Fiber, Fabric, Or Textile Patents (Class 423/447.1)
  • Publication number: 20120077031
    Abstract: The present invention relates to a catalyst composition for the synthesis of thin multi-walled carbon nanotube(MWCNT). More particularly, this invention relates to a multi-component metal catalyst composition comprising i) main catalyst of Co and Al, ii) inactive support of Mg and iii) optional co-catalyst at least one selected from Ni, Cr, Mn, Mo, W, Pb, Ti, Sn, or Cu. Further, the present invention affords thin multi-walled carbon nanotube having 5˜20 nm of diameter and 100˜10,000 of aspect ratio in a high yield.
    Type: Application
    Filed: July 14, 2010
    Publication date: March 29, 2012
    Applicant: KOREA KUMHO PETROCHEMICAL CO., LTD.
    Inventors: Sang-Hyo RYU, Wan Sung LEE, Youngchan JANG
  • Publication number: 20120070641
    Abstract: Provided are a graphene sheet and a process of preparing the same. Particularly, a process of economically preparing a large-area graphene sheet having a desired thickness and a graphene sheet prepared by the process are provided.
    Type: Application
    Filed: November 28, 2011
    Publication date: March 22, 2012
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Jae-young CHOI, Hyeon-Jin SHIN, Seon-mi YOON
  • Patent number: 8137652
    Abstract: The invention provides a method of functionalizing the sidewalls of a plurality of carbon nanotubes with oxygen moieties, the method comprising: exposing a carbon nanotube dispersion to an ozone/oxygen mixture to form a plurality of ozonized carbon nanotubes; and contacting the plurality of ozonized carbon nanotubes with a cleaving agent to form a plurality of sidewall-functionalized carbon nanotubes.
    Type: Grant
    Filed: June 27, 2006
    Date of Patent: March 20, 2012
    Assignee: The Research Foundation of State University of New York
    Inventors: Stanislaus S. Wong, Sarbajit Banerjee
  • Patent number: 8137810
    Abstract: A process for producing polyacrylonitrile-base precursor fibers for production of carbon fibers, which comprises spinning a spinning dope containing 10 to 25 wt % of a polyacrylonitrile-base polymer having an intrinsic viscosity of 2.0 to 10.0 by extruding the spinning dope from a spinneret by a wet spinning or a dry wet spinning method, drying and heat-treating fibers obtained by the spinning, and then steam drawing the resulting fibers, wherein the linear extrusion rate of the polyacrylonitrile-base polymer from the spinneret is 2 to 15 m/min. Carbon fibers which are produced by stabilizing-carbonizing treatment of the polyacrylonitrile-base precursor fibers and which have a strand tensile modulus of 320 to 380 GPa and a conduction electron density of 3.0×1019 to 7.0×1019 spins/g as determined by electron spin resonance.
    Type: Grant
    Filed: December 6, 2006
    Date of Patent: March 20, 2012
    Assignee: Toray Industries, Inc.
    Inventors: Masafumi Ise, Isao Nakayama, Makoto Endo
  • Patent number: 8137591
    Abstract: The present invention relates to a catalyst composition for preparing carbon nanotube containing multi-component support materials of amorphous Si, Mg and Al as well as a bulk scale preparation process for preparing carbon nanotube using said catalyst composition. More specifically, this invention relates to a process for preparing carbon nanotube using the catalyst composition comprising a transition metal catalyst and support materials of amorphous Si, Mg and Al.
    Type: Grant
    Filed: September 29, 2009
    Date of Patent: March 20, 2012
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Dong Hwan Kim, Sang-Hyo Ryu, Wan Sung Lee, Namsun Choi, Hyun-Kyung Sung, Youngchan Jang
  • Publication number: 20120058889
    Abstract: Disclosed is a composition containing carbon nanotubes which meets all of the following conditions (1) to (4). (1) When observed via transmission electron microscopy, at least 50 out of every 100 carbon nanotubes are double-walled carbon nanotubes. (2) The carbon nanotubes have an average outer diameter in the range of 1.0 to 3.0 nm. (3) During thermogravimetric analysis under atmosphere at a temperature increase rate of 10° C./minute, a high temperature combustion peak is at 700 to 850° C., and the relationship between low temperature weight loss (TG(L)) and high temperature weight loss (TG(H)) is TG(H)/(TG(L)+TG(H))?0.75. (4) The composition containing carbon nanotubes has a volume resistance value between 1.0×10?2 ?·cm and 1.0×10?4 ?·cm, inclusive. The disclosed composition containing carbon nanotubes primarily has double-walled carbon nanotubes with high electrical conductivity and high heat resistance.
