With Metal Or Metal Oxide Patents (Class 208/110)
- With group VII metal or metal oxide (i.e., Mn, Tc, Re, or oxide thereof) (Class 208/111.05)
- With group IV metal or metal oxide (i.e., Ti, Zr, Hf, Ge, Sn, Pb, or oxide thereof) (Class 208/111.1)
- With group I metal or metal oxide (i.e., alkali metal, Ag, Au, Cu, or oxide thereof) (Class 208/111.15)
- With group V metal or metal oxide (i.e., V, Nb, Ta, As, Sb, Bi, or oxide thereof) (Class 208/111.2)
- With group II metal or metal oxide (i.e., alkaline earth metal, Be, Mg, Zn, Cd, Hg, or oxide thereof) (Class 208/111.25)
- With group VI metal or metal oxide (i.e., Cr, Mo, W, Po, or oxide thereof) (Class 208/111.3)
- With group VIII metal or metal oxide (i.e., iron, or platinum group metal, or oxide thereof) (Class 208/111.35)
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Publication number: 20120145595Abstract: A process for treating a hydrocarbon-containing feedstock is provided in which a hydrocarbon-containing feedstock comprising at least 20 wt. % of heavy hydrocarbons is mixed with hydrogen, hydrogen sulfide and a metal-containing catalyst at a temperature of 375° C. to 500° C. and a pressure of from 6.9 MPa to 27.5 MPa to produce a vapor comprising a first hydrocarbon-containing product, where the hydrogen sulfide is mixed with the feedstock, metal-containing catalyst, and hydrogen at a mole ratio of hydrogen sulfide to hydrogen of at least 1:10. The vapor comprising the first hydrocarbon-containing product is separated from the mixture, and, apart from the mixture, the first hydrocarbon-containing product is contacted with hydrogen and a catalyst containing a Column 6 metal at a temperature of 260° C.-425° C. and a pressure of from 3.4 MPa to 27.5 MPa to produce a second hydrocarbon-containing product.Type: ApplicationFiled: December 8, 2011Publication date: June 14, 2012Applicant: SHELL OIL COMPANYInventors: Stanley Nemec MILAM, Michael Anthony REYNOLDS, Scott Lee WELLINGTON, Frederik Arnold BUHRMAN
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Publication number: 20120085681Abstract: The invention is to provide a support which can give a zeolite-based hydrocracking catalyst having a stable catalyst life and showing high cracking activity over a long period, and to provide a hydrocracking catalyst employing the support and a method for hydrocracking of hydrocarbon oil containing aromatics using the catalyst. The invention relates to a support for hydrocracking catalyst of hydrocarbon oil, which comprises a modified zeolite obtained by incorporating titanium into a faujasite-type zeolite, wherein the modified zeolite satisfies the followings (a) to (e), and to a hydrocracking catalyst employing the support and a method for hydrocracking of hydrocarbon oil containing aromatics using the catalyst. (a) The modified zeolite has a titanium content of 1-17% by mass in terms of metal oxide amount, (b) the modified zeolite contains aluminum and silicon in an Al/Si atomic ratio of 0.14-0.35, and (c) the modified zeolite has a lattice constant of 24.36-24.Type: ApplicationFiled: July 16, 2010Publication date: April 12, 2012Applicant: COSMO OIL CO., LTD.Inventors: Masaki Abe, Akira Takaya, Hiroshi Munakata
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Patent number: 8142644Abstract: A process for hydrocracking and hydro-isomerization of a paraffinic feedstock obtained by Fischer-Tropsch hydrocarbon synthesis comprising at least 50 wt % of components boiling above 370° C. to obtain a hydro-isomerized feedstock, the process comprising contacting the feedstock, in the presence of hydrogen, at elevated temperature and pressure with a catalyst comprising a hydrogenating compound supported on a carrier comprising amorphous silica-alumina, the carrier having a pore volume of at least 0.8 ml/g, wherein at most 40% of the pore volume comes from pores having a pore diameter above 35 nm and wherein at most 20% of the pore volume comes from pores having a pore diameter below 50 ? and above 37 ?, the carrier having a median pore diameter of at least 85 ?, wherein the product of (surface area per pore volume) and (median pore diameter as measured by mercury intrusion porosimetry) of the carrier is at least 34,000 ?·m2/ml.Type: GrantFiled: September 10, 2008Date of Patent: March 27, 2012Assignee: Shell Oil CompanyInventors: Focco Kornelis Bijlsma, Jan Lodewijk Maria Dierickx, Arend Hoek
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Publication number: 20120061295Abstract: The present invention is a method for synthesizing non-zeolitic molecular sieves which have a three dimensional microporous framework comprising [AlO2] and [PO2] units. In preparing the reaction mixture, a surfactant is used, coupled with non-aqueous impregnation to prevent acid sites from being destroyed by water during Pt impregnation. The superior SAPO exhibits higher activity and selectivity especially in catalytic hydroisomerization of waxy feeds, due to the presence of medium-sized silica islands distributed throughout the SAPO.Type: ApplicationFiled: October 4, 2011Publication date: March 15, 2012Applicant: CHEVRON U.S.A. INC.Inventor: Stephen J. MILLER
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Patent number: 8128805Abstract: A catalyst for the hydrogenation, hydroisomerisation, hydrocracking and/or hydrodesulfurisation, of hydrocarbon feedstocks, the catalyst consisting of a substantially binder free bead type support material obtained through a sol-gel method, and a catalytically active component selected from precious metals, the support comprising 5 to 50 wt. % of at least one molecular sieve material and 50 to 95 wt. % of silica-alumina.Type: GrantFiled: April 18, 2001Date of Patent: March 6, 2012Assignee: BASF CorporationInventor: Marius Vaarkamp
