Silicide Of Platinum Group Metal Patents (Class 257/455)
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Patent number: 11004999Abstract: A photodetector element according to an aspect of the present disclosure includes a semiconductor layer with an uneven structure on one surface side that is constituted of projection portions and recess portions, and converts light into surface plasmons, and a metal film that is provided on the one surface side of the semiconductor layer in a manner corresponding to the uneven structure and a Schottky junction is formed between the metal film and the semiconductor layer. The semiconductor layer is constituted of n-type conductive silicon, and the other surface side of the semiconductor layer serves as an incident surface for light. The metal film is constituted of a material including nickel which form the Schottky junction when combined with the semiconductor layer.Type: GrantFiled: March 14, 2019Date of Patent: May 11, 2021Assignee: HAMAMATSU PHOTONICS K.K.Inventors: Wei Dong, Hiroyasu Fujiwara
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Patent number: 9013002Abstract: An iridium interfacial stack (“IrIS”) and a method for producing the same are provided. The IrIS may include ordered layers of TaSi2, platinum, iridium, and platinum, and may be placed on top of a titanium layer and a silicon carbide layer. The IrIS may prevent, reduce, or mitigate against diffusion of elements such as oxygen, platinum, and gold through at least some of its layers.Type: GrantFiled: June 27, 2012Date of Patent: April 21, 2015Assignee: The United States of America as Represented by the Administrator of National Aeronautics and Space AdministrationInventor: David James Spry
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Patent number: 9006785Abstract: Semiconductor trilayer structures that are doped and strained are provided. Also provided are mechanically flexible transistors, including radiofrequency transistors, incorporating the trilayer structures and methods for fabricating the trilayer structures and transistors. The trilayer structures comprise a first layer of single-crystalline semiconductor material, a second layer of single-crystalline semiconductor material and a third layer of single-crystalline semiconductor material. In the structures, the second layer is in contact with and sandwiched between the first and third layers and the first layer is selectively doped to provide one or more doped regions in the layer.Type: GrantFiled: January 28, 2013Date of Patent: April 14, 2015Assignee: Wisconsin Alumni Research FoundationInventors: Zhenqiang Ma, Jung-Hun Seo, Max G. Lagally
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Patent number: 8916451Abstract: A method for wafer transfer includes forming a spreading layer, including graphene, on a single crystalline SiC substrate. A semiconductor layer including one or more layers is formed on and is lattice matched to the crystalline SiC layer. The semiconductor layer is transferred to a handle substrate, and the spreading layer is split to remove the single crystalline SiC substrate.Type: GrantFiled: February 5, 2013Date of Patent: December 23, 2014Assignee: International Business Machines CorporationInventors: Can Bayram, Jack O. Chu, Christos Dimitrakopoulos, Jeehwan Kim, Hongsik Park, Devendra K. Sadana
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Patent number: 8878329Abstract: A high voltage device having a Schottky diode integrated with a MOS transistor includes a semiconductor substrate a Schottky diode formed on the semiconductor substrate, at least a first doped region having a first conductive type formed in the semiconductor substrate and under the Schottky diode, and a control gate covering a portion of the Schottky diode and the first doped region positioned on the semiconductor substrate.Type: GrantFiled: September 17, 2010Date of Patent: November 4, 2014Assignee: United Microelectronics Corp.Inventor: Min-Hsuan Tsai
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Patent number: 8835309Abstract: A method of performing a silicide contact process comprises a forming a nickel-platinum alloy (NiPt) layer over a semiconductor device structure; performing a first rapid thermal anneal (RTA) so as to react portions of the NiPt layer in contact with semiconductor regions of the semiconductor device structure, thereby forming metal rich silicide regions; performing a first wet etch to remove at least a nickel constituent of unreacted portions of the NiPt layer; performing a second wet etch using a dilute Aqua Regia treatment comprising nitric acid (HNO3), hydrochloric acid (HCl) and water (H2O) to remove any residual platinum material from the unreacted portions of the NiPt layer; and following the dilute Aqua Regia treatment, performing a second RTA to form final silicide contact regions from the metal rich silicide regions.Type: GrantFiled: September 13, 2012Date of Patent: September 16, 2014Assignee: International Business Machines CorporationInventors: David F. Hilscher, Christian Lavoie, Ahmet S. Ozcan
