Using Diffusion Into Or Out Of Solid From Or Into Gaseous Phase (epo) Patents (Class 257/E21.467)
  • Patent number: 8846459
    Abstract: A highly reliable semiconductor device and a method for manufacturing the semiconductor device are provided. The semiconductor device is manufactured with a high yield to achieve high productivity. In the manufacture of a semiconductor device including a transistor in which a gate electrode layer, a gate insulating film, and an oxide semiconductor film are sequentially stacked and a source electrode layer and a drain electrode layer are provided in contact with the oxide semiconductor film, the source electrode layer and the drain electrode layer are formed through an etching step and then a step for removing impurities which are generated by the etching step and exist on a surface of the oxide semiconductor film and in the vicinity thereof is performed.
    Type: Grant
    Filed: October 16, 2012
    Date of Patent: September 30, 2014
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Katsuaki Tochibayashi, Satoshi Higano, Shunpei Yamazaki
  • Patent number: 8614442
    Abstract: A thin film transistor (TFT) may include a channel layer, a source electrode, a drain electrode, a protective layer, a gate electrode, and/or a gate insulating layer. The channel layer may include an oxide semiconductor material. The source electrode and the drain electrode may face each other on the channel layer. The protective layer may be under the source electrode and the drain electrode and/or may cover the channel layer. The gate electrode may be configured to apply an electric field to the channel layer. The gate insulating layer may be interposed between the gate electrode and the channel layer.
    Type: Grant
    Filed: February 17, 2011
    Date of Patent: December 24, 2013
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Jae-chul Park, Young-soo Park, Sun-Il Kim
  • Patent number: 8501521
    Abstract: A method for forming a thin film photovoltaic device. The method includes providing a transparent substrate comprising a surface region. A first electrode layer is formed overlying the surface region. A copper layer is formed overlying the first electrode layer and an indium layer is formed overlying the copper layer to form a multi-layered structure. The method subjects at least the multi-layered structure to a thermal treatment process in an environment containing a sulfur bearing species to form a copper indium disulfide material and a thickness of substantially copper sulfide material. The thickness of the copper sulfide material is removed to expose a surface region having a copper poor surface comprising a copper to indium atomic ratio of less than about 0.95:1. The method subjects the copper poor surface to a copper species to convert the copper poor surface from an n-type semiconductor characteristic to a p-type semiconductor characteristic.
    Type: Grant
    Filed: September 21, 2009
    Date of Patent: August 6, 2013
    Assignee: Stion Corporation
    Inventor: Howard W. H. Lee
  • Patent number: 8476104
    Abstract: A method for forming a thin film photovoltaic device. The method includes providing a transparent substrate comprising a surface region, forming a first electrode layer overlying the surface region, forming a copper layer overlying the first electrode layer and forming an indium layer overlying the copper layer to form a multi-layered structure. The multi-layered structure is subjected to a thermal treatment process in an environment containing a sulfur bearing species to forming a copper indium disulfide material. The copper indium disulfide material comprising a copper-to-indium atomic ratio ranging from about 1.2:1 to about 2:1 and a thickness of substantially copper sulfide material having a copper sulfide surface region. The thickness of the copper sulfide material is selectively removed to expose a surface region having a copper poor surface comprising a copper to indium atomic ratio of less than about 0.95:1.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: July 2, 2013
    Assignee: Stion Corporation
    Inventor: Howard W. H. Lee
  • Patent number: 8440578
    Abstract: A method for amorphizing a layer on a substrate is described. In one embodiment, the method includes treating the substrate with a first gas cluster ion beam (GCIB) using a first beam energy selected to yield an amorphous sub-layer within the substrate of a desired thickness, which produces a first interfacial roughness of an amorphous-crystal interface between the amorphous sub-layer and a crystalline sub-layer of the substrate. The method further includes treating the substrate with a second GCIB using a second beam energy, less than the first beam energy, to reduce the first interfacial roughness of the amorphous-crystal interface to a second interfacial roughness.
    Type: Grant
    Filed: March 28, 2011
    Date of Patent: May 14, 2013
    Assignee: TEL Epion Inc.
