Oxide-containing Component Patents (Class 428/632)
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Publication number: 20010014410Abstract: An object of the invention is to provide a surface-treated copper foil capable of consistently attaining a percent loss of peel strength in resistance against hydrochloric acid degradation of 10% or less as measured on a copper pattern prepared from the copper foil and having a line width of 0.2 mm, by bringing out the maximum effect of the silane coupling agent employed in brass-plated anti-corrosive copper foil. The Another object is to impart excellent moisture resistance to the surface-treated copper foil.Type: ApplicationFiled: January 26, 2001Publication date: August 16, 2001Applicant: Mitsui Mining & Smelting Co., Ltd.Inventors: Masakazu Mitsuhashi, Takashi Kataoka, Naotomi Takahashi
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Patent number: 6273678Abstract: An article is formed of a gas turbine component having a substrate, an internal passage through the substrate defining an internal surface of the substrate, and an internal protective layer overlying the internal surface of the substrate. The internal protective layer has a composition of aluminum, plus, in weight percent, on average from about 0.1 to about 5.0 percent of a modifying element selected from the group consisting of hafnium, yttrium, zirconium, chromium, and silicon, and combinations thereof, and elements found in the substrate.Type: GrantFiled: August 11, 1999Date of Patent: August 14, 2001Assignee: General Electric CompanyInventor: Ramgopal Darolia
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Publication number: 20010012567Abstract: A material having a titanium dioxide crystalline orientation film oriented in a specific direction on a surface of a substrate is produced by spraying a vaporized titanium alkoxide onto the surface of the substrate heated under atmospheric pressure along with an inert gas as a carrier. The material having the titanium dioxide crystalline orientation film is excellent in properties such as an antimicrobial activity, a stain resistance, an ultra-hydrophilic property and the like, and is widely used as kitchen appliances such as cooking utensils, tableware and a refrigerator, tools for medical care, materials for a toilet or a toilet room, a filter of an air-conditioner, electronic parts, building materials and road-associated materials.Type: ApplicationFiled: February 6, 2001Publication date: August 9, 2001Applicant: KOUSEI CO. LTD.Inventors: Hidetoshi Saitoh, Shigeo Ohshio, Norio Tanaka, Hideki Sunayama
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Publication number: 20010012569Abstract: Provided are a substrate with a zinc oxide layer, in which at least a zinc oxide layer is provided on a support substrate, wherein the zinc oxide layer comprises a zinc oxide layer having the c axis perpendicular to the support substrate and a zinc oxide layer having the c axis slantindicular to the support substrate in the order from the side of the support substrate; and a photovoltaic device in which a semiconductor layer is formed on the substrate with the zinc oxide layer. Thus provided is the inexpensive photovoltaic device with excellent reflective performance and optical confinement effect and with high photoelectric conversion efficiency.Type: ApplicationFiled: April 3, 2001Publication date: August 9, 2001Inventors: Kozo Arao, Hideo Tamura, Noboru Toyama, Yuichi Sonoda, Yusuke Miyamoto
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Patent number: 6270914Abstract: The invention provides a method of surface hardening a titanium material wherein titanium-aluminum alloy powders or aluminum oxide powders are brought into contact with the surface of the titanium material, and a heat treatment is applied thereto, causing aluminum contained in the powders to be diffused in the surface of the titanium material so that intermetallic compounds such as Ti3Al, TiAl, and the like are formed inmediately underneath the surface of the titanium material, thereby enhancing surface hardness without causing surface exfoliation. The invention also provides a surface-hardened titanium-base material, and decorative articles and watchcases, composed of the surface-hardened titanium-base material, which are substantially impervious to scratches, and not prone to cause metallic allergy.Type: GrantFiled: November 10, 1998Date of Patent: August 7, 2001Assignee: Citizen Watch Co., Ltd.Inventors: Naoto Ogasawara, Yasumasa Kusano, Shizue Itoh, Kotaro Ishiyama
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Publication number: 20010008706Abstract: A method for forming an oxide film on a substrate by a sputtering process using a target comprising a metal as the main component, wherein sputtering is carried out in an atmosphere which contains a gas containing carbon atoms.Type: ApplicationFiled: May 19, 1999Publication date: July 19, 2001Inventors: JUNICHI EBISAWA, NOBUTAKA AOMINE, YASUO HAYASHI, SATORU TAKAKI
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Publication number: 20010008708Abstract: A ceramic heat barrier coating is deposited on a substrate so that the coating has a columnar growth pattern which is interrupted and repeated a number of times throughout its thickness by successive regermination of the ceramic deposit. The regermination is obtained by a vapour phase deposition process wherein a polluting gas is introduced intermittently during the deposition of the ceramic. The resulting ceramic coating has a lower thermal conductivity than conventional columnar ceramic coatings.Type: ApplicationFiled: January 12, 2001Publication date: July 19, 2001Applicant: SOCIETE NATIONAL D'ETUDE ET DE CONSTRUCTION DE MOTEURS D'AVIATION "SNECMA"Inventors: Yann Philippe Jaslier, Andre Hubert Louis Malie, Jean-Pierre Julien Charles Huchin, Serge Alexandre Alperine, Romain Portal
