Catalytic Patents (Class 208/108)
  • Patent number: 7547386
    Abstract: An integrated process for the hydroprocessing of multiple feedstreams including vacuum gas oil and light cycle oil. The light cycle oil is reacted with hydrogen in a hydrocracking zone and the hydrocarbon feedstream comprising vacuum gas oil is reacted with hydrogen in a hydrodesulfurization reaction zone. The hydrotreated vacuum gas oil is good FCC feedstock. Naphtha and ultra low sulfur diesel are recovered in a common fractionation column.
    Type: Grant
    Filed: February 2, 2005
    Date of Patent: June 16, 2009
    Assignee: UOP LLC
    Inventors: Vasant P. Thakkar, Richard K. Hoehn
  • Patent number: 7544285
    Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminium, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurisation and hydrodenitrification.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: June 9, 2009
    Assignee: Shell Oil Company
    Inventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
  • Patent number: 7540952
    Abstract: The present invention relates to a thermo catalytic process to produce diesel oil from vegetable oils, in refineries which have two or more Catalytic Cracking (FCC) reactors. At least one reactor processes heavy petroleum or residue in conventional operation conditions while at least one reactor processes vegetable oils in proper operation conditions to produce diesel oil. This process employs the same catalyst employed in the FCC process, which processes conventional feedstocks simultaneously. This process transforms high heat content raw materials into fuel hydrocarbons. It may improve efficiency for the obtainment of highly pure products and may not yield glycerin, one by-product of the transesterification process. The diesel oil produced by said process may have superior qualities and/or a cetane number higher than 40. Once cracking conditions occur at lower temperatures, it may form a less oxidized product, which is consequently purer than those obtained by existent technology.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: June 2, 2009
    Assignee: Petroleo Brasileiro S.A. - Petrobras
    Inventors: Andrea De Rezende Pinho, Mauro Silva, Amilcar Pereira Da Silva Neto, Júlio Amilcar Ramos Cabral
  • Publication number: 20090134064
    Abstract: The instant invention relates to an upflow for upgrading heavy oil feed stock and a method for upgrading heavy oil feed stock employing an upflow reactor and with a slurry catalyst. In one embodiment, the upflow reactor is a liquid recirculating reactor, which is operated in manner corresponding to a dispersed bubble flow regime, which requires a high liquid to gas ratio. A dispersed bubble flow regime results in more even flow patterns, increasing the amount of liquid, i.e., heavy oil feed stock that can be upgraded in a single reactor.
    Type: Application
    Filed: January 16, 2009
    Publication date: May 28, 2009
    Inventor: BRUCE REYNOLDS
  • Publication number: 20090134063
    Abstract: The present invention relates to a device and respective process for distribution of mixed charges comprising a flat tray in the form of a disc drained by a series of drainage tubes located above the surface of fixed beds of catalysts, capable of promoting the homogenisation and distribution of charges by means of said device. Such drainage tubes mounted in said manner have the objective of restricting and reorienting the flow of mixed charges, multiplying the points whereon they fall, principally of the liquid phase, onto said beds of catalysts. For the purpose of doing so said drainage ducts, being segments of tubes, distributed on the entire surface of said tray possess caps affixed at the upper extremity thereof impeding the direct flow of charge onto the bed of catalyst, creating a reservoir of liquid on the tray, subsequently being drained down such device in a more controlled manner.
    Type: Application
    Filed: October 10, 2008
    Publication date: May 28, 2009
    Applicant: PETROLEO BRASILEIRO S.A.
    Inventors: Wilson Kenzo Huziwara, Donizeti Aurelio Silva Belato, Jose Antonio Vidal Vieira, Angelo Jose Gugelmin, Shelton Rolim Cercal, Jorivaldo Medeiros, William Victor Carlos Candido, Ademaro Marchiori, Jorge Roberto Duncan Lima, Roberto Ruva, Marcelle Vensao Camargo Foschiani, Alinson Francisco Geros
  • Patent number: 7517446
    Abstract: A fixed bed hydroprocessing system, and also a method for upgrading a pre-existing fixed bed hydroprocessing system, involves preliminarily upgrading a heavy oil feedstock in one or more slurry phase reactors using a colloidal or molecular catalyst and then further hydroprocessing the upgraded feedstock within one or more fixed bed reactors using a porous supported catalyst. The colloidal or molecular catalyst is formed by intimately mixing a catalyst precursor composition into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the precursor composition to form the colloidal or molecular catalyst in situ. Asphaltene or other hydrocarbon molecules otherwise too large to diffuse into the pores of the fixed bed catalyst can be upgraded by the colloidal or molecular catalyst.