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Publication number: 20120006724Abstract: Provided are hydrocracking catalysts comprising a cracking component and a hydrogenation component, wherein, for example: the cracking component comprises at least one molecular sieve present in an amount ranging from 0% to 20% by weight relative to the total weight of the catalyst and at least one amorphous silica-alumina present in an amount ranging from 20% to 60% by weight relative to the total weight of the catalyst; the hydrogenation component comprises at least one hydrogenation metal present in a total amount ranging from 34% to 75% by weight calculated by the mass of oxides, relative to the total weight of the catalyst; and the hydrocracking catalyst has a specific surface area ranging from 150 m2/g to 350 m2/g and a pore volume ranging from 0.20 cm3/g to 0.50 cm3/g, such as from 0.30 cm3/g to 0.45 cm3/g, and the product (M×S) of the percentage amount of the total mass of the hydrogenation metal (M) and the specific surface area (S) is equal to or more than 100 m2/g, i.e., M×S?100 m2/g.Type: ApplicationFiled: July 6, 2011Publication date: January 12, 2012Inventors: Yanze Du, Minghua Guan, Fenglai Wang, Chang Liu
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Patent number: 8062505Abstract: A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. Performance of the iron oxide and alumina catalyst at high mean particle diameters is comparable to performance at low mean particle diameters.Type: GrantFiled: June 30, 2008Date of Patent: November 22, 2011Assignee: UOP LLCInventors: Alakananda Bhattacharyya, Maureen L. Bricker, Beckay J. Mezza, Lorenz J. Bauer
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Patent number: 8022003Abstract: A porous crystalline composition having a molar composition as follows: YO2:m X2O3:n ZO, wherein Y is a tetravalent element selected from the group consisting of silicon, germanium, tin, titanium and combinations thereof, X is a trivalent element selected from the group consisting of aluminum, gallium, boron, iron and combinations thereof, Z is a divalent element selected from the group consisting of magnesium, zinc, cobalt, manganese, nickel and combinations thereof, m is between about 0 and about 0.5, n is between about 0 and about 0.5; and the composition has an x-ray diffraction pattern which distinguishes it from the materials. A process for making the composition, and a process using the composition to treat an organic compound are also provided.Type: GrantFiled: August 6, 2010Date of Patent: September 20, 2011Assignee: Intevep, S.A.Inventors: Andres Quesada Perez, Gerardo Vitale Rojas
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Patent number: 8021642Abstract: A porous crystalline composition having a molar composition as follows: YO2:m X2O3:n ZO, wherein Y is a tetravalent element selected from the group consisting of silicon, germanium, tin, titanium and combinations thereof, X is a trivalent element selected from the group consisting of aluminum, gallium, boron, iron and combinations thereof, Z is a divalent element selected from the group consisting of magnesium, zinc, cobalt, manganese, nickel and combinations thereof, m is between about 0 and about 0.5, n is between about 0 and about 0.5; and the composition has an x-ray diffraction pattern which distinguishes it from the materials. A process for making the composition, and a process using the composition to treat an organic compound are also provided.Type: GrantFiled: June 13, 2007Date of Patent: September 20, 2011Assignee: Intevep, S.A.Inventors: Andres Quesada Perez, Gerardo Vitale Rojas
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Patent number: 8002970Abstract: The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10?10 m to 24.15×10?10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).Type: GrantFiled: December 13, 2005Date of Patent: August 23, 2011Assignee: IFP Energies NouvellesInventors: Patrick Euzen, Patrick Bourges, Christophe Gueret, Carole Bobin, Alexandra Chaumonnot, Hugues Dulot
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Publication number: 20110192765Abstract: The present invention relates to a catalyst comprising at least one IZM-2 zeolite, at least one amorphous matrix, at least one hydro-dehydrogenating element selected from the group formed by the elements from group VIB and from group VIII of the periodic table and excluding platinum and palladium. The catalyst also optionally contains a controlled quantity of at least one doping element selected from phosphorus, boron and silicon, optionally at least one element from group VB of the periodic table of the elements, and optionally a group VIIA element. The invention also relates to hydrocracking and hydrotreatment processes implementing this catalyst.Type: ApplicationFiled: July 29, 2009Publication date: August 11, 2011Applicant: IFP Energies nouvellesInventors: Emmanuelle Guillon, Laurent Simon
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Patent number: 7976696Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.Type: GrantFiled: June 5, 2008Date of Patent: July 12, 2011Assignee: Massachusetts Institute of TechnologyInventors: Jackie Y. Ying, Javier García-Martínez
