Abstract: A coaxial injection device for injecting and dispersing reagents into a reactor, including an exterior duct for high-velocity gas injection; an outer-middle injector with at least one nozzle for liquid injection; an inner-middle duct for low-velocity gas injection; and an interior injector with nozzle for liquid injection; wherein, the exterior duct is formed by the internal wall of an insert and the external wall of the outer-middle injector; and is located externally to and circumferentially surrounds all other injectors and ducts; the outer-middle injector is formed by two concentric cylinders with end plate and injector nozzles; the inner-middle duct is formed by interior wall of the outer-middle injector and the exterior wall of the interior injector; the interior injector is formed by a cylinder with an endplate, the endplate having a nozzle; thereby ensuring the mixing and dispersion of the liquids and gases into the reactor to increase reaction homogeneity, reaction efficiency, reactor efficiency and

Abstract: Recirculation of treated flue gas either independently or as a substitute for ambient air at specific points of ingress in a flue gas treatment system is provided to stabilize approach temperature and related parameters such as reagent consumption and pollution admission rate preventing both the accumulation of particulate matter and excessive corrosion associated with ambient air ingress. This recirculation provides a desired turbulence within remote regions of the flue gas treatment system to reduce the amount of particulate matter that may otherwise settle and accumulate in the absorber vessel or other areas of the system thereby causing particulate matter to be conveyed to the particulate removal device.

Abstract: A method for producing a substantially desulfurized a hydrocarbon fuel stream at temperatures less than 100° C. The method includes providing a nondesulfurized fuel cell hydrocarbon fuel stream that may include water and passing the fuel stream sequentially through a zeolite Y adsorbent and a selective sulfur adsorbent. The zeolite Y adsorbent may be exchanged with copper ions. The method produces a substantially desulfurized hydrocarbon fuel stream containing less than 50 ppb sulfur.

Abstract: Methods and apparatuses are provided for protecting a catalyst within a combustor. In one embodiment, a catalytic reactor includes a protective coating that may be chemically removed or mechanically removed while the catalytic reactor is disposed in a combustor.

Abstract: Sorbent compositions containing halogen and calcium are added to coal to mitigate the release of sulfur and/or other harmful elements, including mercury, into the environment during combustion of coal containing natural levels of mercury.

Abstract: Disclosed is a process for removing organic sulfur from more than one reactive fuel gas stream. A reactor vessel that is provided with at least one bed of hydrodesulfurization catalyst is used to hydrodesulfurize multiple reactive fuel gas streams with a less reactive fuel gas stream being introduced into the reactor vessel at a point above the introduction point of a more reactive fuel gas stream. An hydrotreated fuel gas is yielded from the reactor vessel having a hydrogen sulfide concentration and a low organic sulfur content.

Abstract: Apparatus, process and article for treating a gas containing one or more of a chemical and/or biological contaminant. The process includes contacting the gas with an aggregate composition comprising an insoluble rare earth-containing compound to form a gas depleted of chemical and active biological contaminants. The insoluble rare earth-containing compound can include one or more of cerium, lanthanum, or praseodymium. The composition comprises no more than two elements selected from the group consisting of yttrium, scandium, and europium when the aggregate has been sintered. A suitable insoluble cerium-containing compound can be derived from cerium carbonate. In one embodiment, the aggregate composition consists essentially of one or more cerium oxides, and optionally, a binder. Although intended for a variety of fluid treatment applications, such applications specifically include the treatment of breathing gases such as air that may contain chemical and/or biological contaminants.

Abstract: A method of scrubbing mercury compounds and nitrogen oxides from a gas stream employing a scrubbing operation. The method involves the contact of the stream which contains mercury, SOx and NOx compounds with a sorbent to remove at least a portion of the latter compounds. This results in a partially cleaned stream. The method further involves contacting the latter stream with an oxidant to oxidize and remove substantially all residual nitrogen oxides, mercury and mercury compounds remaining in the stream.

Abstract: Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.