    Type: Grant
    Filed: April 28, 2005
    Date of Patent: April 14, 2009
    Assignee: Headwaters Heavy Oil, LLC
    Inventors: Roger K. Lott, Lap-Keung Lee, Peter C. Quinn
  • Patent number: 7513989
    Abstract: The invention relates to a hydrocracking process for hydrocracking petroleum and chemical feedstocks using bulk Group VIII/VIB catalysts. Preferred catalysts include those comprised of Ni—Mo—W.
    Type: Grant
    Filed: January 14, 2000
    Date of Patent: April 7, 2009
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Stuart Leon Soled, Kenneth Lloyd Riley, Gary P. Schleicher, Richard A. Demmin, Darlene Schuette, legal representative, Ian Alfred Cody, William L. Schuette
  • Patent number: 7510645
    Abstract: Increased yields of naphtha and increased catalyst activity are obtained in a hydrocracking process by the use of a catalyst containing a beta zeolite and a Y zeolite having a unit cell size from 24.38 to 24.50 angstrom. The catalyst has a relatively high amount of Y zeolite relative to beta zeolite.
    Type: Grant
    Filed: November 4, 2005
    Date of Patent: March 31, 2009
    Assignee: UOP LLC
    Inventor: Li Wang
  • Patent number: 7507325
    Abstract: The invention relates to a process and installation for treating heavy petroleum feedstocks for producing a gas oil fraction that has a sulfur content of less than 50 ppm and most often 10 ppm that includes the following stages: a) mild hydrocracking in a fixed catalyst bed, b) separation from hydrogen sulfide of a distillate fraction that includes a gas oil fraction and a heavier fraction than the gas oil, c) hydrotreatment (including desulfurization) of said distillate fraction, and d) separation of a gas oil fraction with less than 50 ppm of sulfur. Advantageously, the heavy fraction is sent into catalytic cracking. The process preferably operates with make-up hydrogen that is brought to stage c), and very advantageously all of the make-up hydrogen of the process in introduced in stage c).
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: March 24, 2009
    Assignee: Institut Francais du Petrole
    Inventors: Christophe Gueret, Pierre Marion, Cecile Plain, Jerome Bonnardot, Eric Benazzi, Olivier Martin
  • Patent number: 7507326
    Abstract: The present invention is directed to a method for hydroprocessing Fischer-Tropsch products. The invention in particular relates to an integrated method for producing liquid fuels from a hydrocarbon stream provided by Fischer-Tropsch synthesis. The method involves separating the Fischer-Tropsch products into a light fraction (FT condensate) and a heavy fraction. The heavy fraction is subjected to hydrocracking conditions, preferably through multiple catalyst beds, to reduce the chain length. The products of the hydrocracking reaction following the last catalyst bed are subjected to a separation step. The lighter material is combined with the Fischer-Tropsch condensate and hydrotreated. The hydrotreatment conditions hydrogenate double bonds, reduce oxygenates to paraffins, and desulfurize and denitrify the products. The heavier material from the separation step is sent to the lube plant for hydroisomerization, or is subjected to subsequent fraction steps to produce fuels and middle distillates.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: March 24, 2009
    Assignee: Chevron U.S.A. Inc.
    Inventors: Darush Farshid, Richard O. Moore, Jr.
  • Patent number: 7497941
    Abstract: A process to prepare two or more lubricating base oil grades and a gas oil by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch product, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch product have at least 30 carbon atoms; (b) separating the product of step (a) into one or more gas oil fractions and a base oil precursor fraction; (c) performing a pour point reducing step to the base oil precursor fraction obtained in step (b); and (d) separating the effluent of step (c) in two or more base oil grades.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: March 3, 2009
    Assignee: Shell Oil Company
    Inventor: Gilbert Robert Bernard Germaine
  • Publication number: 20090050526
    Abstract: The instant invention is directed to a process employing slurry catalyst compositions in the upgrading of heavy oils. The slurry catalyst composition is not permitted to settle, which would result in possible deactivation. The slurry is recycled to an upgrading reactor for repeated use and products require no further separation procedures for catalyst removal.
