Processes Of Growth From Solid Or Gel State (e.g., Solid Phase Recrystallization) Patents (Class 117/4)
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Patent number: 11674237Abstract: Fabricating a crystalline metal-phosphide layer may include providing a crystalline base substrate and a step of forming a crystalline metal-source layer. The method may further include performing a chemical conversion reaction to convert the metal-source layer to the crystalline metal phosphide layer. One or more corresponding semiconductor structures can be also provided.Type: GrantFiled: May 14, 2019Date of Patent: June 13, 2023Assignee: International Business Machines CorporationInventors: Yannick Baumgartner, Bernd W. Gotsmann, Jean Fompeyrine, Lukas Czornomaz
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Patent number: 11268021Abstract: Multi-chromatic photoluminescent, oxide-capped semiconductor nanocrystals and methods for forming such semiconductor nanocrystals. The method includes exposing one or more oxide-capped semiconductors, preferably type IV semiconductor nanocrystals, to electron beam radiation, wherein the radiation has an energy between 1 and 30 keV, the radiation introducing color centers in the oxide that exhibit photoluminescence in at least the green band of the visible spectrum.Type: GrantFiled: September 8, 2017Date of Patent: March 8, 2022Inventors: Katerina Newell, Benjamin Bruhn, Benjamin Brenny
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Patent number: 10799984Abstract: Systems and methods for additive manufacturing, and, in particular, such methods and apparatus as employ pulsed lasers or other heating arrangements to create metal droplets from donor metal micro wires, which droplets, when solidified in the aggregate, form 3D structures. A supply of metal micro wire is arranged so as to be fed towards a nozzle area by a piezo translator. Near the nozzle, an end portion of the metal micro wire is heated (e.g., by a laser pulse or an electric heater element), thereby causing the end portion of the metal micro wire near the nozzle area to form a droplet of metal. A receiving substrate is positioned to receive the droplet of metal jetted from the nozzle area.Type: GrantFiled: November 9, 2018Date of Patent: October 13, 2020Assignee: Granat Research, Ltd.Inventor: Michael Zenou
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Patent number: 10485419Abstract: An optical imaging apparatus includes a splitting unit configured to split return light, obtained by applying measurement light from a light source to an object to be examined via a measurement optical path, into a plurality of beams, a light receiving unit configured to measure intensities of the beams, a changing unit configured to change a ratio of signal components of as an image to be displayed based on the measured intensities of the beams, an angle specifying unit configured to specify an angle, and a generating unit configured to generate an image by calculation using the changed ratio of the signal components. The ratio of signal components of an image to be displayed based on intensities of beams is changed in accordance with information about a specified angle to generate an image of an object such that the direction of edge enhancement on the object is changed.Type: GrantFiled: June 30, 2015Date of Patent: November 26, 2019Assignee: Canon Kabushiki KaishaInventors: Toshiaki Sato, Futoshi Hirose, Kohei Takeno, Kaishi Ohashi, Kei Suzuki, Shoichi Yamazaki
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Patent number: 10435816Abstract: An oriented alumina substrate for epitaxial growth according to an embodiment of the present invention includes crystalline grains constituting a surface thereof, the crystalline grains having a tilt angle of 1° or more and 3° or less and an average sintered grain size of 20 ?m or more.Type: GrantFiled: February 22, 2018Date of Patent: October 8, 2019Assignee: NGK Insulators, Ltd.Inventors: Morimichi Watanabe, Kei Sato, Kiyoshi Matsushima, Tsutomu Nanataki
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Patent number: 10435815Abstract: An oriented alumina substrate for epitaxial growth according to an embodiment of the present invention includes crystalline grains constituting a surface thereof, the crystalline grains having a tilt angle of 0.1° or more and less than 1.0° and an average sintered grain size of 10 ?m or more.Type: GrantFiled: February 22, 2018Date of Patent: October 8, 2019Assignee: NGK Insulators, Ltd.Inventors: Morimichi Watanabe, Kei Sato, Kiyoshi Matsushima, Tsutomu Nanataki
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Patent number: 10427949Abstract: An alumina sintered body of the present invention has a degree of c-plane orientation of 5% or more, which is determined by a Lotgering method using an X-ray diffraction profile in a range of 2?=20° to 70° obtained under X-ray irradiation, and an XRC half width of 15.0° or less in rocking curve measurement, an F content of less than 0.99 mass ppm when measured by D-SIMS, a crystal grain diameter of 15 to 200 ?m, and 25 or less pores having a diameter of 0.2 ?m to 1.0 ?m when a photograph of a viewing area 370.0 ?m in a vertical direction and 372.0 ?m in a horizontal direction taken at a magnification factor of 1000 is visually observed.Type: GrantFiled: March 1, 2018Date of Patent: October 1, 2019Assignee: NGK Insulators, Ltd.Inventors: Kiyoshi Matsushima, Morimichi Watanabe, Kei Sato, Tsutomu Nanataki
