Silicide Of Platinum Group Metal Patents (Class 257/455)
  • Patent number: 11004999
    Abstract: A photodetector element according to an aspect of the present disclosure includes a semiconductor layer with an uneven structure on one surface side that is constituted of projection portions and recess portions, and converts light into surface plasmons, and a metal film that is provided on the one surface side of the semiconductor layer in a manner corresponding to the uneven structure and a Schottky junction is formed between the metal film and the semiconductor layer. The semiconductor layer is constituted of n-type conductive silicon, and the other surface side of the semiconductor layer serves as an incident surface for light. The metal film is constituted of a material including nickel which form the Schottky junction when combined with the semiconductor layer.
    Type: Grant
    Filed: March 14, 2019
    Date of Patent: May 11, 2021
    Assignee: HAMAMATSU PHOTONICS K.K.
    Inventors: Wei Dong, Hiroyasu Fujiwara
  • Patent number: 9013002
    Abstract: An iridium interfacial stack (“IrIS”) and a method for producing the same are provided. The IrIS may include ordered layers of TaSi2, platinum, iridium, and platinum, and may be placed on top of a titanium layer and a silicon carbide layer. The IrIS may prevent, reduce, or mitigate against diffusion of elements such as oxygen, platinum, and gold through at least some of its layers.
    Type: Grant
    Filed: June 27, 2012
    Date of Patent: April 21, 2015
    Assignee: The United States of America as Represented by the Administrator of National Aeronautics and Space Administration
    Inventor: David James Spry
  • Patent number: 9006785
    Abstract: Semiconductor trilayer structures that are doped and strained are provided. Also provided are mechanically flexible transistors, including radiofrequency transistors, incorporating the trilayer structures and methods for fabricating the trilayer structures and transistors. The trilayer structures comprise a first layer of single-crystalline semiconductor material, a second layer of single-crystalline semiconductor material and a third layer of single-crystalline semiconductor material. In the structures, the second layer is in contact with and sandwiched between the first and third layers and the first layer is selectively doped to provide one or more doped regions in the layer.
    Type: Grant
    Filed: January 28, 2013
    Date of Patent: April 14, 2015
    Assignee: Wisconsin Alumni Research Foundation
    Inventors: Zhenqiang Ma, Jung-Hun Seo, Max G. Lagally
  • Patent number: 8916451
    Abstract: A method for wafer transfer includes forming a spreading layer, including graphene, on a single crystalline SiC substrate. A semiconductor layer including one or more layers is formed on and is lattice matched to the crystalline SiC layer. The semiconductor layer is transferred to a handle substrate, and the spreading layer is split to remove the single crystalline SiC substrate.
    Type: Grant
    Filed: February 5, 2013
    Date of Patent: December 23, 2014
    Assignee: International Business Machines Corporation
    Inventors: Can Bayram, Jack O. Chu, Christos Dimitrakopoulos, Jeehwan Kim, Hongsik Park, Devendra K. Sadana
  • Patent number: 8878329
    Abstract: A high voltage device having a Schottky diode integrated with a MOS transistor includes a semiconductor substrate a Schottky diode formed on the semiconductor substrate, at least a first doped region having a first conductive type formed in the semiconductor substrate and under the Schottky diode, and a control gate covering a portion of the Schottky diode and the first doped region positioned on the semiconductor substrate.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: November 4, 2014
    Assignee: United Microelectronics Corp.
    Inventor: Min-Hsuan Tsai
  • Patent number: 8835309
    Abstract: A method of performing a silicide contact process comprises a forming a nickel-platinum alloy (NiPt) layer over a semiconductor device structure; performing a first rapid thermal anneal (RTA) so as to react portions of the NiPt layer in contact with semiconductor regions of the semiconductor device structure, thereby forming metal rich silicide regions; performing a first wet etch to remove at least a nickel constituent of unreacted portions of the NiPt layer; performing a second wet etch using a dilute Aqua Regia treatment comprising nitric acid (HNO3), hydrochloric acid (HCl) and water (H2O) to remove any residual platinum material from the unreacted portions of the NiPt layer; and following the dilute Aqua Regia treatment, performing a second RTA to form final silicide contact regions from the metal rich silicide regions.
