Of Amorphous Precursor Patents (Class 117/8)
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Patent number: 7687380Abstract: In order to promote an effect of laser annealing in respect of a semiconductor film, moisture is intentionally included in an atmosphere in irradiating laser beam to these miconductor film by which a temperature holding layer comprising water vapor is formed on the surface of these miconductor film in irradiating the laser beam and the laser annealing operation can be performed effectively.Type: GrantFiled: March 26, 2008Date of Patent: March 30, 2010Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Naoto Kusumoto, Shunpei Yamazaki, Koichiro Tanaka
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Patent number: 7666767Abstract: A mask for sequential lateral solidification (SLS) process with at least one transparency region is provided. The transparent region is defined by two lengthwise edges, a front edge, and a rear edge. The two lengthwise edges also define a quadrilateral. The front edge is located outside the quadrilateral, and the rear edge is located inside the quadrilateral.Type: GrantFiled: July 31, 2006Date of Patent: February 23, 2010Assignee: AU Optronics Corp.Inventor: Ming-Wei Sun
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Publication number: 20100001620Abstract: A method of manufacturing a microstructure of perovskite-type oxide single crystal having a desired composition and exhibiting excellent properties. The method includes the steps of: (a) forming a coating layer on a surface of a seed single crystal substrate, the coating layer containing the same metallic elements as those in a predetermined perovskite-type oxide; (b) forming a joint body having a micro-structured precursor of the predetermined perovskite-type oxide adhered to a surface of the coating layer; and (c) heat-treating the joint body to induce solid phase epitaxy, and thereby, single-crystallizing the precursor.Type: ApplicationFiled: June 17, 2009Publication date: January 7, 2010Applicant: FUJIFILM CorporationInventors: Shigenorii YUUYA, Masayuki Suzuki, Masahiro Takata
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Patent number: 7635412Abstract: An laser crystallization device and a method for crystallizing silicon by using the same is disclosed, to carry out the crystallization process at both the X-axis and Y-axis directions without rotation of a stage, wherein the laser crystallization device is includes a mask including first and second regions, the first region having an open part oriented in the X-axis direction, and the second region having an open part oriented in the Y-axis direction.Type: GrantFiled: June 22, 2004Date of Patent: December 22, 2009Assignee: LG Display Co., Ltd.Inventor: Yun Ho Jung
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Patent number: 7629209Abstract: A method for fabricating polysilicon film is disclosed. First, a first substrate is provided, wherein a plurality of sunken patterns has been formed on the front surface of the first substrate. Then, a second substrate is provided and an amorphous polysilicon film is formed on the second substrate. Next, the amorphous polysilicon film formed on the second substrate is in contact with the front surface of the first substrate. The amorphous polysilicon film is transferred into a polysilicon film by performing an annealing process. Then, the first substrate and the second substrate are separated from each other. This method reduces the cost and the time for fabricating polysilicon film.Type: GrantFiled: October 17, 2005Date of Patent: December 8, 2009Assignee: Chunghwa Picture Tubes, Ltd.Inventors: YewChung Sermon Wu, Chih-Yuan Hou, Guo-Ren Hu, Po-Chih Liu
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Patent number: 7608144Abstract: A process of lateral crystallization is provided for increasing the lateral growth length (LGL). A localized region of the substrate is heated for a short period of time. While the localized region of the substrate is still heated, a silicon film overlying the substrate is irradiated to anneal the silicon film to crystallize a portion of the silicon film in thermal contact with the heated substrate region. A CO2 laser may be used as a heat source to heat the substrate, while a UV laser or a visible spectrum laser is used to irradiate and crystallize the film.Type: GrantFiled: October 31, 2005Date of Patent: October 27, 2009Assignee: Sharp Laboratories of America, Inc.Inventors: Apostolos T. Voutsas, Robert S. Sposili, Mark A. Crowder
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Patent number: 7608148Abstract: A crystallization apparatus includes an illumination system which illuminates a phase shifter having a phase shift portion, and irradiates a polycrystal semiconductor film or an amorphous semiconductor film with a light beam having a predetermined light intensity distribution in which a light intensity is minimum in a point area corresponding to the phase shift portion of the phase shifter, thereby forming a crystallized semiconductor film, the phase shifter has four or more even-numbered phase shift lines which intersect at a point constituting the phase shift portion. An area on one side and an area on the other side of each phase shift line have a phase difference of approximately 180 degrees.Type: GrantFiled: September 14, 2006Date of Patent: October 27, 2009Assignee: Advanced LCD Technologies Development Center Co., Ltd.Inventors: Masakiyo Matsumura, Yukio Taniguchi
