Nine Percent Or More Chromium Containing Patents (Class 148/325)
  • Patent number: 7396421
    Abstract: A duplex stainless steel containing C, Si, Mn, P, S, Al, Ni, Cr, Mo, N (nitrogen, O (oxygen), Ca, Mg, Cu, B, and W, and the balance Fe and impurities, where a number of oxide-based inclusions, which have a total content of Ca and Mg of 20 to 40% by mass and also have a long diameter of not less than 7 ?m, is not more than a 10 per 1 mm2 of the cross section perpendicular to the working direction, or further, the number of oxide-based inclusions, which have a content of S of not less than 15% by mass and also have a long diameter of not less than 1 ?m, is not more than 10 per 0.1 mm2 of the cross section perpendicular to the working direction. Particularly, the contents of Cu, B and W are desirably 0.2 to 2%, 0.001 to 0.01%, and 0.1 to 4% by mass, respectively.
    Type: Grant
    Filed: May 24, 2005
    Date of Patent: July 8, 2008
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Tomohiko Omura, Satoshi Matsumoto
  • Patent number: 7377989
    Abstract: A steel tube excellent in exfoliation resistance of scale on its inner surface is provided. The steel tube includes 9 to 28% by mass of Cr and has a maximum height of profile (Rz) on the inner surface after cold working of 15 ?m or more. Preferably ?Hv of the tube is 100 or more, wherein ?Hv is the difference in Vickers hardness between an inner surface layer and a thickness center part of the tube. The steel may desirably have a microstructure of ASTM austenite grain size No. 7. or more.
    Type: Grant
    Filed: June 24, 2005
    Date of Patent: May 27, 2008
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventor: Hiroshi Matsuo
  • Patent number: 7361236
    Abstract: A martensitic stainless steel having a C content of 0.01 to 0.1 mass %, a Cr content of 9 to 15 mass % and a N content of not more than 0.1 mass %, wherein the maximum length of the carbides in the steel is 10 to 200 nm in the direction of the minor axis, or wherein the ratio of the average Cr concentration [Cr] to the average Fe concentration [Fe] in carbides in the steel ([Cr]/[Fe]) is not more than 0.4, or wherein the content of M23C6 type carbides is not more than 1 volume %, the content of M3C type carbides is 0.01 to 1.5 volume % and the content of MN type or M2N type nitrides is not more than 0.3 volume % is provided. This stainless steel has a high toughness in spite of both a relatively more C content and a high strength, thereby providing a, wide applicability to pipe material for oil wells containing carbon dioxide and a small amount of hydrogen sulfide, in particular for oil wells having a much greater depth.
    Type: Grant
    Filed: April 11, 2003
    Date of Patent: April 22, 2008
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Kunio Kondo, Takahiro Kushida, Yuichi Komizo, Masaaki Igarashi
  • Patent number: 7347903
    Abstract: A duplex stainless steel for use in urea manufacturing plants, in mass %, consisting of C: 0.03% or less, Si: 0.5% or less, Mn: 2% or less, P: 0.04% or less, S: 0.003% or less, Cr: 26% or more, but less than 28%, Ni: 6-10%, Mo: 0.2-1.7%, W: more than 2%, but no more than 3%, N: more than 0.3%, but no more than 0.4%, with the balance being Fe and impurities, in which the content of Cu as an impurity is not more than 0.3%. The duplex stainless steel may also have Ca, Ce, and B content, and it is desirable that levels of Al and O (oxygen) as an impurities be no more than 0.05% and 0.01% respectively. Further, it is preferable that an increase in the Vickers hardness of the steel should not be more than 80, before and after the solution treated steel is subjected to the heat treatment of 800° C. for 30 minutes and subsequent water cooling. This duplex stainless steel possesses a high corrosion resistance.
    Type: Grant
    Filed: January 29, 2003
    Date of Patent: March 25, 2008
    Assignees: Sumitomo Metal Industries, Ltd., Toyo Engineering Corporation
    Inventors: Yoshimi Yamadera, Eiki Nagashima
  • Patent number: 7341637
    Abstract: A ferritic stainless steel sheet excellent in press formability and operability, characterized by: containing appropriate amounts of C, N, Cr, Si, Mn, P, S, Al, Ti and V, with the balance consisting of Fe and unavoidable impurities; having a solid lubricating film or films on one or both of the surfaces; and having a ratio Z, defined as Z=Z1/Z2, of less than 0.5, a tensile strength of 450 MPa or less and an average r-value of 1.7 or more, wherein Z1 is a friction coefficient of the surface of a solid lubricating film and Z2 that of the surface of a reference material coated with neither a coating nor lubricating oil. In the ferritic stainless steel sheet, the amounts of Sol-Ti and Insol-V may be regulated to appropriate ranges, wherein Sol-Ti means the amount of Ti existing in the state of solid solution in steel and Insol-V means the amount of V existing in the state of precipitation in steel.
    Type: Grant
    Filed: December 6, 2002
    Date of Patent: March 11, 2008
    Assignee: Nippon Steel & Sumikin Stainless Steel Corporation
    Inventors: Ken Kimura, Masao Kikuchi, Masayuki Tendo, Junichi Hamada, Satoshi Akamatsu
  • Patent number: 7341690
    Abstract: The soft Cr-containing steel includes, on a % by mass basis, C: from about 0.001% to about 0.020%, Si: more than about 0.10% and less than about 0.50%, Mn: less than about 2.00%, P: less than about 0.060%, S: less than about 0.008%, Cr: from about 12.0% to about 16.0%, Ni: from about 0.05% to about 1.00%, N: less than about 0.020%, Nb: from about 10×(C+N) to about 1.00%, Mo: more than about 0.80% and less than about 3.00%, wherein the contents of alloying elements, represented by Si and Mo, respectively, on a % by mass, satisfy the formula Si?1.2?0.4Mo, so as to prevent precipitation of the Laves phase and to stably secure an effect of increasing high-temperature strength due to solid solution Mo.
