Scintillator panel and radiation image sensor
The surfaces of an amorphous carbon substrate of a scintillator panel have undergone sandblasting, and an Al film 1 serving as a reflecting film is formed on one surface, and a columnar scintillator for converting incident radiation into visible light is formed on the surface of the Al film.
Latest Hamamatsu Photonics K.K. Patents:
This is a Continuation-In-Part application of U.S. application Ser. No. 10/225,416 filed on Aug. 22, 2002, which issued on Feb. 1, 2005 as U.S. Pat. No. 6,849,336, which is a continuation application of Ser. No. 09/560,911 filed on Apr. 28, 2000, which issued on Mar. 11, 2003 as U.S. Pat. No. 6,531,225, which is a Continuation-In-Part application of International Patent application serial No. PCT/JP99/01911 filed on Apr. 9, 1999.
BACKGROUND OF THE INVENTION1. Field of the Invention
The present invention relates to a scintillator panel and radiation image sensor used for medical X-ray photography and the like.
2. Related Background Art
Conventionally, X-ray photosensitive films have been used for medical and industrial X-ray photography. However, radiation imaging systems using radiation detectors have come into widespread use owing to advantages in convenience and retention of photographic results. In such a radiation imaging system, pixel data based on 2D radiation is acquired as an electrical signal by the radiation detector, and the signal is processed by the processor and displayed on the monitor.
As a conventional, typical radiation detector, a radiation detector having a structure in which an image sensing element is stuck to a scintillator panel having a scintillator formed on a substrate made of aluminum, glass, molten quartz, or the like is available. In this radiation detector, the scintillator converts radiations incident from the substrate side into light, and the image sensing element detects the light (see Japanese Patent Publication No. 7-21560).
A radiation detector for medical purposes, especially for dental examination, uses low-energy X-rays. If, therefore, an aluminum substrate is used, quite a few X-ray components are absorbed by the substrate. In a radiation detector using low-energy X-rays, therefore, the substrate of the scintillator panel is required to have high radiation transmittance.
It is an object of the present invention to provide a scintillator panel which increases the optical output by using a substrate having high radiation transmittance for the scintillator panel, and a radiation image sensor using the scintillator panel.
SUMMARY OF THE INVENTIONA scintillator panel of the present invention is characterized by comprising a substrate made of carbon as a major constituent, a reflecting film formed on said substrate, a scintillator deposited on said reflecting film, a protective film covering said substrate and said scintillator.
According to this scintillator panel, since the substrate made of carbon as a major constituent has high radiation transmittance, the amount of radiation absorbed by the substrate can be decreased, and the amount of radiation reaching the scintillator can be increased.
A radiation image sensor according to the present invention is characterized by having an image sensing element placed to oppose the scintillator of the scintillator panel comprising a substrate made of carbon as a major constituent, a scintillator deposited on the substrate, and a protective film covering the scintillator.
According to this radiation image sensor, since the scintillator panel has the substrate made of carbon as a major constituent having high radiation transmittance, the amount of light reaching the image sensing element can be increased.
The present invention will be more fully understood from the detailed description given hereinbelow and the accompanying drawings, which are given by way of illustration only and are not to be considered as limiting the present invention.
Further scope of applicability of the present invention will become apparent from the detailed description given hereinafter. However, it should be understood that the detailed description and specific examples, while indicating preferred embodiments of the invention, are given by way of illustration only, since various changes and modifications within the spirit and scope of the invention will be apparent to those skilled in the art from this detailed description.
The first embodiment of the present invention will be described below with reference to
As shown in
As shown in
The steps in manufacturing the scintillator panel 1 will be described next with reference to
The Al film 12 serving as a reflecting film is then formed on one surface of the substrate 10 to a thickness of 100 nm by vacuum vapor deposition (see
CsI used to form this scintillator 14 has high hygroscopicity, and hence absorbs water vapor from the air and deliquesces if it is kept exposed to the air. In order to prevent this, the polyparaxylylene film 16 is formed by the CVD method. More specifically, the substrate 10 on which the scintillator 14 is formed is placed in a CVD apparatus, and the polyparaxylylene film 16 is formed to a thickness of 10 μm. With this process, the polyparaxylylene film 16 is formed on the entire surfaces of the scintillator 14 and substrate 10 (see
Note that the formation of the fine projections/recesses on the surfaces of the substrate 10 by sandblasting can improve the adhesion characteristics between the polyparaxylylene film 16 and the substrate 10, thus preventing peeling of the polyparaxylylene film 16.
