Chromium Containing Patents (Class 420/583)
  • Patent number: 6485678
    Abstract: A unique iron base alloy for wear resistant applications, characterized in one aspect by its hardening ability when exposed to a certain temperature range, is useful for valve seat insert applications. The alloy also possesses excellent wear resistance, hot hardness and oxidation resistance. The alloy comprises less than 0.1 wt % carbon; about 18 to about 32 wt % molybdenum, about 6 to about 15 wt % chromium, about 1.5 to about 3% silicon, about 8 to about 15 wt % cobalt and at least 40% iron, with less than 0.5 wt % nickel. In another aspect, for lower temperature applications, the cobalt is optional, the nickel content can be up to 14 wt %, but the molybdenum must be in the range of about 29% to about 36%. In one further aspect, for higher temperature applications, the cobalt is optional, but may be used up to 15 wt %, nickel must be used at a level of between about 3 and about 14 wt %, and the molybdenum will be in the range of about 26 to about 36 wt %.
    Type: Grant
    Filed: June 20, 2000
    Date of Patent: November 26, 2002
    Assignee: Winsert Technologies, Inc.
    Inventors: Xuecheng Liang, Gary R. Strong
  • Publication number: 20020141897
    Abstract: In a process for producing a workpiece from a chromium alloy, consisting of: 1 32-37 % by weight chromium, 28-36 % by weight nickel, max. 2 % by weight manganese, max. 0.5 % by weight silicon, max. 0.1 % by weight aluminum, max. 0.03 % by weight carbon, max. 0.025 % by weight phosphorus, max. 0.01 % by weight sulfur, max. 2 % by weight molybdenum, max. 1 % by weight copper, 0.3-0.
    Type: Application
    Filed: March 21, 2002
    Publication date: October 3, 2002
    Inventors: Peter Ernst, Peter Uggowitzer, Hannes Speidel, Markus Speidel
  • Patent number: 6454879
    Abstract: An austenitic, paramagnetic and corrosion-resistant material, particularly in media with high chloride concentrations, the material having high strength, yield strength, and ductility, including carbon, silicon, chromium, manganese, nitrogen, and optionally, nickel, molybdenum, copper, boron, and carbide-forming elements. The material is preferably substantially completely austenitic. A process utilizing alloying technology that includes a deformation and synergistically results in production of a ferrite-free material that is reliably paramagnetic, is corrosion-resistant, and has high yield strength, strength, and ductility. The material can be very beneficially used, for example, in connection with oil field technology, such as for bore rods and drilling string components as well as for precision-forged components, and for high strength attachment and connection elements.
    Type: Grant
    Filed: July 14, 2000
    Date of Patent: September 24, 2002
    Assignees: Schoeller-Bleckman Oilfield Technology GmbH & Co. KG, Bohler Edelstahl GmbH & Co. KG
    Inventors: Herbert Aigner, Günter Hochörtler, Josef Bernauer
  • Patent number: 6355212
    Abstract: The invention is directed to anti-corrosive alloys and relates in particular to an alloy containing cobalt, chromium, aluminum, yttrium, silicon, a metal from the second main group, together with the corresponding oxide, in the following proportions: chromium (Cr) 26.0-30%; aluminum (Al) 5.5-13.0%; yttrium (Y) 0.3-1.5%; silicon (Si) 1.5-4.5%; metal from the second main group (magnesium, calcium, barium, strontium) 0.1-2.0%; oxide of the corresponding metal from the second main group 0.1-2.0%; cobalt (Co) remaining percentage. Preferably, tantalum (Ta) is also added in a proportion of 0.5-4.0%, and the remaining percentage of cobalt is replaced by a remaining percentage of Me, Me being understood to mean a metal which may be nickel (Ni) or iron (Fe) or cobalt (Co) or a composition comprising Ni—Fe—Co, Ni—Fe, Ni—Co, Co—Fe.
    Type: Grant
    Filed: January 5, 2000
    Date of Patent: March 12, 2002
    Assignee: Turbocoating SpA
    Inventor: Nelso Antolotti
  • Patent number: 6190465
    Abstract: Soft magnetic alloy of the iron-nickel type, the chemical composition of which comprises, by weight: 40%≦Ni+Co≦65%; 0%≦Co≦7%; 2%≦Cr≦5%; 1%≦Ti≦3%; 0%≦Al≦0.5%; 0%≦Mn+Si≦2%; optionally, up to 3% Mo, 2% W, 2% V, 1.5% Nb, 1% Ta and 3% Cu, the sum of the Cr, Mo, W, V, Nb, Ta and Cu contents being less than 7% and the sum of the Mo, W, V, Nb, Ta and Cu contents being less than 4%; the balance being iron and impurities, such as carbon, sulfur and phosphorus, resulting from the smelting process, the chemical composition furthermore satisfying the relationships: Cr<5−0.015×(Ni+Co−52.5)2, if: Ni+Co≦52.5; Cr<5−0.040×(Ni+Co−52.5)2, if: Ni+Co≧52.5; the alloy having a saturation induction Bs of greater than 0.9 tesla, a coercive field of less than 10 A/m, an electrical resistivity p of greater than 60 &mgr;&OHgr;.cm and a hardness of greater than 200 HV. Process for manufacturing the alloy and uses.
