Abstract: A two-step method is provided for the production of a pressure sensitive adhesive by radiation curing. The method comprises the steps of initially irradiating a monomer composition comprised of 65 to 100 percent by weight of monomers having a Tg<0.degree. C. to form a coatable syrup, followed by adding at least one monomer having a Tg>0.degree. C. and at least one multifunctional monomer or oligomer to said syrup, and further irradiating the mixture to form a pressure sensitive adhesive.

Abstract: There is provided a method of forming a conductive film having a predetermined pattern in hybrid ICs, high frequency dielectric filters and the like which makes it possible to safely and efficiently perform a series of the steps of preparing an activating catalytic solution for forming a photoreactive film on a base, forming the photoreactive film through the application of the activating catalytic solution, producing an activating catalyst by exposing particular regions of the photoreactive film, developing by flushing away the photoreactive film in unexposed regions, and immersing the base in an electroless plating bath without using an organic solvent and which allows the formation of a plating film having high electrical conductivity and high strength of adherence. A hydrophilic activating catalytic solution is used which is obtained by dissolving copper oxalate, a palladium salt such as palladium chloride into an alkaline solution such as ammonia.

Abstract: A hydrophilic coating on a polymeric substrate is prepared by subjecting at least one hydrophilic vinyl monomer to radiation-induced graft polymerization on an activated substrate surface.

Abstract: A method for fabricating a multi-domain liquid crystal cell is disclosed, wherein first and second alignment directions are formed in first and second portions of an alignment layer provided on a substrate by selectively subjecting the first and second portions to different energy doses of linearly polarized ultraviolet light. Liquid crystal material is then injected between the one substrate and another substrate and into contact with the alignment layer, thereby obtaining a wide viewing angle in the liquid crystal device.

Abstract: There is disclosed a method for the permanent application of indicia to the surface of the polyolefin object by applying pigmented material to the surface in an indica pattern, preferably from a transfer sheet. Preferably the pigmented material is a mixture of finely divided pigment, hydrocarbon wax and finely divided polyolefin. The polyolefin surface bearing the indicia is coated with a coating mixture comprising a mixture of polyolefin and a binder such as a rosin or wax. Thereafter, the coated, indicia-bearing polyolefin surface is surface-heated to a temperature sufficient to fuse the coating and incorporate the coating and indicia permanently into the polyolefin object. The heating can be performed by passing a heat source across the surface.

Abstract: The invention relates to a method of producing a magnetic material for use in an ultrahigh density magnetic recording medium and to the medium itself. The method general includes the steps of vaporing a ferromagnetic lanthanide rare earth, growing clusters of the ferromagnetic lanthanide rare earth at a temperature below the temperature at which the ferromagnetic lanthanide rare earth forms locked-moment clusters, filtering superparamagnetic clusters from locked-moment clusters, and collecting the locked-moment clusters. Preferably, the ferromagnetic lanthanide rare earth is a ytterbium rare earth. Advantageously lanthanide alloys, mixtures of lanthanide rare earths and alloys of a mixture of lanthanide rare earths can be used. The filtering employs a gradient magnetic field to separate superparamagnetic clusters from moment-locked clusters. The gradient field magnet separates the superparamagnetic clusters which deflect by a large amount from the locked-moment clusters which deflect by a small amount.

Abstract: The present invention is generally directed to a process and a system for transforming a liquid into a solid material using light energy. In particular, a solution containing a parent material in a liquid form is atomized in a reaction vessel and directed towards a substrate. The atomized liquid is exposed to light energy which causes the parent material to form a solid coating on a substrate. The light energy can be provided from one or more lamps and preferably includes ultraviolet light. Although the process of the present invention is well suited for use in many different and various applications, one exemplary application is in depositing a dielectric material on a substrate to be used in the manufacture of integrated circuit chips.

Abstract: Alternate formation of high-resistance and low-resistance layers form a thin film with reduced dopant gradient in its thickness. A desired sheet resistance is attained by adjusting the thickness of the stacked layers, the degree of doping of the film, and the number of layers used to make the thin film during the film formation process.