The radiation image sensor 2 is manufactured by sticking the image sensing element (CCD) 18 to the distal end portion side of the scintillator 14 of the completed scintillator panel 1 such that the light-receiving portion opposes the distal end portion side (see
According to the radiation image sensor 2 of this embodiment, radiation incident from the substrate 10 side is converted into light by the scintillator 14 and detected by the image sensing element 18. In this case, since a-C substrate 10 has high radiation transmittance, the amount of radiation absorbed by the substrate 10 can be reduced. Hence, the amount of radiation reaching the scintillator 14 can be increased. In addition, since the Al film 12 as a reflecting film is formed, light incident on the light-receiving portion of the image sensing element 18 can be increased. This makes it possible to sharpen the image detected by the radiation image sensor.
The second embodiment of the present invention will be described next. Note that the same reference numerals denoting the parts of the scintillator panel l and radiation image sensor 2 as in the first embodiment denote the same parts in the second embodiment.
As shown in
The steps in manufacturing the scintillator panel 3 will be described next. First of all, sandblasting is performed on the surfaces of the rectangular or circular a-C substrate 10 (thickness: 1 mm) by using glass beads (#800), thereby forming fine projections/recesses on the surfaces of the substrate 10.
The Al film 12 serving as a reflecting film is then formed on one surface of the substrate 10 to a thickness of 100 nm by vacuum vapor deposition, and the LiF film 22 as a low-refractive-index member is formed on the Al film 12 to a thickness of 100 nm by vacuum vapor deposition. A Tl-doped columnar CsI crystal is grown on the surface of the LiF film 22 by vapor deposition to form the scintillator 14 having a thickness of 250 μm. The polyparaxylylene film 16 is formed to a thickness of 10 μm by the CVD method. With this process, the polyparaxylylene film 16 is formed on the entire surfaces of the scintillator 14 and substrate 10. Since the polyparaxylylene film 16 is formed on the surfaces of the substrate 10, the moisture-proof characteristics of the scintillator 14 can be improved. In addition, since the polyparaxylylene film 16 is formed on the entire surfaces of the substrate 10, the moisture-proof characteristics of the scintillator 14 can be further improved.
The radiation image sensor 4 is manufactured by sticking the image sensing element (CCD) 18 to the distal end portion of the scintillator 14 of the completed scintillator panel 3 such that the light-receiving portion opposes the distal end portion (see
According to the radiation image sensor 4 of this embodiment, radiation incident from the substrate 10 side is converted into light by the scintillator 14 and detected by the image sensing element 18. In this case, since a-C substrate 10 has high radiation transmittance, the amount of radiation absorbed by the substrate 10 can be reduced. Hence, the amount of radiation reaching the scintillator 14 can be increased. In addition, since the Al film 12 as a reflecting film and the LiF film 22 as a low-refractive-index member are formed, light incident on the light-receiving portion of the image sensing element 18 can be increased. This makes it possible to sharpen the image detected by the radiation image sensor.
As shown in
The third embodiment of the present invention will be described next. Note that the same reference numerals denoting the parts of the scintillator panels 1 and 3 and radiation image sensors 2 and 4 as in the first and second embodiments denote the same parts in the third embodiment.
As shown in
The steps in manufacturing the scintillator panel 5 will be described next. First of all, sandblasting is performed on the surfaces of the rectangular or circular a-C substrate 10 (thickness: 1 mm) by using glass beads (#800), thereby forming fine projections/recesses on the surfaces of the substrate 10.
The LiF film 22 as a low-refractive-index member is then formed on one surface of the substrate 10 to a thickness of 100 nm by vacuum vapor deposition. A Tl-doped columnar CsI crystal is grown on the surface of the LiF film 22 by vapor deposition to form the scintillator 14 having a thickness of 250 μm. The polyparaxylylene film 16 is formed to a thickness of 10 μm by the CVD method. With this process, the polyparaxylylene film 16 is formed on the entire surfaces of the scintillator 14 and substrate 10. Since the polyparaxylylene film 16 is formed on the surfaces of the substrate 10, the moisture-proof characteristics of the scintillator 14 can be improved. In addition, since the polyparaxylylene film 16 is formed on the entire surfaces of the substrate 10, the moisture-proof characteristics of the scintillator 14 can be further improved.