    Type: Application
    Filed: March 4, 2010
    Publication date: March 8, 2012
    Inventors: Hidekazu Nishino, Hajime Kato, Naoyo Okamoto, Shuko Ikeuchi, Kenichi Sato, Shiho Tanaka, Kazuyoshi Higuchi
  • Patent number: 8128901
    Abstract: A method of removing metal impurities from carbon nanotubes includes treating carbon nanotubes with distilled bromine in a substantially oxygen- and water-free atmosphere and then removing the distilled bromine from the carbon nanotubes. Purified carbon nanotubes having an iron content from about 2.5 to about 3.5 by weight that are substantially free of derivatization at the ends and defect sites are made available via this method.
    Type: Grant
    Filed: May 7, 2007
    Date of Patent: March 6, 2012
    Assignee: William Marsh Rice University
    Inventors: Yuri Mackeyev, Lon J. Wilson
  • Patent number: 8128900
    Abstract: An atmosphere of a carbon source comprising an oxygenic compound is brought into contact with a catalyst with heating to yield single-walled carbon nanotubes. The carbon source comprising an oxygenic compound preferably is an alcohol and/or ether. The catalyst preferably is a metal. The heating temperature is preferably 500 to 1,500° C. The single-walled carbon nanotubes thus yield contain no foreign substances and have satisfactory quality with few defects.
    Type: Grant
    Filed: February 13, 2003
    Date of Patent: March 6, 2012
    Assignees: Toudai TLO, Ltd., Toray Industries, Inc.
    Inventors: Shigeo Maruyama, Masahito Yoshikawa
  • Patent number: 8129017
    Abstract: A carbon fiber strand obtained by bundling 20,000-30,000 carbon fibers each having, in the surface thereof, creases which are parallel to the fiber-axis direction. In an examination with a scanning probe microscope, the creases in the carbon fiber surface are apart from each other at a distance of 120-160 nm and have a depth of 12-23 nm, excluding 23 nm. The carbon fibers have an average fiber diameter of 4.5-6.5 nm, specific surface area of 0.9-2.3 m2/g, and density of 1.76 g/cm3 or higher. The carbon strand has a tensile strength of 5,900 MPa or higher and a tensile modulus of 300 GPa or higher. When would on a bobbin at a tension of 9.8 N, the strand on the bobbin has a width of 5.5 mm or larger. When the carbon fiber strand is examined by a strand splitting evaluation method in which the strand is caused to run through three stainless-steel rods while applying a tension of 9.8 N thereto, no strand splitting is observed.
    Type: Grant
    Filed: October 31, 2008
    Date of Patent: March 6, 2012
    Assignee: Toho Tenax Co., Ltd.
    Inventors: Hidekazu Yoshikawa, Taro Oyama, Hiroshi Kimura
  • Patent number: 8124228
    Abstract: A carbon fiber strand which is produced by obtaining a solidified-yarn strand by spinning with a spinneret having 20,000-30,000 spinning holes, passing the strand through an interlacing nozzle having an air blowing pressure of 20-60 kPa to obtain precursor fibers, oxidizing them in heated air having a temperature of 200-280° C. to obtain oxidized fibers, subjecting these oxidized fibers to a first carbonization treatment in an inert-gas atmosphere at a temperature of 300-900° C. in which the fibers are firstly stretched in a stretch ratio of 1.03-1.06 and then secondarily stretched in a stretch ratio of 0.9-1.01, subsequently conducting a second carbonization treatment in an inert-gas atmosphere at 1,360-2,100° C., and then conducting a surface oxidization treatment in an aqueous solution of an inorganic acid salt in a quantity of electricity of 20-100 C per g of the carbon fibers.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: February 28, 2012
    Assignee: Toho Tenax Co., Ltd.
    Inventors: Hidekazu Yoshikawa, Taro Oyama, Hiroshi Kimura
  • Patent number: 8124044
    Abstract: Carbon nanotubes, a method for preparing the same and an element using the same are provided. The method for preparing carbon nanotubes includes synthesizing carbon nanotubes from carbon source using an arc-discharge method in the presence of catalysts and promoter, wherein the promoter contains an element capable of reducing the surface energy of carbon nanotubes. Carbon nanotubes with high purity and narrow diameter distribution can thus be prepared.
    Type: Grant
    Filed: September 28, 2009
    Date of Patent: February 28, 2012
    Assignee: Sony Corporation
    Inventors: Hisashi Kajiura, Yongming Li, Liping Huang, Yunqi Liu, Dacheng Wei, Yu Wang, Hongliang Zhang
  • Patent number: 8124043
    Abstract: The present teachings are directed toward a matrix containing nanosized metal components and carbon nanotubes, with the carbon nanotubes being produced in situ by the nanosized metal components upon the contacting of the nanosized metal components with a carbon source under conditions sufficient to produce the carbon nanotubes. Also disclosed are methods of producing the matrix containing the nanosized metal components and carbon nanotubes.
    Type: Grant
    Filed: March 16, 2007
    Date of Patent: February 28, 2012
    Assignee: Honda Motor Co., Ltd.
