Fiber, Fabric, Or Textile Patents (Class 423/447.1)
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Publication number: 20140210125Abstract: A method includes the following steps. An original carbon nanotube film is provided. The original carbon nanotube film includes a plurality of carbon nanotubes substantially oriented along a first direction. The original carbon nanotube film is suspended. The suspended original carbon nanotube film is soaked with an atomized organic solvent to shrink into a carbon nanotube film. Wherein the atomized organic solvent comprises a plurality of dispersed organic droplets with diameters of larger than or equal to 10 micrometers, and less than or equal to 100 micrometers.Type: ApplicationFiled: June 26, 2013Publication date: July 31, 2014Inventors: YU-QUAN WANG, LI QIAN
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Patent number: 8785343Abstract: This invention relates to a mesoporous carbon supported copper based catalyst comprising mesoporous carbon, a copper component and an auxiliary element supported on said mesoporous carbon, production and use thereof. The catalyst is cheap in cost, friendly to the environment, and satisfactory in high temperature resistance to sintering, with a highly improved and a relatively stable catalytic activity.Type: GrantFiled: August 27, 2012Date of Patent: July 22, 2014Assignees: China Petroleum & Chemical Corp., Sinopec Yangzi Petrochemical Co., Ltd.Inventors: Jingwei Liu, Zezhuang Li, Shaohui Chen, Aiwu Yang, Jiye Bai, Lijuan Liu, Yingwu Wang
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Publication number: 20140199229Abstract: The present invention generally relates to compositions, methods, and systems for separating carbon-based nanostructures.Type: ApplicationFiled: March 14, 2013Publication date: July 17, 2014Applicant: Massachusetts Institute of TechnologyInventors: Michael S. Strano, Thomas P. McNicholas, Andrew J. Hilmer, Rishabh M. Jain, Kevin C. Tvrdy
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Publication number: 20140199855Abstract: A method for making a carbon nanotube film includes the steps of: (a) adding a plurality of carbon nanotubes to a solvent to create a carbon nanotube floccule structure in the solvent; (b) separating the carbon nanotube floccule structure from the solvent; and (c) shaping the separated carbon nanotube floccule structure to obtain the carbon nanotube film.Type: ApplicationFiled: December 20, 2007Publication date: July 17, 2014Applicants: HON HAI Precision Industry CO., LTD., Tsinghua UniversityInventors: Ding Wang, Chang-Hong Liu, Shou-Shan Fan
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Patent number: 8778478Abstract: Provided is an assembly including a block co-polymer film and a plurality of nano-rods; where the plurality of nano-rods are oriented at the surface of the block co-polymer film, substantially perpendicular to at least one interface between block co-polymer domains. Further provided are methods of assembly formation and devices including such assemblies.Type: GrantFiled: February 4, 2010Date of Patent: July 15, 2014Assignee: Yissum Research Development Company of the Hebrew University of Jerusalem, Ltd.Inventors: Roy Shenhar, Uri Banin, Elina Ploshnik, Asaf Salant
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Patent number: 8778296Abstract: A dispersible carbon nanotube (“CNT”) comprising a CNT backbone and an organic moiety attached to the carbon nanotube backbone and comprising a hydroxyl substituted C6 to C14 aromatic group are described, as well as a CNT-polymer composite and a method of manufacturing the CNT-polymer composite.Type: GrantFiled: October 13, 2009Date of Patent: July 15, 2014Assignees: Samsung Electronics Co., Ltd., Korea Advanced Institute of Science and TechnologyInventors: Jong-jin Park, Tae-gwan Park, Yu-han Lee, Kwang-hee Lee
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Publication number: 20140191165Abstract: Provided are a method for post-treatment of a carbonaceous material using dehydrocyclization, a carbonaceous material post-treated by the method, and a polymer composite material including the carbonaceous material. More particularly, provided are a method for post-treatment of a carbonaceous material using dehydrocyclization, including subjecting the carbonaceous material to dehydrocyclization at room temperature to heal structural defects in the carbonaceous material, while increasing the effective conjugated length of the carbonaceous material to improve the electrical conductivity thereof, as well as a carbonaceous material post-treated by the method and a polymer composite material including the carbonaceous material.Type: ApplicationFiled: March 12, 2013Publication date: July 10, 2014Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Munju GOH, Ok-kyung PARK, Yong Mun CHOI, Bon-Cheol KU, Joong Hee LEE, Nam Ho YOU, Han Sol YOU
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Publication number: 20140194645Abstract: The present technology provides a carbon fiber reinforced plastic that includes carbon fibers covalently bonded to an energetic polymer and a polymer matrix. Also described is a method for recycling carbon fibers from the carbon fiber reinforced plastic material using microwave energy to separate the carbon fibers from the polymer matrix.Type: ApplicationFiled: August 10, 2012Publication date: July 10, 2014Inventors: Kraig Anderson, Angele Sjong