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Patent number: 8482084Abstract: A Schottky field effect transistor is provided that includes a substrate having a layer of semiconductor material atop a dielectric layer, wherein the layer of semiconductor material has a thickness of less than 10.0 nm. A gate structure is present on the layer of semiconductor material. Raised source and drain regions comprised of a metal semiconductor alloy are present on the layer of semiconductor material on opposing sides of the gate structure. The raised source and drain regions are Schottky source and drain regions. In one embodiment, a first portion of the Schottky source and drain regions that is adjacent to a channel region of the Schottky field effect transistor contacts the dielectric layer, and a non-reacted semiconductor material is present between a second portion of the Schottky source and drain regions and the dielectric layer.Type: GrantFiled: March 18, 2010Date of Patent: July 9, 2013Assignees: International Business Machines Corporation, Global Foundries, Inc.Inventors: Marwan H. Khater, Christian Lavoie, Bin Yang, Zhen Zhang
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Patent number: 8344398Abstract: A method of making a diode begins by depositing an AlxGa1-xN nucleation layer on a SiC substrate, then depositing an n+ GaN buffer layer, an n? GaN layer, an AlxGa1-xN barrier layer, and an SiO2 dielectric layer. A portion of the dielectric layer is removed and a Schottky metal deposited in the void. The dielectric layer is affixed to the support layer with a metal bonding layer using an Au—Sn utectic wafer bonding process, the substrate is removed using reactive ion etching to expose the n+ layer, selected portions of the n+, n?, and barrier layers are removed to form a mesa diode structure on the dielectric layer over the Schottky metal, and an ohmic contact is deposited on the n+ layer.Type: GrantFiled: October 15, 2010Date of Patent: January 1, 2013Assignee: Cree, Inc.Inventors: Primit Parikh, Sten Heikman
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Patent number: 8278199Abstract: Reliability of a semiconductor element and its product yield are improved by reducing variations in the electrical characteristic of a metal silicide layer. After forming a nickel-platinum alloy film over a semiconductor substrate, by carrying out a first thermal treatment at a thermal treatment temperature of 210 to 310° C. using a heater heating device, the technique causes the nickel-platinum alloy film and silicon to react with each other to form a platinum-added nickel silicide layer in a (PtNi)2Si phase. After removing unreacted nickel-platinum alloy film, the technique carries out a second thermal treatment having the thermal treatment temperature higher than that of the first thermal treatment to form the platinum-added nickel silicide layer in a PtNiSi phase. The temperature rise rate of each thermal treatment is set to 10° C./s or more.Type: GrantFiled: September 23, 2011Date of Patent: October 2, 2012Assignee: Renesas Electronics CorporationInventors: Shigenari Okada, Takuya Futase, Yutaka Inaba
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Patent number: 8237170Abstract: To provide a Schottky electrode in a diamond semiconductor, which has a good adhesion properties to diamonds, has a contacting surface which does not become peeled due to an irregularity in an external mechanical pressure, does not cause a reduction in yield in a diode forming process and does not cause deterioration in current-voltage characteristics, and a method of manufacturing the Schottky electrode. A Schottky electrode which includes: scattered island-form pattern Pt-group alloy thin films which are formed on a diamond surface formed on a substrate, in which the Pt-group alloy includes 50 to 99.9 mass % of Pt and 0.Type: GrantFiled: April 14, 2008Date of Patent: August 7, 2012Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Kazuhiro Ikeda, Hitoshi Umezawa, Shinichi Shikata
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Patent number: 8164154Abstract: A low profile high power Schottky barrier bypass diode for solar cells and panels with the cathode and anode electrodes on the same side of the diode and a method of fabrication thereof are disclosed for generating a thin chip with both electrodes being on the same side of the chip. In an embodiment, a mesa isolation with a Zener diode over the annular region surrounding the central region of the mesa anode in the Epi of the substrate is formed. In an embodiment, a P-type Boron dopant layer is ion implanted in the annular region for the Zener Diode. This controls recovery from high voltage spikes from the diode rated voltage. A Schottky barrier contact for the anode and a contact for the cathode are simultaneously created on the same side of the chip.Type: GrantFiled: December 17, 2010Date of Patent: April 24, 2012Inventors: Aram Tanielian, Garo Tanielian
