Oxide Patents (Class 428/629)
  • Patent number: 5856027
    Abstract: A thermal barrier protected nickel based or cobalt based superalloy component for use in a gas turbine engine includes a thermal barrier coating system having a multi-layered structure. The first bondcoat layer of the thermal barrier coating system comprises a chemical vapor deposited, platinum modified diffusion aluminide layer on the superalloy component (substrate). The diffusion aluminide layer includes an inner diffusion zone proximate the substrate and an outer layer region comprising a platinum modified (platinum-bearing) intermediate phase of aluminum and at least one of nickel and cobalt depending on the superalloy composition. The intermediate phase is a non-ordered solid solution having a range of compositions and is free of other phase constituents.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: January 5, 1999
    Assignee: Howmet Research Corporation
    Inventor: Kenneth S. Murphy
  • Patent number: 5843589
    Abstract: A ferromagnetic and antiferromagnetic material having a high exchange coupling and a high thermal stability, and a magnetic storage system using this material which has excellent reliability and recording density, and a magnetoresistive storage/read separation head having a high sensitivity and a low noise property. The magnetic storage/read system of the invention mounts a magnetoresistive head using a chromium-manganese antiferromagnetic layer/a cobalt alloy layer as a pinning layer or the longitudinal bias layer of the spin-valve type magnetoresistive layered film.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: December 1, 1998
    Assignee: Hitachi, Ltd.
    Inventors: Hiroyuki Hoshiya, Yoshihiro Hamakawa, Susumu Soeya, Shigeru Tadokoro
  • Patent number: 5840429
    Abstract: The present invention relates to an aircraft transparency including an electroconductive metal oxide coating over a rigid plastic substrate, and a polyurethane protective liner over the metal oxide coating, and more specifically to the use of a primer for adhering the metal oxide coating to the substrate and/or a primer for adhering the polyurethane protective liner to the metal oxide coating. The metal oxide primer includes a carbonate diol-based crosslinked polyurethane. The polyurethane primer is selected from the group consisting of a crosslinked copolymer of acrylic acid and substituted acrylates such as 2-ethylhexylacrylate; a crosslinked copolymer of cyanoethylacrylate and acrylic acid; and a crosslinked terpolymer of 2-ethylhexylacrylate, cyanoethylacrylate and acrylic acid.
    Type: Grant
    Filed: November 5, 1996
    Date of Patent: November 24, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Thomas G. Rukavina, Robert M. Hunia
  • Patent number: 5837385
    Abstract: An environmental coating and a method for forming the coating on a nickel aluminide component designed for use in a hostile thermal environment, such as turbine, combustor and augmentor components of a gas turbine engine. The environmental coating includes a metal that has been diffused into the surface of the nickel aluminide component, and an aluminum oxide layer on the surface of the nickel aluminide component. According to this invention, the metal is one or more noble metals, chromium and/or an MCr alloy, and forms a diffusion region comprising noble metal-aluminides and/or chromium-aluminides. The environmental coating optionally contains up to about 1.0 atomic percent of at least one oxygen-active element, such as yttrium, hafnium, zirconium and/or cerium. According to the invention, the environmental coating need only consist of the diffusion region and the aluminum oxide layer, and therefore does not require additional environmentally-resistant layers (e.g.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: November 17, 1998
    Assignee: General Electric Company
    Inventors: Jon C. Schaeffer, David F. Lahrman
  • Patent number: 5780171
    Abstract: A gas turbine engine component coating having superior abradability and erosion resistance is disclosed. The coating includes a base coat foundation layer, a graded interlayer and an abradable top layer for an overall thickness of preferably about 50 mils. The coating is characterized by a plurality of vertical microcracks. By precisely controlling the deposition parameters, composition of the layers and layer particle morphology, segmentation is achieved, as well as superior abradability and erosion resistance.
    Type: Grant
    Filed: August 15, 1997
    Date of Patent: July 14, 1998
    Assignee: United Technologies Corporation
    Inventors: David M. Nissley, Harold D. Harter, Daniel R. Godin, George E. Foster
  • Patent number: 5763107
    Abstract: A coated article includes a superalloy substrate, an intermediate bond coat and a thermal barrier coating. The bond coat may include a platinum aluminide layer underlying a thin oxide layer. The thin oxide layer may include alumina. The coated article has high strength and durability at high temperatures over extended periods of time and thus is especially useful in the form of, e.g., a turbine blade or turbine vane.
    Type: Grant
    Filed: March 17, 1997
    Date of Patent: June 9, 1998
    Assignees: Rolls-Royce plc, Chromalloy United Kingdom Ltd.
    Inventors: David S. Rickerby, Daniel K. White, Stanley R. Bell
  • Patent number: 5756130
    Abstract: There is provided a stamper for producing a recording medium exhibiting excellent durability and capable of stably forming projections and pits and a method of producing the stamper. A stamper for producing a recording medium comprising projections and pits in a predetermined pattern on the surface thereof, wherein a value of tan .theta..sup.-1 obtainable from an enlargement angle .theta. of an output from a cartridge with respect to an enlargement of an output denoting a load measured by a test of scratching the surface having the projections and pits under conditions that a diameter of a stylus is 100 .mu.m and a loading speed of 1 .mu.m/second is 1.3 or more.