    Type: Application
    Filed: September 18, 2008
    Publication date: February 26, 2009
    Inventors: Kaidong Chen, Julie Chabot
  • Patent number: 7479217
    Abstract: The invention concerns a process for treating a hydrocarbon feed comprising a series of a first upstream process for hydrocarbon hydroconversion comprising at least one reaction chamber, the reaction or reactions occurring inside said chambers and employing at least one solid phase, at least one liquid phase and at least one gas phase, and a second downstream steam reforming process comprising at least one reaction chamber, characterized in that the said upstream process is carried out in a “slurry” and/or an ebullated bed mode and in that the downstream process comprises a first step for at least partial conversion of hydrocarbons heavier than methane into methane, termed the pre-reforming step, and in that the reaction or reactions occurring inside the chambers of the downstream stream reforming process enables the production of a reagent, namely hydrogen, which is necessary for the reactions in the first upstream process.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: January 20, 2009
    Assignee: Institut Francais du Petrole
    Inventors: Mathieu Pinault, Thierry Gauthier, Stéphane Kressmann, Arnault Selmen
  • Publication number: 20090000986
    Abstract: A method for hydrocracking a feedstream comprising liquid hydrocarbon by forming a dispersion comprising hydrogen-containing gas bubbles dispersed in the liquid hydrocarbon, wherein the bubbles have a mean diameter of less than about 5 ?m, and introducing the dispersion into a hydrocracker comprising hydrocracking catalyst. A method for hydrocracking by subjecting a fluid mixture comprising hydrogen-containing gas and liquid hydrocarbons to a shear rate greater than 20,000 s?1 to produce a dispersion of hydrogen in a continuous phase of the liquid hydrocarbons, and introducing the dispersion into a fixed bed hydrocracking reactor from which a hydrocracked product is removed. A system for hydrocracking a hydrocarbonaceous feedstream including at least one high shear device capable of producing a tip speed of the at least one rotor of greater than 5.0 m/s, and a hydrocracker containing hydrocracking catalyst and comprising an inlet fluidly connected to an outlet of the high shear device.
    Type: Application
    Filed: June 12, 2008
    Publication date: January 1, 2009
    Applicant: H R D CORPORATION
    Inventors: Abbas Hassan, Ebrahim Bagherzadeh, Rayford G. Anthony, Gregory Borsinger, Aziz Hassan
  • Patent number: 7470358
    Abstract: An integrated process for the production of low sulfur diesel. The process utilizes a middle distillate hydrocarbon stream and a heavy distillate hydrocarbon stream. The middle distillate hydrocarbon feedstock is reacted with a hydrogen rich gaseous stream having a first pressure in a hydrodesulfurization reaction zone and the heavy distillate hydrocarbon feedstock is reacted with a hydrogen rich gaseous stream having a second pressure in a hydrocracking zone.
    Type: Grant
    Filed: December 19, 2005
    Date of Patent: December 30, 2008
    Assignee: UOP LLC
    Inventor: Tom N. Kalnes
  • Patent number: 7470357
    Abstract: An integrated process for the upgrading of a vacuum gas oil feedstock and a light cycle oil feedstock. The vacuum gas oil feedstock is hydrodesulfurized and the light cycle oil feedstock is hydrocracked.
    Type: Grant
    Filed: December 8, 2005
    Date of Patent: December 30, 2008
    Assignee: UOP LLC
    Inventors: Richard K. Hoehn, Vedula K. Murty
  • Patent number: 7462276
    Abstract: Increased yields of LPG and middle distillate products are obtained in a two stage hydrocracking process by the use of a catalyst containing a beta zeolite. In embodiments, the beta zeolite has not been hydrothermally treated or has been hydrothermally treated at a relatively low temperature. In another embodiment, the catalyst contains a relatively low amount of beta zeolite.
    Type: Grant
    Filed: December 19, 2006
    Date of Patent: December 9, 2008
    Assignee: UOP LLC
    Inventors: Li Wang, Hemant B. Gala, Christopher J. Anderle, Roger R. Lawrence
  • Publication number: 20080277314
    Abstract: A method for thermally cracking a feed composed of whole crude oil and/or natural gas condensate using a vaporizer to vaporize the feed before cracking same, recovering pyrolysis gas oil from the cracked feed, subjecting the recovered pyrolysis gas oil to hydrotreating to form a hydrotreated product, and passing the hydrotreated product to the vaporizer as additional thermal cracking feed.
