Forming An Intended Mixture (excluding Mixed Crystal) (e.g., Doped) Patents (Class 117/19)
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Patent number: 12084788Abstract: A method for producing a silicon single crystal, wherein a silicon nitride powder is introduced into a raw material before start of melting and the silicon single crystal doped with nitrogen is pulled by Czochralski method, wherein nitrogen doping is performed while an upper limit amount of usable silicon nitride powder is limited based on an amount of carbon impurities contained in the silicon nitride powder so that a carbon concentration in the silicon single crystal is equal to or less than allowable value. This makes it possible to achieve the required nitrogen doping amount at low cost while achieving the low carbon-concentration specification.Type: GrantFiled: December 1, 2020Date of Patent: September 10, 2024Assignee: SHIN-ETSU HANDOTAI CO., LTD.Inventors: Kosei Sugawara, Ryoji Hoshi, Tomohiko Ohta
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Patent number: 11903202Abstract: In one embodiment, a method of manufacturing a semiconductor device includes forming a semiconductor layer including a plurality of metal atoms on a substrate, and forming a first layer including a plurality of silicon atoms and a plurality of nitrogen atoms on the semiconductor layer. The method further includes transferring at least some of the metal atoms in the semiconductor layer into the first layer. and removing the first layer after transferring the at least some of the metal atoms in the semiconductor layer into the first layer. Furthermore, a ratio of a number of the nitrogen atoms relative to a number of the silicon atoms and the nitrogen atoms in the first layer is smaller than 4/7.Type: GrantFiled: August 4, 2021Date of Patent: February 13, 2024Assignee: Kioxia CorporationInventors: Aki Maeda, Noritaka Ishihara, Atsushi Fukumoto, Shuto Yamasaka
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Patent number: 11827826Abstract: The present disclosure relates to a method for growing a crystal. The method includes: weighting reactants according to a molar ratio of the reactants according to a reaction equation for generating the crystal after a first preprocessing operation is performed on the reactants, wherein the first preprocessing operation includes a roasting operation under 800° C.˜1400° C.; placing the reactants on which a second preprocessing operation has been performed into a crystal growth device, wherein the second preprocessing operation includes at least one of an ingredient mixing operation or a pressing operation at room temperature; introducing a flowing gas into the crystal growth device after sealing the crystal growth device; and activating the crystal growth device to execute a crystal growth to grow the crystal based on Czochralski technique.Type: GrantFiled: January 13, 2022Date of Patent: November 28, 2023Assignee: MEISHAN BOYA ADVANCED MATERIALS CO., LTD.Inventors: Yu Wang, Weiming Guan, Min Li
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Patent number: 11299819Abstract: A crystal pulling apparatus for producing an ingot is provided. The apparatus includes a furnace and a gas doping system. The furnace includes a crucible for holding a melt. The gas doping system includes a feeding tube, an evaporation receptacle, and a fluid flow restrictor. The feeding tube is positioned within the furnace, and includes at least one feeding tube sidewall, a first end through which a solid dopant is introduced into the feeding tube, and an opening opposite the first end through which a gaseous dopant is introduced into the furnace. The evaporation receptacle is configured to vaporize the dopant therein, and is disposed near the opening of the feeding tube. The fluid flow restrictor is configured to permit the passage of solid dopant therethrough and restrict the flow of gaseous dopant therethrough, and is disposed within the feeding tube between the first end and the evaporation receptacle.Type: GrantFiled: July 23, 2019Date of Patent: April 12, 2022Assignee: GlobalWafers Co., Ltd.Inventors: Stephan Haringer, Roberto Scala, Marco D'Angella
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Patent number: 11028499Abstract: Ingot puller apparatus for preparing silicon ingots that include a dopant feed system are disclosed. The dopant feed system include a dopant conduit having a porous partition member disposed across the dopant conduit. Solid dopant falls onto the partition member where it sublimes. The sublimed dopant is carried by inert gas through the partition member to contact and dope the silicon melt.Type: GrantFiled: December 14, 2018Date of Patent: June 8, 2021Assignee: GlobalWafers Co., Ltd.Inventors: Roberto Scala, Stephan Haringer, Franco Battan
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Patent number: 11028500Abstract: Ingot puller apparatus for preparing silicon ingots that include a dopant feed system are disclosed. The dopant feed system include a dopant conduit having a porous partition member disposed across the dopant conduit. Solid dopant falls onto the partition member where it sublimes. The sublimed dopant is carried by inert gas through the partition member to contact and dope the silicon melt.Type: GrantFiled: December 14, 2018Date of Patent: June 8, 2021Assignee: GlobalWafers Co., Ltd.Inventors: Roberto Scala, Stephan Haringer, Franco Battan