The radiation image sensor 6 is manufactured by sticking the image sensing element (CCD) 18 to the distal end portion side of the scintillator 14 of the completed scintillator panel 5 such that the light-receiving portion opposes the distal end portion side (see
According to the radiation image sensor 6 of this embodiment, radiation incident from the substrate 10 side is converted into light by the scintillator 14 and detected by the image sensing element 18. In this case, since a-C substrate 10 has high radiation transmittance, the amount of radiation absorbed by the substrate 10 can be reduced. Hence, the amount of radiation reaching the scintillator 14 can be increased. In addition, since the LiF film 22 is formed as a low-refractive-index member, light satisfying the total reflection condition is reflected by the interface between the scintillator 14 and the LiF film 22, and the amount of light incident on the light-receiving portion of the image sensing element 18 can be increased. This makes it possible to sharpen the image detected by the radiation image sensor.
As shown in
The fourth embodiment of the present invention will be described next. Note that the same reference numerals denoting the parts of the scintillator panel 1 and radiation image sensor 2 as in the first embodiment denote the same parts in the fourth embodiment.
A columnar scintillator 14 for converting incident radiation into visible light is formed on the other surface of this substrate. Note that Tl-doped CsT is used for the scintillator 14. The scintillator 14 is covered with a polyparaxylylene film 16, together with the substrate 10.
As shown in
The steps in manufacturing the scintillator panel 7 will be described next. First of all, sandblasting is performed on the surfaces of the rectangular or circular a-C substrate 10 (thickness: 1 mm) by using glass beads (#800), thereby forming fine projections/recesses on the surfaces of the substrate 10. In addition, the other surface of the substrate 10 is mirror-polished.
A TI-doped columnar CsI crystal is grown on the other surface of the substrate 10 by vapor deposition to form the scintillator 14 having a thickness of 250 μm. The polyparaxylylene film 16 is formed to a thickness of 10 μm by the CVD method. With this process, the polyparaxylylene film 16 is formed on the entire surfaces of the scintillator 14 and substrate 10. Since the polyparaxylylene film 16 is formed on the surfaces of the substrate 10, the moisture-proof characteristics of the scintillator 14 can be improved. In addition, since the polyparaxylylene film 16 is formed on the entire surfaces of the substrate 10, the moisture-proof characteristics of the scintillator 14 can be further improved.
The radiation image sensor 8 is manufactured by sticking the image sensing element (CCD) 18 to the distal end portion side of the scintillator 14 of the completed scintillator panel 7 such that the light-receiving portion opposes the distal end portion side (see
According to the radiation image sensor 8 of this embodiment, radiation incident from the substrate 10 side is converted into light by the scintillator 14 and detected by the image sensing element 18. In this case, since a-C substrate 10 has high radiation transmittance, the amount of radiation absorbed by the substrate 10 can be reduced. Hence, the amount of radiation reaching the scintillator 14 can be increased. This can increase the amount of light incident on the light-receiving portion of the image sensing element 18, thereby sharpening the image detected by the radiation image sensor 8.
As shown in
Next, the other modified scintillator panels will be explained. All modified scintillator panels explained below are characterized in the placement of the scintillator on the substrate. Hereinafter, modified scintillator panel will be illustrated with the states before covering the protective films.
When the scintillator 14 deposited on the substrate, the substrate 10 holds by a deposition holder 31 in deposition chamber 30. This deposition holder 31 has two cavity portion 31a and the substrate 10 is housed in this cavity portion 31a. Therefore, the scintillator 14 is not deposited on these two portion of the first surface 10a, these two portions remains exposed.
When the first surface 10a has 460 mm×460 mm area, the width of strip regions exposing the first surface 10a of the substrate 10 may be 2 mm.
When the scintillator 14 is deposited on the substrate 10, this strip region is used to hold the substrate 10 by the deposition holder in deposition chamber.
In each embodiment described above, the polyparaxylylene film 16 is formed on the entire surfaces of the substrate 10. However, the polyparaxylylene film 16 may be formed on a part of the surfaces of the substrate 10. For example, the polyparaxylylene film 16 may be formed on a part of the exposed surface of the substrate 10, having no scintillator thereon.
In each embodiment described above, the a-C substrate is used. However, a graphite substrate may be used. The graphite substrate has high radiation transmittance like the a-C substrate. In this case, therefore, the amount of radiation reaching the scintillator can be increased as in the case wherein the a-C substrate is used.
In the above embodiments, a LiF film is used as a thin transparent film. However, a film made of a material containing selected from the group consisting of LiF, MgF2, CaF2, SiO2, Al2O3, MgO, NaCl, KBr, KCl, and AgCl may be used.
In each embodiment described above, CsI (Tl) is used as the scintillator 14. However, the present invention is not limited to this. For example, CsI (Na), NaI (Tl), Li (Eu), or KI(Tl) may be used.