    Type: Grant
    Filed: May 17, 1994
    Date of Patent: May 26, 1998
    Assignees: Hitaci Maxell, Ltd., Hitachi, Ltd.
    Inventors: Nobuhiro Umebayashi, Hiroshi Obara, Hiroshi Ishihama, Yoshitaka Kojima, Shoichi Nakashima, Shizuka Yamaguchi
  • Patent number: 5747180
    Abstract: A method of fabricating two-dimensional regimented and quasi periodic arrays of metallic and semiconductor nanostructures (quantum dots) with diameters of .about.100 .ANG.(10 nm) includes the steps of polishing and anodizing a substrate to form a regimented quasi-periodic array of nanopits. The array forms a template for metallic or semiconductor material. The desired material is deposited in the nanopits by immersing the substrate in an appropriate solution and using the substrate as one cathode and inserting a second cathode in the solution.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: May 5, 1998
    Assignee: University of Notre Dame Du Lac
    Inventors: Albert E. Miller, Supriyo Bandyopadhyay
  • Patent number: 5740515
    Abstract: An article of manufacture which is subject to erosive and corrosive attack in a high-temperature environment is formed of a substrate of nickel or cobalt-based superalloy, and a protective silicide coating disposed on the substrate. A thermal barrier layer of ceramic may be disposed between the superalloy and the silicide layer, and an MCrAlY layer may be disposed between the ceramic and the superalloy substrate. The silicide coating is preferably MoSi.sub.2.
    Type: Grant
    Filed: April 6, 1995
    Date of Patent: April 14, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventor: Wolfram Beele
  • Patent number: 5738947
    Abstract: Disclosed is a corrosion-resistant film for protecting the surfaces of Ag, which comprises an Ag--Mg alloy having an Mg content of from 1 to 10 atomic % and which is applied to an Ag substrate. Also disclosed is a corrosion-resistant composite structure composed of an Ag substrate and a protective film of an Ag--Mg alloy with an Mg content of from 1 to 10 atomic % formed on the surface of the Ag substrate. The corrosion-resistant film protects an Ag with a silver-white gloss from being blackened by sulfide components, etc. The adhesiveness between the film and the Ag substrate is good. The composite structure has a high reflectivity and is useful as a reflective film for photo-magnetic recording media, optical recording media, reflectors, illuminators, etc. The surface of the corrosion-resisting film is oxidized to form an MgO layer on the film, and the film exhibits a high protecting effect.
    Type: Grant
    Filed: February 8, 1996
    Date of Patent: April 14, 1998
    Assignee: Mitsubishi Materials Corporation
    Inventors: Kenichi Hijikata, Rie Mori
  • Patent number: 5725963
    Abstract: It is an object of the present invention to provide a magnetoresistance effect element which has a film with a spin valve structure or an artificial lattice film having good soft magnetic characteristics, and which can be applied to a high-sensitivity magnetic head. The present invention provides a magnetoresistance effect element including a stacked film formed on a substrate by sequentially stacking a ferromagnetic film containing as its main constituents at least one elements selected from the group consisting of Co, Fe, and Ni, a nonmagnetic film, and the ferromagnetic film, wherein the two ferromagnetic films are not coupled with each other, and the closest packed plane of each ferromagnetic film is oriented in a direction perpendicular to the film surface.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: March 10, 1998
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hitoshi Iwasaki, Yuichi Ohsawa, Reiko Kondoh, Susumu Hashimoto, Atsuhito Sawabe, Yuzo Kamiguchi, Masashi Sahashi
  • Patent number: 5723221
    Abstract: A press plate for decorative laminate production has an aluminum alloy core plate exhibiting a 0.2% compressive yield stress of not less than about 180 MPa at 140.degree. C., an aluminum cladding layer integrally bonded to opposing surfaces of the core plate, and a layer of aluminum oxide formed on the aluminous cladding which is substantially free of grain line effects.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: March 3, 1998
    Assignee: Formica Corporation
    Inventors: Alan Thomas Brooker, Pascale Marie Elisabeth Cordiez
  • Patent number: 5723224
    Abstract: A phosphorescent material has an excellent life time characteristic when it is applied to display device such as a fluorescent display device and includes a body portion composed of alkali metal and an oxide, and a protective coat formed over a surface of the body portion. The protective coat is composed of an oxide containing at least one element selected from the group consisting of Al, Ti, Si, Zn, Sn, Bi, Sb, Ce, Y, Ta, Gd, Ru and Ga.
    Type: Grant
    Filed: April 12, 1996
    Date of Patent: March 3, 1998
    Assignee: Futaba Denshi Kogyo K.K.
