Metal Base Patents (Class 427/435)
  • Patent number: 5897918
    Abstract: A faster and more efficient method for applying ultra thin films to substrate surfaces is disclosed. The method comprises heating a film forming composition comprising amphiphilic molecules to a liquid state, immersing the substrate surface in the heated liquid composition to heat the surface, and washing away the excess composition. For surfaces that ordinarily have insufficient or no chemical moieties reactive with the amphiphilic molecules, the immersion in the heated composition causes the substrate to become porous and expose previously unavailable chemically reactive moieties in the surface matrix. The amphiphilic molecules then self-assemble, chemically bond to the surface matrix and self-polymerize with each other and with other surface matrix-bound and/or surface-bound molecules to form the ultra thin surface film. The method is also faster and more efficient for coating non porous and metal surfaces.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: April 27, 1999
    Assignee: nanoFilm, Ltd.
    Inventors: Brij P. Singh, Pramod K. Arora
  • Patent number: 5895691
    Abstract: A magnetic conveyor system for transporting ferro-magnetic cans through an immersion or electro-immersion coating bath includes a magnetic infeed conveyor for transporting the cans toward an inlet end of the coating bath, a magnetic coating conveyor for removing the cans from the infeed conveyor and transporting them through the coating bath, and a magnetic outfeed conveyor for removing the cans from the coating conveyor at an outlet end of the coating bath. The magnetic coating conveyor includes an endless conveyor belt which defines inclined inlet and outlet runs relative to a surface of the coating bath. The cans are transported on the conveyor belt with a closed bottom of each can magnetically held to the conveyor belt and an open top of each can facing outwardly from the belt. The cans are transported into the coating bath at the inlet run with the closed bottom of each can entering the bath before the open top.
    Type: Grant
    Filed: November 3, 1998
    Date of Patent: April 20, 1999
    Assignee: Eagle-Picher Industries, Inc.
    Inventors: Bryan R. Boger, Joseph G. Vanden-Eynden
  • Patent number: 5885716
    Abstract: Using a material comprising a metal organic compound and an inorganic filler, a composite film is obtained by coating a substrate with said material and heat-treating the coating. The obtained composite film improves the properties of the substrate.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: March 23, 1999
    Assignees: Osaka Municipal Government, Tomoe Works Co., Ltd.
    Inventors: Hiroshi Nagasawa, Masami Nakamoto
  • Patent number: 5879745
    Abstract: In the method for stabilizing an artificial patina layer produced on a copper panel, a transparent cover layer consisting of water glass and hydroxycellulose is applied onto the patina layer immediately after it is produced. The cover layer can consist of sodium or potassium water glass and hydroxycellulose, and is applied onto an artificially patinated copper panel by either immersion or spraying. After immersion or spraying, the cover layer is dried. This occurs in an atmosphere with a temperature of approximately 20.degree. C. to 150.degree. C., within a time period of approximately one to one and a half hours.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: March 9, 1999
    Assignee: KM Europa Metal AG
    Inventors: Ulrich Reiter, Stefan Priggemeyer, Stefan Hoveling
  • Patent number: 5875547
    Abstract: This invention relates to a method for preventing transport of fluids--such as water and/or gas--through a joint between at least two insulated cable conductors (1,2;21,22,23). The method includes provision of a jointing ferrule (3) for insertion of the conductor ends into the ferrule and making required electrical contacts, --and provision of a molded sheath (8) of insulation material over the joint in sealed contact with the conductor insulation. The ferrule is precovered with a coating containing EEA copolymer to obtain improved adhesion between the ferrule and the insulation sheath. The mold material must be compatible with--and preferably of the same material--as the conductor insulation.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: March 2, 1999
    Assignee: Alcatel
    Inventors: Bj.o slashed.rn Larsson, Liv Molvik Lundegaard
  • Patent number: 5871815
    Abstract: An antistatic film comprising a chemically adsorbed film of straight chain molecules each containing a conductive group and provided on a chargeable substrate via covalent bonds each containing a Si group, said chemically adsorbed film having a conductivity of 10.sup.-10 S/cm or above. With the antistatic chemically adsorbed film according to the invention, conductive functional groups are secured via chemically adsorbed molecules and by siloxane bonds to the surface of a substrate material such as ceramics, glass, synthetic resins or synthetic fibers, a film, a plate, an display screen surface, a light-emitting tube. Thus, the film provides an antistatic effect and does not separate. In addition, this chemically adsorbed film has a thickness at the nanometer level and is thus excellently transparent, as well as capable of preventing contamination of the substrate surface due to charging thereof. The film is also excellently durable.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: February 16, 1999
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Kazufumi Ogawa, Norihisa Mino, Mamoru Soga
  • Patent number: 5868874
    Abstract: A process for forming a zinc phosphate coating on an aluminum substrate is provided to obtain good coverage by the coating. The coating preferably has a columnar or nodular crystal morphology and a coating weight of at least about 150 mg/ft.sup.2. The aluminum substrate is contacted with a zinc phosphate conversion coating bath which contains: (a) from about 0.4 to 2.5 g/l zinc ion; (b) from about 5 to 26 g/l phosphate ion; (c) from about 0.4 to 1.5 g/l fluoride ion; (d) from about 4 to 400 mg/l ferrous ion; and (e) from about 0.01 to 2 g/l ammonium ion. The zinc phosphate conversion coating is formable on an aluminum substrate in the presence or absence of an accelerator. Also provided is an aqueous zinc phosphate conversion coating concentrate which contains: (a) from about 10 to 60 g/l zinc ion; (b) from about 160 to 400 g/l phosphate ion; (c) from about 2 to 40 g/l fluoride ion; (d) from about 0.2 to 2.0 g/l ferrous ion; and (e) from about 1.0 to 25 g/l ammonium ion.