    Inventors: Avetik Harutyunyan, Elena Mora
  • Publication number: 20120045385
    Abstract: A system is provided that can be utilized to generate nanotubes with substantially similar chirality. The system provides a resonant frequency, keyed to a desired radial breathing mode linked to the desired chirality, that causes a template of catalysts particles or nanotubes to oscillate at the provided resonant frequency, so as to stimulate growing nanotubes to oscillate at a corresponding resonant frequency. This resonant frequency can be a result of a high frequency field or the natural heat radiation generated by the system.
    Type: Application
    Filed: October 28, 2011
    Publication date: February 23, 2012
    Applicant: Nanocomp Technologies, Inc.
    Inventors: David S. Lashmore, Craig Lombard
  • Publication number: 20120047600
    Abstract: The invention provides methods for increasing lignin content in plants by expression of a cinnamoyl CoA reductase 2 (CCR2) coding sequence in the plant. Also provided are methods for reducing lignin content in a plant by down-regulation of CCR2 expression in the plant. Nucleic acid molecules for modulation of CCR2 expression and transgenic plants the same are also provided. Plants described herein may be used, for example, as improved biofuel feedstock and as highly digestible forage crops. Methods for processing plant tissue and for producing biofuels by utilizing such plants are also provided.
    Type: Application
    Filed: July 12, 2011
    Publication date: February 23, 2012
    Inventors: Rui ZHOU, Richard A. DIXON, Fang CHEN
  • Patent number: 8119074
    Abstract: The present invention relates to an apparatus for the continuous production of carbon nanotubes (CNT), as well as the method to carry it out. The apparatus for the CNT synthesis includes: two sets or more of tubes to synthesize in its interior the CNT; a set of nozzles for the same number of tubes that each set has, to feed to the interior of the tubes the precursory chemical compounds of the CNT; a furnace to maintain one of the sets to a suitable temperature to allow the formation of the CNT inside the tubes; a system for the detaching and collection of the CNT formed in the previous stage; and a control system, preferably a PLC (PLC by its abbreviation in English) to program the sequence of activities of the equipment.
    Type: Grant
    Filed: April 21, 2009
    Date of Patent: February 21, 2012
    Assignee: Centro de Investigacion en Materiales Avanzados, S.C
    Inventors: Alfredo Aguilar Elguezabal, Manuel Roman Aguirre, Beatriz Ortega Garcia, Gustavo Vicente Camacho Villarello
  • Patent number: 8119095
    Abstract: The present invention relates to a composite sintering materials using a carbon nanotube (including carbide nano particles, hereinafter the same) and a manufacturing method thereof, the method comprises the steps of: combining or generating carbon nanotubes in metal powers, a compacted product, or a sintered product; growing and alloying the carbon nanotubes by compacting or sintering the metal powers, the compacted product, or the sintered product; and strengthening the mechanical characteristics by repeatedly performing the sintering process and the combining process or the generating process of the carbon nanotubes.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: February 21, 2012
    Assignee: C & Tech Co., Ltd.
    Inventors: Sang-chul Ahn, Sun-hwa Yang, Hyeung-eun Ahn
  • Patent number: 8119093
    Abstract: Disclosed is a thin line having a hollow structure portion composed of a C70 fullerene molecule, which is a novel functional material useful for a capsule for containing various chemical substances, a reaction site, a gas adsorbent, a catalyst supporting material, an electrode material, a semiconductor and the like. Also disclosed is a method for producing the same.
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: February 21, 2012
    Assignee: National Institute for Materials Science
    Inventors: Kun-ichi Miyazawa, Tetsuro Yoshii
  • Publication number: 20120039790
    Abstract: A nanotube separation method includes depositing a tag on a nanotube in a nanotube mixture. The nanotube has a defect and the tag deposits at the defect where a deposition rate is greater than on another nanotube in the mixture lacking the defect. The method includes removing the tagged nanotube from the mixture by using the tag. As one option, the tag may contain a ferromagnetic material and the removing may include applying a magnetic field. As another option, the tag may contain an ionic material and the removing may include applying an electric field. As a further option, the tag may contain an atom having an atomic mass greater than the atomic mass of carbon and the removing may include applying a centrifugal force to the nanotube mixture. Any two or more of the indicated removal techniques may be combined.
    Type: Application
    Filed: October 18, 2011
    Publication date: February 16, 2012
    Applicant: Micron Technology, Inc.
    Inventor: Gurtej S. Sandhu
  • Publication number: 20120037840
    Abstract: Methods and compositions for removing a contaminant from its environment. The method includes forming a magnetic composition comprising the contaminant and an amphiphilic substance, and applying a magnetic field to the magnetic composition so as to separate the magnetic composition from the environment. One composition includes a micelle array confined in a magnetic mesoporous framework. Another composition is formed by adhering an amphiphilic material comprising functional surface groups to a contaminant, then interacting a magnetic material with the functional surface groups of the amphiphilic material. In various versions, the contaminant can be a hydrophobic organic compound, or a fullerene-related nanoparticle. The methods can also be used to purify hydrophobic organic compounds or fullerene-related nanoparticles.