Abstract: A method for purifying waste gases of an at least partially burnt solid fuel to reduce pollutants such as SOx and/or HCl and NOx. The waste gas flows into a moving bed reactor from below through a lower and upper layer of an adsorption and/or absorption agent already polluted with NOx, SOx and/or HCl. SOx and/or HCl components are adsorbed from the waste gas into the NOx loaded adsorption and/or absorption agent. Thereafter, the waste gas is mixed with an ammonium-containing compound and flows through an upper horizontal gas inflow and bulk material removal tray of the moving bed reactor into the upper layer of the adsorption and/or absorption agent already polluted with NOx and small quantities of SOx and/or HCl. During the throughflow of the upper layer, NOx components are adsorbed from the waste gas onto the adsorption/absorption agent.

Abstract: Disclosed herein are systems and methods for treating carbon dioxide in an environmentally effective manner. Systems and methods include providing a carbon dioxide enriched stream having CO2 and at least one oxidizable sulfur compound and passing at least some of the carbon dioxide enriched stream to carbon dioxide storage, wherein the method further comprises passing at least some of the carbon dioxide enriched stream to selective sulfur removal during a period of system upset. Selective sulfur removal may comprise treatment with an solid or liquid capable of oxidizing the oxidizable sulfur compound.

Abstract: A method for desulfurizing natural gas includes contacting the natural gas with an adsorbent which preferentially adsorbs at least one of hydrogen sulfide, COS, sulfur odorants, or combinations thereof, at a selected temperature and pressure, thereby producing desulfurized natural gas and an at least one of hydrogen sulfide/COS/sulfur odorant/combinations thereof-rich adsorbed component. The adsorbent includes a copper species adapted to form ?-complexation bonds and direct metal-sulfur bonds with the at least one of hydrogen sulfide, COS, sulfur odorants, or combinations thereof, and wherein the preferential adsorption occurs by ?-complexation and direct metal-sulfur bonding.

Abstract: The present invention describes the process of preparing ceramics for the absorption of ACIDIC gases, which worsen the greenhouse effect, that are released in combustion systems, or that are present in closed environments. In relation to carbon dioxide, principal target of the present invention, the process of absorption, transport, processing and transformation of the gas into other products is described. The process uses ceramic materials prepared through the solid mixture of one or more metallic oxides, with one or more binding agents and an expanding agent. The product generated can be processed and the absorbent system regenerated. The carbon dioxide obtained in the processing can be used as analytic or commercial carbonic gas, various carbamates and ammonium carbonate.

Abstract: Sorbent compositions containing halogen and calcium are added to coal to mitigate the release of sulfur and/or other harmful elements, including mercury, into the environment during combustion of coal containing natural levels of mercury.

Abstract: An integrated system [1000] is described for reducing operating costs of power plants while keeping gaseous pollutants in exhaust flue gasses, such as Mercury (Hg), below acceptable limits. Controller [1800] monitors and controls operation of a scrubber [1300], activator injection system [1400], sorbent injection system [1500] and a filter [1600]. Scrubber [1300] provides a neutralizer to remove SO2 emissions. Activator injection system [1400] provides and activator that increases affinity of the pollutant gasses for a sorbent. Sorbent injection system [1500] employs novel low friction injection lances [1590] that evenly distribute the sorbent particles. A filter [1600] collects the sorbent particles that cake onto filter bags [1620] that are periodically cleaned. A controller [1800] receives the costs of materials consumed and the filter bag life for the plant and performs an optimization of the multiple variables to minimize costs while keeping the pollutant emissions below a prescribed limit.

Abstract: A process for removing organic sulfur from a fuel gas stream that further contains light olefins by catalytic hydrodesulfurization to yield a treated fuel gas having an very low concentration of organic sulfur. The effluent of the catalytic hydrodesulfurization reactor may be cooled with a portion thereof being recycled and introduced along with the fuel gas stream that is charged to the hydrodesulfurization reactor. The remaining, unrecycled portion of the effluent may further be treated to remove the hydrogen sulfide that is yielded from by the hydrodesulfurization of the fuel gas stream.