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Publication number: 20110155633Abstract: The invention relates to a process for the production of middle distillates from a paraffinic feedstock that is produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one zeolite that has at least one series of channels of which the opening is defined by a ring with 12 oxygen atoms modified by a) a stage for introducing at least one alkaline cation that belongs to group IA or IIA of the periodic table, b) a stage for treatment of said zeolite in the presence of at least one molecular compound that contains at least one silicon atom, c) at least one stage for partial exchange of said alkaline cations by NH4+ cations such that the remaining content of alkaline cations in the modified zeolite at the end of stage c) is such that the alkaline cation/aluminum molar ratioType: ApplicationFiled: October 13, 2010Publication date: June 30, 2011Applicants: ENI S.P.A., IFP ENERGIES NOUVELLESInventors: Laurent SIMON, Christophe Bouchy
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Publication number: 20110127192Abstract: The present invention relates to a hydrocracking catalyst comprising an acidic silica-alumina, an optional alumina, an effective quantity of at least one VIII Group metal component(s), an effective quantity of at least one VIB Group metal component(s) and an organic additive, wherein the organic additive is one or more selected from the group consisting of an oxygen-containing or nitrogen-containing organic compound, and the molar ratio of the organic additive to the VIII Group metal component(s) is 0.01-10. The present invention relates further to a process for producing the hydrocracking catalyst and use of the catalyst in a process for hydrocracking hydrocarbon oils. The hydrocracking catalyst provided according to the present invention shows a higher activity for aromatic hydrosaturating and ring-opening reaction, as compared with the prior art hydrocracking catalyst.Type: ApplicationFiled: December 3, 2010Publication date: June 2, 2011Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, Research Institute of Petroleum Processing, SinopecInventors: Yichao Mao, Hong Nie, Jianwei Dong, Zhenlin Xiong, Zhihai Hu, Yahua Shi, Dadong Li
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Publication number: 20110120910Abstract: This invention describes a process for the production of middle distillates from a paraffinic feedstock that is produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one dealuminified Y zeolite that has an initial overall atomic ratio of silicon to aluminum of between 2.5 and 20, a starting extra-lattice aluminum atom fraction by weight that is greater than 10%, relative to the total mass of aluminum that is present in the zeolite, a starting mesopore volume that is measured by nitrogen porosimetry that is greater than 0.07 ml.g?1, and a starting crystalline parameter ao of the elementary mesh of between 24.38 ? and 24.Type: ApplicationFiled: November 9, 2010Publication date: May 26, 2011Applicants: ENI S.p.A., IFP Energies nouvellesInventors: Laurent Simon, Emmanuelle Guillon, Christophe Bouchy
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Patent number: 7922894Abstract: The present invention pertains to a process for hydroprocessing a heavy hydrocarbon oil, comprising contacting a heavy hydrocarbon oil in the presence of hydrogen with a mixture of hydroprocessing catalyst I and hydroprocessing catalyst II. The process of the invention combines high contaminant removal with high conversion, low sediment formation, and high process flexibility.Type: GrantFiled: December 8, 2003Date of Patent: April 12, 2011Assignees: Albemarle Netherlands, B.V., Nippon Ketjen Co., Ltd.Inventors: Frans Lodewijk Plantenga, Katsuhisa Fujita, Satoshi Abe
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Publication number: 20110073522Abstract: The present invention concerns a catalyst comprising at least one amorphous material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said amorphous material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said spherical particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having amorphous and microporous walls with a thickness in the range 1.5 to 50 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.Type: ApplicationFiled: May 13, 2009Publication date: March 31, 2011Applicant: IFP ENERGIES NOUVELLESInventors: Audrey Bonduelle, Alexandra Chaumonnot
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Patent number: 7879224Abstract: The present invention concerns doped catalysts on an alumino-silicate support with an adapted macropore content and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table, a controlled quantity of phosphorus (optionally in combination with boron and/or silicon) as a doping element, and a non-zeolitic support based on alumina-silica containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).Type: GrantFiled: September 20, 2005Date of Patent: February 1, 2011Assignee: IFP Energies NouvellesInventors: Patrick Euzen, Alexandra Chaumonnot, Magalie Roy-Auberger, Patrick Bourges, Tivadar Cseri, Maryline Delage, Nathalie Lett
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Patent number: 7837857Abstract: A method for obtaining jet fuel from diesel fuel is provided, the method comprising subjecting the diesel fuel to hydrocracking to convert at least a portion of the diesel fuel into a mixture of light hydrocarbons, kerosene, naphtha and a liquefied petroleum gas, isolating the kerosene, recovering jet fuel from the kerosene, subjecting at least a portion of the mixture of kerosene, naphtha and a liquefied petroleum gas to steam forming to obtain a synthesis gas containing hydrogen, and recycling hydrogen contained in the synthesis gas to the hydrocracking step. A modular system for performing the method is also provided.Type: GrantFiled: January 30, 2008Date of Patent: November 23, 2010Assignee: UOP LLCInventors: Rajeev Gautam, William H. Keesom, Gavin P. Towler