    Type: Application
    Filed: February 25, 2009
    Publication date: February 16, 2012
    Inventors: Galen Stucky, Arturo A. Keller, Yifeng Shi, Peng Wang, Qihui Shi, Hongjun Liang
  • Patent number: 8114373
    Abstract: Disclosed is a method of exfoliating a layered material (e.g., graphite and graphite oxide) to produce nano-scaled platelets having a thickness smaller than 100 nm, typically smaller than 10 nm, and often between 0.34 nm and 1.02 nm. The method comprises: (a) subjecting the layered material in a powder form to a halogen vapor at a first temperature above the melting point or sublimation point of the halogen at a sufficient vapor pressure and for a duration of time sufficient to cause the halogen molecules to penetrate an interlayer space of the layered material, forming a stable halogen-intercalated compound; and (b) heating the halogen-intercalated compound at a second temperature above the boiling point of the halogen, allowing halogen atoms or molecules residing in the interlayer space to exfoliate the layered material to produce the platelets.
    Type: Grant
    Filed: January 4, 2011
    Date of Patent: February 14, 2012
    Inventors: Bor Z. Jang, Aruna Zhamu
  • Publication number: 20120020870
    Abstract: We disclose a process to produce carbon nanotubes from microalgae. Microalgae is been utilized for biodiesel production. The algal membrane resulted from oil extraction of microalgae is used here to produce carbon nanotubes. The process utilized for the conversion is composed of two steps, in the first step the algal membrane is converted to carbon black through a pyrolysis process in inert atmosphere, in the second step the resulted carbon black is converted to carbon nanotubes by mixing the carbon black with a fluid with known self ignition condition and subjecting the mix to said self ignition condition.
    Type: Application
    Filed: September 29, 2011
    Publication date: January 26, 2012
    Applicant: UNITED ARAB EMIRATES UNIVERSITY
    Inventor: Yousef Haik
  • Patent number: 8097361
    Abstract: This invention concerns a novel method for surface derivatization of electrode materials for Li-ion batteries. The derivatization is based on adsorption of a composite assembly consisting of amphiphilic redox active molecule attached to single walled carbon nanotube (SWCNT). Its role consists in the enhancement of electronic conductivity of electrode materials, such as phosphate olivines, without requesting any significant increase of the electrode volume and mass. The SWCNT is linked to the redox molecule via non-covalent or covalent interaction with the hydrophobic part of the molecule or electrostatic interaction. The hydrophilic part of the molecule serves as the anchoring site for surface modification of the electrode active material. The redox potential of the molecule is close to the redox potential of the electrode active material. The adsorbed assembly of redox-molecule & SWCNT thus improves the charge transfer from a current collector to the electrode active material.
    Type: Grant
    Filed: October 18, 2007
    Date of Patent: January 17, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Ivan Exnar, Shaik Mohammed Zakeeruddin, Michael Gratzel, Ladislav Kavan
  • Patent number: 8092774
    Abstract: The present invention is directed toward compositions comprising carbon nanotubes (CNTs) that are sidewall-functionalized with amino acid groups, and to amino acid compositions comprising carbon nanotubes. The present invention is also directed to simple and relatively inexpensive methods for the preparation of such compositions. Such compositions are expected to greatly extend the bio-medical applications of CNTs.
    Type: Grant
    Filed: January 18, 2005
    Date of Patent: January 10, 2012
    Assignee: William Marsh Rice University
    Inventors: Valery N. Khabashesku, Haiqing Peng, John L. Margrave, Mary Lou Margrave, legal representative
  • Patent number: 8093174
    Abstract: A carbon nanohorn (CNH) is oxidized to make an opening in the side of the CNH. A substance to be included, e.g., a metal, is introduced through the opening. The inclusion substance is moved to a tip part of the carbon nanohorn through heat treatment in vacuum or an inert gas. The CNH is further heat treated in an atmosphere containing oxygen in a low concentration to remove the carbon layer in the tip through catalysis of the inclusion substance. This exposes the inclusion substance. If the inclusion substance is a metal which is not moved to a tip part by the heat treatment in vacuum or an inert gas, the carbon part surrounding the fine catalyst particle is specifically burned by a heat treatment in an low oxygen concentration atmosphere, while utilizing the catalysis. Thus, the fine catalyst particle is fixed to the tip part of the CNH.
    Type: Grant
    Filed: January 16, 2008
    Date of Patent: January 10, 2012
    Assignee: NEC Corporation
    Inventors: Ryota Yuge, Masako Yudasaka, Sumio Iijima
  • Patent number: 8092775
    Abstract: Provided is a continuous method and apparatus for purifying carbon nanotubes. Carbon nanotube is fed together with solvent into a preheater via a heat exchanger to produce a carbon nanotube mixture. The carbon nanotube mixture is preheated at 100 to 370° C. Then, the carbon nanotube mixture is purified in a purifying reactor under a subcritical water condition of 50 to 400 atm. The resulting purified product is cooled down to 0 to 100° C. and depressurized into 1 to 10 atm by feeding the purified product into a cooling down and depressurizing part via the heat exchanger. Finally, the cooled and depressurized product is recovered.