    Type: Grant
    Filed: January 23, 1998
    Date of Patent: February 9, 1999
    Assignee: PPG Industries, Inc.
    Inventor: Charles E. Rossio
  • Patent number: 5853506
    Abstract: A method of treating metal working dies by the steps of: forming a metal working die part to be constituted of consolidated particulate material with a porosity in the range of 0.01-0.5%; immersing the part in a lubricant that is flowable under the working conditions of use for the die part, the lubricant being contained within a pressure chamber; raising the pressure within the chamber to 3,500 psi and the temperature of the lubricant to about 100.degree. C. for a period of time sufficient to allow the lubricant to migrate and be trapped within the micro pores of the part with a positive internal pressure; and placing into use the treated cold working die part so that such die part is subjected to shear, such use being without the need for burn in and redressing.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: December 29, 1998
    Assignee: Ford Motor Company
    Inventor: Fritz Meldrum
  • Patent number: 5853797
    Abstract: Disclosed is a method and solution for providing corrosion protection for electrical contact members. The contact members are exposed to the solution, which in one embodiment includes a phosphonate, a lubricant, and a solvent. In a preferred embodiment, the phosphonate is phosphonic acid, the lubricant is polyphenyl ether or tricresylphosphate, and the solvent includes an isoparaffinic hydrocarbon. In a further embodiment, the lubricant can be omitted from the solution.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: December 29, 1998
    Assignee: Lucent Technologies, Inc.
    Inventors: Harold E. Fuchs, Henry Hon Law, Daniel George Muth
  • Patent number: 5851597
    Abstract: A process for surface-treating a body made of metal is disclosed, which includes a step of immersing the body made of metal in an aqueous solution containing at least one organometallic compound and at least one film-forming assistant, thereby forming a transparent film on a surface of the body made of metal. Further, in accordance with the present invention, there is provided a composition of matter including a substrate made of magnesium or a magnesium alloy and a transparent film formed on the substrate, which can be prepared by the process.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: December 22, 1998
    Assignees: Sony Corporation, Denka Himaku Inc.
    Inventors: Masahiko Kakizaki, Masahiro Akimoto
  • Patent number: 5844058
    Abstract: A new family of polysaccharide graft polymers are provided as corrosion resistant coatings having antimicrobial properties which are useful on light metals such as aluminum, magnesium, zinc, steel and their alloys. Methods of making the polysaccharide graft polymers are also included. The methods of making the polysaccharide graft polymers involve reacting a polysaccharide source with an antimicrobial agent under conditions of hydrolysis-condensation.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: December 1, 1998
    Assignee: Brookhaven Science Associates
    Inventor: Toshifumi Sugama
  • Patent number: 5843532
    Abstract: A method of coating a conduit outlet fitting is disclosed. In the method, a tooling plate is positioned between a cover and a body of the conduit outlet fitting. The tooling plate has a hanger tooling block and a plug tooling block affixed thereto and positioned inside the body when the tooling plate is positioned between the body and the cover. A hanger is passed through a conduit opening and attached to the hanger tooling block. A plug is passed through another conduit opening and attached to the plug tooling block. The hanger and the plug each have a cap disposed thereon for covering an external end of their respective conduit openings. The assembled structure is suspended from the hanger and dipped into a liquid protective coating material to form an external coating thereon. The cover, the body and the tooling plate cooperate to form complementary male and female seals on the cover and the body. The dip coated structure is removed from the coating material and cured.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: December 1, 1998
    Assignee: Robroy Industries
    Inventor: John Joseph Dodds
  • Patent number: 5837078
    Abstract: A formable, weldable, VOC-free protective coating for use on a number of substrates including metal, wood, concrete, plastic, pipe and transportation equipment. The composition includes beeswax, ammonia, water and, optionally, paraffin. It may also include fillers, dyes, pigments and corrosion inhibitors, but does not require surfactants or stabilizers. The composition is particularly useful for protecting steel prior to welding. It can be removed without organic solvents.