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Patent number: 7594965Abstract: The inhomogeneous energy distribution at the beam spot on the irradiated surface is caused by a structural problem and processing accuracy of the cylindrical lens array forming an optical system. According to the present invention, in the optical system for forming a rectangular beam spot, an optical system for homogenizing the energy distribution of the shorter side direction of a rectangular beam spot of a laser light on an irradiated surface is replaced with a light guide. The light guide is a circuit that can confine emitted beams in a certain region and guide and transmit its energy flow in parallel with the axis of a path thereof.Type: GrantFiled: September 22, 2003Date of Patent: September 29, 2009Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Koichiro Tanaka
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Patent number: 7591894Abstract: An LuAP scintillation detector and a method for improving the light output and uniformity of an LuAP scintillator crystal is provided, wherein the method includes disposing the scintillator crystal in a predetermined environment at a threshold temperature to generate an initial scintillator crystal, annealing the initial scintillator crystal in the predetermined environment at the threshold temperature to create an annealed scintillator crystal and cooling the annealed scintillator crystal in the predetermined environment to a final temperature.Type: GrantFiled: November 27, 2006Date of Patent: September 22, 2009Assignee: Schlumberger Technology CorporationInventors: Arthur J. Becker, Yanqi Wang, Bradley A. Roscoe, John Simonetti
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Patent number: 7569109Abstract: A method of making a rare earth halide single crystal material is provided. The method includes providing a polycrystalline material having a plurality of grains. The method further includes adding a seed crystal to the polycrystalline material to define a plane of growth for the polycrystalline material. Further, the polycrystalline material having the seed crystal may be subjected to heat-treating, where the heat-treating does not include melting the polycrystalline material.Type: GrantFiled: August 23, 2006Date of Patent: August 4, 2009Assignee: General Electric CompanyInventor: Venkat Subramaniam Venkataramani
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Patent number: 7566669Abstract: It is an object of the present invention to provide a laser irradiation apparatus which can manufacture a homogenously crystallized film by varying the energy intensity of an irradiation beam in forward and backward directions of the irradiation. A laser irradiation apparatus of the present invention comprises a laser oscillator and means for varying beam intensity wherein a laser beam is obliquely incident into the irradiation surface, the laser beam is scanned relative to the irradiation surface, and the beam intensity is varied in accordance with the scanning direction. Further, the laser oscillator is a continuous wave solid-state laser, gas laser, or metal laser. A pulsed laser having a repetition frequency of 10 MHz or more can also be used.Type: GrantFiled: June 15, 2005Date of Patent: July 28, 2009Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Koichiro Tanaka, Yoshiaki Yamamoto
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Publication number: 20090155561Abstract: A single-crystal graphene sheet includes a polycyclic aromatic molecule wherein a plurality of carbon atoms are covalently bound to each other, the single-crystal graphene sheet comprising between about 1 layer to about 300 layers; and wherein a peak ratio of a Raman D band intensity to a Raman G band intensity is equal to or less than 0.2. Also described is a method for preparing a single-crystal graphene sheet, the method includes forming a catalyst layer, which includes a single-crystal graphitizing metal catalyst sheet; disposing a carbonaceous material on the catalyst layer; and heat-treating the catalyst layer and the carbonaceous material in at least one of an inert atmosphere and a reducing atmosphere. Also described is a transparent electrode including a single-crystal graphene sheet.Type: ApplicationFiled: July 9, 2008Publication date: June 18, 2009Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Jae-young CHOI, Hyeon-Jin SHIN, Seon-mi YOON, Jai-yong HAN
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Patent number: 7544244Abstract: A method of manufacturing a ceramic film by using an AD method, by which a film having good crystallinity can be fabricated without using a high-temperature process. The method of manufacturing a ceramic film by using an aerosol including the steps of: (a) dispersing ceramic raw material powder containing an amorphous component in a gas to generate an aerosol; and (b) supplying the aerosol generated at step (a) into a chamber in which a substrate is placed and depositing the ceramic raw material powder on the substrate to form a ceramic film.Type: GrantFiled: December 6, 2005Date of Patent: June 9, 2009Assignee: FUJIFILM CorporationInventors: Yukio Sakashita, Takamichi Fujii