    Type: Application
    Filed: May 8, 2007
    Publication date: November 13, 2008
    Inventor: Richard B. Halsey
  • Patent number: 7449102
    Abstract: A process for the production of low sulfur diesel and a residual hydrocarbon stream containing a reduced concentration of sulfur. A residual hydrocarbon feedstock and a heavy distillate hydrocarbon feedstock are used in the process.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: November 11, 2008
    Assignee: UOP LLC
    Inventor: Tom N. Kalnes
  • Patent number: 7449103
    Abstract: An ebullated bed hydroprocessing system, and also a method for upgrading a pre-existing ebullated bed hydroprocessing system, involves introducing a colloidal or molecular catalyst, or a precursor composition capable of forming the colloidal or molecular catalyst, into an ebullated bed reactor. The colloidal or molecular catalyst is formed by intimately mixing a catalyst precursor composition into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the precursor composition to form the colloidal or molecular catalyst in situ. The improved ebullated bed hydroprocessing system includes at least one ebullated bed reactor that employs both a porous supported catalyst and the colloidal or molecular catalyst to catalyze hydroprocessing reactions involving the feedstock and hydrogen. The colloidal or molecular catalyst provides catalyst in what would otherwise constitute catalyst free zones within the ebullated bed hydroprocessing system.
    Type: Grant
    Filed: April 28, 2005
    Date of Patent: November 11, 2008
    Assignee: Headwaters Heavy Oil, LLC
    Inventors: Roger K. Lott, Lap-Keung Lee
  • Patent number: 7442290
    Abstract: Mesoporous aluminum oxides with high surface areas have been synthesized using inexpensive, small organic templating agents instead of surfactants. Optionally, some of the aluminum can be framework-substituted by one or more other elements. The material has high thermal stability and possesses a three-dimensionally randomly connected mesopore network with continuously tunable pore sizes. This material can be used as catalysts for dehydration, hydrotreating, hydrogenation, catalytic reforming, steam reforming, amination, Fischer-Tropsch synthesis and Diels-Alder synthesis, etc.
    Type: Grant
    Filed: March 21, 2007
    Date of Patent: October 28, 2008
    Assignee: Lummus Technology Inc.
    Inventors: Zhiping Shan, Jacobus Cornelius Jansen, Chuen Y. Yeh, Philip J. Angevine, Thomas Maschmeyer
  • Patent number: 7435331
    Abstract: A method of converting an original FCC unit of side by side configuration to a converted FCC unit for processing light feedstock by replacing an regenerator in the original FCC unit with an embodied regenerator. From the original FCC unit, the air supply assembly is removed and a centerwell is installed with a fluidization gas, fuel, and air inlet(s) through the centerwell. Distribution rings are connected to each of fluidization gas and fuel inlet(s). An internal pipe and a standpipe portion are installed, wherein a lower end of the standpipe extends into the centerwell creating a radial slot, and wherein the lower end of the standpipe is spaced above the deflector plate in the centerwell to allow flow of spent catalyst through the standpipe and provide deflection of the spent catalyst flow for mixing the spent catalyst with fuel oil that is vaporized within the centerwell.
    Type: Grant
    Filed: November 15, 2006
    Date of Patent: October 14, 2008
    Assignee: Kellogg Brown & Root LLC
    Inventors: Robert B. Peterson, Chris Santner, Michael Tallman
  • Patent number: 7431824
    Abstract: The instant invention is directed to a process employing slurry catalyst compositions in the upgrading of heavy oils. The slurry catalyst composition is not permitted to settle, which would result in possible deactivation. The slurry is recycled to an upgrading reactor for repeated use and products require no further separation procedures for catalyst removal.
    Type: Grant
    Filed: September 10, 2004
    Date of Patent: October 7, 2008
    Assignee: Chevron U.S.A. Inc.
    Inventors: Kaidong Chen, Julie Chabot
  • Patent number: 7432310
    Abstract: A process (10) for synthesising hydrocarbons includes feeding a gaseous feedstock (18) comprising hydrogen and carbon monoxide, into a first Fischer-Tropsch reaction stage (12) which is a three-phase low temperature catalytic Fischer-Tropsch reaction stage, and allowing the hydrogen and carbon monoxide partially to react catalytically in the first reaction stage (12) to form hydrocarbons. At least a portion of a tail gas (32) which includes unreacted hydrogen and carbon monoxide obtained from the first reaction stage, is fed into a second Fischer-Tropsch reaction stage (42) which is a two-phase high temperature catalytic Fischer-Tropsch reaction stage. The hydrogen and carbon monoxide are allowed at least partially to react catalytically in the second reaction stage (42) to form gaseous hydrocarbons.