    Type: Grant
    Filed: September 29, 2009
    Date of Patent: January 10, 2012
    Assignee: Hanwha Chemical Corporation
    Inventors: Joo Hee Han, Jin Seo Lee, Seung-Hoe Do, Seong Cheol Hong
  • Patent number: 8092778
    Abstract: A method for producing a hydrogen enriched fuel and carbon nanotubes includes the steps of providing a flow of methane gas, and providing a catalyst mixture comprising a Fe based catalyst and carbon. The method also includes the steps of pretreating the catalyst mixture using microwave irradiation and exposure to CH4, heating the catalyst mixture and the methane gas using microwave irradiation at a selected microwave power, directing the flow of methane gas over the catalyst mixture, and controlling the microwave power to produce a product gas having a selected composition and the carbon nanotubes. For producing multi walled carbon nanotubes (MWNTs) only a flow of methane gas into the reactor is required. For producing single walled carbon nanotubes (SWNTs), a combination of hydrogen gas and methane gas into the reactor is required.
    Type: Grant
    Filed: March 1, 2008
    Date of Patent: January 10, 2012
    Assignee: Eden Energy Ltd.
    Inventors: Zhonghua John Zhu, Jiuling Chen, Gaoqing Max Lu, Gregory Solomon
  • Patent number: 8088352
    Abstract: A composition of matter including at least one graphitic-carbon-nanofiber/polymer brush. A method of making the graphitic-carbon-nanofiber/polymer brush includes covalently bonding a polymer to a surface of a graphitic-carbon-nanofiber by atom-transfer-radical-polymerization. An apparatus includes an analyte sensor including at least one graphitic-carbon-nanofiber/polymer brush. A method includes detecting an analyte including exposing at least one graphitic-carbon-nanofiber/polymer brush to the analyte.
    Type: Grant
    Filed: November 28, 2007
    Date of Patent: January 3, 2012
    Assignee: Vanderbilt University
    Inventors: Charles Martin Lukehart, Lang Li
  • Patent number: 8083905
    Abstract: The internal and external walls of the carbon nanotubes are doped with nano-sized metallic catalyst particles uniformly to a degree of 0.3-5 mg /cm2. The carbon nanotubes are grown over a carbon substrate using chemical vapor deposition or plasma enhanced chemical vapor deposition. Since the carbon nanotubes have a large specific surface area, and metallic catalyst particles are uniformly distributed over the internal and external walls thereof, the reaction efficiency in an electrode becomes maximal when the carbon nanotubes are used for the electrode of a fuel cell. The carbon nanotubes fabricated using the method can be applied to form a large electrode. The carbon nanotubes grown over the carbon substrate can be readily applied to an electrode of a fuel cell, providing economical advantages and simplifying the overall electrode manufacturing process. A fuel cell using as the carbon nanotubes for its electrode provides improved performance.
    Type: Grant
    Filed: July 29, 2009
    Date of Patent: December 27, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Won-bong Choi, Jae-uk Chu, Chan-ho Pak, Hyuk Chang
  • Patent number: 8083970
    Abstract: The present invention relates to electroconductive inks and methods of making and using the same. The electroconductive inks include carbon fibrils and a liquid vehicle. The electroconductive ink may further include a polymeric binder. The electroconductive filler used is carbon fibrils which may be oxidized. The ink has rheological properties similar to that of commercially available electroconductive inks that use carbon black as their filler. The ink can be screen-printed, slot-coated, sprayed, brushed or dipped onto a wide variety of substrates to form an electroconductive coating.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: December 27, 2011
    Assignee: Hyperion Catalysis International, Inc.
    Inventors: Jun Ma, Alan Fischer, Chunming Niu, Lein Ngaw
  • Patent number: 8084927
    Abstract: A thermal electron emitter includes at least one carbon nanotube twisted wire and a plurality of electron emission particles mixed with the twisted wire. The carbon nanotube twisted wire comprises a plurality of carbon nanotubes. A work function of the electron emission particles is lower than the work function of the carbon nanotubes. A thermal electron emission device using the thermal electron emitter is also related.
    Type: Grant
    Filed: March 12, 2009
    Date of Patent: December 27, 2011
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Lin Xiao, Liang Liu, Chang-Hong Liu, Shou-Shan Fan
  • Patent number: 8084011
    Abstract: A carbon nanotube manufacturing method wherein a catalyst is heated in a reaction chamber while the reaction chamber is filled with argon gas containing hydrogen. When a predetermined temperature is reached in the reaction chamber, the reaction chamber is evacuated. Then a raw material gas as a carbon source is charged and sealed in the reaction chamber whereupon the synthesis of carbon nanotube begins. Subsequently, when a condition in which the synthesis of carbon nanotubes has proceeded to a predetermined level is detected, gases in the reaction chamber are exhausted. Then, the raw material gas is changed and sealed in the reaction tube again. Thereafter, the charging (synthesizing) operation and the exhausting operation are repeated until the carbon nanotube with a desired film thickness are synthesized. A carbon nanotube manufacturing apparatus is also disclosed.
