Abstract: A coating process for fatigue critical components is provided. The coating process comprises the steps of providing a substrate having a first modulus of elasticity, depositing a layer of a material having a second modulus of elasticity less than the first modulus of elasticity onto the substrate, and depositing a coating over the material layer.

Abstract: Coatings on a substrate and application methods result in coatings that can withstand different types or groups of bulk cargo and operations. This novel approach includes use of a combination of layers of coating materials at certain thicknesses and applied with certain techniques. In certain embodiments, the coating system includes coatings applied to a pretreated substrate, e.g., blasted steel cargo hold plates of an oceangoing vessel. The coatings include a bond layer and a resistance layer, e.g., an anti-corrosive layer tailored to resist at least one of corrosion, erosion, impact and wear of the substrate.

Abstract: Methods of making multi-layered, hydrogen-containing thermite structures including at least one metal layer and at least one metal oxide layer adjacent to the metal layer are disclosed. At least one of the metal layers contains hydrogen, which can be introduced by plasma hydrogenation. The thermite structures can have high hydrogen contents and small dimensions, such as micrometer-sized and nanometer-sized dimensions.

Abstract: A protecting coating for a copper substrate is disclosed. The coating comprises seed layer comprising titanium ions that forms an “alloy-like” structure with the copper substrate. The coating further comprises a first layer of carbon disposed on the seed layer comprising titanium ions. A second layer comprising titanium is disposed on the first layer of carbon, and a second layer of carbon is disposed on the second layer comprising titanium.

Abstract: A method for manufacturing a carbon nanotube field emission cathode includes the steps of: providing a substrate (110) with a metallic layer (130) thereon; defining holes (131) in the metallic layer; oxidizing the metallic layer to form a metallic oxide layer (132) thereon; removing portions of the metallic oxide layer in the holes so as to expose corresponding portions of the metallic layer; forming a metal-salt catalyst layer (580) on the exposed portions of the metallic layer in the holes; and growing carbon nanotubes (690) on the substrate in the holes.

Abstract: In order to achieve micro alloying of protective coatings for components such as turbine blades in a turbine engine, a base metal is splutter coated by deposition of a trace element to a desired proportion. A protective layer of the base metal is then applied over the trace element to prevent further reaction or oxidation of the trace elements. A coating consumable is therefore formed from the base metal and the trace element. The consumable may be produced immediately prior to coating of the component or may be inertly stored for subsequent use. The consumable is applied by laser deposition techniques whereby a coating is formed in the melting process.

Abstract: A method for depositing a platinum-group-containing layer on a substrate includes furnishing the substrate, and preparing a water-base paint containing metallic platinum-group powder, water, and a binder. The method further includes spraying the water-base paint overlying the substrate to form a platinum-group-containing layer, and thereafter heating the platinum-group-containing layer to interdiffuse the platinum-group-containing layer.

Abstract: A turbine component having a protective bilayer coating thereon comprising: a superalloy substrate; and a bilayer protective coating applied to the substrate wherein the bilayer protective coating comprises a first inner layer of platinum and aluminum; and a second outer oxidation-resistant layer applied over the first inner layer, the second outer layer comprising an MCrAlX alloy where M is selected from Fe, Ni and Co, and where X is yttrium or another rare earth element. A method of improving oxidation resistance of a Ni or Co-based superalloy turbine component comprising: depositing a bilayer protective coating on a turbine component by depositing a first inner platinum-aluminum layer on a surface of the turbine Component; and depositing a second outer layer comprising an MCrAlX alloy over the first inner layer, wherein M is a metal selected from Fe, Ni and Co, and X is yttrium or another rare earth element.

Abstract: A method of fabricating or reparing a blisk (10) that comprises a plurality of blades (14) attached to the outer periphery of a disc (12). Blades (14) are formed separately from the disc (12) and are attached to stubs (13) on the disc (12) by friction welding. A metal powder, such as titanium, is sprayed onto the stubs (13) to reinforce them during the friction welding process. Once the stub (13) has been coated with the powder spray, plates (20) are fastened on the disc (12) between which the sprayed coating (18) is clamped. The plates (20) restrain the sprayed coating (18) to prevent delamination during friction welding. Once each of the blades (14) has been welded onto the respective stubs (13) the clamping plates (20) are removed and the sprayed coating (18) is machined away.