Abstract: The method of forming a multilayer printed circuit board includes applying a photopolymerizable coating append having a solid content of 70 to 95% by weight and a viscosity of 10 to 60 Pa.s of 25.degree. C. to a surface of the applicator cooled to a temperature of 5.degree. C. by a metering roll surface of which is controllably maintained at a temperature range from 25.degree. to 60.degree. C., so that the coating agent is deposited on opposite sides of a board and has an application viscosity of 20 to 100 Pa.s at a coating speed of 5 to 20 m/min to form a film thickening of 10 to 200 .mu.m.

Abstract: The invention relates to a powder paint binder composition. The binder composition comprises a hydroxyl functional polymer and a crosslinker containing blocked isocyanate groups. The crosslinker includes (i) a crystalline compound containing blocked isocyanate groups and ii) an amorphous compound containing blocked isocyanate groups. Preferably the crosslinker is a mixture of blocked hexamethylene diisocyanate trimer and blocked 1,6-hexamethylene diisocyanate.

Abstract: A diamond wafer including a substrate and a (100) oriented polycrystalline diamond film grown on the substrate for making surface acoustic wave devices, semiconductor devices or abrasion-resistant discs. The (100) oriented film is produced by changing a hydrocarbon ratio in a material gas halfway from a higher value to a lower value. The wafer is monotonously distorted with a distortion height H satisfying 2 .mu.m.ltoreq..vertline.H.vertline..ltoreq.150 .mu.m. The film is polished to a roughness of less than Rmax50 nm and Ra20 nm.

Abstract: A method of forming a thermal barrier coating on an article designed for use in a hostile thermal environment, such as turbine, combustor and augmentor components of a gas turbine engine. The method is particularly directed to increasing spallation resistance of thermal barrier coatings composed of an aluminum-containing bond coat formed on the surface of an article, and an insulating ceramic layer overlaying the bond coat. Processing steps include forming the bond coat on the surface of the article, and then treating the surface of the bond coat with laser energy so as to form a diffusion barrier layer of alumina. Thereafter, a ceramic material is deposited on the surface of the diffusion barrier layer so as to form the insulating ceramic layer. A preferred technique for the treating step is to scan the surface of the bond coat with an ultraviolet laser beam characterized by an appropriate beam geometry and fluence to yield the desired diffusion barrier layer.

Abstract: A method of applying strengthening coatings to metallic or metal-containing surfaces is provided in which the surface (2) to which a strengthening coating is to be applied is first subjected to activation, then at least one strengthening coating layer (1) is applied to the surface thus prepared. Said layer is treated with a laser beam (3) having a diameter (d) ranging from 0.2 mm to half the diameter (d) of the laser beam (3) entering into focusing element (5), with a power of at least 0.5 kW, with a rate of relative travel (A) of the surface being treated (2) and the laser beam (3) of at least 50 mm/min, the distance (L) between the focal plane (f) of the focusing element (5) to the surface being treated (2) being less than or equal to half the focal distance (F).

Abstract: The present invention relates to coating and printing methods for the deposition of aqueous compositions. The composition may be adapted to any method without the need to change its chemical content. Viscosity is determined and adjusted by raising and lowering the temperature. High gloss value, increased film integrity and enhanced mar resistance result.

Abstract: In order to improve a process for the production of a composite consisting of electrode material, catalyst material and a solid-electrolyte membrane for an electrochemical cell, in particular a fuel cell, with which solid-electrolyte material is brought into pore-deep contact with the electrode material and the catalyst material by softening it, such that this can be carried out as effectively and inexpensively as possible, it is suggested that a catalytic powder comprising electrode material, catalyst material and solid-electrolyte material be produced, that the catalytic powder be arranged on a surface area, that the catalytic powder be heated on a side facing away from the surface area in order to soften the solid-electrolyte material and that subsequently the catalytic powder be applied to the solid-electrolyte membrane under pressure with the side facing away from the surface area while the solid-electrolyte material is still softened in order to form a composite.

Abstract: A process for coating a front surface of a cathode ray, the process being characterized by using a ultraviolet ray setting plastic material as a coating material. According to the process, a preformed cathode ray tube bulb having a front surface is maintained with the front surface directed upwards and a transparent, fluidized or molten plastic material of ultraviolet setting property is discharged to the front surface of the bulb through a plurality of thin nozzles arranged in at least one row or one or more nozzles each having an elongated nozzle opening. In this instance, it is preferable that the molten plastic material discharged from the nozzles is received by a film forming surface which is arranged adjacent to the nozzles to form a thin plastic film before it reaches the front surface of the bulb. Preferably, the film forming surface is provided by a sheet of a material, such as a silicon rubber, which is not wettable to the plastic material.