    Type: Grant
    Filed: December 9, 2003
    Date of Patent: March 11, 2008
    Assignee: JFE Steel Corporation
    Inventors: Atsushi Miyazaki, Junichiro Hirasawa, Mineo Muraki, Yoshihiro Yazawa, Osamu Furukimi
  • Patent number: 7294212
    Abstract: Material for stainless steel sheets is heated to a temperature within a range of 850 to 1250° C. and cooled at a rate 1° C./s or faster, the material including 0.02% by mass or less of C, 1.0% by mass or less of Si, 2.0% by mass or less of Mn, 0.04% by mass or less of P, 0.01% by mass or less of S, 0.1% by mass or less of Al, 11% by mass or more but less than 17% by mass of Cr, 0.5% by mass or more but, less than 3.0% by mass of Ni, and 0.02% by mass or less of N, so as to satisfy specific relationships between the compositions.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: November 13, 2007
    Assignee: JFE Steel Corporation
    Inventors: Junichiro Hirasawa, Takumi Ujiro, Osamu Furukimi
  • Patent number: 7294214
    Abstract: Alloy compositions suitable for fabricating medical devices, such as stents, are disclosed. In certain embodiments, the compositions have small amounts of nickel, e.g., the compositions can be substantially free of nickel.
    Type: Grant
    Filed: January 8, 2003
    Date of Patent: November 13, 2007
    Assignee: Scimed Life Systems, Inc.
    Inventor: Charles Horace Craig
  • Patent number: 7288157
    Abstract: A powder metallurgy corrosion and wear resistant tool steel article, and alloy thereof. The article is manufactured by hot isostatic compaction of nitrogen atomized, prealloyed high-chromium, high-vanadium, high-niobium powder particles. The alloy is characterized by very high wear and corrosion resistance, making it particularly useful for use in the manufacture of components for advanced bearing designs as well as machinery parts exposed to severe abrasive wear and corrosion conditions, as encountered, for example, in the plastic injection molding industry and food industry.
    Type: Grant
    Filed: November 13, 2006
    Date of Patent: October 30, 2007
    Assignee: Crucible Materials Corp.
    Inventors: Alojz Kajinic, Andrzej L. Wojcieszynski, Maria K. Sawford
  • Patent number: 7267730
    Abstract: A ferrite stainless steel for an automobile exhaust system member superior in thermal fatigue strength comprised of, by wt %, C: 0.020% or less, Si: 0.02 to 0.15%, Mn: 0.05 to 0.20%, P: 0.040% or less, S: 0.010% or less, Al: 0.005 to 0.10%, N: 0.020% or less, Cr: 15 to 18%, Mo: 1.5 to 2.0%, Ti: 3×(C+N) to 0.25%, Nb: 0.4 to 0.8%, B: 0.0003 to 0.0050%, the C and N satisfying the relationship of C+N: 0.030% or less, and the Al, Si, and Mn satisfying the relationship of Al×(Si+Mn): 0.001 to 0.020, and a balance of Fe and unavoidable impurities. The 0.2% proof stress at 900° C. before heat treatment in the atmosphere at 900° C. for 300 hours is at least 15 MPa, and a difference of the 0.2% proof stress before and after the heat treatment is not more than 5 MPa.
    Type: Grant
    Filed: April 1, 2005
    Date of Patent: September 11, 2007
    Assignees: Nippon Steel & Sumikin Stainless Steel Corporation, Toyota Jidosha Kabushiki Kaisha
    Inventors: Yoshiharu Inoue, Masao Kikuchi, Haruhiko Kajimura, Nobuhiko Hiraide, Yasuhisa Tanaka, Yosuke Sumi
  • Patent number: 7260966
    Abstract: A pierced shell of an austenitic stainless steel having a good inner surface condition is provided, and a means is established which can perform mass production on an industrial scale of a good quality seamless steel pipe of stainless steel. An austenitic stainless steel billet with a P content of at most 0.040% and an S content of at most 0.020% is pierced under conditions such that the pipe expansion ratio H (outer diameter of shell/diameter of billet to be worked) satisfies the following equation to obtain a tube shell of an austenitic stainless steel. {P(%)/(0.025×H?0.01)}2+{S(%)/(0.015×H?0.01)}2?1. When manufacturing a seamless steel pipe of an austenitic stainless steel, the above-described shell is rolled to form a pipe.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: August 28, 2007
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Kazuhiro Shimoda, Tomio Yamakawa, Hiroyuki Semba, Hirofumi Hori, Tsuneo Kondo
  • Patent number: 7261955
    Abstract: Protective layers of the MCrAlX type according to the prior art are often provided with a platinum layer to prevent diffusion of elements out of the base material into the MCrAlX. The MCrAlX alloy according to the invention includes halogens (F, Cl, Br, I), which prevent this diffusion, in particular of titanium.
    Type: Grant
    Filed: February 17, 2006
    Date of Patent: August 28, 2007
    Assignee: Siemens Aktiengesellschaft
    Inventors: Michael Schütze, Werner Stamm
  • Patent number: 7252249
    Abstract: A solenoid-type fuel injector assembly having at least one component formed of stabilized, solenoid-quality ferritic stainless steel. In a preferred embodiment, an austenitic fuel tube is laser-welded to an injector body and to a solenoid pole piece formed of the subject material. The stabilized, solenoid-quality ferritic stainless steel, preferably a free-machining grade thereof, comprises from about 10% to about 35% chromium, and at least one stabilizing element selected from the group consisting of titanium and columbium. Components thus formed are weldable, exhibit soft magnetic properties sufficiently strong for carrying a magnetic flux in a solenoid pole piece, have desired structural and mechanical properties, and reduce the susceptibility of a solenoid-type fuel injector to metallurgical sensitization and intergranular corrosive attack at weld sites.