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Patent number: 8771630Abstract: A method for the preparation of graphene is provided, which includes: (a) oxidizing a graphite material to form graphite oxide; (b) dispersing graphite oxide into water to form an aqueous suspension of graphite oxide; (c) adding a dispersing agent to the aqueous suspension of graphite oxide; and (d) adding an acidic reducing agent to the aqueous suspension of graphite oxide, wherein graphite oxide is reduced to graphene by the acidic reducing agent, and graphene is further bonded with the dispersing agent to form a graphene dispersion containing a surface-modified graphene. The present invention provides a method for the preparation of graphene using an acidic reducing agent. The obtained graphene can be homogeneously dispersed in water, an acidic solution, a basic solution, or an organic solution.Type: GrantFiled: January 26, 2012Date of Patent: July 8, 2014Assignee: Enerage, Inc.Inventors: Yi-Shuen Wu, Cheng-Yu Hsieh, Cheng-Shu Peng, Jing-Ru Chen, Jun-Meng Lin, Geng-Wei Lin
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Patent number: 8771822Abstract: Methods for growing a three-dimensional nanorod network in three-dimensional growth spaces, including highly confined spaces, are provided. The methods are derived from atomic layer deposition (ALD) processes, but use higher temperatures and extended pulsing and/or purging times. Through these methods, networks of nanorods can be grown uniformly along the entire inner surfaces of confined growth spaces.Type: GrantFiled: January 18, 2011Date of Patent: July 8, 2014Assignee: Wisconsin Alumni Research FoundationInventors: Xudong Wang, Jian Shi
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Patent number: 8771628Abstract: Certain applicator liquids and method of making the applicator liquids are described. The applicator liquids can be used to form nanotube films or fabrics of controlled properties. An applicator liquid for preparation of a nanotube film or fabric includes a controlled concentration of nanotubes dispersed in a liquid medium containing water. The controlled concentration is sufficient to form a nanotube fabric or film of preselected density and uniformity.Type: GrantFiled: November 4, 2009Date of Patent: July 8, 2014Assignee: Nantero Inc.Inventors: Ramesh Sivarajan, Thomas Rueckes, Rahul Sen, Brent M. Segal, Eliodor G. Ghenciu, Jonathan W. Ward, Tzong-Ru T. Han
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Patent number: 8771623Abstract: Residual impurity reduction methods and apparatus are provided. A method comprises conducting a gaseous stream through an unlined portion of a pipe, wherein the gaseous stream comprises sodium and wherein the unlined portion of the pipe is at least about eighteen inches long, injecting a neutralizing agent into the gaseous stream at an injection point, wherein the injection point is located at a point where the sodium is in at least a partially condensed state. The gaseous stream is conducted through a heated portion of a pipe and a cooled portion of a pipe. In addition, methods and apparatus may include a trap system for use with a carbonization furnace.Type: GrantFiled: October 30, 2009Date of Patent: July 8, 2014Assignee: Goodrich CorporationInventors: Tim Centa, Greg Hawkins, Doug Hayes
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Patent number: 8758716Abstract: An atmosphere of a carbon source comprising an oxygenic compound is brought into contact with a catalyst with heating to yield single-walled carbon nanotubes. The carbon source comprising an oxygenic compound preferably is an alcohol and/or ether. The catalyst preferably is a metal. The heating temperature is preferably 500 to 1,500° C. The single-walled carbon nanotubes thus obtained contain no foreign substances and have satisfactory quality with few defects.Type: GrantFiled: February 17, 2012Date of Patent: June 24, 2014Assignees: Toudai Tlo, Ltd., Toray Industries, IncInventors: Shigeo Maruyama, Masahito Yoshikawa
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Patent number: 8758717Abstract: A method of cutting, thinning, welding and chemically functionalizing multiwalled carbon nanotubes (CNTs) with carboxyl and allyl moieties, and altering the electrical properties of the CNT films by applying high current densities combined with air-exposure is developed and demonstrated. Such welded high-conductance CNT networks of functionalized CNTs could be useful for device and sensor applications, and may serve as high mechanical toughness mat fillers that are amenable to integration with nanocomposite matrices.Type: GrantFiled: October 18, 2007Date of Patent: June 24, 2014Assignee: Rensselaer Polytechnic InstituteInventors: Ramanath Ganapathiraman, Saurabh Agrawal, Raghuveer S. Makala