    Type: Grant
    Filed: December 7, 2007
    Date of Patent: December 27, 2011
    Assignee: DENSO CORPORATION
    Inventors: Yoshinobu Suzuki, Shinichi Mukainakano, Kenji Okeyui, Toshiyuki Morishita, Hisayoshi Ooshima
  • Publication number: 20110305625
    Abstract: A method for making semiconducting carbon nanotubes is provided. A catalyst precursor is disposed on a substrate. The catalyst precursor includes blood. Organic substances contained in the blood are removed and iron ions contained in the blood are oxidized to yield discrete ferric oxide nano-particles on the substrate. The ferric oxide nano-particles are reduced to yield isolated iron nano-particles on the substrate. Carbon nanotubes then grow on the iron nano-particles.
    Type: Application
    Filed: November 23, 2010
    Publication date: December 15, 2011
    Applicants: HON HAI PRECISION INDUSTRY CO., LTD., TSINGHUA UNIVERSITY
    Inventors: XUE-SHEN WANG, QUN-QING LI, SHOU-SHAN FAN
  • Patent number: 8075864
    Abstract: Provided are a graphene sheet and a process of preparing the same. Particularly, a process of economically preparing a large-area graphene sheet having a desired thickness and a graphene sheet prepared by the process are provided.
    Type: Grant
    Filed: July 7, 2008
    Date of Patent: December 13, 2011
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Jae-young Choi, Hyeon-Jin Shin, Seon-mi Yoon
  • Publication number: 20110300056
    Abstract: A process for the production of nano-structures is presented, involving providing a graphite flake comprising graphene layers; intercalating the graphite flake to form a graphite intercalation compound exhibiting Stage I, II or III intercalation; and exfoliating the graphite intercalation compound by exposing it to a temperature between about 1600° C. and about 2400° C. such that a plurality of individual graphene layers are separated from the graphite intercalation compound.
    Type: Application
    Filed: June 7, 2010
    Publication date: December 8, 2011
    Inventor: Robert Angelo Mercuri
  • Publication number: 20110300057
    Abstract: A process for the production of nano-structures is presented, involving providing a graphite flake comprising graphene layers; intercalating the graphite flake by non-contact intercalation to form a graphite intercalation compound exhibiting Stage I, II or III intercalation; and exfoliating the graphite intercalation compound by bringing it to a temperature between about 1600° C. and about 2400° C. such that a plurality of individual graphene layers are separated from the graphite intercalation compound.
    Type: Application
    Filed: June 7, 2010
    Publication date: December 8, 2011
    Inventor: Robert Angelo Mercuri
  • Patent number: 8071216
    Abstract: In the bundle of long thin carbon structures of the present invention, end parts of the bundle are interconnected in a carbon network. The interconnected end parts form a flat surface. By this, an electrical connection structure with low resistance and/or a thermal connection structure with high thermal conductivity are obtained. The bundle of long thin carbon structures can be used suitably as a via, heat removal bump or other electronic element.
    Type: Grant
    Filed: December 3, 2007
    Date of Patent: December 6, 2011
    Assignee: Fujitsu Limited
    Inventor: Daiyu Kondo
  • Patent number: 8067091
    Abstract: A method for preparing resin-impregnated graphite articles, including providing a sheet of compressed particles of exfoliated graphite having two major surfaces; impregnating the sheet with a first resin system to form a resin-impregnated sheet; surface treating the resin-impregnated sheet to form at least one structure on at least one of the major surfaces of the sheet to form a surface treated sheet; and treating the sheet with a second resin system.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: November 29, 2011
    Assignee: GrafTech International Holdings Inc.
    Inventors: Zdenka Brunovska, Bradley E. Reis, Jeffrey J. Gough, Lawrence K. Jones, Thomas W. Weber, David J. Stuart, Suha M. Yazici, Jeremy Klug, Franco Frate
  • Publication number: 20110287258
    Abstract: A method for dispersing nanotubes, comprising contacting the nanotubes with an electronic liquid comprising a metal and an amine solvent, a solution of dispersed nanotuhes, comprising individual nanotuhes at a concentration of greater than about 0.01 mgml?1 and a solvent and a nanotube crystal comprising a close packed array of nanotubes, wherein the crystal has a thickness of 100 nm or more are described.
