Abstract: The present invention is a process for modifying the properties of a porous freeform fabricated part by increasing its density and reducing its porosity. The porosity and density of a freeform fabricated part are altered by packing the pores in a freeform part with an infiltrant, such as a preceramic polymer. The process includes drawing a vacuum on or pressurizing the freeform part while it is in an infiltrant bath, thereby forcing the infiltrant into the pores of the freeform part. After removing the densified freeform part from the infiltrant bath, the freeform part is subjected to a treating process, such that the infiltrant within the pores transforms to a ceramic or ceramic-containing phase to thereby increasing the density of the freeform part.

Abstract: Improved autodeposited coatings on metallic surfaces are formed by contacting the metallic surfaces with an autodepositing composition comprising an acidic aqueous coating solution containing dispersed solid resin particles or either an internally stabilized or externally stabilized vinylidene chloride polymer, an exemplary internally stabilized polymer being prepared from vinylidene chloride and a monomeric surfactant which includes an inorganic ionizable group, and an exemplary externally stabilized polymer being prepared from vinylidene chloride and a reactive comonomer, the resulting resin particles having surfactant adsorbed thereon, said autodeposited coatings having extremely good corrosion resistant properties without treatment with a reaction rinse such as a chromium rinse.

Abstract: A process for providing an outer layer on a supporting substrate including mixing an outer layer material with fluorinated carbon and zinc oxide to form a filled outer layer material, and providing at least one of the filled outer layer(s) onto the supporting substrate, where bleeding of contaminants to imaging members is decreased or eliminated.

Abstract: Thin, light weight bipolar plates for use in electrochemical cells are rapidly, and inexpensively manufactured in mass production by die casting, stamping or other well known methods for fabricating magnesium or aluminum parts. The use of a light metal, such as magnesium or aluminum minimizes weight and simultaneously improves both electrical and thermal conductivity compared to conventional carbon parts. For service in electrochemical cells these components must be protected from corrosion. This is accomplished by plating the surface of the light weight metal parts with a layer of denser, but more noble metal. The protective metal layer is deposited in one of several ways. One of these is deposition from an aqueous solution by either electroless means, electrolytic means, or a combination of the two. Another is deposition by electrolytic means from a non-aqueous solution, such as a molten salt.

Abstract: A method of treating a substrate comprises contacting a surface of said substrate, with a pressurized fluid comprising carbon dioxide and a surface treatment component, the surface treatment component being entrained in the pressurized fluid and contacting the surface so that the surface treatment component lowers the surface tension of the surface of the substrate and treats the substrate. The contacting step is preferably carried out by immersion, the fluid is preferably a liquid or supercritical fluid, the substrate is preferably a metal or fabric substrate, and the surface treatment component is preferably a fluoroacrylate polymer.

Abstract: Manufacture of superalloy component wherein the component is blasted with abrasive grit particles at one or more stages during the manufacture, is treated with a chemical grit removal medium effective to dissolve and remove abrasive grit particles from the surface of the component without degradation of the component (substrate), and then is coated with a protective coating such that entrapped grit particles are substantially reduced or eliminated from the coating.

Abstract: A method and a bath for protecting a Zn or Zn alloy surface against the corrosion and oxidation and for improving the wettability characteristics of a Zn or Zn alloy surface with a Sn solder alloy. The method is particularly useful in the manufacture of electronic components, when the deposition of a thin layer of Zn or Zn alloy is needed before the deposition of the Sn alloy (particularly Pb free) to improve the solderability characteristics of the Cu surface.

Abstract: A method of treating a substrate comprises contacting a surface of said substrate, with a pressurized fluid comprising carbon dioxide and a surface treatment component, the surface treatment component being entrained in the pressurized fluid and contacting the surface so that the surface treatment component lowers the surface tension of the surface of the substrate and treats the substrate. The contacting step is preferably carried out by immersion, the fluid is preferably a liquid or supercritical fluid, the substrate is preferably a metal or fabric substrate, and the surface treatment component is preferably a fluoroacrylate polymer.