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Patent number: 8039308Abstract: Embodiments of a multi-chip module (MCM) are described. This MCM includes a first semiconductor die and a second semiconductor die, where a given semiconductor die, which can be the first semiconductor die or the second semiconductor die, includes proximity connectors proximate to a surface of the given semiconductor die. Moreover, the given semiconductor die is configured to communicate signals with the other semiconductor die via proximity communication through one or more of the proximity connectors. Furthermore, the MCM includes an alignment plate and a top plate coupled to the alignment plate. This alignment plate includes a first negative feature configured to accommodate the first semiconductor die and a second negative feature configured to accommodate the second semiconductor die, and the top plate includes a positive feature. Note that the positive feature is coupled to the first semiconductor die, and the positive feature facilitates mechanical positioning of the first semiconductor die.Type: GrantFiled: January 13, 2011Date of Patent: October 18, 2011Assignee: Oracle America, Inc.Inventors: James G. Mitchell, John E. Cunningham, Ashok V. Krishnamoorthy
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Patent number: 8039378Abstract: To provide a technique capable of improving the reliability of a semiconductor element and its product yield by reducing the variations in the electrical characteristic of a metal silicide layer. After forming a nickel-platinum alloy film over a semiconductor substrate 1, by carrying out a first thermal treatment at a thermal treatment temperature of 210 to 310° C. using a heater heating device, the technique causes the nickel-platinum alloy film and silicon to react with each other to form a platinum-added nickel silicide layer in a (PtNi)2Si phase. Subsequently, after removing the unreacted nickel-platinum alloy film, the technique carries out a second thermal treatment having the thermal treatment temperature higher than that of the first thermal treatment to form the platinum-added nickel silicide layer in a PtNiSi phase. The temperature rise rate of the first thermal treatment is set to 10° C./s or more (for example, 30 to 250° C.Type: GrantFiled: January 23, 2009Date of Patent: October 18, 2011Assignee: Renesas Electronics CorporationInventors: Shigenari Okada, Takuya Futase, Yutaka Inaba
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Patent number: 7999340Abstract: An apparatus and method for forming optical black pixels having uniformly low dark current. Optical Black opacity is increased without having to increase Ti/TiN layer thickness. A hybrid approach is utilized combining a Ti/TiN OB layer in conjunction with in-pixel metal stubs that further occlude the focal radius of each pixel's incoming light beam. Additional metal layers can be used to increase the opacity into the infrared region.Type: GrantFiled: March 7, 2007Date of Patent: August 16, 2011Assignee: AltaSens, Inc.Inventors: Giuseppe Rossi, Lester Kozlowski, Henry Lin, John Richardson, Gregory Chow, Gaurang Patel
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Patent number: 7999344Abstract: An optoelectronic device comprises a photodetector feature, an interfacial layer disposed above at least a portion of the photodetector feature, and a vertical contact disposed on at least a portion of the interfacial layer. The photodetector feature comprises germanium and is operative to convert a light signal into an electrical signal. The interfacial layer comprises nickel. Finally, the vertical contact is operative to transmit the electrical signal from the photodetector feature.Type: GrantFiled: May 6, 2010Date of Patent: August 16, 2011Assignee: International Business Machines CorporationInventors: Solomon Assefa, Stephen Walter Bedell, Yurii A. Vlasov, Fengnian Xia
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Patent number: 7847326Abstract: A backside illuminated image sensor includes a photodiode, formed below the top surface of a semiconductor substrate, for receiving light illuminated from the backside of the semiconductor substrate to generate photoelectric charges, a reflecting gate, formed on the photodiode over the front upper surface of the semiconductor substrate, for reflecting light illuminated from the backside of the substrate and receiving a bias to control a depletion region of the photodiode, and a transfer gate for transferring photoelectric charges from the photodiode to a sensing node of a pixel.Type: GrantFiled: June 27, 2008Date of Patent: December 7, 2010Inventors: Sung-Hyung Park, Ju-Il Lee