Abstract: Systems and methods of capturing and sequestering carbon dioxide, comprising mixing a substantially non-aqueous solvent and an alkali such that the solvent and alkali form a solvent suspension, mixing water and a flue gas containing carbon dioxide with the solvent suspension such that a reaction occurs, the reaction resulting in the formation of a carbonate, water and heat. Methods and processes of environmental remediation and recovering metals from waste streams are also provided.

Abstract: Disclosed herein is an apparatus and methods for decontaminating syngas generated in a fluidized-bed gasifier wherein metal contaminants, inter alia, alkali metals, halogens, particulates, and transition metals and sulfur containing contaminants are removed prior to the catalytic thermal cracking of tar and ammonia. Further disclosed is an apparatus and methods for removing ammonia from syngas.

Abstract: A method of removing hydrogen sulfide from an emissions stream is disclosed, wherein the method includes directing the emissions stream into a hydrogen sulfide converter having a metal oxide catalyst, adsorbing the hydrogen sulfide in the emissions stream to the metal oxide catalyst in the hydrogen sulfide converter, reacting the hydrogen sulfide with at least one of an oxidant and a reductant in the hydrogen sulfide converter to chemically transform the hydrogen sulfide, and adjusting an air-fuel ratio of the emissions stream based on exhaust temperature of an emission control device, where the adjustment varies a duration of at least one of lean and rich operation to perform the adsorbing and reacting even as exhaust temperature varies.

Abstract: The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.

Abstract: Sorbent compositions containing halogen and calcium are added to coal to mitigate the release of sulfur and/or other harmful elements, including mercury, into the environment during combustion of coal containing natural levels of mercury.

Abstract: Disclosed is a method for reducing emissions from exhaust gas generated during the grinding and drying of cement raw meal as part of a cement manufacturing process. The invention comprises circuiting the exhaust gas between a raw mill and a clinker cooler. In the clinker cooler at least a portion of said emissions are delivered to a cement kiln in which said emissions are removed by being combusted and/or absorbed.

Abstract: Sorbent components containing calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents are added to the coal ahead of combustion and/or are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.

Abstract: Methods and systems for reducing emissions of particulate matter from a gaseous stream are provided. The subject systems include a catalyst that reduces the amount of particulate matter emissions in the gaseous stream. Embodiments of the subject systems may also reduce the amount of particulate matter precursor emissions in the gaseous stream. In some cases, the subject systems and methods include a sorber that facilitates the reduction in particulate matter and particulate matter precursors in the gaseous stream. The subject methods and systems find use in a variety of applications where it is desired to reduce particulate matter emissions from a gaseous stream.

Abstract: A cement kiln chlorine/sulfur bypass system wherein the equipment cost is suppressed and the sulfur included in a combustion gas bled from a cement kiln is separated and effectively utilized. The cement kiln chlorine/sulfur bypass system comprises an air bleed means for bleeding a kiln exhaust gas passage, which runs from the end of the cement kiln to a bottom cyclone, of a part of the combustion gas, a separating means for separating dust in the gas bled by the air bleed means into coarse particles and fine particles, and a wet dust collector for collecting dust from the gas containing the fine particles separated by the separating means. The separating means is preferably a classifier in which the cut size is changeable. The wet dust collector is preferably a mixing scrubber.

Abstract: Finely divided ferrous carbonate absorbent, siderite granules or absorbent particles made by mixing, agglomerating and shaping finely powdered ferrous carbonate, preferably siderite, in combination with minor effective amounts of water or an optional binder, followed by drying, are used to treat and significantly reduce concentrations of hydrogen sulfide, carbonyl sulfide, organic disulfides, mercaptans and other sulfurous compounds and contaminants in gaseous and liquid fluid streams such as natural gas, light hydrocarbon streams, crude oil, acid gas mixtures, carbon dioxide gas and liquid streams, anaerobic gas, landfill gas, geothermal gases and liquids, and the like. Methods for absorbing sulfur compounds in a moist atmospheric environment and for regenerating the absorbent by contacting it with air and steam or, continuously, by mixing the feed stream with moist air are also disclosed.

