Abstract: The present invention provides an aqueous composition and process for the electrodeposition of a layer of zinc containing silicon and phosphorus on a metal substrate. The electrodeposition composition is prepared by reacting metallic silicon and zinc with phosphoric acid and an alkali metal hydroxide in the ratio of between 0.4 and 1.3 moles of alkali metal hydroxide per mole of phosphoric acid, and adjusting the solution to a pH of 2 or higher after completion of the reaction. The coating is deposited on the metal substrate by electrodeposition and comprises about 70% to about 99.5% by weight of zinc, and about 0.10% to about 10% by weight of silicon, and about 0.5% to about 20% by weight of phosphorus.The resultant zinc/silicon/phosphorus coating improves the resistance of the metal substrate to corrosion, wear, galling and stress corrosion cracking.

Abstract: The present invention relates an aqueous composition and process for electro-depositing at a pH of about 1 to 3.5, a ductile, highly adhesive, adsorptive and absorptive zinc coating on a metal article. The article with the electro-deposited zinc coating can be subjected to further treatment, such as, a second functional or decorative coating or painting and forming. The ductile zinc coating is resistant to cracking during forming and metal articles treated in accordance to the present invention, including the formed areas, are highly resistant to corrosion, stress corrosion cracking, wear and galling.

Abstract: A novel low temperature vacuum seal and method of making same for joining a nonmetallic element, such as an optical port, to a metallic element is described which comprises first and second thin metallic layers applied to the nonmetallic element to provide substantial adhesion and solderability to the nonmetallic element, and a third metallic layer applied to the metallic element to provide solderability to the metallic element, the nonmetallic and metallic elements being joined by a layer of low temperature solder interfacing their respective solder surfaces. A further thin metallic layer may be applied to the nonmetallic element to provide substantial wetability to the solderable second layer.

Abstract: A wire electrode for a spark-eroding system for erosion cutting of workpieces using intermittent electrical charges includes a core of a current-conducting material and a wire coating of a material with a lower evaporation temperature, for example zinc. The core consists of one of the following alloys according to DIN (German Industrial Standard) 17666:(a) Cu Mg 0.4;(b) Cu Fe 2P;(c) Cu Cr Zr;(d) Cu Zr.

Abstract: An aluminum or aluminum alloy shape for manufacture of heat exchangers, coated with a metallic layer of a zinc-base alloy constituting a fluxless soldering or low temperature brazing material when heated. A process for direct coating of formed aluminum shapes in nascent state includes the steps of providing a non-reactive atmosphere around the shape, providing a coating material of zinc-base alloy and bringing the aluminum shape and the coating material into contact and maintaining the contact at an elevated temperature for a predetermined period of time for forming a coherent coating on the aluminum shape.

Abstract: A zinc alloy, having a copper layer coated thereon, consists essentially of from about 0.1 to about 0.8 weight percent copper, about 0.01 or more weight percent aluminum; up to about 0.05 weight percent magnesium, the balance being essentially zinc. The copper coated zinc alloy is advantageously employed to produce various cast, extruded, molded articles and the like including trim, fixtures as well as coin blanks. Further, the present invention relates to a metal article comprising a zinc base alloy having a copper overlayer in direct contact with the zinc base alloy, said alloy comprising about 1.5 weight percent or less aluminum and the remainder zinc. From another aspect, the subject invention contemplates a method for reducing the diffusion between a copper layer and a zinc base metal, said layer being in direct contact with the zinc base metal, said method comprising incorporating at least about 0.01 weight percent aluminum in said zinc base metal.

Abstract: A magnetic memory disk which has controlled magnetic characteristics in the radial direction is provided by controlling the thickness and composition of the magnetic layer which is formed on the disk. The thickness of the layer may be varied in the radial direction to control the remanence of the disk and the composition of the magnetic layer varied to control the coercivity of the disk. The magnetic layer is formed by an electroplating operation employing one or more rotating apertured masks in an electrolyte solution between an anode and a disk (cathode) which is to be plated. The thickness of the plated layer is determined by the configuration of the apertures in the mask, and the relative composition of the layer is determined by the variation and distance of the mask to the disk in the radial direction. Thickness characteristics of layers other than the magnetic layer may also be precisely controlled in the radial direction to achieve desired characteristics.

Abstract: An aureate coin, coin blank, medallion, medallion blank, token or token blank has a coin-shaped core with opposed faces and a peripheral side edge and of mintable metallic material. An electroplated coating of copper and tin completely encases the core and provides a golden appearance. The electroplated coating contains from about 8 to about 16% tin by weight and has a thickness of from about 10 to about 150 .mu.m.