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Patent number: 7799206Abstract: A method is disclosed for producing a stable pipelineable blend from a heavy residue of a catalytic hydroconversion process operating at high (60-80%) conversion rate by blending the heavy residue with a virgin bitumen, such as a bitumen produced from the Peace River or Cold Lake oil sand deposits in Alberta, Canada, and/or with a Wabasca virgin heavy crude oil wherein the 524° C.+ Fraction of the blend is controlled such that: 1) The blend comprises less than 40 vol % of heavy 524° C.+ components, i.e. components which boil at atmospheric pressure at a temperature above about 524 Degrees Celsius; and 2) The 524° C.+ fraction in the blend comprises less than about 80 vol % of heavy residue originating from the hydroconversion process.Type: GrantFiled: May 7, 2004Date of Patent: September 21, 2010Assignee: Shell Oil CompanyInventors: Franciscus Gondulfus Antonius Van Den Berg, Scott John Fryer, Marshall Glenn Letts, Michael Robert Margerum, William James Power, Oscar Kui Yin Sy, Larry Vadori
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Publication number: 20100179361Abstract: The invention describes a porous composite material that comprises a porous substrate based on a refractory inorganic oxide in which said substrate has a zeolite crystal content that is less than 25% by mass, whereby said crystals are dispersed homogeneously in the pores of said substrate, and the distribution coefficient that is measured by Castaing microprobe is between 0.75 and 1.25, and in which the total pore volume of said substrate represents at least 40% of the initial total pore volume of the substrate, and the mean diameter of the pores represents at least 50% of the mean diameter of the pores of the initial substrate, its process for preparation and its use as catalyst in the hydrocarbon feedstock conversion reactions.Type: ApplicationFiled: August 14, 2009Publication date: July 15, 2010Applicant: IFPInventors: Simone GOERGEN, Loic ROULEAU, Emmanuelle GUILLON, Florent GUILLOU, Laurent SIMON, Christophe BOUCHY, Joël PATARIN
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Publication number: 20100170828Abstract: Provided is a catalyst for hydrocracking a paraffinic hydrocarbon which provides satisfactorily high cracking activity and middle fraction yield as well as the low pour point of the fuel base material (the middle fraction) all together. The catalyst of the present invention comprises a USY zeolite derived from NaY used as the raw material and having a peak intensity of 30 or lower, appearing on the 111 surface upon X-ray diffraction, and a noble metal of Group VIII of the periodic table.Type: ApplicationFiled: March 22, 2007Publication date: July 8, 2010Applicant: Nippon Oil CorporationInventors: Masahiro Higashi, Hiroyuki Seki, Sumio Saito, Ryuzo Kuroda, Takashi Kameoka
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Patent number: 7704378Abstract: The invention relates to a process for preparing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises at least one hydrodehydrogenating element chosen from the group formed by the noble elements of Group VIII of the periodic table, a silica-alumina-based non-zeolitic support obtained from wherein the non-zeolitic silica-alumina based support was obtained from a process comprising starting from a mixture of a partially soluble alumina compound in an acid medium with a totally soluble silica compound or with a totally soluble combination of alumina and hydrated silica, the resultant moldable mixture is concentrated to form a moldable mixture, the resultant mixture is molded and the resultant molded article is subjected to a hydrothermal or thermal treatment.Type: GrantFiled: January 16, 2004Date of Patent: April 27, 2010Assignees: Institut Francais du Petrole, ENI S.p.A.Inventors: Eric Benazzi, Patrick Euzen
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Patent number: 7674367Abstract: The present invention relates to an iron-containing crystalline aluminosilicate, a hydrocracking catalyst comprising the same and a process for hydrocracking utilizing the catalyst, and employing the catalyst in hydrocracking for heavy oil results in easy production of great quality kerosene and gas oil having low contents of sulfur and nitrogen as well as increased production thereof.Type: GrantFiled: November 2, 2005Date of Patent: March 9, 2010Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Inamura, Hiroshi Iida, Yoshihiro Okazaki, Akira Iino
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Publication number: 20100032341Abstract: The present invention provides a hydrocracking catalyst comprising a moulded composite support of a zeolite molecular sieve with alumina, at least one of VIII Group metal components, at least one of VIB Group metal components and an organic additive; said organic additive is one or more compounds selected from the group consisting of oxygen-containing or nitrogen-containing organic compounds; the content of said zeolite molecular sieve is 3˜60 wt %, the content of said alumina is 10˜80 wt %, and the content of said organic additive is 0.1˜40 wt % based on the weight of said catalyst; the content of said VIII Group metal component is 1˜15 wt % and the content of said VIB Group metal component is 5˜40 wt % as calculated on oxide and based on the weight of said catalyst. The present invention relates also to a preparation method of said hydrocracking catalyst and use of the catalyst in the hydrocracking process of hydrocarbon oil.Type: ApplicationFiled: April 26, 2006Publication date: February 11, 2010Inventors: Yichao Mao, Hong Nie, Jianwei Dong, Zhenlin Xiong, Zhihai Hu, Dadong Li