Abstract: The present invention involves a catalytic process for purifying a gas stream comprising purifying the gas stream at a temperature from about 250° to 550° C. by removing sulfur compounds and including a gas shift reaction to convert carbon monoxide to carbon dioxide to produce a partially purified gas stream. The warm gas stream purification involves COS hydrolysis and hydrogenation to H2S, the removal of H2S, and a CO gas shift to convert CO to CO2 to produce a partially purified stream. Then the carbon dioxide and other impurities are removed from the partially purified gas stream.

Abstract: Compositions and associated methods directed to the removal of sulfurous compounds from air are presented herein. The compositions and methods may be able to treat air with H2S concentrations of at least 1000 ppm. The compositions and associated methods are used to remove sulfurous compounds from air associated with wastewater systems in various aspects.

Abstract: Sulfur oxides are removed from an oxygen-containing acid gas in configurations and methods in which oxygen is removed from the acid gas using reducing gases at relatively high temperature. The so treated acid gas is then fed to a direct reduction reactor in which the sulfur species are converted to elemental sulfur. Contemplated configurations are particularly effective and economically attractive as they are generally not limited by reaction equilibrium as present in a Claus reaction and do not require solvent and solvent-associated equipment.

Abstract: Mixing small amounts of an inorganic halide, such as NaCl, to basic copper carbonate followed by calcination at a temperature sufficient to decompose the carbonate results in a significant improvement in resistance to reduction of the resulting copper oxide. The introduction of the halide can be also achieved during the precipitation of the carbonate precursor. These reduction resistant copper oxides can be in the form of composites with alumina and are especially useful for purification of gas or liquid streams containing hydrogen or other reducing agents. These reduction resistant copper oxides can function at near ambient temperatures.

Abstract: Disclosed herein are various types of systems and methods for the efficient production of sulfur from a sulfur-laden gas. The system described herein includes a desulfurization unit, a regenerator receiving sulfurized mass from the desulfurization unit, a sulfur recovery unit, a sulfur track in fluid communication with the regenerator and the sulfur recovery unit, and a sulfur concentrator on a sulfur track. The sulfur stream coming out of the regenerator is concentrated using the sulfur concentrator and converted into a sulfur product at the sulfur recovery unit.

Abstract: A method for desulfurizing a fluid comprising at least one sulfur compound is provided. The method includes providing an oxide composition comprising at least one byproduct oxide from a process for removing one or more impurities from coal and contacting the oxide composition with the fluid. The oxide composition reacts with the at least one sulfur compound to form a solid precipitate. Methods for operating a coal combustion system are also provided.

Abstract: A method of introducing flue gas, from a flue stack in a steam-assisted production facility, into a heat exchanger. The flue gas comprises boiler combustion products selected from at least one of commercial pipeline gas and produced gas. The method begins by cooling a portion of the water vapor in the flue gas in the heat exchanger to produce flue gas water. This flue gas water is then collected and removed as make-up water.

Abstract: A method of removing SOx from a flue gas stream including SOx includes providing a source of trona and injecting the trona as a dry sorbent into the flue gas stream. The temperature of the flue gas is at an elevated temperature greater than 400° F., preferably between about 600° F. and about 900° F. The trona is maintained in contact with the flue gas for a time sufficient to react a portion of the trona with a portion of the SOx to reduce the concentration of the SO2 and/or SO3 in the flue gas stream.

Abstract: A system for removing sulfur dioxide (SO2) from SO2 laden flue gas resulting from the burning of fossil fuel, includes an absorber and first and second separators. The absorber captures SO2 from a flow of the SO2 laden flue gas with a sorbent. The first separator separates a first portion of the sorbent with captured SO2 both from a second portion of the sorbent with captured SO2 and from the flue gas. The second separator separates the second portion of sorbent from the flue gas.

Abstract: The invention provides a process for the removal of COS and H2S from a synthesis gas stream comprising COS and H2S, the process having the steps of: removing H2S from a feed synthesis gas stream with a first solid adsorbent to obtain a first synthesis gas stream, converting COS in the first synthesis gas stream to H2S by contacting the first synthesis gas stream with a COS-hydrolysing catalyst in the presence of water in a hydrolysis zone to obtain a second synthesis gas stream depleted of COS and enriched in H2S; and removing H2S from the second synthesis gas stream by contacting the second synthesis gas stream with a second solid adsorbent in a H2S removal zone to obtain a third synthesis gas stream depleted of H2S and depleted of COS to very low levels.

