Abstract: High strength fiber reinforced ceramic composites having low dielectric constants stable against high temperatures are made possible by post oxidation of 35-60 volume percent ceramic matrix enveloping 20-60 volume percent ceramic fiber.

Abstract: A composition for forming a film, comprising a solution of metal compounds in an organic solvent, wherein a molar ratio of metals in said solution is (Sr.sub.1-n R.sub.n):Bi:(Ta.sub.Y Nb.sub.1-Y)=X:Q:2, R is at least one element selected from the group consisting of La, Ce, Pr, Nd, Eu, Sm, Tb, Gd and Er, and 0<n.ltoreq.0.1, 0.4.ltoreq.X<1, 0.ltoreq.Y.ltoreq.1 and 1.5.ltoreq.Q.ltoreq.3.5, can be used to form a ferroelectric film. This ferroelectric film is useful in a ferroelectric capacitor, particularly a ferroelectric capacitor for a non-volatile memory.

Abstract: In accordance with the principles of the present invention, there is disclosed herein a structure and method of fabricating an anode plate for use in a field emission device. The method comprises the steps of providing a transparent substrate 20 and applying transparent insulative material 28 over the substrate 20. Next, particles of luminescent material 25 are partially embedded in selective areas of the transparent insulative material 28. A layer of electrically conductive material 23 is then applied over the luminescent material 25. The layer of electrically conductive material 23 is abraded so as to remove portions of the layer of electrically conductive material 23 and portions of at least some of the luminescent particles 25.

Abstract: A method is provided for industrially preparing a group II-VI or III-V compound single crystal from a polycrystalline group II-VI or III-V starting compound, such that the resultant single crystal has a small number of crystal defects by effectively preventing polycrystallization. The method includes steps of coating an inner surface of a crucible with a film consisting of powdered solids and a vitreous substance, placing the polycrystalline compound in the coated crucible, placing the crucible in a furnace, heating the crucible with furnace for melting the polycrystalline compound in the crucible, and cooling the crucible and the melted compound for growing a single-crystalline compound. Additionally, the surface of a seed crystal and a gap between the seed crystal and a wall of the crucible may also be coated with a film of powdered solids and a vitreous substance.

Abstract: Silica-containing ceramic coatings are produced on substrates at low temperatures by applying a coating comprising a silica precursor on a substrate and heating the coated substrate under an environment comprising nitrous oxide at a temperature sufficient to convert the silica precursor to the silica-containing ceramic coating. This method is especially valuable for forming protective and dielectric coatings on electronic devices.

Abstract: A PZT ferroelectric thin film is sputter deposited on an electrode without microcracks while avoiding oxygen and Pb ion deficiencies at the electrode interface by initially forming a buffer layer containing a sufficient amount of a volatile Pb component and a sufficient amount of oxygen to easily absorb the energy of sputter particles. The PZT ferroelectric thin film can also be deposited by laser ablation.

Abstract: Composition and method providing a chromium oxide densified insulative coating for a substrate comprising an insulative coating comprised of refractory oxide bubbles with a melting point above that of glass bubbles, a refractory oxide and a solution of a binder capable of being converted to an oxide upon being heated, thereby effecting a bond between the refractory oxide and the substrate. The coating is thin and provides increased thermal barrier characteristics.

Abstract: Hygroscopic ceramic materials which are difficult to waterproof with a silane, substituted silane or silazane waterproofing agent, such as an alumina containing, fibrous, flexible and porous, fibrous ceramic insulation used on a reentry space vehicle, are rendered easy to waterproof if the interior, porous surface of the ceramic is first coated with a thin coating of silica. The silica coating is achieved by coating the interior surface of the ceramic with a silica precursor, converting the precursor to silica either in-situ or by oxidative pyrolysis and then applying the waterproofing agent to the silica coated ceramic. The silica precursor comprises almost any suitable silicon containing material such as a silane, silicone, siloxane, silazane and the like applied by solution, vapor deposition and the like. If the waterproofing is removed by, e.g., burning, the silica remains and the ceramic is easily rewaterproofed.

Abstract: Alkoxymetals, .beta.-diketones or metal acetates which are metal compounds corresponding independently to Bi, metallic element A (which is at least one member of the group consisting of Ca, Ba, Sr, Pb and Bi) and metallic element B (which is at least one member of the group consisting of Ti, Nb and Ta) are reacted with alcohols, carboxylic anhydrides, glycols, .beta.-diketones or dicarboxylic acid monoesters to prepare compounds for inclusion in coating solutions for use in forming Bi-based dielectric thin films. The coating solutions are used to produce dielectric thin films or memories.