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: September 16, 2014
    Assignee: International Business Machines Corporation
    Inventors: David F. Hilscher, Christian Lavoie, Ahmet S. Ozcan
  • Patent number: 8482084
    Abstract: A Schottky field effect transistor is provided that includes a substrate having a layer of semiconductor material atop a dielectric layer, wherein the layer of semiconductor material has a thickness of less than 10.0 nm. A gate structure is present on the layer of semiconductor material. Raised source and drain regions comprised of a metal semiconductor alloy are present on the layer of semiconductor material on opposing sides of the gate structure. The raised source and drain regions are Schottky source and drain regions. In one embodiment, a first portion of the Schottky source and drain regions that is adjacent to a channel region of the Schottky field effect transistor contacts the dielectric layer, and a non-reacted semiconductor material is present between a second portion of the Schottky source and drain regions and the dielectric layer.
    Type: Grant
    Filed: March 18, 2010
    Date of Patent: July 9, 2013
    Assignees: International Business Machines Corporation, Global Foundries, Inc.
    Inventors: Marwan H. Khater, Christian Lavoie, Bin Yang, Zhen Zhang
  • Patent number: 8344398
    Abstract: A method of making a diode begins by depositing an AlxGa1-xN nucleation layer on a SiC substrate, then depositing an n+ GaN buffer layer, an n? GaN layer, an AlxGa1-xN barrier layer, and an SiO2 dielectric layer. A portion of the dielectric layer is removed and a Schottky metal deposited in the void. The dielectric layer is affixed to the support layer with a metal bonding layer using an Au—Sn utectic wafer bonding process, the substrate is removed using reactive ion etching to expose the n+ layer, selected portions of the n+, n?, and barrier layers are removed to form a mesa diode structure on the dielectric layer over the Schottky metal, and an ohmic contact is deposited on the n+ layer.
    Type: Grant
    Filed: October 15, 2010
    Date of Patent: January 1, 2013
    Assignee: Cree, Inc.
    Inventors: Primit Parikh, Sten Heikman
  • Patent number: 8278199
    Abstract: Reliability of a semiconductor element and its product yield are improved by reducing variations in the electrical characteristic of a metal silicide layer. After forming a nickel-platinum alloy film over a semiconductor substrate, by carrying out a first thermal treatment at a thermal treatment temperature of 210 to 310° C. using a heater heating device, the technique causes the nickel-platinum alloy film and silicon to react with each other to form a platinum-added nickel silicide layer in a (PtNi)2Si phase. After removing unreacted nickel-platinum alloy film, the technique carries out a second thermal treatment having the thermal treatment temperature higher than that of the first thermal treatment to form the platinum-added nickel silicide layer in a PtNiSi phase. The temperature rise rate of each thermal treatment is set to 10° C./s or more.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: October 2, 2012
    Assignee: Renesas Electronics Corporation
    Inventors: Shigenari Okada, Takuya Futase, Yutaka Inaba
  • Patent number: 8237170
    Abstract: To provide a Schottky electrode in a diamond semiconductor, which has a good adhesion properties to diamonds, has a contacting surface which does not become peeled due to an irregularity in an external mechanical pressure, does not cause a reduction in yield in a diode forming process and does not cause deterioration in current-voltage characteristics, and a method of manufacturing the Schottky electrode. A Schottky electrode which includes: scattered island-form pattern Pt-group alloy thin films which are formed on a diamond surface formed on a substrate, in which the Pt-group alloy includes 50 to 99.9 mass % of Pt and 0.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: August 7, 2012
    Assignee: National Institute of Advanced Industrial Science and Technology
    Inventors: Kazuhiro Ikeda, Hitoshi Umezawa, Shinichi Shikata
  • Patent number: 8164154
    Abstract: A low profile high power Schottky barrier bypass diode for solar cells and panels with the cathode and anode electrodes on the same side of the diode and a method of fabrication thereof are disclosed for generating a thin chip with both electrodes being on the same side of the chip. In an embodiment, a mesa isolation with a Zener diode over the annular region surrounding the central region of the mesa anode in the Epi of the substrate is formed. In an embodiment, a P-type Boron dopant layer is ion implanted in the annular region for the Zener Diode. This controls recovery from high voltage spikes from the diode rated voltage. A Schottky barrier contact for the anode and a contact for the cathode are simultaneously created on the same side of the chip.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: April 24, 2012
    Inventors: Aram Tanielian, Garo Tanielian
  • Patent number: 8039308
    Abstract: Embodiments of a multi-chip module (MCM) are described. This MCM includes a first semiconductor die and a second semiconductor die, where a given semiconductor die, which can be the first semiconductor die or the second semiconductor die, includes proximity connectors proximate to a surface of the given semiconductor die. Moreover, the given semiconductor die is configured to communicate signals with the other semiconductor die via proximity communication through one or more of the proximity connectors. Furthermore, the MCM includes an alignment plate and a top plate coupled to the alignment plate. This alignment plate includes a first negative feature configured to accommodate the first semiconductor die and a second negative feature configured to accommodate the second semiconductor die, and the top plate includes a positive feature. Note that the positive feature is coupled to the first semiconductor die, and the positive feature facilitates mechanical positioning of the first semiconductor die.