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Patent number: 8753602Abstract: A method of forming a carbon nanotube array on a substrate is disclosed. One embodiment of the method comprises depositing a composite catalyst layer on the substrate, oxidizing the composite catalyst layer, reducing the oxidized composite catalyst layer, and growing the array on the composite catalyst layer. The composite catalyst layer may comprise a group VIII element and a non-catalytic element deposited onto the substrate from an alloy. In another embodiment, the composite catalyst layer comprises alternating layers of iron and a lanthanide, preferably gadolinium or lanthanum. The composite catalyst layer may be reused to grow multiple carbon nanotube arrays without additional processing of the substrate. The method may comprise bulk synthesis by forming carbon nanotubes on a plurality of particulate substrates having a composite catalyst layer comprising the group VIII element and the non-catalytic element. In another embodiment, the composite catalyst layer is deposited on both sides of the substrate.Type: GrantFiled: April 11, 2007Date of Patent: June 17, 2014Assignee: University of CincinnatiInventors: Vesselin N. Shanov, Andrew Gorton, Yeo-Heung Yun, Mark J. Schulz
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Patent number: 8753543Abstract: The present invention provides a chemically functionalized submicron graphitic fibril having a diameter or thickness less than 1 ?m, wherein the fibril is free of continuous thermal carbon overcoat, free of continuous hollow core, and free of catalyst. The fibril is obtained by splitting a micron-scaled carbon fiber or graphite fiber along the fiber axis direction. These functionalized graphitic fibrils exhibit exceptionally high electrical conductivity, high thermal conductivity, high elastic modulus, high strength and good interfacial bonding with a matrix resin in a composite. The present invention also provides several products that contain submicron graphitic fibrils: (a) paper, thin-film, mat, and web products; (b) rubber or tire products; (c) energy conversion or storage devices, such as fuel cells, lithium-ion batteries, and supercapacitors; (d) adhesives, inks, coatings, paints, lubricants, and grease products; (e) heavy metal ion scavenger; (f) absorbent (e.g.Type: GrantFiled: July 16, 2010Date of Patent: June 17, 2014Assignee: Nanotek Instruments, Inc.Inventors: Aruna Zhamu, Bor Z. Jang
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Patent number: 8753603Abstract: A method of synthesizing carbon nanotubes. In one embodiment, the method includes the steps of: (a) dissolving a first amount of a first transition-metal salt and a second amount of a second transition-metal salt in water to form a solution; (b) adding a third amount of tannin to the solution to form a mixture; (c) heating the mixture to a first temperature for a first duration of time to form a sample; and (d) subjecting the sample to a microwave radiation for a second duration of time effective to produce a plurality of carbon nanotubes.Type: GrantFiled: March 22, 2011Date of Patent: June 17, 2014Assignee: Board of Trustees of the University of ArkansasInventor: Tito Viswanathan
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Publication number: 20140161711Abstract: A furnace to flame-resistantly treat a precursor fiber strand by sending hot air to a heat treatment chamber through a hot air blowing nozzle in a direction parallel to a running direction of the strand is provided. The hot air passes through a porous plate and a rectifying member satisfying the following conditions: (1) AB?4.0; (2) 0.15???0.35; (3) 0?B?d?20; and (4) 80% or more of the area of one opening of the porous plate when facing surfaces of the porous plate and the rectifying member overlap is included in one opening of the rectifying member, where A is the rectifying member hot air passage distance (mm), B is a horizontal maximum distance (mm) of one opening of the rectifying member, ? is a rate of hole area of the porous plate, and d is the porous plate equivalent diameter (mm).Type: ApplicationFiled: July 26, 2012Publication date: June 12, 2014Applicant: Mitsubishi Rayon Co., Ltd.Inventors: Satoshi Kaji, Nobuyuki Yamamoto, Atsushi Kawamura, Hitoshi Tomobe
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Patent number: 8747799Abstract: The present invention relates to a method of forming single-walled carbon nanotubes. The method comprises contacting a gaseous carbon source with mesoporous TUD-1 silicate at suitable conditions. The mesoporous TUD-1 silicate comprises a metal of groups 3-13 of the Periodic Table of the Elements.Type: GrantFiled: July 5, 2010Date of Patent: June 10, 2014Assignee: Nanyang Technological UniversityInventors: Yuan Chen, Yanhui Yang
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Patent number: 8743546Abstract: The sheet structure includes a plurality of linear structure bundles 12 each of which comprises a plurality of linear structures of carbon atoms arranged, spaced from each other at a first gap and which are arranged at a second gap which is larger than the first gap; and a filling layer 14 filled in the first gap and the second gap and supporting the plurality of linear structure bundles 12.Type: GrantFiled: October 21, 2008Date of Patent: June 3, 2014Assignee: Fujitsu LimitedInventors: Taisuke Iwai, Daiyu Kondo, Yoshitaka Yamaguchi, Ikuo Soga, Shinichi Hirose