    Type: Grant
    Filed: February 22, 2002
    Date of Patent: August 7, 2007
    Assignee: Delphi Technologies, Inc.
    Inventor: James R. Molnar
  • Patent number: 7238434
    Abstract: This invention relates to a welded line pipe structure for transporting corrosive petroleum or natural gas. It is constituted by martensitic stainless steel pipes containing 8–16% Cr and at most 0.05% C. By suitably controlling the welding conditions at the time of girth welding of the steel pipes so as to ensure that the Cr concentration in grain boundary Cr-depleted portions existing immediately beneath a weld oxide scale is at least 5%, the occurrence of SCC in a high temperature CO2 environment can be prevented.
    Type: Grant
    Filed: March 3, 2006
    Date of Patent: July 3, 2007
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Hisashi Amaya, Kazuhiro Ogawa, Kunio Kondo, Masayuki Sagara, Hiroyuki Hirata
  • Patent number: 7217905
    Abstract: A filler metal including not more than about 0.1% C, not more than about 1.0% Si; not more than about 0.8% Mn; from about 10.5% to about 13.0% Cr; from about 0.65% to about 4.0% Ni; from about 10(% C) to about 1.5% Ti; not more than about 0.5% each of N, S, P, Mo, Nb, Cu, V, or Co; and balance essentially Fe, wherein a weld test pad of the filler metal contains a microstructure comprising martensite. A method of attaching together two components using a modified filler metal which forms a weld containing an amount of martensite sufficient to increase the volume of the weld thereby at least partially offsetting shrinkage of the weld upon cooling, and articles produced thereby.
    Type: Grant
    Filed: October 29, 2003
    Date of Patent: May 15, 2007
    Assignee: Delphi Technologies, Inc.
    Inventors: Jeffrey B. Hardesty, David E. Nelson
  • Patent number: 7214278
    Abstract: A carbon steel alloy that exhibits the combined properties of high strength, ductility, and corrosion resistance is one whose microstructure contains ferrite regions combined with martensite-austenite regions, with carbide precipitates dispersed in the ferrite regions but without carbide precipitates are any of the interfaces between different phases. The microstructure thus contains of four distinct phases: (1) martensite laths separated by (2) thin films of retained austenite, plus (3) ferrite regions containing (4) carbide precipitates. In certain embodiments, the microstructure further contains carbide-free ferrite regions.
    Type: Grant
    Filed: December 29, 2004
    Date of Patent: May 8, 2007
    Assignee: MMFX Technologies Corporation
    Inventors: Grzegorz J. Kusinski, Gareth Thomas
  • Patent number: 7211159
    Abstract: A ferritic heat-resistant steel, which exhibits excellent creep characteristics even at a high temperature exceeding 600° C., comprises, on the basis of percent by weight, 1.0 to 13% of chromium, 0.1 to 8.0% of cobalt, 0.01 to 0.20% of nitrogen, 3.0% or less of nickel, 0.01 to 0.50% of one or more of elements selected from a group consisting of vanadium, niobium, tantalum, titanium, hafnium, and zirconium that are MX type precipitate forming elements, and 0.01% or less of carbon and a balance being substantially iron and inevitable impurities, wherein the MX type precipitates precipitate on grain boundaries and in entire grains and the grain boundary existing ratio of an M23C6 type precipitate precipitating on the grain boundaries is 50% or less.
    Type: Grant
    Filed: April 19, 2002
    Date of Patent: May 1, 2007
    Assignees: National Institute for Materials Science, Mitsubishi Heavy Industries, Ltd.
    Inventors: Masaki Taneike, Fujio Abe
  • Patent number: 7128791
    Abstract: The present invention provides a martensitic heat resistant alloy having a composition (A) comprising, % by weight: 0.03 to 0.15% of C; 0.01 to 0.9% of Si: 0.01 to 1.5% of Mn; 8.0 to 13.0% of Cr; 0.0005 to 0.015% of Al; no more than 2.0% of Mo; no more than 4.0% of W; 0.05 to 0.5% of V; 0.01 to 0.2% of Nb; 0.1 to 5.0% of Co; 0.008 to 0.03% of B; less than 0.005% of N: and Fe and inevitable impurities as the remainder, wherein (B) the contents (% by weight) of Mo, W, B and N satisfy the following formulae (1) and (2). B?0.772N>0.007??(1) W+1.916Mo?16.99B>2.0??(2) The martensitic heat resistant alloy of the present invention has excellent oxidation resistance, hot workability and ductility and exhibits high creep rupture strength in a range of relatively long rupture time at a high temperature.
    Type: Grant
    Filed: January 30, 2002
    Date of Patent: October 31, 2006
    Assignees: National Institute for Materials Science, Sumitomo Metal Industries, Ltd., Hitachi, Ltd.
    Inventors: Toshiaki Horiuchi, Masaaki Igarashi, Fujio Abe
  • Patent number: 7081173
    Abstract: A super-austenitic stainless steel alloy with a composition, balanced in such a way that products made from the alloy fulfill high requirements on a combination of high corrosion resistance, especially in inorganic and organic acids and mixtures thereof, good general corrosion resistance, good structure stability as well as improved mechanical properties in combination with good workability, in particular in tubes, especially seamless tubes and seam welded tubes for application in these environments and with following composition, in weight-percent: Cr 23.0–30.0 Ni 25.0–35.0 Mo ?2.0–6.0 Mn ?1.0–6.0 N ??0–0.4 C up to 0.05 Si up to 1.0 S up to 0.02 Cu up to 3.0 W ??0–6.0 up to 2.0 of one or more element of the group Mg, Ce, Ca, B, La, Pr, Zr, Ti, Nd, and the balance being Fe and normally occurring impurities and steel making additions.
