Containing Over 50 Per Cent Metal But No Base Metal Patents (Class 420/580)
  • Patent number: 5800639
    Abstract: The present invention discloses a type of novel material compositions for hydrogen storage. The material compositions includes a hydrogen storage Laves-phase alloy which has a material composition represented by A.sub.1-X B.sub.X C.sub.Y where A=(Zr or Hf).sub.1-X1 Ti.sub.X1 and X1 has a value between zero to one, B=La, Ce, Pr, Nd and mixed rare earth, alkaline, or alkaline earth metallic element, C=V.sub.Y1 Ni.sub.Y2, where Y1 has a value between zero to 0.8, Y2 has a value between 1.3 to 3.0, and X has a value between zero to 0.2 and Y has a value between 2.0 to 3.0. In a preferred embodiment, when the value of X is greater than zero, the Laves-phase alloy includes a plurality of B--Ni clusters.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: September 1, 1998
    Assignee: Mobius Green Energy, Inc.
    Inventor: De Yi Yan
  • Patent number: 5728913
    Abstract: A method of treating hydrocarbon fuels with a base metal catalyst is provided for improving the performance of hydrocarbon fuels used internal and external combustion engines The catalyst is a base metal alloy catalyst including tin antimony, lead and mercury. The catalyst operates at ambient temperatures and atmospheric pressure and in the presence of a small but effective quantity of water. The method of treating the fuel with the catalyst may be employed at any point after refining of the fuel and prior to combustion thereof.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: March 17, 1998
    Inventor: Anthony W. Finkl
  • Patent number: 5728279
    Abstract: Target for a magnetron-cathode sputtering apparatus is made from a cobalt base alloy containing additional elements in such concentrations that intermetallic phases are formed with at least one of these elements and intermetallic phases are observed on the basis of the phase diagram in the state of equilibrium at the operating temperature of the target. The grain boundaries, sub-grain boundaries, twin-grain boundaries or slip bands of the cobalt mixed crystal forming the matrix are decorated with the elements forming the intermetallic phases. X-ray diffraction diagrams made from the target display reflections of an intermetallic phase which is largely absent in the cast state and which forms only during a heat treatment in the temperature range below the solidus temperature of the alloy by a solid state reaction.
    Type: Grant
    Filed: December 15, 1994
    Date of Patent: March 17, 1998
    Assignee: Leybold Materials GmbH
    Inventors: Martin Schlott, Martin Weigert, Kwei Teng, Bruce Gehman
  • Patent number: 5690889
    Abstract: A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g. a transition metal and optional boron), and a carbide-forming element (e.g. a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g. Nd.sub.2 Fe.sub.14 B or LaNi.sub.5) and a carbide of the carbide-forming element are formed.
    Type: Grant
    Filed: February 15, 1996
    Date of Patent: November 25, 1997
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: R. William McCallum, Timothy W. Ellis, Kevin W. Dennis, Robert J. Hofer, Daniel J. Branagan
  • Patent number: 5667600
    Abstract: Disclosed is a practical aluminum-based alloy containing 1 to 99 weight percent beryllium and improved methods for the investment casting of net shape aluminum-beryllium alloy parts.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: September 16, 1997
    Assignee: Brush Wellman, Inc.
    Inventors: Fritz C. Grensing, James M. Marder, Jere H. Brophy
  • Patent number: 5662834
    Abstract: An alloy of formula:Ti.sub.30+x Ru.sub.15+y Fe.sub.25+z O.sub.30+t M.sub.uwherein M represent at least one metal selected from the group consisting of chromium, manganese, vanadium, tungsten, antimony, platinum and lead; x is an integer ranging between -30 and +50; y is an integer ranging between -10 and +35; z is an integer ranging between -25 and +70; t is an integer ranging between -28 and +10; and u is an integer ranging between 0 and +50; x, y, z, t and u being selected so that: x+y+z+t+u=0. This alloy, especially when it has a nanocrystalline structure, is useful for the manufacture cathodes for the electro-chemical synthesis of sodium chlorate. These cathodes have an over-potential of hydrogen lower than the one of the soft-steel cathodes presently in use.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: September 2, 1997
    Assignee: Hydro-Quebec
    Inventors: Robert Schulz, Andre Van Neste, Sabin Boily, Shize Jin
  • Patent number: 5625118
    Abstract: A method of treating hydrocarbon fuels with a base metal catalyst is provided for improving the performance of hydrocarbon fuels used in internal and external combustion engines. The catalyst is a base metal alloy catalyst including tin, antimony, lead and mercury. The catalyst operates at ambient temperatures and atmospheric pressure. The method of treating the fuel with the catalyst may be employed at any point after refining of the fuel and prior to combustion thereof.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: April 29, 1997
    Inventor: Anthony W. Finkl
  • Patent number: 5532076
    Abstract: A hydrogen storage alloy preferably used for electrodes in alkaline rechargeable battery is of the general formula: Zr.sub.1.2-a Ti.sub.a Mn.sub.v Al.sub.w Ni.sub.x M.sub.y Cr.sub.z wherein M represents at least one element selected from the group consisting of Si, Zn, Sn, Fe, Mo, Cu and Co; and wherein 0.1.ltoreq.a<1.2, 0.4.ltoreq.v.ltoreq.1.2, 0<w.ltoreq.0.3, 0.8.ltoreq.x.ltoreq.1.6, 0.ltoreq.y.ltoreq.0.2, 0.ltoreq.z.ltoreq.0.3, and 1.7.ltoreq.(v+w+x+y+z).ltoreq.2.7. The alloy has at least one of a C14-type Laves phase of a crystal structure similar to that of MgZn.sub.2 and a C15-type Laves phase of a crystal structure similar to that of MgCu.sub.2 as a main alloy phase.