    Type: Grant
    Filed: June 6, 1997
    Date of Patent: November 17, 1998
    Assignees: Molecular Architects, Darren E. Lowe
    Inventor: Darren E. Lowe
  • Patent number: 5830580
    Abstract: The present invention relates to a painted sheet metal part, such as a car body, with a polyacid layer between the coat of paint and the surface of the sheet metal part and to a method for applying such a coating on the part before painting. Initially, the part is cleaned and de-greased, and subsequently the polyacid layer is deposited and stabilized. In order to be able to apply this layer without losing wet adhesion qualities of the coat of paint and the anti-corrosive effect of coating layer, while presenting fewer ecological disadvantages or harmful consequences, polyacids, which comprise homopolymers or copolymers of carboxylic acids containing double bonds or of functional esters of carboxylic esters, or copolymers of carboxylic acids with vinyl compounds, are used pursuant to the present invention as the protective bonding layer. The polyacids used are further combined with polymers having a glass transition temperature above 100.degree. C.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: November 3, 1998
    Assignee: Mercedes Benz AG
    Inventors: Ute Flammer, Fritz Mezger, Anja Keller, Werner Funke
  • Patent number: 5827576
    Abstract: A hot dip coating apparatus and method for coating a continuous steel strip, wire, or like continuous member with zinc, aluminum, tin, lead, or alloys of each. A molten coating bath is contained in a vessel having a bottom opening upwardly through which the steel member is directed. Magnetic containment devices located below the vessel's bottom opening prevent the escape of molten metal from the vessel through the opening. There are no guide rolls, or other rolls that act on the continuous steel member, in the bath.
    Type: Grant
    Filed: March 21, 1997
    Date of Patent: October 27, 1998
    Assignee: Inland Steel Company
    Inventors: William A. Carter, John A. Tanski, Ismael G. Saucedo, Howard L. Gerber
  • Patent number: 5820931
    Abstract: Coating for the tube beds and heat exchanger coolant tubes extending from them, especially steam condensers, based on hardening plastic mixtures, obtainable by cleaning the surfaces provided for coating using an abrasive; closing the tube inlets and outlets with removable plugs; applying at least one layer of a hardening plastic coating on the tube bed; allowing the coating to harden so that additional mechanical processing can ensue, and processing the surface; removing the plugs from the tube inlets and outlets as well as applying at least one layer of a hardening plastic coating at least in the inlet area of the coolant tube, and allowing it to harden, coating of the coolant tubes by timed applications being done reactively to the tube bed coating and the coolant tube coating exhibiting in comparison to the tube bed coating a greater elasticity having an elongation at tear at least 2% greater in accordance with DIN 53152 with respect to the elongation at tear of the tube bed coating, and process for coatin
    Type: Grant
    Filed: October 28, 1994
    Date of Patent: October 13, 1998
    Assignee: Dipl.-Ing. Ernst Kreiselmaier Wasser-und Metall-Chemie KG
    Inventor: Richard Kreiselmaier
  • Patent number: 5811192
    Abstract: There is provided a substrate of which the surface is coated with a titanium dioxide film having a photocatalytic activity, which substrate is obtained by:depositing titanium dioxide in a film form on a surface of a substrate by contacting the substrate with a reaction solution containing ammonium titanium fluoride, water and an additive which shifts the following equilibrium reaction:(NH.sub.4).sub.2 TiF.sub.6 +2H.sub.2 O<=>TiO.sub.2 +4HF+2NH.sub.4 Ftoward a right side, andcalcining the deposited titanium dioxide film.
    Type: Grant
    Filed: September 12, 1996
    Date of Patent: September 22, 1998
    Assignee: Matsushita Electric Works, Ltd.
    Inventors: Koichi Takahama, Hirotsugu Kishimoto, Takaharu Nakagawa, Shigehito Deki, Noboru Hashimoto
  • Patent number: 5807612
    Abstract: A composition and method is described for providing conformal protective or decorative polymer coatings on metals such as aluminum, copper, iron, steel, zinc, and their by dip autopolymerization. In accordance with the present invention, an acidic solution of organic monomer undergoes autopolymerization upon contact with a metal substrate, thereby forming a polymeric coating on the substrate. The method comprises providing the acidic monomer solution, dipping the metal substrate to be coated for a prescribed period of time depending on the thickness of the coating desired, and then removing the substrate from the solution. Importantly, the polymerization requires no application of external driving force, such as thermal or electrical energy. The coatings thus formed are up to 50 microns thick, and conform to the shape of the substrate. These coatings further have uniform thickness, and excellent thermal stability and protective properties.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: September 15, 1998
    Assignee: The University of Connecticut
    Inventors: James P. Bell, Xu Zhang, Rajat Agarwal
  • Patent number: 5804252
    Abstract: A durable and extremely water- and oil repellent ultra thin film is formed on the surface of a substates such as glass, ceramics, fabrics, fur and cloth by a dehydrochlorination reaction between a functional group such as a hydroxyl group or an imino group on the surface of the substrate. The coating film of the material comprises a plurality of chlorosilyl groups was formed on the surface of the substrate by dipping and holding the substrate comprising functional groups on its surface in a solution prepared by dissolving a material comprising fluorocarbon groups and a plurality of chlorosilyl groups in a non-aqueous solvent and drying the substrate which is then taken out from the solution in a substantially moistureless or low moisture atomosphere and removing the non-aqueous solvent remaining on the substrate. Further, when the coating film is left in an atomosphere comprising moisture, i.e.