    Inventors: Hitoshi Toki, Yoshihisa Yonezawa, Yoshitaka Kagawa
  • Patent number: 5722379
    Abstract: This invention provides a porous thermal barrier layer for protecting parts of an internal-combustion engine having parts which are acted upon by combustion, and particularly by heat, and to a process for applying such a thermal barrier layer to these parts. The thermal barrier layer, which is formed of grains and/or fibers connected with one another on the exterior side, and is produced at least partially from a heat-resistant, temperature-shock-stable and abrasion-proof barrier material, has a heat penetration number defined by the following formulab=.sqroot.p.cndot.C.cndot..lambda.withb: the heat penetration number of the thermal barrier layerin ?J.cndot.(Kcm.sup.2 .sqroot.s).sup.-1 !,p: the density of the thermal barrier layer in ?g/cm.sup.3 !,.lambda.: the thermal conductivity of the barrier material in ?W/cmK!, andC: the specific heat of the barrier material in ?J/gK!which heat penetration number is smaller than 0.25 ?J.cndot.(Kcm.sup.2 .sqroot.s).sup.-1 !, particularly smaller than 0.1 ?J.cndot.(Kcm.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: March 3, 1998
    Assignee: Daimler-Benz AG
    Inventors: Klaus Binder, Karl-Ludwig Weisskopf, Patrick Izquierdo
  • Patent number: 5718983
    Abstract: A composition of materials having ferromagnetic and piezoelectric properties is disclosed. In the preferred embodiment, the composition of materials comprises a first layer of Pb.sub.(1-x-y) Cd.sub.x Fe.sub.y and a second layer of Cr.sub.(1-z-w) Zn.sub.z Te.sub.w where x, y, z and w are values within the ranges of 0.38.ltoreq.x.ltoreq.0.042, 0.08.ltoreq.y.ltoreq.0.094, 0.38.ltoreq.z.ltoreq.0.41, 0.28.ltoreq.w.ltoreq.0.31, and 0.25.ltoreq.(1-z-w).ltoreq.0.32. Additionally, each of the layers contain the elements of Bi, O, and S. A random-accessible, non-volatile memory built using the This memory provides for storing two independent bits of binary information in a single storage cell. Each cell comprises two orthogonal address lines formed on the opposite surface of a Si substrate, a composition of materials of the present invention formed over each of the address lines, and an electrode formed over each composition of materials. The data is stored electromagnetically and retrieved as a piezoelectric voltage.
    Type: Grant
    Filed: January 6, 1997
    Date of Patent: February 17, 1998
    Assignee: Kappa Numerics, Inc.
    Inventor: Shimon Gendlin
  • Patent number: 5716720
    Abstract: A thermal barrier protected nickel based or cobalt based superalloy component for use in a gas turbine engine includes a thermal barrier coating system having a multi-layered structure. The first bondcoat layer of the thermal barrier coating system comprises a chemical vapor deposited, platinum modified diffusion aluminide layer on the superalloy component (substrate). The diffusion aluminide layer includes an inner diffusion zone proximate the substrate and an outer layer region comprising a platinum modified (platinum-bearing) intermediate phase of aluminum and at least one of nickel and cobalt depending on the superalloy composition. The intermediate phase is a non-ordered solid solution having a range of compositions and is free of other phase constituents.
    Type: Grant
    Filed: March 21, 1995
    Date of Patent: February 10, 1998
    Assignee: Howmet Corporation
    Inventor: Kenneth S. Murphy
  • Patent number: 5714049
    Abstract: A post plating or post coating method for improving formability and weldability properties in sheet steel product having a protective zinc or zinc alloy layer formed on at least one surface thereof. The steps of the method comprise immersing the sheet steel product into a bath containing at least zinc to apply the protective layer, removing the sheet steel product from the bath, the sheet steel product having a protective zinc or zinc alloy layer formed on at least one surface thereof, and applying an alkaline solution to the protective layer to form a zinc oxide layer thereon, the alkaline solution being applied at a location outside the bath.
    Type: Grant
    Filed: December 16, 1996
    Date of Patent: February 3, 1998
    Assignee: Bethlehem Steel Corporation
    Inventors: C. Ramadeva Shastry, Stavros G. Fountoulakis, Elmer J. Wendell
  • Patent number: 5708117
    Abstract: The description relates to coating agents for use as primers and fillers in the manufacture of multilayer lacquer coatings, more particularly in the motor-vehicle sector.The coating agent contains a binder mixture ofA) 60-75 wt. % of a hydroxy-functional copolymer with an OH number of 110 to 170 mg KOH/g, obtainable froma) 5-60 wt. %, preferably 10-30 wt. % of at least one diester of an alpha, beta-olefinically unsaturated dicarboxylic acid with saturated monohydric alcohols containing 1-8 carbon atoms,b) 10-70 wt. %, preferably 35-60 wt. % of one or more vinyl aromatic hydrocarbons,c) 0-30 wt. %, preferably 0-15 wt. % of one or more glycidyl esters of aliphatic saturated monocarboxylic acids branched in the alpha position,d) 25-50 wt. % of at least one hydroxy alkyl ester or a mixture of at least one alkyl ester and one hydroxyl alkyl ester of an alpha, beta-olefinically unsaturated monocarboxylic acid, ande) 0-10 wt. % of one or more alpha, beta-unsaturated monocarboxylic acids,B) 1-6 wt.