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Publication number: 20140147372Abstract: An electrostatic printing method such as laser printing can be employed for cost-effective and scalable patterning of nanostructure growth catalysts onto growth substrates, either directly or via one or more transfer substrates. Particles comprising a nanostructure growth catalyst are deposited onto the substrate in an electrostatically defined growth pattern. Another aspect of the method includes pressing a mixture of a nanostructure growth catalyst and a binder against the substrate to bond the mixture to the substrate. Nanostructures are grown from the deposited pattern in known nanostructure growth environments. The method allows a user to define a nanostructure growth pattern using familiar, user-friendly computer programs such as word processors, CAD, or other graphics software. Carbon nanotube forests can be grown from magnetic ink character recognition (MICR) toner printed on or transferred to the substrate.Type: ApplicationFiled: November 26, 2013Publication date: May 29, 2014Inventors: Anastasios John Hart, Erik Polsen
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Publication number: 20140147366Abstract: The invention relates to a process for producing carbon fibres, in which polyacrylonitrile (PAN) is pyrolytically carbonized with liberation of hydrocyanic acid (HCN) to form carbon fibres and also a plant for carrying out the process. It is an object of the invention to make the process more economical. This is achieved by utilization of the hydrocyanic acid as material by collecting the hydrocyanic acid liberated and scrubbing it by means of an alkaline medium to give a liquor containing cyanide salt.Type: ApplicationFiled: April 19, 2012Publication date: May 29, 2014Applicant: EVONIK DEGUSSA GmbHInventor: Matthias Berghahn
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Patent number: 8728430Abstract: The present disclosure is directed to a method for producing SWCNT from endothermic carbon-containing feedstock, such as, methane gas, using an activated alumina supported Fe:Mo catalyst. The SWCNT growth temperature is less than about 560° C., and the catalyst is activated by exposure to a reducing atmosphere at a temperature greater than about 900° C.Type: GrantFiled: June 18, 2009Date of Patent: May 20, 2014Assignee: Honda Motor Co., Ltd.Inventors: Elena Mora, John M. Pigos, Avetik R. Harutyunyan
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Patent number: 8715608Abstract: A method for synthesizing carbon nanotubes having a narrow distribution of diameter and/or chirality is presented. The method comprises providing catalyst particles to a reactor for synthesizing the carbon nanotubes, wherein the catalyst particles are characterized by a narrow distribution of catalyst-particle diameters and a narrow distribution of catalyst-particle compositions. Preferably, the catalyst particles are characterized by a mean catalyst-particle diameter of 2.6 nm or less and a composition of NixFe1-x, wherein x is less than or equal to 0.5.Type: GrantFiled: November 29, 2010Date of Patent: May 6, 2014Assignee: Case Western Reserve UniversityInventors: R. Mohan Sankaran, Wei-Hung Chiang
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Device for Manufacturing Recycled Carbon Fibers, and Method for Manufacturing Recycled Carbon Fibers
Publication number: 20140120026Abstract: The purpose of the present invention is to provide a manufacturing device and a manufacturing method that use carbon fiber reinforced plastic (CFRP) as a source material for the efficient, low-cost manufacture of recycled carbon fibers exhibiting excellent ease of handling. A device for manufacturing recycled carbon fibers is provided with: a dry distillation-carbonization furnace (101) having a box-shaped main body (105), a dry distillation-carbonization chamber (102) which accommodates CFRP (40), a combustion chamber (103) equipped with a burner (104), and a heating chamber (115) formed in the space between the main body (105) and the dry distillation-carbonization chamber (102); and a continuous furnace (26) that continuously heats the CFRP (25) after dry distillation and removes a portion of the fixed carbon.Type: ApplicationFiled: August 29, 2012Publication date: May 1, 2014Applicant: Carbon Fiber Recycle Industry Ltd.Inventors: Hidehito Itazu, Hajime Kanki -
Patent number: 8709133Abstract: The invention concerns carbon molecular sieve membranes (“CMS membranes”), and more particularly the use of such membranes in gas separation. In particular, the present disclosure concerns an advantageous method for producing CMS membranes with desired selectivity and permeability properties. By controlling and selecting the oxygen concentration in the pyrolysis atmosphere used to produce CMS membranes, membrane selectivity and permeability can be adjusted. Additionally, oxygen concentration can be used in conjunction with pyrolysis temperature to further produce tuned or optimized CMS membranes.Type: GrantFiled: June 28, 2013Date of Patent: April 29, 2014Assignees: Georgia Tech Research Corporation, Shell Oil CompanyInventors: Mayumi Kiyono, Paul Jason Williams, William John Koros