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Patent number: 6258466Abstract: Disclosed is a method for in situ formation of titanium aluminide. The disclosed method is directed to overcoming voiding problems which result in conventional titanium and aluminum metal interconnect stacks. The steps of the method comprise first providing a silicon substrate, which typically comprises an in-process integrated circuit wafer. Next, an insulating passivation layer is provided on the silicon substrate. The next step is the sputtering of a titanium layer of a given thickness over the passivation. Subsequently, an aluminum film of three times the thickness of the titanium layer is sputtered over the titanium layer. The next step comprises annealing the titanium layer and the aluminum film in situ in a metal anneal chamber to form titanium aluminide. Following the in situ anneal, the remainder of the needed aluminum is sputtered over the titanium aluminide and a further passivation layer of titanium nitride is then sputtered over the aluminum.Type: GrantFiled: January 18, 2000Date of Patent: July 10, 2001Assignee: Micron Technology, Inc.Inventor: Allen McTeer
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Publication number: 20010006737Abstract: An article is coated with a multi-layer coating comprising a nickel layer, a chrome layer, a refractory metal layer, a refractory metal compound layer, and a refractory metal oxide layer or a layer comprised of the reaction products of refractory metal, oxygen and nitrogen. The coating is decorative and also provides abrasion protection, corrosion protection, and improved chemical resistance.Type: ApplicationFiled: February 21, 2001Publication date: July 5, 2001Inventors: Richard P. Welty, Patrick Jonte, Carl W. Trendelman
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Patent number: 6255004Abstract: A device made of a III-V nitride compound semiconductor comprising a substrate of sapphire, a Si single crystal, a GaAs single crystal, or a GaP single crystal; a GaN single crystal film with a thickness not greater than 3 nm formed on the substrate; and at least one layer of a III-V nitride compound semiconductor formed on the GaN single crystal film. Also a device made of a III-V nitride compound semiconductor comprising a Si single crystal substrate having a natural oxide film; a SiOn film formed by partially nitriding the natural oxide film; and a layer of a III-V nitride compound semiconductor formed on the SiON film.Type: GrantFiled: July 14, 1998Date of Patent: July 3, 2001Assignee: The Furukawa Electric Co., Ltd.Inventor: Seikoh Yoshida
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Patent number: 6255001Abstract: A thermal barrier coating system and a method for forming the coating system on an article. The coating system employs a bond coat of a nickel aluminide alloy over which a thermal-insulating ceramic layer is deposited. The nickel aluminide bond coat contains zirconium, but is otherwise predominantly of the beta (&bgr;) NiAl phase. The bond coat is preferably deposited by a physical vapor deposition process to have a fine-grain microstructure and a limited diffusion zone in the article surface.Type: GrantFiled: January 19, 1999Date of Patent: July 3, 2001Assignee: General Electric CompanyInventor: Ramgopal Darolia
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Patent number: 6251526Abstract: The cast part (1) comprises a basic body (2) of a first material and a coating of at least one second material. The second material is applied to a co-cast skeleton structure (3) on the surface (20) of the basic body, with it forming a covering (4) or a covering layer (42).Type: GrantFiled: February 2, 1999Date of Patent: June 26, 2001Assignee: Sulzer Innotec AGInventor: Fritz Staub
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Patent number: 6248416Abstract: The present invention provides for magnetic and magneto-optic recording media, transducers and data storage devices constructed therefrom that have highly oriented films having long range order in the crystal structure of the film. The recording medium includes a magnetic recording layer comprised of Co-based material, such as Co or one or more Co alloys having a (10{overscore (1)}0) crystal texture, a substrate, a first underlayer having a fcc structure and a (110) crystal texture disposed between the substrate and the magnetic recording layer. A second underlayer having a bcc structure and a (112) crystal texture is also disposed between the magnetic recording layer and the first underlayer. In particular, if a (110) Si single crystal substrate is non-oxidized certain metals having fcc structures, such as Ag, Cu, Al, and Au and fcc derivative structures, such L10 and L12 structures, can be epitaxially grown on the Si surface.Type: GrantFiled: November 10, 1997Date of Patent: June 19, 2001Assignee: Carnegie Mellon UniversityInventors: David N. Lambeth, David E. Laughlin, Wei Yang, Heng Gong, Jie Ziou