    Type: Grant
    Filed: July 2, 1998
    Date of Patent: February 20, 2001
    Assignee: Imphy Ugine Precision
    Inventors: Lucien Coutu, Laurent Chaput, Thierry Waeckerle
  • Patent number: 6168757
    Abstract: An article of equipment intended to be submerged in molten zinc, molten aluminum and mixtures thereof, said article containing an alloy material comprised of: Percent Carbon 1.6-2.6 Chromium 15.0-30.0 Tungsten 10.0-30.0 Molybdenum 2.0-8.0 Iron 10.0-50.0 and including, vanadium, niobium, cobalt, boron, and manganese and being substantially free of silicon.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: January 2, 2001
    Assignee: Alphatech, Inc.
    Inventor: Jorge A. Morando
  • Patent number: 6123898
    Abstract: It is an objective of the present invention to provide low thermal expansion alloys having excellent high temperature mechanical properties, the oxidation resistance, and the electrical conductivity by modifying the basic Cr--W--Fe alloy in order to meet various industrial demands including prolonging the life of plant machinery being operated at high temperature and a scaling-up solid oxide fuel cell, so that the coefficient of thermal expansion can be approximated to those of stabilized zirconia. In order to achieve these objectives, Co is added to Cr--W--Fe system alloy possessing an excellent thermal matching characteristic to stabilized zirconia in order to enhance the high temperature mechanical properties without changing original properties of thermal matching, the oxidation resistance and the electrical conductivity. Cr and Al are added in order to further improve the oxidation resistance and to approximate the coefficient of surface thermal expansion to that of stabilized zirconia.
    Type: Grant
    Filed: May 25, 1999
    Date of Patent: September 26, 2000
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Hitoshi Taimatsu, Masami Ueda
  • Patent number: 6057045
    Abstract: A powder-metallurgy produced high-speed steel article having a combination of high hardness and wear resistance, particularly at elevated temperatures. This combination of properties is achieved by the combination of W, Mo, V, and Co. The article is particularly suitable for use in the manufacture of gear cutting tools, such as hobs, and surface coatings.
    Type: Grant
    Filed: October 14, 1997
    Date of Patent: May 2, 2000
    Assignee: Crucible Materials Corporation
    Inventors: Andrzej L. Wojcieszynski, William Stasko
  • Patent number: 6004507
    Abstract: An article suitable for submergence in molten zinc, aluminum and aluminum/zinc melts. The article is formed of an alloy comprising from greater than 1.0% to less than 5.0% carbon; from greater to 10.0% to less than 30.0% chromium; from greater than or equal to 0.0% nickel to less than 30.0% nickel; from greater than 1.0% to less than 15.0% tungsten; from greater than 1.0% to less than 10.0% molybdenum; from greater than 0.0% to less than 10.0% vanadium; from greater than 0.0% to less than 10.0% niobium; from greater than 0.0% to less than 20.0% percent cobalt; from greater than 0.0% to less than 5.0% boron; from greater than 10.0% to less than 50.0% iron; from greater than or equal to 0.0% to less than or equal to 6.0% zirconium; from greater than 2 to less than 6.5% manganese; and from greater than or equal to 0.0% to less than 1.0% silicon.
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: December 21, 1999
    Assignee: Alphatech, Inc.
    Inventor: Jorge A. Morando
  • Patent number: 5888317
    Abstract: The present invention relates to a material for hydrogen-storage constituted by Ti-Mn alloy system which has a high hydrogen-storage capacity, plateau hydrogen dissociation equilibrium pressure, hypostoichiometric composition and crystal structure of C14. Ti-Mn alloy system for hydrogen-storage of the invention which has a C14 crystal structure, is represented as: Ti.sub.u Zr.sub.v Mn.sub.w Cr.sub.x V.sub.y X.sub.z, wherein, X is at least one of element selected from the group consisting of Fe, Al and Ni; u, v, w, x, y and z are mole numbers of each components; 0.7<u<1.0; 0<v<0.3; 1.0.ltoreq.w.ltoreq.1.3; 0.1.ltoreq.x.ltoreq.0.4; 0<y<0.3; 0.ltoreq.z.ltoreq.0.2; 0.7<u+v<1.0; 1.4.ltoreq.w+x.ltoreq.1.7; and, 1.3.ltoreq.w+x+y+z<2.0.
    Type: Grant
    Filed: April 30, 1996
    Date of Patent: March 30, 1999
    Assignee: Korea Advanced Institute of Science and Technology
    Inventors: Jai-Young Lee, Ki-Young Lee, Han-Ho Lee, Dong-Myung Kim, Ji-Sang Yu, Jae-Han Jung, Soo-Geun Lee
  • Patent number: 5851690
    Abstract: A hydrogen absorbing alloy for use in an environment where the alloy has the possibility of contacting oxygen is capable of inhibiting impairment of the hydrogen absorbing ability thereof when coming into contact with oxygen. The alloy has a composition represented in atomic ratio by Ti.sub.1-x Y.sub.x Mn.sub.y wherein x and y are in the range of 0<x.ltoreq.0.2 and 1.5.ltoreq.y.ltoreq.2.0, respectively, and comprises a C14-type crystal structure of Laves phase, the Laves phase having a segregaton phase of high Y concentration. Ti can be replaced by Hf and/or Zr within the range of over 0 to not greater than (1-x)/2 included in 1-x for the Ti atom. Mn can be replaced by V or Fe within the range of over 0 to not greater than y/2 included in y for the Mn atom.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: December 22, 1998
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Yumiko Nakamura, Hiroshi Nakamura, Maki Kamikawa, Hiroshi Watanabe, Shin Fujitani, Ikuo Yonezu
  • Patent number: 5833919
    Abstract: The present invention provides a Fe--Mn--Cr--Al cryogenic alloy having high ductility, strength, toughness and corrosion-resistance, and a process for preparing the same. The cryogenic structural alloy of the invention is prepared by the steps of: air-induced melting of a metallic alloy composition which consists of Fe 48.6 to 64.7 wt %, Mn 25.0 to 35.0 wt %, Cr 10.0 to 13.0 wt %, Al 0.1 to 2.0 wt %, C 0.1 to 0.4 wt % and Si 0.1 to 1.0 wt %; hot-rolling of the melted alloy at 1,090.degree. to 1,110 .degree. C.; and, solution heat treatment of the hot-rolled alloy at 1,040.degree. to 1,060.degree. C. for 50 to 70 minutes.