Abstract: An apparatus for forming an optical element on the surface of a substrate by ejecting a curable light guide forming liquid from a nozzle onto the substrate and curing the curable light guide forming liquid. A waveguide may be formed by moving the nozzle in a linear pattern over the surface of the substrate during ejection of the liquid from the nozzle. Curing the liquid may include exposing the liquid to ultraviolet radiation, and the radiation may be applied to only a small portion of the liquid. A multilayered waveguide may be formed by ejecting a further light guide forming liquid onto the first and curing it. A core and cladding may be formed simultaneously by ejecting core forming liquid from an inner tube and cladding forming liquid from an annulus about the inner tube. The waveguide may be formed in a groove, and a splitter may be formed by branching a second waveguide from a first, or by laying out two parallel waveguides and connecting them.

Abstract: A method of increasing the tack of a pressure sensitive adhesive by exposing a polymeric pressure sensitive adhesive to an activating treatment, activatable articles containing such an adhesive and adhesive compositions resulting from such an activating treatment. The activatable, polymeric, pressure sensitive adhesive is preferably a water based adhesive prepared by free radical polymerization of acrylic acid, methacrylic acid, acrylate, or methacrylate monomers having from 1 to about 12 carbon atoms. The activating treatment is preferably corona charging or corona charging in combination with uv light.

Abstract: A process and apparatus for the preparation and coating of the surface of a substrate by thermal projection, in which the surface of the substrate is progressively subjected to laser irradiation thereby at least partially to eliminate a superficial contaminating film on the surface of the substrate, and then there is projected by a thermal projection device a deposit material on the surface thus prepared immediately after the preparation. The surface of the substrate is subjected to successive laser and thermal projection treatments thereby to lay down on the surface a plurality of layers of deposit material. The substrate can be cylindrical, and can be rotated about its axis while continuously applying laser radiation and thermal projection thereto, with the substrate rotating in a direction such that the surface of the substrate is subjected first to laser radiation and subsequently to thermal projection. The laser is a pulsed laser.

Abstract: A method is for curing ultraviolet light-curable coatings, inks or adhesives on heat sensitive substrates, wherein the substrates are coated and then passed under ultraviolet light. It includes reducing the temperatures of the substrates while being passed under the ultraviolet light by providing a shield at a location between the ultraviolet light and the substrates. The shield is substantially infrared light reflective and absorptive to prevent infrared light from reaching the substrates and is also substantially ultraviolet light permeable to permit ultraviolet light to reach the substrates. An ultraviolet light curing device utilizing the aforesaid shield is also described for curing ultraviolet light-curable coatings, printings and adhesives on heat sensitive substrates.

Abstract: A tube-shaped film, made of fluorine resin, has a fold-free, smooth, and uniform inner peripheral surface formed thereon by a surface treatment. An apparatus for treating the inner peripheral surface of the tube-shaped film includes a holding device for holding the tube-shaped film on the inner peripheral surface of a cylindrical body with a cylindrical configuration of the tube-shaped film maintained. A treatment device is inserted into the cylindrical body to treat the inner peripheral surface of the tube-shaped film held on the inner peripheral surface of the cylindrical body. The holding device and the treatment device make a uniform linear motion relative to each other and a uniform rotary motion relative to each other.

Abstract: The present invention provides an acid-resistant protective coating, preferably an acid- and abrasion-resistant protective coating, for thermoplastic transparencies, particularly aircraft transparencies. The coating is prepared from a silica-free protective coating precursor composition comprising a multifunctional ethylenically unsaturated ester of acrylic acid, a multifunctional ethylenically unsaturated ester of methacrylic acid, or a combination thereof; and an acrylamide.

Abstract: A formulation for a resilient gasket coating which is curable by ultraviolet radiation without emitting fumes into the surrounding environment. Different portions of the coating are cured by successive exposure to two different wavelengths of ultraviolet radiation during a continuous in-line process. The first wavelength cures an inner portion of the coating and bonds the coating to the substrate. The second wavelength cures a coating surface. The formulation permits ultraviolet curing of thicker pigmented coatings than have been previously known.