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Patent number: 11028498Abstract: A single crystal pulling apparatus including a dopant supplying means which includes: a charging device provided outside a chamber for storing a dopant and charging the dopant into the chamber; a sublimation room provided inside the chamber for holding and sublimating the dopant charged from the charging device; a carrier gas-introducing device for introducing a carrier gas into the sublimation room; and a blowing device for blowing the dopant sublimated in the sublimation room together with the carrier gas onto a surface of a raw-material melt. The blowing device includes a tube connected to the sublimation room and blowing ports such that the sublimated dopant is scattered from the blowing ports via the tube and blown onto the surface of the raw-material melt. This provides a single crystal pulling apparatus capable of efficient doping with a sublimable dopant within the shortest possible time.Type: GrantFiled: September 19, 2017Date of Patent: June 8, 2021Assignee: SHIN-ETSU HANDOTAI CO., LTD.Inventors: Satoshi Soeta, Kazuya Nakagawa
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Patent number: 10995102Abstract: The present disclosure discloses a method for growing a crystal for detecting neutrons, gamma rays, and/or x rays. The method may include weighting reactants based on a molar ratio of the reactants according to a reaction equation (1-x-z)X2O3+SiO2+2xCeO2+zZ2O3?X2(1-x-z)Ce2xZ2zSiO5+x/2O2? or (1-x-y-z)X2O3+yY2O3+SiO2+2xCeO2+zZ2O3?X2(1-x-y-z)Y2yCe2xZ2zSiO5+x/2O2?; placing the reactants on which a second preprocessing operation has been performed into a crystal growth device after an assembly processing operation is performed on at least one component of the crystal growth device; introducing a flowing gas into the crystal growth device after sealing the crystal growth device; and activating the crystal growth device to grow the crystal based on the Czochralski technique.Type: GrantFiled: June 16, 2020Date of Patent: May 4, 2021Assignee: MEISHAN BOYA ADVANCED MATERIALS CO., LTD.Inventors: Yu Wang, Weiming Guan, Min Li
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Patent number: 10889913Abstract: A crystal pulling apparatus for producing an ingot is provided. The apparatus includes a furnace and a gas doping system. The furnace includes a crucible for holding a melt. The gas doping system includes a feeding tube, an evaporation receptacle, and a fluid flow restrictor. The feeding tube is positioned within the furnace, and includes at least one feeding tube sidewall, a first end through which a solid dopant is introduced into the feeding tube, and an opening opposite the first end through which a gaseous dopant is introduced into the furnace. The evaporation receptacle is configured to vaporize the dopant therein, and is disposed near the opening of the feeding tube. The fluid flow restrictor is configured to permit the passage of solid dopant therethrough and restrict the flow of gaseous dopant therethrough, and is disposed within the feeding tube between the first end and the evaporation receptacle.Type: GrantFiled: December 20, 2018Date of Patent: January 12, 2021Assignee: GlobalWafers Co., Ltd.Inventors: Stephan Haringer, Roberto Scala, Marco D'Angella
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Patent number: 10811537Abstract: A device includes a semiconductor substrate, an isolation structure, and an epitaxial fin portion. The semiconductor substrate has an implanted region. The implanted region has a bottom fin portion thereon, in which a depth of the implanted region is smaller than a thickness of the semiconductor substrate. The isolation structure surrounds the bottom fin portion. The epitaxial fin portion is disposed over a top surface of the bottom fin portion, in which the implanted region of the semiconductor substrate includes oxygen and has an oxygen concentration lower than about 1·E+19 atoms/cm3.Type: GrantFiled: July 13, 2018Date of Patent: October 20, 2020Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.Inventors: Che-Yu Lin, Ming-Hua Yu, Tze-Liang Lee, Chan-Lon Yang
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Patent number: 10541345Abstract: The present disclosure generally relates to a solar cell device that includes a substrate comprising a front side surface and a backside surface; an epitaxial region overlying the substrate, wherein the epitaxial region comprises a first Bragg reflector disposed below a first solar cell, wherein the first solar cell has a first bandgap, wherein the first Bragg reflector is operable to reflect a first range of radiation wavelengths back into the first solar cell, and is operable to cool the solar cell device by reflecting a second range of radiation wavelengths that are outside the photogeneration wavelength range of the first solar cell or that are weakly absorbed by the first solar cell, and may additionally comprise a second Bragg reflector operable to reflect a third range of radiation wavelengths back into the first solar cell.Type: GrantFiled: January 12, 2016Date of Patent: January 21, 2020Assignee: THE BOEING COMPANYInventors: Richard R. King, Moran Haddad, Philip T. Chiu, Xingquan Liu, Christopher M. Fetzer
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Patent number: 10475663Abstract: A semiconductor device of the present invention includes a substrate having a drift layer, metal wiring formed on an upper surface of the substrate, and an electrode formed on a back surface of the substrate, wherein the lifetime of carriers in the drift layer satisfies the following expression 1: [Expression 1] ??1.5×10?5exp(5.4×103tN-)??expression 1 ?: the lifetime of carriers in the drift layer tN-: the layer thickness of the drift layer.Type: GrantFiled: October 2, 2012Date of Patent: November 12, 2019Assignee: Mitsubishi Electric CorporationInventor: Katsumi Nakamura