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Patent number: 6242097Abstract: There is disclosed a cable having a covering layer on the outside of a multicore stranded wire composed of plural insulated conductors that are intertwined, wherein at least an outermost layer of the covering layer is made of a crosslinked product of a resin composition containing (a) 10 to 60% by weight of a polyamide elastomer made up of a block copolymer whose hard segment is a polyamide, (b) 5 to 60% by weight of a thermoplastic polyurethane resin, (c) 10 to 60% by weight of a thermoplastic polyester elastomer, and (d) 0 to 20% by weight of a thermoplastic styrene elastomer. The airtightness and the watertightness at the interface between the cable and a molded body are kept for extended periods without taking any particular sealing measures. The corrosion of the conductors in the cable and the deterioration of the performance of the connected parts of machinery and tools can be prevented, and the cable has excellent water resistance.Type: GrantFiled: August 5, 1998Date of Patent: June 5, 2001Assignee: The Furukawa Electric Co., Ltd.Inventors: Masaki Nishiguchi, Dai Hashimoto, Hitoshi Yamada, Ryoji Ohno
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Patent number: 6238808Abstract: Provided are a substrate with a zinc oxide layer, in which at least a zinc oxide layer is provided on a support substrate, wherein the zinc oxide layer comprises a zinc oxide layer having the c axis perpendicular to the support substrate and a zinc oxide layer having the c axis slantindicular to the support substrate in the order from the side of the support substrate; and a photovoltaic device in which a semiconductor layer is formed on the substrate with the zinc oxide layer. Thus provided is the inexpensive photovoltaic device with excellent reflective performance and optical confinement effect and with high photoelectric conversion efficiency.Type: GrantFiled: January 20, 1999Date of Patent: May 29, 2001Assignee: Canon Kabushiki KaishaInventors: Kozo Arao, Hideo Tamura, Noboru Toyama, Yuichi Sonoda, Yusuke Miyamoto
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Patent number: 6231999Abstract: A heat-resistant transparent glass article is formed with a film stack deposited on a glass substrate, the film stack comprising one or more infrared reflective films each bearing on its surface facing away from the substrate a protective film of niobium metal having a thickness of up to 25 Å and preferably in the range of about 7 Å to 20 Å. A protective film of niobium metal or metal oxide may be formed on the other surface (facing the substrate) of each infrared reflective film. Metal nitride films such as silicon nitride may be employed between neighboring infrared reflective films, and as an outer protective film.Type: GrantFiled: February 13, 1997Date of Patent: May 15, 2001Assignee: Cardinal IG CompanyInventor: Annette J. Krisko
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Patent number: 6224963Abstract: A turbine shroud having a coating comprising a bond layer covering the shroud substrate, and a thick ceramic stabilized zirconia layer with a segmented morphology covering the bond coat. The segmented morphology is defined by an array of slots or grooves which extend from the outer surface of the ceramic layer inwards through almost the entire thickness of the coating but without piercing the underlying substrate. The segmented morphology comprises a plurality of grooves that are laser drilled into the ceramic layer. Each groove is formed by laser drilling a series of holes that are spaced from each other so that the groove has a fully segmented portion and a partially segmented portion.Type: GrantFiled: April 27, 1998Date of Patent: May 1, 2001Assignee: AlliedSignal Inc.Inventor: Thomas E. Strangman
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Patent number: 6221513Abstract: Methods for hermetically sealing an interface surface of ceramic materials, such as zirconia, to an interface surface of metallic materials, such as titanium alloys, using a titanium-nickel alloy filler material are disclosed. Preferred ceramic materials include stabilized zirconia materials; preferred metallic materials include titanium-niobium alloys; and a preferred titanium-nickel filler material is a 50-50 titanium-nickel alloy. At least one of the interfaces is contacted by the titanium-nickel alloy filler material and sealing is accomplished under vacuum conditions at temperatures of from 900 to 1200° C. during application of pressure to the joint. The methods are especially suitable for use in hermetically sealing ceramic and metallic components for applications such as implantable medical devices, electrical connectors, electronic packages, sporting goods, structural components, and the like.Type: GrantFiled: May 12, 1998Date of Patent: April 24, 2001Assignee: Pacific Coast Technologies, Inc.Inventor: Brian J. Lasater
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Patent number: 6221511Abstract: In the present invention, a metal-ceramic composite substitute is produced by joining a metal plate to a ceramic substrate by using a brazing material in a paste form prepared by adding 10-14 parts by weight of a vehicle to 100 parts by weight of a powder of which the solid centent comprises 90.0˜99.5% of an Ag powder, 0˜9.5% of a Cu powder and 0.5˜4.0% of an active metal powder, and 0.0˜0.9% of a titanium oxide powder if necessary.Type: GrantFiled: March 9, 1998Date of Patent: April 24, 2001Assignee: Dowa Mining Co. Ltd.Inventors: Masami Sakuraba, Masami Kimura, Masaya Takahara, Junji Nakamura