    Type: Grant
    Filed: April 1, 1996
    Date of Patent: September 8, 1998
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Kazufumi Ogawa, Mamoru Soga
  • Patent number: 5795623
    Abstract: A cover assembly and methods for covering undersink piping includes insulative cover pieces placed over respective pipe sections such that their ends are adjacent at pipe junctures. Collars are slidable over or inside the cover pieces to be moved to cover the junctures. An alternative cover structure may be wrapped around the pipe juncture to form a generally continuous insulative cover, or alternatively, the fastening structures are insulated such that when the pipe sections are assembled together, the cover pieces and insulating fastening structures form a continuous insulative cover. In an alternative embodiment, one of the cover pieces is dimensioned to slide upwardly and downwardly on a pipe section and a collar structure is placed over the exposed pipe section to provide a continuous cover piece.
    Type: Grant
    Filed: November 3, 1997
    Date of Patent: August 18, 1998
    Assignee: McGuire Manufacturing Co., Inc.
    Inventor: John A. Helmsderfer
  • Patent number: 5792518
    Abstract: The present invention relates to a pipe treatment process that is a portable, field-applied, coating process. The process produces a two-layer composite protective coating system with a finished, seamless, chemical bond within its interlayers as well as to adjacent coating materials, The process is suitable for both metailic and concrete substrates, which may or may not be cathoadically protected, and may be used to either coat now or to recoat e.g.
    Type: Grant
    Filed: October 8, 1996
    Date of Patent: August 11, 1998
    Inventors: Mark Gibson, Kenneth Fogh
  • Patent number: 5786030
    Abstract: A reaction rinse containing strong alkali, betaine surfactants, and a complexing agent for iron enhances the gloss of a dried and cured autodeposited coating that is contacted with the reaction rinse while still wet, particularly if the autodeposited coating consists predominantly of a copolymer of vinylidene chloride.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: July 28, 1998
    Assignee: Henkel Corporation
    Inventors: Bashir M. Ahmed, Douglas A. Brown, William E. Fristad
  • Patent number: 5786036
    Abstract: The invention relates to an apparatus for blowing off surplus coating material in the continuous coating of a metal band, in particular in the zinc coating of steel bands, with a pair of blow-off nozzles, between whose nozzle bodies 2, which are chargeable with a blow-off medium, in particular compressed air, the metal band 1 is guided at a distance from the nozzle orifices 3 extending transversally to the running direction of the band. To improve the axial arrangement of the metal band between the nozzle bodies 2 it is provided that at least one of the two nozzle bodies 2 which are adjustable relative to the metal band carries an optical measuring device 4a, 4b which is movable parallel to the nozzle orifice 3 covering at least the zone of an edge K of the metal band 1 and that the opposing nozzle body is provided with a reflector 11 towards which the optical axis of the measuring device 4a, 4b is directed in its position outside of the metal band edge.
    Type: Grant
    Filed: October 20, 1995
    Date of Patent: July 28, 1998
    Inventors: Heinrich Pannenbecker, Ronald Jabs
  • Patent number: 5780122
    Abstract: A solution which is stored in a treatment bath is stirred by vibration stirring means provided in the treatment bath in a range of receiving a metal molded article or around a substantially horizontal surface of the metal molded article so that mean acceleration a expressed in the following equation is at least 8 cm/sec.sup.2 : ##EQU1## where X, Y and Z, which are in units of cm/sec.sup.2, represent average acceleration values of flow rate changes within 60 seconds, measured simultaneously in three axial directions of X, Y and Z which are perpendicular to each other at a measuring position.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: July 14, 1998
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Seiichiro Shirahata, Mitsuo Shinomiya, Satoshi Miyamoto, Tamotsu Sobata
  • Patent number: 5776611
    Abstract: A hydrophilic, lubricious, durable, flexible, coating comprising a crosslinked polyurea matrix complexed with a hydrophilic polymer selected from the group consisting of poly (ethylene oxide) and polyvinylpyrrolidone, said crosslinked polymer formed from the reaction of an isocyanate and a compound having at least two active hydrogens per molecule selected from the group consisting of polyamines, polymercaptans, and polycarboxylates or compounds with NH, NH.sub.2, SH or COOH groups on same molecule in the presence of said hydrophilic polymer, with the total sum of the average isocyanate functionality plus the average active hydrogen functionality exceeding 4 and the molar ratio of total NCO groups to total active hydrogens being at least 0.8.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: July 7, 1998
    Assignee: C.R. Bard, Inc.