Abstract: A surface-treating method of of screw parts, which method consists of coating beforehand a liquid organic resin based coating composition capable of forming a film having a volume resistivity of 1014 &OHgr;·cm or more at normal temperature onto a thread of screw parts to be mounted onto an automobile body by welding prior to a coating step of the automobile body, followed by heating and drying.

Abstract: The present invention relates to an improvement in an anodic aluminum oxide coating on which microbials are easy to adhere and propagate, for constantly keeping it clean. The present invention provides an anti-microbial aluminum product comprising: a porous oxide coating covering the surface of the aluminum core for the product and an inorganic bacteria controlling ingredient being carried in the micropores of the oxide coating. The anodic oxide coating is preferably sealed.

Abstract: A method of treating a substrate comprises contacting a surface of said substrate, with a pressurized fluid comprising carbon dioxide and a surface treatment component, the surface treatment component being entrained in the pressurized fluid and contacting the surface so that the surface treatment component lowers the surface tension of the surface of the substrate and treats the substrate. The contacting step is preferably carried out by immersion, the fluid is preferably a liquid or supercritical fluid, the substrate is preferably a metal or fabric substrate, and the surface treatment component is preferably a fluoroacrylate polymer.

Abstract: Improvements in MolyPhos corrosion resistant coatings for zinc plated surfaces and zinc alloy surfaces are presented, which enhances corrosion protection in marine environments, and other corrosive atmospheres. In particular a cerium fluoride stabilized MolyPhos coating, and organic acid stabilized coatings are provided, which improve resistance to standard salt fog test exposures to at least 300 hrs, thus extending applicability of a conventional MolyPhos coating to applications to telecommunications, electronics, automotive and aviation equipment. MolyPhos coatings offer promise as an environmentally friendly alternative to conventional chromate corrosion coatings.

Abstract: The formation of passivation coatings on ferrous substrates is disclosed by heating the substrate in an aqueous 1.0 to 6.0 M basic metal hydroxide treatment bath containing SiO.sub.2 and a water-soluble glycol, at a temperature that is effective to form a passivation coating on the substrate until the passivation coating is formed thereon, wherein the treatment bath contains from about 0.25 to about 1.0 moles of SiO.sub.2 per liter of glycol and water.

Abstract: An integrated circuit package derives increased mechanical robustness and electrical reliability consistent with increased heat dissipation capacity by edge bonding of integrated circuit chips onto a substrate such as a chip, board, module or another integrated circuit by forming a solder or conductive adhesive bond between a bonding/contact pad on the substrate and a metallization feature extending at least on limited opposing areas of major surfaces of the chip and, preferably, across the edge of the chip. Thermally conducting material contained in a cap may provide additional, distributed support for the chip by a combination of viscosity and density providing buoyancy of the chips. Alternatively, a cap may be provided which further stabilizes the edge-mounting of chips while increasing velocity of cooling fluid against the chips.

Abstract: The susceptibility to heat degradation of an autodeposited coating in which the principal organic constituents are copolymers of vinylidene chloride in which vinylidene chloride residues constitute at least half the weight of the total binder phase in the autodeposited coating is improved if the wet autodeposited coatings are rinsed, before being later dried and cured, with a water-based liquid rinse that comprises dissolved phosphate ions in a concentration that corresponds stoichiometrically to at least 0.5 g/l of tripolyphosphate ions. The water-based liquid rinse preferably has a strongly alkaline pH and also comprises dissolved organic molecules that are effective chelating agents for dissolved iron cations by reason of having in each molecule at least two carboxyl, carboxylate, and/or other hydroxy moieties.

Abstract: A process for treating the surface of a metal roll, to extend the rolling campaign of the roll and ultimately the work life of the roll in a metal forming operation, comprises the steps of heating the metal roll surface to a temperature of at least 100 degrees F., and enveloping the metal roll in a bath of perfluoroethylene resin and an aliphatic naphthene solvent for a time sufficient to coat the surface of the metal roll with the perfluoroethylene resin.