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Patent number: 10301742Abstract: To provide a lithium niobate (LN) substrate which allows treatment conditions regarding a temperature, a time, and the like to be easily managed and in which an in-plane distribution of a volume resistance value is very small, and a method of producing the same. A method of producing an LN substrate by using an LN single crystal grown by the Czochralski process, in which an LN single crystal having a Fe concentration of 50 mass ppm or more and 1000 mass ppm or less in the single crystal and processed into a form of a substrate is buried in an Al powder or a mixed powder of Al and Al2O3, and heat-treated at a temperature of 350° C. or more and less than 450° C., to produce a lithium niobate single crystal substrate having a volume resistivity controlled to be within a range of more than 1×1010 ?·cm to 2×1012 ?·cm or less.Type: GrantFiled: June 8, 2016Date of Patent: May 28, 2019Assignee: SUMITOMO METAL MINING CO., LTD.Inventor: Tomio Kajigaya
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Patent number: 10276302Abstract: Process for treating a magnetic structure, wherein it comprises the following steps: providing a magnetic structure comprising one first layer of magnetic material comprising a CoFeB alloy; irradiating the magnetic structure with light low-energy ions; and simultaneously holding the magnetic structure with a preset temperature profile and for a preset time.Type: GrantFiled: February 21, 2014Date of Patent: April 30, 2019Assignees: Centre National de la Recherche Scientifique (CNRS), Universite Paris SUD (Paris II)Inventor: Dafine Ravelosona
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Patent number: 10112873Abstract: A three-dimensional (3D) printing composition includes ceramic filaments comprising an additive having an aspect ratio of at least 2:1. 3D printed ceramic articles include the ceramic filaments.Type: GrantFiled: May 29, 2015Date of Patent: October 30, 2018Assignee: RAYTHEON COMPANYInventor: Christopher S. Nordahl
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Patent number: 9994971Abstract: A method for fabricating a carbon-based composite material includes: bearing a carbon-based composite material layer containing an amorphous carbon matrix and a plurality of equi-axed ultrananocrystalline diamond grains dispersed in the amorphous carbon matrix on a susceptor and applying a plasma treatment on the carbon-based composite material layer in a plasma environment containing a C2 species and a CN species. The susceptor is provided with a negative bias voltage, and is bombarded by the plasma species to be naturally heated to a working temperature less than 500° C. The C2 species and CN species are attracted by the negative bias voltage to the carbon-based composite material layer to make the carbon-based composite material layer generate a phase transformation, so as to facilitate growth of each of the adjacent equi-axed ultrananocrystalline diamond into a nano needle-like diamond grain wrapped by a nano graphite phase.Type: GrantFiled: December 1, 2016Date of Patent: June 12, 2018Assignee: TAMKANG UNIVERSITYInventor: I-Nan Lin
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Patent number: 9793686Abstract: A semiconductor device comprising a silicon substrate on which is grown a <100 nm thick epilayer of AlAs or related compound, followed by a compound semiconductor other than GaN buffer layer. Further III-V compound semiconductor structures can be epitaxially grown on top. The AlAs epilayer reduces the formation and propagation of defects from the interface with the silicon, and so can improve the performance of an active structure grown on top.Type: GrantFiled: April 15, 2016Date of Patent: October 17, 2017Assignee: UCL Business PLCInventors: Huiyun Liu, Andrew David Lee, Alwyn John Seeds
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Patent number: 9731262Abstract: The present invention relates to a method for preparing an aqueous or hydro-alcoholic colloidal solution of metal chalcogenide amorphous nanoparticles notably of the Cu2ZnSnS4 (CZTS) type and to the obtained colloidal solution. The present invention also relates to a method for manufacturing a film of large-grain crystallized semi-conducting metal chalcogenide film notably of CZTS obtained from an aqueous or hydro-alcoholic colloidal solution according to the invention, said film being useful as an absorption layer deposited on a substrate applied in a solid photovoltaic device.Type: GrantFiled: July 4, 2013Date of Patent: August 15, 2017Assignee: IMRA EUROPE SASInventors: Stephane Bourdais, Christophe Chone, Yan Cuccaro
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Patent number: 9184246Abstract: A silicon carbide substrate has a first main surface, and a second main surface opposite to the first main surface. A region including at least one main surface of the first and second main surfaces is made of single-crystal silicon carbide. In the one main surface, sulfur atoms are present at not less than 60×1010 atoms/cm2 and not more than 2000×1010 atoms/cm2, and carbon atoms as an impurity are present at not less than 3 at % and not more than 25 at %. Thereby, a silicon carbide substrate having a stable surface, a semiconductor device using the substrate, and methods for manufacturing them can be provided.Type: GrantFiled: February 26, 2013Date of Patent: November 10, 2015Assignee: SUMITOMO ELECTRIC INDUSTRIES, LTD.Inventor: Keiji Ishibashi