Abstract: The invention relates to the production and use of novel bioactive devices and metallic coatings for example for sterilizing, disinfecting, and decontaminating water or aqueous solutions. The known oligodynamic effect of silver for reducing the amount of germs is thereby improved and increased by combining silver with ruthenium and a vitamin or derivative thereof. The novel properties of these bioactive metal surfaces lead to faster and more efficient killing of microorganisms. Simultaneously, these novel bioactive metal surfaces prevent infestation by microorganisms and attachment or permanent deposition of problematic biomolecules such as for example DNA, RNA, or proteins. A self-cleaning surface is thus obtained, which very quickly and efficiently and over extended periods of time sterilizes water and aqueous solutions when they come in contact with said surface.

Abstract: To produce at least two bonded-together layers (11, 13; 11?, 13), it is proposed that the material of at least one of the layers (13) is melted and subsequently, by spray compacting with a spray cone (10, 10?), is applied to the other layer, which is moved in relation to the spray cone (10, 10?), in such a way that the material composite is thereby produced.

Abstract: According to the present invention, in order to suppress whisker formation on a plated member having a plated layer comprising a lead-free material, the orientation index of the plane (321) in a plated layer for a plated member 3 having a plated layer 2 comprising a lead-free material on the surface of a base material 1 is 2.5 to 4.0. In another embodiment, the value (220)/(321) derived from the ratio of the orientation index of the plane (220) to that of the plane (321) for the plated layer is 0.5 to 1.5. An undercoat layer 4 having the orientation plane (220) may be formed between the base material 1 and the plated layer 2.

Abstract: A method for a surface being plated locally includes a fixture for holding at least a work piece and the fixture is supported with two opposite lateral walls of a plating tank. Hence, a plated zone on a surface of the work piece can be immerged into the liquid contained in the plating tank for the plated zone being coated with de-oxide layer and plating layer sequentially.

Abstract: A method of treating a metal surface of a portion of a substrate processing system to lower a defect concentration near a processed surface of a substrate includes forming a protective coating on the metal surface, wherein the protective coating includes nickel (Ni) and a fluoropolymer. Forming the protective coating on the metal surface can further include forming a nickel layer on the metal surface, impregnating the nickel layer with a fluoropolymer, and removing fluoropolymer from the surface leaving a predominantly nickel surface so the fluoropolymer is predominantly subsurface. A substrate processing system includes a process chamber into which a reactant gas is introduced, a pumping system for removing material from the process chamber, a first component with a protective coating, wherein the protective coating forms a surface of the component which is exposed to an interior of the substrate processing chamber or an interior of the pumping system.

Abstract: A diffusion barrier coating includes, in an exemplary embodiment, a composition selected from the group consisting of a solid-solution alloy comprising rhenium and ruthenium wherein the ruthenium comprises about 50 atom % or less of the composition and where a total amount of rhenium and ruthenium is greater than 70 atom %; an intermetallic compound including at least one of Ru(TaAl) and Ru2TaAl, where Ru(TaAl) has a B2 structure and Ru2TaAl has a Heusler structure; and an oxide dispersed in a metallic matrix wherein greater than about 50 volume percent of the matrix comprises the oxide.

Abstract: Composites comprising carbon nanotubes are provided. In some embodiments, the composite may include at least one metal/carbon nanotube layer disposed between at least two metal layers, where the metal/carbon nanotube layer includes metal and a plurality of carbon nanotubes distributed in selected regions of the metal. In other embodiments, the composite may include a carbon nanotube rope and at least one metal layer disposed on an outer surface of the carbon nanotube rope.

Abstract: A body of iron, steel or other such ferrous material is protected from thermochemical erosion by a layer of an iron nitride having a relatively low nitrogen content. The atomic percentage of nitrogen in the iron nitride layer is no greater than 20%, and in specific embodiments is in the range of 10-15%. The nitride layer may have a layer of a refractory material deposited thereatop. Some refractory materials include metals such as chromium. The invention has specific utility for protecting gun barrels, turbines, internal combustion engines, drilling equipment, machine tools, aerospace systems and chemical reactors which are exposed to extreme conditions of temperature and pressure. Specifically disclosed is a gun barrel which incorporates the invention.

