Metal Coating Patents (Class 427/436)
  • Patent number: 5330700
    Abstract: A porous electrode for pacemakers is comprised of a plurality of platinum globules sintered together to form a porous mass of semi-hemispherical shape at the end of a platinum electrode stem. The globules, which are themselves made by sintering together spherically-shaped particles of approximately one micron diameter, provide the globules with an irregular outer surface of high total surface area. The globules have diameters within a critical range of 40-200 microns. The large total surface area of the globules improves the sensing function of an electrode configuration of given size and surface area, while the globule diameters of 40-200 microns have been found to beneficially accommodate tissue ingrowth within the electrode. In a preferred method of making the electrode, the platinum globules, which are formed by sintering together platinum particles of much smaller size, are mixed with organic solvent and organic binder to form a paste.
    Type: Grant
    Filed: September 18, 1991
    Date of Patent: July 19, 1994
    Assignee: Siemens Pacesetter, Inc.
    Inventors: Thomas M. Soukup, Paul E. Kreyenhagen
  • Patent number: 5284680
    Abstract: A method for producing ultra-high strength galvanized steel strip from a martensitic, plain carbon, steel strip which is pre-treated by induction heating rapidly or by fluxing, then hot dip galvanized and tempered, and then cooled to stop further tempering. The resulting galvanized steel strip has a microstructure comprising tempered martensite, a tensile strength substantially greater than 120,000 psi (827 MPa) and a coating weight substantially greater than 30 g/m.sup.2 /side.
    Type: Grant
    Filed: April 27, 1992
    Date of Patent: February 8, 1994
    Assignee: Inland Steel Company
    Inventor: Yaz F. Bilimoria
  • Patent number: 5275891
    Abstract: The R-TM-B permanent magnet member having an improved corrosion resistance comprising an R-TM-B permanent magnet body provided with a nickel plating layer and then with a chromate coating layer, which may be then subjected to an immersion treatment in an alkali solution.
    Type: Grant
    Filed: October 4, 1991
    Date of Patent: January 4, 1994
    Assignee: Hitachi Metals, Ltd.
    Inventors: Atsushi Tagaya, Motoharu Shimizu
  • Patent number: 5234714
    Abstract: A chromate/silicate surface treatment for providing an aluminum heat exchanger with a corrosive-resistent hydrophilic coating. The subject process includes sequentially immersing an aluminum heat exchanger in a series of chemical solutions. The chemical solutions include a cleaning solution, followed by a rinse solution, chromate solution, additional rinse solution, and a silicate solution. The chemical concentrations of the cleaning solution, chromate solution and silicate solution are precisely controlled in order to avoid producing a coating which emits a musty odor.
    Type: Grant
    Filed: December 30, 1992
    Date of Patent: August 10, 1993
    Inventors: Bipin B. Patel, Steven J. Rasso, Jr.
  • Patent number: 5232740
    Abstract: A method of manufacturing plated hollow metallic blocks for further processing into seamless tubes of the type in which a body is immersed one or more times into a melt includes: protecting the inner surfaces of a hollow body of plating material against the admission of a melt of support material during the immersion of the hollow body in the melt of support material; immersing such hollow body formed of plating material into the melt of support material; removing the hollow body from the melt of support material; and crystallizing a layer of support material on the outer surface of the hollow body.
    Type: Grant
    Filed: November 13, 1991
    Date of Patent: August 3, 1993
    Assignee: Mannesmannufer Aktiengesellschaft
    Inventors: Ingo Von Hagen, Christoph Prasser, Fritz P. Pleschiutschnigg, Lothar Parschat
  • Patent number: 5217759
    Abstract: A process for continuous dip coating of a steel strip by passing it through a zinc bath containing aluminum and silicon wherein the aluminum content is approximately 55% by weight, the silicon content is 1% to 2% by weight, and the bath further includes strontium in a quantity in the range of 0.0001% to 0.2% by weight and at least one other element selected from among vanadium in a quantity in the range of 0.02% to 0.2% by weight and chromium in the range of 0.005% to 0.2% by weight. The addition of strontium and chromium and/or vanadium stabilizes the structure of the coating and reduces the formation of acicular precipitates of silicon. The coating has an improved adherence and ductility which permits it to be formed without cracking, while retaining an excellent resistance to corrosion. The resulting crystallization pattern of the coating is also finer and more regular and is independent of the substrate.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: June 8, 1993
    Assignee: Centre de Recherches Metallurgiques-Centrum Voor Research in de Metallurgie
    Inventors: Marcel Lamberigts, Vincent Leroy
  • Patent number: 5211831
    Abstract: A stabilized spray displacement tin plating process of copper printed circuit innerlayers is disclosed for the manufacture of multilayer printed circuit boards. During prolonged use of spray tin plating, the plating solution becomes saturated with cupurous thiourea complex which precipitates interfering with spray nozzles and other mechanical components. The tin plating solution is stabilized by removing portions from the reservoir before saturation is reached, selectively precipitating the thiourea complex, and returning the remaining solution back to the reservoir. The precipitated cupurous thiourea complex is redissolved in acid and either disposed of by conventional waste treatment or the acid solution can be electrowinned to reclaim copper and oxidize thiourea to form a more acceptable acid solution for waste treatment.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: May 18, 1993
    Assignee: McGean-Rohco, Inc.