    Type: Grant
    Filed: November 22, 2002
    Date of Patent: July 25, 2006
    Assignee: Sandvik Intellectual Property AB
    Inventors: Babak Bahar, Johan Frodigh, Pasi Kangas, Ulf Kivisäkk
  • Patent number: 7014719
    Abstract: An austenitic stainless steel comprising (C+½N) up to 0.060 mass %, Si up to 1.0 mass %, Mn up to 5 mass %, S up to 0.003 mass %, S/Mn ratio up to 0.003, 15–20 mass % Cr, 5–12 mass % Ni, Cu up to 5 mass %, 0–3.0 mass % Mo and the balance being Fe except inevitable impurities under the condition that a value Md30 (representing a ratio of a strain-induced martensite) defined by the under-mentioned formula is controlled within a range of ?60 to ?10. Hardness increase of the steel sheet after being cold-rolled is preferably 20% or more as Vickers hardness. A metallurgical structure of the steel sheet is preferably adjusted to grain size number of #8 to #11 in a finish annealed state. The steel sheet is blanked with high dimensional accuracy, and a die life is also prolonged. Md30=551?462(C+N)?9.2Si?29(Ni+Cu)?8.1Mn?13.7Cr?18.5Mo.
    Type: Grant
    Filed: August 23, 2002
    Date of Patent: March 21, 2006
    Assignee: Nisshin Steel Co., Ltd.
    Inventors: Satoshi Suzuki, Takashi Igawa, Hiroshi Fujimoto, Naoto Hiramatsu
  • Patent number: 7005105
    Abstract: The present invention relates to Fe—Cr—Ar type alloys with additions to improve workability thereof, strength, and heat resistance. The present Fe—Cr—Al alloy for electric resistance wires comprises a basic alloy added with only Be of below 0.01 wt % or with both Be and misch metal composed of rare earth elements wherein the basic alloy consists of a balance element of Fe, a Cr element of 12˜30 wt %, an Al element of 3˜14 wt %, a Zr element of 0.01˜1.5 wt %, and a Ti element of 0.001˜0.1 wt %. The present Fe—Cr—Al type alloys remarkably improve physical properties of Fe—Cr—Al ferritic alloys, especially, workability and mechanical properties, and heating characteristic.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: February 28, 2006
    Assignee: Korea Electrotechnology Research Institute
    Inventors: Hee Woong Lee, Su Dong Park
  • Patent number: 6974506
    Abstract: This invention relates to a method of manufacturing an improved ferritic or martensitic alloy based on iron and chromium strengthened by a dispersion of oxides, commonly called an Oxide Dispersion Strengthened or ODS alloy, and, more particularly to a method of manufacturing a ferritic or martensitic ODS alloy with large grains based on iron and chromium which has a single phase ferritic or martensitic matrix having an isotropic microstructure and a grain size that is sufficient to guarantee mechanical strength compatible with a use of this alloy at high temperature and/or under neutron irradiation. According to the invention, the method comprises slow cooling of an austenite at a cooling rate less than or equal to the critical cooling rate for transformation of this austenite into ferrite.
    Type: Grant
    Filed: September 25, 2002
    Date of Patent: December 13, 2005
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Véronique Lambard, Ana Alamo, Jean-Louis Seran
  • Patent number: 6939415
    Abstract: An austenitic stainless steel excellect in high temperature strength and creep rupture ducitility which comprises, on the percent by mass basis, C: 0.03-0.12%, Si: 0.2-2%, Mn: 0.1-3%, P: 0.03% or less, S: 0.01% or less, Ni: more than 18% and less than 25%, Cr: more than 22% and less than 30%, Co: 0.04-0.8%, Ti: 0.002% or more and less than 0.01%, Nb: 0.1-1%, V: 0.01-1%, B: more than 0.0005% and 0.2% or less, sol. Al: 0.0005% or more and less than 0.03%, N: 0.1-0.35% and O (Oxygen): 0.001-0.008%, with the balance being Fe and impurities. The austenitic stainless steel may contain a specified amount of one or more element(s) of Mo and W, and/or a specified amount of one or more element(s) of Mg, Zr, Ca, REM, Pd and Hf.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: September 6, 2005
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Atsuro Iseda, Hiroyuki Semba
  • Patent number: 6936217
    Abstract: A high temperature material which consists of a chromium oxide forming iron alloy including: a) 12 to 28 wt % chromium, b) 0.01 to 0.4 wt % La, c) 0.2 to 1.0 wt % Mn, d) 0.05 to 0.4 wt % Ti, e) less than 0.2 wt % Si, f) less than 0.2 wt % Al, wherein, at temperatures of 700° C. to 950° C., the high temperature material is capable of forming a Mn Cr2O4 spinel phase. At a temperature of 700° C. to 950° on Mn, Cr2O4 the spinel phase formed protects a body, such as spark plug electrodes and other electrodes.