Abstract: A process for surface-treating a body made of metal is disclosed, which includes a step of immersing the body made of metal in an aqueous solution containing at least one organometallic compound and at least one film-forming assistant, thereby forming a transparent film on a surface of the body made of metal. Further, in accordance with the present invention, there is provided a composition of matter including a substrate made of magnesium or a magnesium alloy and a transparent film formed on the substrate, which can be prepared by the process.

Abstract: After immersing an extruded flat tubed strip, in an immersion tank containing a slurry of a brazing material having brazing metallic powder and brazing flux powder mixed in alcohol that has binder dissolved therein, the extruded flat tubed strip is pulled up virtually vertically. Furthermore, the slurry coated on the extruded flat tubed strip pulled up from the immersion tank is dried and bonded/baked on the extruded flat tubed strip through the drying means.

Abstract: The present invention provide a recyclable cold curing aqueous coating composition comprising an acrylic group-modified epoxidized ester resin with acid vale of 25 to 60, which is formed from an epoxy resin (a), a fatty acid (b) and an ethylenically unsaturated monomer (c) in a component (a)/component (b)/component (c) weigh % ratio of 20 to 70/20 to 50/3 to 50, the sum of (a), (b) and (c) being 100 weight %, and a method for reusing it. For the method of the present invention, the coating composition has improved recycling properties by optimizing the properties such as acid value of the resin, the pH of a collecting solution for use to collect the coating composition and a content of a hydrophilic solvent in the collecting solution.

Abstract: A method for forming an indium oxide film on an electrically conductive substrate by immersing the substrate and a counter electrode in an aqueous solution containing at least nitrate and indium ions and flowing an electric current between the substrate and the couter electrode, thereby causing indium oxide film formation on the substrate, is provided. A substrate for a semiconductor element and a photovoltaic element produced using the film forming method are also provided. An aqueous solution for the formation of an indium oxide film by an electroless deposition process, containing at least nitrate and indium ions and tartrate, is also disclosed. A film-forming method for the formation of an indium oxide film on a substrate by an electroless deposition process, using the aqueous solution, and a substrate for a semiconductor element and a photovoltaic element produced using the film-forming method are further provided.

Abstract: A process for forming a zinc oxide film including immersing an electroconductive substrate having a surface including a plurality of linear projections in an aqueous solution containing at least nitrate ions and zinc ions to form a zinc oxide film on the electroconductive substrate by a liquid-phase deposition. The plurality of linear projections may preferably provide an uneven surface which has a center-line average surface roughness Ra(X) of 15-300 nm when scanned in a direction parallel to the linear projections, a center line average surface roughness Ra(Y) of 20-600 nm when scanned in a direction perpendicular to the linear projections, and an Ra(X)/Ra(Y) ratio of at most 0.8. The thus formed zinc oxide film is provided with an uneven surface suitable for an optical-confinement layer of a photo-electricity generating device excellent in photoelectric performances.

Abstract: Processes for attaching colors and prints to stainless steel product in the present invention comprises actions of: (1) roughening surface with an abrasive paper, (2) cleaning with water, (3) applying priming paint to the stainless steel, (4) hanging the stainless steel on a support, (5) placing a film with colors and prints thereon on water, (6) contacting the stainless steel with the film, (7) washing with cleaning water, (8) drying; and (9) applying gold lacquer in order for the stainless steel to have a shining surface.

Abstract: Disclosed are a super-antirust coating used for a vehicle, which comprises 5 to 45% (by weight, hereinafter the same) of petroleum sulfonate and/or a metal salt thereof, 0.5 to 35% of lanolin fatty acid and/or a metal salt thereof, 0.5 to 35% of hardened castor oil, and 0.05 to 35% of a scaly filler and/or a fibrous filler, and an antirust treating method comprising coating a necessary site on a surface of an outer panel or a part of a vehicle with the super-antirust coating to a thickness of 50 .mu.m to 200 .mu.m, and drying the coating at 5 to 30.degree. C. for 1 to 2 hours to form a reinforced antirust coating.