    Type: Grant
    Filed: January 9, 1997
    Date of Patent: November 10, 1998
    Assignee: Korea Advanced Institute of Science and Technology
    Inventors: Soon-Hyung Hong, Young-Soo Han
  • Patent number: 5800152
    Abstract: Metallic materials which possess suitable characteristics for serving as an intermediate layer between a thermal barrier coating and a matrix substrate, or as a separator for a solid oxide fuel cell, contain 15 to 40 wt % Cr, 5 to 15 wt % W, 0.01 to 1 wt % M (where M is one or more than two elements chosen from Y, Hf, Ce, La, Nd, and Dy), 0.001 to 0.01 wt % B and a balance of Fe. The average value of the coefficient of thermal expansion of the metallic material is in a range from more than 12.0.times.10.sup.-6 /K to less than 13.0.times.10.sup.-6 /K in a temperature range from room temperature to 1,000.degree. C., and the value is close to that of stabilized zirconia. The metallic materials display excellent high temperature oxidation resistance.
    Type: Grant
    Filed: February 14, 1997
    Date of Patent: September 1, 1998
    Assignee: Sumitomo Special Metals Company, Limited
    Inventors: Hitoshi Taimatu, Masami Ueda
  • Patent number: 5709836
    Abstract: A chromium steel sheet having excellent press formability, particularly deep-drawing formability and resistance to secondary work brittleness. The construction is a chromium steel sheet including C: not more than 0.03 wt %, Si: not more than 1.0 wt %, Mn: not more than 1.0 wt %, P: not more than 0.05 wt %, S: not more than 0.015 wt %, Al: not more than 0.10 wt %, N: not more than 0.02 wt %, Cr: 5-60 wt %, Ti: 4(C+N)-0.5 wt %, Nb: 0.003-0.020 wt %, B: 0.0002-0.005 wt %, and, if necessary, one or more selected from Mo: 0.01-5.0 wt %, Ca: 0.0005-0.01 wt % and Se: 0.0005-0.025 wt %, and the balance being Fe and inevitable impurities.
    Type: Grant
    Filed: February 28, 1996
    Date of Patent: January 20, 1998
    Assignee: Kawasaki Steel Corporation
    Inventors: Mitsuyuki Fujisawa, Yasushi Kato, Takumi Ujiro, Susumu Satoh, Koji Yamato
  • Patent number: 5662864
    Abstract: It is directed to provide an Fe--Cr alloy exhibiting an excellent ridging resistance and surface characteristic, comprising:0.01% (percent by weight; the same as below) or less of C;1.0% or less of Si;1.0% or less of Mn;0.01 or less of S;9% or more to 50% or less of Cr;0.07% or less of A1;0.02% or less of N;0.01% or less of O; andthe balance being Fe and inevitable impurities;wherein the C and N contents satisfy the following equations:N(%)/C(%).gtoreq.2,and0.006.ltoreq.[C(%)+N(%)].ltoreq.0.025;andthe Ti content satisfy the following equations:{Ti(%)-2.times.S(%)-3.times.O(%)}/[C(%)+N(%)].ltoreq.4,and[Ti(%)].times.[N(%)].ltoreq.30.times.10.sup.-4.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: September 2, 1997
    Assignee: Kawasaki Steel Corporation
    Inventors: Yasushi Kato, Takumi Ujiro, Susumu Sato, Koji Yamato
  • Patent number: 5643531
    Abstract: Disclosed is a manufacture and coating method of mechanical products using ferrous alloy in order to improve wear, corrosion, and heat resistances of the mechanical products which are exposed to friction and wear environments with or without lubricating conditions. The mechanical products of the invention include rotation contact parts such as bush and shaft in the inside of caterpillar roller, mechanical seal under high surface pressure, and drawing dice and plug under sliding friction stress. A ferrous alloy composition used for coating in the invention comprises Cr:18.0-42.0 wt %, Mn: 1.0-3.2 wt %, B:3.0-4.5 wt %, Si: 1.0-3.0 wt %, C: less than 0.3 wt %, inevitably incorporated impurities, and Fe for the rest of content. A ferrous alloy composition used for manufacturing bush type product comprises C: less than 4.5%, Si:2.5%, Mn:less than 2%, Cr:0.5-35%, and Fe for the rest of content.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: July 1, 1997
    Assignee: Samsung Heavy Industry Co., Ltd.
    Inventors: Kang-Hyung Kim, Maeng-Roh Park, Seung-Ho Yang, Yong-Kwon Chi
  • Patent number: 5501834
    Abstract: A Ni free ferrous nonmagnetic alloy having excellent corrosion resistance and workability and high cost performance is described.The alloy comprises, by weight, 9 to 25% Cr, 3 to 35% Mn, 3 to 40% Co and the balance Fe and incidental impurities, and sum of Mn and 0.6Co is in accordance with a general relationship as indicated by formula 1/ , and preferably a restricted relationship as indicated by formula 2/ .19%.ltoreq.Mn+0.6 Co.ltoreq.40% 1/22%.ltoreq.Mn+0.6 Co.ltoreq.36% 2/One type of alloy of this invention further containing 0.02 to 2% Ag has excellent machinability as well as corrosion resistance, workability and nonmagnetism.