Abstract: The present invention relates to a ceramic coating composition comprising a preceramic material such as silicon oxide precursors, silicon carbonitride precursors, silicon carbide precursors, and silicon nitride precursors and a flux material such as B.sub.2 O.sub.3, PbO.sub.2, P.sub.2 O.sub.5, and Bi.sub.2 O.sub.3. The present invention also relates to a substrate such as an electronic device having said coating applied and ceramified thereon.

Abstract: Dielectrics represented by (Sr.sub.x Bi.sub.1-x)Bi.sub.2 Ta.sub.2 O.sub.y, wherein 0<x<1, and y represents the total number of oxygen atoms bonded to the respective metals, and thin films thereof, can be prepared by repeating the steps of applying compositions for forming the Sr--Bi--Ta--O-based dielectric thin films on substrates, drying and conducting a first-firing a plurality of times until the desired film thickness is achieved, and then conducting a second-firing for crystallization and compositions for forming Bi-based ferroelectric thin films and target materials for forming Bi-based ferroelectric thin films, both represented by the metal composition ((Sr.sub.a (Ba.sub.b, Pb.sub.c)).sub.x Bi.sub.y (Ta and/or Nb).sub.z wherein 0.4.ltoreq.X<1.0, 1.5.ltoreq.Y.ltoreq.3.5, Z=2, 0.7X.ltoreq.a<X, and 0<b+c.ltoreq.0.

Abstract: A method and apparatus for extraction and re-implantation of a natural tooth, such tooth being cleaned and repaired while extracted. The crown of the repaired tooth is mechanically masked and the tooth is then mounted in a partitioned vacuum cavity wherein gradual application of vacuum is used to degas and dehydrate the tooth root. Following degassing and dehydration of the tooth root a mass of titanium is heated in the cavity partition, by way of an electron beam source, the energy output of the beam source being thereafter ramped up to vaporize the mass. The partition in the cavity is then opened to expose the root to the titanium vapor after which the tooth may be reinserted into the original void.

Abstract: Nonporous inorganic support materials can be coated with metal and/or metal oxide in an abrasion-resistant manner by applying very dilute aqueous solutions of at least one metal compound to the heated shaped body so that the water can vaporize immediately and, if desired, subsequently calcining the shaped bodies at elevated temperature.

Abstract: A process for joining two parts of which at least one is made of an intermetallic material comprises:mixing elemental powders to form an intermetallic compound of the same type as that of the intermetallic part or parts;compacting and forming an intermediate part from the said compound at a temperature below that of the reaction sintering temperature of the compound;placing the intermediate part in position between the two parts to be joined;subjecting the assembly of parts to a first thermal cycle so as to effect a reaction sintering of the intermediate part and a consolidation of the assembly; and,subjecting the assembly to a second thermal cycle at a temperature above 0.8 of the fusion temperature of said intermetallic compound so as to effect a diffusion treatment and mechanical consolidation of the assembly.The process may also be adapted to form a coating or a repair of a part using an intermetallic material.

Abstract: A method is disclosed for coating a biomaterial to be placed in contact with a patient's blood flow to inhibit blood coagulation from adhering to the biomaterial that would otherwise result from such contact. A biodegradable material of liquid state compatible with the blood and tissue of the human body is prepared, and an anti-coagulant drug is incorporated into the liquid state of the biodegradable material to form a liquid coating material. The liquid coating material is adhesively applied to a surface of the biomaterial in a substantially continuous overlying layer having a formulation, pattern and thickness selected according to the period of time over which the coating material is to perform its anti-coagulant action. Thereafter the coating material is dried to a layer thickness less than about 100 microns for continuous disintegration thereof as a function of time when the layer is in contact with flowing blood.

Abstract: A process includes a step of melting aluminium alkoxide in hexylene glycol (2-methyl 2,4-pentonediol). Then, the solution is subject hydrolysis. During this, hydrolysis and dehydrating condensation of hexylene glycol is controlled by alkoxide. This is found effective for obtaining alumina having uniform porous structure with high specific surface area.