    Type: Grant
    Filed: August 20, 2004
    Date of Patent: October 7, 2008
    Assignee: Sasol Technology (Proprietary) Limited
    Inventors: André P. Steynberg, Jacob W. De Boer, Herman G. Nel, Werner S. Ernst, Johannes J. Liebenberg
  • Patent number: 7429318
    Abstract: A process for preparing high VI lubricating oil basestocks comprising hydrotreating, hydrodewaxing and optionally hydrofinishing. The hydrotreated feedstock is hydrodewaxed using a dewaxing catalyst that has been selectively activated by oxygenate treatment. The hydrodewaxed product may then be hydrofinished.
    Type: Grant
    Filed: May 18, 2006
    Date of Patent: September 30, 2008
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ian A. Cody, William J. Murphy, Sylvain Hantzer, David W. Larkin, John E. Gallagher, Jr., Jeenok T. Kim
  • Publication number: 20080230443
    Abstract: A method and apparatus for treating a fraction consisting predominantly of hydrocarbons having at least six carbon atoms (C6+ fraction) as produced in a plant for catalytic splitting of hydrocarbon-containing feedstock, is disclosed. The C6+ fraction undergoes steam dealkylation, where two useable product materials benzene and hydrogen are produced.
    Type: Application
    Filed: August 17, 2007
    Publication date: September 25, 2008
    Applicant: Linde Aktiengesellschaft
    Inventors: Helmut FRITZ, Volker Goeke
  • Patent number: 7427348
    Abstract: A process with an increased efficiency for the preparation of middle distillates with excellent properties at low temperatures and substantially without oxygenated organic compounds, starting from a synthetic mixture of hydrocarbons at least partly waxy, containing a fraction of alcohols, comprising the separation of the mixture into a low-boiling fraction and a high-boiling fraction; the subsequent hydrogenation of the low-boiling fraction under such conditions as to avoid any substantial variation in its average molecular weight; the joining of at least a part of the hydrogenated fraction with said high-boiling fraction, and the subsequent catalytic hydrocracking treatment of the mixture of hydrocarbons thug formed, to obtain a substantial conversion of the waxy part into middle distillate.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: September 23, 2008
    Assignees: ENI S.p.A., Enitecnologie S.p.A., Institut Francais du Petrole
    Inventors: Vincenzo Calemma, Silvia Guanziroli, Silvia Pavoni, Roberto Giardino
  • Patent number: 7427349
    Abstract: The present invention relates to the field of hydroprocessing, and more particularly relates to a process directed to fuels hydrocracking and distillate feed hydrofining. This process has at least two stages. A relatively unconverted hydrofined product may be removed prior to the second stage, providing flexibility. In another embodiment, fresh feed may be added prior to the second stage. In both embodiments, fuels production is maintained at a constant level.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: September 23, 2008
    Assignee: Chevron U.S.A. Inc.
    Inventors: Ujjal K. Mukherjee, Kevin L. Hofer, Darush Farshid
  • Patent number: 7419582
    Abstract: A hydrocracking process wherein the feedstock is hydrotreated and the liquid and gaseous effluent from the hydrotreater is directly introduced into the upper end of a hydrocracking vessel which provides a liquid seal to prevent the passage of the gaseous stream containing hydrogen sulfide and ammonia from the hydrotreater to enter the hydrocracking zone containing hydrocracking catalyst. Fresh hydrogen is then introduced into the hydrocracking zone. An apparatus for hydrocracking a hydrocarbon feedstock is also disclosed.
    Type: Grant
    Filed: July 11, 2006
    Date of Patent: September 2, 2008
    Assignee: UOP LLC
    Inventors: Richard K. Hoehn, Vasant P. Thakkar, Vedula K. Murty, Douglas W. Kocher-Cowan, Jennifer L. Anderson
  • Patent number: 7416653
    Abstract: Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. In some embodiments, gas is produced during contact with one or more catalysts and the crude feed.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: August 26, 2008
    Assignee: Shell Oil Company
    Inventors: Scott Lee Wellington, Thomas Fairchild Brownscombe, Stanley Nemec Milam
  • Patent number: 7413646
    Abstract: Contact of a crude feed with a hydrogen source in the presence of an inorganic salt catalyst produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The inorganic salt catalyst may include one or more alkali metals. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: August 19, 2008
    Assignee: Shell Oil Company
    Inventors: Scott Lee Wellington, Thomas Fairchild Brownscombe
  • Patent number: 7413647
    Abstract: The present invention consists of an improved method and apparatus to upgrade bitumen in various forms which comprises four main components; namely, a fractionator equipped with a condenser, a heavy gas oil catalytic treater, a catalyst regenerator/gasifier and a gas cleanup assembly. In operation, the bitumen in liquid form is fed to the fractionator for initial separation of fractions with the bulk of the bitumen leaving the bottom of the fractionator in the form of a heavy gas oil which is pumped to the catalytic treater and sprayed on a hot catalyst to crack the heavy gas oil (an endothermic reaction) to release lighter hydrocarbons in the form of H2 rich volatile matter while depositing carbon on the catalyst. The volatile matter from the treater is directed to the fractionator where the condensable fractions are separated from the non-condensable H2 rich gas, a valuable primary gas.