In each embodiment described above, examples of the polyparaxylylene are polymonochloroparaxylylene, polydichloroparaxylylene, polytetrachloroparaxylylene, polyfluoroparaxylylene, polydimethylparaxylylene, and polydiethylparaxylylene.
According to the scintillator panel of the present invention, since the substrate made of carbon as a major constituent has high radiation transmittance, the amount of radiation absorbed by the substrate can be decreased, and the amount of radiation reaching the scintillator can be increased.
In addition, according to the radiation image sensor of the present invention, since the scintillator panel has the substrate made of carbon as a major constituent having high radiation transmittance, the amount of light reaching the image sensing element can be increased.
As described above, the scintillator panel and radiation image sensor of the present invention are suited for medical X-ray photography and the like.
The basic Japanese Application Nos. 171190/1998 filed on Jun. 18, 1998 and 171191/1998 filed on Jun. 18, 1998 are hereby incorporated by reference.
From the invention thus described, it will be obvious that the embodiments of the invention may be varied in many ways. Such variations are not to be regarded as a departure from the spirit and scope of the invention, and all such modifications as would be obvious to one skilled in the art are intended for inclusion within the scope of the following claims.
Claims
1. A scintillator panel comprising:
- a multi-sided substrate made of amorphous carbon;
- a scintillator formed so as to cover a substantial portion of a first side of the substrate, with at least one portion of the first side of the substrate being uncovered by the scintillator; and
- a protective film substantially covering all exposed surfaces of the substrate and the scintillator, including a second side of the substrate opposite the first side of the substrate as well as the portion of the first side of the substrate uncovered by the scintillator.
2. A scintillator panel according to claim 1, further comprising a reflecting film, wherein said reflecting film is disposed between a radiation emitting surface of said substrate and said scintillator.
3. A scintillator panel according to claim 2, wherein said reflecting film is a metal film.
4. A scintillator panel according to claim 2, wherein said reflecting film is a thin transparent film having a refractive index lower than a refractive index of said scintillator.
5. A scintillator panel according to claim 4, wherein said thin transparent film is a film made of a material containing a substance selected from the group consisting of LiF, MgF2, CaF2, SiO2, Al2O3, MgO, NaCl, KBr, KCl, and AgCl.
6. A scintillator panel according to claim 1, wherein the portion of the first side of the substrate uncovered by the scintillator is located adjacent to an edge of the first side of the substrate.
7. A scintillator panel according to claim 1, wherein at least two portions of the first side of the substrate are uncovered by the scintillator and the protective film substantially covers the portions of the first side of the substrate uncovered by the scintillator.
8. A scintillator panel according to claim 7, wherein the portions of the first side of the substrate uncovered by the scintillator are located adjacent to different edges of the first side of the substrate.
9. A scintillator panel according to claim 7 wherein the portions of the first side of the substrate uncovered by the scintillator are located adjacent to opposing edges of the first side of the substrate.
10. A scintillator panel according to claim 1, wherein multiple portions of the first side of the substrate are uncovered by the scintillator and the protective film covers the portions of the first side of the substrate uncovered by the scintillator, the portions of the first side of the substrate uncovered by the scintillator are located adjacent to different edges of the first side of the substrate, and the sides of the substrate connecting the first side and the second side are covered by the protective film.
11. A scintillator panel according to claim 10, wherein the portions of the first side of the substrate uncovered by the scintillator are located adjacent to opposing edges of the first side of the substrate.
12. A scintillator panel according to claim 1, wherein said protective film further covers at least a part of said substrate.
13. A scintillator panel according to claim 12, wherein said protective film covers entire surfaces of said substrate.
14. A radiation image sensor comprising an image sensing element placed to oppose said scintillator of said scintillator panel defined in claim 1.
15. A scintillator panel comprising:
- a multi-sided substrate made of graphite;
- a scintillator formed so as to cover a substantial portion of a first side of the substrate, with at least one portion of the first side of the substrate being uncovered by the scintillator; and
- a protective film substantially covering all exposed surfaces of the substrate and the scintillator, including a second side of the substrate opposite the first side of the substrate as well as the portion of the first side of the substrate uncovered by the scintillator.
16. A scintillator panel according to claim 15, further comprising a reflecting film, wherein said reflecting film is disposed between a radiation emitting surface of said substrate and said scintillator.
17. A scintillator panel according to claim 16, wherein said reflecting film is a metal film.
18. A scintillator panel according to claim 16, wherein said reflecting film is a thin transparent film having a refractive index lower than a refractive index of said scintillator.