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Patent number: 7641787Abstract: Compositions for reduction of NOx generated during a catalytic cracking process, preferably, a fluid catalytic cracking process, are disclosed. The compositions comprise a fluid catalytic cracking catalyst composition, preferably containing a Y-type zeolite, and a particulate NOx composition containing particles of a zeolite having a pore size ranging from about 3 to about 7.2 Angstroms and a SiO2 to Al2O3 molar ratio of less than about 500. Preferably, the NOx reduction composition contains NOx reduction zeolite particles bound with an inorganic binder. In the alternative, the NOx reduction zeolite particles are incorporated into the cracking catalyst as an integral component of the catalyst. Compositions in accordance with the invention are very effective for the reduction of NOx emissions released from the regenerator of a fluid catalytic cracking unit operating under FCC process conditions without a substantial change in conversion or yield of cracked products.Type: GrantFiled: November 7, 2008Date of Patent: January 5, 2010Assignee: W.R. Grace & Co.-Conn.Inventors: George Yaluris, Michael Scott Ziebarth, Xinjin Zhao
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Publication number: 20090314683Abstract: A method for producing an LPG fraction, a gasoline fraction, a kerosene fraction, a gas oil fraction, monocyclic aromatic hydrocarbon and a non-aromatic naphtha fraction from hydrocracked oil includes hydrocracking hydrocarbon oil containing polycyclic aromatic hydrocarbon to convert into a light hydrocarbon fraction, and efficiently and selectively producing monocyclic aromatic hydrocarbon with higher valuable alkylbenzenes. The method for producing hydrocarbon fraction comprises subjecting hydrocarbon feedstock containing polycyclic aromatic hydrocarbon and in which the ratio of carbons constituting an aromatic ring to the total carbons in the hydrocarbon oil (the aromatic ring-constituting carbon ratio) is 35 mole % or more to catalytic cracking in the presence of hydrogen. 40% or more of a fraction with a boiling point of 215° C. or higher in the hydrocarbon feedstock is converted into a fraction with a boiling point lower than 215° C.Type: ApplicationFiled: May 17, 2007Publication date: December 24, 2009Applicant: JAPAN ENERGY CORPORATIONInventor: Koichi Matsushita
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Patent number: 7632395Abstract: A method and apparatus for metering catalyst in a fluid catalytic cracking catalyst injection system are provided. In one embodiment, apparatus for metering catalyst in a fluid catalytic cracking catalyst injection system includes a low pressure storage vessel coupled to a pressure vessel that defines a high pressure side of the apparatus, where the determination of the amount of catalyst transferred is made on the low pressure side of the apparatus.Type: GrantFiled: June 28, 2005Date of Patent: December 15, 2009Assignee: Intercat Equipment, Inc.Inventor: Martin Evans
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Patent number: 7476309Abstract: The present invention pertains to a method for hydroprocessing a heavy hydrocarbon oil, comprising bringing a heavy hydrocarbon oil into contact with hydroprocessing catalyst I in the presence of hydrogen in a first stage, after which the effluent of the first stage is contacted in whole or in part with hydroprocessing catalyst II in the presence of hydrogen in a second stage. The method according to the invention combines efficient contaminant removal with high cracking rate and low sediment formation. The invention also pertains to the combination of catalysts.Type: GrantFiled: June 10, 2002Date of Patent: January 13, 2009Assignee: Albemarle Netherlands B.V.Inventors: Satoshi Abe, Katsuhisa Fujita
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Two stage hydrocracking process using beta zeolite for production of LPG and distillate hydrocarbons
Patent number: 7462276Abstract: Increased yields of LPG and middle distillate products are obtained in a two stage hydrocracking process by the use of a catalyst containing a beta zeolite. In embodiments, the beta zeolite has not been hydrothermally treated or has been hydrothermally treated at a relatively low temperature. In another embodiment, the catalyst contains a relatively low amount of beta zeolite.Type: GrantFiled: December 19, 2006Date of Patent: December 9, 2008Assignee: UOP LLCInventors: Li Wang, Hemant B. Gala, Christopher J. Anderle, Roger R. Lawrence -
Patent number: 7449169Abstract: The present invention refers to a microporous crystalline material of zeolitic nature (ITQ-22) which, in the calcined state, has the empirical formula x(M1/nX02):yYO2:zR:wH20 wherein M is H+ or at least one inorganic cation of charge +n; X is at least one chemical element of oxidation state +3, preferably selected from the group consisting of Al, Ga, B, Fe and Cr; Y is at least one chemical element with oxidation state +4 other than Si and Ge, preferably selected from the group consisting of Ti, Sn and V; x has a value less than 0.2, preferably less than 0.1 and can take the value zero, y has a value less than 0.1, preferably less than 0.05 and can take the value zero, z has a value less than 0.8, preferably between 0.005 and 0.5 and can take the value zero, with a characteristic X-ray diffraction pattern, to the method of preparation and to the use of the material in separation and transformation processes of organic compounds.Type: GrantFiled: November 23, 2004Date of Patent: November 11, 2008Assignees: Consejo Superior de Investigaciones Cientificas, Universidad Politecnica de ValenciaInventors: Avelino Corma Canós, Fernando Rey García, Susana Valencia Valencia, Luis Joaquín Martinez Triguero