    Type: Grant
    Filed: March 7, 2005
    Date of Patent: August 19, 2008
    Inventors: Albert Calderon, Terry James Laubis, Richard Owen McCarthy
  • Patent number: 7404890
    Abstract: The invention concerns a process and apparatus wherein the paraffin effluent from the Fischer-Tropsch process is separated into a heavy fraction with an initial boiling point of 120-200° C., said heavy fraction then optionally being hydrotreated then brought into contact with an amorphous hydroisomerization/hydrocracking catalyst that converts at least 80% by weight of the 370° C.+ products into products with a boiling point of less than 370° C. After distilling the hydrocracked fraction obtained to separate middle distillates, the residual heavy fraction is recycled.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: July 29, 2008
    Assignees: Institut Francais du Petrole, Agip Petroli S.p.A., Eni S.p.A, Lini Technologie S.p.A.
    Inventors: Eric Benazzi, Christophe Gueret
  • Publication number: 20080149531
    Abstract: The invention concerns a process for converting heavy feeds carried out in a slurry reactor in the presence of hydrogen and in the presence of a catalyst comprising at least one catalytic metal or a compound of a catalytic metal from group VIB and/or VIII supported on alumina, the pore structure of which is composed of a plurality of juxtaposed agglomerates each formed by a plurality of acicular platelets, the platelets of each agglomerate being generally radially oriented with respect to the others and with respect to the centre of the agglomerate, said catalyst having an irregular and non-spherical shape and being mainly in the form of fragments, obtained using a process including the following steps: a) granulation starting from an active alumina powder having a low crystallinity and/or amorphous structure, to obtain agglomerates in the form of beads; b) maturing in a moist atmosphere between 60° C. and 100° C.
    Type: Application
    Filed: December 20, 2007
    Publication date: June 26, 2008
    Inventors: Magalie Roy-Auberger, Denis Guillaume
  • Patent number: 7390394
    Abstract: The invention is directed to a method of making a catalyst comprising an intermediate pore size molecular sieve, preferably a zeolite of the MTT or TON type. SSZ-32 and ZSM-22 are examples of such molecular sieves. This catalyst is modified with a metal or metals selected from the group consisting of Ca, Cr, Mg, La, Ba, Pr, Sr, K and Nd. The catalyst is additionally loaded with a Group VIII metal or metals for hydrogenation purposes. The catalyst is suitable for use in a process whereby a feed including straight chain and slightly branched paraffins having 10 or more carbon atoms is isomerized.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: June 24, 2008
    Assignee: Chevron U.S.A. Inc.
    Inventors: Joseph A. Biscardi, Darren P. Fong, Paul Marcantonio
  • Patent number: 7390395
    Abstract: The present invention relates to new crystalline molecular sieve SSZ-56 prepared using a N,N-diethyl-2-methyldecahydroquinolinium cation as a structure directing agent, methods for synthesizing SSZ-56 and processes employing SSZ-56 in a catalyst.
    Type: Grant
    Filed: June 16, 2006
    Date of Patent: June 24, 2008
    Inventor: Saleh Elomari
  • Publication number: 20080135450
    Abstract: A process for slurry hydroprocessing, which involves preconditioning a slurry catalyst for activity improvement in vacuum residuum hydroprocessing units Preconditioning the slurry catalyst raises its temperature, thereby reducing shock on the catalyst slurry as it enters the hydroprocessing reactor.
    Type: Application
    Filed: December 6, 2006
    Publication date: June 12, 2008
    Applicant: CHEVRON U.S.A. INC.