    Type: Grant
    Filed: November 18, 2002
    Date of Patent: August 30, 2005
    Assignee: Forschungszentrum Jülich GmbH
    Inventors: Willem Joseph Quadadakkers, Vladimir Shemet, Lorenz Singheiser
  • Patent number: 6921440
    Abstract: A process for production of sheet-metal strip of niobium-stabilized 14% chromium ferritic steel, characterized in that certain steel is subjected to: cold rolling of the hot sheet metal with or without preliminary annealing, final annealing of the sheet-metal strip at a temperature of between 800° C. and 1100° C. for a duration of between 1 minute and 5 minutes and preferably at a temperature of about 1050° C. for a time of about 2 minutes. Steel and exhaust manifold.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: July 26, 2005
    Assignee: Ugine SA
    Inventors: Silke Liesert, Laurent Antoni, Pierre Olivier Santacreu
  • Patent number: 6911098
    Abstract: A ferritic stainless steel sheet contains abut 0.01 percent by mass or less of carbon; about 1.0 percent by mass or less of silicon; about 1.5 percent by mass or less of manganese; about 11 to about 23 percent by mass of chromium; about 0.06 percent by mass or less of phosphorous; about 0.03 percent by mass or less of sulfur; about 1.0 percent by mass or less of aluminum; about 0.04 percent by mass or less of nitrogen; about 0.0005 to about 0.01 percent by mass of boron; about 0.3 percent by mass or less of vanadium; about 0.8 percent by mass or less of niobium and/or about 1.0 percent by mass or less of titanium wherein 18?Nb/(C+N)+2(Ti/(C+N))?60; and the balance being iron and unavoidable impurities. The average crystal grain diameter is about 40 ?m or less and the average surface roughness is about 0.3 ?m or less.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: June 28, 2005
    Assignee: JFE Steel Corporation
    Inventors: Yoshihiro Yazawa, Osamu Furukimi, Yasushi Kato, Yoshihiro Ozaki
  • Patent number: 6899772
    Abstract: A castable and machinable alloy suitable for submersion in a molten magnesium or magnesium aluminum melt has the following composition: ELEMENT CONTENT (weight %) Boron 0.01-2.0? Carbon 0.01-2.0? Sulphur Trace Phosphorus Trace Chromium ?5.0-15.0 Silicon 0.0-2.0 Molybdenum ?2.00-12.00 Tunsten ?0.5-10.00 Vanadium 0.5-5.0 Niobium 0.5-5.0 Cobalt ?0.5-10.0 Iron Balance The alloy is resistant to dissolution by the melt at temperatures of up to around 1800° F.
    Type: Grant
    Filed: March 27, 2000
    Date of Patent: May 31, 2005
    Assignee: Alphatech, Inc.
    Inventor: Jorge A. Morando
  • Patent number: 6899773
    Abstract: An iron based, fine-grained, martensitic stainless steel essentially free of delta ferrite has a nominal composition of (wt. %): 0.05<C<0.15; 7.5<Cr<15; 2<Ni<5; Co<4; Cu<1.2; Mn<5; Si<1; (Mo+W)<4; 0.01<Ti<0.75; 0.135<(1.17Ti+0.6Zr+0.31Ta+0.31Hf)<1; V<2; Nb<1; N<0.02; Al<0.2; Al and Si both present such that (Al+Si)>0.01; B<0.1; P<0.1; S<0.03; and the balance essentially iron and impurities. This steel is different from other martensitic stainless steels because thermal mechanical treatment is used to refine the grains and precipitate a relatively uniform dispersion of fine, coarsening-resistant, MX-type particles. The steel combines high strength and impact toughness with good corrosion resistance.
    Type: Grant
    Filed: May 8, 2003
    Date of Patent: May 31, 2005
    Assignee: Advanced Steel Technology, LLC
    Inventor: Robert F. Buck
  • Patent number: 6896847
    Abstract: A steel alloy has a chemical composition which contains in weight-%, 0.16-0.27 C, 0.06-0.13 N, wherein total content of C+N shall satisfy the condition, 0.3<C+N<0.4, 0.1-1.5 Si, 0.1-1.2 Mn, 12.5-14.5 Cr, 0.5-1.7 Ni, 0.2-0.8 Mo, 0.1-0.5 V. The steel is suitable for plastic molding tools.
    Type: Grant
    Filed: May 11, 2001
    Date of Patent: May 24, 2005
    Assignee: Uddeholm Tooling Aktiebolage
    Inventors: Odd Sandberg, Maganss Tidesten
  • Patent number: 6893727
    Abstract: This invention relates to a stainless steel gasket having markedly improved strength and fatigue properties due to precipitation strengthening. Its composition comprises C: at most 0.03%, Si: at most 1.0%, Mn: at most 2%, Cr: 16.0%-18.0%, Ni: 6.0%-8.0%, N: at most 0.25%, if necessary Nb: at most 0.30%, and a remainder of Fe and unavoidable impurities. After cold rolling, final annealing is carried out, and after a structure is formed of recrystallized grains with an average grain diameter of at most 5 ?m having an area ratio of 50-100% and an unrecrystallized portion having an area ratio of 0-50%, a metal gasket is formed by steps including temper rolling with a reduction of at least 30% to make the area ratio of a strain induced martensite phase at least 40%, and forming and heat treatment at 200-350° C.
    Type: Grant
    Filed: October 24, 2003
    Date of Patent: May 17, 2005
    Assignees: Sumitomo Metal Industries, Ltd., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Kazuhiko Adachi, Seishi Ishiyama, Kenichi Goshokubo, Takashi Katsurai
  • Patent number: 6890393
    Abstract: An iron based, fine-grained, alloy.