Abstract: The invention relates to a method for coating a cooling element (1) mainly made of copper, provided with water cooling pipes (2) and used particularly in connection with metallurgic furnaces or the like, wherein the cooling element includes a fire surface (3) that is in contact with molten metal, suspension or process gas; side surfaces (6) and an outer surface (7), so that at least part of the fire surface (3) is coated by a corrosion resistant coating (5).

Abstract: The present disclosure relates to an improved low-cost metallic coating to be deposited on gas turbine engine components. The metallic coating consists of 1.0 to 18 wt % cobalt, 3.0 to 18 wt % chromium, 5.0 to 15 wt % aluminum, 0.01 to wt % yttrium, 0.01 to 0.6 wt % hafnium, 0.0 to 0.3 wt % silicon, 0.0 to 1.0 wt % zirconium, 0.0 to 10 wt % tantalum, 0.0 to 9.0 wt % tungsten, 0.0 to 10 wt % molybdenum, 0.0 to 43.0 wt % platinum, and the balance nickel.

Abstract: Disclosed is a multilayer alloy coating film capable of maintaining heat resistance, high-temperature oxidation resistance and creep resistance for a long time even in an ultra high temperature environment. The multilayer alloy coating film comprises a barrier layer formed on a base surface, and an aluminum reservoir layer formed on the barrier layer and composed of an alloy containing Al. The barrier layer comprises an inner sacrificial barrier layer composed of an alloy containing Re, an inner stabilization layer formed on the inner sacrificial barrier layer, a diffusion barrier layer formed on the inner stabilization layer and composed of an alloy containing Re, an outer stabilization layer formed on the diffusion barrier layer, and an outer sacrificial barrier layer formed on the outer stabilization layer and composed of an alloy containing Re.

Abstract: A protective coating for a metal substrate is provided that is light, durable, galvanically protective, and easily applied at the site of manufacture. The coating has at least two layers, one of which is a galvanizing layer and one of which is a micro-composite of a galvanic metal and a non-conducting material, such as polymer. Such coatings are useful for example to protect pipes or other metal surfaces in corrosive environments. Methods of producing the coating are provided, including methods that use advanced spraying techniques to provide very thin but consistent layers. Using the advanced spraying methods the composite layer can be created by co-spraying the galvanic metal and the nonconductive material onto the surface of the galvanic coating. Optionally, an outer coat of insulating material can be applied to provide further protection to the surface.

Abstract: A coated article includes a substrate and a substantially pure metal layer coated thereon. The substantially pure metal layer is configured to enhance the strength of the underlying substrate. A method is also disclosed for making a coated article by providing a substrate and coating a substantially pure metal layer thereon.

Abstract: A method of applying a metallic finish onto a substrate using a metallic mixture having a mix of polyurethane, polyurethane hardener, polyurethane solvent, and a metal additive. The method involves applying coats of polyurethane along with the metallic mixture onto a substrate and then burnishing the finish.

Abstract: A substrate is coated by applying a first layer atop the substrate and including, in major weight part, a non-refractory first metal. A second layer is applied atop the first layer and includes, in major weight part, a carbide and/or nitride of a second metal. A third layer is applied atop the second layer and comprises, in major weight part, a ceramic. The substrate may be a refractory metal-based investment casting core.

Abstract: A transition joint for joining dissimilar metals with the chemical composition of the joint varied in a controlled manner from end to end. The transition joint has a first end of having a chemical composition similar to that of one of the metals to be joined and a second end having a chemical composition similar to that of the other metal with a gradual composition variation between the first and second ends.