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Patent number: 7834367Abstract: A method of making a diode begins by depositing an AlxGa1?xN nucleation layer on a SiC substrate, then depositing an n+ GaN buffer layer, an n? GaN layer, an AlxGa1?xN barrier layer, and an SiO2 dielectric layer. A portion of the dielectric layer is removed and a Schottky metal deposited in the void. The dielectric layer is affixed to the support layer with a metal bonding layer using an Au-Sn utectic wafer bonding process, the substrate is removed using reactive ion etching to expose the n+ layer, selected portions of the n+, n?, and barrier layers are removed to form a mesa diode structure on the dielectric layer over the Schottky metal,; and an ohmic contact is deposited on the n+ layer.Type: GrantFiled: January 19, 2007Date of Patent: November 16, 2010Assignee: Cree, Inc.Inventors: Primit Parikh, Sten Heikman
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Patent number: 7790495Abstract: An optoelectronic device comprises a photodetector feature, an interfacial layer disposed above at least a portion of the photodetector feature, and a vertical contact disposed on at least a portion of the interfacial layer. The photodetector feature comprises germanium and is operative to convert a light signal into an electrical signal. The interfacial layer comprises nickel. Finally, the vertical contact is operative to transmit the electrical signal from the photodetector feature.Type: GrantFiled: October 26, 2007Date of Patent: September 7, 2010Assignee: International Business Machines CorporationInventors: Solomon Assefa, Stephen Walter Bedell, Yurii A. Vlasov, Fengnian Xia
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Patent number: 7679662Abstract: Disclosed herein is a solid-state imaging element which includes a plurality of drive signal inputs, a plurality of bus lines, and a plurality of vertical transfer register electrodes. In the solid-state imaging element, a charge accumulated in light-receiving elements in a pixel region is vertically transferred by the drive signals input to the electrodes. Each of the electrodes has a contact part connected to the second contact and having a width smaller than a width of the electrodes in the pixel region, and a blank region is formed between predetermined adjacent two of the contact parts so that a width of the blank region is larger than a distance between respective two of the contact parts other than the predetermined adjacent two of the contact parts. The first contact is disposed on the blank region.Type: GrantFiled: November 9, 2006Date of Patent: March 16, 2010Assignee: Sony CorporationInventors: Sadamu Suizu, Masaaki Takayama
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Patent number: 7420215Abstract: A transparent conductive film substantially made from In2O3, SnO2 and ZnO, having a molar ratio In/(In+Sn+Zn) of 0.65 to 0.8 and also a molar ratio Sn/Zn of 1 or less: The transparent conductive film has a favorable electric contact property with an electrode or line made from Al or Al alloy film. Further, a semiconductor device having an electrode or line made from the transparent conductive film has high reliability and productivity.Type: GrantFiled: June 22, 2007Date of Patent: September 2, 2008Assignee: Mitsubishi Electric CorporationInventors: Kazunori Inoue, Nobuaki Ishiga, Kensuke Nagayama, Toru Takeguchi, Kazumasa Kawase
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Patent number: 7329927Abstract: Integrated circuit devices are provided including an integrated circuit substrate and a gate on the integrated circuit substrate. The gate has sidewalls. A barrier layer spacer is provided on the sidewalls of the gate. A portion of the barrier layer spacer protrudes from the sidewalls of the gate exposing a lower surface of the barrier layer spacer that faces the integrated circuit substrate. A silicide layer is provided on the portion of the barrier layer spacer protruding from the sidewalls of the gate.Type: GrantFiled: June 24, 2005Date of Patent: February 12, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Se-myeong Jang, Gyo-young Jin, Yong-chul Oh, Hyun-chang Kim
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Patent number: 7176537Abstract: A semiconductor device having a metal/metal silicide gate and a Schottky source/drain and a method of forming the same are provided. The semiconductor device includes a gate dielectric overlying a semiconductor substrate, a metal or metal silicide gate electrode having a work function of less than about 4.3 eV or greater than about 4.9 eV overlying the gate dielectric, a spacer having a thickness of less than about 100 ? on a side of the gate electrode, and a Schottky source/drain having a work function of less than about 4.3 eV or greater than about 4.9 eV wherein the Schottky source/drain region overlaps the gate electrode. The Schottky source/drain region preferably has a thickness of less than about 300 ?.Type: GrantFiled: May 23, 2005Date of Patent: February 13, 2007Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Wen-Chin Lee, Chung-Hu Ke, Min-Hwa Chi