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Patent number: 6218029Abstract: A multi-layer thermal barrier coating for a superalloy article includes a metallic matrix coating containing particles, a MCrAlY alloy bond coating on the metallic matrix coating, a thin oxide layer on the MCrAlY alloy bond coating and a columnar grain ceramic thermal barrier coating. The metallic matrix coating includes a 80 wt % nickel-20 wt % chromium alloy. The particles include metallic compounds such as carbides, oxides, borides and nitrides, which react with harmful transition metal elements such as titanium, tantalum and hafnium, in the superalloy substrate. One suitable compound is chromium carbide because the harmful transition metal elements will take part in an exchange reaction with the chromium in the chromium carbide to form a stable carbide of the harmful transition metal element. This reduces the amount of harmful elements in the superalloy reaching the oxide layer and increases the service life of the thermal barrier coating.Type: GrantFiled: November 17, 1997Date of Patent: April 17, 2001Assignees: Rolls-Royce, PLC, Chromalloy United Kingdom LimitedInventor: David S Rickerby
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Patent number: 6218027Abstract: A steel suitable for a fabric with or without painting and has good corrosion resistance with reproducibility, even if the steel is composed mainly of ordinary carbon steel or low alloy steel, wherein the surface of the steel is coated with rust comprising one or more selected from Ti, Nb, Ta, Zr, V and Hf in the total amount of 0.01 wt % or more. In the steel, the fraction of &agr;-FeOOH and an amorphous rust is 35 wt % or more, and the fraction of &bgr;-FeOOH is 20 wt % or less.Type: GrantFiled: August 27, 1999Date of Patent: April 17, 2001Assignee: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd)Inventors: Fumio Yuse, Takenori Nakayama, Toshiaki Kan
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Patent number: 6207297Abstract: A turbine component contains a substrate (22) such as a superalloy, a basecoat (24) of the type MCrAlY, and a continuous barrier layer (28) between the substrate and basecoat, where the barrier layer (28) is made of an alloy of (Re, Ta, Ru, Os)X, where X can be Ni, Co or their mixture, where the barrier layer is at least 2 micrometers thick and substantially prevents materials from both the basecoat and substrate from migrating through it.Type: GrantFiled: September 29, 1999Date of Patent: March 27, 2001Assignee: Siemens Westinghouse Power CorporationInventors: Stephen M. Sabol, John G. Goedjen, Steven J. Vance
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Patent number: 6203932Abstract: A method of manufacturing steel wire for reinforcement of rubber articles comprises the steps of passing a wire rod plated with brass, through a group of dies immersed in a lubricant containing phosphate in continuous wet processing, winding the resulting steel wire around a spool, mounting the spool on a pay of unit of a twister assembly, and drawing the steel wire by the use of one or more dies arranged between the pay of unit and twisting unit of the twister assembly and having an area reduction per die of at least 5%, to reduce the diameter of the steel wire. Phosphor compound in the coating film formed on the brass plating of the steel wire contains phosphor in the range of 0.2 to 0.9 mg/m2 and zinc oxide in the range of 20.0 to 70.0 mg/m2. Also, provided is a steel cord which comprises twisted steel wires.Type: GrantFiled: June 18, 1998Date of Patent: March 20, 2001Assignee: Bridgestone CorporationInventor: Hara Hisakatu
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Patent number: 6193835Abstract: A process for producing a rubber-based composite material including steps of laminating a rubber compound onto a substrate, with a bonding layer of metal or metal compound interposed therebetween, and subsequently vulcanizing the rubber compound, characterized in that a prime-coating film is interposed between the substrate and the bonding film of metal or metal compound. The rubber-based composite material retains good bond strength even when used in such a way that its bond interface is in contact with water. In addition, it has good adhesion to the substrate treated by conversion treatment.Type: GrantFiled: April 10, 1998Date of Patent: February 27, 2001Assignee: Bridgestone CorporationInventors: Masato Yoshikawa, Nobuko Kato
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Patent number: 6194083Abstract: A ceramic composite material comprises a ceramic material constituting a matrix, and dispersion particles disposed in the matrix in a dispersing manner. A specific shape of a ceramic composite material is, for instance, a sinter or a thermally sprayed layer. The dispersion particles are consisting of a composite oxide including at least one kind of a first metallic element selected from alkaline earth metals such as Mg and Ca, and at least one kind of a second metallic element selected from W, Ti, Ta, Mo, Nb, V, B, Te, Ge and Si, for instance, are composite oxide particles precipitated by reacting a compound containing a first metallic element and a compound including a second metallic element through heat treatment. The precipitated particles consisting of such a composite oxide can be dispersed as planar particles or acicular particles in the ceramic layer to which, for instance, thermal spraying is applied.Type: GrantFiled: July 27, 1998Date of Patent: February 27, 2001Assignee: Kabushiki Kaisha ToshibaInventors: Kazuhiro Yasuda, Seiichi Suenaga, Kunihiko Wada, Hiroki Inagaki, Yasuhiro Goto
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Patent number: 6183884Abstract: A metallic article includes a bond coating and a ceramic thermal barrier coating on the bond coating. The ceramic thermal barrier coating includes a plurality of columnar grains, which extend perpendicularly to the surface of the metallic article. Each columnar grain includes a plurality of layers. Some of the layers include sub-grains extending at an acute angle to the surface of the metallic article to form voids between adjacent sub-grains. The voids are arranged at an acute angle to the surface of the metallic article and reduce the thermal conductivity of the ceramic thermal barrier coating. Some of the layers include sub-grains extending perpendicularly to the surface of the metallic article to provide erosion resistance.Type: GrantFiled: December 16, 1998Date of Patent: February 6, 2001Assignees: Rolls-Royce PLC, Chromalloy United Kingdom LimitedInventor: David S Rickerby