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Patent number: 9130111Abstract: The present invention provides a method for manufacturing a monocrystalline film and a device formed by the above method, and according to the method mentioned above, lift-off of the monocrystalline silicon film is preferably performed and a high-purity monocrystalline silicon film can be obtained. A monocrystalline silicon substrate (template Si substrate) 201 is prepared, and on this monocrystalline silicon substrate 201, an epitaxial sacrificial layer 202 is formed. Subsequently, on this sacrificial layer 202, a monocrystalline silicon thin film 203 is rapidly epitaxially-grown using a RVD method, followed by etching of the sacrificial layer 202, whereby a monocrystalline silicon thin film 204 used as a photovoltaic layer of solar cells is formed.Type: GrantFiled: December 8, 2010Date of Patent: September 8, 2015Assignee: JAPAN SCIENCE AND TECHNOLOGY AGENCYInventor: Suguru Noda
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Patent number: 9039832Abstract: A high pressure high temperature (HPHT) method for synthesizing single crystal diamond, wherein a single crystal diamond seed having an aspect ratio of at least (1) and a growth surface substantially parallel to a {110} crystallographic plane is utilized is described. The growth is effected at a temperature in the range from 1280° C. to 1390° C.Type: GrantFiled: January 15, 2010Date of Patent: May 26, 2015Assignee: Element Six Technologies LimitedInventors: Raymond Anthony Spits, Carlton Nigel Dodge
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Patent number: 9034102Abstract: A method of fabricating a hybrid orientation substrate is described. A silicon substrate with a first orientation having a silicon layer with a second orientation directly thereon is provided, and then a stress layer is formed on the silicon layer. A trench is formed between a first portion and a second portion of the silicon layer through the stress layer and into the substrate. The first portion of the silicon layer is amorphized. A SPE process is performed to recrystallize the amorphized first portion of the silicon layer to be a recrystallized layer with the first orientation. An annealing process is performed at a temperature lower than 1200° C. to convert a surface layer of the second portion of the silicon layer to a strained layer. The trench is filled with an insulating material after the SPE process or the annealing process, and the stress layer is removed.Type: GrantFiled: March 29, 2007Date of Patent: May 19, 2015Assignee: UNITED MICROELECTRONICS CORP.Inventors: Yao-Tsung Huang, Chien-Ting Lin, Che-Hua Hsu, Guang-Hwa Ma
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Patent number: 9034104Abstract: A larger substrate can be used, and a transistor having a desirably high field-effect mobility can be manufactured through formation of an oxide semiconductor layer having a high degree of crystallinity, whereby a large-sized display device, a high-performance semiconductor device, or the like can be put into practical use. A single-component oxide semiconductor layer is formed over a substrate; then, crystal growth is carried out from a surface to an inside by performing heat treatment at 500° C. to 1000° C. inclusive, preferably 550° C. to 750° C. inclusive so that a single-component oxide semiconductor layer including single crystal regions is formed; and a multi-component oxide semiconductor layer including single crystal regions is stacked over the single-component oxide semiconductor layer including single crystal regions.Type: GrantFiled: December 15, 2010Date of Patent: May 19, 2015Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Shunpei Yamazaki, Takuya Hirohashi, Masahiro Takahashi, Takashi Shimazu
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Patent number: 8999058Abstract: This disclosure enables high-productivity fabrication of semiconductor-based separation layers (made of single layer or multi-layer porous semiconductors such as porous silicon, comprising single porosity or multi-porosity layers), optical reflectors (made of multi-layer/multi-porosity porous semiconductors such as porous silicon), formation of porous semiconductor (such as porous silicon) for anti-reflection coatings, passivation layers, and multi-junction, multi-band-gap solar cells (for instance, by forming a variable band gap porous silicon emitter on a crystalline silicon thin film or wafer-based solar cell). Other applications include fabrication of MEMS separation and sacrificial layers for die detachment and MEMS device fabrication, membrane formation and shallow trench isolation (STI) porous silicon (using porous silicon formation with an optimal porosity and its subsequent oxidation).Type: GrantFiled: May 5, 2010Date of Patent: April 7, 2015Assignee: Solexel, Inc.Inventors: George D. Kamian, Somnath Nag, Subbu Tamilmani, Mehrdad M. Moslehi, Karl-Josef Kramer, Takao Yonehara
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Patent number: 8956453Abstract: The present invention provides a method for providing a crystalline germanium layer on a crystalline base substrate having a crystalline surface. The method comprises cleaning the base substrate for removing contaminants and/or native oxides from the surface, providing an amorphous germanium layer on the surface of the base substrate while exposing to the base substrate to a hydrogen source such as e.g. a hydrogen plasma, a H2 flux or hydrogen originating from dissociation of GeH4 and/or to a non-reactive gas source such as N2, He, Ne, Ar, Kr, Xe, Rn or mixtures thereof, and crystallizing the amorphous germanium layer by annealing the base substrate so as to provide a crystalline germanium layer.Type: GrantFiled: July 18, 2008Date of Patent: February 17, 2015Assignees: IMEC, Vrije Universiteit BrusselInventors: Ruben Lieten, Stefan Degroote
