the insulating columns and encapsulates the trenches and vias; and
- filling the encapsulated trenches and vias with metal.
17. The method of claim 16 wherein patterning the high modulus insulator film using the hard mask forms an array of insulating columns that are freestanding.
18. The method of claim 16 wherein the air gaps are tapered and extend vertically within the insulating columns.
19. The method of claim 16 wherein filling the encapsulated trenches and vias with metal includes first depositing a conformal metal liner and then depositing a bulk metal.
20. The method of claim 16 wherein filling the encapsulated trenches and vias with metal forms metal lines directly above filled vias.
21. The method of claim 16 wherein patterning the high modulus insulator film uses a dual damascene process that includes first etching trenches followed by etching vias, stopping on the substrate, to create the array of freestanding insulating columns.
22. The method of claim 16 wherein patterning the high modulus insulator film uses a dual damascene process that includes first etching vias, stopping on the substrate, and then etching trenches to create the array of freestanding insulating columns.
23. The method of claim 16 wherein patterning the high modulus insulator film uses a dual damascene process in which trenches and vias are aligned and have approximately equal widths.
24. The method of claim 16 wherein patterning the high modulus insulator film uses a dual damascene process in which trenches and vias are formed such that the trenches are approximately twice as deep as the vias.
25. A method of fabricating an integrated circuit interconnect structure on a semiconductor substrate, the method comprising:
- patterning trenches and vias in a high modulus insulator;
- forming U-shaped structures containing tapered air gaps; and
- filling the trenches and vias to form metal lines and filled vias among the U-shaped structures.
26. The method of claim 25 wherein the patterning dielectric U-shaped structures uses a sidewall image transfer technique.
27. The method of claim 25 wherein the dielectric U-shaped structures have at least a 4:1 aspect ratio.
28. The method of claim 25 wherein at least some of the metal lines are aligned on top of filled vias to form metal interconnect structure elements having a substantially uniform width.
29. The method of claim 25 wherein the dielectric U-shaped structures are made of a bi-layer material that includes one or more of SiN, SiC, and SiCxNy on top of a ULK dielectric.
Filed: Dec 5, 2013
Publication Date: Jun 11, 2015
Applicants: International Business Machines Corporation (Armonk, NY), STMicroelectronics, Inc. (Coppell, TX)
Inventors: John H. Zhang (Altamont, NY), Yann Mignot (Slingerlands, NY), Lawrence A. Clevenger (LaGrangeville, NY), Carl Radens (LaGrangeville, NY), Richard Stephen Wise (Ridgefield, CT), Yiheng Xu (Hopewell Junction, NY), Yannick Loquet (Domene), Hsueh-Chung Chen (Cohoes, NY)
Application Number: 14/098,286