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Patent number: 10407797Abstract: A system for forming an ingot from a melt includes a first crucible defining a cavity for receiving the melt and a second crucible in the cavity. The second crucible separates an outer zone from an inner zone. The second crucible includes a passageway therethrough to allow the melt located within the outer zone to move into the inner zone. The inner zone defines a growth area for the ingot. The system also includes a barrier located within the outer zone to limit movement of the melt through the outer zone. The barrier includes members that are arranged to define a labyrinth for melt flow.Type: GrantFiled: May 4, 2017Date of Patent: September 10, 2019Assignee: Corner Start LimitedInventors: Salvador Zepeda, Richard J. Phillips, Christopher Vaughn Luers
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Patent number: 10312330Abstract: In a method for fabricating a semiconductor substrate according to an embodiment, an SiC substrate is formed by vapor growth and C (carbon) is introduced into the surface of the SiC substrate to form an n-type SiC layer on the SiC substrate by an epitaxial growth method.Type: GrantFiled: February 27, 2018Date of Patent: June 4, 2019Assignee: Kabushiki Kaisha ToshibaInventors: Johji Nishio, Ryosuke Iijima, Kazuto Takao, Takashi Shinohe
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Patent number: 10227709Abstract: A method of growing a rare-earth oxyorthosilicate crystal, and crystals grown using the method are disclosed. The method includes preparing a melt by melting a first substance including at least one first rare-earth element and providing an atmosphere that includes an inert gas and a gas including oxygen.Type: GrantFiled: February 17, 2015Date of Patent: March 12, 2019Assignee: Siemens Medical Solutions USA, Inc.Inventors: Mark S. Andreaco, Peter Carl Cohen, Alexander Andrew Carey
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Patent number: 10167573Abstract: A method of producing a SiC single crystal includes: disposing a SiC seed crystal at a bottom part inside a graphite crucible; causing a solution containing Si, C and R (R is at least one selected from the rare earth elements inclusive of Sc and Y) or X (X is at least one selected from the group consisting of Al, Ge, Sn, and transition metals exclusive of Sc and Y) to be present in the crucible; supercooling the solution so as to cause the SiC single crystal to grow on the seed crystal; and adding powdery or granular Si and/or SiC raw material to the solution from above the graphite crucible while keeping the growth of the SiC single crystal.Type: GrantFiled: November 21, 2011Date of Patent: January 1, 2019Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Tadao Nomura, Norio Yamagata, Takehisa Minowa
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Patent number: 9887263Abstract: An SiC semiconductor device includes an SiC layer including a drift region forming a surface and a body region forming a part of a surface and being in contact with the drift region, a drain electrode electrically connected to a region on a side of the surface in the drift region, and a source electrode electrically connected to the body region. Main carriers which pass through the drift region and migrate between the drain electrode and the source electrode are only electrons. Z1/2 center is introduced into the drift region at a concentration not lower than 1×1013 cm?3 and not higher than 1×1015 cm?3.Type: GrantFiled: July 16, 2014Date of Patent: February 6, 2018Assignee: Sumitomo Electric Industries, Ltd.Inventors: Toru Hiyoshi, Keiji Wada
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Patent number: 9822466Abstract: A system for growing an ingot from a melt includes an outer crucible, an inner crucible, and a weir. The outer crucible includes a first sidewall and a first base. The first sidewall and the first base define an outer cavity for containing the melt. The inner crucible is located within the outer cavity, and has a central longitudinal axis. The inner crucible includes a second sidewall and a second base having an opening therein. The opening in the second base is concentric with the central longitudinal axis. The weir is disposed between the outer crucible and the inner crucible for supporting the inner crucible.Type: GrantFiled: November 22, 2013Date of Patent: November 21, 2017Assignee: Corner Star LimitedInventors: Tirumani N. Swaminathan, John David Hilker, Salvador Zepeda
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Patent number: 9777394Abstract: A method of producing silicon single crystal ingot by pulling the silicon single crystal ingot made of an N-region by the CZ method, including: performing an EOSF inspection including a heat treatment to manifest oxide precipitates and selective etching on sample wafer from the silicon single crystal ingot composed of the N-region to measure a density of EOSF; performing a shallow-pit inspection to investigate a pattern of occurrence of a shallow pit; adjusting the pulling conditions according to result of identification of a defect region of the sample wafer by the EOSF and shallow-pit inspections to pull a next silicon single crystal ingot composed of the N-region, wherein in the identification of the defect region, for an N-region, what portion of an Nv-region or Ni-region the defect region corresponds to is also identified.Type: GrantFiled: January 31, 2014Date of Patent: October 3, 2017Assignee: SHIN-ETSU HANDOTAI CO., LTD.Inventors: Susumu Sonokawa, Wataru Sato, Nobuaki Mitamura, Tomohiko Ohta