Abstract: A process for forming a silica film on a substrate, comprising the steps of preparing a liquid composition comprising silicic acid, water, an alkali and an organic solvent, said liquid composition having a volume ratio of water to the organic solvent in a range of 0.2 to 10.0 and a concentration of silicon element in a range of 0.0001 to 5.0 mol/l; contacting a surface of a substrate with the liquid composition; and maintaining the contact between the surface of the substrate with the liquid composition to selectively deposit silica on the surface of the substrate until a silica film is formed on the surface of the substrate.

Abstract: The invention concerns a diaphragm chlor-alkali electrolysis cell comprising a cover, a conductive base for supporting the anodes and a cathode in the form of a box provided with internal wall, external wall and tubular fingers made of a mesh or perforated sheet covered with a porous diaphragm. One or more copper sheets for electric current distribution are fixed to the cathode external walls. The connection between the copper sheets and the cathode external walls is made by means of bolts with the interposition of a conductive and deformable element provided with residual elasticity under compression. The weldings for the assembling of the cathode walls are free from internal stresses.

Abstract: A method of preparing metal oxide thin films by a solution method. A .beta.-metal .beta.-diketonate or carboxylate compound, where the metal is selected from groups 8, 9, 10, 11, and 12 of the Periodic Table, is solubilized in a strong Lewis base to form a homogeneous solution. This precursor solution forms within minutes and can be deposited on a substrate in a single layer or a multiple layers to form a metal oxide thin film. The substrate with the deposited thin film is heated to change the film from an amorphous phase to a ceramic metal oxide and cooled.

Abstract: Disclosed is a room temperature wet chemical growth (RTWCG) process of SiO-based insulator coatings on silicon substrates for electronic and photonic (optoelectronic) device applications. The process includes soaking the Si substrates into the growth solution. The process utilizes a mixture of H.sub.2 SiF.sub.6, N-n-butylpyridinium chloride, redox Fe.sup.2+ /Fe.sup.3+ aqueous solutions, and a homogeneous catalyst.

Abstract: A process for making a light-reflective bicycle frame and a light-reflective bicycle frame made therefrom are provided. The process includes: preparing a bicycle frame, providing a transparent adhesive layer on the bicycle frame, spreading uniformly light-reflective particles on the transparent adhesive layer to form a light-reflective particle layer which is substantially free of any superimposed or overlapping particles, and providing a transparent protective layer on the light-reflective particle layer.

Abstract: A two-step method to porcelain-coat an article is provided particularly useful for porcelain-coating a gas burner used in a gas-fired residential barbecue grill. A gas burner constructed from mild enameling-grade steel is dipped in a slip containing porcelain frit and manipulated so that the slip adequately coats and adheres to the interior surfaces of the burner. The porcelain-containing slip simultaneously coats and adheres to the peripheral "shoulders" and particularly to the interior "shoulders", of the gas jet openings of the burner. A second coating of porcelain-containing powder is then applied, for example, electrostatically or by other conventional powder application techniques, to the exterior surfaces of the burner. The properties of the porcelain-containing powder of the second coating are adjusted for optimal coating properties. Then, the double coated gas burner is fired in a continuous furnace at a peak firing temperature of 1480.degree. F. to 1550.degree. F., with a target of 1530.degree. F..

Abstract: The present invention relates to a method of treating a metal substrate to provide permanent corrosion resistance. The method comprises applying a solution containing one or more vinyl silanes in admixture with one or more multi-silyl-functional silanes to a metal substrate in order to form a coating. The method is particularly suitable for use on zinc coated surfaces.

Abstract: The invention concerns an aqueous corrosion-protective cleaning solution for tin-plated steel, in particular for tin-plated steel cans, the solution containing complex fluorides of the elements boron, titanium, zirconium, and hafnium; non-ionic surfactants; and corrosion inhibitors and having a pH within the range from 3 to 6. The invention also concerns an aqueous concentrate for preparing the solution by dilution with water and a method of cleaning tin-plated cans using the solution.