Abstract: A method for depositing an SiO.sub.2 layer, which acts as an inter-metal dielectric (IMD), is provided. The method includes the steps of applying to the topography an organodisiloxane which is dissolved in an organic solvent, the organodisiloxane is then polymerized, and the polymer formed is decomposed, the polymer changing in the process to become an SiO.sub.2 -rich layer. The method of the present invention results in SiO.sub.2 layers which achieve an excellent local and global degree of planarization and have a distinctly lower dielectric constant than SiO.sub.2 layers prepared using conventional methods.

Abstract: The present invention provides a method for strongly adhering a diamond-like carbon coating to a metal alloy substrate using ion beam assisted deposition of silicon and/or germanium followed by ion beam assisted deposition of diamond-like carbon.

Abstract: A process for the metallization of a phosphor screen which process comprises the steps of: i)applying to a process screen a coating composition comprising a poly(acrylate) or poky(methacrylate) dissolved in an acrylate or methacrylate monomer, the said composition including an initiator therein; ii) subjecting the coated to irradiation in order to form a polymeric film coating, iii)depositing a layer of metal upon the coated screen to form a composite; and iv) heating the composite to a temperature above the decomposition temperature of the film coating in order to decompose and/or volatilize the polymeric film coating.

Abstract: Thick opaque ceramic coatings are used to protect delicate microelectronic devices against excited energy sources, radiation, light, abrasion, and wet etching techniques. The thick opaque ceramic coating are prepared from a mixture containing phosphoric anhydride, i.e., phosphorous pentoxide (P.sub.2 O.sub.5), and a pre-ceramic silicon-containing material. It is preferred to also include tungsten carbide (WC) and tungsten metal (W) in the coating mixture. The coating is pyrolyzed to form a ceramic SiO.sub.2 containing coating. A second coating of plasma enhanced chemical vapor deposited (PECVD) silicon carbide (SiC), diamond, or silicon nitride (Si.sub.3 N.sub.4), can be applied over the thick opaque ceramic coating to provide hermeticity. These coatings are useful on patterned wafers, electronic devices, and electronic substrates. The thick opaque ceramic coating is unique because it is resistant to etching using wet chemicals, i.e., acids such as H.sub.3 PO.sub.4 and H.sub.2 SO.sub.4, or bases.

Abstract: Methods of brazing and coating and preparing articles for brazing and coating are disclosed. Prior to assembly and brazing, the articles are coated with a coating composition including a hot melt adhesive medium and brazing materials. To coat the articles, the hot melt adhesive medium and brazing materials are first mixed at elevated temperatures to form a liquid coating material, the material is allowed to harden, and the hardened material is then melted onto the articles to form a hard coating. The coated articles are then assembled for brazing. During the brazing process, the articles are first preheated to a sufficient temperature to substantially gasify and remove the hot melt adhesive medium from the articles. This leaves only the brazing materials on the articles for clean and efficient brazing of the articles in a conventional brazing oven. In one embodiment, the hot melt adhesive medium takes the form of a hot melt glue from the chemical family of ethylene-vinyl acetate bases.

Abstract: A process capable of forming an inorganic film which can be used at a relatively large thickness equivalent to, or greater than, the thickness of an organic SOG, without being subjected to oxidation by O.sub.2 plasma treatment used in a fabrication process of a semiconductor device. Polysilazane is first coated on a base, and the resulting polysilazane film is converted to a silicon dioxide film.

Abstract: Structured inorganic layers are produced by optionally mixing a composition which is obtainable by hydrolysis and polycondensation of(A) at least one hydrolyzable silane of general formula (I)SiX.sub.4 (I)wherein the radicals X are identical or different and represent hydrolyzable groups or hydroxyl groups, or an oligomer derived therefrom, and(B) at least one organosilane of general formula (II)R.sup.1.sub.a R.sup.2.sub.b SiX.sub.(4-a-b) (II)wherein R.sup.1 is a non-hydrolyzable group, R.sup.2 represents a radical carrying a functional group, X has the meaning specified above, and a and b are 0, 1, 2 or 3, the sum (a+b) being 1, 2 or 3, or an oligomer derived therefrom,in a ratio of amount of substance (A):(B) of 5-50:50-95, as well as(C) optionally, one or more compounds of glass- or ceramic forming elements,with a fine-scaled filler, applying the resulting composition onto a substrate, structuring the applied composition and thermally densifying the structured coating to form a structured layer.

Abstract: High strength fiber reinforced ceramic composites having low dielectric constants stable against high temperatures are made possible by post oxidation of 35-60 volume percent ceramic matrix enveloping 20-60 volume percent ceramic fiber.