    Inventor: John Gumpher
  • Patent number: 8435826
    Abstract: A method for forming a thin film photovoltaic device. The method includes providing a transparent substrate comprising a surface region and forming a first electrode layer overlying the surface region. The method forms a bulk copper indium disulfide material from a multi-layered structure comprising a copper species, an indium species, and a sulfur species overlying the first electrode layer. The bulk copper indium disulfide material comprises one or more portions of a copper poor copper indium disulfide material, a copper poor surface regions, and one or more portions of a sulfur deficient copper indium disulfide material characterized by at least a CuInS2-x species, where 0<x<2. The copper poor surface and one or more portions of the copper poor copper indium disulfide material are subjected to a sodium species derived from a sodium sulfide material to convert the copper poor surface from an n-type characteristic to a p-type characteristic.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: May 7, 2013
    Assignee: Stion Corporation
    Inventor: Howard W. H. Lee
  • Publication number: 20130099231
    Abstract: A highly reliable semiconductor device and a method for manufacturing the semiconductor device are provided. In a semiconductor device including a bottom-gate transistor in which an insulating layer functioning as a channel protective film is provided over an oxide semiconductor film, elements contained in an etching gas can be prevented from remaining as impurities on a surface of the oxide semiconductor film by performing impurity-removing process after formation of an insulating layer provided over and in contact with the oxide semiconductor film and/or formation of source and drain electrode layers. The impurity concentration in the surface of the oxide semiconductor film is lower than or equal to 5×1018 atoms/cm3, preferably lower than or equal to 1×1018 atoms/cm3.
    Type: Application
    Filed: October 16, 2012
    Publication date: April 25, 2013
    Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
    Inventor: Semiconductor Energy Laboratory Co., Ltd.
  • Patent number: 8394662
    Abstract: A method for forming a thin film photovoltaic device. The method includes providing a transparent substrate comprising a surface region. A first electrode layer is formed overlying the surface region. A copper layer is formed overlying the first electrode layer and an indium layer is formed overlying the copper layer to form a multi-layered structure. The method subjects at least the multi-layered structure to a thermal treatment process in an environment containing a sulfur bearing species to form a copper indium disulfide material. The copper indium disulfide material comprising a copper-to-indium atomic ratio ranging from about 1.2:1 to about 2:1 and a thickness of substantially copper sulfide material. The thickness of the copper sulfide material is removed to expose a surface region having a copper poor surface comprising a copper to indium atomic ratio of less than about 0.95:1.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: March 12, 2013
    Assignee: Stion Corporation
    Inventor: Howard W. H. Lee
  • Publication number: 20120153295
    Abstract: Radiation detector. The detector includes an ionic junction having an ionically bonded wide band gap material having a first region dominated by positively charged ionic defects in intimate contact with a second region dominated by negatively charged ionic defects forming depleted regions on both sides of the junction resulting in a built-in electric field. The detector also includes an ionic junction having a first ionically bonded wide band gap material dominated by positively charged ionic defects in intimate contact with a second ionically bonded wide band gap material dominated by negatively charged ionic defects forming depleted regions on both sides of the junction resulting in a built-in electric field. Circuit means are provided to establish a voltage across the junction so that radiation impinging upon the junction will cause a current to flow in the circuit.
    Type: Application
    Filed: February 25, 2011
    Publication date: June 21, 2012
    Applicant: Massachusetts Institute of Technology
    Inventors: Harry L. Tuller, Sean R. Bishop
  • Publication number: 20120077349
    Abstract: Embodiments related to depositing thin conformal films using plasma-activated conformal film deposition (CFD) processes are described herein. In one example, a method of processing a substrate includes, applying photoresist to the substrate, exposing the photoresist to light via a stepper, patterning the resist with a pattern and transferring the pattern to the substrate, selectively removing photoresist from the substrate, placing the substrate into a process station, and, in the process station, in a first phase, generating radicals off of the substrate and adsorbing the radicals to the substrate to form active species, in a first purge phase, purging the process station, in a second phase, supplying a reactive plasma to the surface, the reactive plasma configured to react with the active species and generate the film, and in a second purge phase, purging the process station.
    Type: Application
    Filed: January 21, 2011
    Publication date: March 29, 2012
    Inventors: Ming Li, Hu Kang, Mandyam Sriram, Adrien LaVoie
  • Publication number: 20110294284
    Abstract: According to the present invention, a method for depositing an ultra-fine crystal particle polysilicon thin film supplies a source gas in a chamber loaded with a substrate to deposit a polysilicon thin film on the substrate, wherein the source gas contains a silicon-based gas, a nitrogen-based gas and a phosphorous-based gas. The mixture ratio of the nitrogen-based gas to the silicon-based gas among the source gas may be 0.03 or lower (but, excluding zero). Nitrogen in the thin film may be 11.3 atomic percent or lower (but, excluding zero).