    Type: Grant
    Filed: September 1, 1994
    Date of Patent: March 26, 1996
    Assignees: Sumitomo Metal Industries, Ltd., Sanyo Special Alloys, Ltd.
    Inventors: Kazuyuki Nakasuji, Masaki Takashima
  • Patent number: 5447683
    Abstract: Dense monolithic SiC or SiC ceramic composites are strongly bonded using brazing compositions which, in their preferred composition, include a braze alloy consisting essentially of less than 50 weight percent silicon and at least two metals from the group of Fe, Cr, Co and V and produce a joint suitable for use in a high neutron flux environment. Brazing is carried out at a temperature of about 1200.degree. to 1500.degree. C. in an inert atmosphere and is complete in about 15 minutes. Broadly, a genus of brazing compounds are disclosed which include between about 10 and about 45 weight percent silicon and at least two elements selected from the following group: Li, Be, B, Na, Mg, P, Sc, Ti, V, Cr, Mn, Fe, Co, Zn, Ga, Ge, As, Rb, Y, Sb, Te, Cs, Pr, Nd, Ta, W and Tl.
    Type: Grant
    Filed: November 8, 1993
    Date of Patent: September 5, 1995
    Assignee: General Atomics
    Inventors: Frederick C. Montgomery, Holger H. Streckert
  • Patent number: 5273712
    Abstract: A method of protecting and a protective coating for metal components formed of nickel or cobalt-based superalloys are disclosed. The protective coating essentially consists of the following constituents (in percent by weight):1 to 20% rhenium,15 to 50% chromium,0 to 15% aluminum, the share of chromium and aluminum taken together being at least 25% and at most 53%,0.3 to 2% in total of at least one reactive element from the group consisting of the rare earths, and0 to 3% silicon, impurities, as well as the following elective components:0 to 5% hafnium,0 to 12% tungsten,0 to 10% manganese,0 to 15% tantalum,0 to 5% titanium,0 to 4% niobium, and0 to 2% zirconium,the total share of the elective components being from 0 to a maximum of 15%, and a remainder primarily being at least one of the elements iron, nickel, and cobalt. The protective coating is primarily suited for use with metal components in gas turbines and aircraft engines.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: December 28, 1993
    Assignee: Siemens Aktiengesellschaft
    Inventors: Norbert Czech, Friedhelm Schmitz
  • Patent number: 5176762
    Abstract: A beta titanium alloy having exceptional high temperature strength properties in combination with an essential lack of combustibility is described. In its basic form the alloy contains chromium, vanadium and titanium the nominal composition of the basic alloy being defined by three points on the ternary titanium-vanadium-chromium phase diagram: Ti-22V-13Cr, Ti-22V-36Cr, and Ti-40V-13% Cr. The alloys of the invention are comprised of the beta phase under all the temperature conditions, have strengths much in excess of the prior art high strength alloys in combination with excellent creep properties, and are nonburning under conditions encountered in gas turbine engine compressor sections.
    Type: Grant
    Filed: December 23, 1986
    Date of Patent: January 5, 1993
    Assignee: United Technologies Corporation
    Inventor: Douglas M. Berczik
  • Patent number: 5154885
    Abstract: A protective coating for metal components formed of nickel or cobalt-based superalloys essentially consists of the following constituents (in percentages by weight):1 to 20% rhenium,22 to 50% chromium,0 to 15% aluminum, the share of chromium and aluminum taken together being at least 25% and at most 53%,0.3 to 2% in total of at least one reactive element from the group consisting of the rare earths, and0 to 3% silicon,impurities, as well as the following elective components:0 to 5% hafnium,0 to 12% tungsten,0 to 10% manganese,0 to 15% tantalum,0 to 5% titanium,0 to 4% niobium, and0 to 2% zirconium,the total share of the elective components being from 0 to a maximum of 15%, and a remainder primarily being at least one of the elements iron, nickel, and cobalt.
    Type: Grant
    Filed: August 10, 1990
    Date of Patent: October 13, 1992
    Assignee: Siemens Aktiengesellschaft
    Inventors: Norbert Czech, Friedhelm Schmitz
  • Patent number: 5114503
    Abstract: A magnetic core comprised of an amorphous alloy ribbon wound into a toroidal shape, wherein the said amorphous alloy has a composition of the formula:(Co.sub.1-x-y-z Fe.sub.x Ni.sub.y Mn.sub.z).sub.100-a-b-c M.sub.a Si.sub.b B.sub.cwherein M is at least one element selected from the group consisting of Nb, Cr and Mo, and x, y, z, a, b and c are numbers which satisfy relations of 0<a.ltoreq.6, 13.ltoreq.b.ltoreq.16, 7.ltoreq.b.ltoreq.10, 0<x.ltoreq.0.1, 0.ltoreq.y.ltoreq.0.2 and 0.ltoreq.x.ltoreq.0.13 respectively, said amorphous alloy after heat treatment having a rectangular ratio Br/Bs of at least 80%, a Bs value in a range of 5 KG to 8 KG and a stress relief ratio of at least 75%.
    Type: Grant
    Filed: March 24, 1987
    Date of Patent: May 19, 1992
    Assignee: Hitachi Metals, Inc.