Abstract: The present invention provides a method for growing or depositing artificial bone materials called organoapatites on a metal surgical alloy. The method involves pretreating the alloy with at least one aqueous solution of a poly(amino acid). After this pretreatment step, the organoapatites can be synthesized onto the alloy. Because most surgical implants are made from metal alloys, this method can be used to make implants which contain organoapatites may promote the formation of natural bone when placed into a human patient in vivo.

Abstract: A two-step method to porcelain-coat an article is provided particularly useful for porcelain-coating a gas burner used in a gas-fired residential barbecue grill. A gas burner constructed from mild enameling-grade steel is dipped in a slip containing porcelain frit and manipulated so that the slip adequately coats and adheres to the interior surfaces of the burner. The porcelain-containing slip simultaneously coats and adheres to the peripheral "shoulders", and particularly to the interior "shoulders", of the gas jet openings of the burner. A second coating of porcelain-containing slip is then applied, for example, by spraying or other conventional wet application techniques, to the exterior surfaces of the burner. The properties, for example specific gravity, of the porcelain-containing slip of the second wet coating are adjusted for optimal coating properties. Then, the double slip-coated gas burner is fired in a continuous furnace at a peak firing temperature of 1480.degree. F. to 1550.degree. F.

Abstract: A process for producing a carbon foam heat sink is disclosed which obviates the need for conventional oxidative stabilization. The process employs mesophase or isotropic pitch and a simplified process using a single mold. The foam has a relatively uniform distribution of pore sizes and a highly aligned graphic structure in the struts. The foam material can be made into a composite which is useful in high temperature sandwich panels for both thermal and structural applications. The foam is encased and filled with a phase change material to provide a very efficient heat sink device.

Abstract: The present invention relates to a process for adhering a powder to a substrate. The process includes the steps of: a) providing an oscillating magnetic field, b) continuously introducing into the magnetic field coating material, a substrate, and a means of affixing the coating material to the substrate by forming a fluidized bed of at least the coating material and providing sufficient force to cause the coating material to adhere to the surface of the substrate, and c) continuously collecting the coated substrate.

Abstract: The hydrophobic composition prepared by dissolving a hydrophobic resin in a perfluorocarbon solvent, can be very thinly and uniformly coated on a plate. Therefore, when a cell is prepared by using the coated plate, internal pressure of the cell can be decreased.

Abstract: An apparatus for modifying an intravascular stent with endothelial cells and/or engineered endothelial cells which may have genetically altered DNA to minimize failure rates includes an external conductor sleeve, an insulating tube held therein, and a pair of insulated end caps, each detachably securable over each end of said insulating tube. Each insulated cap has a substantially centered aperture therethrough and a stent holder extending transversely therefrom to hold opposite ends of the stent therebetween. The insulated end caps and the insulating tube hold a solution containing the endothelial cells inside the insulating tube to surround exposed surfaces of the stent. An insulated internal conductor is received through the apertures.

Abstract: The corrosion protection of a metal article is accomplished by treating the metal article, which has not been treated with a conversion coating, with a wash coat solution comprising polyphenylene oxide, such as alkyl substituted polyphenylene oxide, preferably poly(2,6-dimethyl-1,4-polyphenylene oxide).

Abstract: A process for coating sheet metal is disclosed that comprises the steps of 1) cleaning the sheet metal to remove surface contaminants that may interfere with the coating adhering to the sheet metal; 2) pretreating the sheet metal to promote adhesion of the coating to the sheet metal; 3) applying an electron beam curable coating to the sheet metal that when curing is complete, adheres to the sheet metal; and, 4) exposing the coating on the sheet metal to an electron beam to cure the coating, the cleaning, pretreating and curing resulting in no emission of pollutants that need to be removed before the emission is released into the atmosphere.

Abstract: This invention relates to a process comprising the steps of contacting a metal surface with an aqueous composition comprising water and specific amounts by weight of phosphate ions, condensed phosphate ions and water soluble polymer molecules of a specific general formula, separating the contacted metal surface from the aqueous composition, rinsing with water and heating.

Abstract: A process for making a field emitter cathode is disclosed, which comprises the steps of depositing a solution of a metal compound in a solvent and an electron emitting powder onto the surface of a substrate and heating the substrate containing the solution and the electron emitting powder deposited thereon for a time and temperature sufficient for the metal compound to be completely reduced to a metal.