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Patent number: 7528057Abstract: A laser-annealing method includes the steps of a first step of cleaning a non-monocrystal silicon film formed on a substrate, and a second step of laser-annealing the non-monocrystal silicon film in an atmosphere containing oxygen therein, wherein the first and second steps are conducted continuously without being exposed to the air. Also, a laser-annealing device includes a cleaning chamber, and a laser irradiation chamber, wherein a substrate to be processed is transported between the cleaning chamber and the laser irradiation chamber without being exposed to the air.Type: GrantFiled: May 8, 2006Date of Patent: May 5, 2009Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Naoto Kusumoto, Toru Takayama, Masato Yonezawa
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Patent number: 7520930Abstract: A bulk silicon carbide single crystal of good crystalline quality which includes a minimized number of structural defects and is free from micropipe defects can be produced by crystal growth in a melt of an alloy comprising Si, C, and M (wherein M is either Mn or Ti) and having an atomic ratio between Si and M in which the value of x, when express as Si1-xMx, is 0.1?x?0.7 in the case where M is Mn or 0.1?x?0.25 in the case where M is Ti at a temperature of the melt which is below 2000° C. The C component is preferably supplied into the melt by dissolution of a graphite crucible which contains the melt such that the melt is free from undissolved C. One method of crystal growth is performed by cooling the melt after a seed substrate is immersed in the melt.Type: GrantFiled: October 15, 2004Date of Patent: April 21, 2009Assignee: Sumitomo Metal Industries, Ltd.Inventors: Kazuhiko Kusunoki, Shinji Munetoh, Kazuhito Kamei
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Patent number: 7520931Abstract: A method of making a single crystal material is provided. The method includes providing a polycrystalline material having a plurality of grains. The method further includes adding a seed crystal to the polycrystalline material to define a plane of growth for the polycrystalline material. Further, the polycrystalline material having the seed crystal may be subjected to heat-treating, where the heat-treating does not include melting the polycrystalline material.Type: GrantFiled: August 23, 2006Date of Patent: April 21, 2009Assignee: General Electric CompanyInventors: Venkat Subramaniam Venkataramani, Wesley Hackenberger, Seongtae Kwon, Paul William Rehrig
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Patent number: 7507289Abstract: In a solid solution system of Al2O3 and CAO or SrO, it has been difficult to obtain a material having a high electrical conductivity (>10?4 S·cm?) at room temperature. A compound is provided in which electrons at a high concentration are introduced into a 12CaO.7Al2O3 compound, a 12SrO.7Al2O3 compound, or a mixed crystal compound containing 12CaO.7Al2O3 and 12SrO.7Al2O3. The compound formed by substituting all the free oxygen ions with electrons is regarded as an electride compound in which [Ca24Al28O64]4+(4e?) or [Sr24Al28O64]4+(4e?) serves as a cation and electrons serve as anions. When a single crystal or a hydrostatic pressure press molded material of a fine powder thereof is held at approximately 700° C. in an alkaline metal vapor or an alkaline earth metal vapor, melt of a hydrostatic pressure press molded material of a powder is held at approximately 1,600° C. in a carbon crucible, followed by slow cooling for solidification, or a thin film of the compound held at approximately 600° C.Type: GrantFiled: February 12, 2004Date of Patent: March 24, 2009Assignee: Japan Science and Technology AgencyInventors: Hideo Hosono, Masahiro Hirano, Katsuro Hayashi, Masashi Miyakawa, Isao Tanaka
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Patent number: 7507290Abstract: A flux assisted solid phase epitaxy that can make a thin film having a crystalline perfection comparable with that of a bulk crystal and at a reduced cost is provided in which an amorphous film of a mixture of an objective substance to be grown epitaxially and a flux of a substance producing a eutectic with the objective substance but not producing any compound therewith is deposited on a substrate at a temperature less than a eutectic point of the substances, and the substrate is heat-treated at a temperature not less than the eutectic point of the objective and flux substances. A solid phase reaction, namely solid phase diffusion causes the objective and flux substances to be mixed together to form a liquid phase in their eutectic state from which the objective substance precipitates and epitaxially grows on the substrate.Type: GrantFiled: March 22, 2005Date of Patent: March 24, 2009Assignee: Japan Science and Technology AgencyInventors: Hideomi Koinuma, Yuji Matsumoto, Ryota Takahashi
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Patent number: 7503975Abstract: In a crystalline silicon film fabricated by a related art method, the orientation planes of its crystal randomly exist and the orientation rate relative to a particular crystal orientation is low. A semiconductor material which contains silicon as its main component and 0.1-10 atomic % of germanium is used as a first layer, and an amorphous silicon film is used as a second layer. Laser light is irradiated to crystallize the amorphous semiconductor films, whereby a good semiconductor film is obtained. In addition, TFTs are fabricated by using such a semiconductor film.Type: GrantFiled: June 25, 2001Date of Patent: March 17, 2009Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Shunpei Yamazaki, Toru Mitsuki, Kenji Kasahara, Taketomi Asami, Tamae Takano, Takeshi Shichi, Chiho Kokubo