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Publication number: 20150024177Abstract: Disclosed is a method of fabricating a single crystal colloidal monolayer on a substrate. The method includes preparing a pair of adhesive substrates, arranging powder particles between the substrates, and uniaxially rubbing one of the substrates in any one direction to allow the particles to be close-packed between the substrates, thereby forming a single crystal monolayer.Type: ApplicationFiled: July 15, 2014Publication date: January 22, 2015Inventors: Unyong JEONG, JaeMin MYOUNG, Taeil LEE, ChooJin PARK
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Patent number: 8894765Abstract: A PIN-PMN-PT ferroelectric single crystal and a method of manufacture are disclosed. The PIN-PMN-PT ferroelectric single crystal is oriented and polarized along a single crystallographic direction. The PIN-PMN-PT ferroelectric single crystal ferroelectric has increased remnant polarization.Type: GrantFiled: November 12, 2010Date of Patent: November 25, 2014Assignee: TRS Technologies, Inc.Inventors: Wesley S. Hackenberger, Edward F. Alberta
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Patent number: 8895416Abstract: Systems and methods for semiconductor device PN junction fabrication are provided. In one embodiment, a method for fabricating an electrical device having a P-N junction comprises: depositing a layer of amorphous semiconductor material onto a crystalline semiconductor base, wherein the crystalline semiconductor base comprises a crystalline phase of a same semiconductor as the amorphous layer; and growing the layer of amorphous semiconductor material into a layer of crystalline semiconductor material that is epitaxially matched to the lattice structure of the crystalline semiconductor base by applying an optical energy that penetrates at least the amorphous semiconductor material.Type: GrantFiled: March 11, 2013Date of Patent: November 25, 2014Assignee: Alliance for Sustainable Energy, LLCInventors: Bhushan Sopori, Anikara Rangappan
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Patent number: 8871022Abstract: The disclosed subject matter relates to the use of laser crystallization of thin films to create epitaxially textured crystalline thick films. In one or more embodiments, a method for preparing a thick crystalline film includes providing a film for crystallization on a substrate, wherein at least a portion of the substrate is substantially transparent to laser irradiation, said film including a seed layer having a predominant surface crystallographic orientation; and a top layer disposed above the seed layer; irradiating the film from the back side of the substrate using a pulsed laser to melt a first portion of the top layer at an interface with the seed layer while a second portion of the top layer remains solid; and re-solidifying the first portion of the top layer to form a crystalline laser epitaxial with the seed layer thereby releasing heat to melt an adjacent portion of the top layer.Type: GrantFiled: October 14, 2013Date of Patent: October 28, 2014Assignee: The Trustees of Columbia University in the City of New YorkInventor: James S. Im
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Patent number: 8864907Abstract: A condition of a single crystal manufacturing step subjected to the Czochralski method applying an initial oxygen concentration, a dopant concentration or resistivity, and a heat treatment condition is determined simply and clearly on the basis of the conditions of a wafer manufacturing step and a device step so as to obtain a silicon wafer having a desired gettering capability. A manufacturing method of a silicon substrate which is manufactured from a silicon single crystal grown by the CZ method and provided for manufacturing a solid-state imaging device is provided. The internal state of the silicon substrate, which depends on the initial oxygen concentration, the carbon concentration, the resistivity, and the pulling condition of the silicon substrate, is determined by comparing a white spot condition representing upper and lower limits of the density of white spots as device characteristics with the measured density of white spots.Type: GrantFiled: March 4, 2009Date of Patent: October 21, 2014Assignee: Sumco CorporationInventors: Kazunari Kurita, Shuichi Omote
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Publication number: 20140219902Abstract: The presently disclosed and/or claimed inventive concept(s) relates generally to hexagonal osmium boride, OsB2, and methods of producing the same. In one non-limiting embodiment, hexagonal OsB2 is produced by mechanochemical synthesis of osmium and boron in a high energy ball mill.Type: ApplicationFiled: January 16, 2014Publication date: August 7, 2014Applicant: University of Central Florida Research Foundation, Inc.Inventors: Nina Orlovskaya, Zhilin Xie, Richard G. Blair