    Type: Grant
    Filed: March 11, 1996
    Date of Patent: January 13, 1998
    Assignee: Herberts Gesellschaft mit Beschrankter Haftung
    Inventors: Heinz Dietholf Becker, Gerhard Bremer, Fritz Sadowski, Werner Stephan
  • Patent number: 5702832
    Abstract: It is an object of the present invention to provide a magnetoresistance effect element which has a film with a spin valve structure or an artificial lattice film having good soft magnetic characteristics, and which can be applied to a high-sensitivity magnetic head. The present invention provides a magnetoresistance effect element including a stacked film formed on a substrate by sequentially stacking a ferromagnetic film containing as its main constituents at least one elements selected from the group consisting of Co, Fe, and Ni, a nonmagnetic film, and the ferromagnetic film, wherein the two ferromagnetic films are not coupled with each other, and the closest packed plane of each ferromagnetic film is oriented in a direction perpendicular to the film surface.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: December 30, 1997
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hitoshi Iwasaki, Yuichi Ohsawa, Reiko Kondoh, Susumu Hashimoto, Atsuhito Sawabe, Yuzo Kamiguchi, Masashi Sahashi
  • Patent number: 5698335
    Abstract: It is an object of the present invention to provide a magnetoresistance effect element which has a film with a spin valve structure or an artificial lattice film having good soft magnetic characteristics, and which can be applied to a high-sensitivity magnetic head. The present invention provides a magnetoresistance effect element including a stacked film formed on a substrate by sequentially stacking a ferromagnetic film containing as its main constituents at least one elements selected from the group consisting of Co, Fe, and Ni, a nonmagnetic film, and the ferromagnetic film, wherein the two ferromagnetic films are not coupled with each other, and the closest packed plane of each ferromagnetic film is oriented in a direction perpendicular to the film surface.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: December 16, 1997
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hitoshi Iwasaki, Yuichi Ohsawa, Reiko Kondoh, Susumu Hashimoto, Atsuhito Sawabe, Yuzo Kamiguchi, Masashi Sahashi
  • Patent number: 5679464
    Abstract: The present invention provides a joined product of heat-resisting alloys, comprising heat-resisting alloy sheets or foils optionally having an oxide film on their surfaces, said heat-resisting alloy sheets or foils being joined to each other at their surfaces facing each other with an composite having a melting point in the range of from 800.degree. to 1400.degree. C. The joined product of heat-resisting alloys is produced by putting the above-described composite oxide on a heat-resisting alloy in a sheet or foil form at its portion to be joined, putting another heat-resisting alloy in a sheet or foil form and heating the resulting assembly at a temperature of 9/10 or more of the melting point of the composite oxide.
    Type: Grant
    Filed: November 30, 1993
    Date of Patent: October 21, 1997
    Assignee: Nippon Steel Corporation
    Inventors: Shogo Konya, Akira Okamoto
  • Patent number: 5672436
    Abstract: The invention relates to a titanium article of manufacture having an oxidation resistant surface and a process for producing such article wherein said titanium has an aluminized surface layer formed on it by the vapor deposition of aluminum on the titanium followed by oxidizing the surface layer.
    Type: Grant
    Filed: May 31, 1990
    Date of Patent: September 30, 1997
    Assignee: Grumman Aerospace Corporation
    Inventor: Albert G. Tobin
  • Patent number: 5656382
    Abstract: An oriented conductive thin film useful as a thin film electrode or a thin film resistor is disclosed, comprising an epitaxial or oriented ABO.sub.3 type oxide (e.g., BaPbO.sub.3) conductive thin film which is obtained by coating a single crystal oxide substrate or a single crystal semiconductor substrate with a solution of a metal oxide precursor comprising an organometallic compound, thermally decomposing the coating layer, followed by annealing. An epitaxial or oriented ABO.sub.3 type ferroelectric thin film may further be provided on the conductive thin film.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: August 12, 1997
    Assignee: Fuji Xerox Co., Ltd.
    Inventor: Keiichi Nashimoto
  • Patent number: 5631090
    Abstract: An iron-based heat-generating material excellent in oxidation resistance at an elevated temperature which comprises an iron-based alloy capable of generating heat by passing electricity therethrough and a coating of aluminum and oxygen formed on the surface of the alloy, the amount of the oxygen in the coating is less than the stoichiometric amount of oxygen in Al.sub.2 O.sub.3. The material can be prepared by vacuum evaporation of Al onto the surface of the iron-based alloy wherein an oxygen partial pressure in a vacuum gaseous atmosphere for the vacuum evaporation is adjusted so that there is formed on the surface of the alloy a coating consisting of aluminum and oxygen, the amount of the oxygen in the coating being less than the stoichiometric amount of oxygen in Al.sub.2 O.sub.3. When the material is heated in ambient or oxidizing atmosphere, an outermost layer of the coating is rapidly converted to Al.sub.2 O.sub.3.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: May 20, 1997
    Assignee: Nisshin Steel Co., Ltd.