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Patent number: 7488384Abstract: Colloidal nanocrystals or “quantum dots” of GaN are directly produced by heating amidogallium dimer, i.e., (Ga2[N(CH3)2]6), in the presence of a functional amine. The GaN quantum dots obtained, which comprise isolated particles 2-3 nm in diameter with a relative broad size distribution (e.g., 20% standard deviation) exhibit strong exciton confinement.Type: GrantFiled: May 3, 2006Date of Patent: February 10, 2009Assignee: Ohio UniversityInventors: Paul Gregory Van Patten, Guiquan Pan
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Patent number: 7452790Abstract: Disclosed is a method of fabricating a thin film transistor in which, in order to control the concentration of metal catalysts remaining on a polycrystalline silicon layer when an amorphous silicon layer formed on an insulating substrate is crystallized into the polycrystalline silicon layer by a super grain silicon (SGS) crystallization method, the substrate is annealed so that a very small amount of metal catalyst is adsorbed or diffused into a capping layer, and then a crystallization process is carried out, thereby minimizing the concentration of the metal catalysts remaining on the polycrystalline silicon layer, as well as forming a thick metal catalyst layer.Type: GrantFiled: December 22, 2004Date of Patent: November 18, 2008Assignee: Samsung SDI Co., Ltd.Inventors: Hye-Hyang Park, Ki-Yong Lee
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Patent number: 7438759Abstract: An ambient environment nanowire sensor and corresponding fabrication method have been provided. The method includes: forming a substrate such as Silicon (Si) or glass; growing nanowires; depositing an insulator layer overlying the nanowires; etching to expose tips of the nanowires; forming a patterned metal electrode, with edges, overlying the tips of the nanowires; and, etching to expose the nanowires underlying the electrode edges. The nanowires can be a material such as IrO2, TiO2, InO, ZnO, SnO2, Sb2O3, or In2O3, to mane just a few examples. The insulator layer can be a spin-on glass (SOG) or low-k dielectric. In one aspect, the resultant structure includes exposed nanowires grown from the doped substrate regions and an insulator core with embedded nanowires. In a different aspect, the method forms a growth promotion layer overlying the substrate. The resultant structure includes exposed nanowires grown from the selectively formed growth promotion layer.Type: GrantFiled: November 1, 2005Date of Patent: October 21, 2008Assignee: Sharp Laboratories of America, Inc.Inventors: Fengyan Zhang, Robert A. Barrowcliff, Jong-Jan Lee, Sheng Teng Hsu
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Patent number: 7422630Abstract: Concentration of metal element which promotes crystallization of silicon and which exists within a crystal silicon film obtained by utilizing the metal element is reduced. A first heat treatment for crystallization is implemented after introducing nickel to an amorphous silicon film 103. Then, laser light is irradiated to diffuse the nickel element concentrated locally. After that, another heat treatment is implemented within an oxidizing atmosphere at a temperature higher than that of the previous heat treatment. A thermal oxide film 106 is formed in this step. At this time, the nickel element is gettered to the thermal oxide film 106. Then, the thermal oxide film 106 is removed. Thereby, a crystal silicon film 107 having low concentration of the metal element and a high crystallinity can be obtained.Type: GrantFiled: June 5, 2006Date of Patent: September 9, 2008Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Shunpei Yamazaki, Satoshi Teramoto, Jun Koyama, Yasushi Ogata, Masahiko Hayakawa, Mitsuaki Osame
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Patent number: 7413604Abstract: The present invention provides a process for producing a polycrystal silicon film which comprises a step of forming a polycrystal silicon film by light irradiation of a silicon film set on a substrate, and a step of selecting substrate samples having an average grain size in a plane of the sample of 500 nm or more. According to the present invention, stable production of a high-performance poly-silicon TFT liquid crystal display becomes possible.Type: GrantFiled: September 17, 2004Date of Patent: August 19, 2008Assignee: Hitachi, Ltd.Inventors: Kazuo Takeda, Masakazu Saito, Yukio Takasaki, Hironobu Abe, Makoto Ohkura, Yoshinobu Kimura, Takeo Shiba
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Patent number: 7396712Abstract: A thin film processing method for processing the thin film by irradiating an optical beam to the thin film. A unit of the irradiation of the optical beam includes a first and a second optical pulse irradiation to the thin film, and the unit of the irradiation is carried out repeatedly to process the thin film. The first and the second optical pulse have pulse waveforms different from each other. Preferably, a unit of the irradiation of the optical beam includes the a first optical pulse irradiated to the thin film and a second optical pulse irradiated to the thin film starting substantially simultaneous with the first optical pulse irradiation. In this case, the relationship between the first and the second optical pulse satisfies (the pulse width of the first optical pulse)<(the optical pulse of the second optical pulse) and (the irradiation intensity of the first optical pulse)?(the irradiation intensity of the second optical pulse).Type: GrantFiled: April 10, 2006Date of Patent: July 8, 2008Assignees: NEC Corporation, Sumitomo Heavy Industries, LtdInventors: Hiroshi Tanabe, Akihiko Taneda