    Inventors: Richard Elton, Margret Opolski
  • Patent number: 5770268
    Abstract: A coating composition for preventing corrosion of a substrate including corrodable material, the coating composition comprising: a cycloaliphatic epoxy compound; a polyester compound; and a catalyst.
    Type: Grant
    Filed: January 4, 1996
    Date of Patent: June 23, 1998
    Assignee: R.J. Tower Corporation
    Inventors: Ming C. Kuo, Staer S. Kirsten, Gary W. Marshall
  • Patent number: 5766672
    Abstract: An oxygen concentration detector element 2 includes a cup-shaped solid electrolyte 20 with an inside chamber 25 opened at one end and closed at the other end. An external electrode 21 is formed on an outer surface of solid electrolyte 20 by dipping solid electrolyte 20 in first chemical plating liquid 81, while an internal electrode 22 is formed on an inner surface of solid electrolyte 20 by introducing second chemical plating liquid 82 into inside chamber 25. First, in an injecting step, an injection needle 11 is inserted into inside chamber 25 and second chemical plating liquid 82 is introduced into inside chamber 25 via injection needle 11, and then injection needle 11 is pulled out of inside chamber 25. Next, in a plating step, internal electrode 22 is formed on the inner surface of inside chamber 25 using second chemical plating liquid 82. Then, in a discharging step, residual second chemical plating liquid 82 is discharged from inside chamber 25.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: June 16, 1998
    Assignee: Nippondenso Co., Ltd.
    Inventors: Yasumichi Hotta, Hiromi Sano, Namitsugu Fujii, Naoto Miwa
  • Patent number: 5756218
    Abstract: Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds.
    Type: Grant
    Filed: January 9, 1997
    Date of Patent: May 26, 1998
    Assignee: Sandia Corporation
    Inventors: Rudolph G. Buchheit, Michael A. Martinez
  • Patent number: 5747727
    Abstract: A metal oxide layer is provided around a thermocouple element. The metal oxide layer is formed by preparing a sol, in which particulates of a metal oxide are dispersed, by a sol-gel method, dipping the thermocouple element in this sol, energizing the thermocouple element as a cathode for bonding the precursor particulates of the metal oxide thereto, and heat treating the same. The thermocouple according to the present invention is compact with a thin insulating layer, excellent in flexibility, and provides no gas adsorption source.
    Type: Grant
    Filed: April 25, 1997
    Date of Patent: May 5, 1998
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Kazuo Sawada, Shinji Inazawa, Kouichi Yamada
  • Patent number: 5736202
    Abstract: The method of providing molten bronze for cladding onto steel strip, wherein the raw material for the product consists of bronze in wire form. The wire is fed at a controlled rate into a cylindrical refractory tube that has induction coils wrapped around the outside. Wire is progressively heated, melted and discharged from the refractory tube through a spout directly onto a moving steel strip to thereby achieve the desired steel/bronze laminate.
    Type: Grant
    Filed: December 30, 1996
    Date of Patent: April 7, 1998
    Assignee: Glacier Vandervell, Inc.
    Inventor: Nigel J. Chivers
  • Patent number: 5725905
    Abstract: A method for selectively protecting a component made of an iron-base alloy, cobalt-base alloy or nickel-base alloy with a protective arrangement which protects select areas of the component from aluminizing or chromizing during gas diffusion coating, wherein a first layer acts as an interlayer and a second layer acts as a getter layer for reaction gases. The method comprises the steps of depositing a first layer of slip cast material comprising oxide ceramic particles carried in a low-carbon, halide free, liquid vehicle; depositing a second layer comprising metal or a metallic slip, which comprises at least 50% by weight of the base metal of the component and all major alloy constituents of the component; aluminizing or chromizing by gas diffusion coating; and removing the protective arrangement from the component.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: March 10, 1998
    Assignee: MTU Motoren- Und Turbinen-Union
    Inventors: Heinrich Walter, Horst Pillhofer, Michael Strasser, Frank Brungs, Ralph Kropp, Martin Schaipp
  • Patent number: 5723180
    Abstract: A method for applying a coating of a corrosion resistant material to an individual vehicle frame component or to an assembled vehicle frame structure includes the initial step of heating the vehicle frame component to a predetermined temperature, such as by passing it through a furnace. Then, a coating of a first corrosion resistant material, such as wax, is applied to the vehicle frame. Preferably, the coating of the first wax is applied to the vehicle frame structure by dipping it in a hot bath of the first wax material. The vehicle frame structure is then removed from the bath, and heat is maintained thereon to allow excess first wax to drip off. A coating of a second corrosion resistant material, such as wax, is then applied at localized areas of the vehicle frame structure in place of the first wax coating. The first wax can be removed by any suitable method, such as by scraping, dissolving, or masking the localized area of the vehicle frame structure.