    Inventors: Yasushi Fukui, Atsushi Ando, Yoshikazu Morita, Masanori Matsuno, Minoru Saito, Hideo Miyake, Masahiko Souda
  • Patent number: 5601932
    Abstract: A ceramic member (52) is direct-bonded to a copper composite substrate by heating to diffuse copper to the surface of the copper composite substrate (56), oxidizing the copper composite substrate following heating, placing a ceramic member in contact with the resulting oxidized substrate, and forming a copper-copper oxide eutectic (54) at the interface between the copper composite substrate and the ceramic member by heating. The eutectic, upon cooling, forms a bond between the copper composite and the ceramic.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: February 11, 1997
    Assignee: Hughes Aircraft Company
    Inventors: Alvin L. Krum, William T. Campbell
  • Patent number: 5585197
    Abstract: In a magneto-optical recording medium having a substrate, a recording layer having at least a rare earth-transition metal alloy film formed on the substrate, and a dielectric layer formed on the recording layer, a depth of penetration in the recording layer for an element derived from the dielectric layer is set to 70.ANG. or less from an interface between the recording layer and the dielectric layer in a depth-directional film structure analysis by an Auger electron spectroscopy. Accordingly, mixing of impurities into the recording layer can be suppressed to thereby lower the value of the required recording magnetic field.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: December 17, 1996
    Assignee: Sony Corporation
    Inventors: Etsuro Ikeda, Masahiro Kikkawa, Takashi Kishi
  • Patent number: 5573863
    Abstract: A soft magnetic alloy film includes: a fine crystalline phase having an average grain size of 10 nm or less and essentially consisting of Fe of b-c-c structure; and an amorphous phase containing a rare earth element or at least one of the elements, Ti, Zr, Hf, V, Nb, Ta and W, and O (oxygen) in a large amount, the fine crystalline phase and amorphous phase existing in a mixed state, with the proportion of the fine crystalline phase of Fe of b-c-c structure to the entire structure being 50% or less. A plane magnetic element employs such a soft magnetic alloy.
    Type: Grant
    Filed: February 25, 1994
    Date of Patent: November 12, 1996
    Assignee: Alps Electric Co., Ltd.
    Inventors: Ysuo Hayakawa, Akinori Kojima, Akihiro Makino
  • Patent number: 5562998
    Abstract: A thermal barrier coating for superalloy turbine engine vanes and blades that are exposed to high temperature gas is disclosed. The coating includes an Aluminide or MCrAlY layer, an alumina layer, and a ceramic top layer. The ceramic layer has a columnar grain microstructure. A bond inhibitor is disposed in the gaps between the columnar grains. This inhibitor is either unstabilized zirconia, unstabilized hafnia, or a mixture thereof.
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: October 8, 1996
    Assignee: AlliedSignal Inc.
    Inventor: Thomas E. Strangman
  • Patent number: 5549978
    Abstract: It is an object of the present invention to provide a magnetoresistance effect element which has a film with a spin valve structure or an artificial lattice film having good soft magnetic characteristics, and which can be applied to a high-sensitivity magnetic head. The present invention provides a magnetoresistance effect element including a stacked film formed on a substrate by sequentially stacking a ferromagnetic film containing as its main constituents at least one elements selected from the group consisting of Co, Fe, and Ni, a nonmagnetic film, and the ferromagnetic film, wherein the two ferromagnetic films are not coupled with each other, and the closest packed plane of each ferromagnetic film is oriented in a direction perpendicular to the film surface.
    Type: Grant
    Filed: November 1, 1993
    Date of Patent: August 27, 1996
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hitoshi Iwasaki, Yuichi Ohsawa, Reiko Kondoh, Susumu Hashimoto, Atsuhito Sawabe, Yuzo Kamiguchi, Masashi Sahashi
  • Patent number: 5545489
    Abstract: A multi-layer sliding bearing having an excellent anti-fretting property, comprises a back steel layer, and a bearing alloy layer formed on the back steel layer. A film of phosphate having a thickness of 0.1-15 .mu.m is formed on a back surface of the back steel layer, thereby enhancing the anti-fretting property of the bearing. The provision of the phosphate film well compatible with a mating material overcomes damage to the bearing due to fretting in a high-speed range. Therefore, the bearing can fully exhibit a bearing performance even under severe conditions of use in a high-speed, high-temperature and high-load range as typically experienced in a high-performance engine.
    Type: Grant
    Filed: October 20, 1994
    Date of Patent: August 13, 1996
    Assignee: Daido Metal Company Ltd.
    Inventors: Tadashi Tanaka, Masaaki Sakamoto, Koichi Yamamoto, Tohru Kato, Mitsuru Sugita
  • Patent number: 5543130
    Abstract: A multi-layer metal-ceramic material including an alumina layer and a metallic layer including an Mg-containing alloy. The alumina layer and metallic layer are bonded together via a reaction layer including MgAl.sub.2 O.sub.4 spinel. The alumina and metallic layers are pressed together and heated to a temperature below the solidus of the Mg-containing alloy, whereby the Mg migrates through the metallic layer to the interface and reacts with the alumina layer to form the spinel reaction layer. The bonded interface is excellent in resistance to Na attack.
    Type: Grant
    Filed: February 13, 1995
    Date of Patent: August 6, 1996
    Assignee: NGK Insulators, Ltd.
    Inventors: Nobuo Tsuno, Tomoyuki Fujii
  • Patent number: 5534357
    Abstract: A brazing sheet for vacuum brazing is provided wherein the sheet is cladded with an aluminum alloy brazing filler metal having a content of Mg sufficient for vacuum brazing but less than 1.2 wt. % and wherein the Mg.sub.2 Si particle size among Mg contained in the metal is not more than 5 .mu.m as a typical value.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: July 9, 1996
    Assignee: Nippondenso Co., Ltd.