    Inventors: Americus C. Vitale, Carl W. Reinbold, Randal D. King, John R. Dodd
  • Patent number: 5182006
    Abstract: A method for producing smooth metal coatings on zincated aluminum substrates using a specially formulated zincating bath containing an additive comprising a bath soluble cationic condensation polymer represented by the general formula: ##STR1## wherein: Z represents a group of atoms necessary to complete a heterocylic compound having a five or six membered ring containing at least 2 nitrogen atoms;R is nothing or the alkyl group of an alkylating agent;X is Cl, Br or I, andn is >1.
    Type: Grant
    Filed: February 4, 1991
    Date of Patent: January 26, 1993
    Assignee: Enthone-OMI Inc.
    Inventors: Juan Haydu, Vincent Paneccasio, Jr., Patricia A. Cacciatore
  • Patent number: 5178918
    Abstract: Deposition of gold without the use of electric current is described. The system produces thick gold films without the use of strong reducing agents. Discontinuous land areas on high reliability printed wiring boards or ceramic circuits can be readily coated with gold to any desired thickness. Long lead glass-to-metal seals can be uniformly plated without distortion of the leads.
    Type: Grant
    Filed: September 13, 1991
    Date of Patent: January 12, 1993
    Inventors: Robert Duva, George Ondecker
  • Patent number: 5176812
    Abstract: A copper fin material for heat-exchangers is characterized in that, on the surface of Cu or Cu alloy strip, an inner side diffused layer comprising Cu and Zn and a surface side diffused layer provided on the surface side thereof comprising Cu, Zn and elements with a lower diffusion coefficient into Cu than that of Zn is formed. A method of producing the same is characterized in that, after an alloy film comprising Zn and element with a lower diffusion coefficient into Cu than that of Zn is formed on the surface of a Cu or Cu alloy strip, a diffusion treatment is performed under heat so that, on the surface of the Cu or Cu alloy strip, an inner side diffused layer comprising Cu and Zn and a surface side diffused layer provided on the surface side thereof comprising Cu, Zn and elements with a lower diffusion coefficient into Cu than that of Zn are formed. Alternatively, the diffusion treatment under heat is combined with a rolling processing step.
    Type: Grant
    Filed: July 29, 1991
    Date of Patent: January 5, 1993
    Assignees: The Furukawa Electric Co., Ltd., Nippondenso Co., Ltd.
    Inventors: Hideo Suda, Norimasa Sato, Katsuhiko Takada, Sumio Susa, Yasushi Aiyoshizawa, Kenichi Omata
  • Patent number: 5175022
    Abstract: A metal fuel for producing power for propulsion is disclosed. The fuel is made up of a metal core, a metal barrier and an oxidizer layer. The combination of materials disclosed provides a means for melting the metal core so that it can be oxidized in an exothermic reaction to produce power. The metal fuel may also be stabilized with respect to auto-ignition by adding a binder layer. A method for producing the metal fuel is also described herein.
    Type: Grant
    Filed: July 19, 1991
    Date of Patent: December 29, 1992
    Assignee: Alliant Techsystems Inc.
    Inventors: Mark E. Stout, Gary G. Wittmer
  • Patent number: 5175026
    Abstract: A method of pretreating and hot-dip coating aluminum or aluminum alloys on a chromium-containing steel strip to provide an improved coating comprising annealing final gauge steel strip in an oxygen excess atmosphere to produce a chromium-rich oxide on the surface and thereafter electrolytically descaling the strip in an aqueous salt solution to remove the oxide and to expose a chromium depleted surface of the strip. The strip is then transported to a coating line where it is heated to a temperature at or above the temperature of a bath of aluminum or aluminum alloy. A substantially hydrogen atmosphere is maintained over the bath while the dew point is maintained below minus 35.degree. C. The strip is then drawn through the bath to coat the strip.
    Type: Grant
    Filed: July 16, 1991
    Date of Patent: December 29, 1992
    Assignees: Wheeling-Nisshin, Inc., Allegheny Ludlum Corporation
    Inventors: William A. Bertol, Yoshio Hayashi, James B. Hill, Eisuke Otani, Donald R. Zaremski, John P. Ziemianski
  • Patent number: 5173109
    Abstract: An acid solution for displacement plating of a reflowable tin lead alloy having a melting point not exceeding 500.degree. F. over a cupreous surface. The displacement plating solution contains stannous ions in an amount of from 0.05 to 0.50 moles per liter, plumbous ions in an amount of from 0.01 to 0.15 moles per liter, a total content of stannous ions and plumbous ions in an amount of from 0.05 to 0.60 moles per liter and a ratio of stannous ions to plumbous ions varying from about 1.0:3.0 to 50.0:1.0. The solution is characterized by an ability to plate the tin lead alloy at a plating rate of at least 100 microinches per 15 minutes. The deposit obtained is capable of reflow and is useful in the manufacture of printed circuit boards.