    Type: Grant
    Filed: March 29, 1994
    Date of Patent: July 2, 1996
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yasuharu Yamamura, Hajime Seri, Yoichiro Tsuji, Naoko Owada, Tsutomu Iwaki
  • Patent number: 5514334
    Abstract: This invention relates to a connection method for a semiconductor material enabling a formation of a bump electrode with a wire bonder, keeping always a cutting position of the wire at a specified position and improving a continuous workability and stability and to a connection material to be used in the connecting method, wherein any one of Pb, Sn, In is applied as a major element and the alloy having additive elements mixed with it is made as a fine wire under a rapid cooling and condensation process and further to a semiconductor device made by the above-mentioned connecting method.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: May 7, 1996
    Assignee: Tanaka Denshi Kogyo Kabushiki Kaisha
    Inventor: Toshinori Ogashiwa
  • Patent number: 5512385
    Abstract: A hydrogen storage alloy for negative electrodes in an alkaline storage battery is disclosed. The alloy is represented by the general formula MmNi.sub.x M.sub.y, wherein Mm is a misch metal or a mixture of rare earth elements, and M is at least one element selected from the group consisting of Al, Mn, Co, Cu, Fe, Cr, Zr, Ti and V and wherein 5.0.gtoreq.x +y.gtoreq.5.5, and has a microstructure comprising a phase composed of a crystal structure of CaCu.sub.5 type and is capable of absorbing and desorbing hydrogen in a reversible manner, and at least one phase consisting mainly of an element or elements other than Mm, and incapable of storing hydrogen.
    Type: Grant
    Filed: February 23, 1995
    Date of Patent: April 30, 1996
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Katsunori Komori, Osamu Yamamoto, Yoshinori Toyoguchi, Kohei Suzuki, Seiji Yamaguchi, Ayako Tanaka, Munehisa Ikoma
  • Patent number: 5503475
    Abstract: In measuring a cooling curve by means of thermal analysis of cast iron, a compressed powder moulding or sintered moulding of tellurium, bismuth, boron, zinc and/or aluminum is fixed to the inner surface of a cooling curve measuring cup, and a melt is poured into said cup when primaly crystalized and eutectic temperatures based on the metastable solidification of iron, cementite and silicon cleary appear. This method allows the carbon equivalent, carbon content and silicon content of the cast iron to be determined and the physical and mechanical properties of the iron to be estimated. Additionally, said compressed metallic powder moulding or sintered moulding is arranged at and fixed to said cooling curve measuring cup used in the method, while enclosing a thermocouple.
    Type: Grant
    Filed: July 5, 1994
    Date of Patent: April 2, 1996
    Assignee: Metec Corporation
    Inventor: Takeshi Yamaguchi
  • Patent number: 5501917
    Abstract: Improved multicomponent alloys for hydrogen storage and rechargeable hydride electrode applications, and in particular for rechargeable hydride battery applications, according to the formula: A.sub.a B.sub.b Ni.sub.c D.sub.y M.sub.x R.sub.z, and the hydride thereof, where A is at least one element selected from the group consisting of Ti, Zr, Hf, Y, V, Nb, Pd, Mg, Be, and Ca; B is at least one element selected from the group consisting of Mg, Al, V, Wb, Ta, Cr, Mn, Si, C, B, and Mo; D is at least one element selected from the group consisting of W, Fe, Co, Cu, Zn, Ag, Sb and Sn; M is at least one element selected from the group consisting of Li, Na, K, Rb, Cs, P, S, Sr, and Ba; R is at least one element selected from the group consisting of Sc, Y, La, Ce, Pr, and Yb; and where a, b, c, x, y and z are defined by: 0.10.ltoreq.a.ltoreq.0.85, 0.02.ltoreq.b.ltoreq.0.85, 0.02.ltoreq.c.ltoreq.0.85, 0.01.ltoreq.x.ltoreq.0.30, 0.ltoreq.y.ltoreq.0.25, 0.ltoreq.z.ltoreq.0.12 and a+b+c+x+y=1.00.
    Type: Grant
    Filed: January 28, 1994
    Date of Patent: March 26, 1996
    Inventor: Kuochih Hong
  • Patent number: 5486225
    Abstract: A process for producing finely divided 20 to 500 angstrom metal particles, metals with oxide coatings or metal oxides using an alkalide or electride in a non-reactive solvent is described. The process produces various forms of the metal depending upon the oxidizability of the metal initially produced by the process. The process is useful for producing catalysts, alloys, colloidal solutions, semi-conductors and the like.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: January 23, 1996
    Assignee: Board of Trustees operating Michigan State University
    Inventors: James L. Dye, Ahmed S. Ellaboudy, Kuo-Lih Tsai
  • Patent number: 5486242
    Abstract: Tantalum-based and niobium-based alloys made up entirely of a crystalline medium exhibiting a substantially continuous centered cubic structure, comprising an intermetallic compound of formula Ti.sub.2 AlMo, and having the following compositions on an atomic basis:______________________________________ Ta + Cr 20 to 35% Cr 0 to 5% Ti 20 to 40% Al 8 to 20% Mo 8 to 20%, ______________________________________wherein the concentration of Ta is less than 30%; and ______________________________________ Nb + Cr 20 to 60% Cr 0 to 5% Ti 20 to 40% Al 8 to 20% Mo 8 to 20%. ______________________________________ .