Abstract: A piezoelectric device, such as a surface acoustic wave filter, comprises a piezoelectric film composed of a lead zirconium titanate compound applied to a substrate formed of silicon or gallium arsenide. The device includes an intermediate film between the piezoelectric film and the substrate and composed of a lead-free zirconium titanate compound to prevent interaction between lead oxide in the piezoelectric material and the material of the substrate that would otherwise cause spilling or adversely effect the electrical properties of the substrate. The piezoelectric device is made by first applying the film of the lead-free zirconium titanate compound and thereafter applying the film of the lead zirconium titanate compound. Preferably, the lead-free zirconium titanate film is applied by sputtering and annealed to densify the material and increase the dielectric constant prior to depositing the piezoelectric material.

Abstract: A method of making a water absorptive article comprising, a fibrous substrate impregnated with a water absorptive, water insoluble polymer, wherein the polymer is intertwined and interlocked with fibers of the fibrous substrate, and the article has high water absorbing capacity.

Abstract: Proposed is an improved method for the formation of a silica-based coating film on the surface of a substrate such as a silicon wafer in the manufacture of semiconductor devices by coating the substrate surface with a polysilazane-containing coating solution followed by conversion of the coating layer of polysilazane into a silica-based coating film. The method comprises drying the coating layer of the polysilazane according to a heating schedule at a specified heating rate with continuous or stepwise increase of the temperature up to 240.degree. to 350.degree. C. followed by an irradiation treatment with far ultraviolet light at a temperature of 240.degree. to 350.degree. C. and then by a baking treatment at 350.degree. to 800.degree. C.

Abstract: This invention is in the general field of surgical instruments and, in particular, catheters. Specifically, it relates to procedures for coating the interior surfaces of surgical devices with a cross-linkable lubricious polymer, preferably one which is hydrophilic. These catheters may be variously used in cardiovascular and endovascular procedures to deliver diagnostic, therapeutic, or vaso-occlusive agents or devices to a target site within a human or animal body and to catheters used to guide other catheters to a particular site in that body. The interior of the catheters are coated using the noted procedure in such a way that the interior is exceptionally slippery and very durable.

Abstract: A positive metallization process for metallizing a plastic composite piece containing a polymer and grains of one or more oxides, includes three successive steps. The first step consists of irradiating the plastic piece surface to be metallized with a light beam emitted by an excimer laser. The second step consists of immersing the irradiated piece into at least one autocatalytic bath containing metal ions and without palladium. This immersion induces the deposit of the metal ions onto the irradiated surface to form a metal film onto the surface. The third step consists of thermally processing the metallized plastic piece to induce the diffusion of the deposited metal into the plastic piece.

Abstract: An effective non-specular reflector, for use in a Liquid Crystal Display, is formed by first coating a substrate with a two component solution. One component hardens when heated or when exposed to ultraviolet light (optionally through a mask) while the other component remains liquid. The result is a solid layer in which are dispersed multiple liquid regions, some of which break the surface where they are easily removed, leaving behind a roughened surface. Once a high reflectance metal has been deposited onto this surface it becomes an effective nonspecular reflector. Examples of materials for use as the two components are given.

Abstract: A magnetic recording medium having an improved CSS characteristics is made by a process including a surface texture treatment step of either (1) focusing an ultraviolet laser beam in a ring-shaped band, or (2) focusing a pulsed ultraviolet laser beam at an energy density of at least 0.01 J/cm.sup.2 but lower than the threshold level successively at least two times but up to 1,000 times, on a substrate composed of glass or silicon, followed by the formation of an undercoat, a magnetic layer, and a protective coating in this order on the surface-textured substrate.

Abstract: A process is described for providing a conductive metal circuit using a coherent radiation source. The circuit pattern is directly written onto a laser addressable element having a supercooling material layer. A conductive metal toner is then applied to the light struck areas and fired in a furnace to provide a conductive metal circuit.