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Patent number: 8709373Abstract: The present disclosure describes carbon nanotube arrays having carbon nanotubes grown directly on a substrate and methods for making such carbon nanotube arrays. In various embodiments, the carbon nanotubes may be covalently bonded to the substrate by nanotube carbon-substrate covalent bonds. The present carbon nanotube arrays may be grown on substrates that are not typically conducive to carbon nanotube growth by conventional carbon nanotube growth methods. For example, the carbon nanotube arrays of the present disclosure may be grown on carbon substrates including carbon foil, carbon fibers and diamond. Methods for growing carbon nanotubes include a) providing a substrate, b) depositing a catalyst layer on the substrate, c) depositing an insulating layer on the catalyst layer, and d) growing carbon nanotubes on the substrate. Various uses for the carbon nanotube arrays are contemplated herein including, for example, electronic device and polymer composite applications.Type: GrantFiled: December 11, 2009Date of Patent: April 29, 2014Assignee: William Marsh Rice UniversityInventors: Robert Hauge, Cary Pint, Noe Alvarez, W. Carter Kittrell
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Patent number: 8709122Abstract: The invention is directed to a method for producing an oxygenated biochar material possessing a cation-exchanging property, wherein a biochar source is reacted with one or more oxygenating compounds in such a manner that the biochar source homogeneously acquires oxygen-containing cation-exchanging groups in an incomplete combustion process. The invention is also directed to oxygenated biochar compositions and soil formulations containing the oxygenated biochar material.Type: GrantFiled: February 27, 2013Date of Patent: April 29, 2014Assignee: UT-Battelle, LLCInventors: James W. Lee, Archibald C. Buchanan, III, Barbara R. Evans, Michelle K. Kidder
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Patent number: 8709217Abstract: Electromagnetic irradiation of functionalized fullerenes in an oxygen-free environment induces conversion of the functionalized fullerenes to carbon nanotubes, carbon nanohorns, carbon onions, diamonds and/or carbon schwarzites. The carbon nanotubes can be multi-wall carbon nanotubes. Advantageously, the subject invention can be used for in-situ synthesis of carbon nanostructures within a matrix to form a carbon nanostructure composite, where positioning of the carbon nanostructures is controlled by the manner of dispersion of the functionalized fullerenes in the matrix. Carbon nanotube comprising features, such as electrical connects, can be formed on a surface by irradiating a portion of a functionalized fullerene coating with a laser beam.Type: GrantFiled: November 9, 2009Date of Patent: April 29, 2014Assignee: University of Florida Research Foundation, Inc.Inventors: Vijay Krishna, Brij M. Moudgil, Benjamin L. Koopman
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Patent number: 8709374Abstract: Disclosed herein is a scaled method for producing substantially aligned carbon nanotubes by depositing onto a continuously moving substrate, (1) a catalyst to initiate and maintain the growth of carbon nanotubes, and (2) a carbon-bearing precursor. Products made from the disclosed method, such as monolayers of substantially aligned carbon nanotubes, and methods of using them are also disclosed.Type: GrantFiled: February 6, 2008Date of Patent: April 29, 2014Assignee: Seldon Technologies, LLCInventors: Christopher H. Cooper, Hai-Feng Zhang, Richard Czerw
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Patent number: 8709372Abstract: A fiber of carbon nanotubes was prepared by a wet-spinning method involving drawing carbon nanotubes away from a substantially aligned, supported array of carbon nanotubes to form a ribbon, wetting the ribbon with a liquid, and spinning a fiber from the wetted ribbon. The liquid can be a polymer solution and after forming the fiber, the polymer can be cured. The resulting fiber has a higher tensile strength and higher conductivity compared to dry-spun fibers and to wet-spun fibers prepared by other methods.Type: GrantFiled: October 2, 2008Date of Patent: April 29, 2014Assignee: Los Alamos National Security, LLCInventors: Yuntian T. Zhu, Paul Arendt, Xiefei Zhang, Qingwen Li, Lei Fu, Lianxi Zheng
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Patent number: 8703091Abstract: A high modulus graphite fiber with a tensile modulus of 270˜650 GPa and a plurality of crystal structures with a thickness (Lc) of 20˜70 angstroms is disclosed. Carbon fiber is used as a raw material, and a microwave focusing method is used to perform an ultra quick high temperature graphitization process to increase the temperature of the carbon fiber at a heating speed of 10˜100° C. per minute to a graphitization temperature of 1400˜3000° C., and then to perform a quick graphitization process for 0.5˜10 minutes to form the high modulus graphite fiber.Type: GrantFiled: July 31, 2012Date of Patent: April 22, 2014Assignee: UHT Unitech Co., Ltd.Inventor: Chih-Yung Wang