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Patent number: 7390728Abstract: The present invention is to reduce display unevenness in a display device caused by dispersion of energy density of a laser beam. It is difficult for a periodical pattern to be recognized as display unevenness in display image. The display device of the present invention can visually reduce the display unevenness in the display image by utilizing the visual advantage described above. The display device can be manufactured using a TFT array substrate in which electric characteristic of plural TFTs arranged in a line in the minor axis direction of an linear shaped laser beam periodically fluctuates depending on the place in which each TFT is formed.Type: GrantFiled: December 24, 2003Date of Patent: June 24, 2008Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Masaki Koyama
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Patent number: 7384476Abstract: A method for crystallizing silicon is provided. The method includes: forming an amorphous silicon layer on a substrate; aligning a mask above the substrate, the mask being divided into a plurality of blocks, each block having at least two transmission patterns, the transmission patterns of one block and the transmission patterns of another adjacent block being complimentary with each other and the mask including at least two diffraction patterns disposed between the transmission patterns; forming a first crystallization region on the amorphous silicon layer by irradiating a laser beam through the transmission patterns of the mask; and displacing the substrate or the mask by a predetermined distance and irradiating a laser beam onto the substrate to recrystallize the crystallization region using the laser beam that passes through the diffraction patterns, and forming a second crystallization region using the laser beam that passes through the transmission patterns.Type: GrantFiled: May 24, 2004Date of Patent: June 10, 2008Assignee: LG Display Co., Ltd.Inventor: JaeSung You
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Patent number: 7357963Abstract: A sequential lateral solidification apparatus includes a laser generator for generating and emitting a laser beam; an X-Y stage movable in two orthogonal axial directions; and a mask arranged between the laser generator and the X-Y stage. The mask has a plurality of slits through which the laser beam passes. An objective lens for scaling down the laser beam is arranged between the mask and the X-Y stage. A mask stage is connected to the mask for controlling minute movement of the mask for crystallizing amorphous silicon in one block.Type: GrantFiled: December 26, 2001Date of Patent: April 15, 2008Assignee: LG.Philips LCD Co., Ltd.Inventor: Yun-Ho Jung
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Patent number: 7354810Abstract: A method of manufacturing a semiconductor thin film includes (A) forming an amorphous semiconductor film on a substrate, (B) irradiating a beam to a surface of the amorphous semiconductor film such that a predetermined region of the amorphous semiconductor film is melted and solidified to form a crystallized semiconductor film, and (C) scanning the beam in a first direction. A second direction is a direction on the surface of the amorphous semiconductor film perpendicular to the first direction. A length along the second direction of a cross section of the beam is substantially equal to or less than two times a width along the second direction of the crystallized semiconductor film.Type: GrantFiled: May 28, 2004Date of Patent: April 8, 2008Assignee: NEC CorporationInventors: Hiromichi Takaoka, Mitsuru Nakata
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Patent number: 7351646Abstract: In order to promote an effect of laser annealing in respect of a semiconductor film, moisture is intentionally included in an atmosphere in irradiating laser beam to the semiconductor film by which a temperature holding layer comprising water vapor is formed on the surface of the semiconductor film in irradiating the laser beam and the laser annealing operation can be performed effectively.Type: GrantFiled: February 4, 2003Date of Patent: April 1, 2008Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Naoto Kusumoto, Shunpei Yamazaki, Koichiro Tanaka
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Patent number: 7348226Abstract: A method (and resultant structure) of forming a semiconductor structure, includes processing an oxide to have a crystalline arrangement, and depositing an amorphous semiconductor layer on the oxide by one of evaporation and chemical vapor deposition (CVD).Type: GrantFiled: July 6, 2005Date of Patent: March 25, 2008Assignee: International Business Machines CorporationInventors: Nestor Alexander Bojarczuk, Jr., Matthew Warren Copel, Supratik Guha, Vijay Narayanan