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: January 23, 1996
    Assignee: Office National d'Etudes et de Recherches Aerospatiales
    Inventors: Shigehisa Naka, Tasadduq Khan, Andre Walder, Michel Marty, Christophe Delaunay, Pierre Thevenin
  • Patent number: 5480495
    Abstract: Disclosed is a magnetic material which suppresses formation of impurity phase of Fe, Co or Fe-Co alloy, possesses a stable ThMn.sub.12 crystal structure as the principal phase, and is excellent in magnetic properties and lower in cost. Such magnetic material is expressed in a general formula:R1.sub.x R2.sub.y Si.sub.z M.sub.u T.sub.vwhere R1is at least one element selected from Zr and Hf, R2is at least one element selected from rare earth element, M is at least one element selected from C, N and P, T is at least one element selected from Fe and Co, x+y+z+u+v=100, x, y, z, u, v are atomic percent individually defined as 0.1.ltoreq.x.ltoreq.20, 2.ltoreq.y.ltoreq.20, 0.5.ltoreq.z.ltoreq.20, 0.ltoreq.u.ltoreq.20, v.gtoreq.50, and of which principal phase possesses a ThMn.sub.12 crystal structure.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: January 2, 1996
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Shinya Sakurada, Takahiro Hirai, Akihiko Tsutai, Masashi Sahashi
  • Patent number: 5476529
    Abstract: A process for recovery of magnesium from magnesium alloy waste by charging an electric furnace with a flux including at least one salt, the flux being inert with respect to magnesium and having a melting point <1000.degree. C. The flux is raised by the Joule effect at a reduced pressure to a temperature of 900.degree. to 1100.degree. C. to produce a bath having a density higher than that of magnesium, a vapor pressure <0.1 torr and an electrical resistivity of between 1 and 10 milliohm.m. The magnesium alloy waste is introduced in the bath, and magnesium and any other elements in the waste which are more volatile than magnesium are recovered from a vapor phase above the bath. Any elements in the waste which are less volatile than magnesium are recovered from a molten phase in a bottom portion of the furnace.
    Type: Grant
    Filed: November 23, 1994
    Date of Patent: December 19, 1995
    Assignee: Pechiney Electrometallurgie
    Inventor: Pierre Faure
  • Patent number: 5462437
    Abstract: A dental alloy is provided which is compatible with a wide variety of composites and porcelain compositions. The alloy has a melting range of between about 870.degree. C. and 1230.degree. C. and a coefficient of thermal expansion of between 15.5.times.10.sup.-6 and 17.5.times.10.sup.-6 in/in/.degree. C. when heated from room temperature to 500.degree. C. The alloy contains between one and 85 percent by weight gold, between two and 65 percent by weight of a thermal expansion adjuster, between 0.25 and 34 percent by weight of a strengthener and oxide former, up to about one percent by weight grain refiner, and up to about 0.25 percent by weight deoxidizer.
    Type: Grant
    Filed: November 10, 1993
    Date of Patent: October 31, 1995
    Assignee: Jeneric/Pentron Incorporated
    Inventors: Arun Prasad, Martin Schulman
  • Patent number: 5447683
    Abstract: Dense monolithic SiC or SiC ceramic composites are strongly bonded using brazing compositions which, in their preferred composition, include a braze alloy consisting essentially of less than 50 weight percent silicon and at least two metals from the group of Fe, Cr, Co and V and produce a joint suitable for use in a high neutron flux environment. Brazing is carried out at a temperature of about 1200.degree. to 1500.degree. C. in an inert atmosphere and is complete in about 15 minutes. Broadly, a genus of brazing compounds are disclosed which include between about 10 and about 45 weight percent silicon and at least two elements selected from the following group: Li, Be, B, Na, Mg, P, Sc, Ti, V, Cr, Mn, Fe, Co, Zn, Ga, Ge, As, Rb, Y, Sb, Te, Cs, Pr, Nd, Ta, W and Tl.
    Type: Grant
    Filed: November 8, 1993
    Date of Patent: September 5, 1995
    Assignee: General Atomics
    Inventors: Frederick C. Montgomery, Holger H. Streckert
  • Patent number: 5441826
    Abstract: Three types of novel hydrogen-absorbing alloy electrodes A, B and C usable for metal hydride secondary batteries are provided. All three types are represented by the general formula AB.sub.x wherein A represents Ti or elements that principally comprise Ti and generate heat upon absorption of hydrogen, B represents Mo and Ni or elements that principally comprise Mo and Ni and absorb heat upon absorption of hydrogen and 0.5.ltoreq.X.ltoreq.2, and are readily producible and difficult to undergo cycle deterioration and need only short activation treatment time. (A) uses a hydrogen-absorbing alloy obtained by quenching and solidifying an alloy melt under an atmosphere of a reducing gas containing hydrogen at a cooling rate of at least 1.times.10.sup.3 .degree. C.