    Type: Grant
    Filed: January 13, 2011
    Date of Patent: October 18, 2011
    Assignee: Oracle America, Inc.
    Inventors: James G. Mitchell, John E. Cunningham, Ashok V. Krishnamoorthy
  • Patent number: 8039378
    Abstract: To provide a technique capable of improving the reliability of a semiconductor element and its product yield by reducing the variations in the electrical characteristic of a metal silicide layer. After forming a nickel-platinum alloy film over a semiconductor substrate 1, by carrying out a first thermal treatment at a thermal treatment temperature of 210 to 310° C. using a heater heating device, the technique causes the nickel-platinum alloy film and silicon to react with each other to form a platinum-added nickel silicide layer in a (PtNi)2Si phase. Subsequently, after removing the unreacted nickel-platinum alloy film, the technique carries out a second thermal treatment having the thermal treatment temperature higher than that of the first thermal treatment to form the platinum-added nickel silicide layer in a PtNiSi phase. The temperature rise rate of the first thermal treatment is set to 10° C./s or more (for example, 30 to 250° C.
    Type: Grant
    Filed: January 23, 2009
    Date of Patent: October 18, 2011
    Assignee: Renesas Electronics Corporation
    Inventors: Shigenari Okada, Takuya Futase, Yutaka Inaba
  • Patent number: 7999340
    Abstract: An apparatus and method for forming optical black pixels having uniformly low dark current. Optical Black opacity is increased without having to increase Ti/TiN layer thickness. A hybrid approach is utilized combining a Ti/TiN OB layer in conjunction with in-pixel metal stubs that further occlude the focal radius of each pixel's incoming light beam. Additional metal layers can be used to increase the opacity into the infrared region.
    Type: Grant
    Filed: March 7, 2007
    Date of Patent: August 16, 2011
    Assignee: AltaSens, Inc.
    Inventors: Giuseppe Rossi, Lester Kozlowski, Henry Lin, John Richardson, Gregory Chow, Gaurang Patel
  • Patent number: 7999344
    Abstract: An optoelectronic device comprises a photodetector feature, an interfacial layer disposed above at least a portion of the photodetector feature, and a vertical contact disposed on at least a portion of the interfacial layer. The photodetector feature comprises germanium and is operative to convert a light signal into an electrical signal. The interfacial layer comprises nickel. Finally, the vertical contact is operative to transmit the electrical signal from the photodetector feature.
    Type: Grant
    Filed: May 6, 2010
    Date of Patent: August 16, 2011
    Assignee: International Business Machines Corporation
    Inventors: Solomon Assefa, Stephen Walter Bedell, Yurii A. Vlasov, Fengnian Xia
  • Patent number: 7847326
    Abstract: A backside illuminated image sensor includes a photodiode, formed below the top surface of a semiconductor substrate, for receiving light illuminated from the backside of the semiconductor substrate to generate photoelectric charges, a reflecting gate, formed on the photodiode over the front upper surface of the semiconductor substrate, for reflecting light illuminated from the backside of the substrate and receiving a bias to control a depletion region of the photodiode, and a transfer gate for transferring photoelectric charges from the photodiode to a sensing node of a pixel.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: December 7, 2010
    Inventors: Sung-Hyung Park, Ju-Il Lee
  • Patent number: 7834367
    Abstract: A method of making a diode begins by depositing an AlxGa1?xN nucleation layer on a SiC substrate, then depositing an n+ GaN buffer layer, an n? GaN layer, an AlxGa1?xN barrier layer, and an SiO2 dielectric layer. A portion of the dielectric layer is removed and a Schottky metal deposited in the void. The dielectric layer is affixed to the support layer with a metal bonding layer using an Au-Sn utectic wafer bonding process, the substrate is removed using reactive ion etching to expose the n+ layer, selected portions of the n+, n?, and barrier layers are removed to form a mesa diode structure on the dielectric layer over the Schottky metal,; and an ohmic contact is deposited on the n+ layer.