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Patent number: 8734583Abstract: One aspect of the present subject matter relates to a method for forming a transistor. According to an embodiment, a fin of amorphous semiconductor material is formed on a crystalline substrate, and a solid phase epitaxy (SPE) process is performed to crystallize the amorphous semiconductor material using the crystalline substrate to seed the crystalline growth. The fin has a cross-sectional thickness in at least one direction less than a minimum feature size. The transistor body is formed in the crystallized semiconductor pillar between a first source/drain region and a second source/drain region. A surrounding gate insulator is formed around the semiconductor pillar, and a surrounding gate is formed around and separated from the semiconductor pillar by the surrounding gate insulator. Other aspects are provided herein.Type: GrantFiled: April 4, 2006Date of Patent: May 27, 2014Assignee: Micron Technology, Inc.Inventor: Leonard Forbes
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Publication number: 20140119981Abstract: A Bi1-xSbx thin film is provided that includes a Dirac-cone with different degrees of anisotropy in their electronic band structure by controlling the stoichiometry, film thickness, and growth orientation of the thin film, so as to result in a consistent inverse-effective mass tensor including non-parabolic or linear dispersion relations.Type: ApplicationFiled: October 25, 2012Publication date: May 1, 2014Applicant: Massachusetts Institute of TechnologyInventors: Shuang Tang, Mildred S. Dresselhaus
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Publication number: 20140102355Abstract: Methods of producing a polarization-modulating element that modulates a polarization state of incident light into a predetermined polarization state, the polarization-modulating element being used with an illumination optical apparatus, include preparing an optical material having optical activity, and providing the optical material with a circumferentially varying thickness profile and a central region that is an aperture having no optical activity. The thickness profile is set so that light in a linearly polarized state having a direction of polarization substantially along a single direction, is transformed into light in an azimuthal polarization state having a direction of polarization substantially along a circumferential direction or into light in a radially polarized state having a direction of polarization substantially along the radial direction.Type: ApplicationFiled: December 17, 2013Publication date: April 17, 2014Applicant: Carl Zeiss SMT GmbHInventors: Damian Fiolka, Markus Deguenther
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Patent number: 8696808Abstract: Each region, which should be left on a substrate after patterning, of a semiconductor film is grasped in accordance with a mask. Then, each region to be scanned with laser light is determined so that at least the region to be obtained through the patterning is crystallized, and a beam spot is made to hit the region to be scanned, thereby partially crystallizing the semiconductor film. Each portion with low output energy of the beam spot is shielded by a slit. In the present invention, the laser light is not scanned and irradiated onto the entire surface of the semiconductor film but is scanned such that at least each indispensable portion is crystallized to a minimum. With the construction described above, it becomes possible to save time taken to irradiate the laser light onto each portion to be removed through the patterning after the crystallization of the semiconductor film.Type: GrantFiled: September 5, 2006Date of Patent: April 15, 2014Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Shunpei Yamazaki, Hisashi Ohtani, Masaaki Hiroki, Koichiro Tanaka, Aiko Shiga, Satoshi Murakami, Mai Akiba
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Patent number: 8673073Abstract: A method for purifying silicon bearing materials for photovoltaic applications includes providing metallurgical silicon into a crucible apparatus. The metallurgical silicon is subjected to at least a thermal process to cause the metallurgical silicon to change in state from a first state to a second state, the second stage being a molten state not exceeding 1500 Degrees Celsius. At least a first portion of impurities is caused to be removed from the metallurgical silicon in the molten state. The molten metallurgical silicon is cooled from a lower region to an upper region to cause the lower region to solidify while a second portion of impurities segregate and accumulate in a liquid state region. The liquid state region is solidified to form a resulting silicon structure having a purified region and an impurity region. The purified region is characterized by a purity of greater than 99.9999%.Type: GrantFiled: July 3, 2012Date of Patent: March 18, 2014Inventors: Masahiro Hoshino, Cheng C. Kao
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Patent number: 8663491Abstract: High quantum yield InP nanocrystals are used in the bio-technology, bio-medical, and photovoltaic, specifically IV, III-V and III-VI nanocrystal technological applications. InP nanocrystals typically require post-generation HF treatment. Combining microwave methodologies with the presence of a fluorinated ionic liquid allows Fluorine ion etching without the hazards accompanying HF. Growing the InP nanocrystals in the presence of the ionic liquid allows in-situ etching to be achieved. The optimization of the PL QY is achieved by balancing growth and etching rates in the reaction.Type: GrantFiled: October 5, 2012Date of Patent: March 4, 2014Assignee: The Florida State University Research Foundation, Inc.Inventors: Geoffrey F. Strouse, Derek D. Lovingood