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Patent number: 9758899Abstract: Disclosed is a silicon single crystal pull-up apparatus that can grow a silicon single crystal having a desired electrical resistivity, to which a sublimable dopant has been reliably added, regardless of the length of the time necessary for the formation of a first half part of a straight body part in a silicon single crystal. Also disclosed is a process for producing a silicon single crystal. The silicon single crystal pull-up apparatus pulls up a silicon single crystal from a melt by a Czochralski method. The silicon single crystal pull-up apparatus comprises a pull-up furnace, a sample chamber that is externally mounted on the pull-up furnace and houses a sublimable dopant, a shielding mechanism that thermally shields the pull-up furnace and the sample chamber, and supply means that, after the release of shielding of the shielding mechanism, supplies the sublimable dopant into the melt.Type: GrantFiled: December 22, 2014Date of Patent: September 12, 2017Assignee: SUMCO TECHXIV CORPORATIONInventor: Tomohiro Fukuda
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Patent number: 9725821Abstract: A pull rod for use in producing a single crystal from a molten alloy is provided that includes an elongated rod having a first end and a second end, a first cavity defined at the first end and a second cavity defined at the first end and in communication with the first cavity. The first cavity receives the molten alloy and the second cavity vents a gas from the molten alloy to thereby template a single crystal when the pull rod is dipped into and extracted from the molten alloy.Type: GrantFiled: February 27, 2015Date of Patent: August 8, 2017Assignee: The United States of America as Represented by the Administrator of National Aeronautics and Space AdministrationInventor: Jon Goldsby
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Patent number: 9691617Abstract: A IIIA-VA group semi-conductor single crystal substrate (2) has one of or both of the following two properties: an oxygen content of 1.6×1016-5.6×1017 atoms/cm3 in a range from the surface to a depth of 10 ?m of the wafer, and an electron mobility of 4,800 cm2/V·s-5,850 cm2/V·s. Further, a method for preparing the semi-conductor single crystal substrate (2) comprises: placing a single crystal substrate (2) to be processed in a container (4); sealing said container (4), and keeping said single crystal substrate (2) to be processed at a temperature in the range of from the crystalline melting point ?240° C. to the crystalline melting point ?30° C. for 5 hours to 20 hours; preferably, keeping a gallium arsenide single crystal at a temperature of 1,000° C. to 1,200° C. for 5 hours to 20 hours.Type: GrantFiled: March 26, 2012Date of Patent: June 27, 2017Assignee: BEIJING TONGMEI XTAL TECHNOLOGY CO., LTD.Inventors: Morris Young, Davis Zhang, Vincent Wensen Liu, Yuanli Wang
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Patent number: 9469917Abstract: Provided is an ingot growing apparatus, which includes a crucible containing a silicon melt, a pulling device pulling a silicon single crystal ingot grown from the silicon melt, and a dopant supply unit disposed adjacent to the pulling device and for supplying a dopant during growing of the ingot. The neck portion may be doped at a concentration higher than that of the ingot through the dopant supply unit. Therefore, dislocation propagation velocity may be decreased and a propagation length may be shortened.Type: GrantFiled: August 10, 2012Date of Patent: October 18, 2016Assignee: LG SILTRON INC.Inventors: Jin-Woo Ahn, Bong-Woo Kim, II-Soo Choi, Do-Yeon Kim
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Patent number: 9340445Abstract: Optical fibers with previously unattainable characteristics and the method of producing the same are disclosed and claimed herein. Specifically, the application discloses and claims a method to produce ZBLAN, Indium Fluoride, Germanate and Chalcogenide optical fibers and other similar optical fibers in a microgravity environment. The resulting optical fibers have unique molecular structures not attainable when optical fibers with the identical chemical composition are produced in a standard 1 gravity environment. The method of the invention requires a novel draw tower and modified preform, which are specifically designed to operate in microgravity environments. A lead wire is inserted into the preform that, when wound onto a spool in the draw tower, causes a fiber to form. The pull rate of the lead wire controls the diameter of the fiber.Type: GrantFiled: March 15, 2013Date of Patent: May 17, 2016Inventors: Richard L. Glover, William F. Seng
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Publication number: 20150136992Abstract: A method for making a rare-earth oxyorthosilicate scintillator single crystal includes growing a single crystal from a melt of compounds including a rare-earth element (such as Lu), silicon and oxygen, a compound including a rare-earth activator (such as Ce), and a compound of a Group-7 element (such as Mn). The method further includes selecting an scintillation performance parameter (such as decay), and based on the scintillation performance parameter to be achieved, doping activator and Group-7 element at predetermined levels, or relative levels between the two, so as to achieve stable growth of the single-crystalline scintillator material from the melt.Type: ApplicationFiled: November 10, 2014Publication date: May 21, 2015Inventors: Peter Carl Cohen, A. Andrew Carey, Mark S. Andreaco, Matthias J. Schmand, Brant Quinton