Abstract: A coated article that includes a substrate and a wear-resistant coating scheme. The coated article may be a cutting insert shown to improve performance in chip-forming material removal operations or a wear-resistant component used in chipless forming operations. The wear-resistant coating scheme has an underlayer and top layer containing aluminum, chromium, and nitrogen. The coating scheme also includes a mediate multi-periodicity nanolayer coating scheme containing titanium, aluminum, chromium and nitrogen. The mediate multi-periodicity nanolayer coating scheme includes a plurality of sets of alternating layer arrangements. Each one of the alternating layer arrangements has a base layer comprising titanium, aluminum and nitrogen and a nanolayer region having a plurality of sets of alternating nanolayers. Each set of alternating nanolayers has one nanolayer having aluminum, chromium, titanium and nitrogen and another nanolayer having aluminum, chromium, titanium and nitrogen.

Abstract: Problems to be solved by the invention: It is an object of the present invention to provide a brass-plated steel wire for reinforcing rubber articles capable of surely improving adhesiveness between brass-plated steel wire and rubber and a method for manufacturing the same. Means for solving the problem: A brass-plated steel wire 10 for reinforcing rubber articles according to the invention comprises a steel wire having a brass-plating layer 11 thereon, wherein the brass-plating layer 11 has an amorphous portion 11a formed of crystal grains having a grain size of 20 nm or less. It may also be such that the brass-plating layer 11 is of a laminated structure 13 of an amorphous portion 11a on the surface side and a crystalline portion 11b on the inner side, wherein the amorphous portion 11a is formed of crystal grains having a grain size of 20 nm or less and the crystalline portion 11b is formed of crystal grains having a grain size of more than 20 nm.

Abstract: An exemplary core insert includes a main body having a central protruding portion and a peripheral flange portion surrounding the central protruding portion, and a multilayer film formed on the central protruding portion. The multilayer film includes a nickel-phosphorus layer formed on the central protruding portion, a chromium layer formed on the nickel-phosphorus layer, a chromium nitride layer formed on the chromium layer, and a diamond-like carbon layer formed on the chromium nitride layer. The core insert has excellent hardness, good corrosion resistance, good wear resistance, high adhesion, and a long operational lifetime.

Abstract: A quasi-single phase or single phase thick platinum nickel aluminide coating and methods for forming the coating over a nickel-based superalloy substrate are provided. The method includes the steps of forming a metal layer over a surface of the nickel-based superalloy substrate, the metal layer comprising platinum, growing a diffusion zone comprising a platinum nickel alloy layer from the metal layer and the nickel-based superalloy substrate, and subjecting the platinum nickel alloy to one or more aluminization cycles to transform the platinum nickel alloy into a platinum nickel aluminide coating having a platinum aluminide phase formed therein.

Abstract: A method for making an oxidation resistant article, including (a) depositing a layer of a Pt group metal on a substrate to form a platinized substrate; and (b) depositing on the platinized substrate layer of Pt group metal a layer of a reactive element selected from the group consisting of Hf, Y, La, Ce and Zr and combinations thereof to form a surface modified region thereon, wherein the surface modified region includes the Pt-group metal, Ni, Al and the reactive element in relative concentration to provide a ?-Ni+??-Ni3Al phase constitution.

Abstract: A method of forming a gas turbine part includes forming a bonding underlayer on a superalloy metal substrate, the underlayer including an intermetallic compound of aluminum, nickel, and platinum, and forming a ceramic outer layer on the alumina film formed on the bonding underlayer. The bonding underlayer essentially comprises an Ni—Pt—Al ternary system constituted by an aluminum-enriched ?-NiPt type structure, in particular an Ni—Pt—Al ternary system having a composition NizPtyAlx in which z, y, and x are such that 0.05?z?0.40, 0.30?y?0.60, and 0.15?x?0.40.

Abstract: In order to protect a monocrystalline superalloy rich in rhenium against corrosion whilst avoiding the formation of progressive secondary reaction zones, a layer (3) formed of tungsten and cobalt is deposited on its surface before aluminisation treatment.

Abstract: A multi-layered metallic material comprising a metallic glass layer comprising an alloy layer that has a hardness of at least about 9.2 GPa and a metal layer having a hardness of less than about 9.2 GPa. In application form, an armor structure is provided that is suitable for protecting against ballistic projectiles.