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Patent number: 7075158Abstract: A semiconductor device can be manufactured which has a low resistance, and device characteristics of which do not vary. The semiconductor device includes a silicon layer, a gate dielectric film formed on the silicon layer, a gate electrode formed on the gate dielectric film and including a nitrided metal silicide layer which is partially crystallized, and source and drain regions formed in a surface region of the silicon layer at both sides of the gate electrode.Type: GrantFiled: October 6, 2005Date of Patent: July 11, 2006Assignee: Kabushiki Kaisha ToshibaInventors: Masato Koyama, Akira Nishiyama, Masamichi Suzuki, Yuuichi Kamimuta, Tsunehiro Ino
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Patent number: 6982467Abstract: A semiconductor device can be manufactured which has a low resistance, and device characteristics of which do not vary. The semiconductor device includes a silicon layer, a gate dielectric film formed on the silicon layer, a gate electrode formed on the gate dielectric film and including a nitrided metal silicide layer which is partially crystallized, and source and drain regions formed in a surface region of the silicon layer at both sides of the gate electrode.Type: GrantFiled: June 9, 2004Date of Patent: January 3, 2006Assignee: Kabushiki Kaisha ToshibaInventors: Masato Koyama, Akira Nishiyama, Masamichi Suzuki, Yuuichi Kamimuta, Tsunehiro Ino
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Patent number: 6956274Abstract: A metallization stack is provided for use as a contact structure in an integrated MEMS device. The metallization stack comprises a titanium-tungsten adhesion and barrier layer formed with a platinum layer formed on top. The platinum feature is formed by sputter etching the platinum in argon, followed by a wet etch in aqua regia using an oxide hardmask. Alternatively, the titanium-tungsten and platinum layers are deposited sequentially and patterned by a single plasma etch process with a photoresist mask.Type: GrantFiled: January 11, 2002Date of Patent: October 18, 2005Assignee: Analog Devices, Inc.Inventors: Susan A. Alie, Bruce K. Wachtmann, David S. Kneedler, Scott Limb, Kieran Nunan
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Patent number: 6846731Abstract: In the present invention, there is provided semiconductor devices such as a Schottky UV photodetector fabricated on n-type ZnO and MgxZn1-xO epitaxial films. The ZnO and MgxZn1-xO films are grown on R-plane sapphire substrates and the Schottky diodes are fabricated on the ZnO and MgxZn1-xO films using silver and aluminum as Schottky and ohmic contact metals, respectively. The Schottky diodes have circular patterns, where the inner circle is the Schottky contact, and the outside ring is the ohmic contact. Ag Schottky contact patterns are fabricated using standard liftoff techniques, while the Al ohmic contact patterns are formed using wet chemical etching. These detectors show low frequency photoresponsivity, high speed photoresponse, lower leakage current and low noise performance as compared to their photoconductive counterparts. This invention is also applicable to optical modulators, Metal Semiconductor Field Effect Transistors (MESFETs) and more.Type: GrantFiled: May 30, 2002Date of Patent: January 25, 2005Assignee: Rutgers, The State University of New JerseyInventors: Yicheng Lu, Haifeng Sheng, Sriram Muthukumar, Nuri William Emanetoglu, Jian Zhong
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Patent number: 6798034Abstract: A passive mechanism suppresses injection, into any active guard regions interposed between the edge of a photodiode array chip and the outer photodiode pixels or into the outer pixels themselves, of minority carrier current generated in the physically disrupted region at the edge of the semiconductor die created by cleaving, sawing or otherwise separating the chip from the remainder of the wafer on which the die was fabricated. A thin metallic layer covers all or part of the edge region, thereby creating a Schottky barrier. This barrier generates a depletion region in the adjacent semiconductor material. The depletion region inherently creates an energy band distribution which preferentially accelerates minority carriers generated or near the metal-semiconductor interface towards the metal, thereby suppressing collection of these carriers by any active regions of the guard structure or by the photodiode pixels.Type: GrantFiled: August 7, 2002Date of Patent: September 28, 2004Assignee: Diglrad CorporationInventor: Lars S. Carlson
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Patent number: 6756651Abstract: A novel photodetector CMOS-compatible photodetector is disclosed in which photo-generation of carriers (electrons) is carried out in the metal of the electrodes, rather than as electron-hole pairs in the semiconductor on which the metal electrodes are deposited. The novel photo detector comprises a silicon or other semiconductor substrate material characterized by an electron energy bandgap, and a pair of metal electrodes disposed upon a surface of the silicon to define therebetween a border area of the surface. One of the two electrodes being exposed to the incident radiation and covering an area of said surface which is larger than the aforesaid border area, the aforesaid metal of the electrodes being characterized by a Fermi level which is within said electron energy bandgap.Type: GrantFiled: September 26, 2001Date of Patent: June 29, 2004Assignee: International Business Machines CorporationInventors: Ferenc M. Bozso, Fenton Read McFeely, John Jacob Yurkas