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Patent number: 8663387Abstract: A method and system for processing at least one portion of a thin film sample on a substrate, with such portion of the film sample having a first boundary and a second boundary. One or more first areas of the film sample are successively irradiated by first beamlets of an irradiation beam pulse so that the first areas are melted throughout their thickness and allowed to re-solidify and crystallize thereby having grains grown therein. Thereafter, one or more second areas of the film sample are irradiated by second beamlets so that the second areas are melted throughout their thickness. At least two of the second areas partially overlap a particular area of the re-solidified and crystallized first areas such that the grains provided in the particular area grow into each of the at least two second areas upon re-solidification thereof.Type: GrantFiled: March 9, 2006Date of Patent: March 4, 2014Assignee: The Trustees of Columbia University in the City of New YorkInventor: James S. Im
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Patent number: 8580031Abstract: A method of producing a three-dimensional photonic crystal by laminating a layer having a periodic structure, the method including the steps of forming a first structure and a second structure each including the layer having the periodic structure; and bonding a first bonding layer of the first structure and a second bonding layer of the second structure. The first bonding layer is one layer obtained by dividing a layer constituting the three-dimensional photonic crystal at a cross section perpendicular to a lamination direction, and the second bonding layer is the other layer obtained by dividing the layer constituting the three-dimensional photonic crystal at the cross section perpendicular to the lamination direction.Type: GrantFiled: April 6, 2010Date of Patent: November 12, 2013Assignee: Canon Kabushiki KaishaInventors: Aihiko Numata, Hikaru Hoshi, Kenji Tamamori
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Patent number: 8557040Abstract: The disclosed subject matter relates to the use of laser crystallization of thin films to create epitaxially textured crystalline thick films. In one or more embodiments, a method for preparing a thick crystalline film includes providing a film for crystallization on a substrate, wherein at least a portion of the substrate is substantially transparent to laser irradiation, said film including a seed layer having a predominant surface crystallographic orientation; and a top layer disposed above the seed layer; irradiating the film from the back side of the substrate using a pulsed laser to melt a first portion of the top layer at an interface with the seed layer while a second portion of the top layer remains solid; and re-solidifying the first portion of the top layer to form a crystalline laser epitaxial with the seed layer thereby releasing heat to melt an adjacent portion of the top layer.Type: GrantFiled: November 21, 2008Date of Patent: October 15, 2013Assignee: The Trustees of Columbia University in the City of New YorkInventor: James S. Im
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Patent number: 8506703Abstract: A method for forming colloidal photonic crystals comprises; surrounding an outer circumference of a cylinder with a flexible substrate, spacing the cylinder a predetermined distance from a panel coated with a colloidal solution, and rotating the cylinder to form colloidal photonic crystals on the flexible panel.Type: GrantFiled: January 26, 2009Date of Patent: August 13, 2013Assignee: Samsung Display Co., Ltd.Inventors: Young-sang Cho, Mi-jeong Song, Hong-seok Lee
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Patent number: 8475588Abstract: A wafer structure and epitaxial growth method for growing the same. The method may include forming a mask layer having nano-sized areas on a wafer, forming a porous layer having nano-sized pores on a surface of the wafer by etching the mask layer and a surface of the wafer, and forming an epitaxial material layer on the porous layer using an epitaxial growth process.Type: GrantFiled: March 13, 2009Date of Patent: July 2, 2013Assignee: Samsung Corning Precision Materials Co., Ltd.Inventor: Sung-Soo Park
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Patent number: 8470089Abstract: The invention relates to a process for manufacturing a single crystal comprising a rare-earth halide, having improved machining or cleavage behavior, comprising heat treatment in a furnace, the atmosphere of which is brought, for at least 1 hour, to between 0.70 times Tm and 0.995 times Tm of a single crystal comprising a rare-earth halide, Tm representing the melting point of said single crystal, the temperature gradient at any point in the atmosphere of the furnace being less than 15 K/cm for said heat treatment. After carrying out the treatment according to the invention, the single crystals may be machined or cleaved without uncontrolled fracture. The single crystals may be used in a medical imaging device, especially a positron emission tomography system or a gamma camera or a CT scanner, for crude oil exploration, for detection and identification of fissile or radioactive materials, for nuclear and high-energy physics, for astrophysics or for industrial control.Type: GrantFiled: May 15, 2008Date of Patent: June 25, 2013Assignee: Saint-Gobain Cristaux et DetecteursInventors: Dominique Richaud, Alain Iltis, Vladimir Ouspenski