    Inventors: Tatsuhiko Nonoyama, Shoei Teshima, Haruhiko Otsuka, Yasuyuki Tanaka, Kouji Hiragami
  • Patent number: 5532031
    Abstract: A ceramic substrate having an improved I/O pad adhesion layer. The ceramic substrate has an I/O pad for joining to an I/O pin. The I/O pad includes an improved adhesion layer of TiO, followed by layers of Ti (or Ti and Ni) and a solder wettable layer which may be Au or Pt. Also disclosed are low yield stress solders of Sn/Sb, Sn/Ag, Sn/Cu and Sn/Cu/Ti.
    Type: Grant
    Filed: January 29, 1992
    Date of Patent: July 2, 1996
    Assignee: International Business Machines Corporation
    Inventors: Shaji Farooq, Sampath Purushothaman, Srinivasa S. N. Reddy, Vivek M. Sura
  • Patent number: 5518823
    Abstract: An aluminum foil to be etched for use as the electrolytic condenser electrodes is composed of a foil body of an aluminum purity of 99.9% or higher, and an oxide layer 20-70 .ANG. thick and formed due to contact of the foil body with an oxidizing atmosphere. At least one etching nuclei-forming element is concentrated in a boundary region and/or in an outermost surface region of the oxide layer, the boundary region being disposed between the foil body and the oxide layer, and both the regions having a thickness of 20 .ANG. or less. The ratio in ion intensity of a maximum concentration of the elements in these regions to a concentration of the elements in the inner layer of the foil body is 1.2-30. There are three patterns in distribution of the elements, so that the maximum concentration is in a predetermined ratio to the concentration in the surface region, the inner layer or a minimum concentration appearing between the regions.
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: May 21, 1996
    Assignee: Showa Aluminum Kabushiki
    Inventors: Tadao Fujihira, Masashi Sakaguchi, Kiyoshi Tada, Makoto Tanio, Eizo Isoyama
  • Patent number: 5512382
    Abstract: A thermal barrier coating for superalloy turbine engine vanes and blades that are exposed to high temperature gas is disclosed. The coating includes a ceramic layer applied to an Aluminide or MCrAlY bond coat by electron beam physical vapor deposition. The ceramic layer has a first portion having unstabilized porosity, a second portion, overlying the first portion, with stabilized porosity, and an outer portion wherein the pores are coated with a noble metal. The stabilized porosity portion along with the noble metal coating reduce the thermal conductivity of the ceramic layer. Stabilizing the porosity renders it more resistant to sintering densification at high temperatures.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: April 30, 1996
    Assignee: AlliedSignal Inc.
    Inventor: Thomas E. Strangman
  • Patent number: 5499905
    Abstract: A metallic component of a gas-turbine installation is formed of a nickel-based base material and at least two coating layers superimposed on the base material for improving corrosion-resistance thereof. The coating layers include a first layer having a composition and/or thickness for resisting corrosive attack of the nickel-based base material at temperatures of 600.degree. C. to 800.degree. C. (HTCII), and a second coating layer having a composition and/or thickness for resisting corrosive attack of the base material at temperatures of 800.degree. C. to 900.degree. C. (HTCI).
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: March 19, 1996
    Assignee: Siemens Aktiengesellschaft
    Inventors: Friedhelm Schmitz, Norbert Czech, Bruno Deblon
  • Patent number: 5478655
    Abstract: Painted metal sheet pretreated with a composite coating including an insoluble, inorganic inner layer and an organic outer layer. The inorganic layer is formed by rinsing the sheet with an alkaline solution containing at least 0.005M of at least one of a dissolved silicate or a dissolved aluminate. The sheet is dried to form an inorganic layer having a thickness of at least 2 .ANG.. The inorganically coated sheet then is rinsed with a solution containing at least 0.1 vol.-% of a hydrolyzed silane and at least 0.02 vol.-% of a hydrolyzed crosslinking agent. The silane treated sheet is dried to form a siloxane layer having an average thickness at least 5 .ANG.. After being painted, the siloxane layer forms an adherent bond between the paint and the metal substrate. The metal preferably is a chromium alloyed steel and may be etched prior to being rinsed with the alkaline solution to remove chromium oxide to further enhance the paint adhesion.
    Type: Grant
    Filed: January 25, 1994
    Date of Patent: December 26, 1995
    Assignee: Armco Inc.
    Inventors: Ashok Sabata, Wim J. van Ooij
  • Patent number: 5455121
    Abstract: A steel material for colored springs is formed with a metallic deposit on the surface. The metallic deposit contains copper, zinc, and chromium. In an annealing process, copper and zinc diffuse in the deposit to exhibit a gold color tone while chromium is oxidized to exhibit a dark gray color tone. The combination of these color tones exhibits a beautiful black color tone which is distinguishable from a normal spring. The deposit improves the formability in the spring shaping process.