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Patent number: 6180259Abstract: In order to advantageously solve problems such as lowering of the productivity, contamination of alloy coating due to the adoption of different metal, increase of the cost due to the adoption of different coating process, a coating of MCrAlX alloy containing an oxide such as CoO, NiO or the like is directly formed at a thickness of 10˜500 &mgr;m through a low pressure plasma spraying process containing substantially no oxide and thereafter the same MCrAlX alloy xontaining no oxide is applied thereonto at a thickness of 100˜800 &mgr;m through a low pressure plasma spraying process in a non-oxidizing atmosphere to form a composite sprayed coating.Type: GrantFiled: November 20, 1998Date of Patent: January 30, 2001Assignee: Tocalo Co., Ltd.Inventors: Yoshio Harada, Tatsuo Suizu, Takema Teratani
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Patent number: 6180260Abstract: A method for providing a substantially-smooth protective coating on a metal-based substrate is disclosed. It comprises the steps of: (a) applying a thermal barrier coating over the substrate by plasma-spraying; (b) plasma-heating the applied coating according to a time- and temperature schedule sufficient to re-melt the surface region of the coating, allowing it to flow and smoothen; and then (c) cooling the surface region to a temperature below its melting point. The thermal barrier coating is often zirconia-based, e.g., yttria-stabilized zirconia. After being cooled, the surface is much smoother than when originally applied, thereby allowing the coating to be used in a higher-temperature environment.Type: GrantFiled: June 3, 1999Date of Patent: January 30, 2001Assignee: General Electric CompanyInventors: Dennis Michael Gray, Wayne Charles Hasz, Timothy Francis Bethel, Curtis Alan Johnson, Marcus Preston Borom
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Patent number: 6180570Abstract: A method of preparing a biaxially textured article comprises the steps of providing a metal preform, coating or laminating the preform with a metal layer, deforming the layer to a sufficient degree, and rapidly recrystallizing the layer to produce a biaxial texture. A superconducting epitaxial layer may then be deposited on the biaxial texture. In some embodiments the article further comprises buffer layers, electromagnetic devices or electro-optical devices.Type: GrantFiled: July 9, 1998Date of Patent: January 30, 2001Assignee: UT-Battelle, LLCInventor: Amit Goyal
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Patent number: 6168860Abstract: A composite film on a substrate having a first magnetostrictive, magnetoresistive, anisotropic ferromagnetic thin-film provided on that substrate with a second ferromagnetic thin-film provided immediately thereon which is also magnetorestrictive, magnetoresistive, anisotropic, with a composition differing from the first ferromagnetic thin-film. Various parameters of said first and second ferromagnetic thin-films are selected to provide such a composite film with little or no magnetostriction. Such composite films can be used in various devices.Type: GrantFiled: July 12, 1996Date of Patent: January 2, 2001Assignee: Nonvolatile Electronics, IncorporatedInventor: James M. Daughton
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Patent number: 6168874Abstract: A thermal barrier coating system and a method for forming the coating system on a component designed for use in a hostile thermal environment, such as superalloy turbine, combustor and augmentor components of a gas turbine engine. The coating system includes a diffusion aluminide bond coat whose oxide growth rate is significantly reduced to improve the spallation resistance of a thermal barrier layer by forming the bond coat to include a dispersion of aluminum, chromium, nickel, cobalt and/or platinum group metal oxides. The oxides preferably constitute about 5 to about 20 volume percent of the bond coat. A preferred method of forming the bond coat is to initiate a diffusion aluminizing process in the absence of oxygen to deposit a base layer of diffusion aluminide, and then intermittently introduce an oxygen-containing gas into the diffusion aluminizing process to form within the bond coat the desired dispersion of oxides.Type: GrantFiled: February 2, 1998Date of Patent: January 2, 2001Assignee: General Electric CompanyInventors: Bhupendra K. Gupta, Thomas E. Mantkowski, Nripendra N. Das, Raymond W. Heidorn
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Patent number: 6159621Abstract: The invention concerns a transparent substrate provided with a thin-film stack comprising at least one metallic film with reflective properties in the infrared, under which is disposed a first antireflection coating consisting essentially of one or more metal oxides, and an upper protective metallic film characterized in that the protective metallic film consists of an alloy of Ti, Zr or Hf with Al, Pt or Pd or an AlSi alloy.According to the invention, the second upper antireflection coating includes at least two metal oxide films, one of which is ZnO based and contains 0.1 to 10% by weight of at least one of the elements B, Si, Ga, Sm, Al, Co, Mg, Mn, Fe, Ni and/or Cr and the other is SnO.sub.2 or Bi.sub.2 O.sub.3 based, and a final, hard oxide based film.Type: GrantFiled: July 31, 1998Date of Patent: December 12, 2000Assignee: Saint-Gobain VitrageInventors: Heinz Schicht, Uwe Schmidt, Wilfried Kaiser, Bodo Hryniw