Abstract: Stabilization of alkyltin compounds that are liquid at room temperature, especially alkyltin trihalides, is achieved by addition of 0.1 to 10 wt. % of one or more compounds that are soluble in the alkyltin compounds and that are reactive with water.

Abstract: An improved dielectric layer of an electroluminescent laminate, and method of preparation are provided. The dielectric layer is formed as a thick layer from a ceramic material to provide:a dielectric strength greater than about 1.0.times.10.sup.6 V/m;a dielectric constant such that the ratio of the dielectric constant of the dielectric material to that of the phosphor layer is greater than about 50:1;a thickness such that the ratio of the thickness of the dielectric layer to that of the phosphor layer is in the range of about 20:1 to 500:1; anda surface adjacent the phosphor layer which is compatible with the phosphor layer and sufficiently smooth that the phosphor layer illuminates generally uniformly at a given excitation voltage.The invention also provides for electrical connection of an electroluminescent laminate to voltage driving circuity with through hole technology. The invention also extends to laser scribing the transparent conductor lines of an electroluminescent laminate.

Abstract: A method for determining the instantaneous and cumulative mass rate of change of a conductive body in a deposition, densification or etching process through the use of a gaseous, liquid or particulate solids precursor. In one application, porous solid structures are densified by thermally decomposing a gaseous precursor to deposit an electrically and thermally conductive deposit within the structure. The rate of densification is determined by measuring the change of the electrical conductivity of the structure over time as the structure increases in mass.

Abstract: A metal oxide layer is provided around a thermocouple element. The metal oxide layer is formed by preparing a sol, in which particulates of a metal oxide are dispersed, by a sol-gel method, dipping the thermocouple element in this sol, energizing the thermocouple element as a cathode for bonding the precursor particulates of the metal oxide thereto, and heat treating the same. The thermocouple according to the present invention is compact with a thin insulating layer, excellent in flexibility, and provides no gas adsorption source.

Abstract: A phosphor (200) for low voltage applications including a plurality of light-emitting particles (10) being made from a UV-excitable light-emitting phosphor, a diffusion barrier (25) being formed as a film on the light-emitting particles (10), and a coating (30) of an electron-excitable UV-emitting material being formed on the diffusion barrier (25). A method for making a low voltage phosphor including the steps of (i) providing a UV-excitable light-emitting phosphor (ii) forming a diffusion barrier on the UV-excitable light-emitting phosphor via sol-gel techniques (iii) forming, via sol-gel techniques, a film of an electron-excitable UV-emitting material on the diffusion barrier.

Abstract: In a method of depositing a metal sulfide film on a substrate, at least one metal compound precursor comprising at least one thiocarboxylate ligand SECR and at least one solubility-improving ligand L is dissolved in a solvent to produce a solution, wherein a) E is selected from the group consisting of O and S and R is selected from the group consisting of alkyl, aryl, substituted alkyl, substituted aryl, halogenated alkyl, and halogenated aryl; and wherein b) L is selected from the group of monodentate ligands, multidentate ligands, and R.sup.1 O ligands. The solution is coated onto a substrate and the substrate is heated to a reaction temperature sufficient to decompose the metal compound precursor to form a metal sulfide film of at least one metal on the substrate.

Abstract: The invention is directed to a method of forming an implant having a porous surface using an organic binder compound to enhance the bonding between the porous surface layer and implant. Preferably, the binder is formed from a water-soluble protein that carbonizes during the sintering process to alloy with the metal of the porous surface layer. The porous surface layer may be in the form of beads or of fiber metal and can be preformed to fit with an implant or formed over the surface of the implant.

Abstract: A method of manufacturing a metal oxide coated glass which is a glass substrate bearing a pyrolytically formed coating composed of at least two metal oxides and which has a corrosion resistance at least equal to 5 as determined by Applicants' defined transmission test, the method including contacting a hot glass substrate with a coating precursor material composed of a tin-containing material and a titanium-containing material in the presence of oxygen to form a metal oxide coating composed of at least two metal oxides including tin oxide and titanium oxide on the hot glass substrate by pyrolyzing the coating precursor material as it contacts the hot glass substrate, wherein the titanium-containing material comprises a titanium chelate which is a reaction product of octyleneglycol titanate and acetylacetone.