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Patent number: 6608360Abstract: This disclosure describes one-chip micro-integrated optoelectronic sensors and methods for fabricating and using the same. The sensors may include an optical emission source, optical filter and a photodetector fabricated on the same transparent substrate using the same technological processes. Optical emission may occur when a bias voltage is applied across a metal-insulator-semiconductor Schottky contact or a p-n junction. The photodetector may be a Schottky contact or a p-n junction in a semiconductor. Some sensors can be fabricated on optically transparent substrate and employ back-side illumination. In the other sensors provided, the substrate is not transparent and emission occurs from the edge of a p-n junction or through a transparent electrode. The sensors may be used to measure optical absorption, optical reflection, scattering or fluorescence.Type: GrantFiled: December 15, 2000Date of Patent: August 19, 2003Assignee: University of HoustonInventors: David Starikov, Igor Berishev, Abdelhak Bensaoula
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Patent number: 6597050Abstract: A method of contacting a silicide-based Schottky diode including the step of providing a contact to the silicide that is fully bordered with respect to an internal edge of the guard ring area. A Schottky diode having silicide contacting a guard ring of the Schottky diode and a contact to the silicide that is fully bordered by silicide with respect to an internal edge of the guard ring.Type: GrantFiled: May 19, 2000Date of Patent: July 22, 2003Assignee: International Business Machines CorporationInventors: James Stuart Dunn, Peter Brian Gray, Kenneth Knetch Kieft, III, Nicholas Theodore Schmidt, Stephen St. onge
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Publication number: 20030025171Abstract: A method of forming a semiconductor substrate having a plurality of epitaxial regions disposed at different lateral locations, includes assembling a plurality of epitaxial layers vertically adjacent to each other on a host substrate to form an epitaxial structure; etching a surface of the epitaxial structure to reveal epitaxial regions of the epitaxial layers at different lateral locations on the host substrate; and wafer bonding the etched surface of the epitaxial structure to a transfer substrate.Type: ApplicationFiled: July 31, 2002Publication date: February 6, 2003Inventors: Jonathan Charles Geske, Vijaysekhar Jayaraman
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Patent number: 6211560Abstract: PtSi/Si Schottky diode infrared detectors are currently being used in large-area focal plane arrays for imaging in the 3-5 micron atmospheric transmission window. Their photoresponse cuts off at about 6 microns, beyond which they cannot detect infrared ratiation. Because of the nature of Schottky diodes, this cut-off wavelength cannot be adjusted during operation, but is relatively fixed, varying only in proportion of the fourth root of an externally applied bias. This disclosure describes a Schottky diode infrared detector with a voltage-tunable cut-off wavelength. The tunability is obtained by modification of the Schottky diode band diagram by insertion of a SiGe layer, with the appropriate parameters, between the silicide and the Si substrate, making the detector a silicide/SiGe/Si Schottky diode detector. The SiGe/Si interface has a valence band offset that can be used to engineer the shape, or depth profile, of the Schottky barrier.Type: GrantFiled: June 16, 1995Date of Patent: April 3, 2001Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Jorge R. Jimenez, Paul W. Pellegrini
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Patent number: 5710447Abstract: Disclosed is a solid state image device which has a plurality of photosensitive units which are disposed in parallel with each other and each of which includes a row of a plurality of photosensitive devices each of which includes a first N(or P)-type impurity region which is selectively formed on the surface of a P(or N)-type semiconductor region at the surface of a semiconductor substrate, a CCD register for executing electronic scanning which is disposed in parallel to the row of photosensitive devices, and a read-out gate in which a signal charge is transferred from the photosensitive device to the CCD register, wherein a transparent Schottky electrode is formed on the first N(or P)-type impurity region except a portion adjacent to the read-out gate region, the Schottky electrode is electrically connected to a P.sup.+ (or N.sup.Type: GrantFiled: October 27, 1995Date of Patent: January 20, 1998Assignee: NEC CorporationInventor: Shigeru Tohyama