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Patent number: 7449103Abstract: An ebullated bed hydroprocessing system, and also a method for upgrading a pre-existing ebullated bed hydroprocessing system, involves introducing a colloidal or molecular catalyst, or a precursor composition capable of forming the colloidal or molecular catalyst, into an ebullated bed reactor. The colloidal or molecular catalyst is formed by intimately mixing a catalyst precursor composition into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the precursor composition to form the colloidal or molecular catalyst in situ. The improved ebullated bed hydroprocessing system includes at least one ebullated bed reactor that employs both a porous supported catalyst and the colloidal or molecular catalyst to catalyze hydroprocessing reactions involving the feedstock and hydrogen. The colloidal or molecular catalyst provides catalyst in what would otherwise constitute catalyst free zones within the ebullated bed hydroprocessing system.Type: GrantFiled: April 28, 2005Date of Patent: November 11, 2008Assignee: Headwaters Heavy Oil, LLCInventors: Roger K. Lott, Lap-Keung Lee
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Publication number: 20080190811Abstract: The present invention relates to a hydrocracking catalyst comprising an acidic silica-alumina, an optional alumina, an effective quantity of at least one VIII Group metal component(s), an effective quantity of at least one VIB Group metal component(s) and an organic additive, wherein the organic additive is one or more selected from the group consisting of an oxygen-containing or nitrogen-containing organic compound, and the molar ratio of the organic additive to the VIII Group metal component(s) is 0.01-10. The present invention relates further to a process for producing the hydrocracking catalyst and use of the catalyst in a process for hydrocracking hydrocarbon oils. The hydrocracking catalyst provided according to the present invention shows a higher activity for aromatic hydrosaturating and ring-opening reaction, as compared with the prior art hydrocracking catalyst.Type: ApplicationFiled: April 26, 2006Publication date: August 14, 2008Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEInventors: Yichao Mao, Hong Nie, Jianwei Dong, Zhenlin Xiong, Zhihai Hu, Yahua Shi, Dadong Li
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Patent number: 7381321Abstract: Process for transforming a gas-oil fraction that makes it possible to produce a fuel that has a quality according to stringent requirements in terms of sulfur content, aromatic compound content, cetane number, boiling point, T95, of 95% of the compounds and density, d15/4, at 15° C. This process comprises a hydrorefining stage and a hydrocracking stage, whereby the latter uses a catalyst that contains at least one zeolite. The conversion of products that have a boiling point of less than 150° C. is, throughout the two stages of hydrocracking and hydrorefining, less than 40% by weight and, for the hydrorefining stage, between 1 and 15% by weight. The temperature, TR2, of the hydrocracking stage is less than the temperature, TR1, of the hydrorefining stage, and the variation between temperatures TR1 and TR2 is between 0 and 80° C.Type: GrantFiled: February 19, 2003Date of Patent: June 3, 2008Assignee: Institut Francais du PetroleInventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Pierre Marion
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Patent number: 7332071Abstract: Process for transforming a gas oil fraction that makes it possible to produce a fuel that has a quality according to stringent requirements in terms of sulfur content, aromatic compound content, cetane number, boiling point, T95, of 95% of the compounds and density, d15/4, at 15° C. This process comprises a hydrorefining stage and a subsequent stage, whereby the latter uses a catalyst that is selected from the group that consists of hydrorefining catalysts and catalysts that comprise at least one mixed oxide, a metal of group VIB, and a non-noble metal of group VIII. The conversion of products that have a boiling point of less than 150° C. is, for the hydrorefining stage, between 1 and 15% by weight. The temperature, TR2, of the subsequent stage is less than the temperature, TR1, of the hydrorefining stage, and the variation between temperatures TR1 and TR2 is between 0 and 80° C.Type: GrantFiled: February 19, 2003Date of Patent: February 19, 2008Assignee: Institut Francais du PetroleInventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Pierre Marion
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Publication number: 20070170094Abstract: Provided are a catalyst which inhibits light paraffins form being produced in catalytic cracking of heavy hydrocarbons and which effectively produces olefins and a process in which the above catalyst is used to produce olefins from heavy hydrocarbons at a high yield. The catalyst is a catalytic cracking catalyst for catalytically cracking a hydrocarbon raw material, comprising (A) pentasil type zeolite modified with a rare earth element and zirconium and (B) faujasite type zeolite, and the process is a production process for olefin and a fuel oil, comprising bringing a heavy oil containing 50 mass % or more of a hydrocarbon fraction having a boiling point of 180° C. or higher into contact with the catalyst described above to crack it.Type: ApplicationFiled: January 17, 2007Publication date: July 26, 2007Applicants: Rsrch Assoc. of Refinery Integration for Group-Op., Idemitsu Kosan Co., Ltd.Inventors: Kenichi Wakui, Kinsho Furusawa, Akio Suwa, Toshio Itoh, Hisao Nagashima