Abstract: The performance of phosphor screens can be improved by adding an antistatic agent into the protective topcoat of the radiographic screen when the antistatic agent preferably comprises a fluorocarbon or silicone antistatic agent. These antistatic agents are particularly useful where the screen is made by coating phosphor dispersion/mixture onto a substrate while the dispersion/mixture contains less than 5% by weight of polymerizable components with a molecular weight less than 300, preferably with less than 5% by weight of polymerizable components having molecular weights less than 500, and a topcoat contains the antistatic agent. Formation of the antistatic topcoat is preferably formed by inclusion of the antistatic agent into the polymerizable composition and allowing the antistatic agent to migrate to the surface of the composition during polymerization to form a layer consisting essentially of the antistatic agent.

Abstract: In a high-speed electrogalvanizing process, steel strip is protected from the formation of troublesome zinc nodules by masking the edges of the strip, while the strip is moving and upstream from the electrogalvanizing step, with an ultraviolet curable coating, and curing the coating, while the strip is moving, prior to introduction to the electrogalvanizing step.

Abstract: This invention relates to a method for light-assisted curing of coatings by providing coatings with an enamine content sufficient to enhance the cure rate of the coatings. The coatings exhibit improved weatherability and gloss retention when exposed to light.

Abstract: A heat-resistant roll for copying machine use which comprises a metallic roll having a surface which has been coated with a varnish containing polybenzimidazole as a major resin component, followed by curing, wherein the coating is conducted by means of rotational coating with application of pressure.

Abstract: The present invention relates to a process for forming a laminate and the laminate using silicone release coating compositions comprising (A) a mixture of (i) a dimethylsiloxane-methylvinylsiloxane-methylphenylsiloxane copolymer and (ii) a dimethylsiloxane-methylvinylsiloxane copolymer, (B) an organohydrogenpolysiloxane, (C) a platinum catalyst, and (D) an organic solvent. The silicone release coating compositions of the present invention provide small release resistance values both at low and high peeling velocities and do not impair the residual adhesion of tacky substances that have come into contact with the coating.

Abstract: A glass fiber reinforced polymer which excels in mechanical properties and is suitable for use in a large-sized structural members, formed from a dispersion liquid by dispersing reinforcement glass fibers and particulate thermoplastic resin in a surfactant-containing aqueous medium in which bubbles of air are dispersed, forming a sheet-like web on a porous support plate, and applying heat and pressure to form a sheet. The reinforcement glass fibers include a silane coupling agent while the matrix resin has functional groups bonded to the silane coupling agent. The concentration of said functional groups is higher in the regions adjacent the surfaces of said reinforcement glass fibers than in regions farther removed therefrom, and said concentration progressively decreases in the direction away from said reinforcement glass fibers.

Abstract: There is disclosed a method for annealing oxide thin film superconductors having layered structures including at least Cu--O layers in which each oxide thin film superconductor is heated partially by a heating means and the heating portion is moved at a predetermined speed.

Abstract: An improved method for preparing copper clad laminates from a copper substrate without a conventional or infrared oven. The method contains the steps of: (a) preparing a precursory coating composition which can be subsequently cured to become polyimide; (b) coating the precursory coating composition on a copper substrate; and (c) exposing the precursory coating composition to an infrared heater provided in an infrared curing apparatus. The infrared heater is selected such that it emits infrared rays of wavelengths correponding to the absorption spectrum of the precursory coating composition. A plurality of infrared heaters can be provided in the infrared curing apparatus, each can be designed to have a different effective heating length and/or operated at a uniquely predetermined surface temperature for optimum energy efficiency.

Abstract: A method for producing a bottom resist for a two-layer O.sub.2 /Reactive Ion Etching system which fulfills all the requirements set for such a resist. A varnish layer of a base polymer containing an aromatic, a cross-linking agent and an acid-forming agent is applied to a substrate. The varnish layer is flood-exposed to release a strong acid from the acid-forming agent in the surface region of the layer. This is followed by thermal curing.

Abstract: A formulation for a resilient gasket coating which is curable by ultraviolet radiation without emitting fumes into the surrounding environment. Different portions of the coating are cured by successive exposure to two different wavelengths of ultraviolet radiation during a continuous in-line process. The first wavelength cures an inner portion of the coating and bonds the coating to the substrate. The second wavelength cures a coating surface. The formulation permits ultraviolet curing of thicker pigmented coatings than have been previously known.