    Inventors: Bruce E. Reynolds, Axel Brait
  • Patent number: 7384537
    Abstract: According to the method of manufacturing refined oil of the present invention, refined oil which has a viscosity of 20 cst or lower at 135° C., a pour point of 30° C. or lower, an alkali metal content of 1 wt ppm or less, a vanadium content of 10 wt ppm or less and a sulfur content of 0.3 wt % or lower can be prepared, by bringing feed oil into contact with hydrogen in the presence of the demetalizing/desulfurizing catalyst 3 and the hydrogenolysis catalyst 5. This method can decrease the viscosity, pour point and sulfur concentration of the refined oil to sufficiently low levels, and decreases the production cost.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: June 10, 2008
    Assignee: JGC Corporation
    Inventors: Shigeki Nagamatsu, Makoto Inomata, Susumu Kasahara
  • Patent number: 7384542
    Abstract: A process for the production of low sulfur diesel and high octane naphtha.
    Type: Grant
    Filed: June 7, 2004
    Date of Patent: June 10, 2008
    Assignee: UOP LLC
    Inventors: Vasant P. Thakkar, Richard K. Hoehn
  • Patent number: 7374657
    Abstract: The present invention relates to distillate fuels or distillate fuel blend stocks comprising a blend of a Fischer-Tropsch derived product and a petroleum derived product that is hydrocracked under conditions to preserve aromatics. The resulting distillate fuel product is a low sulfur, moderately aromatic distillate fuel. The resulting distillate fuel or distillate fuel blend stock exhibits excellent properties, including good seal swell, density, and thermal stability. The present invention also relates to processes for making these distillate fuels or distillate fuel blend stocks.
    Type: Grant
    Filed: December 23, 2004
    Date of Patent: May 20, 2008
    Assignee: Chevron USA Inc.
    Inventors: Stephen J. Miller, Dennis J. O'Rear
  • Patent number: 7368619
    Abstract: A process for the production of low sulfur diesel and aromatic compounds wherein C9+ hydrocarbons are hydrocracked to produce low sulfur diesel and a naphtha boiling range stream which is transalkylated in an integrated transalkylation zone to produce xylene.
    Type: Grant
    Filed: June 15, 2004
    Date of Patent: May 6, 2008
    Assignee: UOP LLC
    Inventors: Stanley J. Frey, Vasant P. Thakkar
  • Patent number: 7361264
    Abstract: The present invention is directed to methods for mitigating the deleterious effect of at least one metal on an FCC catalyst. This objective is achieved by using a mixed metal oxide compound comprising magnesium and aluminum, that has not been derived from a hydrotalcite compound, and having an X-ray diffraction pattern displaying at least a reflection at a two theta peak position at about 43 degrees and about 62 degrees, wherein the ratio of magnesium to aluminum in the compound is from about 0.6:1 to about 10:1. In one embodiment, the ratio of magnesium to aluminum in the compound is from about 1:1 to about 6:1. In one embodiment, the ratio of magnesium to aluminum in the compound is from about 1.5:1 to about 10:1. In another embodiment, the invention is directed to methods wherein the ratio of magnesium to aluminum in the compound is from about 1.5:1 to about 6:1.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: April 22, 2008
    Assignee: Intercat, Inc.
    Inventor: Albert A. Vierheilig
  • Patent number: 7361319
    Abstract: The present invention is directed to methods for reducing SOx, NOx, and CO emissions from a fluid stream comprising contacting said fluid stream with a compound comprising magnesium and aluminum and having an X-ray diffraction pattern displaying at least a reflection at a two theta peak position at about 43 degrees and about 62 degrees, wherein the ratio of magnesium to aluminum in the compound is from about 1:1 to about 10:1. In one embodiment, the ratio of magnesium to aluminum in the compound is from about 1:1 to about 6:1. In one embodiment, the ratio of magnesium to aluminum in the compound is from about 1.5:1 to about 10:1. In another embodiment, the invention is directed to methods wherein the ratio of magnesium to aluminum in the compound is from about 1.5:1 to about 6:1.
    Type: Grant
    Filed: November 23, 2004
    Date of Patent: April 22, 2008
    Assignee: Intercat, Inc.
    Inventor: Albert Vierheilig
  • Patent number: 7344631
    Abstract: Fischer-Tropsch hydrocarbon synthesis using a noncobalt catalyst is used to produce waxy fuel and lubricant oil hydrocarbons from synthesis gas derived from natural gas. The waxy hydrocarbons are hydrodewaxed, with reduced conversion to lower boiling hydrocarbons, by contacting the waxy hydrocarbons, in the presence of hydrogen, with an unsulfided hydrodewaxing catalyst that has been reduced and then treated by contacting it with a stream containing one or more oxygenates.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: March 18, 2008
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Adeana Richelle Bishop, William Berlin Genetti, Jack Wayne Johnson, Loren Leon Ansell, Nancy Marie Page
  • Publication number: 20080053871
    Abstract: An expanded bed hydroprocessing system and related method includes at least one expanded bed reactor that employs a solid catalyst to catalyze hydroprocessing reactions involving hydrogen and a high molecular weight hydrocarbon feedstock (e.g., a Fischer-Tropsch wax) that is contaminated with solid particulates. Hydroprocessing the high molecular weight hydrocarbon feedstock in an expanded bed reactor results in formation of a hydroprocessed material from the hydrocarbon feedstock, while eliminating the risk of plugging of the supported catalyst bed by the solid particulates as compared to a reactor including a stationary catalyst bed.