    Type: Grant
    Filed: January 19, 2007
    Date of Patent: November 16, 2010
    Assignee: Cree, Inc.
    Inventors: Primit Parikh, Sten Heikman
  • Patent number: 7790495
    Abstract: An optoelectronic device comprises a photodetector feature, an interfacial layer disposed above at least a portion of the photodetector feature, and a vertical contact disposed on at least a portion of the interfacial layer. The photodetector feature comprises germanium and is operative to convert a light signal into an electrical signal. The interfacial layer comprises nickel. Finally, the vertical contact is operative to transmit the electrical signal from the photodetector feature.
    Type: Grant
    Filed: October 26, 2007
    Date of Patent: September 7, 2010
    Assignee: International Business Machines Corporation
    Inventors: Solomon Assefa, Stephen Walter Bedell, Yurii A. Vlasov, Fengnian Xia
  • Patent number: 7679662
    Abstract: Disclosed herein is a solid-state imaging element which includes a plurality of drive signal inputs, a plurality of bus lines, and a plurality of vertical transfer register electrodes. In the solid-state imaging element, a charge accumulated in light-receiving elements in a pixel region is vertically transferred by the drive signals input to the electrodes. Each of the electrodes has a contact part connected to the second contact and having a width smaller than a width of the electrodes in the pixel region, and a blank region is formed between predetermined adjacent two of the contact parts so that a width of the blank region is larger than a distance between respective two of the contact parts other than the predetermined adjacent two of the contact parts. The first contact is disposed on the blank region.
    Type: Grant
    Filed: November 9, 2006
    Date of Patent: March 16, 2010
    Assignee: Sony Corporation
    Inventors: Sadamu Suizu, Masaaki Takayama
  • Patent number: 7420215
    Abstract: A transparent conductive film substantially made from In2O3, SnO2 and ZnO, having a molar ratio In/(In+Sn+Zn) of 0.65 to 0.8 and also a molar ratio Sn/Zn of 1 or less: The transparent conductive film has a favorable electric contact property with an electrode or line made from Al or Al alloy film. Further, a semiconductor device having an electrode or line made from the transparent conductive film has high reliability and productivity.
    Type: Grant
    Filed: June 22, 2007
    Date of Patent: September 2, 2008
    Assignee: Mitsubishi Electric Corporation
    Inventors: Kazunori Inoue, Nobuaki Ishiga, Kensuke Nagayama, Toru Takeguchi, Kazumasa Kawase
  • Patent number: 7329927
    Abstract: Integrated circuit devices are provided including an integrated circuit substrate and a gate on the integrated circuit substrate. The gate has sidewalls. A barrier layer spacer is provided on the sidewalls of the gate. A portion of the barrier layer spacer protrudes from the sidewalls of the gate exposing a lower surface of the barrier layer spacer that faces the integrated circuit substrate. A silicide layer is provided on the portion of the barrier layer spacer protruding from the sidewalls of the gate.
    Type: Grant
    Filed: June 24, 2005
    Date of Patent: February 12, 2008
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Se-myeong Jang, Gyo-young Jin, Yong-chul Oh, Hyun-chang Kim
  • Patent number: 7176537
    Abstract: A semiconductor device having a metal/metal silicide gate and a Schottky source/drain and a method of forming the same are provided. The semiconductor device includes a gate dielectric overlying a semiconductor substrate, a metal or metal silicide gate electrode having a work function of less than about 4.3 eV or greater than about 4.9 eV overlying the gate dielectric, a spacer having a thickness of less than about 100 ? on a side of the gate electrode, and a Schottky source/drain having a work function of less than about 4.3 eV or greater than about 4.9 eV wherein the Schottky source/drain region overlaps the gate electrode. The Schottky source/drain region preferably has a thickness of less than about 300 ?.