    Type: Grant
    Filed: March 11, 1994
    Date of Patent: October 3, 1995
    Assignee: Shinko Kosen Kogyo Kabushiki Kaisha
    Inventors: Masao Yamada, Keiji Hattori, Hirofumi Ueki, Takashi Kubo
  • Patent number: 5427866
    Abstract: A coated article comprises a base article having a substrate made of a material selected from the group consisting of a nickel-base alloy and a cobalt-base alloy, an intermediate metallic coating structure, and a thermal barrier coating. The intermediate metallic coating structure may be a protective layer of platinum, rhodium, or palladium on the base article, with no bond coat. The intermediate metallic coating may also be a bond coat, either oxidized or unoxidized, with a protective layer of platinum, rhodium, or palladium thereon. The protective layer typically partially interdiffuses with the underlying metallic structure.
    Type: Grant
    Filed: March 28, 1994
    Date of Patent: June 27, 1995
    Assignee: General Electric Company
    Inventors: Bangalore A. Nagaraj, William B. Connor, Richard W. Jendrix, David J. Wortman, Larry W. Plemmons
  • Patent number: 5403419
    Abstract: A rubbery composite material comprising a substrate and a rubber composition bonded thereto is prepared by metallizing a substrate with a thin film of zinc, copper, cobalt or an alloy thereof by dry plating such as vacuum deposition, ion plating, DC magnetron sputtering, bipolar sputtering, and RF sputtering processes, and pressing a vulcanizable rubber composition to the metallized substrate under heat and pressure to effect vulcanization bonding.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: April 4, 1995
    Assignee: Bridgestone Corporation
    Inventors: Masato Yoshikawa, Yukio Fukuura, Setsuo Akiyama, Makoto Nakamura, Kazuo Naito, Toshio Honda
  • Patent number: 5374488
    Abstract: A method for producing a tin free steel having double layers consisting of a lower layer of flatly deposited metallic chromium and an upper layer of insoluble hydrated chromium oxide which is characterized by a dissolution of soluble hydrated chromium oxide after the formation of three layers consisting of a bottom layer of metallic chromium, a middle layer of insoluble hydrated chromium oxide and an upper layer of soluble hydrated chromium oxide on a steel base by using a chromic acid electrolyte with a small amount of fluoride compound. By using this tin free steel, a welded can body can be produced at high speed without the removal of the plated layer in the welded part because this tin free steel has an excellent weldability.
    Type: Grant
    Filed: July 17, 1992
    Date of Patent: December 20, 1994
    Assignee: Toyo Kohan Co., Ltd.
    Inventors: Nobuyoshi Shimizu, Fumio Kunishige, Hideaki Hamano, Tsuneo Inui
  • Patent number: 5356724
    Abstract: A material for producing far-infrared radiation is disclosed. The material comprises a substrate and an Al--Mn alloy-derived oxide surface layer on the substrate, the oxide surface layer being porous with an average pore diameter of 0.01-2.0 micrometers and a porosity of 10.sup.3 -10.sup.12 pores/cm.sup.2, the weight ratio of Mn/Al of the oxide surface layer being 0.001-2.0, and the thickness of the oxide surface layer being 0.1-100 micrometers.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: October 18, 1994
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Tetsuaki Tsuda, Yasuhiro Yamamoto, Junichi Uchida, Hirohisa Seto, Kunihiro Fukui, Shinya Hikino
  • Patent number: 5336567
    Abstract: A nickel alloy electroplated cold-rolled steel sheet excellent in press-formability and phosphating-treatability, which comprises: (a) a cold-rolled steel sheet consisting essentially of: carbon (C): up to 0.06 wt. %, silicon (Si): up to 0.5 wt. %, manganese (Mn): up to 2.5 wt. %, phosphorus (P): up to 0.1 wt. %, sulfur (S): up to 0.025 wt. %, soluble aluminum (Sol.Al): up to 0.10 wt. %, nitrogen (N): up to 0.005 wt. %, and the balance being iron (Fe) and incidental impurities; (b) a nickel alloy electroplating layer, formed on at least one surface of the cold-rolled steel sheet, the nickel alloy electroplating layer consisting of nickel alloy particles precipitated at a distribution density of at least 1.times.10.sup.12 /m.sup.2, the nickel alloy particles containing at least one of phosphorus (P), boron (B) and sulfur (S) in an amount of 1 to 15 wt. %, the plating weight of the nickel alloy electroplating layer being 5 to 60 mg/m.sup.
    Type: Grant
    Filed: December 30, 1991
    Date of Patent: August 9, 1994
    Assignee: NKK Corporation
    Inventors: Toyofumi Watanabe, Akihiko Furuta, Tadashi Ono, Yoshinori Yomura, Shuichi Iwado
  • Patent number: 5246787
    Abstract: A coated tool or instrument has a wear-resistant hard coating (7) which is preferably titanium nitride for working organic material which is disposed on a separating layer (9) applied on a basic body (3). The separating layer (9) comprises a ceramic electrically non-conducting material. Such a material is preferably an oxide, nitride or oxynitride of silicon. The separating layer (9) protects the basic body (3) of the tool or instrument of e.g. a non-corrosion resistant steel. During the coating of the basic body (3) with the ceramic material, a pulsating dc voltage is applied to the basic body (3) or its holders. The pulse height is changed during the vapor deposition from high negative values to low negative values.