    Inventors: Yoshihito Yoshizawa, Kiyotaka Yamauchi
  • Patent number: 5077006
    Abstract: This invention relates to heat and corrosion resistant alloys for structural parts in industrial furnaces and similar installations requiring hot strength, long life and resistance to hot gas corrosion, carburization and thermal fatigue, and to master alloys to aid in the production of these alloys. The alloys consist of additions of less than one percent by weight each of the components tungsten, zirconium, molybdenum, columbium, titanium and one or more rare earth elements to base alloys of the types standardized by the Alloy Castings Institute Division of the Steel Founders Society of America or to similar base alloys. The master alloys consist of all of these components, with the possible exception of Mo, combined together in the desired proportions, possibly along with some combination of iron, nickel or chromium in total content of up to about half of the master alloys by weight as partial diluents. The resultant master alloys are always denser than molten baths of the base heat resistant alloys.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: December 31, 1991
    Assignee: Carondelet Foundry Company
    Inventor: John H. Culling
  • Patent number: 5030519
    Abstract: A matrix-bonded carbide-containing material of high hardness is prepared using a mixture containing a matrix alloy having a composition in weight percent of from about 15 to about 45 percent chromium, from 0 to about 3 percent silicon, from about 2 to about 6 percent boron, from about 3 to about 11 percent titanium (either as metal or as a compound), balance iron and impurities, and a mass of tungsten carbide particles, the tungsten carbide particles preferably being present in an amount of from about 15 to about 60 percent by weight of the total mixture and the matrix alloy preferably being present in an amount of from about 85 to about 40 percent by weight of the total mixture. The matrix alloy is melted to produce a flowable mixture having a liquid phase and solid tungsten carbide particles, and thereafter solidified. During melting, the tungsten carbide particle size is reduced by interaction with the liquid phase.
    Type: Grant
    Filed: April 24, 1990
    Date of Patent: July 9, 1991
    Assignee: Amorphous Metals Technologies, Inc.
    Inventors: David M. Scruggs, Gerald A. Croopnick
  • Patent number: 5028388
    Abstract: Reduction of chromium oxide is performed by utilizing refinement or reduction container having top-blowing capability. Chromium oxide is charged in the molten iron bath in the aforementioned container. Content of slag is adjusted to maintain the following condition:CaO/SiO.sub.2 :2.1 to 3.5MgO/Al.sub.2 O.sub.3 :0.6 to 0.
    Type: Grant
    Filed: November 19, 1990
    Date of Patent: July 2, 1991
    Assignee: Kawasaki Steel Corporation
    Inventors: Chikashi Tada, Keizo Taoka, Sumio Yamada, Hajime Bada
  • Patent number: 5006054
    Abstract: Low density, high temperature and aluminum-rich intermetallic alloys displaying excellent elevated temperature properties, including oxidation resistance, are disclosed. Based on the aluminum/titanium system, specifically modifications of Al.sub.3 Ti compositions, useful alloys are derived from changes in crystal structure and properties effected by selected-site substitution alloying with manganese and/or chromium, and, where used, vanadium, or equivalent site-substituting alloying elements.
    Type: Grant
    Filed: March 30, 1989
    Date of Patent: April 9, 1991
    Assignee: Technology Development Corporation
    Inventor: Donald E. Nikkola
  • Patent number: 4999158
    Abstract: This invention relates to iron-base alloy compositions, nickel containing austenitic ferrous alloy compositions (especially low nickel compositions) and dopants added to low nickel austenitic alloys as a means of improving the elevated temperature oxidation resistance of the resultant material.
    Type: Grant
    Filed: November 2, 1988
    Date of Patent: March 12, 1991
    Assignee: Chrysler Corporation
    Inventor: John M. Corwin
  • Patent number: 4985075
    Abstract: A method for manufacturing a chromium-bearing pig iron comprises the steps of charging cold bond pellets, iron ore and coke lumps into a blast furnace from above and blowing a gas containing more than 50% oxygen therein and tuyere nose flame temperature control agent into the blast furnace through the tuyere, the cold bond pellets being comprised of powdered chromium ore and powdered coke as principal feed materials. The cold bond pellets are manufactured by performing a mixing, a pelletizing and a curing step. The tuyere nose flame temperature control agent is a top gas, steam, water or CO.sub.2, which is used to control the flame temperature to 2000.degree. to 2900.degree. C.
    Type: Grant
    Filed: January 12, 1989
    Date of Patent: January 15, 1991
    Assignee: Nippon Kokan Kabushiki Kaisha
    Inventors: Yotaro Ohno, Masahiro Matsuura, Kenkichi Sato, Hiroshi Fukuyo
  • Patent number: 4983356
    Abstract: A substantial gain in the properties of conventional FeCrAlY is achieved by adding RuAl to a melt of the conventional material. The resultant composition has a use temperature above the melting point of nickel base superalloys and has good strength and ductility properties to permit its use as a high temperature structural material.
    Type: Grant
    Filed: July 31, 1989
    Date of Patent: January 8, 1991
    Assignee: General Electric Company
    Inventor: Melvin R. Jackson
  • Patent number: 4888153
    Abstract: An Fe-base build-up alloy excellent in resistance to corrosion and wear is disclosed. This alloy comprises in weight percent:C: from 0.005 to 1.6%,Mn: from 4 to 28%,Cr: from 12 to 36%,Mo: from 0.01 to 9%,Hf: from 0.005 to 15%,N: from 0.01 to 0.9%, andoptionally contained:Si: from 0 to 5%,Ni: from 0 to 30%, andone or both of:Nb and W: from 0 to 6%, andthe balance being Fe and incidental impurities.