    Type: Grant
    Filed: January 31, 1994
    Date of Patent: August 15, 1995
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Hiroshi Watanabe, Akio Furukawa, Shin Fujitani, Ikuo Yonezu, Takahiro Isono
  • Patent number: 5423680
    Abstract: A dental alloy is provided which is free of palladium, gallium and copper and which is compatible with a wide variety of composites and porcelain compositions. The alloy has a melting range of between about 870.degree. C. and 1230.degree. C. and a coefficient of thermal expansion of between 15.5.times.10.sup.-6 and 17.5.times.10.sup.-6 in/in/.degree. C. when heated from room temperature to 500.degree. C. The alloy contains between about 40 and 80 percent by weight gold, between 5 and 50 percent by weight of thermal expansion adjuster, between two and 15 percent by weight strengthener and oxide former, up to about 1.5 percent by weight grain refiner, and up to about 0.25 percent by weight deoxidizer.
    Type: Grant
    Filed: November 10, 1993
    Date of Patent: June 13, 1995
    Assignee: Jeneric/Pentron, Incorporated
    Inventor: Arun Prasad
  • Patent number: 5393723
    Abstract: The catalyst is provided for improving the performance of hydrocarbon fuels used in internal combustion engines. The catalyst is a based metal alloy catalyst including tin, antimony, lead, mercury and thallium in the following proportions by weight percent:Sb 18-20Pb 4.5-5.5Hg 12-14Tl 0.1-0.5and the balance consisting essentially of Sn. The catalyst operates at ambient temperatures and atmospheric pressure. The catalyst is intended to pretreat fuel before combustion and may be disposed in the fuel tank, fuel line or return fuel line.
    Type: Grant
    Filed: May 11, 1993
    Date of Patent: February 28, 1995
    Inventor: Anthony W. Finkl
  • Patent number: 5384209
    Abstract: The present invention provides a hydridable material for the negative electrode of a nickel-hydride storage cell mainly comprising a Laves phase of the C14 hexagonal type (MgZn.sub.2), characterized by the general formula: ##EQU1## where A represents at least one element from Ti, Y, Ce, Ca, and Mg, and where M is chosen from Cr, V, and Si.
    Type: Grant
    Filed: October 22, 1993
    Date of Patent: January 24, 1995
    Assignee: Saft
    Inventors: Jacques Bouet, Bernard Knosp, Annick Percheron-Guegan, Olivier Canet
  • Patent number: 5384090
    Abstract: This invention relates to a connection method for a semiconductor material enabling a formation of a bump electrode with a wire bonder, keeping always a cutting position of the wire at a specified position and improving a continuous workability and stability and to a connection material to be used in the connecting method, wherein any one of Pb, Sn, In is applied as a major element and the alloy having additive elements mixed with it is made as a fine wire under a rapid cooling and condensation process and further to a semiconductor device made by the above-mentioned connecting method.
    Type: Grant
    Filed: October 30, 1992
    Date of Patent: January 24, 1995
    Assignee: Tanaka Denshi Kogyo Kabushiki Kaisha
    Inventor: Toshinori Ogashiwa
  • Patent number: 5372779
    Abstract: A white gold alloy composition consisting essentially of about 35 to 50 weight percent of gold, about 35 to 63 weight percent of silver, about 0.1 to 7 weight percent of a whitening component of zinc, germanium or both, and palladium in an amount of about 9 weight percent or less. The whitening component and the palladium are present in an amount sufficient to impart a white gold appearance and a liquidus temperature of no greater than about 1950.degree. F. to the alloy, preferably between about 1700.degree. and 1900.degree. F., and more preferably less than about 1850.degree. F. Thus, the preferred amount of palladium is about 2 to 5 weight percent and the preferred amount of the whitening component is about 0.5 to 6 weight percent.
    Type: Grant
    Filed: May 12, 1993
    Date of Patent: December 13, 1994
    Assignee: Handy & Harman
    Inventor: Aldo M. Reti
  • Patent number: 5372661
    Abstract: A molybdneum, rhenium, and tungsten alloy having an improved erosion, ductility, strength and a higher recrystallization temperature. The alloy may be fabricated into equipment which is useful for manufacturing chemicals such as a hydrochlorofluorocarbon.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: December 13, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Vinci M. Felix, Yong J. Park
  • Patent number: 5366565
    Abstract: The alloy is preferably an alloy having a niobium and titanium base according to the expression:Nb-Ti.sub.27-40.5 -Al.sub.4.5-10.5 -Hf.sub.1.5-5.5 Cr.sub.4.5-7.9 V.sub.0-6,wherein the ratio of concentrations of Ti to Nb (Ti/Nb) is greater than or equal (.gtoreq.) to 0.5, andwherein the maximum concentration of the Hf+V+Al+Cr additives is less than or equal (.ltoreq.) to the expression:16.5+(5.times.Ti/Nb),and the minimum concentration of these additives is 10.5.The crystal form of the alloy is specifically body centered cubic crystal form.