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Publication number: 20080047483Abstract: A method of making a single crystal material is provided. The method includes providing a polycrystalline material having a plurality of grains. The method further includes adding a seed crystal to the polycrystalline material to define a plane of growth for the polycrystalline material. Further, the polycrystalline material having the seed crystal may be subjected to heat-treating, where the heat-treating does not include melting the polycrystalline material.Type: ApplicationFiled: August 23, 2006Publication date: February 28, 2008Inventors: Venkat Subramaniam Venkataramani, Wesley Hackenberger, Seongtae Kwon, Paul William Rehrig
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Patent number: 7335261Abstract: Disclosed are apparatus for forming a semiconductor film having an excellent crystallinity from a non-single crystal semiconducting layer formed on a base layer made of an insulating material. The apparatus includes a light source, a homogenizer for homogenizing an intensity distribution of the emitted light, an amplitude-modulation means for performing the amplitude-modulation such that the amplitude of the light, of which the intensity distribution is homogenized, is increased in the direction of the relative motion of the light to the base layer, an optional light projection optical system for projecting the amplitude-modulated light onto the surface of the non-single crystal semiconductor such that a predetermined irradiation energy can be obtained, a phase shifter for providing a low temperature point in the surface irradiated by the light, and a substrate stage to move the light relative to the substrate thereby enabling scanning in the X and Y axis.Type: GrantFiled: August 5, 2005Date of Patent: February 26, 2008Assignee: Kabushiki Kaisha Ekisho Sentan Gijutsu Kaihatsu CenterInventors: Masakiyo Matsumura, Mikihiko Nishitani, Yoshinobu Kimura, Masayuki Jyumonji, Yukio Taniguchi, Masato Hiramatsu, Fumiki Nakano
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Patent number: 7335255Abstract: The present invention provides a method for removing a metal element effectively from a crystalline semiconductor film obtained with the use of the metal element, without increasing the number of processes. In the present invention, an amorphous semiconductor film is formed on an insulating surface, a metal element for promoting crystallization is added to the amorphous semiconductor film, the amorphous semiconductor film is heated to form a crystallized semiconductor film, a continuous wave laser beam is irradiated to the crystallized semiconductor film, and an upper portion of the crystallized semiconductor film is removed.Type: GrantFiled: November 26, 2003Date of Patent: February 26, 2008Assignee: Semiconductor Energy Laboratory, Co., Ltd.Inventors: Shinji Maekawa, Hidekazu Miyairi
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Patent number: 7323356Abstract: Disclosed is a method of producing an LnCuOX single-crystal thin film (wherein Ln is at least one selected from the group consisting of lanthanide elements and yttrium, and X is at least one selected from the group consisting of S, Se and Te), which comprises the steps of growing a base thin film on a single-crystal substrate, depositing an amorphous or polycrystalline LnCuOX thin film on the base thin film to form a laminated film, and then annealing the laminated film at a high temperature of 500° C. or more.Type: GrantFiled: February 19, 2003Date of Patent: January 29, 2008Assignee: Japan Science and Technology AgencyInventors: Hideo Hosono, Masahiro Hirano, Hiromichi Ota, Masahiro Orita, Hidenori Hiramatsu, Kazushige Ueda
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Patent number: 7318866Abstract: The present invention is directed to systems and methods for irradiating regions of a thin film sample(s) with laser beam pulses having different energy beam characteristics that are generated and delivered via different optical paths.Type: GrantFiled: January 9, 2004Date of Patent: January 15, 2008Assignee: The Trustees of Columbia University in the City of New YorkInventor: James Im
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Patent number: 7311771Abstract: A crystallization apparatus according to the present invention includes a first irradiation system which irradiates a predetermined area on a glass substrate having an irradiation target, i.e., an a-Si thin film with light beams having a substantially homogeneous light intensity distribution, and a second irradiation system which irradiates the predetermined area with light beams having a light intensity distribution with an inverse peak pattern that a light intensity is increased toward the periphery from an area in which the light intensity is minimum.Type: GrantFiled: March 18, 2004Date of Patent: December 25, 2007Assignee: Advanced LCD Technologies Development Center Co., Ltd.Inventors: Yukio Taniguchi, Masakiyo Matsumura
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Patent number: 7309476Abstract: Novel diamondoid-based components that may be used in nanoscale construction are disclosed. Such components include rods, brackets, screws, gears, rotors, and impellers. Subassemblies (or subsystems) may comprise one or more diamondoid components. Exemplary subassemblies include atomic force microscope tips, molecular tachometers and signal waveform generators, and self-assembling cellular membrane pores and channels.Type: GrantFiled: July 16, 2003Date of Patent: December 18, 2007Assignee: Chevron U.S.A. Inc.Inventors: Robert M. Carlson, Jeremy E. Dahl, Shenggao Liu