Abstract: Certain exemplary embodiments can involve contacting a predetermined portion of a medium and a reaction product resulting from a reaction between predetermined reactants that can include a predetermined active ferric chelate and a nitrate/nitrite, the contacting occurring at a pH of approximately 6 to approximately 8, the contacting effective to oxidize at least a portion of a sulfide contaminant associated with the predetermined portion of the medium.

Abstract: Disclosed is a method for the reduction of mercury emissions from an industrial plant utilizing a cement or minerals kiln that has a high level of mercury. The invention allows for the repeated treatment of a gas stream to reduce the level of mercury and other pollutants through reduction steps, allowing targeted treatment of specific compounds. The invention utilizes multiple sorbent injections for the step-wise reduction in pollutants. Utilizing the multiple stages of reaction, very high levels of mercury emissions may be controlled to greater reduction percentages than existing methods.

Abstract: In a method for the purifying of the waste gases of a sintering process of ores in the production of metals, in which ore material is sintered with a solid fuel, with the combustion of the solids and passage through a smoldering process, at least the pollutants SOx and/or HCl and NOx are reduced or extensively eliminated. To this end, the sintering waste gas is guided into a moving bed reactor (50) from below through a lower and upper layer (54B; 54A) of an adsorption and/or absorption agent already polluted with NOx and SOx and/or HCl, wherein at least the main quantity of SOx and/or HCl components is adsorbed from the sintering waste gas into the pore system of the NOx-loaded adsorption and/or absorption agent.

Abstract: This disclosure relates generally to processes for efficient incineration and conversion of the tail gas streams from sulfur recovery units containing sulfur compounds such as H2S, CO2, COS, CS2, and other sulfur species and sulfur vapors from S1 to S8 to SO2. The present disclosure describes the use of a combination of catalysts to achieve efficient oxidation of all reduced sulfur compounds as well as oxidation of CO and H2 to meet the industry emission requirements. The catalytic tail gas incineration process described herein can advantageously operate at lower temperatures, which in turn can represent a savings in reduced fuel gas costs.

Abstract: A method of removing SO3 from a flue gas of a boiler. The method includes the following steps: injecting chloride salts into a stream of the flue gas at a position located downstream of an air pre-heater—the position is selected so that the flue gas has a temperature at the position of substantially between 100° C. and 400° C.; reacting chloride salts with the SO3 to form a sulfate-containing reaction product; and collecting the sulfate-containing reaction product in a particulate collector downstream of the boiler. A purge stream from a wet flue gas desulfurization system may be used as a source of the chloride salts. Additional chlorides may be added to the purge stream as necessary.

Abstract: The invention relates to a process and a device for the removal of dust, HF, HCl, SO2, SO3, heavy metals, heavy-metal compounds, polyhalogenated hydrocarbons and polycyclic hydrocarbons from combustion flue gases by treating the pollutant-containing combustion flue gases with a sorbent in a circulating fluidized bed. The process is characterized in that the sorbent used is a mixture of Ca(OH)2, at least one naturally occurring zeolite and a carbon-containing substance, in that the treatment of the pollutant-containing combustion flue gases with the sorbent is carried out at from 120 to 180° C.

Abstract: Disclosed is a process for removing sulfur from a fuel gas stream that comprises an organic sulfur compound and a light olefin. The process includes introducing a fuel gas stream into an elongated hydrotreating reactor vessel in which it is contacted with a hydrodesulfurization catalyst under hydrodesulfurization process conditions. A quench gas stream is also introduced into the elongated hydrotreating reactor vessel at a location below the point of introduction of the fuel gas stream. A reactor effluent is yielded that contains hydrogen sulfide and a significantly reduced organic sulfur concentration that is below the organic sulfur concentration of the fuel gas stream.