    Type: Application
    Filed: July 3, 2009
    Publication date: November 24, 2011
    Applicants: IMPERIAL INNOVATIONS LTD., UCL BUSINESS PLC
    Inventors: Christopher Howard, Skipper Neal, Milo Shaffer, Sian Fogden
  • Patent number: 8062748
    Abstract: In some embodiments, the present invention is directed to methods of fully integrating CNTs and the surrounding polymer matrix in CNT/polymer composites. In some such embodiments, such integration comprises interfacial covalent bonding between the CNTs and the polymer matrix. In some such embodiments, such interfacial covalent bonding is provided by a free radical reaction initiated during processing. In some such embodiments, such free radical initiation can be provided by benzoyl peroxide. In some or other embodiments, the present invention is directed to CNT/polymer composite systems, wherein the CNTs within such systems are covalently integrated with the polymer. In some or other embodiments, the present invention is directed to articles of manufacture made from such CNT/polymer composite systems.
    Type: Grant
    Filed: July 22, 2009
    Date of Patent: November 22, 2011
    Assignee: William Marsh Rice University
    Inventors: Valery N. Khabashesku, Enrique V. Barrera, Daneesh McIntosh, Laura Peña-Paras
  • Publication number: 20110280791
    Abstract: To provide a method for separating metallic CNT and semiconducting CNT by treating a CNT-containing gel or a CNT dispersion as combined with a gel, according to a physical separation means to thereby make semiconducting CNT exist in gel and metallic CNT exist in solution, in which the semiconducting CNT adsorbed by gel are collected in a more simplified manner not dissolving the gel. A CNT-containing gel or a CNT dispersion combined with a gel is treated according to a physical separation means of a centrifugal method, a freezing squeezing method, a diffusion method or a permeation method, to thereby make semiconducting CNT exist in gel and metallic CNT exist in solution so that the metallic CNT and the semiconducting CNT are separated from each other, and further, a suitable eluent is made to react on the gel that adsorbs semiconducting CNT to elute the semiconducting CNT from the gel.
    Type: Application
    Filed: June 22, 2010
    Publication date: November 17, 2011
    Inventors: Takeshi Tanaka, Hiromichi Kataura, Huaping Liu
  • Patent number: 8057776
    Abstract: We disclose a process to produce carbon nanotubes from microalgae. Microalgae is been utilized for biodiesel production. The algal membrane resulted from oil extraction of microalgae is used here to produce carbon nanotubes. The process utilized for the conversion is composed of two steps, in the first step the algal membrane is converted to carbon black through a pyrolysis process in inert atmosphere, in the second step the resulted carbon black is converted to carbon nanotubes by mixing the carbon black with a fluid with known self ignition condition and subjecting the mix to said self ignition condition.
    Type: Grant
    Filed: December 26, 2009
    Date of Patent: November 15, 2011
    Assignee: United Arab Emirates University
    Inventor: Yousef Haik
  • Patent number: 8057777
    Abstract: A system is provided that can be utilized to generate nanotubes with substantially similar chirality. The system provides a resonant frequency, keyed to a desired radial breathing mode linked to the desired chirality, that causes a template of catalysts particles or nanotubes to oscillate at the provided resonant frequency, so as to stimulate growing nanotubes to oscillate at a corresponding resonant frequency. This resonant frequency can be a result of a high frequency field or the natural heat radiation generated by the system.
    Type: Grant
    Filed: July 25, 2008
    Date of Patent: November 15, 2011
    Assignee: Nanocomp Technologies, Inc.
    Inventors: David S. Lashmore, Craig Lombard
  • Patent number: 8057686
    Abstract: A nanotube separation method includes depositing a tag on a nanotube in a nanotube mixture. The nanotube has a defect and the tag deposits at the defect where a deposition rate is greater than on another nanotube in the mixture lacking the defect. The method includes removing the tagged nanotube from the mixture by using the tag. As one option, the tag may contain a ferromagnetic material and the removing may include applying a magnetic field. As another option, the tag may contain an ionic material and the removing may include applying an electric field. As a further option, the tag may contain an atom having an atomic mass greater than the atomic mass of carbon and the removing may include applying a centrifugal force to the nanotube mixture. Any two or more of the indicated removal techniques may be combined.
    Type: Grant
    Filed: March 2, 2007
    Date of Patent: November 15, 2011
    Assignee: Micron Technology, Inc.
    Inventor: Gurtej S. Sandhu
  • Patent number: 8057778
    Abstract: The present disclosure relates to a method for forming a carbon nanotube array. In the method a tubular substrate is provided. The tubular substrate includes an outer sidewall with a catalyst layer located on the outer sidewall. The heating member, and the tubular substrate with the catalyst layer is received in a reacting chamber. The tubular substrate is heated by the heating member. A carbon source gas is supplied into the reacting chamber to grow the carbon nanotube array on the tubular substrate.
    Type: Grant
    Filed: August 13, 2010
    Date of Patent: November 15, 2011
    Assignee: Beijing FUNATE Innovation Technology Co., Ltd.