    Type: Grant
    Filed: December 30, 1996
    Date of Patent: March 3, 1998
    Assignee: Dana Corporation
    Inventor: Peter D. Boulanger
  • Patent number: 5716672
    Abstract: There are provided methods of lining the internal surface of a pipe, which includes first inserting two lining pigs into the pipe and then introducing a batch of resin thereinto, or inserting one lining pig between two batches of a resin, or first inserting a lining pig and then inserting two batches of a resin with another lining pig therebetween, or first introducing a lining pig made of a soft material capable of deforming so as to pass through a narrow-passing section and then introducing a batch of a resin into the pipe, causing the resin to move forward until the front end of the resin reaches an inner end of the pipe, and sucking the resin back from the inner end so as to line the internal surface of the pipe with the resin. There are also provided improved liquid blocking pigs for use in pipe lining treatment, each of such pigs comprises a spherical body made of a soft resilient material and a least one flexible liquid barrier diaphragm interposed in the spherical body.
    Type: Grant
    Filed: November 6, 1996
    Date of Patent: February 10, 1998
    Assignee: Tokyo Gas Co., LTD.
    Inventors: Shigeru Toyoda, Shuichi Yagi, Masaaki Itagaki
  • Patent number: 5711996
    Abstract: Aqueous coating compositions are described which comprise(A) at least one cyclic hydroxy compound selected from the group consisting of cyclic polyhydroxy compounds and substituted phenols;(B) phosphate ions;(C) at least one oxidizer-accelerator; and(D) water.The coating compositions also may contain fluoride ions and/or iron. A method of improving the corrosion resistance of iron, steel, and zinc-coated surfaces also is described, and the method comprises contacting the surfaces with an aqueous acidic coating composition as described above. The coated metal surfaces may be subsequently provided with an organic or inorganic top-coat or seal-coat resulting in improved corrosion resistance, adhesion and detergent resistance properties.
    Type: Grant
    Filed: September 28, 1995
    Date of Patent: January 27, 1998
    Assignee: Man-Gill Chemical Company
    Inventor: William J. Claffey
  • Patent number: 5698267
    Abstract: A method for fabricating a high-activity cermet electrode which is applied on an exhaust gas sensor including an oxygen ion conducting solid electrolyte, which is composed of a cermet material composed of at least one catalytically active material and at least one oxygen ion conducting ceramic material, which is bonded to the solid electrolyte of the exhaust sensor by co-sintering the cermet electrode and the solid electrolyte at a temperature ranging from 1300.degree. to 1600.degree. C. to provide a porous cermet electrode, and which contains at least one further catalytically active material which is embedded in the pores of the porous cermet electrode after co-sintering, the method including bonding together an unsintered solid electrolyte which conducts oxygen ions and a cermet electrode by co-sintering at from 1300.degree. to 1600.degree. C. to provide a porous cermet electrode; and subsequently introducing at least one further catalytically active material into pores of the porous cermet electrode.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: December 16, 1997
    Assignee: Robert Bosch GmbH
    Inventors: Karl-Hermann Friese, Hans-Martin Wiedenmann, Frank Stanglmeier
  • Patent number: 5693372
    Abstract: A process for dip coating drums comprising providing a drum having an outer surface to be coated, an upper end and a lower end, providing at least one coating vessel having a bottom, an open top and a cylindrically shaped vertical interior wall having a diameter greater than the diameter of the drum, flowing liquid coating material from the bottom of the vessel to the top of the vessel, immersing the drum in the flowing liquid coating material while maintaining the axis of the drum in a vertical orientation, maintaining the outer surface of the drum in a concentric relationship with the vertical interior wall of the cylindrical coating vessel while the drum is immersed in the coating material, the outer surface of the drum being radially spaced from the vertical interior wall of the cylindrical coating vessel, maintaining laminar flow motion of the coating material as it passes between the outer surface of the drum and the vertical interior wall of the vessel, maintaining the radial spacing between the outer
    Type: Grant
    Filed: February 29, 1996
    Date of Patent: December 2, 1997
    Assignee: Xerox Corporation
    Inventors: Alan B. Mistrater, Steven J. Grammatica, Peter J. Valianatos, Timothy J. Leenhouts, April M. Mattox, Rachael A. Forgit, John S. Chambers, Roger T. Janezic, Leslie B. Cummins, Richard C. Petralia, Edward C. Williams, Mark S. Thomas, John T. Dilko, John K. Williams
  • Patent number: 5693371
    Abstract: Methods for providing a conversion coating to a metal surface are provided. The methods comprise applying to a metal surface an aqueous composition comprising a diglycidyl ether of Bisphenol A, a fluoacid, and a silicon compound containing a hydrolyzable group.