    Type: Grant
    Filed: October 3, 1991
    Date of Patent: December 22, 1992
    Assignee: Shipley Company Inc.
    Inventor: Richard Iantosca
  • Patent number: 5169692
    Abstract: A process for replenishing a tin-lead alloy displacement plating solution which comprises periodically adding complexing agent to the solution during use of the same to bring the total concentration of complexing agent to an amount sufficient to ensure adhesion of the deposit to its underlying substrate.
    Type: Grant
    Filed: November 19, 1991
    Date of Patent: December 8, 1992
    Assignee: Shipley Company Inc.
    Inventors: Edward C. Couble, Steven M. Florio, Richard F. Staniunas
  • Patent number: 5164235
    Abstract: A process for imparting tarnish resistance to copper and copper alloy materials, particularly copper foil. The material is first treated with an acidic chromium-containing solution to deposit chromium ions on said foil. Thereafter the material is treated with a basic zinc ion containing solution to deposit zinc ions thereon. Finally, the material is rinsed in distilled water to remove any residual basic solution.
    Type: Grant
    Filed: March 6, 1990
    Date of Patent: November 17, 1992
    Assignee: Olin Corporation
    Inventor: Chung-Yao Chao
  • Patent number: 5143750
    Abstract: According to the invention, a chemically adsorbing material is reacted with a substrate surface having active hydrogen groups by dipping the substrate into a solution of the chemically adsorbing material simultaneous and applying ultrasonic waves to the solution. In this way, a high concentration monomolecular and/or polymer film substantially free from pin holes can be formed in a short period of time. That is, while the ultrasonic waves are applied, a chemical adsorbing material having an end functional chlorosilyl group is adsorbed onto the substrate surface, thereby forming a chemically adsorbed monomolecular and/or polymer film. The frequency of the ultrasonic waves are suitably in a range of 25 to 50 kHz. In addition, after formation of the adsorbed film, the substrate is washed for making monomolecular film by dipping it in a washing solution while applying ultrasonic waves. In this way, non-reacted chemical adsorbing material remaining on the substrate can be efficiently washed away.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: September 1, 1992
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yoshikazu Yamagata, Norihisa Mino, Kazufumi Ogawa, Mamoru Soga
  • Patent number: 5120577
    Abstract: An electronic component chip holder employed for coating metallized surfaces on both longitudinal ends of a plurality of electronic component chips with a metal such as solder, while holding the same. The holder comprises a plurality of holding portions for holding the electronic component chips one by one. Each of the holding portions is defined by a through hole, and each of the electronic component chips is inserted in the holding so as to be longitudinally aligned with the axis of the through hole. An elastic member is formed on an inner peripheral surface defining each holding portion, to elastically hold a longitudinal intermediate portion of each electronic component chip. A plurality of electronic component chips thus held by the holder are collectively dipped in a molten bath of a metal such as solder, so that coating films of such a metal are formed on the metallized surfaces.
    Type: Grant
    Filed: April 30, 1990
    Date of Patent: June 9, 1992
    Inventors: Masami Yamaguchi, Kenji Minowa
  • Patent number: 5114750
    Abstract: Compositions and a process are disclosed for producing tungsten and tungsten nitride coatings on metals or ceramics, utilizing a tungsten-containing metal-organic precursor compound dissolved in an organic solvent. Conversion of the precursor compound to a tungsten or tungsten nitride coating is accomplished by heating the coated metal or ceramic to a temperature of about 600.degree.-1200.degree. C. under a nitrogen or other inert gas atmosphere.
    Type: Grant
    Filed: November 6, 1990
    Date of Patent: May 19, 1992
    Assignee: The Dow Chemical Company
    Inventor: Kevin E. Howard
  • Patent number: 5114751
    Abstract: A process forming an organic coating, such as an autodeposited coating, on a plurality of small metallic articles by contacting the articles with a liquid coating composition containing an organic film-forming material comprising:(A) providing a plurality of said articles, with at least some of the articles being in contact with at least one other of said articles;(B) immersing the articles into a bath of said composition under conditions such that said articles are not in conttact with another article in said composition;(C) maintaining said articles in separated form in said composition for a period of time sufficiently long for the entirety of the surfaces of said articles to be coated with said composition; and(D) collecting the coated articles in the bath in a form in which at least some of the coated articles are in contact with another of said coated articles;wherein the coating composition is capable of forming on a steel panel immersed therein a coating having a wet strength such that its rinse resis
    Type: Grant
    Filed: September 6, 1991
    Date of Patent: May 19, 1992
    Assignee: Henkel Corporation
    Inventors: Bashir M. Ahmed, Barry P. Gunagan, Wilbur S. Hall
  • Patent number: 5104688
    Abstract: Metallic surfaces to be provided with a tin-lead coating from an immersion tin-lead bath, and particularly copper surfaces (e.g., through-holes, pads) of a printed circuit board having other metallic surfaces thereon covered by a hydrophobic solder mask, are prepared for receipt of immersion tin-lead coating by, e.g., contact thereof with a strongly acidic aqueous pre-dip solution containing at least one surface active agent functional to reduce the surface tension of the pre-dip solution and/or to provide the solution with improved affinity for the metallic surface.