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Patent number: 7294539Abstract: A method of manufacturing a semiconductor device, includes: forming an insulating layer on a single crystal semiconductor substrate; forming a non-crystalline semiconductor layer on the insulating layer; forming an insulating film on the non-crystalline semiconductor layer; forming an opening section for exposing a part of a surface of the single crystal semiconductor substrate through the insulating film, the non-crystalline semiconductor layer and the insulating layer; forming a single crystal semiconductor layer embedded in the opening section so as to have contact with the non-crystalline semiconductor layer; removing the insulating film and the insulating layer while the single crystal semiconductor layer supporting the non-crystalline semiconductor layer above the single crystal semiconductor substrate; forming a single-crystallized semiconductor layer obtained by single-crystallizing the non-crystalline semiconductor layer using the single crystal semiconductor layer as a seed by providing a thermal trType: GrantFiled: March 29, 2006Date of Patent: November 13, 2007Assignee: Seiko Epson CorporationInventor: Kei Kanemoto
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Patent number: 7271042Abstract: In order to promote an effect of laser annealing in respect of a semiconductor film, moisture is intentionally included in an atmosphere in irradiating laser beam to the semiconductor film by which a temperature holding layer comprising water vapor is formed on the surface of the semiconductor film in irradiating the laser beam and the laser annealing operation can be performed effectively.Type: GrantFiled: August 20, 2004Date of Patent: September 18, 2007Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Naoto Kusumoto, Shunpei Yamazaki, Koichiro Tanaka
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Patent number: 7217319Abstract: A crystallization apparatus includes an illumination system which illuminates a phase shifter having a phase shift portion, and irradiates a polycrystal semiconductor film or an amorphous semiconductor film with a light beam having a predetermined light intensity distribution in which a light intensity is minimum in a point area corresponding to the phase shift portion of the phase shifter, thereby forming a crystallized semiconductor film, the phase shifter has four or more even-numbered phase shift lines which intersect at a point constituting the phase shift portion. An area on one side and an area on the other side of each phase shift line have a phase difference of approximately 180 degrees.Type: GrantFiled: December 1, 2003Date of Patent: May 15, 2007Assignee: Advanced LCD Technologies Development Center Co., Ltd.Inventors: Masakiyo Matsumura, Yukio Taniguchi
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Patent number: 7214574Abstract: To provide a method and a device for subjecting a film to be treated to a heating treatment effectively by a lamp annealing process, ultraviolet light is irradiated from the upper face side of a substrate where the film to be treated is formed and infrared light is irradiated from the lower face side by which the lamp annealing process is carried out. According to such a constitution, the efficiency of exciting the film to be treated is significantly promoted since electron excitation effect by the ultraviolet light irradiation is added to vibrational excitation effect by the infrared light irradiation and strain energy caused in the film to be treated by the lamp annealing process is removed or reduced by a furnace annealing process.Type: GrantFiled: May 7, 2002Date of Patent: May 8, 2007Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Shunpei Yamazaki, Hisashi Ohtani
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Patent number: 7208041Abstract: An effective, simple and low-cost a method for growing single crystals of perovskite oxideshaving primary and secondary abnormal grain growths according to temperature condition higher than a determined temperature or an atmosphere of heat treatment, involves a perovskite seed single crystal being adjoined to a polycrystal of perovskite oxides and heating the adjoined combination whereby the seed single crystal grows into the polycrystal at the interface therebetween repressing secondary abnormal grain growths inside the polycrystal. 1) The composition ratio of the polycrystal is controlled and/or the specific component(s) of the polycrystal is(are) added in an excess amount compared to the amount of the component(s) of the original composition of the polycrystal, 2) the heating is performed in the temperature range which is over primary abnormal grain growths completion temperature and below secondary abnormal grain growths activation temperature, whereby the seed single crystal grows continuously.Type: GrantFiled: May 14, 2004Date of Patent: April 24, 2007Assignee: Ceracomp Co., Ltd.Inventors: Ho-Yong Lee, Jong-Bong Lee, Tae-Moo Hur