    Type: Grant
    Filed: October 16, 1996
    Date of Patent: December 2, 1997
    Assignee: BetzDearborn Inc.
    Inventors: Edward A. Rodzewich, Jiangbo Ouyang, Joseph E. Murphy
  • Patent number: 5693050
    Abstract: An electrosurgical instrument comprising a work implement having a medically acceptable working edge with a plurality of layers of different compositions including an inner primer layer with an electrically conductive polymer with a coating thickness of about 0.3 mil, an intermediate layer having a coating thickness of about 0.1 mil, and an outer protective layer having a low coefficient of friction with a thickness of about 0.3 mil to reduce the adhesion of charred tissue during surgical procedures involving cauterization or cutting of tissue utilizing high frequency electrical energy as the source of power.
    Type: Grant
    Filed: November 7, 1995
    Date of Patent: December 2, 1997
    Assignee: Aaron Medical Industries, Inc.
    Inventor: Eric N. Speiser
  • Patent number: 5683816
    Abstract: Zinciferous and/or aluminiferous metal surfaces can be passivated by treatment with a chromium-free aqueous solution of phosphoric acid and molybdenum that is at least partially in a valence state lower than +6, to produce, especially with an acrylic overcoating, a surface as resistant to corrosion as the surface of the same substrate after passivation with conventional liquid compositions that contain hexavalent chromium.
    Type: Grant
    Filed: January 23, 1996
    Date of Patent: November 4, 1997
    Assignee: Henkel Corporation
    Inventor: Bruce H. Goodreau
  • Patent number: 5679402
    Abstract: A mass of ferromagnetic particles encapsulated in a polymeric shell having a plurality of denuded organic lubricant particles adhering to the surface of the shell so as to stand in relief from said surface unimpaired by the polymer or any other binder.
    Type: Grant
    Filed: September 23, 1996
    Date of Patent: October 21, 1997
    Assignee: General Motors Corporation
    Inventor: Howard Hong-Dough Lee
  • Patent number: 5667844
    Abstract: A process for treating cutting tools to extend the useful duty cycles of the tools by immersing the tools to be treated in a bath of a solvent in sufficient amounts and at a temperature to remove contamination from the surface of the tools and to coat the tool surfaces with perfluoroethylene. The solvent and perfluoroethylene resin are circulated throughout the immersed tools for a time sufficient to coat the surfaces with polyfluoroethylene resin.
    Type: Grant
    Filed: July 25, 1996
    Date of Patent: September 16, 1997
    Assignee: Macro Specialty Industries, Inc.
    Inventors: Morton R. Smith, James L. Maassel
  • Patent number: 5667841
    Abstract: There are provided methods of lining the internal surface of a pipe, which includes first inserting two lining pigs into the pipe and then introducing a batch of resin thereinto, or inserting one lining pig between two batches of a resin, or first inserting a lining pig and then inserting two batches of a resin with another lining pig therebetween, or first introducing a lining pig made of a soft material capable of deforming so as to pass through a narrow-passing section and then introducing a batch of a resin into the pipe, causing the resin to move forward until the front end of the resin reaches an inner end of the pipe, and sucking the resin back from the inner end so as to line the internal surface of the pipe with the resin. There are also provided improved liquid blocking pigs for use in pipe lining treatment, each of such pigs comprises a spherical body made of a soft resilient material and a least one flexible liquid barrier diaphragm interposed in the spherical body.
    Type: Grant
    Filed: November 6, 1996
    Date of Patent: September 16, 1997
    Assignee: Tokyo Gas Co., Ltd.
    Inventors: Shigeru Toyoda, Shuichi Yagi, Masaaki Itagaki
  • Patent number: 5667845
    Abstract: A process enhances corrosion resistance of autodeposited coatings on metallic surfaces by contacting the uncured coating on the metallic surface with a reaction rinse solution containing complex fluoride anions. In a preferred use, because the protective properties of the autodeposited coatings are improved on both cold rolled and galvanized steel, both may be processed simultaneously, providing practical and economic advantages.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: September 16, 1997
    Assignee: Henkel Corporation
    Inventors: Oscar E. Roberto, Shawn E. Dolan
  • Patent number: 5665160
    Abstract: An air knife device for regulating the thickness of a layer deposited on a strip at the output of a bath, comprising at least one nozzle defined by two lips spaced a small distance apart, the nozzle being supplied with pressurized fluid in order to blow at least one flat jet of fluid onto the strip. The device is associated with at least one fluid cushion stabilizer arranged on at least one side of the nozzle along one of its lips and comprising a substantially flat wall extending from this lip in a direction substantially parallel to the strip so as to define a thin, flat space between the wall and the strip. A fluid is introduced into this space for the formation of a fluid cushion which is able to stabilize the vibrations of the strip.