    Type: Grant
    Filed: June 4, 1990
    Date of Patent: April 14, 1992
    Assignee: MacDermid, Incorporated
    Inventors: Donald R. Ferrier, Barry H. Williams
  • Patent number: 5102700
    Abstract: Pyrophorically activated aluminides of iron, nickel and cobalt, or mixtures thereof, are formed as discs or as coatings on substrates such as thin foils. The aluminide can be formed in situ by reacting aluminum powder with the aluminide-forming metal. Mixtures of these reactants can be applied to a substrate as such or suspended in a liquid like water or volatilizable organic liquids. Water is preferably used with a little binder such as an alkali metal silicate. An inhibitor is used to keep the water from reacting with finely-divided aluminum, and those silicates also perform such function. The pyrophoric products can be discharged to decoy heat-seeking missiles, or they can have their pyrophoricity destroyed to make catalysts. Pyrophoric action can be heightened by additives such as boron, and by post treatment with mild acid.
    Type: Grant
    Filed: November 1, 1990
    Date of Patent: April 7, 1992
    Assignee: Alloy Surfaces Company, Inc.
    Inventor: Alfonso L. Baldi
  • Patent number: 5102697
    Abstract: A structural component of titanium or titanium alloy is provided with a protective coating made substantially of an oxidation resistant and diffusion inhibiting base layer (2), an intermediate layer (3) forming a titanium fire inhibiting layer, and a cover layer (4) forming a passivating sealing layer. These layers are applied by various methods.
    Type: Grant
    Filed: November 2, 1990
    Date of Patent: April 7, 1992
    Assignee: MTU Motoren- und Turbinen-Union Muenchen GmbH
    Inventors: Richard Grunke, Lothar Peichl, Franz Puchinger, Gerhard Wydra
  • Patent number: 5091223
    Abstract: Zinciferous surfaces, particularly those of galvanized steel, may be effectively coated with an adherent corrosion resistant black layer of fine metal particles by contacting the surfaces with an aqueous solution containing (A) at least 0.5 g/L of the treatment solution of Ni.sup.2+ and/or Co.sup.2+ ions; and (B) an amount, sufficient to complex all the ions of component (A), of a weak complexing component selected from the group consisting of ammonia, saturated aliphatic compounds having at least two amino groups of which at least one is a primary amino group, and/or amino acids; and, optionally but preferably, (C) at least 50 parts per million ("ppm") by weight of a component selected from the group consisting of nitrite ions, nitrate ions, carbonate ions, thiocyanate ions, thiosulfate ions, thiourea, hypophosphite ions, phosphite ions, and/or perchlorate ions.
    Type: Grant
    Filed: June 27, 1990
    Date of Patent: February 25, 1992
    Assignee: Henkel Corporation
    Inventors: Kazuhiko Mori, Toshi Miyawaki, Hitoshi Ishii
  • Patent number: 5091225
    Abstract: An improved magnetic disc member for use in a magnetic disc device, said member comprising a base plate, a number of fine noble metal particles adhered to a surface thereof to form microprotuberances and a nonmagnetic layer coated further thereon; the surface roughness of the member being controlled by changing a thickness of the nonmagnetic layer.
    Type: Grant
    Filed: August 23, 1989
    Date of Patent: February 25, 1992
    Assignee: NEC Corporation
    Inventor: Fumio Goto
  • Patent number: 5087300
    Abstract: First, a steel wire is continuously dipped in molten copper or molten copper alloy so that copper or copper alloy builds up and solidifies on the peripheral surface of said steel wire, thereby obtaining an initial copper-clad steel wire. Then, the initial copper-clad steel wire is subjected to a first cycle of hot rolling by a caliber roll. The hot-rolled wire is dipped in molten copper or molten copper-alloy at least once so that copper or copper alloy builds up and solidifies thereon, thereby obtaining a final copper-clad steel wire.The final copper-clad steel wire is hot-rolled at a temperature of 750.degree. to 850.degree. C. and with a rolling ratio of 10 to 40%. Then, the hot-rolled wire is cold-rolled with a reduction of area of 20% or more.Thus, 75 to 95% of the cross sectional area of the obtained copper-clad steel trolley wire is occupied by the copper or copper alloy covering layer so that the electric conductivity of the trolley wire is as high as 80% IACS or more.
    Type: Grant
    Filed: August 22, 1990
    Date of Patent: February 11, 1992
    Assignee: Fujikura Ltd.