    Type: Grant
    Filed: June 1, 1992
    Date of Patent: September 21, 1993
    Assignee: Balzers Aktiengesellschaft
    Inventors: Hans Schulz, Helmut Daxinger, Erich Bergmann, Jurgen Ramm
  • Patent number: 5238752
    Abstract: A thermal barrier coating system for high temperature superalloys includes an intermetallic bond coating on the substrate and a ceramic topcoat having a columnar grain structure with the columnar axis perpendicular to the surface of the coating. The intermetallic coating is preferably a nickel aluminide or a platinum aluminide, whose upper surface is oxidized during processing to form a thin layer of predominantly aluminum oxide. The ceramic topcoat is preferably zirconium oxide having from about 6 to 20 percent yttrium oxide.
    Type: Grant
    Filed: May 7, 1990
    Date of Patent: August 24, 1993
    Assignee: General Electric Company
    Inventors: Edward C. Duderstadt, Bangalore A. Nagaraj
  • Patent number: 5236791
    Abstract: A magnetic recording medium that uses, as a protective coating layer provided on a magnetic layer for magnetically recording signals, a layer made of a nonmagnetic material consisting of two ore more elements of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W, and one or more elements of N, C, O, and B, or made of a magnetic material consisting of one or more elements of Co, Fe, Ni, and Gd, one or more elements of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W, and one or more elements of N, C, O, B, and Si is excellent in sliding endurance. When the protective coating layer is made of the nonmagnetic material, the magnetic recording medium is also excellent in corrosion resistance, and when the protective coating layer is made of the magnetic material, the spacing between a magnetic head and the magnetic recording medium can advantageously be made large. Both the cases are high in reliability, and suitable for high density magnetic recording.
    Type: Grant
    Filed: August 28, 1989
    Date of Patent: August 17, 1993
    Assignee: Hitachi, Ltd.
    Inventors: Yotsuo Yahisa, Yoshihiro Shiroishi, Sadao Hishiyama, Tomoyuki Ohno, Shinichiro Saitoh, Suzuki Hiroyuki, Yoshibumi Matsuda, Norikazu Tsumita, Masaki Ohura, Noriyuki Shige, Kazumasa Takagi
  • Patent number: 5230965
    Abstract: Selective electrolytic deposition on either conductive or non-conductive bodies is provided by forming a layer of a metal which forms a plating-preventing compound on the surface of the body to be plated, and selectively interdiffusing a plating-enabling metal into the surface of that compound-forming metal in those locations where plating is desired and electroplating the body. The interdiffusion may be done before or after the plating-preventing compound has formed on the surface of the compound-forming layer. During the electroplating, the electroplating metal deposits only in those locations where the plating-enabling metal has interdiffused with the compound-forming metal. At the end of the process, the compound-forming metal may be removed in those locations where it is not covered by the electroplated metal to provide a plurality of separate plated conductors.
    Type: Grant
    Filed: June 8, 1992
    Date of Patent: July 27, 1993
    Assignee: General Electric Company
    Inventors: Herbert S. Cole, Jr., James W. Rose
  • Patent number: 5209987
    Abstract: An article of manufacture, for example a conductor for an electrical wire or cable, is provided with a refractory coating preferably formed from a refractory metal or semi-metal oxide or nitride and preferably deposited on the surface of the article by a vacuum deposition process such as a sputter ion plating method. Adhesion of the refractory coating, especially at high temperatures may be improved, and migration of the substrate metal through the coating may be suppressed by varying the stoichiometry of the coating through its thickness and/or by the provision of a metallic or refractory intermediate layer. The articles are particularly suitable for use in circuit and signal integrity cables.The vacuum deposited refractory layer may constitute the sole refractory, or additional refractory layers may be deposited by other methods e.g. a sol-gel method.
    Type: Grant
    Filed: October 30, 1990
    Date of Patent: May 11, 1993
    Assignee: Raychem Limited
    Inventors: Richard J. Penneck, James M. O'Brien, Stephen J. Duckworth, Nicholas J. G. Smith
  • Patent number: 5200276
    Abstract: A brown coated article which exhibits stable color is provided by the composition and structure of a zinc hot-dip galvanizing layer. The zinc hot-dip galvanizing layer consists essentially of from 1 to 15% by weight of Fe and from 0.05 to 1% by weight of Mn, and balance of Zn. A brown Zn-Mn-Fe oxide layer is present on the surface of the zinc hot-dip galvanizing layer.
    Type: Grant
    Filed: July 15, 1992
    Date of Patent: April 6, 1993
    Assignee: Nippon Mining & Metals Co., Limited
    Inventors: Hiroshi Tasaki, Eiji Nishimura, Yasunori Yamamoto
  • Patent number: RE34173
    Abstract: An erosion and corrosion resistant coating is formed of a plurality of alternating layers of metallic and ceramic materials. The two materials selected for the layers have complementary wear resistant characteristics, such that one is relatively ductile and the other is relatively brittle. The concentration of the two materials at the interface between adjacent layers is graded to improve the adhesion of the layers and to provide a more unified coating. Preferably radio-frequency sputtering is employed to deposit the coating, since it does not produce excessive heating which could negate any prior heat treatment of the substrate onto which the coating is deposited.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: February 2, 1993
    Assignee: Midwest Research Technologies, Inc.
    Inventor: Susan M. Kerber