    Type: Grant
    Filed: November 12, 2003
    Date of Patent: May 10, 2005
    Assignee: Advanced Steel Technology, LLC
    Inventor: Robert F. Buck
  • Patent number: 6884388
    Abstract: A martensitic stainless steel sheet which is hard to be softened by tempering caused by heating during the use of a disk brake, can maintain the predetermined hardness, and has excellent punching workability, bending workability before quenching, and a particularly small shear drop, and in which a predetermined hardness after quenching is constantly achieved, in a low carbon martensitic stainless steel sheet used only after quenching. Specifically, the sheet contains, on the basis of mass percent, 0.030% to 0.100% C; 0.50% or less of Si; 1.00% to 2.50% Mn; more than 10.00% to 15.00% Cr; at least one selected from the group consisting of 0.01% to 0.50% Ti, 0.01% to 0.50% V, 0.01% to 1.00% Nb, and 0.01% to 1.00% Zr; N in an amount defined by the following expression, N: 0.005% to (Ti+V)×14/50+(Nb+Zr)×14/90; and the balance being Fe and incidental impurities.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: April 26, 2005
    Assignee: JFE Steel Corporation
    Inventors: Yoshihiro Ozaki, Toshimitsu Nagaya, Atsushi Miyazaki, Susumu Satoh, Mineo Muraki, Setsuo Kakihara, Toshihiro Kasamo
  • Patent number: 6881280
    Abstract: An iron-based corrosion resistant and wear resistant alloy is addressed. The alloy contains (in weight percent) 1.1-1.4% carbon, 11-14.25% chromium, 4.75-6.25% molybdenum, 3.5-4.5% tungsten, 0-3% cobalt, 1.5-2.5% niobium, 1-1.75% vanadium, 0-2.5% copper, up to 1.0% silicon, up to 0.8% nickel, up to 0.6% manganese, and the balance iron. The alloy is suitable for use in valve seat insert applications.
    Type: Grant
    Filed: August 15, 2002
    Date of Patent: April 19, 2005
    Assignee: L.E. Jones Company
    Inventor: Cong Yue Qiao
  • Patent number: 6855214
    Abstract: An anti-friction bearing is provided which is low in vibration and excellent in quietness. The anti-friction bearing has rolling elements provided in inner and outer ring raceway grooves, which are made of martensitic stainless steel composed of 0.60 to 0.75 percent of carbon by weight, 10.5 to 13.5 percent of chromium by weight, 1.0 percent or less of silicon by weight and 0.3 to 0.8 percent of manganese by weight, the remainder of the composition being iron and inevitably introduced impurities, having a hardness of HRC 58 or higher, containing eutectic carbide particles of 10 microns or less in diameter, having oxygen and titanium concentrations of 10 ppm or less respectively, and less than 10 percent by volume of retained austenite.
    Type: Grant
    Filed: September 24, 2001
    Date of Patent: February 15, 2005
    Inventors: Rikuro Obara, Yutaka Daikuhara
  • Patent number: 6855213
    Abstract: A ferritic non-ridging stainless steel and process therefor. A chromium alloyed steel melt containing sufficient titanium and nitrogen but a controlled amount of aluminum is cast into an ingot or continuously cast into a strip or a slab having an as-cast fine equiaxed grain structure substantially free of columnar grains. The as-cast steel contains 0.08% C, at least about 8% Cr, up to 1.50% Mn, <0.020% Al, ?0.05% N, ?1.5% Si, <2.0% Ni, Ti?0.10%, the ratio of (Ti×N)/Al?0.14, all percentages by weight, the balance Fe and residual elements. Preferably, the titanium is controlled so that (Ti/48)/[(C/12)+(N/14)]>1.5. A hot processed sheet may be formed from a continuously cast slab without grinding the surfaces of the slab. The hot processed sheet may be descaled, cold reduced to a final thickness and recrystallization annealed. Annealing the hot processed sheet prior to cold reduction is not required to obtain an annealed sheet essentially free of ridging and having high formability.
    Type: Grant
    Filed: September 15, 1998
    Date of Patent: February 15, 2005
    Assignee: Armco Inc.
    Inventors: Eizo Yoshitake, Alan R. McKague
  • Patent number: 6841011
    Abstract: The present invention is directed to an iron, aluminum, chromium, carbon alloy and a method of producing the same, wherein the alloy has g good room temperature ductility, excellent high temperature oxidation resistance and ductility. The alloy includes about 10 to 70 at. % iron, about 10 to 45 at. % aluminum, about 1 to 70 at. % chromium and about 0.9 to 15 at. % carbon. The invention is also directed to a material comprising a body-centered-cubic solid solution of this alloy, and a method for strengthening this material by the precipitation of body-centered-cubic particles within the solid solution, wherein the particles have substantially the same lattice parameters as the underlying solid solution. The ease of processing and excellent mechanical properties exhibited by the alloy, especially at high temperatures, allows it to be used in high temperature structural applications, such as a turbocharger component.
    Type: Grant
    Filed: September 26, 2002
    Date of Patent: January 11, 2005
    Inventor: Hui Lin
  • Publication number: 20040261910
    Abstract: A forging alloy for manufacturing a golf club head is a stainless steel alloy including carbon 0.08-0.16 wt %, silicon <0.8 wt %, manganese <1.0 wt %, chromium 11.5-17.0 wt %, with the remaining portion being iron. When the forging temperature of the stainless steel alloy is below a transition temperature of a delta ferrite phase thereof, the stainless steel alloy can be subjected to warm forging in a smooth manner at a temperature of 720-960 ° C. and an operational force of 580-860 ton. Thus, a highly rust-resisting and highly wear-resistant golf club head can be manufactured.
    Type: Application
    Filed: July 30, 2003
    Publication date: December 30, 2004
    Inventors: Chan-Tung Chen, Chun-Yung Huang
  • Publication number: 20040250923
    Abstract: A high Cr ferritic heat-resistant steel (Cr content of 15 mass % or less), which, at least a region 10 &mgr;m in depth as measured from the surface has a worked texture comprising elongated ferritic grains or a fine crystal grain texture comprising ferritic grains of 3 &mgr;m or less in diameter, and has a protective coating film on the surface; it is a high Cr ferritic heat-resistant steel improved in oxidation resistance without causing drop in high temperature strength or in toughness.