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Patent number: 6153313Abstract: A coating system (20) for articles used in hostile thermal environments, such as turbine, combustor and augmentor components (10) of a gas turbine engine. The coating system (20) of this invention employs a NiAl-based intermetallic coating (24) containing 30 to 60 atomic percent aluminum so as to be predominantly of the .beta.-NiAl phase, but also contains alloying additions intended to increase the creep strength of the coating (24), and optionally contains alloying additions to getter impurities, increase fracture resistance, and promote oxidation resistance. For this purpose, the coating (24) preferably includes additions of chromium, titanium, tantalum, silicon, hafnium and/or gallium, and optionally contains additions of calcium, zirconium, yttrium, and/or iron.Type: GrantFiled: October 6, 1998Date of Patent: November 28, 2000Assignee: General Electric CompanyInventors: Joseph D. Rigney, Ramgopal Darolia, William S. Walston, Reed R. Corderman
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Patent number: 6153320Abstract: A magnetic device uses laminated ferromagnetic layers containing antiferromagnetically coupled ferromagnetic films coupled together with improved antiferromagnetically coupling (AFC) films. The AFC films are formed of the binary and ternary alloys comprising combinations of Ru, Os and Re. The ferromagnetic film thicknesses, the AFC film thicknesses and the compositions of the films in the laminated layer can be varied to engineer the magnetic properties of the device. The magnetic devices whose properties are improved with the improved laminated layers include spin valve magnetoresistive read heads and magnetic tunnel junction (MTJ) devices for use as magnetic memory cells and magnetoresistive read heads.Type: GrantFiled: May 5, 1999Date of Patent: November 28, 2000Assignee: International Business Machines CorporationInventor: Stuart Stephen Papworth Parkin
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Patent number: 6143422Abstract: A material which can be improved in its resistance to corrosion caused by alcohol-containing fuels after formation without detriment to weldability and without any substantial cost increase is developed.ConstitutionA chromate film is applied to a Zn--X alloy electroplating layer, in which X is one or more of Ni: 3-18 wt %, Co: 0.02-3 wt %, Mn: 25-45 wt %, or Cr: 8-20 wt %. The Zn--Ni alloy plating layer underlying the chromate film has cracks with a density of 1000-150000 in terms of the number of plated regions surrounded by cracks in a 1 mm.times.1 mm visual field, with cracks having a maximum width of 0.5 .mu.m or less comprising 90% or more of the total number of the cracks, and with cracks having a depth of 80% or more of the thickness of the plating layer comprising 80% or more of the total number of the cracks.Type: GrantFiled: February 5, 1998Date of Patent: November 7, 2000Assignee: Sumitomo Metal Industries, Ltd.Inventors: Hiroyuki Nagai, Yoshihiro Kawanishi, Eiji Kajiyama, Hiroyuki Kashiwagi, Shinichi Tsuchiya
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Patent number: 6143425Abstract: A rolling device includes: an outer member; an inner member; and a plurality of rolling elements arranged between the outer and inner members, the outer member having a first contact surface which contacts the rolling elements, the inner member having a second contact surface which contacts the rolling elements, each of the rolling elements rolling against the first and second contact surfaces. At least one of the outer member, inner member, and rolling elements is formed of steel containing: C of less than 0.6 wt %; Cr of 10.0 wt % to 22.0 wt %; Mn of 0.1 wt % to 1.5 wt %; Si of 0.1 wt % to 2.0 wt %; N from 0.05 wt % to less than 0.2 wt %; Mo of 0 to 3.0 wt %, and V of 0 to 2.0 wt %; and the balance Fe and inevitable impurities, the steel satisfying C %+N %.gtoreq.0.45 wt %. The rolling device has excellent characteristics in fatigue strength, wear resistance, corrosion resistance, and acoustic characteristic.Type: GrantFiled: December 23, 1998Date of Patent: November 7, 2000Assignee: NSK Ltd.Inventors: Susumu Tanaka, Kenji Yamamura, Manabu Ohori
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Patent number: 6143430Abstract: Surface treated steel sheet for fuel containers having excellent corrosion resistance, formability and weldability is provided. A steel sheet containing 0.0005-0.0040% of C, 0.005-0.020% of P, 0.0005-0.0040% of N, and 0.0005-0.0030% of B has on at least one surface a first coating layer constituted as a Zn coating layer of a coating weight of 5-80g/m.sup.2 and a second coating layer on the first coating layer constituted as a Ni coating layer of a coating weight of 0.5-10g/m.sup.2. The Zn coating layer is composed of Zn, Zn--Fe alloy or Zn--Ni alloy. Alternatively, one surface is formed with the first coating layer and the second coating layer and the other surface is formed with a Zn coating layer.Type: GrantFiled: July 29, 1999Date of Patent: November 7, 2000Assignee: Nippon Steel CorporationInventors: Akihiro Miyasaka, Shinichi Suzuki