Abstract: Calcium bromide is a component of sorbent compositions that can be added on to coal to reduce the amount of sulfur gases released into the atmosphere from a coal burning facility. The sorbent components are added onto coal before the coal is added into the furnace and combusted. The fuel being burned is any fuel that contains sulfur, such as lignite, bituminous, and anthracite coal. The sorbent can contain other components such as silica, alumina, cement kiln dust, lime kiln dust, Portland cement, and aluminosilicate clay. Sulfur emissions are monitored during combustion of the fuel, and the rate of sorbent addition can be changed or a adjusted based on the monitored sulfur levels.

Abstract: A flue gas desulfurization process and system that utilize ammonia as a reactant, and in which any hydrogen sulfide and/or mercaptans within the ammonia are separated during the desulfurization process so as to prevent their release into the atmosphere. The process and system entail absorbing acidic gases from a flue gas with a scrubbing media containing ammonium sulfate to produce a stream of scrubbed flue gas, collecting the scrubbing media containing the absorbed acidic gases, injecting into the collected scrubbing media a source of ammonia that is laden with hydrogen sulfide and/or mercaptans so that the injected ammonia is absorbed into and reacted with the collected scrubbing media, stripping the hydrogen sulfide and/or mercaptans from the collected scrubbing media by causing the hydrogen sulfide and/or mercaptans to exit the collected scrubbing media as stripped gases, and collecting the stripped gases without allowing the stripped gases to enter the stream of scrubbed flue gas.

Abstract: Sorbent components containing calcium, alumina, silica, and halogen are used in combination during coal combustion to produce environmental benefits. Sorbents are added to the coal ahead of combustion and/or are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components ? reduce emissions of mercury and sulfur; ? reduce emissions of elemental and oxidized mercury; ? increase the efficiency of the coal burning process through de-slagging of boiler tubes; ? increase the level of Hg, As, Pb, and/or Cl in the coal ash; ? decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and ? make a highly cementitious ash product.

Abstract: A system and method for removing sulfur-containing contaminants from indoor air includes a panel system having a first layer and a second layer. The first layer can include a base media onto which sodium bicarbonate is attached. The second layer can include a base media onto which activated carbon is attached. Indoor air including sulfur-containing contaminants can contact and pass through the first layer. Sulfuric acid can react with the sodium bicarbonate to produce sodium sulfate, which can, in turn, act as a drying agent for organic sulfur-containing contaminants in the indoor air, such as carbon disulfide and carbonyl sulfide. As a result of such drying, the second layer can more effectively trap and/or bind (adsorb) the organic sulfur-containing contaminants so that these contaminants are removed from the contaminated air. The treated air can be returned to an indoor space of the structure.

Abstract: A COS treatment apparatus for a gasified gas includes an O2 removal catalyst and a COS conversion catalyst located on the downstream side of a gasified gas flow with respect to the O2 removal catalyst. Also, a COS treatment apparatus includes a TiO2 catalyst that carries Cr2O3 or NiO. Further, a COS treatment method includes a first step in which O2 is removed by the reaction with H2S and CO, and a second step in which COS is converted to H2S.

Abstract: Powdered lime composition having a BET specific surface area that is equal to or greater than 25 m2/g and a BJH total pore volume obtained from nitrogen desorption that is equal to or greater than 0.1 cm3/g, and furthermore comprising an alkali metal. The alkali metal content is equal to or greater than 0.2% and equal to or less than 3.5% based on the total weight of the composition. There is also described a method of preparing the composition and use thereof to reduce flue gases.

Abstract: Finely divided ferrous carbonate absorbent, siderite granules or absorbent particles made by mixing, agglomerating and shaping finely powdered ferrous carbonate, preferably siderite, in combination with minor effective amounts of water or an optional binder, followed by drying, are used to treat and significantly reduce concentrations of hydrogen sulfide, carbonyl sulfide, organic disulfides, mercaptans and other sulfurous compounds and contaminants in gaseous and liquid fluid streams such as natural gas, light hydrocarbon streams, crude oil, acid gas mixtures, carbon dioxide gas and liquid streams, anaerobic gas, landfill gas, geothermal gases and liquids, and the like.