Abstract: A process for polymerizing a free-radically polymerizable composition comprising the steps:(a) coating a coatable free-radically polymerizable mixture onto at least one major surface of a web;(b) deoxygenating a liquid inerting medium;(c) immersing the coated web into the deoxygenated liquid inerting medium; and(d) irradiating the immersed coated web with actinic radiation sufficient to effect polymerization of the free-radically polymerizable mixture, while maintaining the liquid inerting medium in an essentially oxygen-free state.

Abstract: A method for producing a magnetic structure, such as a thin film magnetic head, in which the magnetic and electrical characteristics of magnetic material are tailored to produce magnetic and electrical characteristics in selected localized areas of the magnetic material. In a specific embodiment, the structure comprises a layer of magnetic material having an overlayer and an underlayer, and the magnetic characteristics of the material are modified by rapid thermal annealing.

Abstract: Process for producing a multi-layer lacquer coating by the application of a coat of clear lacquer including coating agents which are curable exclusively by polymerization in radicalic and/or cationic manner to a dried or crosslinked colored and/or effect-producing basecoat film process is performed in light having a wavelength of over 550 nm or subject to the exclusion of light. The application step is followed by initiation or implementation of curing of the clear-lacquer film by high-energy radiation. The process is particularly suitable for producing multi-layer lacquer coatings in the automobile industry.

Abstract: The invention comprises a method for producing optical thin films with a high laser damage threshold and the resulting thin films. The laser damage threshold of the thin films is permanently increased by irradiating the thin films with a fluence below an unconditioned laser damage threshold.

Abstract: The present invention relates to a process for modifying the surfaces of the molded materials made of fluorine resins comprising irradiating an ultraviolet laser beam on said surfaces in the presence of an ultraviolet-absorbing compound and a fluorosurfactant. According to the process, the adhesive and wetting properties and the like of the surfaces of the molded materials made of fluorine resins can be remarkably improved.

Abstract: A fabrication method of a printed wiring board in which the halation effect of light irradiated to a solder resist film is utilized in a process of selectively removing the solder resist film. After a conductive layer is patterned to a given circuit pattern including soldering pads, the solder resist film is formed on the base material to cover the patterned conductive layer. The solder resist film is selectively exposed to light utilizing reflection of the irradiated light from the insulating base material and developed so that the solder resist film is selectively left in areas adjacent to the respective soldering pads. Then, an etching resist film is formed to cover the patterned conductive layer except for the soldering pads, and surface areas of the respective soldering pads are selectively etched using the etching resist film as a mask to produce solder resist dams made of the solder resist film left on the base material. Solder films are formed on the respective soldering pads thus selectively etched.

Abstract: New and improved structures in tools subject to wear and attrition when engaging or engaged by work or material being worked on thereby. Synthetic diamond material is formed in situ on a select portion or portions of the surface of a hard substrate or tool support to define or cover the portion of the tool substrate adjacent the work operated on by the tool in a manner to provide a hard wear resistant work engaging surface or surfaces which offers substantially greater resistance to abrasion and frictional deterioration than the material of the substrate or tool base. In one form, the synthetic diamond material is formed on and welded to the surface of the substrate in a single operation involving the application of intense radiant energy beamed against particles of carbon which are converted to a solid synthetic diamond structure of defined shape directly against the solid substrate.

Abstract: A process for forming a hard surface coating on titanium alloys includes providing a piece of material containing titanium having at least a portion of one surface to be hardened. The piece having a portion of a surface to be hardened is contacted on the backside by a suitable heat sink such that the melting depth of said surface to be hardened may be controlled. A hardening material is then deposited as a slurry. Alternate methods of deposition include flame, arc, or plasma spraying, electrodeposition, vapor deposition, or any other deposition method known by those skilled in the art. The surface to be hardened is then selectively melted to the desired depth, dependent on the desired coating thickness, such that a molten pool is formed of the piece surface and the deposited hardening material. Upon cooling a hardened surface is formed.

Abstract: A method for producing polymeric diacetylene thin films having desirable nonlinear optical characteristics has been achieved by producing amorphous diacetylene polymeric films by simultaneous polymerization of diacetylene monomers in solution and deposition of polymerized diacetylenes on to the surface of a transparent substrate through which ultraviolet light has been transmitted. These amorphous polydiacetylene films produced by photo-deposition from solution possess very high optical quality and exhibit large third-order nonlinear optical susceptibilities, such properties being suitable for nonlinear optical devices such as waveguides and integrated optics.