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Patent number: 7173160Abstract: Hydroprocessing such as hydrocracking is advantageously employed in processes for the recovery and purification of higher diamondoids from petroleum feedstocks. Hydrocracking and other hydroprocesses degrade nondiamondoid contaminants.Type: GrantFiled: July 16, 2003Date of Patent: February 6, 2007Assignee: Chevron U.S.A. Inc.Inventors: Theo Maesen, Robert M. Carlson, Jeremy E. Dahl, Shenggao Liu, Hye Kyung C. Timken, Waqar R. Qureshi
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Patent number: 7151199Abstract: Hydrocarbon or oxygenate conversion process in which a feedstock is contacted with a non zeolitic molecular sieve which has been treated to remove most, if not all, of the halogen contained in the catalyst. The halogen may be removed by one of several methods. One method includes heating the catalyst in a low moisture environment, followed by contacting the heated catalyst with air and/or steam. Another method includes steam-treating the catalyst at a temperature from 400° C. to 1000° C. The hydrocarbon or oxygenate conversion processes include the conversion of oxygenates to olefins, the conversion of oxygenates and ammonia to alkylamines, the conversion of oxygenates and aromatic compounds to alkylated aromatic compounds, cracking and dewaxing.Type: GrantFiled: June 10, 2002Date of Patent: December 19, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: Luc Roger Marc Martens, Stephen N. Vaughn, Albert Edward Schweizer, John K. Pierce, Shun Chong Fung
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Patent number: 7132043Abstract: Process to prepare a lubricating base oil starting from a lubricating base oil which is obtained by first removing part of the aromatic compounds from a petroleum fraction boiling in the lubricating oil range by solvent extraction and subsequently dewaxing the solvent extracted product, wherein the following steps are performed, (a) contacting the lubricating base oil with a suitable sulphided hydrotreating catalyst in a first hydrotreating step; (b) separating the effluent of step (a) into a gaseous fraction and a liquid fraction; (c) contacting the liquid fraction of step (b) with a catalyst comprising a noble metal component supported on an amorphous refractory oxide carrier in the presence of hydrogen in a second hydrotreating step; and (d) recovering the lubricating base oil.Type: GrantFiled: May 26, 2000Date of Patent: November 7, 2006Assignee: Shell Oil CompanyInventors: Eric Duprey, Jean-Paul Fattaz, Roland Albert Charles Garin, Patrick Moureaux
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Patent number: 7125817Abstract: A catalyst system and process for combined cracking and selective hydrogen combustion of hydrocarbons are disclosed. The catalyst comprises (1) at least one solid acid component, (2) at least one metal-based component comprised of one or more elements from Group 3 and one or more elements from Groups 4–15 of the Periodic Table of the Elements; and at least one of oxygen and sulfur, wherein the elements from Groups 3, Groups 4–15 and the at least one of oxygen and sulfur are chemically bound both within and between the groups and (3) at least one of at least one support, at least one filler and at least one binder. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the solid acid component alone.Type: GrantFiled: February 20, 2003Date of Patent: October 24, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: John D. Y. Ou, Neeraj Sangar
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Patent number: 7122493Abstract: A catalyst system and process for combined cracking and selective hydrogen combustion of hydrocarbons are disclosed. The catalyst comprises: (1) at least one solid acid component, (2) at least one metal-based component comprised of (i) at least one of oxygen and sulfur (ii) one or more elements from Groups 5–15 of the Periodic Table of the Elements; and (iii) one or more elements from at least one of (a) Groups 1–2 and (b) Group 4; of the Periodic Table of the Elements; and (3) at least one of at least one support, at least one filler and at least one binder. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the solid acid component alone.Type: GrantFiled: February 5, 2003Date of Patent: October 17, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: John D. Y. Ou, Neeraj Sangar
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Patent number: 7122492Abstract: A catalyst system and process for combined cracking and selective hydrogen combustion of hydrocarbons are disclosed. The catalyst comprises (1) at least one solid acid component, (2) at least one metal-based component comprised of one or more elements from Groups 1 and 2; one or more elements from Group 3; one or more elements from Groups 4–15 of the Periodic Table of the Elements; and at least one of oxygen and sulfur and (3) at least one of at least one support, at least one filler and at least one binder. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the solid acid component alone.Type: GrantFiled: February 5, 2003Date of Patent: October 17, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: John D. Y. Ou, Neeraj Sangar
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Patent number: 7122495Abstract: A catalyst system and process for combined cracking and selective hydrogen combustion of hydrocarbons are disclosed.Type: GrantFiled: September 24, 2003Date of Patent: October 17, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: John Di-Yi Ou, Neeraj Sangar