Abstract: To produce functional vitrous, preferably colored or colloid-dyed layers, a composition produced by hydrolysis and polycondensation of(A) at least on hydrolyzable silane of general formula (I)SiX.sub.4 (I)wherein the radicals X are the same or different and represent hydrolyzable groups or hydroxy groups, or an oligomer derived therefrom, and(B) at least one organosilane of general formula (II)R.sup.1.sub.a R.sup.2.sub.b SiX.sub.(4-a-b) (II)wherein R.sup.1 is a non-hydrolyzable radical, R.sup.

Abstract: A method of planarizing a non-planar substrate, such as filling vias and contact holes, spreads a suspension of a conducting material suspended in a liquid on a substrate. The suspension includes an organometallic material, preferably with particles of a polymerized tin or indium alkoxide. The material is spread by spinning the substrate after applying the suspension. The carrier liquid and organic groups are removed by baking and curing at elevated temperatures, thereby depositing the conductive material on the substrate in a layer which is more planar than the substrate and which has regions of greater and lesser thickness. A relatively brief etch step removes conductive material from regions of lesser thickness, leaving material filling vias or contact holes.

Abstract: Liquid methyltin halide compositions and their use as intermediates in chemical synthesis and as precursors for forming tin oxide coatings on substrates are disclosed.

Abstract: A process which comprises heating at a temperature of from about 31.degree. C. to about 200.degree. C. a mixture of supercritical carbon dioxide, metal or metal oxide, and a surface treating component, optionally removing carbon dioxide, and optionally cooling.

Abstract: A method of forming a phosphor layer of a fluorescent screen of a CRT, having a good screen quality by properly managing the dissolution of a water glass and barium acetate occurring in a covering water step and improve the uniformity. A phosphor layer is formed on an inner surface of a panel portion of a glass bulb by a precipitation process and a lacquer intermediate film is formed on the phosphor layer in a state where the phosphor layer is moistened by covering water. An electrolyte remaining in the phosphor layer after the phosphor layer is moistened by the covering water has a conductivity of 6.0.+-.4.0 .mu.s/cm in 200 ml of pure water of 20.degree. C..+-.1.degree. C.

Abstract: Metal organic acid salt solutions for use as precursor materials for forming layered ferroelectric thin films are synthesized using an organic acid anhydride as the exchange reagent. The reaction is much faster than previous techniques, allows exact control of exchange with control of hydrolysis product, and may be used to control the solvent of the final solution. The reaction creates no water, and can be used to exactly control the extent of reaction of all metals. By using less than or equal to a stoichiometric amount of anhydride and then further reacting the remaining alkoxides, lower carbon content solutions with less decomposable organic can be formed. As such, the present invention discloses a much improved and faster synthesis technique giving improved solutions and corresponding thin film metal oxide compositions with improved and consistent electrical performance.

Abstract: A method of placing a substrate that generates heat by induction on a ceramic or vitreous ceramic food receptacle. A single layer of electrically conductive and/or ferro/ferrimagnetic material is applied to the bottom of the receptacle on the inside or the outside and is subsequently fired.

Abstract: A method of decorating a firable article which includes the step of mixing a metallic salt with a fuel material which can supply oxygen to the salt in a reaction. This mixture causes complex formation of the salt, characterized by raising the pH of the mixture to at least 5. Additives in the mixture promote stability and provide the required viscosity surface tension and conductivity for use in an ink jet printer. When applying a solution of this mixture onto a firable article by ink jet printing, the mixture is such that upon drying, the mixture reacts to form an oxide of the metal to provide a decorative color pigment on the article.

Abstract: This invention relates to a manufacturing method of a compound semiconductor thin film derived from a metal sulfide produced by thermal decomposition of a sulfur-containing metal organic compound, the compound containing at least one functional group having at least one metal atom selected from the group consisting of copper, zinc, cadmium, mercury, and lead, and the functional group also containing at least one sulfur atom. Since the obtained metal sulfides are of high-purity and dense, they can be utilized in various photoelectric devices. Particularly, the photoelectric conversion efficiency of a CdS/CdTe system thin film compound semiconductor solar cell can be improved remarkably by employing a layer made of a CdS thin film as a window of the solar cell.