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Patent number: 8703090Abstract: Methods for producing macroscopic quantities of oxidized graphene nanoribbons are disclosed herein. The methods include providing a plurality of carbon nanotubes and reacting the plurality of carbon nanotubes with at least one oxidant to form oxidized graphene nanoribbons. The at least one oxidant is operable to longitudinally open the carbon nanotubes. In some embodiments, the reacting step takes place in the presence of at least one acid. In some embodiments, the reacting step takes place in the presence of at least one protective agent. Various embodiments of the present disclosure also include methods for producing reduced graphene nanoribbons by reacting oxidized graphene nanoribbons with at least one reducing agent. Oxidized graphene nanoribbons, reduced graphene nanoribbons and compositions and articles derived therefrom are also disclosed herein.Type: GrantFiled: August 19, 2009Date of Patent: April 22, 2014Assignee: William Marsh Rice UniversityInventors: James M. Tour, Dmitry V. Kosynkin, Amanda Higginbotham, Brandi Katherine Price
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Publication number: 20140106257Abstract: Cohesive carbon assemblies are prepared by obtaining a carbon starting material in the form of powder, particles, flakes, or loose agglomerates, dispersing the carbon in a selected organic solvent by mechanical mixing and/or sonication, and substantially removing the organic solvent, typically by evaporation, whereby the cohesive assembly of carbon is formed. The method is suitable for preparing free-standing, monolithic assemblies of carbon nanotubes in the form of films, wafers, or discs, having high carbon packing density and low electrical resistivity. The method is suitable for preparing adherent cohesive carbon assemblies on substrates comprising various materials. The assemblies have various potential applications, such as electrodes or current collectors in electrochemical capacitors, fuel cells, and batteries, or as electromagnetic interference shielding materials.Type: ApplicationFiled: December 13, 2013Publication date: April 17, 2014Applicant: YAZAKI CORPORATIONInventors: Satyabrata RAYCHAUDHURI, Yongan YAN, Leonid GRIGORIAN
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Patent number: 8697026Abstract: Provided is a method of electrophoresis of carbon nanotube for separating them into metallic carbon nanotubes and semiconducting carbon nanotubes, and the method comprises a step of electrifying a carbon nanotube sealed gel in which carbon nanotubes are dispersed in a gel. According to the separation method, metallic CNT and semiconducting CNT may be efficiently and heavily separated and purified from each other in CNT containing both the two within a short period of time and in a simplified manner by the use of inexpensive facilities and according to a simple process, and the method can be readily scaled up, in which CNT can be separated industrially extremely advantageously.Type: GrantFiled: May 21, 2008Date of Patent: April 15, 2014Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Takeshi Tanaka, Hiromichi Kataura, Hehua Jin, Yasumitsu Miyata
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Publication number: 20140099505Abstract: The present invention relates to compositions comprising esterified lignin and poly(lactic acid). In various embodiments, the present invention provides fibers comprising the esterified lignin and poly(lactic acid) blend, carbon fibers made therefrom, and methods of making the fiber and the carbon fibers.Type: ApplicationFiled: October 8, 2013Publication date: April 10, 2014Applicant: Iowa State University Research Foundation, Inc.Inventors: Mahendra Thunga, Keke Chen, Michael Richard Kessler
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Patent number: 8691178Abstract: A method of processing bundles of carbon nanotubes (CNTs). Bundles of CNTs are put into a solution and unbundled using sonication and one or more surfactants that break apart and disperse at least some of the bundles into the solution such that it contains individual semiconducting CNTs, individual metallic CNTs, and remaining CNT bundles. The individual CNTs are separated from each other using agarose bead column separation using sodium dodecyl sulfate as a surfactant. Remaining CNT bundles are then separated out by performing density-gradient ultracentrifugation.Type: GrantFiled: June 3, 2011Date of Patent: April 8, 2014Assignee: The Regents of The University of MichiganInventors: Stephen R. Forrest, Jeramy D. Zimmerman
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Publication number: 20140093728Abstract: A carbon nanostructure that is free of a growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. The carbon nanostructure can be released from a growth substrate in the form of a flake material. Optionally, the carbon nanotubes of the carbon nanostructure can be coated, such as with a polymer, or a filler material can be present within the porosity of the carbon nanostructure. Methods for forming a carbon nanostructure that is free of a growth substrate can include providing a carbon nanostructure adhered to a growth substrate, and removing the carbon nanostructure from the growth substrate to form a carbon nanostructure that is free of the growth substrate. Various techniques can be used to affect removal of the carbon nanostructure from the growth substrate. Isolation of the carbon nanostructure can further employ various wet and/or dry separation techniques.Type: ApplicationFiled: September 24, 2013Publication date: April 3, 2014Applicant: Applied Nanostructured Solutions, LLCInventors: Tushar K. SHAH, Harry Charles Malecki, Rajneeta Rachel Basantkumar, Han Liu, Corey Adam Fleischer, Joseph J. Sedlak, Jigar M. Patel, William Patrick Burgess, Jess Michael Goldfinger