    Inventors: Teruyuki Takayama, Hiroki Nagasawa, Sumihisa Aoki, Haruo Tominaga, Kazuo Yokoyama
  • Patent number: 5077094
    Abstract: A process for applying a metal coating 11 to a metal strip substrate 2 by preheating the casting surface in a non-oxidizing atmosphere and maintaining a casting surface temperature T.sub.s below the solidus temperature of the metal coating material, passing the casting surface through a melt pool 9 of the metal coating material at a pool temperature at least 25.degree. C. in excess of its melting temperature to deposit a melt layer 21 at a casting temperature T.sub.c, and simultaneously rapidly cooling the metal strip substrate from the back surface to solidify the melt layer to an adherent solid coating, wherein the surface temperature T.sub.s is less than about 20 percent (in .degree.K.) below the casting temperature T.sub.c.The process is particularly useful when coating metal strip with an alloy of limited solubility metals.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: December 31, 1991
    Assignee: Battelle Development Corp.
    Inventors: James L. McCall, Robert E. Maringer
  • Patent number: 5068134
    Abstract: This invention is directed to a process of protecting galvanized metal from white rust corrosion which comprises treating the galvanized metal, i.e., zinc-containing coating, at a temperature above about 125.degree. C. with at least one silica compound.
    Type: Grant
    Filed: December 19, 1989
    Date of Patent: November 26, 1991
    Assignee: Zaclon Corporation
    Inventors: James A. Cole, William O. Roberts, Joseph T. Turgeon
  • Patent number: 5066380
    Abstract: Cathodes useful in electrolytic cells, such as a chlor-alkali cell, are disclosed which have a metallic-surfaced substrate coated with an electrocatalytic coating. The electrocatalytic coating includes palladium and at least one primary electrocatlaytic metal, such as a platinum group metal. The coating optionally includes at least one secondary electrocatalytic metal, such as nickel, cobalt, iron, copper, manganese, molybdenum, cadmium, chromium, tin and silicon. Also disclosed is a non-electrolytic reduction method for preparing the cathodes. The method provides a tightly adherent coating, improves electrocatalyst loading and reduces cathode production costs.
    Type: Grant
    Filed: May 29, 1990
    Date of Patent: November 19, 1991
    Assignee: The Dow Chemical Company
    Inventors: Carl E. Byrd, Stephen L. Kelly, Richard N. Beaver
  • Patent number: 5061522
    Abstract: In the gas jet wiping of galvanized wire strip or tube the gas jet wiping nozzle and, preferably a reactive gas containment vessel used for modifying the surface coating on the wire, are made in two or more non-annular parts which when abutted together form an annulus. The parts may be releasably held together in their abutted annular form until the wire, strip or tube requires to be rethreaded, then the parts can be separated from one another transversely of the direction of travel of the wire, strip or tube through the nozzle or containment vessel. The threading of the wire, strip or tube through an annular nozzle or containment vessel is thereby avoided.
    Type: Grant
    Filed: August 29, 1989
    Date of Patent: October 29, 1991
    Assignee: Australian Wire Industries Pty. Limited
    Inventors: Raymond J. Copas, Colin J. Grace, Malcolm A. Robertson
  • Patent number: 5035789
    Abstract: Cathodes useful in an electrolytic cell, such as a chlor-alkali cell, are disclosed which have a metallic-surfaced substrate coated with a catalytic coating composition. In one aspect, the catalytic coating includes a base layer of at least one primary electrocatalytic metal with particles of at least one electrocatalytic metal oxide entrapped therein. In another aspect, at least one upper oxide layer is formed on the base layer. Each upper oxide layer includes a substantially heterogeneous mixture of at least one primary electrocatalytic metal oxide and at least one secondary electrocatalytic metal oxide. The catalytic coatings are tightly adherent to the underlying substrate, resist loss during cell operation and exhibit low hydrogen overvoltage potentials. Also disclosed are methods for preparing the cathodes.
    Type: Grant
    Filed: May 29, 1990
    Date of Patent: July 30, 1991
    Assignee: The Dow Chemical Company
    Inventors: Richard N. Beaver, Carl E. Byrd, Stephen L. Kelly
  • Patent number: 5024707
    Abstract: A process for retarding the formation of incrustation on plant parts in contact with phosphating solutions in phosphating plants and where the working phosphating solution immediately after contacting the metal surface to be phosphated and while the solution is at its working temperature is caused to flow to contact an additionally presented solid surface that is disposed outside the region in which the workpiece metal surface and phosphating solution contact each other. The ratio of the second solid surface area which is contacted by the phosphating solution in the phosphating plant to the surface area of the plant parts in contact with the phosphating solution is at least 2.