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Patent number: 7150788Abstract: A method of adjusting the in-plane lattice constant of a substrate and an in-plane lattice constant adjusted substrate are provided. A crystalline substrate (1) made of SrTiO3 is formed at a first preestablished temperature thereon with a first epitaxial thin film (2) made of a first material, e. g., BaTiO3, and then on the first epitaxial thin film (2) with a second epitaxial thin film (6) made of a second material, e. g., BaxSr1?xTiO3 (where 0<x<1), that contains a substance of the first material and another substance which together therewith is capable of forming a solid solution in a preestablished component ratio. Thereafter, the substrate is heat-treated at a second preselected temperature. Heat treated at the second preestablished temperature, the substrate has dislocations (4) introduced therein and the second epitaxial thin film (6) has its lattice constant relaxed to a value close to the lattice constant of bulk crystal of the second material.Type: GrantFiled: August 21, 2002Date of Patent: December 19, 2006Assignee: Japan Science and Technology AgencyInventors: Hideomi Koinuma, Masashi Kawasaki, Tomoteru Fukumura, Kota Terai
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Patent number: 7108745Abstract: After a Group III-V compound semiconductor layer, to which a p-type dopant has been introduced, has been formed over a substrate, the compound semiconductor layer is annealed. In the stage of heating the compound semiconductor layer, atoms, deactivating the p-type dopant, are eliminated from the compound semiconductor layer by creating a temperature gradient in the compound semiconductor layer.Type: GrantFiled: April 16, 2003Date of Patent: September 19, 2006Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Yoshiaki Hasegawa, Ayumu Tsujimura, Isao Kidoguchi, Yuzaburo Ban
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Patent number: 7105048Abstract: Each region, which should be left on a substrate after patterning, of a semiconductor film is grasped in accordance with a mask. Then, each region to be scanned with laser light is determined so that at least the region to be obtained through the patterning is crystallized, and a beam spot is made to hit the region to be scanned, thereby partially crystallizing the semiconductor film. Each portion with low output energy of the beam spot is shielded by a slit. In the present invention, the laser light is not scanned and irradiated onto the entire surface of the semiconductor film but is scanned such that at least each indispensable portion is crystallized to a minimum. With the construction described above, it becomes possible to save time taken to irradiate the laser light onto each portion to be removed through the patterning after the crystallization of the semiconductor film.Type: GrantFiled: November 27, 2002Date of Patent: September 12, 2006Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Shunpei Yamazaki, Hisashi Ohtani, Masaaki Hiroki, Koichiro Tanaka, Aiko Shiga, Satoshi Murakami, Mai Akiba
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Patent number: 7101431Abstract: A thermal treatment process for improving the resistance of a flux grown, periodically poled KTiOPO4 crystal to photorefractive or photochromic damage comprising the steps of: i) heating said crystal from ambient temperature up to an annealing temperature in the range of from about 200° C. to about 400° C.; ii) maintaining said crystal at said annealing temperature in an oxygen containing atmosphere; iii) allowing said crystal to slowly cool down from said annealing temperature to ambient temperature.Type: GrantFiled: August 3, 2004Date of Patent: September 5, 2006Assignee: Picarro, Inc.Inventor: Carla Miner
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Patent number: 7067006Abstract: A method of forming a single crystalline structure having a substantially linear response at least over the wave lengths of 1,200 to 1,700 nanometers, the resulting structure and its use as an optical media or a barrier coating. Thus, maximum obtainable optical transmission with zero attenuation is provided. There is no intrinsic material absorption.Type: GrantFiled: October 5, 2002Date of Patent: June 27, 2006Assignee: CZT Inc.Inventor: Susana Curatolo
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Patent number: 7041580Abstract: A laser-annealing method includes the steps of a first step of cleaning a non-monocrystal silicon film formed on a substrate, and a second step of laser-annealing the non-monocrystal silicon film in an atmosphere containing oxygen therein, wherein the first and second steps are conducted continuously without being exposed to the air. Also, a laser-annealing device includes a cleaning chamber, and a laser irradiation chamber, wherein a substrate to be processed is transported between the cleaning chamber and the laser irradiation chamber without being exposed to the air.Type: GrantFiled: December 18, 2001Date of Patent: May 9, 2006Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Naoto Kusumoto, Toru Takayama, Masato Yonezawa
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Patent number: 7033435Abstract: A process for preparing p-n or n-p junctions having a p-type oxide film is disclosed. In one embodiment, a p-type zinc oxide film has a net acceptor concentration of at least about 1015 acceptors/cm3.Type: GrantFiled: July 8, 2003Date of Patent: April 25, 2006Assignee: The Curators of the University of MissouriInventors: Henry W. White, Shen Zhu, Yungryel Ryu