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Patent number: 8460461Abstract: The present invention provides an oriented substrate for forming an epitaxial thin film thereon, which has a more excellent orientation than that of a conventional one and a high strength, and a method for manufacturing the same. The present invention provides a clad textured metal substrate for forming the epitaxial thin film thereon, which includes a metallic layer and a silver layer bonded to at least one face of the metallic layer, wherein the silver layer has a {100}<001> cube texture in which a deviating angle ?? of crystal axes satisfies ???9 degree. The textured metal substrate can be manufactured by subjecting the silver sheet containing 30 to 200 ppm oxygen by concentration to the orienting treatment of hot-working and heat-treating, and bonding the metal sheet with the oriented silver sheet by using a surface activated bonding process.Type: GrantFiled: August 15, 2012Date of Patent: June 11, 2013Assignees: Chubu Electric Power Co., Ltd., Tanaka Kikinzoku Kogyo. K.K.Inventors: Naoji Kashima, Shigeo Nagaya, Kunihiro Shima, Hirofumi Hoshino
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Patent number: 8449671Abstract: A method of fabricating an SiC single crystal includes (a) physical vapor transport (PVT) growing a SiC single crystal on a seed crystal in the presence of a temperature gradient, wherein an early-to-grow portion of the SiC single crystal is at a lower temperature than a later-to-grow portion of the SiC single crystal. Once grown, the SiC single crystal is annealed in the presence of a reverse temperature gradient, wherein the later-to-grow portion of the SiC single crystal is at a lower temperature than the early-to-grow portion of the SiC single crystal.Type: GrantFiled: June 26, 2008Date of Patent: May 28, 2013Assignee: II-VI IncorporatedInventors: Ping Wu, Ilya Zwieback, Avinesh K. Gupta, Edward Semenas
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Patent number: 8435418Abstract: High quantum yield InP nanocrystals are used in the bio-technology, bio-medical, and photovoltaic, specifically IV, III-V and III-VI nanocrystal technological applications. InP nanocrystals typically require post-generation HF treatment. Combining microwave methodologies with the presence of a fluorinated ionic liquid allows Fluorine ion etching without the hazards accompanying HF. Growing the InP nanocrystals in the presence of the ionic liquid allows in-situ etching to be achieved. The optimization of the PL QY is achieved by balancing growth and etching rates in the reaction.Type: GrantFiled: October 5, 2012Date of Patent: May 7, 2013Assignee: The Florida State University Research Foundation, Inc.Inventors: Geoffrey F. Strouse, Derek D. Lovingood
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Patent number: 8394194Abstract: A method of forming a layer of amorphous silicon oxide positioned between a layer of rare earth oxide and a silicon substrate. The method includes providing a crystalline silicon substrate and depositing a layer of rare earth metal on the silicon substrate in an oxygen deficient ambient at a temperature above approximately 500° C. The rare earth metal forms a layer of rare earth silicide on the substrate. A first layer of rare earth oxide is deposited on the layer of rare earth silicide with a structure and lattice constant substantially similar to the substrate. The structure is annealed in an oxygen ambience to transform the layer of rare earth silicide to a layer of amorphous silicon and an intermediate layer of rare earth oxide between the substrate and the first layer of rare earth oxide.Type: GrantFiled: June 13, 2012Date of Patent: March 12, 2013Inventors: Rytis Dargis, Andrew Clark, Robin Smith, Michael Lebby
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Patent number: 8357308Abstract: High quantum yield InP nanocrystals are used in the bio-technology, bio-medical, and photovoltaic, specifically IV, III-V and III-VI nanocrystal technological applications. InP nanocrystals typically require post-generation HF treatment. Combining microwave methodologies with the presence of a fluorinated ionic liquid allows Fluorine ion etching without the hazards accompanying HF. Growing the InP nanocrystals in the presence of the ionic liquid allows in-situ etching to be achieved. The optimization of the PL QY is achieved by balancing growth and etching rates in the reaction.Type: GrantFiled: August 29, 2008Date of Patent: January 22, 2013Assignee: Florida State University Research Foundation, Inc.Inventors: Geoffrey F. Strouse, Derek D. Lovingood
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Patent number: 8337618Abstract: A silicon crystallization system includes a vibration device for vibrating a linear laser beam along a longer-axis direction of the linear laser beam. A vibration frequency at which the laser beam is vibrated is periodically generated and randomly changes within a predetermined range.Type: GrantFiled: October 26, 2010Date of Patent: December 25, 2012Assignee: Samsung Display Co., Ltd.Inventors: Oh-Seob Kwon, Sang-Jo Lee, Hong-Ro Lee, Je-Kil Ryu