    Type: Grant
    Filed: July 7, 1988
    Date of Patent: December 19, 1989
    Assignee: Mitsubishi Kinzoku Kabushiki Kaisha
    Inventors: Ritsue Yabuki, Saburo Wakita
  • Patent number: 4869758
    Abstract: An iron/copper/chromium alloy material for a high-strength lead frame or pin grid array, which comprises 20 to 90% by weight of Cu and 2.5 to 12% by weight of Cr, with the balance being mainly iron, and which has an average grain size number of at least 10 in each of the iron/chromium phase and the copper phase, is prepared by continuous casting, cold-working, and aging.
    Type: Grant
    Filed: May 25, 1988
    Date of Patent: September 26, 1989
    Assignee: Nippon Steel Corporation
    Inventors: Kunio Watanabe, Satoshi Nishimura, Kunishige Kaneko
  • Patent number: 4842657
    Abstract: Amorphous alloys containing zirconium as an amorphus forming metal and having the formula X.sub..alpha. Z.sub..gamma. wherein X is at least one of Fe, Co and Ni, .alpha. is 80 to 92 atomic %, Z is zirconium, .gamma. is 8 to 20 atomic % and the sum of .alpha. and .gamma. is 100 atomic %, cause very little variation of properties during aging and embrittlement because they contain no metalloid as the amorphous forming element, and they further have excellent strength, hardness, corrosion resistance and heat resistance and maintain superior magnetic properties which are characteristic of iron group elements.
    Type: Grant
    Filed: December 5, 1980
    Date of Patent: June 27, 1989
    Assignee: Shin-Gijutsu Kaihatsu Jigyodan
    Inventors: Tsuyoshi Masumoto, Kiyoyuki Esashi, Masateru Nose
  • Patent number: 4765955
    Abstract: The alloys according to the invention are the Co-base alloys which contain C, Si, Cr, W, Mo, Ti and Al, and further, as necessary, contain one, two or more elements among Mn, Ni, Fe, Nb and B, having high thermal shock resistance and lead oxide corrosion resistance. Furthermore the alloys can be used for build-up welding and casting, therefore they demonstrate excellent performance when used in the manufacture of engine valves and valves seats of high performance engines.
    Type: Grant
    Filed: September 2, 1986
    Date of Patent: August 23, 1988
    Assignee: Mitsubishi Kinzoku Kabushiki Kaisha
    Inventors: Ritsue Yabuki, Junya Ohe, Sadao Saitoh
  • Patent number: 4735772
    Abstract: The invention relates to magnetic Pd-Co alloys for use in dental prostheses, in particular in root caps. The alloys contain, by weight, 40-60% Pd, 20-59% Co, 0-40% Ni, 0.1-5% Cr, 0.05-0.2% Re, 0.01-0.5% Fe, 0.5-3% Ga, 0-0.1% B, 0-5% Pt or Au, and the gallium may be replaced, in full or in part, by Sn, In, Zn or Mn.
    Type: Grant
    Filed: November 25, 1986
    Date of Patent: April 5, 1988
    Assignee: Elephant Edelmetaal B.V.
    Inventor: Joseph M. van der Zel
  • Patent number: 4728495
    Abstract: The invention relates to removable dental appliances made of cobalt-chromium-cast alloys containing (in % by weight) 0,1 to 1,0% C, 0,05 to 0,5% N, 0,5 to 3,0% Si, 0,3 to 10,0% Mn, 20 to 35% Cr, 2 to 10% Mo, 5 to 40% Fe, at least 20% Cobalt as rest including incidental impurities.
    Type: Grant
    Filed: March 20, 1986
    Date of Patent: March 1, 1988
    Assignee: Thyssen Edelstahlwerke AG
    Inventor: Leo Rademacher
  • Patent number: 4711826
    Abstract: The present invention relates to iron-nickel alloys having improved glass sealing properties. Alloys of the present invention contain from about 30% to about 60% nickel, from about 0.5% to about 3% silicon, from about 0.5% to about 3.5% aluminum and the balance essentially iron. Preferably, the alloys have a total aluminum plus silicon content of less than about 4%. The alloys of the present invention have particular utility in electronic and electrical applications. For example, they may be used as a lead frame or a similar component in a semiconductor package.
    Type: Grant
    Filed: January 27, 1986
    Date of Patent: December 8, 1987
    Assignee: Olin Corporation
    Inventors: Eugene Shapiro, Michael L. Santella
  • Patent number: 4695333
    Abstract: A spinodal decomposition type ternary magnetic allioy is provided which contains, by weight, 3 to 40% vanadium, 5 to 45% chromium and the balance essentially iron. Optionally the alloy may contain at least one additional element, said additional element being present individually in an amount of 0.1 to 5% by weight and not greater than the amount of either vanadium or chromium. The alloy is easy to work and has excellent hard or semi-hard magnetic properties comparable with those of conventional iron-chromium-cobalt alloys. Yet the alloy is low in material cost and simple and inexpensive to manufacture.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: September 22, 1987
    Assignee: Inoue-Japax Research Incorporated
    Inventors: Kiyoshi Inoue, Hideo Kaneko
  • Patent number: 4668310
    Abstract: Amorphous alloys having high strength, high hardness, high crystallization temperature, high saturation magnetic induction, low coercive force, high magnetic permeability and particularly low deterioration of magnetic properties with lapse of time, have a composition formula ofT.sub.a X.sub.b Z.sub.c or T.sub.a' X.sub.b' Z.sub.c' M.sub.d,whereinT is at least one of Fe, Co and Ni,X is at least one of Zr, Ti, Hf and Y,Z is at least one of B, C, Si, Al, Ge, Bi, S and P,a is 70-98 atomic %,b is not more than 30 atomic %,c is not more than 15 atomic %,sum of a, b and c is 100 atomic %,M is at least one Mo, Cr, W, V, Nb, Ta, Cu, Mn, Zn, Sb, Sn, Be, Mg, Pd, Pt, Ru, Os, Rh, Ir, Ce, La, Pr, Nd, Sm, Eu, Gd, Tb and Dy,a' is 70-98 atomic %,b' is not more than 30 atomic %,c' is not more than 15 atomic %,d is not more than 20 atomic %, andsum of a', b', c' and d is 100 atomic %.