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Patent number: 6733657Abstract: A hydrocarbon conversion catalyst contains at least one silica-alumina having the following characteristics: A content by weight of silica SiO2 of between 10 and 60% by weight; an Na content less than 300 ppm by weight; a total pore volume of between 0.5 and 1.2 m/g measured by mercury porosimetry; a porosity of said silica-alumina wherein: the volume of mesopores whose diameter is between 40 Å and 150 Å, and whose mean diameter varies between 80 and 120 Å represents between 30 and 80% of the total pore volume, and (ii) the volume of macropores, whose diameter is greater than 500 Å and preferably between 1000 Å and 10,000 Å represents between 20 and 80% of the total pore volume; a specific surface area greater than 200 m2/g, and at least one hydro-dehydrogenating element selected metals of group VIB and group VIII, and optionally phosphorus, boron, silicon, or elements of group VIIA, VIIB or VB.Type: GrantFiled: January 15, 2002Date of Patent: May 11, 2004Assignee: Institut Francais du PetroleInventors: Eric Benazzi, Tivadar Cseri, Magalie Roy-Auberger, Patrick Euzen
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Patent number: 6709570Abstract: A method for preparing a catalyst comprising a zeolite and a low acidity refractory oxide binder which is essentially free of alumina which method comprises: (a) preparing an extrudable mass comprising a substantially homogenous mixture of zeolite, water, a source of the low acidity refractory oxide binder present which comprises an acid sol, and an amine compound, (b) extruding the extrudable mass resulting from step (a), (c) drying the extrudate resulting from step (b); and, (d) calcining the dried extrudate resulting from step (c).Type: GrantFiled: September 18, 2000Date of Patent: March 23, 2004Assignee: Shell Oil CompanyInventors: Maria Barbara Hendrica Van Crijnen-Beers, Jean-Paul Darnanville, Carolus Matthias Anna Maria Mesters, Thomas Joris Remans
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Publication number: 20040031727Abstract: Cationic layered materials, a process for their preparation and their use in hydrocarbon conversion, purification, and synthesis processes, such as fluid catalytic cracking. Cationic layered materials are especially suitable for the reduction of SOx and NOx emissions and the reduction of the sulfur and nitrogen content in fuels like gasoline and diesel. The new preparation process avoids the use of metal salts and does not require the formation of anionic clay as an intermediate.Type: ApplicationFiled: June 24, 2003Publication date: February 19, 2004Inventors: Paul O'Conner, William Jones, Dennis Stamires
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Patent number: 6689712Abstract: A hydrorefining catalyst containing a metal belonging to group VIB of the Periodic Table and phosphorus is made by bringing the supporting liquid into contact with a porous carrier formed of inorganic oxide. The supporting liquid is an aqueous solution of a metal belonging to group VIB of the Periodic Table, a phosphorus compound, a hydroxycarboxylic acid, and hydrogen peroxide added to water. Thee hydroxycarboxylic acid content of the supporting liquid is such that molar ratio of group VIB metal:hydroxycarboxylic acid is 1:0.05 to 1:1 and the hydrogen peroxide content of the supporting liquid is such that molar ratio of group VIB metal:hydrogen peroxide is 1:0.03 to 1:1. The catalyst made with the supporting liquid has excellent desulfurization activity.Type: GrantFiled: October 19, 2001Date of Patent: February 10, 2004Assignee: Japan Energy CorporationInventor: Hideo Tanaka
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Patent number: 6576120Abstract: The invention relates to a process for the catalytic dewaxing of a hydrocarbon feed containing waxy molecules by contacting the hydrocarbon feed under catalytic dewaxing conditions with a catalyst composition having metallosilicate crystallites, a binder and a hydrogenation component, wherein the weight ratio of the metallosilicate crystallites and the binder is between 5:95 and 35:65. The invention also relates to a catalyst composition having at least a low acidity refractory oxide binder, which binder is essentially free of aluminum, metallosilicate crystallites and a hydrogenation component, wherein the weight ratio of the metallosilicate crystallites and the binder is between 5:95 and 35:65.Type: GrantFiled: May 16, 2001Date of Patent: June 10, 2003Assignee: Shell Oil CompanyInventors: Carolus Maria Van Ballegoy, Edward Julius Creyghton, Jean-Paul Darnanville, Eric Duprey, Laurent Georges Huve, Carolus Matthias Anna Maria Mesters, Thomas Joris Remans, Maria Barbara Hendrica Crijnen-Van Beers
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Patent number: 6551525Abstract: A dust-proof element for reducing creeping dispersion of dust along a free surface formed as one of locally limited dust trap element (5) and dust barrier (7) having a surface with an artificial pimpled microcrystalline structure with bumps and indentations having a size in a range from 5 to 100 &mgr;m and spaced from each other by a distance from 5 to 200 &mgr;m, and a method of protecting hand-held tools and working tools with the dust-proof element.Type: GrantFiled: March 9, 2001Date of Patent: April 22, 2003Assignee: Hilti AktiengesellschaftInventors: Karl-Heinz Hofmann, Alexander Löffler
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Publication number: 20030066784Abstract: The present invention relates to new crystalline zeolite SSZ-59 and processes employing SSZ-59 as a catalyst.Type: ApplicationFiled: July 13, 2001Publication date: April 10, 2003Inventor: Saleh Elomari