Abstract: The problem in forming solderable and bondable layers on printed circuit boards is that the surfaces tarnish after storage of the boards prior to further processing (mounting of the electrical components), thus affecting solderability and bondability. In order to overcome this problem it is suggested to deposit, in a first method step, a first metal which is more noble than copper to the printed circuit board and to plate silver in a second method step with the proviso that the first metal be deposited at a rate that is at most half the rate of silver in the second method step when the first metal is silver.

Abstract: Disclosed herein are methods for coating metal substrates, systems therefore, and articles made therefrom. In one embodiment, the method of coating a metal substrate comprises: disposing a metallic bond coating on the metal substrate, creating ions with a reverse polarity high frequency apparatus at a frequency of greater than or equal to about 2.5 kHz, roughening the surface with the ions to a subsequent average surface roughness of greater than or equal to about 5 ?m, and disposing a ceramic coating on the metallic bond coating surface. The metallic bond coating had a surface with an initial average surface roughness of less than or equal to about 1 ?m.

Abstract: A ball stud having a ball at one end of a rod-shaped stud. The ball stud comprises: a metal plating film formed on the surface of the stud; and a trivalent chromate film continuously formed over both the surface of the metal plating film formed on the stud and the surface of the ball, whereby rust is inhibited in the boundary of the metal plating film. An externally threaded portion is also coated, if formed in the ball stud, on its surface with the metal plating film and the trivalent chromate film.

Abstract: The present invention provides a process for preparing a thin film having alternating monolayers of a metal-metal bonded complex monolayer and an organic monolayer by layer-by-layer growth. The process comprises the steps of: (1) applying onto a surface of a substrate a first linker compound to produce a primer layer; (2) applying onto said primer layer a layer of a metal-metal bonded complex to produce a metal-metal bonded complex monolayer on said primer layer;(3) applying onto said metal-metal bonded complex monolayer a second linker compound; and optionally(4) sequentially repeating steps (2) and (3) at least once to produce said layer-by-layer grown thin film having alternating monolayers of a metal-metal bonded complex monolayer and an organic monolayer.

Abstract: There is provided a method for forming a corrosion-resistant protective film, which can preventing peel off of the protective film and enables long-term stable use of the film under high-temperature conditions. The corrosion-resistant film forming method includes the steps of: carrying out Ni (or Ni—B) plating of a surface of a substrate of a Ni—Cr alloy to form a Ni (or Ni—B) layer on the substrate surface; and carrying out Al diffusion treatment of the surface of the Ni (or Ni—B) layer to form a protective layer of Ni—Al.

Abstract: A sports bat, such as a baseball or softball bat, is electro-deposited with a nanostructured metal. Bats made from aluminum alloys or other metals may be electro-deposited with varying thicknesses of nanostructured metals such as nickel, nickel iron, cobalt phosphorous, or similar materials. The bat substrate alloy can be any metal or alloy. The coating may be done using an electro-deposition process.

Abstract: A process in which a base metal film is formed on the surface of a plastic film using a dry plating process, and a liquid containing an organic monomer is then brought in contact with the base metal film, thereby selectively forming a conductive organic polymer coating within any pinhole defects, and effectively filling the defects. A metal film is then formed on top of the base metal film using an electroplating process, thus forming a metal wet plating layer.

Abstract: A method for applying a NiAl based bond coat and a diffusion aluminide coating to a metal substrate comprises, in part, coating a portion of the external surface of the superalloy substrate, by physical vapor deposition with a layer of a NiAl based metal alloy, wherein the deposited NiAl based metal alloy includes a controlled amount of about 6 to 25 weight percent aluminum, wherein the deposited aluminum level of the NiAl based metal alloy is controlled to be about 50-100% of its final level after aluminizing to form a coated external portion; and subsequently, simultaneously aluminizing the coated external portion and a different surface of the superalloy substrate.

Abstract: An article has a metallic substrate having a first emissivity. A thermal barrier coating atop the substrate may have an emissivity that is a substantial fraction of the first emissivity.