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Publication number: 20150107509Abstract: Disclosed is a silicon single crystal pull-up apparatus that can grow a silicon single crystal having a desired electrical resistivity, to which a sublimable dopant has been reliably added, regardless of the length of the time necessary for the formation of a first half part of a straight body part in a silicon single crystal. Also disclosed is a process for producing a silicon single crystal. The silicon single crystal pull-up apparatus pulls up a silicon single crystal from a melt by a Czochralski method. The silicon single crystal pull-up apparatus comprises a pull-up furnace, a sample chamber that is externally mounted on the pull-up furnace and houses a sublimable dopant, a shielding mechanism that thermally shields the pull-up furnace and the sample chamber, and supply means that, after the release of shielding of the shielding mechanism, supplies the sublimable dopant into the melt.Type: ApplicationFiled: December 22, 2014Publication date: April 23, 2015Applicant: SUMCO TECHXIV CORPORATIONInventor: Tomohiro FUKUDA
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Flowable Chips and Methods for the Preparation and Use of Same, and Apparatus for Use in the Methods
Publication number: 20150090178Abstract: A method for recharging a crucible with polycrystalline silicon comprises adding flowable chips to a crucible used in a Czochralski-type process. Flowable chips are polycrystalline silicon particles made from polycrystalline silicon prepared by a chemical vapor deposition process, and flowable chips have a controlled particle size distribution, generally nonspherical morphology, low levels of bulk impurities, and low levels of surface impurities. Flowable chips can be added to the crucible using conventional feeder equipment, such as vibration feeder systems and canister feeder systems.Type: ApplicationFiled: December 3, 2014Publication date: April 2, 2015Inventors: ARVID NEIL ARVIDSON, TERENCE LEE HORSTMAN, MICHAEL JOHN MOLNAR, CHRIS Tim SCHMIDT, ROGER DALE SPENCER, Jr. -
Publication number: 20150069298Abstract: The scintillator single crystal of the invention comprises a cerium-activated orthosilicate compound represented by the following formula (1). Gd2?(a+x+y+z)LnaLuxCeyLmzSiO5??(1) (In formula (1), Lm represents at least one element selected from among Pr, Tb and Tm, Ln represents at least one element selected from among lanthanoid elements excluding Pr, Tb and Tm, and Sc, and Y, a represents a value of at least 0 and less than 1, x represents a value of greater than 1 and less than 2, y represents a value of greater than 0 and no greater than 0.01, and z represents a value of greater than 0 and no greater than 0.01. The value of a+x+y+z is no greater than 2.Type: ApplicationFiled: November 17, 2014Publication date: March 12, 2015Applicant: HITACHI CHEMICAL COMPANY, LTD.Inventors: Yasushi Kurata, Tatsuya Usui, Naoaki Shimura
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Publication number: 20150040818Abstract: A method of horizontal ribbon growth from a melt of material includes forming a leading edge of the ribbon using radiative cooling, drawing the ribbon in a first direction along a surface of the melt, removing heat radiated from the melt in a region adjacent the leading edge of the ribbon by setting a temperature Tc of a cold plate proximate a surface of the melt at a value that is greater than 50° C. below a melting temperature Tm of the material, setting a temperature at a bottom of the melt at a value that is between 1° C. and 3° C. greater than the Tm, and providing the heat flow through the melt at a heat flow rate that is above that of an instability regime characterized by segregation of solutes during crystallization of the melt, and is below a heat flow rate for stable isotropic crystal growth.Type: ApplicationFiled: October 28, 2014Publication date: February 12, 2015Inventors: Peter L. Kellerman, Dawei Sun, Brian H. Mackintosh
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Patent number: 8940092Abstract: The present invention relates generally to nanocomposite materials. The present invention relates more particularly to hybrid fibers as well as devices including them and methods for making them. Accordingly, one aspect of the invention is a hybrid fiber including a plurality of nanowires, each nanowire having a length, a width, and a thickness, the length being at least 10 times the width and at least 10 times the thickness; and a plurality of binder elements, each binder element having a length, a width, and a thickness, each substantially smaller than the average length of the nanowires and at least one of which is less than about 10 nm in dimension, the binder elements being arranged to intercouple individual nanowires. In certain embodiments, the binder elements are carbon nanotubes, and the nanowires are formed from silicon carbide.Type: GrantFiled: September 26, 2012Date of Patent: January 27, 2015Assignee: University of Washington through its Center for CommercializationInventors: Woon-Hong Yeo, Kieseok Oh, Kyong-Hoon Lee, Fong-Li Chou, Jae-Hyun Chung
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Patent number: 8920561Abstract: A silicon single crystal pull-up apparatus includes a pull-up furnace, a sample chamber in which a sublimable dopant is housed, a sample tube which can be raised and lowered between the interior of the sample chamber and the interior of the pull-up furnace, a raising and lowering means for raising and lowering the sample tube, a supply pipe which is installed inside the pull-up furnace and supplies the sublimable dopant to a melt, and a connection means for connecting the sample tube and the supply pipe. The connection means is constructed from a ball joint structure comprising a convex member which projects from one end of the sample tube and a concave member which is provided at one end of the supply pipe and is formed to be engageable with the convex member. The contact surfaces of the convex member and the concave member are formed to be curved surfaces.Type: GrantFiled: July 28, 2009Date of Patent: December 30, 2014Assignee: Sumco Techxiv CorporationInventors: Yasuhito Narushima, Shinichi Kawazoe, Fukuo Ogawa, Toshimichi Kubota, Tomohiro Fukuda