    Type: Grant
    Filed: October 26, 1995
    Date of Patent: September 9, 1997
    Assignee: Kvaerner Clecim
    Inventors: Jean Davene, Laurent Dondin
  • Patent number: 5660874
    Abstract: Corrosion by water of mild steel pipe is inhibited by the controlled addition of NaHCO.sub.3 to the water (containing calcium ions) in sufficient amounts to induce corrosion and form scale. The scale deposits on the pipe at the corrosion sites form a protective film thereon. The addition of the NaHCO.sub.3 is controlled by the use of corrosion electrode probes placed in the pipe.
    Type: Grant
    Filed: February 14, 1996
    Date of Patent: August 26, 1997
    Assignee: Nalco/Exxon Energy Chemicals, L.P.
    Inventors: Anthony R. Pitochelli, Lawrence M. Cenegy, James D. Watson, John G. Garcia, Jr.
  • Patent number: 5641542
    Abstract: A method of forming a protective coating on aluminum and aluminum alloy surfaces to improve adherence of siccative coatings such as inks, paints, and lacquers. The method involves rinsing acid treatments from aluminum surfaces followed by coating the aluminum surfaces with a polymeric composition. The method provides improved adhesion of siccative coverings to treated aluminum surfaces over chrome containing and non-chrome containing fluoroacid and polymer mixture treatments.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: June 24, 1997
    Assignee: BetzDearborn Inc.
    Inventors: Jeffrey I. Melzer, Barry P. Gunagan
  • Patent number: 5637441
    Abstract: A mechanically and/or electrochemically grained and optionally anodized base material composed of aluminum or its alloys, to which a hydrophilic layer of at least one polymer containing basic and acidic groups is applied. This layer is followed by a further hydrophilic layer which contains at least one compound containing at least one phosphono group. In addition, the invention relates to a method of producing said carrier material and to photosensitive recording material for offset printing plates produced therewith.
    Type: Grant
    Filed: June 19, 1995
    Date of Patent: June 10, 1997
    Assignee: AGFA-Gevaert AG
    Inventors: Michael Brenk, Mathias Eichhorn, Andreas Elsaesser
  • Patent number: 5631845
    Abstract: A phosphate bath control system and method is provided that tracks the set points of one or more of the major process variables of the phosphate bath independently of variations in the production conditions. A detector determines the current values of Zinc, Manganese and Total Acid provides data to a controller which exponentially filters the data and processes the filtered data in accordance with fuzzy logic rules. The controller periodically updates the flow rate of one or more pumps that control the flow of liquid concentrates to the bath in order to maintain a desired concentration of the various constituents of the bath. Control of an accelerator is provided by incorporating in the controller an additional algorithm for indirect estimation of the accelerator concentration based on a math model which represents the material balance of the accelerator in the bath.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: May 20, 1997
    Assignee: Ford Motor Company
    Inventors: Dimitre P. Filev, Irena A. Nagisetty, Alan E. Hyrila, John Huff, Robert A. Sensoli, John C. Cooper
  • Patent number: RE35576
    Abstract: Aluminum and aluminum alloys are protected from corrosion by immersion in an alkaline lithium or alkaline magnesium salt solution. Immersion in the salt solution causes the formation of a protective film on the surface of the aluminum or aluminum alloy which includes hydrotalcite compounds. A post film formation heat treatment significantly improves the corrosion resistance of the protective film.
    Type: Grant
    Filed: September 28, 1995
    Date of Patent: July 29, 1997
    Assignee: Center for Innovative Technology
    Inventors: Rudolph G. Buchheit, Jr., Glenn E. Stoner
  • Patent number: RE35688
    Abstract: A rinse solution for the treatment of conversion-coated metal substrates for improving the adhesion and corrosion resistance of siccative coatings, comprising an aqueous solution of zirconium ion and an organosilane selected from the group consisting of .?.3-glycidoxypropyltrimethoxysilane,.!. methyltrimethoxysilane, .?..gamma.-methacryloxytrimethoxysilane,.!. phenyltrimethoxysilane, and mixtures thereof, with the zirconium ion concentration selected to provide a pH about 2.0 to 9.0. A method for treating such materials by applying the rinse solution to the substrate.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: December 16, 1997
    Assignee: Brent America, Inc.
    Inventor: George J. Gorecki