    Type: Grant
    Filed: May 23, 2005
    Date of Patent: February 13, 2007
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Wen-Chin Lee, Chung-Hu Ke, Min-Hwa Chi
  • Patent number: 7075158
    Abstract: A semiconductor device can be manufactured which has a low resistance, and device characteristics of which do not vary. The semiconductor device includes a silicon layer, a gate dielectric film formed on the silicon layer, a gate electrode formed on the gate dielectric film and including a nitrided metal silicide layer which is partially crystallized, and source and drain regions formed in a surface region of the silicon layer at both sides of the gate electrode.
    Type: Grant
    Filed: October 6, 2005
    Date of Patent: July 11, 2006
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masato Koyama, Akira Nishiyama, Masamichi Suzuki, Yuuichi Kamimuta, Tsunehiro Ino
  • Patent number: 6982467
    Abstract: A semiconductor device can be manufactured which has a low resistance, and device characteristics of which do not vary. The semiconductor device includes a silicon layer, a gate dielectric film formed on the silicon layer, a gate electrode formed on the gate dielectric film and including a nitrided metal silicide layer which is partially crystallized, and source and drain regions formed in a surface region of the silicon layer at both sides of the gate electrode.
    Type: Grant
    Filed: June 9, 2004
    Date of Patent: January 3, 2006
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masato Koyama, Akira Nishiyama, Masamichi Suzuki, Yuuichi Kamimuta, Tsunehiro Ino
  • Patent number: 6956274
    Abstract: A metallization stack is provided for use as a contact structure in an integrated MEMS device. The metallization stack comprises a titanium-tungsten adhesion and barrier layer formed with a platinum layer formed on top. The platinum feature is formed by sputter etching the platinum in argon, followed by a wet etch in aqua regia using an oxide hardmask. Alternatively, the titanium-tungsten and platinum layers are deposited sequentially and patterned by a single plasma etch process with a photoresist mask.
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: October 18, 2005
    Assignee: Analog Devices, Inc.
    Inventors: Susan A. Alie, Bruce K. Wachtmann, David S. Kneedler, Scott Limb, Kieran Nunan
  • Patent number: 6846731
    Abstract: In the present invention, there is provided semiconductor devices such as a Schottky UV photodetector fabricated on n-type ZnO and MgxZn1-xO epitaxial films. The ZnO and MgxZn1-xO films are grown on R-plane sapphire substrates and the Schottky diodes are fabricated on the ZnO and MgxZn1-xO films using silver and aluminum as Schottky and ohmic contact metals, respectively. The Schottky diodes have circular patterns, where the inner circle is the Schottky contact, and the outside ring is the ohmic contact. Ag Schottky contact patterns are fabricated using standard liftoff techniques, while the Al ohmic contact patterns are formed using wet chemical etching. These detectors show low frequency photoresponsivity, high speed photoresponse, lower leakage current and low noise performance as compared to their photoconductive counterparts. This invention is also applicable to optical modulators, Metal Semiconductor Field Effect Transistors (MESFETs) and more.
    Type: Grant
    Filed: May 30, 2002
    Date of Patent: January 25, 2005
    Assignee: Rutgers, The State University of New Jersey
    Inventors: Yicheng Lu, Haifeng Sheng, Sriram Muthukumar, Nuri William Emanetoglu, Jian Zhong
  • Patent number: 6798034
    Abstract: A passive mechanism suppresses injection, into any active guard regions interposed between the edge of a photodiode array chip and the outer photodiode pixels or into the outer pixels themselves, of minority carrier current generated in the physically disrupted region at the edge of the semiconductor die created by cleaving, sawing or otherwise separating the chip from the remainder of the wafer on which the die was fabricated. A thin metallic layer covers all or part of the edge region, thereby creating a Schottky barrier. This barrier generates a depletion region in the adjacent semiconductor material. The depletion region inherently creates an energy band distribution which preferentially accelerates minority carriers generated or near the metal-semiconductor interface towards the metal, thereby suppressing collection of these carriers by any active regions of the guard structure or by the photodiode pixels.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: September 28, 2004
    Assignee: Diglrad Corporation
    Inventor: Lars S. Carlson
  • Patent number: 6756651
    Abstract: A novel photodetector CMOS-compatible photodetector is disclosed in which photo-generation of carriers (electrons) is carried out in the metal of the electrodes, rather than as electron-hole pairs in the semiconductor on which the metal electrodes are deposited. The novel photo detector comprises a silicon or other semiconductor substrate material characterized by an electron energy bandgap, and a pair of metal electrodes disposed upon a surface of the silicon to define therebetween a border area of the surface. One of the two electrodes being exposed to the incident radiation and covering an area of said surface which is larger than the aforesaid border area, the aforesaid metal of the electrodes being characterized by a Fermi level which is within said electron energy bandgap.