    Type: Application
    Filed: August 31, 2006
    Publication date: March 6, 2008
    Applicant: HEADWATERS NANOKINETIX, INC.
    Inventors: Lap-Keung Lee, Lawrence M. Abrams
  • Publication number: 20080047871
    Abstract: HSP crude oil is used as process stream in crude oil storage tanks to address sludge levels both by cleaning sludge accumulations and preventing any significant sludge build up when used on a regular basis. HSP crude oil is also used to optimize cleaning routines. Making HSP oil easily accessible by providing a designated HSP source will make tank maintenance more efficient and allow refineries to use the advantages of the HSP oil to the maximum extent.
    Type: Application
    Filed: August 23, 2006
    Publication date: February 28, 2008
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Glen B. Brons, Douglas S. Meyer, Mohsen N. Harandi, Randolph Perry, John W. Anthony, John S. Jackson
  • Patent number: 7335295
    Abstract: There is provided a coated zeolite catalyst in which the accessibility of the acid sites on the external surfaces of the zeolite is controlled and a process for converting hydrocarbons utilizing the coated zeolite catalyst. The zeolite catalyst comprises core crystals of a first zeolite and a discontinuous layer of smaller size second crystals of a second zeolite which cover at least a portion of the external surface of the first crystals The coated zeolite catalyst finds particular application in hydrocarbon conversion processes where catalyst activity in combination with zeolite structure are important for reaction selectivity, e.g., catalytic cracking, alkylation, disproportional of toluene, isomerization, and transalkylation reactions.
    Type: Grant
    Filed: June 7, 2004
    Date of Patent: February 26, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Jannetje Maatje van den Berge, Gary David Mohr, Kenneth Ray Clem, Wilfried Jozef Mortier, Machteld Maria Mertens, Michael C. Bradford
  • Patent number: 7332072
    Abstract: A process to prepare a waxy raffinate product by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch derived feed, wherein weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch derived feed have at least 30 carbon atoms; and, (b) isolating from the product of step (a) a waxy raffinate product having a T10 wt % boiling point of between 200° C. and 450° C. and a T90 wt % boiling point of between 400° C. and 650° C.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: February 19, 2008
    Assignee: Shell Oil Company
    Inventors: Gilbert Robert Bernard Germaine, David John Wedlock
  • Patent number: 7314602
    Abstract: Contact, mixing, and often quenching box (8), with main dimension (D) and height (H7), comprising at least one duct section (B1) located on the upper part of said box (8) for entry of fluids in which said box (8) comprises, downstream from said duct section (B1), in the direction in which the fluids circulate, a means (B4) that provides, in said box (8), for making the fluids swirl in an approximately nonradial direction, and not parallel to the overall direction of circulation of said fluids, and comprising at least one annular, peripheral duct section (B6) for the exit of said mixture of fluids formed in said box (8) whose lower level is located above the upper level for fluid entry through at least one lateral inlet (B3) located in said box (8) above means (B4). A reaction cell (4), of an elongated shape along an approximately vertical axis comprising the contact, mixing, and quenching box (8) is useful for performing exothermic reactions.
    Type: Grant
    Filed: July 2, 2002
    Date of Patent: January 1, 2008
    Assignee: Institut Francais du Petrole
    Inventors: Ludovic Raynal, Isabelle Harter, Francis Aubry
  • Patent number: 7311814
    Abstract: Hydrocarbon fluids are produced by hydrocracking a vacuum gas oil stream, fractionating and/or hydrogenating the hydrocracked vacuum gas oil. The fluids typically have ASTM D86 boiling point ranges within the range 100° C. to 400° C. the range being no more than 75° C., they also have a naphthenic content greater than 60%, the naphthenics containing polycyclic materials, an aromatic content below 2% and an aniline point below 100° C. The fluids are particularly useful as solvents, for printing inks, drilling fluids, metal working fluids and as silicone extenders.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: December 25, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Pierre-Yves Guyomar, Andre A. Theyskens