    Type: Grant
    Filed: March 3, 1993
    Date of Patent: November 22, 1994
    Assignee: General Electric Company
    Inventor: Melvin R. Jackson
  • Patent number: 5344728
    Abstract: A positive electrode for use in alkaline rechargeable electrochemical cells comprising: a material comprising a compositionally and structurally disordered multiphase nickel hydroxide host matrix which includes at least one modifier chosen from the group consisting of F, Li, Na, K, Mg, Ba, Ln, Se, Nd, Pr, Y, Co, Zn, Al, Cr, Mn, Fe, Cu, Zn, Sc, Sn, Sb, Te, Bi, Ru, and Pb.
    Type: Grant
    Filed: November 12, 1992
    Date of Patent: September 6, 1994
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Stanford R. Ovshinsky, Michael A. Fetcenko, Srinivasan Venkatesan, Arthur Holland
  • Patent number: 5344507
    Abstract: An aluminum-alloy, which is wear-resistant and does not wear greatly the opposed cast iron or steel, and which can be warm worked. The alloyings the following composition and structure. Composition: Al.sub.a Si.sub.b M.sub.c X.sub.d T.sub.e (where M is at least one element selected from the group consisting of Fe, Co and. Ni; X is at least one element selected from the group consisting of Y, Ce, La and Mm (misch metal); Y is at least one element selected from the group consisting of Mn, Cr, V, Ti, Mo, Zr, W, Ta and Hf; a=50-85 atomic %, b=10-49 atomic %, c=0.5-10 atomic %, d=0.5-10 atomic %, e=0-10 atomic %, and a+b+c+d+e=100 atomic %. Structure: super-saturated face-centered cubic crystals and fine Si precipitates.
    Type: Grant
    Filed: March 16, 1992
    Date of Patent: September 6, 1994
    Assignees: Tsuyoshi Masumoto, Yoshida Kogyo KK, Teikoku Piston Ring Co., Ltd.
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Kazuhiko Kita, Hitoshi Yamaguchi
  • Patent number: 5304346
    Abstract: The invention provides a welding material for welding iron containing low CTE alloys. The filler metal contains 25-55% nickel, 0-30% cobalt, 0.05-0.5% carbon, 0.25-5% niobium and balance iron with incidental impurities. The welding material also is operable with fluxes for submerged arc welding. In addition, the welding material may be configured to function as a flux coated or flux-cored electrode.
    Type: Grant
    Filed: October 23, 1992
    Date of Patent: April 19, 1994
    Assignee: INCO Alloys International, Inc.
    Inventors: David B. O'Donnell, Robert A. Bishel
  • Patent number: 5290509
    Abstract: A hydrogen-absorbing alloy electrode for an alkaline storage cell, the electrode including a hydrogen-absorbing alloy expressed by a composition formula ReBxMy, wherein Re is at least one element selected from a group consisting of rare earth elements and alkali earth elements, B is boron, and M is at least one element selected from a group consisting of Ni, Co, Mn, Al, Cr, Fe, Cu. Sn, Sb, Mo, V, Nb, Ta, Zn, Zr and Ti. The alloy consists essentially of an RM.sub.y main metal phase, and a subordinate boron-containing phase, such as a compound phase of boron and a IV-a, V-a, or VI-a group metal.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: March 1, 1994
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Nobuhiro Furukawa, Kazuro Moriwaki, Mitsuzo Nogami, Seiji Kameoka, Motoo Tadokoro
  • Patent number: 5286314
    Abstract: A low melting (liquidus temperature <570.degree. C.) rapidly solidified brazing alloy consists essentially of about 14 to 52 weight percent germanium, 0 to 10 weight percent of at least one element selected from the group consisting of silicon, magnesium, bismuth, strontium, lithium, copper, calcium, zinc and tin, the balance being aluminum and incidental impurities. The alloy has the form of a foil and can be used to braze non-heat-treatable rapidly solidified Al-Fe-Si-V alloy foil, sheet plate and tubing to components such as deicing duct, overduct, radiator, heat exchanger, evaporator, honeycomb panel for elevated temperature applications.
    Type: Grant
    Filed: July 23, 1992
    Date of Patent: February 15, 1994
    Assignee: AlliedSignal Inc.
    Inventors: Santosh K. Das, Chin-Fong Chang
  • Patent number: 5284619
    Abstract: A mixture of rare earth elements, in which La is comprised from 75 to 90 wt % of rare earth elements, with the balance being Ce, Nd, Pr and other rare earth elements (the mixture being referred to as a highly lanthanum-rich misch metal, and is hereinafter designated Lm), is used to produce a hydrogen absorbing alloy having a composition represented by LmNi.sub.x-A-B Co.sub.A Al.sub.B, Lm.sub.1-x Zr.sub.x Ni.sub.Y-A-B Co.sub.A Al.sub.B, or Lm.sub.1-x Zr.sub.x Ni.sub.Y-A-B-C Co.sub.A Mn.sub.B Al.sub.C. By using these hydrogen absorbing alloys as negative electrode materials, nickel metal hydride secondary batteries can be fabricated that have a large discharge capacity and that also have excellent cycle life and high rate discharge characteristics. Such electrode characteristics that are balanced between the aspects of discharge capacity and cycle life have heretofore been unattainable by either La alone or a misch metal having a relatively low La content or a conventional lanthanum-rich misch metal.