    Type: Grant
    Filed: March 14, 1983
    Date of Patent: May 26, 1987
    Assignees: Hitachi Metals, Ltd., Hitachi, Ltd.
    Inventors: Mitsuhiro Kudo, Shinji Takayama, Yoshizo Sawada, Yasunobu Ogata
  • Patent number: 4661415
    Abstract: A zirconium alloy having a plateau region of equilibrium hydrogen dissociation pressure and a small hysteresis, whose hydrogen dissociation pressure is in a range of 0.6 to 3 atm at 20.degree. C., 1 to 5 atm at 40.degree. C., and 1 to 17 atm at 80.degree. C., the activation of which can be effected according to a single procedure of vacuum evacuation at room temperature and pressurization under a hydrogen pressure of 30 atm at room temperature, and which is comparable or superior in the rates of hydrogen absorption and release, the maximum hydrogen absorbing capacity and effective hydrogen releasing capacity to conventional zirconium alloys. A hydrogen absorbing and releasing material comprising an alloy as mentioned above and thin films of one element selected from Pd, Cu, and Ni, which allows only hydrogen to permeate, and covering the surfaces of particles of the alloy.
    Type: Grant
    Filed: October 22, 1985
    Date of Patent: April 28, 1987
    Assignee: Nihon Yakin Kogyo Kabushiki Kaisha
    Inventors: Kazuo Ebato, Yasuaki Osumi, Keiji Tamura, Hiroshi Yoshida
  • Patent number: 4656023
    Abstract: Hydrogen storage materials are provided by a quaternary alloy of the formula:Zr.sub.1-x Ti.sub.x CrFe.sub.ywherein x has a value in a range from 0.1 to 0.3, and y has a value in a range from 1.2 to 1.4, and their hydrides.
    Type: Grant
    Filed: June 14, 1985
    Date of Patent: April 7, 1987
    Assignee: Koppers Company, Inc.
    Inventors: William E. Wallace, Gui-Yu Yu
  • Patent number: 4623387
    Abstract: Amorphous alloys containing zirconium as an amorphous forming metal and having teh formula X.sub..alpha. Z.sub..gamma. wherein X is at least one of Fe, Co and Ni, .alpha. is 80 to 92 atomic %, Z is zirconium, .gamma. is 8 to 20 atomic % and the sum of .alpha. and .gamma. is 100 atomic %, cause little variation of properties during aging and embrittlement because they contain no metalloid as the amorphous forming element, and they further have excellent strength, hardness, corrosion resistance and heat resistance and maintain superior magnetic properties which are characteristic of iron group elements.
    Type: Grant
    Filed: February 5, 1985
    Date of Patent: November 18, 1986
    Assignee: Shin-Gijutsu Kaihatsu Jigyodan
    Inventors: Tsuyoshi Masumoto, Kiyoyuki Esashi, Masateru Nose
  • Patent number: 4556551
    Abstract: An alloy consisting of zirconium, chromium, iron and optionally titanium is characterized in having C14 hexagonal crystal structure and ZrCr.sub.2 stoichiometry. Members of a preferred class of compounds, represented by the empirical formula Zr.sub.1-x Ti.sub.x Cr.sub.2-y Fe.sub.y wherein "x" has a value between 0.0 and 0.9 and "y" has a value of 0.1 to 1.5, are particularly suitable for use as hydrogen storage materials.
    Type: Grant
    Filed: March 22, 1984
    Date of Patent: December 3, 1985
    Assignee: Koppers Company, Inc.
    Inventors: William E. Wallace, Faiz Pourarian
  • Patent number: 4547338
    Abstract: Directed to a corrosion resistant alloy particularly designed for use in power plant exhaust gas scrubbers which contains about 0.015% to about 0.025% carbon, not more than about 1% manganese, not more than about 0.3% silicon, about 19% to about 22% chromium, about 8.5% to about 9.5% molybdenum, about 30% to about 42% nickel, up to about 0.2% nitrogen, with the nickel and nitrogen contents being so related that at about 30% nickel, the nitrogen content is at least about 0.15%, while at a nickel content of at least about 40%, the nitrogen content does not exceed about 0.03%, the balance being essentially iron, with the iron content in the range of about 28% to about 40%.
    Type: Grant
    Filed: December 14, 1984
    Date of Patent: October 15, 1985
    Assignee: AMAX Inc.