    Type: Grant
    Filed: June 22, 1989
    Date of Patent: June 18, 1991
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventor: Werner Rausch
  • Patent number: 5021269
    Abstract: A method for forming a metal film on the surface of a substrate metal, which comprises soaking a substrate metal or a non-metal support carrying the substrate metal thereon in a solution of a metal salt in a high boiling point solvent under heating conditions, characterized in that the metal salt is a salt of the metal to be formed on the surface of the substrate metal with an acidic substance selected from an organic carboxylic acid, a rosin and a rosin derivative. The metal is precipitated from the solution exclusively on the surface of the substrate metal without forming any solid metal particle in the solution or on the substrate metal. Thus, the method is applicable to the formation of a soldering alloy as a film on the surface of a substrate metal without leaving thereon any free metal particle which may cause short circuits in electronic circuits.
    Type: Grant
    Filed: March 13, 1989
    Date of Patent: June 4, 1991
    Assignee: Harima Chemicals, Inc.
    Inventors: Masanao Kono, Yoshihiro Hasegawa, Yasutaka Nishi, Hisao Irie, Tatsuji Mizuta, Shinsuke Ohara
  • Patent number: 4980195
    Abstract: An improved method for inhibiting inland atmospheric corrosion of steel by a sacrificial coating of aluminum, galvanically activated by small surface deposits of metallic indium is disclosed.
    Type: Grant
    Filed: May 8, 1989
    Date of Patent: December 25, 1990
    Assignee: McDonnen-Douglas Corporation
    Inventor: Robert Olds
  • Patent number: 4973500
    Abstract: An inventive method may perform a plating the surface of the metals sheet without using a molten plating metal. This method successively melts a supplied solidus plating metal in close proximity of the passing metal sheet and adheres the molten plating metal as a plating film to the surface of the metal sheet, where the metal sheet passes upwardly and the plating metal is supplied through an upwardly-directed nozzle disposed near the passing sheet, and when or immediately before the plating metal is supplied from the nozzle, it is molten by a heat melting means. The molten plating metal forms a pool at a corner defined between the surface of the passing sheet and the tip of the nozzle, and the molten metal of the pool forms a plating adheres to the sheet surface and forms the plating film.
    Type: Grant
    Filed: October 13, 1989
    Date of Patent: November 27, 1990
    Assignee: NKK Corporation
    Inventors: Toshio Ishii, Shunichi Sugiyama, Yasuhisa Tajiri, Michitaka Sakurai
  • Patent number: 4968529
    Abstract: To obtain an anticorrosive Fe-B-R type permanent magnet; in particular, to reduce deterioration rate of the initial magnetic properties below 10% after the magnet has been kept at 80.degree. C. in 90% relative humidity for 500 hours, the surface of the sintered permanent magnet is coated with metallic coating film layers of at least one noble metal layer and at least one base metal layer disposed on the noble metal layer. Diffusion heat treatment further improves the adhesiveness of the coating film layers.
    Type: Grant
    Filed: December 21, 1989
    Date of Patent: November 6, 1990
    Assignees: Sumitomo Special Metals Co., Ltd., Toda Kogyo Corp.
    Inventors: Atsushi Hamamura, Takaki Hamada, Hiroko Nakamura, Tomoyuki Imai, Toshiki Matsui, Nanao Horiishi
  • Patent number: 4951392
    Abstract: A synthetic press roll for use in paper machines includes a cylindrical mantle to which a surface layer is applied, the surface layer comprising a mixture of a first powder of metallic material and a second powder of an inorganic material. The metallic material of the first powder includes copper, bronze, stainless steel, nickel, chromium and/or a titanium alloy. The inorganic material of the second powder comprises quartz, feldspar, Al.sub.2 O.sub.3, ZrO.sub.2, TiO.sub.2, TiC, SiC, MgO, Si.sub.3 N.sub.4, Cr.sub.2 O.sub.3, WC, NbC, VC, Cr.sub.7 C.sub.3, or other corresponding ceramic material, or mixtures of the same. The surface layer may be produced by thermal spraying, casting, by winding a sintered or rolled band of the mixture around the mantle, or by forming a flexible mat pre-coating in which the desired mixture is bound by a binder, such as PTFE, and by fixing the precoating to the roll mantle by melting it by means of induction or laser heating.
    Type: Grant
    Filed: January 6, 1986
    Date of Patent: August 28, 1990
    Assignee: Valmet Paper Machinery Inc.
    Inventor: Veijo Miihkinen
  • Patent number: 4938999
    Abstract: Adherent metal coatings of metals that cannot be adherently applied directly onto a desired substrate metal by chemical vapor deposition at a temperature below about 300.degree. C. are obtained by applying an adherent metal undercoating to the surface of the metal substrate which weakly or not at all chemisorbs carbon monoxide, then applying the desired outercoat metal to the undercoat substrate by chemical vapor deposition, using a heat decomposable metal carbonyl as the source of the desired outer coating metal. The undercoating metal may be applied by conventional plating processes such as electroplating or electroless plating. In preferred embodiments, the substrate is iron or steel or their alloys, the undercoating metal is copper, and the outer coating metal is a ferrous metal, i.e., nickel, iron, or cobalt.