Abstract: This invention describes the coating of a nickel-phosphorous bond on steel sheets or pipes of common carbon steel with the aim of forming an Fe--Ni--P bond, using a process of diffusion and enabling the resistance of the exhaust gases to corrosion. The deposit, when submitted to continual use of the vehicle, forms an intermetallic layer, which each time protects the substrate against corrosion.

Abstract: The present invention provides a method for selectively allowing film-forming molecules to be chemically adsorbed onto an Si substrate to produce a good and robust organic monomolecular film, wherein molecules with SH groups are chemically adsorbed onto the Si substrate to form a monomolecular film of the molecules by heating an As molecular beam source 4 to allow a monoatomic layer thickness of arsenic to be adsorbed onto the clean surface of the Si substrate set on a sample stage 3 and then immersing the Si substrate terminated by arsenic in a solution containing molecules with SH groups.

Abstract: The invention relates to a process for application of an organic coating on a moving metallurgical product 7 from a bath of a liquid organic material 3 contained in a vat 2 and liable to comprise air bubbles, the transfer of said liquid organic material 3 onto the product being accomplished in a coating zone, characterized in that, in order to eliminate said air bubbles, there is created in at least one zone of the bath, located upstream from said coating zone, an ascending current in the liquid material so as to convey the air bubbles from the bath to the vicinity of its surface and cause their bursting. The invention also relates to an apparatus for the implementation of this process.

Abstract: A zinc phosphate conversion coating which is accelerated only with nitrogen free organic peroxides is low-polluting and able to form uniform, fine, and dense conversion coatings that exhibit an excellent paint adherence when thin and excellent lubricity/lubricant carrier quality when thick.

Abstract: A process for forming a cured paint film from a paint containing, as a binder, a resin containing a carbonyl group, or a resin, or a resin mixture containing a carbonyl group and a carboxyl group or a paint containing, as a binder, a resin containing a resin or a resin mixture containing a group which forms a carboxyl group in the subsequent contact step with a hydrazine compound or polyhydrazide compound. The uncured paint film, which contains a carbonyl group, or a carbonyl group and a carboxyl group or a group that forms a carboxyl group, is subjected to a step of curing the paint film by allowing the uncured paint film to contact with a hydrazine compound or a polyhydrazide compound.

Abstract: This invention relates to a process for producing a selective absorber which contains one or more layers of a non-homogeneous material (cermet), the non-homogeneous material having been produced by means of a sol-gel process.

Abstract: Deleterious effects of friction between bullets and the barrel of a firearm are reduced by improving the lubricity of the surface of the bullet by coating the same with molybdenum disulfide according to a method that includes heating the bullets to be coated to open the pores thereof and then agitating the bullets and molybdenum disulfide with an impacting instrumentality to drive the molybdenum disulfide against the bullet to be deeply absorbed therein. The bullets are also polished and burnished.

Abstract: An electrodepositable coating composition is provided comprising (a) an active hydrogen-containing, cationic salt group-containing resin electrodepositable on a cathode; (b) a curing agent for transurethanation, transamidation or transesterification curing like at least a partially capped polyisocyanate curing agent; and (c) a catalytic mixture of bismuth and an amino acid or amino acid precursor. Optionally, an auxiliary acid may be present to increase the effectiveness of the amino acid in the mixture with bismuth.

Abstract: An insulated metallic strip suitable for use in the coils of power transformers and method of producing the same. Following the extrusion of a flat metallic strip of conductive material for winding into a magnet coil, the flat strip having a predetermined thickness and first and second sides bounded by a pair of fully rounded edges, the method of insulating the strip of conductive material by supporting the flat strip in a level state at a predetermined temperature in a vacuum chamber and while in the vacuum chamber applying a liquid coating of resin to the entire first side of the strip and the pair of rounded edges and extending onto the second side of the strip from each of the edges a distance at least as great as about 0.25" to prevent turn to turn discharge.