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Patent number: 8685362Abstract: The invention relates to an anode for lithium secondary battery comprising vapor grown carbon fiber uniformly dispersed without forming an agglomerate of 10 ?m or larger in an anode active material using natural graphite or artificial graphite, which anode is excellent in long cycle life and large current characteristics. Composition used for production for the anode can be produced, for example, by mixing a thickening agent solution containing an anode active material, a thickening agent aqueous solution and styrene butadiene rubber as binder with a composition containing carbon fiber dispersed in a thickening agent with a predetermined viscosity or by mixing an anode active material with vapor grown carbon fiber in dry state and then adding polyvinylidene difluoride thereto.Type: GrantFiled: July 12, 2011Date of Patent: April 1, 2014Assignee: Showa Denko K.K.Inventors: Masataka Takeuchi, Chiaki Sotowa
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Patent number: 8685361Abstract: Disclosed therein is a method for preparing a polyacrylonitrile-based polymer for preparation of carbon fiber having a melting point controlled by selecting an optimal energy of microwave, and a method for preparing a carbon fiber through melt spinning using the preparation method for polyacrylonitrile-based polymer. The present invention uses microwave to control the properties of the polyacrylonitrile-based polymer in a simplified way and prepare the polymer optimized for preparation of carbon fiber precursor through melt spinning for a short polymerization time, and provides a means for mass production of the polyacrylonitrile-based polymer being suitable for melt spinning at a temperature lower than the stabilization temperature and acquiring properties adequate to preparation of carbon fiber through stabilization. Hence, the present invention is expected to contribute to mass production of high-performance carbon fibers at reduced cost.Type: GrantFiled: May 1, 2012Date of Patent: April 1, 2014Assignee: Korea Institute of Science and TechnologyInventors: Kap-Seung Yang, Sung-Ho Lee, Hyang-Hoon Chae, Dong-Hun Lee
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Patent number: 8668896Abstract: The present invention relates to a method for making a twisted carbon nanotube wire. Two opposite ends of the at least one carbon nanotube film is clamped by two clamps. The two clamps is pulled along two reversed directions to stretch the at least one carbon nanotube film. The at least one carbon nanotube film is twisted by rotating the two clamps while the at least one carbon nanotube film is in a straightening state.Type: GrantFiled: November 12, 2009Date of Patent: March 11, 2014Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Kai Liu, Rui-Feng Zhou, Ying-Hui Sun, Kai-Li Jiang, Liang Liu, Shou-Shan Fan
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Patent number: 8663593Abstract: There is provided a method for fabricating a three dimensional graphene structure using a catalyst template, in which the three dimensional graphene structure in various forms can be obtained through a simple process by using a metal catalyst in various forms as a template and growing graphene thereon. There is also provided a method for controlling length of a three dimensional graphene structure to be from a few nanometers to a few millimeters by controlling length of the metal catalyst template.Type: GrantFiled: November 17, 2011Date of Patent: March 4, 2014Assignee: Research and Business Foundation Sungyunkwan UniversityInventors: Jibeom Yoo, Shashikant P. Patole, Hyunmyoung Lee
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Publication number: 20140037533Abstract: A high modulus graphite fiber with a tensile modulus of 270˜650 GPa and a plurality of crystal structures with a thickness (Lc) of 20˜70 angstroms is disclosed. Carbon fiber is used as a raw material, and a microwave focusing method is used to perform an ultra quick high temperature graphitization process to increase the temperature of the carbon fiber at a heating speed of 10˜100° C. per minute to a graphitization temperature of 1400˜3000° C., and then to perform a quick graphitization process for 0.5˜10 minutes to form the high modulus graphite fiber.Type: ApplicationFiled: July 31, 2012Publication date: February 6, 2014Inventor: CHIH-YUNG WANG
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Publication number: 20140030183Abstract: Carbon nanotubes (CNTs) having a desired diameter are selectively produced by reacting a carbon source with a cyclic compound in which multiple aromatic rings are continuously bonded. The reaction is preferably performed by supplying a gaseous carbon source under reduced pressure and heating. The cyclic compound in which multiple aromatic rings are continuously bonded is preferably a cyclic compound in which bivalent aromatic hydrocarbon groups are continuously bonded, or a modified cycloparaphenylene compound in which a cycloparaphenylene compound or at least one phenylene group of the cycloparaphenylene compound is substituted with a condensed cyclic group such as a naphthylene group.Type: ApplicationFiled: March 8, 2012Publication date: January 30, 2014Applicant: NATIONAL UNIVERSITY CORPORATION NAGOYA UNIVERSITYInventors: Kenichiro Itami, Yasutomo Segawa, Hisanori Shinohara, Ryo Kitaura