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Publication number: 20120315482Abstract: There are provided a cluster of thin sheet graphite crystals or the like which is useful as an electrode material for lithium ion batteries, hybrid capacitors and the like, and a method for efficiently producing the same at high productivity. The method is one for producing a cluster of thin sheet graphite crystals composed of aggregates in such a state that thin sheet graphite crystals extend from the inside toward the outside, comprising charging a powdery and/or particulate material of an organic compound pre-baked to an extent of containing remaining hydrogen in a graphite vessel, and subjecting the powdery and/or particulate material together with the vessel to hot isostatic pressing treatment (HIP treatment) using a compressed gas atmosphere under the predetermined conditions.Type: ApplicationFiled: February 18, 2011Publication date: December 13, 2012Inventors: Kazuo Muramatsu, Masahiro Toyoda
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Patent number: 8287643Abstract: The present invention provides an oriented substrate for forming an epitaxial thin film thereon, which has a more excellent orientation than that of a conventional one and a high strength, and a method for manufacturing the same. The present invention provides a clad textured metal substrate for forming the epitaxial thin film thereon, which includes a metallic layer and a silver layer bonded to at least one face of the metallic layer, wherein the silver layer has a {100}<001> cube texture in which a deviating angle ?? of crystal axes satisfies ???9 degree. The textured metal substrate can be manufactured by subjecting the silver sheet containing 30 to 200 ppm oxygen by concentration to the orienting treatment of hot-working and heat-treating, and bonding the metal sheet with the oriented silver sheet by using a surface activated bonding process.Type: GrantFiled: April 11, 2008Date of Patent: October 16, 2012Assignees: Chubu Electric Power Co., Inc., Tanaka Kikinzoku Kogyo K.K.Inventors: Naoji Kashima, Shigeo Nagaya, Kunihiro Shima, Hirofumi Hoshino
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Patent number: 8257492Abstract: A method for purifying silicon bearing materials for photovoltaic applications includes providing metallurgical silicon into a crucible apparatus. The metallurgical silicon is subjected to at least a thermal process to cause the metallurgical silicon to change in state from a first state to a second state, the second stage being a molten state not exceeding 1500 Degrees Celsius. At least a first portion of impurities is caused to be removed from the metallurgical silicon in the molten state. The molten metallurgical silicon is cooled from a lower region to an upper region to cause the lower region to solidify while a second portion of impurities segregate and accumulate in a liquid state region. The liquid state region is solidified to form a resulting silicon structure having a purified region and an impurity region. The purified region is characterized by a purity of greater than 99.9999%.Type: GrantFiled: November 16, 2010Date of Patent: September 4, 2012Inventors: Masahiro Hoshino, Cheng C. Kao
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Patent number: 8258603Abstract: A solid-state far ultraviolet light emitting element is formed by a hexagonal boron nitride single crystal, excited by electron beam irradiation to emit far ultraviolet light having a maximum light emission peak in a far ultraviolet region at a wavelength of 235 nm or shorter.Type: GrantFiled: October 16, 2009Date of Patent: September 4, 2012Assignee: National Institute for Materials ScienceInventors: Kenji Watanabe, Takashi Taniguchi, Satoshi Koizumi, Hisao Kanda, Masayuki Katagiri, Takatoshi Yamada, Nesladek Milos
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Patent number: 8257494Abstract: One provides nanocrystalline diamond material that comprises a plurality of substantially ordered diamond crystallites that are sized no larger than about 10 nanometers. One then disposes a non-diamond component within the nanocrystalline diamond material. By one approach this non-diamond component comprises an electrical conductor that is formed at the grain boundaries that separate the diamond crystallites from one another. The resultant nanowire is then able to exhibit a desired increase with respect to its ability to conduct electricity while also preserving the thermal conductivity behavior of the nanocrystalline diamond material.Type: GrantFiled: December 13, 2010Date of Patent: September 4, 2012Assignee: Dimerond Technologies, LLCInventor: Dieter M. Gruen
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Publication number: 20120214068Abstract: Graphene based materials are provided in connection with various devices and methods of manufacturing. As consistent with one or more embodiments, an apparatus includes a graphene sheet and a single-crystal structure grown on the graphene sheet, with the graphene sheet and single-crystalline structure functioning as an electrode terminal. In various embodiments, the single-crystalline structure is grown on a graphene sheet, such as by using precursor particles to form nanoparticles at the distributed locations, and diffusing and recrystallizing the nanoparticles to form the single-crystal structure.Type: ApplicationFiled: February 21, 2012Publication date: August 23, 2012Inventors: Hongjie DAI, Hailiang WANG