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Patent number: 8916124Abstract: When a group III nitride crystal is grown in a pressurized atmosphere of a nitrogen-containing gas from a melt 50 including at least a group III element, nitrogen and an alkali metal or an alkali earth metal, a melt-holding vessel 160 that holds the above-described melt 50 is swung about two axes different in direction from each other such as an X-axis and a Y-axis.Type: GrantFiled: November 27, 2008Date of Patent: December 23, 2014Assignee: Ricoh Company, Ltd.Inventors: Hisashi Minemoto, Osamu Yamada, Takeshi Hatakeyama, Hiroaki Hoshikawa, Yasunori Tokunou
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Patent number: 8888911Abstract: The present invention provides a technique which enables production of single crystal silicon having relatively low resistivity by preventing cell growth during crystal growth from occurring, especially in a case where a relatively large amount of dopant is added to a molten silicon raw material. Specifically, the present invention provides a method of producing single crystal silicon by the Czochralski process, comprising producing single crystal silicon having relatively low resistivity by controlling a height of a solid-liquid interface when the single crystal silicon is pulled up.Type: GrantFiled: September 3, 2010Date of Patent: November 18, 2014Assignee: Sumco Techxiv CorporationInventors: Masayuki Uto, Tuneaki Tomonaga, Toshimichi Kubota, Fukuo Ogawa, Yasuhito Narushima
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Publication number: 20140331914Abstract: Provided is an ingot growing apparatus, which includes a crucible containing a silicon melt, a pulling device pulling a silicon single crystal ingot grown from the silicon melt, and a dopant supply unit disposed adjacent to the pulling device and for supplying a dopant during growing of the ingot. The neck portion may be doped at a concentration higher than that of the ingot through the dopant supply unit. Therefore, dislocation propagation velocity may be decreased and a propagation length may be shortened.Type: ApplicationFiled: November 28, 2012Publication date: November 13, 2014Inventors: Ingu Kang, Sanghee Kim
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Patent number: 8864906Abstract: A method for producing a silicon wafer in which occurrence of slip starting from interstitial-type point defects is prevented in a part from the shoulder to the top of the straight cylinder portion of a silicon single crystal when the silicon single crystal is grown by pulling method under growth conditions entering an I-rich region. In order to prevent occurrence of slip in the range from the shoulder (10A) to the top of the straight cylinder portion (10B), the silicon single crystal (10) is pulled under conditions that the oxygen concentration Oi from the shoulder (10A) to the top of the straight cylinder portion (10B) of the silicon single crystal (10) is not lower than a predetermined concentration for preventing slip starting from interstitial-type point defects, more specifically not lower than 9.0×1017 atoms/cm3.Type: GrantFiled: March 20, 2006Date of Patent: October 21, 2014Assignee: Sumco Techxiv Kabushiki KaishaInventors: Hidetoshi Kuroki, Motoaki Yoshinaga, Yutaka Shiraishi, Masahiro Shibata
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Patent number: 8864907Abstract: A condition of a single crystal manufacturing step subjected to the Czochralski method applying an initial oxygen concentration, a dopant concentration or resistivity, and a heat treatment condition is determined simply and clearly on the basis of the conditions of a wafer manufacturing step and a device step so as to obtain a silicon wafer having a desired gettering capability. A manufacturing method of a silicon substrate which is manufactured from a silicon single crystal grown by the CZ method and provided for manufacturing a solid-state imaging device is provided. The internal state of the silicon substrate, which depends on the initial oxygen concentration, the carbon concentration, the resistivity, and the pulling condition of the silicon substrate, is determined by comparing a white spot condition representing upper and lower limits of the density of white spots as device characteristics with the measured density of white spots.Type: GrantFiled: March 4, 2009Date of Patent: October 21, 2014Assignee: Sumco CorporationInventors: Kazunari Kurita, Shuichi Omote
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Patent number: 8852340Abstract: In consideration of influence of segregation, an evaporation area of a volatile dopant and influence of pulling-up speed at the time of manufacturing a monocrystal using a monocrystal pulling-up device, an evaporation speed formula for calculating evaporation speed of the dopant is derived. At predetermined timing during pulling-up, gas flow volume and inner pressure in a chamber are controlled such that a cumulative evaporation amount of the dopant, calculated based on the evaporation speed formula, becomes a predetermined amount. A difference between a resistivity profile of the monocrystal predicted based on the evaporation speed formula and an actual resistivity profile is made small. Since no volatile dopant is subsequently added, increase in workload on an operator, increase of manufacturing time, an increase in amorphous adhering to the inside of the chamber, and an increase in workload at the time of cleaning the inside of the chamber can be prevented.Type: GrantFiled: October 4, 2013Date of Patent: October 7, 2014Assignee: Sumco Techxiv CorporationInventors: Yasuhito Narushima, Fukuo Ogawa, Shinichi Kawazoe, Toshimichi Kubota