    Type: Grant
    Filed: September 26, 2001
    Date of Patent: June 29, 2004
    Assignee: International Business Machines Corporation
    Inventors: Ferenc M. Bozso, Fenton Read McFeely, John Jacob Yurkas
  • Patent number: 6608360
    Abstract: This disclosure describes one-chip micro-integrated optoelectronic sensors and methods for fabricating and using the same. The sensors may include an optical emission source, optical filter and a photodetector fabricated on the same transparent substrate using the same technological processes. Optical emission may occur when a bias voltage is applied across a metal-insulator-semiconductor Schottky contact or a p-n junction. The photodetector may be a Schottky contact or a p-n junction in a semiconductor. Some sensors can be fabricated on optically transparent substrate and employ back-side illumination. In the other sensors provided, the substrate is not transparent and emission occurs from the edge of a p-n junction or through a transparent electrode. The sensors may be used to measure optical absorption, optical reflection, scattering or fluorescence.
    Type: Grant
    Filed: December 15, 2000
    Date of Patent: August 19, 2003
    Assignee: University of Houston
    Inventors: David Starikov, Igor Berishev, Abdelhak Bensaoula
  • Patent number: 6597050
    Abstract: A method of contacting a silicide-based Schottky diode including the step of providing a contact to the silicide that is fully bordered with respect to an internal edge of the guard ring area. A Schottky diode having silicide contacting a guard ring of the Schottky diode and a contact to the silicide that is fully bordered by silicide with respect to an internal edge of the guard ring.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: July 22, 2003
    Assignee: International Business Machines Corporation
    Inventors: James Stuart Dunn, Peter Brian Gray, Kenneth Knetch Kieft, III, Nicholas Theodore Schmidt, Stephen St. onge
  • Publication number: 20030025171
    Abstract: A method of forming a semiconductor substrate having a plurality of epitaxial regions disposed at different lateral locations, includes assembling a plurality of epitaxial layers vertically adjacent to each other on a host substrate to form an epitaxial structure; etching a surface of the epitaxial structure to reveal epitaxial regions of the epitaxial layers at different lateral locations on the host substrate; and wafer bonding the etched surface of the epitaxial structure to a transfer substrate.
    Type: Application
    Filed: July 31, 2002
    Publication date: February 6, 2003
    Inventors: Jonathan Charles Geske, Vijaysekhar Jayaraman
  • Patent number: 6211560
    Abstract: PtSi/Si Schottky diode infrared detectors are currently being used in large-area focal plane arrays for imaging in the 3-5 micron atmospheric transmission window. Their photoresponse cuts off at about 6 microns, beyond which they cannot detect infrared ratiation. Because of the nature of Schottky diodes, this cut-off wavelength cannot be adjusted during operation, but is relatively fixed, varying only in proportion of the fourth root of an externally applied bias. This disclosure describes a Schottky diode infrared detector with a voltage-tunable cut-off wavelength. The tunability is obtained by modification of the Schottky diode band diagram by insertion of a SiGe layer, with the appropriate parameters, between the silicide and the Si substrate, making the detector a silicide/SiGe/Si Schottky diode detector. The SiGe/Si interface has a valence band offset that can be used to engineer the shape, or depth profile, of the Schottky barrier.