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Patent number: 5648667Abstract: Photo-sensing elements are arranged in a form of a matrix, with photo-sensing characteristics substantially equal with each other in a row direction, but different therebetween in a column direction. Vertical charge transfer circuits receive charge signals in parallel from the photo-sensing elements, and transfer them as serial data therealong, respectively, to a horizontal CCD, which receives respective lowermost signals of the serial data from the vertical charge transfer circuits and transfers them as a serial data therealong, in which associated signals are substantially free of siginificant irregularities therebetween, so that the horizontal charge transfer circuit has an improved apparent charge transfer efficiency and an optimized drive amplitude, in addition to that a signal amplification in a data processor may be achieved with an optimized gain.Type: GrantFiled: June 6, 1995Date of Patent: July 15, 1997Assignee: NEC CorporationInventor: Kazuo Konuma
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Patent number: 5648297Abstract: Extended cutoff wavelengths of PtSi Schottky infrared detectors in the long wavelength infrared (LWIR) regime have been demonstrated for the first time. This result was achieved by incorporating a 1-nm-thick p+ doping spike at the PtSi/Si interface. The extended cutoff wavelengths resulted from the combined effects of an increased electric field near the silicide/Si interface due to the p+ doping spike and the Schottky image force. The p+ doping spikes were grown by molecular beam epitaxy at 450 degrees Celsius using elemental boron as the dopant source, with doping concentrations ranging from 1.times.10.sup.19 to 1.times.10.sup.21 cm.sup.-3. The cutoff wavelengths were shown to increase with increasing doping concentrations of the p+ spikes.Type: GrantFiled: May 21, 1996Date of Patent: July 15, 1997Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: True-Lon Lin, Jin S. Park, Sarath D. Gunapala, Eric W. Jones, Hector M. Del Castillo
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Patent number: 5598016Abstract: Disclosed is a photoelectric conversion device in which a photodiode capacitance is increased. A transparent electrode is formed between a reflecting plate and a photodiode constituting a unitary picture element of a CCD image sensor. It is so formed that light is incident from the rear surface and the loop of the standing wave of the light comes on a platinum silicide film, thereby achieving the effective absorption of the incident light. The transparent electrode is formed between the reflecting plate and the photodiode in opposition to the platinum silicide film. The capacitance between the transparent electrode and the platinum silicide film can be utilized as photodiode capacitance.Type: GrantFiled: December 16, 1994Date of Patent: January 28, 1997Assignee: NEC CorporationInventors: Akihito Tanabe, Shigeru Tohyama
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Patent number: 5565676Abstract: Disclosed is a photoelectric conversion device in which a photodiode capacitance is increased. A transparent electrode is formed between a reflecting plate and a photodiode constituting a unitary picture element of a CCD image sensor. It is so formed that light is incident from the rear surface and the loop of the standing wave of the light comes on a platinum silicide film, thereby achieving the effective absorption of the incident light. The transparent electrode is formed between the reflecting plate and the photodiode in opposition to the platinum silicide film. The capacitance between the transparent electrode and the platinum silicide film can be utilized as photodiode capacitance.Type: GrantFiled: June 6, 1995Date of Patent: October 15, 1996Assignee: NEC CorporationInventors: Akihito Tanabe, Shigeru Tohyama
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Patent number: 5488231Abstract: A metal/semiconductor junction Schottky diode optical device using a distortion grown layer is described. A plurality of GaAs mirror and AlAs mirror layers are periodically grown on a semi-insulating GaAs substrate. An n+ or p+ semiconductor layer is formed on the GaAs mirror and AlAs mirror layers. A GaAs buffer layer is formed on the semiconductor layer to grow a Schottky metal layer serving as an electrode and a mirror. A multiple quantum well structure having an electro-optical absorption characteristic is positioned between the semiconductor layer and Schottky metal layer, for constructing a diode with the metal layer/multiple quantum well structure. At least a part of the mirror layers and diode are formed with a layer in order to have resonance and non-resonance conditions between the metal layer and mirror layers. The substrate on which the diode is formed has an opposite side formed with an optical non-reflective layer.Type: GrantFiled: December 9, 1994Date of Patent: January 30, 1996Assignee: Electronics and Telecommunications Research InstituteInventors: O-Kyun Kwon, Young-Wan Choi, El-Hang Lee