Abstract: A process for forming a ceramic coated element formed by first encapsulating the element within a sacrificial material and then encapsulating the element and the sacrificial material with an unsintered ceramic material. The resultant combination of materials and elements is then controllably heated to a temperature that burns the sacrificial material prior to the curing of the ceramic material so as to permit the permeation of the burned sacrificial material through the ceramic material. As the ceramic material is sintered it shrinks around the encapsulated element to form the ceramic coated element. In the preferred embodiment of the invention the coated element is a magnet or magnetizable material that is magnetized to a preferred axis of magnetization during the cooling phase of the process.

Abstract: The instant invention pertains to a multi-layer tamper proof electronic coating wherein the first layer is a protecting layer produced from preceramic silicon containing material and at least one filler. The second layer is a resin sealer coat produced from a sealer resin selected from the group consisting of colloidal inorganic-based siloxane resins, benzocyclobutene based resins, polyimide polymers, siloxane polyimides and parylenes. An optional third layer is a cap coating layer selected from SiO.sub.2 coating, SiO.sub.2 /ceramic oxide coating, silicon containing coatings, silicon carbon containing coatings, silicon nitrogen containing coatings, silicon oxygen nitrogen coatings, silicon nitrogen carbon containing coatings and/or diamond like coatings.

Abstract: A method is provided for reducing the amount of wear particulates generated by a total joint orthopaedic implant. The implant consists of two matched articulating components wherein at least one of the components is made of polymer or other material with similar physical properties. The method includes the steps of placing the total joint orthopaedic implant in a fluid bath and articulating the implant in the fluid bath for at least 1,000 cycles. The articulation may be performed in three stages. In the first, the implant is articulated under a load of substantially 0.1-500 Newtons with sliding speeds of substantially 0.01-0.5 meters per second. During a second stage the articulation takes place under a load of substantially 100-2,500 Newtons with sliding speeds of substantially 0.01-0.5 meters per second. In the third stage the articulation takes place under a load of substantially 2,500-10,000 Newtons at sliding speeds of 0.5-2.0 meters per second.

Abstract: An improved medium for use in preparing ceramic coating compositions. The improvement resides in the employment of pantothenol as a rheology modifier in the medium.

Abstract: Compositions and methods for priming or sealing dental or biological substrates for subsequent bonding. The primer is particularly useful for priming dentin of a tooth to prepare the dentin for bonding with a resinous material. The primer comprises a mixture of a polymerization initiator such as camphoroquinone and a polymerizable promoter such as methacrylic acid. Polymerizable promoters within the scope of the present invention have at least one ethylenically unsaturated group and at least one carboxylic acid group. The primer may further comprise a solvent such as ethanol, a natural resin such as Canadian balsam and a polymerizable resin such as 2-hydroxyethyl methacrylate (HEMA). The primer can also be formed from a mixture of a polymerization initiator, a natural resin and a polymerizable resin.

Abstract: Fiber reinforced ceramic matrix composites are prepared by coating refractory fibers having a interfacial coating thereon with a curable preceramic polymer having a char which contains greater than about 50% sealant oxide atoms followed by forming the coated fibers into the desired shape, curing the coated fibers to form a pre-preg, heating the pre-preg to form a composite and heating the composite in an oxidizing environment to form an in situ sealant oxide coating on the composite. The resultant composites have good oxidation resistance at high temperature as well as good strength and toughness.

Abstract: A method for direct printing of micro-optical components (82) onto optical substrates (84) or active devices to create optical circuit elements as well as micro-optical components and systems, such as plano-convex circular, cylindrical or square lenslets, anamorphic lenslets, waveguides, couplers, mixers and switches and monolithic lenses deposited directly onto optical components such as diode lasers and optical fibers. The method provides a means for precisely depositing a wide range of materials in a wide variety of shapes for fabricating a full range of passive and active micro-optic devices.

Abstract: A shaped object with a roughened surface is immersed in an aqueous solution of a metal salt and/or a solution of an organic metal. After the shaped object is dried, it is heated to form a metal-diffused layer in the shaped object and a ceramic surface layer on the shaped object. The ceramic surface layer has a large hardness, and is prevented from peeling off.

Abstract: This invention is a strand of silicate glass fibers with a carbon skin or sheath around each glass fiber of the strand. The invention uses hydrocarbon pyrolysis with silicate fiber glass manufacturing to produce fibers using conventional melt-bushing technology. The formation of a carbon skin or sheath on the silicate glass fibers offers numerous advantages. For example, pyrolyzing hydrocarbons is endothermic. Heat is removed in the process and fibers are cooled faster. This helps to achieve higher throughput.