Abstract: A coating process and system for an article having a substrate formed of a metal alloy that is prone to the formation of a secondary reaction zone (SRZ). The coating system includes an aluminum-containing overlay coating and a stabilizing layer between the overlay coating and the substrate. The overlay coating contains aluminum in an amount greater by atomic percent than the metal alloy of the substrate, such that there is a tendency for aluminum to diffuse from the overlay coating into the substrate. The stabilizing layer is predominantly or entirely formed of at least one platinum group metal (PGM), namely, platinum, rhodium, iridium, and/or palladium. The stabilizing layer is sufficient to inhibit diffusion of aluminum from the overlay coating into the substrate so that the substrate remains essentially free of an SRZ that would be deleterious to the mechanical properties of the alloy.

Abstract: There is provided a method for depositing a modified MCrAlY coating on a surface of a gas turbine engine component. The method includes cold gas dynamic spraying techniques to provide a metallurgical bond between a substrate, such as a superalloy substrate, and the modified MCrAlY composition. The method further includes post deposition heat treatments including hot isostatic pressing. The modified MCrAlY composition includes one or more elements of Pt, Hf, Si, Zr, Ta, Re, Ru, Nb, B, and C, which improves the corrosion and environmental resistance of the coated component.

Abstract: A diffusion barrier alloy film has a diffusion barrier layer which has more excellent diffusion barrier properties than an Re—Cr alloy film, and can stand usage at higher temperatures (e.g., 1150° C. or higher). The diffusion barrier layer 18 is made of an Re—W alloy ? phase containing 12.5 to 56.5% of. W in terms of atomic composition and the remainder of Re excluding unavoidable impurities. A metal base 10 has a surface coated with a diffusion barrier layer 18. If required, the diffusion barrier layer 18 has a surface coated with a diffusion alloy layer 20 containing 10% or greater and less than 50% of Al, Cr, or Si in terms of atomic composition, providing a high-temperature apparatus member.

Abstract: There is provided a method for depositing a modified MCrAlY coating on a turbine blade tip. The method utilizes laser deposition techniques to provide a metallurgical bond between a turbine blade substrate, such as a superalloy substrate, and the modified MCrAlY composition. Further the modified MCrAlY coating has sufficient thickness such that a post-welding grinding operation to size the turbine blade to a desired dimension will not remove the modified MCrAlY coating entirely. The modified MCrAlY coating thus remains on the finished turbine blade tip after grinding.

Abstract: A method for applying a decorative metal finish to a substrate is provided which includes the following steps. The method employs depositing a thermally cured leveling layer overlying the substrate, and then subsequently a radiation-cured layer overlying the leveling layer. A decorative metallic layer then is deposited overlying the radiation-cured layer, which in a preferred embodiment is selected to provide a strong adhesive bond to the deposited decorative metal layer. A layered structure made by the foregoing method also is provided.

Abstract: An electromagnetic interference shield includes a polymer thin film metalized with conductive metals and a solderable material deposited over the conductive metals. The solderable material has a low melting temperature so that the solder can be heated to form a weld joint between a chip (or component) and the solder without damaging the metalized polymer thin film. One example of a low melting temperature solder is SnBi.

Abstract: An exemplary core insert includes a main body having a central protruding portion and a peripheral flange portion surrounding the central protruding portion, and a multilayer film formed on the central protruding portion. The multilayer film comprising a nickel-phosphorus layer formed on the central protruding portion, a chromium layer formed on the nickel-phosphorus layer, a chromium nitride layer formed on the chromium layer, and a diamond-like carbon layer formed on the chromium nitride layer. The core insert has excellent hardness, good corrosion resistance, good wear resistance, high adhesion and long operational lifetime.

Abstract: The present invention provides a chromium and active elements modified platinum aluminide coating that may be used on a surface of a gas turbine engine component such as a turbine blade. The coating may be used as a protective coating that impedes the progress of corrosion, oxidation, and sulfidation in superalloy materials that comprise the substrate of the turbine blade. Additionally, the coating may be used as a bond coat onto which a thermal barrier coating is deposited. The presence of active elements as well as chromium and platinum provides improved corrosion, oxidation, and sulfidation resistance. The coating is applied using an electron beam physical vapor deposition. The coating is applied alternatively using selected sequential diffusion processing steps involving chromium, platinum and aluminum.