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Patent number: 6139976Abstract: The invention relates to an article of manufacture comprising: a substrate composed of a superalloy containing chromium and a base element selected from the group consisting of iron, cobalt, and nickel; and an enrichment layer containing chromium and placed on the substrate. Therein, the enrichment layer comprises a continuous matrix composed of a gamma-phase solid solution of chromium in the base element. The invention also relates to the manufacture of such an article. The article may in particular be a gas turbine component.Type: GrantFiled: June 7, 1999Date of Patent: October 31, 2000Assignee: Siemens AktiengesellschaftInventors: Norbert Czech, Knut Halberstadt, John Smith, Adrian Kempster
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Patent number: 6136456Abstract: Grain oriented electrical steel sheet with a very low iron loss and a method for producing the same, wherein the surface of the iron substrate of the grain oriented electrical steel sheet is subjected to an enhancement treatment of crystal grain orientation or surface smoothing to a mean roughness of about 0.20 .mu.m or less, electroplating a chromium plating layer on the substrate with heterogeneous growth, and applying a tension coating film to the plating layer.Type: GrantFiled: October 23, 1998Date of Patent: October 24, 2000Assignee: Kawasaki Steel CorporationInventors: Michiro Komatsubara, Hiroi Yamaguchi, Minoru Takashima, Mineo Muraki
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Patent number: 6132888Abstract: A stainless steel wire is plated with nickel (Ni) to a thickness of from not less than 1 .mu.m to not more than 5 .mu.m. An inorganic salt coat film mainly composed of at least one of potassium sulfate and borax (borate) and free from fluorine (F) or chlorine (Cl) is then deposited on the nickel (Ni) plate 2 as the substrate. The steel wire is then drawn to a reduction of area of not less than 60% to adjust the surface roughness thereof to a range of from 0.80 to 12.5 .mu.mRz, preferably from 1.0 to 10.0 .mu.mRz.Type: GrantFiled: July 16, 1999Date of Patent: October 17, 2000Assignee: Sumitomo Electric Industries, Ltd.Inventor: Susumo Yamamoto
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Patent number: 6132889Abstract: An article is coated with a multi-layer coating comprising a nickel layer, a refractory metal or refractory metal alloy layer, a refractory metal compound or refractory metal alloy compound layer, and a refractory metal oxide or refractory metal alloy oxide layer or a layer comprised of the reaction products of refractory metal or refractory metal alloy, oxygen and nitrogen. The coating is decorative and also provides abrasion protection, corrosion protection, and improved chemical resistance.Type: GrantFiled: July 30, 1999Date of Patent: October 17, 2000Assignee: Vapor Technologies, Inc.Inventors: Richard P. Welty, Patrick Jonte, Carl W. Trendelman
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Patent number: 6110606Abstract: A high performance superconducting ceramic article for use in a liquid cryogen bath is provided. It includes a superconducting ceramic tape having at least one surface vulnerable to cryogenic infiltration is sealed on each vulnerable surface to a non-porous metallic laminate, which also provides the desired support structure, in substantially impervious relation by a non-porous metallic bonding agent. This results in greater protection of the superconducting ceramic tape from cryogen infiltration, and permits greater thermal cycling of the superconductor during use without causing degradation of the tape's critical current carrying capacity.Type: GrantFiled: August 30, 1996Date of Patent: August 29, 2000Assignee: American Superconductor CorporationInventors: John D. Scudiere, David M. Buczek
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Patent number: 6110604Abstract: A metallic article includes a bond coating and a ceramic thermal barrier coating on the bond coating. The ceramic thermal barrier coating includes a plurality of columnar grains extending substantially perpendicularly to the surface of the metallic article. Each columnar gain has a plurality of first layers, a plurality of second layers and a plurality of third layers. The first layers have a different structure from the second layers and the third layers. The second layers have a different structure from the third layers. The first layers have the same composition as the third layers. The second layers have a greater proportion of voids than the first layers and the third layers. The voids reduce the thermal conductivity of the thermal barrier coating. The second layers may also have a different composition from the first layers and the third layers to reduce the thermal conductivity.Type: GrantFiled: August 3, 1998Date of Patent: August 29, 2000Assignee: Rolls-Royce, PLCInventor: David S Rickerby
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Patent number: 6106958Abstract: An article, particularly a brass article, is coated with a multi-layer coating comprising a semi-bright nickel layer deposited on the surface of the article, a bright nickel layer deposited on the semi-bright nickel layer, a nickel-tungsten-boron layer deposited on the bright nickel layer, a chrome layer deposited on the nickel-tungsten-boron layer, a layer comprised of a non-precious refractory metal deposited on the chrome layer, a sandwich layer comprised of alternating layers of non-precious refractory metal compound, preferably zirconium nitride, and non-precious refractory metal, preferably zirconium, deposited on the non-precious refractory metal layer, a non-precious refractory metal compound such as zirconium nitride deposited on the sandwich layer, and a layer comprised of a non-precious refractory metal oxide or the reaction products of a non-precious refractory metal, oxygen and nitrogen deposited on the non-precious refractory metal compound layer.Type: GrantFiled: April 30, 1997Date of Patent: August 22, 2000Assignee: Masco CorporationInventors: Rolin W. Sugg, Richard P. Welty, Stephen R. Moysan, III