    Type: Application
    Filed: August 13, 2004
    Publication date: December 16, 2004
    Inventors: Takehiko Itagaki, Shiro Torizuka, Hiroyuki Kutsumi
  • Publication number: 20040244878
    Abstract: The soft Cr-containing steel includes, on a % by mass basis, C: from about 0.001% to about 0.020%, Si: more than about 0.10% and less than about 0.50%, Mn: less than about 2.00%, P: less than about 0.060%, S: less than about 0.008%, Cr: from about 12.0% to about 16.0%, Ni: from about 0.05% to about 1.00%, N: less than about 0.020%, Nb: from about 10×(C+N) to about 1.00%, Mo: more than about 0.80% and less than about 3.00%, wherein the contents of alloying elements, represented by Si and Mo, respectively, on a % by mass, satisfy the formula Si≦1.2−0.4Mo, so as to prevent precipitation of the Laves phase and to stably secure an effect of increasing high-temperature strength due to solid solution Mo.
    Type: Application
    Filed: December 9, 2003
    Publication date: December 9, 2004
    Applicant: JFE STEEL CORPORATION
    Inventors: Atsushi Miyazaki, Junichiro Hirasawa, Mineo Muraki, Yoshihiro Yazawa, Osamu Furukimi
  • Publication number: 20040244884
    Abstract: A ferritic stainless steel sheet has a composition of C up to 0.02 mass %, Si up to 0.8 mass %, Mn up to 1.5 mass %, P up to 0.050 mass %, S up to 0.01 mass %, 8.0-35.0 mass % of Cr, N up to 0.05 mass %, 0.05-0.40 mass % of Ti and 0.10-0.50 mass % of Nb with a product of (% Ti×% N) less than 0.005. Precipitates of 0.15 &mgr;m or more in particle size except TiN are distributed in a steel matrix at a rate of 5000-50000/mm2. The steel sheet is manufactured by hot-rolling a slab at a finish-temperature of 800° C. or lower, annealing the hot-rolled steel sheet at 450-1080° C., cold-rolling the hot-rolled steel sheet in accompaniment with intermediate-annealing at a temperature within a range of from (a recrystallization-finishing temperature −100° C.) to (a recrystallization-finishing temperature) and then finish-annealing the cold-rolled steel sheet at 1080° C. or lower.
    Type: Application
    Filed: June 3, 2004
    Publication date: December 9, 2004
    Applicant: NISSHIN STEELCO., LTD
    Inventors: Yasutoshi Hideshima, Kouki Tomimura, Naoto Hiramatsu
  • Patent number: 6821358
    Abstract: Ferritic stainless steel, comprising the following composition by weight: 0%<C≦0.030% 1%≦Si≦3% 0%<Mn≦0.5% 10%≦Cr≦13% 0%<Ni≦0.5% 0%<Mo≦3% N≦0.030% Cu≦0.5% Ti≦0.5% Nb≦1% Ca≧1×10−4% 0≧10×10−4% S≦0.030% P≦0.030% the remainder being iron and the impurities which are inevitable from the production of the steel.
    Type: Grant
    Filed: March 8, 2002
    Date of Patent: November 23, 2004
    Assignee: Ugine-Savoie Imphy
    Inventors: Etienne Havette, Christophe Bourgin, Benoît Pollet, Jean Lamontanara
  • Publication number: 20040194860
    Abstract: Bearing parts are formed of damping steel containing 0.2 to 0.6 wt. % C, 5.0 to 15.0 wt. % Cr, 0.2 to 1.3 wt. % Si, 0.05 to 0.20 wt. % N, and comprising Fe and inevitable impurities as the remaining. The damping steel may be hardened in an ordinary manner to have a surface hardness, in terms of Rockwell C hardness of at least 57.
    Type: Application
    Filed: April 22, 2004
    Publication date: October 7, 2004
    Applicant: Koyo Seiko Co., Ltd.
    Inventors: Hirofumi Dodoro, Masao Goto
  • Patent number: 6797031
    Abstract: The invention concerns a method for the manufacturing of a wire-shaped product with high wear resistance. The characteristic feature is that a melt is prepared of a martensitic stainless chromium steel which contains in weight-% 0.6-3.0 C, max 2.0 Si max 2.0 Mn, 13-30 Cr, 0-10 Mo, from zero to totally max 10% of those strong carbide forming elements which belong to the group of elements which comprises V, Nb, Ta and Zr, totally max 1% of other, optionally existing alloying elements, balance iron and unavoidable impurities, that the melt is tapped and caused to solidify through cooling at a cooling rate of at least 100° C.
    Type: Grant
    Filed: April 18, 2002
    Date of Patent: September 28, 2004
    Assignee: Haldex Garphyttan Aktiebolag
    Inventor: Claes-Henrik Engström
  • Patent number: 6793745
    Abstract: The invention relates to a high-strength, age-hardenable, corrosion-resistant maraging type spring steel, which is essentially comprised of 6.0 to 9.0 wt. % of Ni, 11.0 to 15.0 wt. % of Cr, 0.1 to 0.3 wt. % of Ti, 0.2 to 0.3 wt. % of Be and of a remainder consisting of Fe, whose martensite temperature Ms≧130° C. and which has a ferrite content cferrite of less than 3%.
    Type: Grant
    Filed: September 16, 2002
    Date of Patent: September 21, 2004
    Assignee: Vacuumschmelze GmbH & Co. KG
    Inventors: Hartwin Weber, Waldemar Doering, Gernot Hausch
  • Patent number: 6793744
    Abstract: The present invention relates to a martensitic stainless steel that can be used in manufacturing articles such as a shaft or an impeller which require high mechanical strength and corrosion resistance and provides a martensitic stainless steel comprising less than 0.06 wt. % C, less than 2.5 wt. % Si, less than 2.5 wt. % Mn, 1.0-6.0 wt. % Ni, 10.0-19.0 wt. % Cr, 0.5-6.0 wt. % W, less than 3.5 wt. % Mo, less than 0.5 wt. % Nb, less than 0.5 wt. % V, less than 3.0 wt. % Cu, 0.05-0.25 wt. % N, and the remainder being Fe and minor impurities.