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Patent number: 8846505Abstract: A method for growing islands of semiconductor monocrystals from a solution on an amorphous substrate includes the procedures of depositing a semiconductor-metal mixture layer, applying lithography and etching for forming at least one platform, heating the at least one platform, and saturating the semiconductor-metal solution until a monocrystal of the semiconductor component is formed. The procedure of depositing a semiconductor-metal mixture layer, includes a semiconductor component and at least one other metal component, is performed on top of the amorphous substrate. The procedure of applying lithography and etching to the semiconductor-metal mixture layer and a portion of the amorphous substrate is performed for forming at least one platform, the at least one platform having a top view shape corresponding to crystal growth direction and habit respective of the semiconductor component.Type: GrantFiled: March 9, 2010Date of Patent: September 30, 2014Assignee: SKOKIE Swift CorporationInventor: Moshe Einav
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Patent number: 8840721Abstract: The present invention provides a method of producing low-resistivity silicon single crystal containing a dopant at a relatively high concentration by adding a large amount of the dopant to silicon melt when the silicon single crystal is pulled up, with suppressing occurrence of dislocation in the crystal. Specifically, the present invention provides a method of manufacturing silicon single crystal by bringing silicon seed crystal into contact with silicon melt and pulling up the silicon seed crystal while rotating the crystal to grow silicon single crystal whose straight body section has a diameter of ? mm below the silicon seed crystal, the method comprising: the dopant-adding step of adding a dopant to the silicon melt during growth of the straight body section of the silicon single crystal, while rotating the silicon single crystal at a rotational speed of ? rpm (where ??24?(?/25)).Type: GrantFiled: November 11, 2010Date of Patent: September 23, 2014Assignee: Sumco Techxiv CorporationInventors: Yasuhito Narushima, Fukuo Ogawa, Toshimichi Kubota
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Patent number: 8834627Abstract: Silicon single crystals are grown by a method of remelting silicon granules, by crystallizing a conically extended section of the single crystal with the aid of an induction heating coil arranged below a rotating plate composed of silicon; feeding inductively melted silicon through a conical tube in the plate, the tube enclosing a central opening of the plate and extending below the plate, to a melt situated on the conically extended section of the single crystal in contact with a tube end of the conical tube, wherein by means of the induction heating coil below the plate, sufficient energy is provided to ensure that the external diameter of the tube end is not smaller than 15 mm as long as the conically extended section of the single crystal has a diameter of 15 to 30 mm.Type: GrantFiled: October 28, 2010Date of Patent: September 16, 2014Assignee: Siltronic AGInventors: Wilfried von Ammon, Ludwig Altmannshofer, Martin Wasner
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Patent number: 8784559Abstract: A Czochralski (“CZ”) single-crystal growth process system continuously grows crystal boules in a chamber furnace during a single thermal cycle. Finished boules are transferred from the furnace chamber, without need to cool the furnace, to an adjoining cooling chamber for controlled cooling. Controlled cooling is preferably accomplished by transporting boules along a path having an incrementally decreasing temperature. In order to maximize crystal boule yield in a single furnace thermal cycle, the crucible assembly may be recharged with crystal growth aggregate and/or slag may be discharged during the crystal boule growth process without opening the furnace.Type: GrantFiled: September 9, 2010Date of Patent: July 22, 2014Assignee: Siemens Medical Solutions USA, Inc.Inventors: James L. Corbeil, Troy Marlar, Piotr Szupryczynski
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Publication number: 20140190397Abstract: Provided is an ingot growing apparatus, which includes a crucible containing a silicon melt, a pulling device pulling a silicon single crystal ingot grown from the silicon melt, and a dopant supply unit disposed adjacent to the pulling device and for supplying a dopant during growing of the ingot. The neck portion may be doped at a concentration higher than that of the ingot through the dopant supply unit. Therefore, dislocation propagation velocity may be decreased and a propagation length may be shortened.Type: ApplicationFiled: August 10, 2012Publication date: July 10, 2014Inventors: Jin-Woo Ahn, Bong-Woo Kim, Il-Soo Choi, Do-Yeon Kim
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Patent number: 8753445Abstract: The invention relates to an apparatus and method for growing a high quality Si single crystal ingot and a Si single crystal ingot and wafer produced thereby. The growth apparatus controls the oxygen concentration of the Si single crystal ingot to various values thereby producing the Si single crystal ingot with high productivity and extremely controlled growth defects.Type: GrantFiled: July 5, 2007Date of Patent: June 17, 2014Assignee: Siltron, Inc.Inventor: Hyon-Jong Cho