    Inventors: Paul J. Grobner, Armand P. Bond, Abraham Poznansky
  • Patent number: 4512965
    Abstract: Quaternary hyperstoichiometric alloys of the formula: ZrCrFeT.sub.x and their hydrides are provided, characterized as having MgZn.sub.2 hexagonal crystal structure wherein T is selected from Mn, Fe, Co, Ni and Cu, and X is a number from 0.1 to 1.0. These alloys readily form hydrides at low hydrogen pressure and are suitable for use as hydrogen storage materials.
    Type: Grant
    Filed: November 21, 1983
    Date of Patent: April 23, 1985
    Assignee: Koppers Company, Inc.
    Inventors: William E. Wallace, Faiz Pourarian
  • Patent number: 4504310
    Abstract: A process for the production of high purity metals or metallic alloys comprises the steps of:(a) producing a metal or metallic alloy, the non-metallic inclusions of which are, preferably, easily reducible oxides of the base metal;(b) milling the metal or metallic alloy thus obtained and agglomerating the milled metal or metallic alloy with an agglomerating agent and a reducing agent, so as to form balls; and(c) subjecting the balls to a reducing treatment under regulated conditions of reduced pressure and elevated temperature, at which the reducing agent acts on the non-metallic inclusions while substantial sublimation of the alloying metal or metals is avoided.The invention is particularly applicable to the production of high purity chromium.
    Type: Grant
    Filed: August 5, 1983
    Date of Patent: March 12, 1985
    Assignee: C. Delachaux
    Inventor: Laurent L. Boulier
  • Patent number: 4496402
    Abstract: An Fe-Cr-Co type magnet body of columnar structure having a maximum energy product (BH).sub.max of 7 MGOe or higher consisting essentially of, by weight ratio, 5-30% cobalt, 15-40% chromium, 0.1-10% molybdenum, 0.05-1.2% titanium and 0.1-5% vanadium, with the balance being iron and inevitable impurities, said body having been subjected to columnar-crystallization.
    Type: Grant
    Filed: March 9, 1982
    Date of Patent: January 29, 1985
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Masaji Endo, Takami Hikone
  • Patent number: 4487744
    Abstract: An austenitic stainless corrosion resistant alloy and articles made therefrom having good resistance to pitting and crevice corrosion in oxidizing chloride-bearing media combined with resistance to general corrosion and to intergranular corrosion in oxidizing media, containing in weight percent about______________________________________ w/o ______________________________________ C 0.06 Max. Mn 1.4 Max. Si 0.9 Max. P 0.035 Max. S 0.035 Max. Cr 20-26 Ni 34-44 Mo 3-<5.1 Cu 0.1-<3.1 N 0.4 Max. B 0.005 Max. Ce + La 0.4 Max. Added Nb 1 Max. Ti 0.5 Max. ______________________________________and the balance iron. The amount of nitrogen is not greater than that which can be retained in solution. When present niobium plus titanium ranges upward from a minimum which is sufficient to combine stoichiometrically with the amount of carbon present in excess of 0.025 w/o. In this composition the elements chromium, nickel, molybdenum and copper are balanced so that the value of Correlation I is equal to or less than 1.
    Type: Grant
    Filed: July 28, 1982
    Date of Patent: December 11, 1984
    Assignee: Carpenter Technology Corporation
    Inventors: Terry A. DeBold, Douglas G. Frick, John S. Kutzamanis
  • Patent number: 4464208
    Abstract: Disclosed is an amorphous alloy for a magnetic head, which is of the formula:(Co.sub.1-a-b-c Fe.sub.a Ru.sub.b TM.sub.c).sub.100-x-y Si.sub.x B.sub.ywherein TM is at least one of Ti, V, Cr, Mn, Ni, Zr, Nb, Mo, Hf, Ta and W, and, in atomic concentrations, 0.02.ltoreq.a.ltoreq.0.08, 0.07.ltoreq.b.ltoreq.0.2, c=0 or 0.01.ltoreq.c.ltoreq.0.1, 0.ltoreq.x.ltoreq.20 and 4.ltoreq.y.ltoreq.9, which is excellent in abrasion-resistance and simultaneously has high permeability.
    Type: Grant
    Filed: December 30, 1982
    Date of Patent: August 7, 1984
    Assignee: Tokyo Shibaura Denki Kabushiki Kaisha
    Inventor: Hiroshi Tateishi
  • Patent number: 4457891
    Abstract: A hydrogen storage material is described which comprises an alloy of the composition of 25 to 30.9% by weight of Ti, about 10 to about 42% by weight of V and about 27.1 to about 65.1% by weight of Mn. The proviso is that more than 2 up to at most 2.2 atoms are present per titanium atom. Up to about 40%, preferably about 10 to about 40%, of the vanadium atoms can be replaced by iron atoms and up to about 10%, preferably about 3 to about 10%, can be replaced by aluminum atoms, but not more than about 40% of the vanadium atoms in total are replaced. Moreover, in place of titanium, a mixture can be used in which up to about 20% of the titanium fraction are replaced by Ca, Y, La, misch metal, or mixtures thereof. Up to about 0.2 atom of Cr per the titanium atom, up to about 0.1 atom of Ni per titanium atom and up to about 0.05 atom of Cu per titanium atom can also be present, but not more than about 0.1 atom of Ni plus Cu, these atoms replacing the same number of vanadium atoms.
    Type: Grant
    Filed: March 14, 1983
    Date of Patent: July 3, 1984
    Assignee: Daimler-Benz Aktiengesellschaft
    Inventors: Otto Bernauer, Klaus Ziegler
  • Patent number: H326
    Abstract: Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.
    Type: Grant
    Filed: June 23, 1986
    Date of Patent: September 1, 1987
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Howard R. Brager, Francis A. Garner