Abstract: An improved treatment for copper foil that is to be used for lamination to a board comprises electrodepositing a dendritic layer of copper on the side of the foil that is to be laminated to the board. The dendritic layer is secured by electrodepositing a gilding layer of copper over it. A barrier layer is next electrodeposited over the gilding layer. The barrier layer is formed by means such as electrodeposition from a solution containing ions of zinc, nickel and antimony. This in turn is covered with an anticorrosion layer that is formed of chromates or phosphates, disposed over the barrier layer.

Abstract: A surface coated steel strip having improved corrosion resistance, comprising a steel strip, a zinc alloy (e.g. Zn-Ni, Zn-Mn, Zn-Co, etc.) layer electroplated on the strip, a chromate film formed on the zinc alloy layer in a weight of 2 to 60 mg/m.sup.2, and a polyethylene coating cured to the chromate film and weighing 0.3 to 5 g/m.sup.2 is prepared by applying a chromate solution to the zinc alloy plated strip and drying it into the chromate film, and applying an aqueous composition of a carboxylated-polyethylene resin, a melamine resin, and colloidal silica to the chromated strip and drying and curing the composition into the coating at elevated temperatures of at least 130.degree. C.

Abstract: The present invention provides an aqueous composition and process for the electrodeposition of a layer of zinc containing silicon and phosphorus on a metal substrate. The electrodeposition composition is prepared by reacting metallic silicon and zinc with phosphoric acid and an alkali metal hydroxide in the ratio of between 0.4 and 1.3 moles of alkali metal hydroxide per mole of phosphoric acid, and adjusting the solution to a pH of 2 or higher after completion of the reaction. The coating is deposited on the metal substrate by electrodeposition and comprises about 70% to about 99.5% by weight of zinc, and about 0.10% to about 10% by weight of silicon, and about 0.5% to about 20% by weight of phosphorus.The resultant zinc/silicon/phosphorus coating improves the resistance of the metal substrate to corrosion, wear, galling and stress corrosion cracking.

Abstract: A magnetic material wire is composed of a core of magnetic material having a Curie point of 70.degree. to 250.degree. C. and a high conductive metal sheathing of a uniform thickness covering the core. The ratio of the metal sheathing to the wire in cross-section is in the range of 15 to 40%. There is also disclosed a method of producing such a wire.

Abstract: A rubber article, such as a vehicle tire, reinforced with steel filaments in the form of cables, cords or wefts. The corrosion speed of the steel is reduced by using rubber having a specific electrical resistance of at least 5.times.107 Ohm centimeter.

Abstract: Tin free steel having three layers consisting of a bottom layer of metallic chromium, a middle layer of nickel-zinc alloy containing 10 to 90 weight percent of zinc and a top layer of hydrated chromium oxide on a steel base, and a method for the continuous production of this tin free steel which comprises:(a) chromium plating a steel base to form a layer of metallic chromium and hydrated chromium oxide, (b) nickel-zinc alloy plating the chromium plated steel base by using a nickel-zinc alloy plating electrolyte sufficiently acidic to dissolve the hydrated chromium oxide and (c) forming a hydrated chromium oxide layer on the chromium plated nickel-zinc plated steel base.Instead of (b) in the above method, a cathodic treatment in an acidic solution can be carried out for the removal of hydrated chromium oxide formed during chromium plating, and thereafter nickel-zinc alloy plating can be carried out by using a known nickel-zinc alloy plating electrolyte.

Abstract: A coating composite provides extended corrosion resistance for substrate metals. The thin metallic undercoat of the composite contains combined metals. The heat curable and substantially resin free topcoat is established from composition containing chromium in non-elemental form, which topcoat composition may further contain particulate metal, all in liquid medium. In addition to outstanding corrosion resistance, the composite can retain substrate weldability and formability, while further enhancing paintability and weatherability.

Abstract: A metal composite is provided extended corrosion resistance. Prior to joining the metals of the composite, at least one of the metals is provided with a metallic undercoat. This undercoat is then coated with a metallic zinc layer. Lastly, a heat curable and substantially resin free topcoat is established on the zinc layer and cured. The topcoat composition contains chromium in non-elemental form and may further contain particulate metal, all in liquid medium. The metal composite is then formed by contacting metals including the thus coated metal. In addition to outstanding corrosion resistance, the composite can retain substrate weldability while further enhancing weatherability.

Abstract: Thin metal plate is cleaned and electrolytically pickled in an acid solution. A zinc layer is electrodeposited on one face of the plate, after which a chrome-chromic oxide coating is deposited on both faces of the plate from a sulphuric acid solution containing compounds of trivalent and exhavalent chrome. The plate is then subjected to a drying-oxidating treatment in air. The plate may be steel having a thickness between 0.1 and 2 mm. The plate may be surface treated by phosphating, and then painted. The chrome-chromic oxide coating may have a thickness between 0.05 and 5 .mu.m, and the zinc coating a thickness between 1 and 30 .mu.m.