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Publication number: 20140023581Abstract: Methods of extracting recycling carbon fibers are provided. Method of extracting and recycling carbon fibers with furan-2-carbaldehyde are provided and systems for performing the same are also provided. Compositions comprising resin composites, carbon fibers, and/or furan-2-carbaldehyde are also provided.Type: ApplicationFiled: July 19, 2012Publication date: January 23, 2014Applicant: EMPIRE TECHNOLOGY DEVELOPMENT LLCInventor: Georgius Abidal Adam
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Patent number: 8628747Abstract: Carbon nanotube structures are formed by providing metal composite particles including a catalyst metal and a non-catalyst metal, where the catalyst metal catalyzes the decomposition of a hydrocarbon compound and the formation of carbon nanotube structures on surfaces of the particles. The metal composite particles are combined with the hydrocarbon compound in a heated environment so as to form carbon nanotube structures on the surfaces of the metal composite particles. The metal composite particles can be include iron and aluminum at varying amounts. The carbon nanotubes formed on the metal particles can remain on the metal particles or, alternatively, be removed from the metal particles for use in different applications.Type: GrantFiled: December 21, 2007Date of Patent: January 14, 2014Assignee: University of Maryland College ParkInventors: Michael R. Zachariah, Soo H. Kim
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Patent number: 8628748Abstract: A purification method for a carbon material containing carbon nanotubes is provided, which satisfies the following requirements: The method should prevent carbon nanotubes from being damaged, broken or flocculated; the method should be capable of removing the catalyst metal and carbon components other than the carbon nanotubes; and the method should be applicable to not only multi-walled carbon nanotubes but also single-walled carbon nanotubes which will undergo significant structural changes when heated to 1400° C. or higher temperatures. The method is characterized by including a carbon material preparation process for preparing a carbon material containing carbon nanotubes by an arc discharge method, using an anode made of a material containing at least carbon and a catalyst metal; and a halogen treatment process for bringing the carbon material into contact with a gas containing a halogen and/or halogen compound.Type: GrantFiled: March 7, 2008Date of Patent: January 14, 2014Assignee: Toyo Tanso Co., Ltd.Inventors: Yuji Takimoto, Naoto Ohta, Tetsuro Tojo
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Publication number: 20140011007Abstract: Syntheses of carbon nanotubes (CNT) are disclosed. The syntheses can take place on a thermally oxidized silicon surface placed inside a furnace prior to a reaction. The setup can have many variables that could affect the resulting CNT arrays, including flow rate and composition of carrier gas, flow rate and composition of precursor solution, and temperature. By varying such variables the density of the resulting CNT arrays can be controlled.Type: ApplicationFiled: June 7, 2012Publication date: January 9, 2014Inventors: Jordan R. RANEY, Chiara DARAIO
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Publication number: 20140010749Abstract: An object of the present invention is to provide a method for producing composite carbon fibers in which two or more carbon fibers are dispersed in a nearly homogenous state, the composite carbon fibers capable of being easily dispersed in a matrix such as a resin without leaving aggregate, and imparting low resistance. Disclosed is a method for producing composite carbon fibers, which comprises imparting a cavitation effect to slurry containing 6% by mass or less of two or more carbon fibers each having a different average fiber diameter under a pressure of 100 MPa or more and less than 245 MPa thereby to form a composite.Type: ApplicationFiled: July 3, 2013Publication date: January 9, 2014Applicant: SHOWA DENKO K.K.Inventors: Takeshi NAKAMURA, Ryuji YAMAMOTO
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Publication number: 20130336874Abstract: The present invention is directed to a method for enriching specific species of carbon nanotubes, comprising contacting a composition of carbon nanotubes with one or more quinone compounds, reacting the carbon nanotubes with the quinone compounds, and separating the carbon nanotubes reacted with the quinone compounds from the unreacted carbon nanotubes. The present invention is also directed to a field-effect transistor comprising a semiconducting single-walled carbon nanotube enriched using a method described herein.Type: ApplicationFiled: May 14, 2013Publication date: December 19, 2013Inventors: Bee Eng Mary Chan, Zhi Dai, Yu Qian Tina Tan, Liangyu Yan