    Type: Grant
    Filed: June 16, 1995
    Date of Patent: April 3, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Jorge R. Jimenez, Paul W. Pellegrini
  • Patent number: 5710447
    Abstract: Disclosed is a solid state image device which has a plurality of photosensitive units which are disposed in parallel with each other and each of which includes a row of a plurality of photosensitive devices each of which includes a first N(or P)-type impurity region which is selectively formed on the surface of a P(or N)-type semiconductor region at the surface of a semiconductor substrate, a CCD register for executing electronic scanning which is disposed in parallel to the row of photosensitive devices, and a read-out gate in which a signal charge is transferred from the photosensitive device to the CCD register, wherein a transparent Schottky electrode is formed on the first N(or P)-type impurity region except a portion adjacent to the read-out gate region, the Schottky electrode is electrically connected to a P.sup.+ (or N.sup.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: January 20, 1998
    Assignee: NEC Corporation
    Inventor: Shigeru Tohyama
  • Patent number: 5648297
    Abstract: Extended cutoff wavelengths of PtSi Schottky infrared detectors in the long wavelength infrared (LWIR) regime have been demonstrated for the first time. This result was achieved by incorporating a 1-nm-thick p+ doping spike at the PtSi/Si interface. The extended cutoff wavelengths resulted from the combined effects of an increased electric field near the silicide/Si interface due to the p+ doping spike and the Schottky image force. The p+ doping spikes were grown by molecular beam epitaxy at 450 degrees Celsius using elemental boron as the dopant source, with doping concentrations ranging from 1.times.10.sup.19 to 1.times.10.sup.21 cm.sup.-3. The cutoff wavelengths were shown to increase with increasing doping concentrations of the p+ spikes.
    Type: Grant
    Filed: May 21, 1996
    Date of Patent: July 15, 1997
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: True-Lon Lin, Jin S. Park, Sarath D. Gunapala, Eric W. Jones, Hector M. Del Castillo
  • Patent number: 5648667
    Abstract: Photo-sensing elements are arranged in a form of a matrix, with photo-sensing characteristics substantially equal with each other in a row direction, but different therebetween in a column direction. Vertical charge transfer circuits receive charge signals in parallel from the photo-sensing elements, and transfer them as serial data therealong, respectively, to a horizontal CCD, which receives respective lowermost signals of the serial data from the vertical charge transfer circuits and transfers them as a serial data therealong, in which associated signals are substantially free of siginificant irregularities therebetween, so that the horizontal charge transfer circuit has an improved apparent charge transfer efficiency and an optimized drive amplitude, in addition to that a signal amplification in a data processor may be achieved with an optimized gain.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 15, 1997
    Assignee: NEC Corporation
    Inventor: Kazuo Konuma
  • Patent number: 5598016
    Abstract: Disclosed is a photoelectric conversion device in which a photodiode capacitance is increased. A transparent electrode is formed between a reflecting plate and a photodiode constituting a unitary picture element of a CCD image sensor. It is so formed that light is incident from the rear surface and the loop of the standing wave of the light comes on a platinum silicide film, thereby achieving the effective absorption of the incident light. The transparent electrode is formed between the reflecting plate and the photodiode in opposition to the platinum silicide film. The capacitance between the transparent electrode and the platinum silicide film can be utilized as photodiode capacitance.
    Type: Grant
    Filed: December 16, 1994
    Date of Patent: January 28, 1997
    Assignee: NEC Corporation
    Inventors: Akihito Tanabe, Shigeru Tohyama
  • Patent number: 5565676
    Abstract: Disclosed is a photoelectric conversion device in which a photodiode capacitance is increased. A transparent electrode is formed between a reflecting plate and a photodiode constituting a unitary picture element of a CCD image sensor. It is so formed that light is incident from the rear surface and the loop of the standing wave of the light comes on a platinum silicide film, thereby achieving the effective absorption of the incident light. The transparent electrode is formed between the reflecting plate and the photodiode in opposition to the platinum silicide film. The capacitance between the transparent electrode and the platinum silicide film can be utilized as photodiode capacitance.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 15, 1996
    Assignee: NEC Corporation
    Inventors: Akihito Tanabe, Shigeru Tohyama
  • Patent number: 5488231
    Abstract: A metal/semiconductor junction Schottky diode optical device using a distortion grown layer is described. A plurality of GaAs mirror and AlAs mirror layers are periodically grown on a semi-insulating GaAs substrate. An n+ or p+ semiconductor layer is formed on the GaAs mirror and AlAs mirror layers. A GaAs buffer layer is formed on the semiconductor layer to grow a Schottky metal layer serving as an electrode and a mirror. A multiple quantum well structure having an electro-optical absorption characteristic is positioned between the semiconductor layer and Schottky metal layer, for constructing a diode with the metal layer/multiple quantum well structure. At least a part of the mirror layers and diode are formed with a layer in order to have resonance and non-resonance conditions between the metal layer and mirror layers. The substrate on which the diode is formed has an opposite side formed with an optical non-reflective layer.