    Type: Grant
    Filed: July 11, 1988
    Date of Patent: July 3, 1990
    Inventor: William C. Jenkin
  • Patent number: 4935193
    Abstract: The quality or durability of an oxidation protective coating produced by alitizing or aluminizing on the surface of a structural component made of titanium or titanium alloy, is improved by adding niobium to the surface of the structural component. The addition may be accomplished prior to the aluminizing or during the aluminizing. Prior application may involve, for example, vapor deposition of the niobium. Simultaneous application involves including a niobium donator powder in the aluminizing powder mixture.
    Type: Grant
    Filed: December 13, 1988
    Date of Patent: June 19, 1990
    Assignee: MTU Motoren-und Turbinen-Union Muenchen GmbH
    Inventors: Richard Grunke, Lothar Peichl, Heinrich Walter
  • Patent number: 4908242
    Abstract: Electroless metal plating solutions are formulated and controlled to provide high quality metal deposits by establishing the intrinsic cathodic reaction rate of the solution less than 110% of the intrinsic anodic reaction rate. Methods are provided to formulate electroless copper plating solutions which can deposit copper on printed wiring boards of quality sufficient to pass a thermal stress of 10 seconds contact with molten solder at 288.degree. C. without cracking the copper deposits on the surface of the printed wiring boards or in the holes. The ratio of the anodic reaction rate to the cathodic reaction rate can be determined by electrochemical measurements, or it can be estimated by varying the concentration of the reactants and measuring the plating rates.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: March 13, 1990
    Assignee: Kollmorgen Corporation
    Inventors: Rowan Hughes, Milan Paunovic, Rudolph J. Zeblisky
  • Patent number: 4908241
    Abstract: The present invention provides a process for the currentless deposition of lectropositive metal layers on to appropriate less electropositive metals by contacting an object to be coated with a coating bath, wherein a coating bath is used which contains a metal complex obtained by reacting a monovalent electropositive metal halide with a base, which is capable of complex formation with the electropositive metal, and a hydrohalic acid.The present invention also provides a coating bath for the currentless deposition of electropositive metal layers on to less electropositive metals, wherein said bath contains an electropositive metal complex obtained by reacting a monovalent electropositive metal halide with a base which is capable of complex formation with the electropositive metal and a hydrohalic acid.
    Type: Grant
    Filed: July 21, 1988
    Date of Patent: March 13, 1990
    Assignee: Max-Planck-Gesellschaft zur Foederung der Wissenschaften e.V.
    Inventors: Helmut Quast, Johannes Raber, Walter Ott, Hans-Georg von Schnering, Karl Peters
  • Patent number: 4904497
    Abstract: The present invention relates to an electromagnetic system for applying a coating to a metal or metal alloy substrate. The system utilizes a high frequency electromagnetic field to maintain a supply of coating material in a molten condition, to restrict the flow of the molten coating material, and to control the thickness of the applied coating layer. Downstream cooling solidifies the coating layer. The system has particular utility in forming tin coated copper or copper base alloy products.
    Type: Grant
    Filed: January 4, 1988
    Date of Patent: February 27, 1990
    Assignee: Olin Corporation
    Inventor: Brian G. Lewis
  • Patent number: 4888218
    Abstract: A process for coating an aluminum article with zinc by immersing the article in an aqueous bath prepared by dissolving solid zinc fluoride in water. Preferably, the pH of the bath is about 4 to about 6. After coating, the article can be heated to diffuse zinc into surface-adjacent regions of the article and thereby to provide a zinc-diffused layer that protects the article against corrosion.
    Type: Grant
    Filed: December 16, 1987
    Date of Patent: December 19, 1989
    Assignee: Alcan International Limited
    Inventors: Masamichi Suzuki, Tadaaki Sano, Toshihiro Suzuki, Tsunehiko Tanaka
  • Patent number: 4876117
    Abstract: Hard magnetic recording disks include a rigid substrate, typically aluminum, ceramic, or glass, having an underlayer thereover, typically being nickel-phosphorus. A ferromagnetic film is formed over the underlayer, and a protective coating layer formed over the ferromagnetic layer. The protective coating layer is a metal oxide formed by applying a liquid metal oxide precursor material over the ferromagnetic layer, and curing the liquid precursor material to leave a metal oxide layer in place. Optionally, a lubricating or carbon layer may be formed over the protective layer.
    Type: Grant
    Filed: February 4, 1988
    Date of Patent: October 24, 1989
    Assignee: Domain Technology
    Inventor: Jonathan G. Bornstein
  • Patent number: 4844848
    Abstract: A composite made by milling Al.sub.2 O.sub.3 gel to a powder in the size range of from about 20 mesh to about 400 mesh, mixing said Al.sub.2 O.sub.3 gel powder with a reinforcement material consisting of SiC, SiO.sub.2, C, Al.sub.2 O.sub.3, ZrO.sub.2, Si.sub.2 N.sub.4, BN, B.sub.4 O, Y.sub.2 O.sub.3, TiC, TiB.sub.2, TiN and aluminosilicate, compressing and firing at an elevated temperature.