    Type: Grant
    Filed: March 21, 1991
    Date of Patent: February 8, 1994
    Assignee: Japan Storage Battery Company, Limited
    Inventor: Tokuichi Hazama
  • Patent number: 5273831
    Abstract: Composite structures having a higher density, stronger reinforcing niobium based alloy embedded within a lower density, lower strength niobium based cladding alloy are provided. The cladding is preferably an alloy having a niobium and titanium base according to the expression:Nb.sub.balance -Ti.sub.27-40.5 -Al.sub.4.5-10.5 -Hf.sub.1.5-5.5 V.sub.0-6 Cr.sub.4.5-8.5 Zr.sub.0-1 C.sub.0-0.5,where each metal of the metal/metal composite has a body centered cubic crystal structure, andwherein the ratio of concentrations of Ti to Nb (Ti/Nb) is greater than or equal (.gtoreq.) to 0.5, andwherein the maximum concentration of the Hf+V+Al+Cr additives is less than or equal (.ltoreq.) to the expression:16.5+5.times.Ti/Nb.The reinforcement may be in the form of plates, sheets or rods of the higher strength, higher temperature niobium based reinforcing alloy. The same crystal form is present in both the matrix and the reinforcement and is specifically body centered cubic crystal form.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: December 28, 1993
    Assignee: General Electric Company
    Inventors: Melvin R. Jackson, Mark G. Benz, John R. Hughes
  • Patent number: 5242656
    Abstract: This invention relates to an active material of hydrogen storage alloy electrode. The composition of the active material has a formula: Mm Ni.sub.5-x-y-z-u A.sub.x B.sub.y C.sub.z D.sub.u ; wherein Mm is mischmetal; A=Mn, Sn, or V; B=Cr, Co, Ti, Nb, Zr, or Si; C=Al, Mg, or Ca; D=Li, Na, or K; 0.ltoreq..times..ltoreq.0.95; 0.ltoreq. y.ltoreq. 1; 0.ltoreq. z.ltoreq. 0.7; and 0.1.ltoreq. u.ltoreq. 0.9. Alternatively, the composition may be of the formula: Ti.sub.2 Ni.sub.1-u Du; wherein D=Li, Na, or K; and 0.04.ltoreq. u.ltoreq. 0.9. This active material can relieve the alkali metal ions M.sup.+ continuously in charge-discharge process of the alkali batteries, increase the concentration of MOH within the battery, take effect in protecting the cathode and the anode validly, and improve the cycle life and the discharge capacity of the battery.
    Type: Grant
    Filed: April 2, 1992
    Date of Patent: September 7, 1993
    Inventors: Yunshi Zhang, Deying Song, Youxiao Chen, Jun Chen, Genshi Wang, Huatang Yuan, Zuoxiang Zhou, Xuejun Cao, Taoshi Zang, Daxin Zhang
  • Patent number: 5240172
    Abstract: White solder alloys for dental and jewelry parts, with working temperatures around 1000.degree. C., contain 38 to 70% by weight gold, 6 to 20% by weight palladium, 8 to 40% by weight silver, 1 to 6% by weight iron and/or cobalt, 0 to 10% by weight copper, 0-5% each by weight indium, zinc and tin, 0 to 4% each by weight gallium and germanium, ruthenium and/or rhenium. The sum of the contents of tin, zinc, indium, gallium and germanium can be between 1 and 5% by weight.
    Type: Grant
    Filed: July 6, 1992
    Date of Patent: August 31, 1993
    Assignee: Degussa Aktiengesellschaft
    Inventors: Rudi Steinke, Stefan Schittny, Bernd Kempf, Werner Groll
  • Patent number: 5234774
    Abstract: There is provided a non-single crystalline material characterized by containing Ir, Ta and Al at the following respective composition rates:______________________________________ 28 atom percent .ltoreq. Ir .ltoreq. 90 atom percent, 5 atom percent .ltoreq. Ta .ltoreq. 65 atom percent, and 1 atom percent .ltoreq. Al .ltoreq. 45 atom percent. ______________________________________There is also provided a member comprising a substrate and a film composed of said non-single crystalline material being disposed on said substrate.
    Type: Grant
    Filed: October 25, 1990
    Date of Patent: August 10, 1993
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kenji Hasegawa, Atsushi Shiozaki, Isao Kimura, Kouichi Touma
  • Patent number: 5192377
    Abstract: In a process of producing strip or wire, which consists of a monotectic aluminum-silicon alloy comprising a matrix consisting of aluminum and an aluminum-silicon eutectic system and as a minority phase 1 to 50% by weight lead or bismuth included in said matrix, which strip or wire has been continuously cast at a high casting velocity and a high cooling rate from a molten material which has been heated to a temperature above the segregation temperature, and which strip or wire has been subjected to plastic deformation and to a heat treatment, the minority phase which is embedded in the form of elongate platelets in the strip or wire is transformed to more compact shapes by a heat treatment at temperatures of 550.degree. to 600.degree. C.