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Patent number: 5471072Abstract: Gold, which is the commonly used metallization on .beta.-silicon carbide, is known to degrade at temperatures above 450.degree. C. It also exhibits poor adhesion to silicon carbide. Schottky contacts with platinum metallization have rectifying characteristics similar to contacts with gold metallization. The platinum Schottky contacts remain stable up to 800.degree. C. Adhesion of the platinum deposited at slightly elevated temperatures is also superior to that for gold. Platinum provides a metallization that is physically more rugged and thermally more stable than conventional gold metallization.Type: GrantFiled: December 13, 1993Date of Patent: November 28, 1995Assignee: The United States of America as represented by the Secretary of the NavyInventor: Nicolas A. Papanicolaou
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Patent number: 5359213Abstract: A charge transfer device and a solid state image sensor using the same, capable of transferring signal charge at a high signal to noise ratio (S/N ratio) and preventing an occurrence of dark current. They include a double-layered charge transfer path structure provided by forming a surface channel region on a buried channel region formed in a semiconductor substrate, the surface channel region having a conductivity opposite to that of the buried channel region. The surface channel region of the doubled-layered structure is used for accumulating dark current generated from boundary surfaces between the substrate and a gate insulating film, whereas the buried channel region is used for transferring optical signal charge. Where minus and/or plus drive voltages are applied to the transfer electrodes, there is no increase in dark current, in accordance with the present invention. The quantity of transferred signal charge can be greatly increased.Type: GrantFiled: March 30, 1993Date of Patent: October 25, 1994Assignee: Goldstar Electron Co., Ltd.Inventors: Seo K. Lee, Uya Shinji
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Patent number: 5326996Abstract: Methods and apparatus for implementing charge skimming and variable integration time in focal plane arrays formed in a silicon substrate. The present invention provides for pulsing a field plate that lies over a diode disposed in the substrate in order to provide for charge skimming and variable integration time. The field plate is normally dc biased to suppress diode edge leakage. No additional structure is needed in the silicon substrate, and basic readout clocking is unaffected. Any interline transfer focal plane array can benefit from using the principles of the present invention.Type: GrantFiled: July 6, 1993Date of Patent: July 5, 1994Assignee: Loral Fairchild Corp.Inventor: Michael J. McNutt
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Patent number: 5285098Abstract: A method and structure are provided for internal photoemission detection. At least one groove (30a) is formed in a side of a semiconductor layer (32). A silicide film (58) is formed in each groove (30a) over the semiconductor layer (32). A metal contact region (44) is electrically coupled to the silicide film (58) such that a voltage at the metal contact region (44) indicates an intensity of radiation incident on the structure (28).Type: GrantFiled: April 30, 1992Date of Patent: February 8, 1994Assignee: Texas Instruments IncorporatedInventor: Sebastian R. Borrello
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Patent number: 5163179Abstract: Platinum Silicide (PtSi) layers formed on silicon substrates are well known for their ability to image in the infrared portion of the electromagnetic spectrum out to 5.75 micrometers. The detectors are formed on p-type silicon substrates of <100> orientation. This is the preferred crystal structure for silicon when used for fabrication of Very Large Scale Integration (VLSI). The cooling required for these devices is 77.degree. K., which is needed to reduce thermal currents in the diodes to be significantly below the infrared generated signal. Detector array operation at these temperatures does not allow for operation in space for extended missions because a closed cycle mechanical cooler must be used. We have developed a new PtSi detector which must be fabricated on p-type silicon having a <111> crystal orientation. The detectors have been measured for their cutoff wavelength and barrier height is 0.310 eV which translates to a cutoff wavelength of 4.0 micrometers.Type: GrantFiled: December 17, 1991Date of Patent: November 10, 1992Assignee: The United States of America as represented by the Secretary of the Air ForceInventor: Paul W. Pellegrini