    Type: Application
    Filed: April 29, 2009
    Publication date: December 1, 2011
    Inventors: Hai Won Kim, Sang Ho Woo, Sung Gil Cho, Song Hwan Park, Kyung Soo Jung
  • Publication number: 20110141100
    Abstract: A thin film transistor (TFT) may include a channel layer, a source electrode, a drain electrode, a protective layer, a gate electrode, and/or a gate insulating layer. The channel layer may include an oxide semiconductor material. The source electrode and the drain electrode may face each other on the channel layer. The protective layer may be under the source electrode and the drain electrode and/or may cover the channel layer. The gate electrode may be configured to apply an electric field to the channel layer. The gate insulating layer may be interposed between the gate electrode and the channel layer.
    Type: Application
    Filed: February 17, 2011
    Publication date: June 16, 2011
    Inventors: Jae-chul Park, Young-soo Park, Sun-Il Kim
  • Publication number: 20100255615
    Abstract: A fin-shaped semiconductor region is formed on a substrate, and then the substrate is placed in a chamber. Then, an ignition gas is introduced into a chamber to thereby turn the ignition gas into a plasma, and then a process gas containing an impurity is introduced into the chamber to thereby turn the process gas into a plasma. Then, a bias voltage is applied to the substrate so as to dope the semiconductor region with the impurity after confirming attenuation of an amount of the ignition gas remaining in the chamber.
    Type: Application
    Filed: October 2, 2008
    Publication date: October 7, 2010
    Inventors: Katsumi Okashita, Yuichiro Sasaki, Keiichi Nakamoto, Bunji Mizuno
  • Patent number: 7754551
    Abstract: This invention proposes a method for making very low threshold voltage (Vt) metal-gate/high-? CMOSFETs using novel self-aligned low-temperature ultra shallow junctions with gate-first process compatible with VLSI. At 1.2 nm equivalent-oxide thickness (EOT), good effective work-function of 5.3 and 4.1 eV, low Vt of +0.05 and 0.03 V, high mobility of 90 and 243 cm2/Vs, and small 85° C. bias-temperature-instability <32 mV (10 MV/cm, 1 hr) are measured for p- and n-MOS.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: July 13, 2010
    Assignee: National Chiao Tung University
    Inventor: Albert Chin
  • Publication number: 20080093658
    Abstract: When nitriding a tunnel oxide film in a nonvolatile memory device a nitrided region is formed in the surface portion of the tunnel oxide film by a plasma processing using a process gas containing nitrogen gas.
    Type: Application
    Filed: December 22, 2005
    Publication date: April 24, 2008
    Applicant: TOKYO ELECTRON LIMITED
    Inventors: Toshihiko Shiozawa, Shingo Furui, Takashi Kobayashi, Junichi Kitagawa
  • Patent number: 7220674
    Abstract: Formation of copper alloy interconnect lines on integrated circuits includes introducing dopant elements into a copper layer. Copper alloy interconnect lines may be formed by providing a doping layer over a copper layer, driving dopant material into the copper layer with a high temperature step, and polishing the copper layer to form individual lines. Copper alloy interconnect lines may be formed by implanting dopants into individual lines. Copper alloy interconnect lines may be formed by providing a doped seed layer with a capping layer to prevent premature oxidation, forming an overlying copper layer, driving in the dopants, and polishing to form individual lines.
    Type: Grant
    Filed: June 1, 2004
    Date of Patent: May 22, 2007
    Assignee: Intel Corporation
    Inventors: Thomas N. Marieb, Paul McGregor, Carolyn Block, Shu Jin
  • Patent number: RE41538
    Abstract: A method for making an integrated circuit device includes forming at least one interconnect structure adjacent a substrate by forming at least one barrier layer, forming a doped copper seed layer on the at least one barrier layer, and forming a copper layer on the doped copper seed layer. The method may further include annealing the integrated circuit device after forming the copper layer to diffuse the dopant from the doped copper seed layer into grain boundaries of the copper layer. The doped copper seed layer may include at least one of calcium, cadmium, zinc, neodymium, tellurium, and ytterbium as a dopant to provide the enhanced electromigration resistance. Forming the copper layer may comprise plating the copper layer. In addition, forming the copper layer may comprise forming the copper layer to include at least one of calcium, cadmium, zinc, neodymium, tellurium, and ytterbium as a dopant.
    Type: Grant
    Filed: April 22, 2005
    Date of Patent: August 17, 2010
    Inventor: James A. Cunningham