    Type: Grant
    Filed: April 22, 1991
    Date of Patent: March 9, 1993
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Bruno Prinz, Alberto Romero, Ingrid Muller
  • Patent number: 5180446
    Abstract: Improvement of Nb-alloys, which are known as heat-resistant alloys, by giving anti-oxidation property thereto and increasing the high temperature strength thereof. In addition to a determined amount of Al, one of (1) suitable amounts of Ti, Cr and V, and (2) suitable amounts of Cr and Co, are added to Nb-matrix, and a high melting temperature metal oxide such as Y.sub.2 O.sub.3 or Al.sub.2 O.sub.3 is dispersed in the matrix. Preferable method of preparing the alloys is combination of mechanical alloying and subsequent hot processing.
    Type: Grant
    Filed: January 27, 1992
    Date of Patent: January 19, 1993
    Assignee: Daido Tokushuko Kabushiki Kaisha
    Inventors: Kenji Tsukuta, Tomohito Iikubo
  • Patent number: 5156806
    Abstract: Ternary metallic alloys of the formula Li.sub.x B.sub.y Mg.sub.z wherein 5.ltoreq.x.ltoreq.0.90, 0.05.ltoreq.y.ltoreq.0.90, 0.05.ltoreq.z.ltoreq.0.90, and x+y+z=1 and a method of preparing them. These alloys find use in areas where superlight weight, high specific strength (strength/weight ratio) and oxidation resistance are required.
    Type: Grant
    Filed: May 5, 1975
    Date of Patent: October 20, 1992
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Raymond A. Sutula, Frederick E. Wang
  • Patent number: 5120498
    Abstract: Heavy metal solders having exceptional ability to wet non-metals, especially glass, are produced by the incorporation of small amounts of the light reactive metals lithium, sodium, potassium, rubidium, cesium, calcium, or magnesium into the heavy metal solder compositions. These heavy metal solder compositions consist essentially of alloys contained within the heavy metal system Pb-Sn-In-Bi-Cd-Sb-Hg-Ga-Ag-Au or within subsystems thereof wherein each heavy metal element present in the system or subsystem can potentially constitute nearly the whole of the total depending upon the specific composition chosen. In cases where a low melting point is desired the resultant solder will in general have the formula:A.sub.a B.sub.bwherein A is at least three metals selected from the group consisting ofPb, Sn, In, Bi, Cd, Sb, Hg, Ga, Ag, and Au;and B is at least one metal selected from the group consisting ofLi, Na, K, Rb, Cs, and Ca, and Mg; andwhereinb ranges from about 0.0001 to about 0.1; anda ranges from about 0.
    Type: Grant
    Filed: May 15, 1991
    Date of Patent: June 9, 1992
    Assignee: C-Innovations, Inc.
    Inventor: Josiah C. Cocks
  • Patent number: 5114504
    Abstract: A high temperature titanium-based shaped memory alloy contains from at least 0.1 at. % hafnium. Articles formed from the disclosed alloy have high transformation temperatures. The alloy of the invention can be successfully hot and cold worked to make articles such as springs and wires.
    Type: Grant
    Filed: November 5, 1990
    Date of Patent: May 19, 1992
    Assignee: Johnson Service Company
    Inventors: David N. AbuJudom, II, Paul E. Thoma, Ming-Yuan Kao, David R. Angst
  • Patent number: 5114503
    Abstract: A magnetic core comprised of an amorphous alloy ribbon wound into a toroidal shape, wherein the said amorphous alloy has a composition of the formula:(Co.sub.1-x-y-z Fe.sub.x Ni.sub.y Mn.sub.z).sub.100-a-b-c M.sub.a Si.sub.b B.sub.cwherein M is at least one element selected from the group consisting of Nb, Cr and Mo, and x, y, z, a, b and c are numbers which satisfy relations of 0<a.ltoreq.6, 13.ltoreq.b.ltoreq.16, 7.ltoreq.b.ltoreq.10, 0<x.ltoreq.0.1, 0.ltoreq.y.ltoreq.0.2 and 0.ltoreq.x.ltoreq.0.13 respectively, said amorphous alloy after heat treatment having a rectangular ratio Br/Bs of at least 80%, a Bs value in a range of 5 KG to 8 KG and a stress relief ratio of at least 75%.
    Type: Grant
    Filed: March 24, 1987
    Date of Patent: May 19, 1992
    Assignee: Hitachi Metals, Inc.
    Inventors: Yoshihito Yoshizawa, Kiyotaka Yamauchi
  • Patent number: 5098656
    Abstract: A unique class of bonding alloys and methods for their use are provided which enable the user to electrically join superconductive materials to themselves, to normal conductive materials, or to semi-conductors. The bonding alloys have enhanced wetting properties and a melting point less than 100.degree. C. in all instances. The bonding alloys are unusual and advantageous in that they create an intimate, direct, mechanical and electrical contact between the superconductive material and any other electrical conductor while minimizing mechanical and chemical stresses and avoiding alterations to the superconductive material itself.
    Type: Grant
    Filed: August 1, 1990
    Date of Patent: March 24, 1992
    Assignee: Trustees of Boston University
    Inventors: George O. Zimmerman, Alvaro Kaplan
  • Patent number: 5098655
    Abstract: The electrical contact alloy is provided comprising Sb and either Au or Ag or both. In such alloys, Sb produces a non-catalytic effect to inhibit formation of carbon from organic gases derived from resin parts. Therefore, when electrical contacts of such alloys are assembled with resin parts into housings, poor contact due to carbon deposition is prevented to increase the useful life and reliability of the electrical contacts.