    Inventors: Chen Feng, Liang Liu
  • Publication number: 20110274611
    Abstract: A method for removing impurities from carbon nanotubes is described. Impurities may be removed from the carbon nanotubes by exposing the carbon nanotubes to a temperature, and controlling the temperature such that the temperature is constantly increasing to remove at least a portion of the impurities from the carbon nanotubes.
    Type: Application
    Filed: November 11, 2009
    Publication date: November 10, 2011
    Applicant: Temple University - of the Commonwealth System of Higher Education
    Inventors: Nikolay N. Dementev, Eric U. Borguet
  • Patent number: 8052952
    Abstract: Provided is a nanotube-polymer composite which can effectively utilize characteristics of a carbon nanotube structure. The composite includes a carbon nanotube structure and a polymer, in which: the carbon nanotube structure has a network structure constructed by mutually cross-linking functional groups bonded to multiple carbon nanotubes through chemical bonding of the functional groups together; and the polymer is filled in the network structure.
    Type: Grant
    Filed: February 1, 2010
    Date of Patent: November 8, 2011
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Miho Watanabe, Kentaro Kishi, Chikara Manabe, Kazunori Anazawa, Masaki Hirakata, Taishi Shigematsu, Hiroyuki Watanabe, Takashi Isozaki, Shigeki Ooma, Shinsuke Okada
  • Patent number: 8052940
    Abstract: Provided are an apparatus for synthesizing carbon nanotubes, the apparatus including a reaction tube that provides a space for carbon nanotubes and is formed vertically long, a heating unit that is formed at the outer side of the reaction tube, and heats the reaction tube, a gas-supply unit that sprays reaction gas for synthesizing the carbon nanotubes by reacting with catalysts positioned inside the reaction tube, an exhaustion unit that is connected to the upper portion of the reaction tube, and discharges non-reacted reaction gas for synthesizing the carbon nanotubes, and a blocking unit that is formed inside the reaction tube, discharges only the non-reacted reaction gas for synthesizing the carbon nanotubes to the exhaustion unit, and blocks the discharge of the carbon nanotubes and catalysts, in which the cross-section of the blocking unit is divided in a plurality of polygon structures, and downward-slanted blocking wings are formed at each divided cell.
    Type: Grant
    Filed: September 29, 2009
    Date of Patent: November 8, 2011
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Chung-Heon Jeong, Jong-Kwan Jeon, Suk-Won Jang
  • Patent number: 8052951
    Abstract: Disclosed are structures formed as bulk support media having carbon nanotubes formed therewith. The bulk support media may comprise fibers or particles and the fibers or particles may be formed from such materials as quartz, carbon, or activated carbon. Metal catalyst species are formed adjacent the surfaces of the bulk support material, and carbon nanotubes are grown adjacent the surfaces of the metal catalyst species. Methods employ metal salt solutions that may comprise iron salts such as iron chloride, aluminum salts such as aluminum chloride, or nickel salts such as nickel chloride. Carbon nanotubes may be separated from the carbon-based bulk support media and the metal catalyst species by using concentrated acids to oxidize the carbon-based bulk support media and the metal catalyst species.
    Type: Grant
    Filed: April 3, 2009
    Date of Patent: November 8, 2011
    Assignee: UT-Battelle, LLC
    Inventors: Paul A. Menchhofer, Frederick C. Montgomery, Frederick S. Baker
  • Publication number: 20110268646
    Abstract: The present invention discloses a preparation method of carbon nanotube by decomposing the polymer with hydrotalcite as a catalyst, which belongs to the field of preparation technology of carbon nanotube (CNT). The technical solution of the present invention are as below: firstly, the hydrotalcite with the particle size at nanometer or sub-micron level is prepared, and then is added into the polymer. After the calcination process at high temperature and a treatment with acid, the nano-scale CNT can be obtained. The CNTs prepared by the method supplied in this invention not only have the advantages including high yield, uniform diameter, few structural defects, low impurity content, low cost and simple preparation process, which is suitable for large-scale industrial production, but also can solve the problem of recirculation of waste plastics and utilization of the resource.
    Type: Application
    Filed: January 12, 2010
    Publication date: November 3, 2011
    Applicant: BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY
    Inventors: Fazhi Zhang, Lixia Zhang, Xiaodong Lei, Rushi Li, Sailong Xu, Xue Duan
  • Patent number: 8048395
    Abstract: Provided are a method of coating a catalyst metal layer by using a nucleic acid, and a method of forming nanocarbon using the method of coating a catalyst metal layer. The method of coating a catalyst metal layer includes preparing an aqueous solution; the aqueous solution including ions of a transition metal and a nucleic acid; disposing a carbon matrix including carbon, in the aqueous solution, and disposing a catalyst metal layer including a transition metal on a surface of the carbon matrix.
    Type: Grant
    Filed: August 12, 2009
    Date of Patent: November 1, 2011
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Jeong-na Heo, Ho-suk Kang, Yong-chul Kim, Yoon-chul Son