19. A scmtillator panel according to claim 18, wherein said thin transparent film is a film made of a material containing a substance selected from the group consisting of LiF, MgF2, CaF2, SiO2, Al2O3, MgO, NaCl, KBr, KCl, and AgCl.
20. A scintillator panel according to claim 15, wherein the portion of the first side of the substrate uncovered by the scintillator is located adjacent to an edge of the first side of the substrate.
21. A scintillator panel according to claim 15, wherein at least two portions of the first side of the substrate are uncovered by the scintillator and the protective film substantially covers the portions of the first side of the substrate uncovered by the scintillator.
22. A scintillator panel according to claim 21, wherein the portions of the first side of the substrate uncovered by the scintillator are located adjacent to different edges of the first side of the substrate.
23. A scintillator panel according to claim 21, wherein the portions of the first side of the substrate uncovered by the scintillator are located adjacent to opposing edges of the first side of the substrate.
24. A scintillator panel according to claim 15, wherein multiple portions of the first side of the substrate are uncovered by the scintillator and the protective film covers the portions of the first side of the substrate uncovered by the scintillator, the portions of the first side of the substrate uncovered by the scintillator are located adjacent to different edges of the first side of the substrate, and the sides of the substrate connecting the first side and the second side are covered by the protective film.
25. A scintillator panel according to claim 24, wherein the portions of the first side of the substrate uncovered by the scintillator are located adjacent to opposing edges of the first side of the substrate.
26. A scintillator panel according to claim 15, wherein said protective film further covers at least a part of said substrate.
27. A scintillator panel according to claim 26, wherein said protective film covers entire surfaces of said substrate.
28. A radiation image sensor comprising an image sensing element placed to oppose said scintillator of said scintillator panel defined in claim 15.
3936645 | February 3, 1976 | Iversen |
4547670 | October 15, 1985 | Sugimoto et al. |
4825085 | April 25, 1989 | Tsuchino et al. |
5041729 | August 20, 1991 | Takahashi et al. |
5132539 | July 21, 1992 | Kwasnick et al. |
5153438 | October 6, 1992 | Kingsley et al. |
5179284 | January 12, 1993 | Kingsley et al. |
5187369 | February 16, 1993 | Kingsley et al. |
5227635 | July 13, 1993 | Iwanczyk |
5310784 | May 10, 1994 | Ide et al. |
5585638 | December 17, 1996 | Hoffman |
5654084 | August 5, 1997 | Egert |
5848124 | December 8, 1998 | Inazuru |
5852303 | December 22, 1998 | Cuomo et al. |
5860584 | January 19, 1999 | Inazuru |
5864146 | January 26, 1999 | Karellas |
6025598 | February 15, 2000 | Tago |
6429437 | August 6, 2002 | Laugier |
6531225 | March 11, 2003 | Homme et al. |
6777690 | August 17, 2004 | Homme et al. |
0 403 802 | December 1990 | EP |
0 528 676 | February 1993 | EP |
63-215987 | September 1988 | JP |
63-216000 | September 1988 | JP |
01-116480 | May 1989 | JP |
1-267500 | October 1989 | JP |
3-163391 | July 1991 | JP |
3-3163391 | July 1991 | JP |
04-174400 | June 1992 | JP |
5-60871 | March 1993 | JP |
5-93780 | April 1993 | JP |
5-39558 | June 1993 | JP |
5-188148 | July 1993 | JP |
05-189757 | July 1993 | JP |
5-203755 | August 1993 | JP |
5-299044 | November 1993 | JP |
7-21560 | March 1995 | JP |
7-218698 | August 1995 | JP |
7-270599 | October 1995 | JP |
8-198687 | August 1996 | JP |
08-329465 | December 1996 | JP |
9-257947 | October 1997 | JP |
WO98/36290 | August 1998 | WO |
WO98/36291 | August 1998 | WO |
WO99/38031 | July 1999 | WO |
Type: Grant
Filed: Jul 30, 2003
Date of Patent: Sep 26, 2006
Patent Publication Number: 20050077473
Assignee: Hamamatsu Photonics K.K. (Shizuoka)
Inventors: Takuya Homme (Hamamatsu), Toshio Takabayashi (Hamamatsu), Hiroto Sato (Hamamatsu)
Primary Examiner: Albert Gagliardi
Attorney: Drinker Biddle & Reath LLP
Application Number: 10/629,820
International Classification: G01T 1/24 (20060101);