    Type: Grant
    Filed: May 26, 1989
    Date of Patent: March 24, 1992
    Assignee: Omron Tateisi Electronics Co.
    Inventor: Masatoshi Ohba
  • Patent number: 5096667
    Abstract: Disclosed is a reversible, electrochemical cell having a high electrochemical activity, hydrogen storage negative electrode. The negative electrode is formed of a reversible, multicomponent, multiphase, electrochemical hydrogen storage alloy. The hydrogen storage alloy is capable of electrochemically charging and discharging hydrogen in alkaline aqueous media. In one preferred exemplification the hydrogen storage alloy is a member of the family of hydrogen storage alloys, derived from the V-Ti-Zr-Ni and V-Ti-Zr-Ni-Cr alloys in which the V, Ti, Zr, Ni and Cr are partially replaced by one or more modifiers, and the alloy has the composition:(V.sub.y'-y Ni.sub.y Ti.sub.x'-x Zr.sub.x Cr.sub.z).sub.a M'.sub.b M".sub.c M.sub.d.sup.ivwhere x' is between 1.8 and 2.2, x is between 0 and 1.5, y' is between 3.6 and 4.4, y is between 0.6 and 3.5, z is between 0.00 and 1.44, a designates that the V-Ni-Ti-Zr-Cr component as a group is from 70 to 100 atomic percent of the alloy, b,c,d,e, . . .
    Type: Grant
    Filed: November 24, 1989
    Date of Patent: March 17, 1992
    Assignee: Energy Conversion Devices, Inc.
    Inventor: Michael A. Fetcenko
  • Patent number: 5089225
    Abstract: A TiAl composition is prepared by ingot metallurgy to have higher strength and to have moderately reduced or improved ductility by altering the atomic ratio of the titanium and niobium to have what has been found to be a highly desirable effective aluminum concentration and by addition of niobium according to the approximate formula Ti.sub.48-37 Al.sub.46-49 Nb.sub.6-14.
    Type: Grant
    Filed: May 2, 1991
    Date of Patent: February 18, 1992
    Assignee: General Electric Company
    Inventor: Shyh-Chin Huang
  • Patent number: 5084301
    Abstract: Disclosed is an alloying process which comprises, in the order stated (1) heating in a reaction vessel a mixture of selenium and tellurium from ambient temperature to form about 270.degree. C. to about 330.degree. C. while maintaining the mixture in a quiescent state; (2) maintaining the mixture at from about 270.degree. C. to about 330.degree. C. until the entire mixture has reached substantial equilibrium with respect to temperature while maintaining the mixture in a quiescent state; (3) subsequently heating the mixture from the range of from about 270.degree. C. to about 330.degree. C. to the range of from about 500.degree. C. to about 580.degree. C. while maintaining the mixture in a quiescent state; (4) maintaining the mixture at from about 500.degree. C. to about 580.degree. C. until the entire mixture has reached substantial equilibrium with respect to temperature while maintaining the mixture in a quiescent state; (5) thereafter maintaining the mixture at from about 500.degree. C. to about 580.degree.
    Type: Grant
    Filed: September 4, 1990
    Date of Patent: January 28, 1992
    Assignee: Xerox Corporation
    Inventors: Monroe J. Hordon, Lawrence E. Kowalczyk
  • Patent number: 5080862
    Abstract: An alloy having a very high resistance to oxidation is taught. The alloy contains between 30 and 75 atom percent of silicon in an iridium base. The alloy may be used in the form of a surface coating to protect structural elements of other materials from oxidation. The alloy may also be used as an ingredient of a composite.
    Type: Grant
    Filed: April 25, 1990
    Date of Patent: January 14, 1992
    Assignee: General Electric Company
    Inventor: Krishan L. Luthra
  • Patent number: 5076865
    Abstract: An amorphous aluminum-valve metal alloy with special characteristics such as high corrosion resistance, high wear resistance and coinsiderable toughness, consisting of Al and at least one element selected from valve metals of Ti and Zr, a portion of the set forth refractory metals being allowed to be substituted with at least one element selected from Mo, W, Ta and Nb.
    Type: Grant
    Filed: October 13, 1989
    Date of Patent: December 31, 1991
    Assignees: Yoshida Kogyo K. K., Koji Hashimoto
    Inventors: Koji Hashimoto, Hideaki Yoshioka, Katsuhiko Asami, Asahi Kawashima
  • Patent number: RE34588
    Abstract: Four groups of advanced hydrogen hydride storage and hydride electrode materials, consisting of two common elements, titanium and nickel. In the first group of materials, zirconium and chromium are added with the common elements. The second group of materials contain three additional elements in addition to the common elements, namely, chromium, zirconium and vanadium. The third group of materials contain also, in addition to the common elements, zirconium and vanadium. The fourth group of materials adds manganese and vanadium with the common elements. The preparation methods of the materials, as well as their hydride electrode are disclosed. Electrochemical studies indicate that these materials have high capacity, long cycle life and high rate capability.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: April 19, 1994
    Inventor: Kuochih Hong