    Type: Grant
    Filed: February 25, 1985
    Date of Patent: July 4, 1989
    Assignee: University of Florida
    Inventors: David E. Clark, Kenneth W. Wistrom
  • Patent number: 4821947
    Abstract: This invention relates to an improved process for application of a metal-comprising coating to a metal-comprising surface without using a flux. The metal-comprising surface must be wettable by or become wettable upon contact with a bath of the metal-comprising coating. Application of the coating is carried out in an environment which is inert at least with respect to the coating material during the time period of its application to the metal-comprising surface, and preferably inert with respect to both the coating material and the metal-comprising surface. The inert environment temperature is sufficiently low that no damage is done to the metal-comprising surface and no damage is done to other materials adjacent to the metal-comprising surface.
    Type: Grant
    Filed: February 8, 1988
    Date of Patent: April 18, 1989
    Assignee: Union Carbide Corporation
    Inventor: Mark S. Nowotarski
  • Patent number: 4784730
    Abstract: A cathode suitable for use in an electrochemical process evolving hydrogen (for example the chloralkali process) in which the cathode comprises an electrically conductive substrate (1) made of a non-ferrous metal or having a coherent coating of non-ferrous metal on which is provided an electrocatalyst (4) comprising platinum and ruthenium and wherein the cathode is made more poison-resistant by a deposition of gold or silver and, optionally, a further deposition of PTFE. The cathode is particularly resistant to poisoning by iron.
    Type: Grant
    Filed: July 16, 1987
    Date of Patent: November 15, 1988
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Peter M. Willis, Ralph L. Phillips
  • Patent number: 4749626
    Abstract: The present invention relates to an addition to tin coating solutions for inhibiting the growth of tin whiskers. The addition comprises a concentration of a metal salt selected from the group consisting of palladium salt, silver salt, nickel salt, iron salt, cadmium salt, platinum salt, gold salt, indium salt, ruthenium salt and cobalt salt. In a preferred embodiment, the metal salt addition is either a palladium salt such as palladium chloride or a silver salt such as silver sulfate.
    Type: Grant
    Filed: July 3, 1986
    Date of Patent: June 7, 1988
    Assignee: Olin Corporation
    Inventors: Igor V. Kadija, Julius C. Fister, Joseph Winter, Arvind Parthasarathi
  • Patent number: 4737381
    Abstract: Aluminum coated ferritic base metal foil formed by cold reduction of hot dip aluminum coated ferritic steel strip containing from 10% to about 35% chromium, up to 3% aluminum, and up to 1% silicon, the foil having a ratio of aluminum coating thickness on both sides to base metal foil thickness of at least 1:10, with at least 4% by weight total aluminum. The method of production includes heating the foil in an oxidizing atmosphere within specified temperature and time limitations to provide a porous surface having a thin layer of aluminum oxide. The foil is adapted for fabrication into monolithic support structures for catalytic converters for internal combustion engine exhaust systems.
    Type: Grant
    Filed: May 8, 1987
    Date of Patent: April 12, 1988
    Assignee: Armco Inc.
    Inventors: Farrell M. Kilbane, F. Curtiss Dunbar
  • Patent number: 4690840
    Abstract: The disclosure describes a method for the preparation of metallic alloys containing an alkali or alkali-earth metal, such as lithium, and a host metal, such as aluminum. Initially, an active organic solution of the alkali or the alkali-earth metal is prepared, and a source of the alkali or alkali-earth metal which are both brought together with one another. On the other hand, a metallic structure containing the host metal is prepared, the metallic structure is brought together with the organic solution which is kept in touch with the source of metal until there is formed an alloy of the host metal and of the alkali or alkali-earth metal with the metallic structure, and the alloy possesses an activity which is determined by that of the organic solution. The organic solution then acts as transfer agent of the alkali or alkali-earth metal towards the host metallic structure. To prepare a negative electrode, the alloy is brought together with an electrolyte, such as a thin polymeric film.
    Type: Grant
    Filed: April 4, 1985
    Date of Patent: September 1, 1987
    Assignees: Hydro-Quebec, Societe Nationale Elf Aquitaine
    Inventors: Michel Gauthier, Denis Fauteux
  • Patent number: 4670312
    Abstract: Method for preparing aluminum, especially large aluminum pieces or articles having a surface layer of aluminum oxide for subsequent metal plating wherein the aluminum or aluminum alloy substrate is immersed in a bath containing metal salts and acid such that the acid content relative to the metal salt is sufficient to remove the surface aluminum oxide layer without substantial attack on the underlying aluminum while enabling the permanent deposit thereon of a continuous, smooth, adherent metal or metal alloy coating directly onto the aluminum, thereby replacing the aluminum oxide layer. Subsequent, essentially blister-free electroless or electrolytic plating of nickel or a nickel alloy, copper or a copper alloy onto the metal or metal alloy coated aluminum are made possible thereby.
    Type: Grant
    Filed: February 7, 1985
    Date of Patent: June 2, 1987
    Assignee: John Raymond
    Inventor: Robert Ehrsam