    Type: Grant
    Filed: November 15, 2000
    Date of Patent: September 21, 2004
    Assignee: Research Institute of Industrial Science & Technology
    Inventor: Jae-Young Jung
  • Patent number: 6793746
    Abstract: Disclosed are stainless steel parts, particularly, parts of electronic apparatus, with which troubles caused by so-called “sulfide gas” mainly of H2S must be avoided. Release of the sulfide gas from the parts is effectively suppressed. The parts have high hardness and corrosion resistance, and can be produced with high finishing accuracy. The stainless steel parts are produced by processing a ferritic or a martensitic stainless steel of a specific alloy composition by forging and/or machining to the shape of the part followed by quenching and tempering, or quenching and tempering followed by machining to the shape of the part, and applying a solution of oxidative acid to the surface of the part so as to dissolve and remove sulfides existing on the surface of the part.
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: September 21, 2004
    Assignee: Daido Steel Co., Ltd.
    Inventors: Tetsuya Shimizu, Michio Okabe
  • Publication number: 20040177900
    Abstract: An electron gun includes a cathode, a control electrode, a screen electrode arranged in front of the control electrode, at least one focusing electrode arranged in front of the screen electrode to form a pre-focusing lens unit, a final accelerating electrode arranged in front of the focusing electrode(s) to form a main lens unit, and a shield cup electrically connected to the final accelerating electrode. The iron-chromium-nickel alloy for the focusing electrode(s), the final accelerating electrode, and the shield cup contains 18-20% or less by weight of chromium, 8-10% by weight of nickel, 0.03% or less by weight of carbon, 1.00% by weight of silicon, 2.00% or less by weight of manganese, 0.04% or less by weight of phosphorous, 0.03% or less by weight of sulfur, a balance of iron, and a trace of impurities, and has an average granularity of 0.010-0.022 mm.
    Type: Application
    Filed: December 22, 2003
    Publication date: September 16, 2004
    Inventors: Seong-Hun Choo, Young-Hoon Lee, Yong-Geol Kwon
  • Patent number: 6786981
    Abstract: A ferritic stainless steel sheet for fuel tanks and fuel pipes comprises, by mass percent, about 0.1% or less of C; about 1.0% or less of Si; about 1.5% or less of Mn; about 0.06% or less of P; about 0.03% or less of S; about 1.0% or less of Al; about 11% to about 20% Cr; about 2.0% or less of Ni; about 0.5% to about 3.0% Mo; about 0.02% to about 1.0% V; about 0.04% or less of N; at least one of about 0.01% to about 0.8% Nb and about 0.01% to about 1.0% Ti; and the balance being Fe and incidental impurities. The ferritic stainless steel sheet is produced by rough-rolling a slab having the above composition; hot-rolling the rough-rolled sheet under a linear pressure of at least about 3.5 MN/m at a final pass in the finish rolling; cold-rolling the hot-rolled sheet at a gross reduction rate of at least about 75%; and annealing the cold-rolled sheet. The cold-rolling step includes one rolling stage or at least two rolling stages including intermediate annealing.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: September 7, 2004
    Assignee: JFE Steel Corporation
    Inventors: Yoshihiro Yazawa, Mineo Muraki, Yoshihiro Ozaki, Kunio Fukuda, Atushi Miyazaki, Yasushi Katoh
  • Publication number: 20040168750
    Abstract: A high-strength dual-phase stainless steel strip has a chemical composition consisting of 0.04-0.15 mass % C, 10.0-20.0 mass % Cr, 0.5-4.0 mass % Ni and the balance being Fe except inevitable impurities, and a metallurgical structure composed of 20-85 vol. % martensite grains and the balance ferrite grains with prior austenite grains controlled to 10 &mgr;m or less in size. The stainless steel strip is conditioned to hardness of HV 300 or more. Transformation strains are uniformly distributed in a steel matrix during martensitic transformation, so that the steel strip is formed and straightened to a belt shape without Lüders band. Consequently, steel belts with fine external appearance are manufactured from the stainless steel strip.
    Type: Application
    Filed: December 10, 2003
    Publication date: September 2, 2004
    Inventors: Kouki Tomimura, Hiroshi Fujimoto, Kenichi Morimoto, Naoto Hiramatsu
  • Patent number: 6783727
    Abstract: Austenitic steel contains from 0.01 to 0.04% by weight of carbon, from 21.00 to 24.00% by weight of chromium, from 0.25 to 5 0.65% by weight of silicon, from 0.25 to 0.70% by weight of manganese, from 1.00 to 1.40% by weight of nitrogen, the balance being iron, the total content of ferrite-forming components in the steel, namely, of silicon and chromium, and the total content of austenite-forming components therein, namely, of carbon, 10 nitrogen and manganese, obeying the following condition: 0.48 ⁢ [Si] + [Cr] 30 ⁢ [C] + 18 ⁢ [N] + 0.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: August 31, 2004
    Assignee: Institut Metallurgii I Materialovedenia Imeni A.A. Baikova Rossiiskoi Akademii NAUK
    Inventors: Oleg Alexandrovich Bannykh, Viktor Mikhailovich Blinov, Maria Vladimirovna Kostina, Viktor Andreevich Malyshevsky, Tsolo Vylkovich Rashev, Grigory Jurievich Kalinin, Ljudmila Georgievna Rigina, Alexei Viktorovich Dymov, Jury Ivanovich Ustinovschikov