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Patent number: 6087023Abstract: The invention provides an improved near net-shape VPS formed multilayered combustion system component having an inner surface consisting of a smooth protective thermal barrier coating, and an outer layer of superalloy capable of withstanding temperatures in excess of 700.degree. C. The invention also includes the method of forming such components by first vacuum plasma spraying a suitable mold with a ceramic top coat, followed by a bond coat and followed by a thick structural layer of superalloy. The mold is then separated from the multilayered structure which results in the desired near net-shape component. Combustor liners and transition ducts of gas turbine engines can be advantageously formed in this manner.Type: GrantFiled: July 14, 1998Date of Patent: July 11, 2000Assignee: Progenesis Inc.Inventors: Peter G. Tsantrizos, George E. Kim, Alexander P. Cavasin, Serge Grenier
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Patent number: 6087027Abstract: A magnetic head of storage/read separation type in which both a reproducing head of magnetoresistive type and a write head of magnetic induction type are formed through a magnetic shield. The magnetic head includes a ferromagnetic material and an antiferromagnetic material in intimate contact with said ferromagnetic material. At least a part of the antiferromagnetic material acts to bring about unidirectional anisotropy in the ferromagnetic material, and is made of Cr--Mn-based alloy, and at least a part of the ferromagnetic material in intimate contact with the antiferromagnetic material is made of Co or Co-based alloy.Type: GrantFiled: June 17, 1998Date of Patent: July 11, 2000Assignee: Hitachi, Ltd.Inventors: Hiroyuki Hoshiya, Yoshihiro Hamakawa, Susumu Soeya, Shigeru Tadokoro
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Patent number: 6083632Abstract: A magnetoresistive effect film is formed by laminating a plurality of magnetic thin films onto a substrate with an intervening non-magnetic thin film, an antiferromagnetic thin film being provided so as to neighbor to one of the ferromagnetic thin film via this intervening non-magnetic thin film. With the bias magnetic field applied to the antiferromagnetic thin film being Hr and the coercivity of the other ferromagnetic thin film being Hc.sub.2, the condition Hc.sub.2 <Hr is satisfied. The antiferromagnetic thin film is made of either a cobalt oxide, a nickel oxide, or an a-phase ion oxide, or of an alloy of two or more of these materials, this being formed as a two-layer film.Type: GrantFiled: January 8, 1998Date of Patent: July 4, 2000Assignee: NEC CorporationInventors: Junichi Fujikata, Masafumi Nakada
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Patent number: 6077616Abstract: A reflective laminated strip includes an aluminum alloy or steel strip having a cleaned and conversion coated outer surface, an adhesive layer adjacent the conversion coated outer surface, and a polymer layer joined to the adhesive layer. An exterior side of the polymer layer is coated with a reflective metal layer that is preferably stainless steel, chromium, nickel or aluminum having a thickness of less than about 5000 .ANG.. In a preferred embodiment, an interior side of the polymer layer is coated with an adhesion-promoting metal layer or metal oxide layer having a thickness of about 50-5000 .ANG..Type: GrantFiled: November 18, 1998Date of Patent: June 20, 2000Assignee: Aluminum Company of AmericaInventors: Daniel L. Serafin, Frank A. Mozelewski, Robert E. Bombalski, Jean Ann Skiles, Edward C. Robinson, Peter M. Emens
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Patent number: 6071629Abstract: An organic rust-roof treated copper foil characterized in that it has a metallic rust-proof layer formed on the non-adhesive side of the original copper foil and has an organic rust-proof layer formed on said metallic rust-proof layer, the organic rust-proof layer comprising a mixture of at least two kinds of chemicals selected from the group consisting of benzotriazole, its derivatives, aminotriazole and its isomers and derivatives is provided with on said metallic rust-proof layer, or it further has a chromate-treated layer formed between said metallic rust-proof layer and said organic rust-proof layer.Type: GrantFiled: January 17, 1997Date of Patent: June 6, 2000Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Toshiko Yokota, Makoto Dobashi, Hiroshi Hata, Hisao Sakai, Susumu Takahashi, Junshi Yoshioka
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Patent number: 6071627Abstract: A ceramic coating layer which is not less than 70 .mu.m in the maximum height Rmax of its profile curves and not less than 45 .mu.m in the 10-point average roughness, or which is less than 650 HV in Vickers hardness is provided on a metallic substrate. A heat-resistant member of such composition is excellent in thermal fatigue resistance and keeps an excellent heat resistance for a long period of time. Quality of a heat-resistant member is evaluated by, measuring at least one of roughness and hardness of a ceramic coating layer on a metallic substrate. According to this method, it is possible to easily and accurately evaluate a thermal resistant life of a heat-resistant member.Type: GrantFiled: March 28, 1997Date of Patent: June 6, 2000Assignee: Kabushiki Kaisha ToshibaInventors: Kazuhiro Yasuda, Seiichi Suenaga, Kunihiko Wada, Hiroki Inagaki, Masako Nakahashi