    Type: Grant
    Filed: December 9, 1994
    Date of Patent: January 30, 1996
    Assignee: Electronics and Telecommunications Research Institute
    Inventors: O-Kyun Kwon, Young-Wan Choi, El-Hang Lee
  • Patent number: 5471072
    Abstract: Gold, which is the commonly used metallization on .beta.-silicon carbide, is known to degrade at temperatures above 450.degree. C. It also exhibits poor adhesion to silicon carbide. Schottky contacts with platinum metallization have rectifying characteristics similar to contacts with gold metallization. The platinum Schottky contacts remain stable up to 800.degree. C. Adhesion of the platinum deposited at slightly elevated temperatures is also superior to that for gold. Platinum provides a metallization that is physically more rugged and thermally more stable than conventional gold metallization.
    Type: Grant
    Filed: December 13, 1993
    Date of Patent: November 28, 1995
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventor: Nicolas A. Papanicolaou
  • Patent number: 5359213
    Abstract: A charge transfer device and a solid state image sensor using the same, capable of transferring signal charge at a high signal to noise ratio (S/N ratio) and preventing an occurrence of dark current. They include a double-layered charge transfer path structure provided by forming a surface channel region on a buried channel region formed in a semiconductor substrate, the surface channel region having a conductivity opposite to that of the buried channel region. The surface channel region of the doubled-layered structure is used for accumulating dark current generated from boundary surfaces between the substrate and a gate insulating film, whereas the buried channel region is used for transferring optical signal charge. Where minus and/or plus drive voltages are applied to the transfer electrodes, there is no increase in dark current, in accordance with the present invention. The quantity of transferred signal charge can be greatly increased.
    Type: Grant
    Filed: March 30, 1993
    Date of Patent: October 25, 1994
    Assignee: Goldstar Electron Co., Ltd.
    Inventors: Seo K. Lee, Uya Shinji
  • Patent number: 5326996
    Abstract: Methods and apparatus for implementing charge skimming and variable integration time in focal plane arrays formed in a silicon substrate. The present invention provides for pulsing a field plate that lies over a diode disposed in the substrate in order to provide for charge skimming and variable integration time. The field plate is normally dc biased to suppress diode edge leakage. No additional structure is needed in the silicon substrate, and basic readout clocking is unaffected. Any interline transfer focal plane array can benefit from using the principles of the present invention.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: July 5, 1994
    Assignee: Loral Fairchild Corp.
    Inventor: Michael J. McNutt
  • Patent number: 5285098
    Abstract: A method and structure are provided for internal photoemission detection. At least one groove (30a) is formed in a side of a semiconductor layer (32). A silicide film (58) is formed in each groove (30a) over the semiconductor layer (32). A metal contact region (44) is electrically coupled to the silicide film (58) such that a voltage at the metal contact region (44) indicates an intensity of radiation incident on the structure (28).
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: February 8, 1994
    Assignee: Texas Instruments Incorporated
    Inventor: Sebastian R. Borrello
  • Patent number: 5163179
    Abstract: Platinum Silicide (PtSi) layers formed on silicon substrates are well known for their ability to image in the infrared portion of the electromagnetic spectrum out to 5.75 micrometers. The detectors are formed on p-type silicon substrates of <100> orientation. This is the preferred crystal structure for silicon when used for fabrication of Very Large Scale Integration (VLSI). The cooling required for these devices is 77.degree. K., which is needed to reduce thermal currents in the diodes to be significantly below the infrared generated signal. Detector array operation at these temperatures does not allow for operation in space for extended missions because a closed cycle mechanical cooler must be used. We have developed a new PtSi detector which must be fabricated on p-type silicon having a <111> crystal orientation. The detectors have been measured for their cutoff wavelength and barrier height is 0.310 eV which translates to a cutoff wavelength of 4.0 micrometers.
    Type: Grant
    Filed: December 17, 1991
    Date of Patent: November 10, 1992
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventor: Paul W. Pellegrini