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Patent number: 8747551Abstract: After adding phosphorus (P) and germanium (Ge) into a silicon melt or adding phosphorus into a silicon/germanium melt, a silicon monocrystal is grown from the silicon melt by a Czochralski method, where a phosphorus concentration [P]L(atoms/cm3) in the silicon melt, a Ge concentration in the silicon monocrystal, an average temperature gradient Gave (K/mm) and a pull speed V (mm/min) are controlled to satisfy a formula (1) as follows, a phosphorus concentration [P](atoms/cm3) and the Ge concentration [Ge](atoms/cm3) in the silicon monocrystal satisfy a relationship according to a formula (2) as follows while growing the silicon monocrystal, where dSi(?) represents a lattice constant of silicon, rSi(?) represents a covalent radius of silicon, rP(?) represents a covalent radius of phosphorus, and rGe(?) represents a covalent radius of Ge: [ P ] L + ( 0.3151 × [ Ge ] + 3.806 × 10 18 ) / 1.5 < 0.Type: GrantFiled: September 26, 2013Date of Patent: June 10, 2014Assignee: Sumco Techxiv CorporationInventors: Shinichi Kawazoe, Yasuhito Narushima, Toshimichi Kubota, Fukuo Ogawa
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Patent number: 8715416Abstract: A doping device includes a first dopant accommodating portion including an opening on an upper portion to accommodate a first dopant that is evaporated near a surface of a semiconductor melt; a second dopant accommodating portion including a dopant holder that holds a second dopant that is liquefied near the surface of the semiconductor melt while including a communicating hole for delivering the liquefied dopant downwardly, and a conduit tube provided on a lower portion of the dopant holder for delivering the liquefied dopant flowed from the communicating hole to the surface of the semiconductor melt; and a guide provided by a cylinder body of which a lower end is opened and an upper end is closed for guiding dopant gas generated by evaporation of the first dopant to the surface of the semiconductor melt.Type: GrantFiled: May 23, 2008Date of Patent: May 6, 2014Assignee: Sumco Techxiv CorporationInventors: Yasuhito Narushima, Shinichi Kawazoe, Fukuo Ogawa, Toshimichi Kubota
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Patent number: 8696809Abstract: A manufacturing method of an epitaxial silicon wafer is provided. The epitaxial silicon wafer includes: a substrate cut out from a silicon monocrystal that has been manufactured, doped with nitrogen and pulled up in accordance with Czochralski method; and an epitaxial layer formed on the substrate. The manufacturing method includes: cleaning a surface of the substrate with fluorinated acid by spraying onto the surface of the substrate fluorinated acid vaporized by a bubbling tank of a substrate cleaning apparatus; and forming an epitaxial layer on the cleaned surface of the substrate.Type: GrantFiled: June 12, 2008Date of Patent: April 15, 2014Assignee: Sumco Techxiv CorporationInventors: Kazuaki Kozasa, Kosuke Miyoshi
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Patent number: 8696811Abstract: A feed assembly and method of use thereof of the present invention is used for the addition of a high pressure dopant such as arsenic into a silicon melt for CZ growth of semiconductor silicon crystals. The feed assembly includes a vessel-and-valve assembly for holding dopant, and a feed tube assembly, attached to the vessel-and-valve assembly for delivering dopant to a silicon melt. An actuator is connected to the feed tube assembly and a receiving tube for advancing and retracting the feed tube assembly to and from the surface of the silicon melt. A brake assembly is attached to the actuator and the receiving tube for restricting movement of the feed tube assembly and locking the feed tube assembly at a selected position.Type: GrantFiled: November 25, 2009Date of Patent: April 15, 2014Assignee: MEMC Electronic Materials, Inc.Inventors: Massoud Javidi, Steve Garner
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Publication number: 20140097349Abstract: According to one embodiment, a crystal includes thallium bromide (TlBr), one or more positively charged dopants, and one or more negatively charged dopants. According to another embodiment, a system includes a monolithic crystal including thallium bromide (TlBr), one or more positively charged dopants, and one or more negatively charged dopants; and a detector configured to detect a signal response of the crystal.Type: ApplicationFiled: October 2, 2013Publication date: April 10, 2014Applicant: Lawrence Livermore National Security, LLCInventors: Cedric Rocha Leao, Vincenzo Lordi
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Publication number: 20140083350Abstract: Provided is a method of producing a group III-V compound, comprising: producing a raw material by housing a group III-V compound semiconductor crystal containing group III element and group V element and an impurity in a crucible, and heating and melting the group III-V compound semiconductor crystal in a state that a surface of the group III-V compound semiconductor crystal to an atmosphere in the crucible; growing the group III-V compound semiconductor single crystal by heating the raw material and an encapsulant by adding the encapsulant into the crucible in which the raw material is housed, and making a seed crystal in contact with a melt of the raw material with a liquid surface covered by the encapsulant in a liquid state, and lifting the seed crystal.Type: ApplicationFiled: September 6, 2013Publication date: March 27, 2014Inventor: Takeshi KIMURA
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Patent number: 8673248Abstract: The present invention relates to a single crystal silicon ingot or wafer wherein the lateral incorporation effect of intrinsic point defects has been manipulated such that the formation of agglomerated intrinsic point defects and/or oxygen precipitate clusters in a ring extending radially inward from about the lateral surface of the ingot segment is limited.Type: GrantFiled: May 18, 2007Date of Patent: March 18, 2014Assignee: MEMC Electronic Materials, Inc.Inventor: Milind S. Kulkarni