Abstract: An article of manufacture comprising a steel substrate coated with an electroplated metallic double layer with good corrosion resistance after painting and wet adhesion of paint film; said article having on the steel substrate a first layer of electroplated Zn-Ni alloy containing 7-15 wt % of Ni and on the first layer and, on said first layer, a second electroplated layer of iron or Fe-Zn alloy containing more than 60% of Fe and less than 40% of Zn.

Abstract: Flexible selective energy control sheet construction formed of a sheet of substantially transparent polymer thin film plastic material having first and second surfaces. A substantially transparent continuous adhesion promoting layer is adherent to the second surface of the sheet. A substantially transparent metal layer is adherent to the adhesion promoting layer and a protective layer is adherent to the metal layer. The metal layer is selected from the materials of copper and silver.

Abstract: A copper-clad laminate having special utility in the production of high resolution printed circuit patterns by either subtractive or semi-additive processing is made by vapor depositing a film of zinc on a copper film on a silica-coated aluminum carrier sheet, vapor depositing a silica film on the resulting zinc-copper foil, bonding the resulting body to a substrate and then stripping the silica-coated aluminum carrier sheet from the copper-clad laminate.

Abstract: A zinc-based composition comprising from 0.01 to 5 percent lead and 0.01 to 20 percent tin, preferably minor amounts of chromium and/or titanium and/or nickel and with the balance being zinc is provided. A minor amount of copper may also be present. The composition is particularly useful for joining copper and copper alloys because it will wet and readily flow on the copper or copper alloy surfaces. It can be used with or without a flux. It has reduced dissolving action on the copper and copper alloys due to its reduced reactivity with them. It also has improved conductivity vis-a-vis conventional lead-tin and lead-tin-silver solders.

Abstract: A multi-layer surface-treated steel plate comprises a zinc-containing plated layer, a lithium silicate film layer formed on said plated layer and an organic composite silicate film layer composed of colloidal silica and an organic resin, which is formed on the lithium silicate film layer.

Abstract: A metal laminate possessing high strength characteristics as well as good ductility and malleability, comprising one or more layers of a superplastic material metallurgically bonded to one or more layers of a non-super plastic material; and the method of preparing the laminate to induce plastic or super plastic characteristics to the nonsuper plastic material.

Abstract: An electroplated corrosion resistant steel, having on a base steel a first plated layer of a Zn-Ni alloy containing 5-20% of Ni and a second electroplated layer of zinc containing 0.005-0.5% of Cr. A method for producing the high corrosion resistant steel material is also disclosed.

Abstract: A steel sheet with its surface prepared for paint coating is disclosed. The surface treated steel sheet comprises a base sheet, and an iron-zinc alloy film plated on the base sheet in an amount of at least 0.1 g/m.sup.2 and having an iron content of from 3 to 30%. A composite silicate resin film is coated on the iron-zinc alloy film in an amount of from 0.05 to 5.0 g/m.sup.2. The resin film is composed of an acrylic copolymer, an epoxy resin, a silica sol and a trialkoxysilane compound. The treated surface provides superior paintability, degrease resistance and corrosion resistance after pain coating.

Abstract: A coated ferrous article with improved properties, e.g., improved overall corrosion resistance and good appearance. The article has a ferrous substrate and a ductile, adherent, corrosion resistant alloy coating metallurgically bonded to the substrate. The alloy coating has a thin intermetallic alloy layer intermediate the substrate and an alloy overlay. The alloy overlay consists essentially of, by weight, magnesium from 3% to 20%, silicon from 3% to 15%, balance aluminum and zinc, where the ##EQU1## is between 1 and 1.5. The metallurgical structure of the overlay is a mixture of (1) cored aluminum-rich dendrites having dendrite arm spacings (DAS) of less than 10.mu., (2) zinc-rich interdendritic regions, and (3) intermetallic phases of zinc, aluminum, magnesium and silicon. The article may be produced by hot dip coating a ferrous substrate in a molten metal bath of the above composition.

Abstract: The present invention is directed to the protecting of uranium and uranium alloy articles from corrosion by providing the surfaces of the articles with a layer of an ion-plated metal selected from aluminum and zinc to a thickness of at least 60 microinches and then converting at least the outer surface of the ion-plated layer of aluminum or zinc to aluminum chromate or zinc chromate. This conversion of the aluminum or zinc to the chromate form considerably enhances the corrosion resistance of the ion plating so as to effectively protect the coated article from corrosion.

Abstract: A copper-clad laminate having special utility in the production of high resolution printed circuit patterns by either subtractive or semi-additive processing is made by vapor depositing a film of zinc on a copper film on a silica-coated aluminum carrier sheet, vapor depositing a silica film on the resulting zinc-copper foil, bonding the resulting body to a substrate and then stripping the silica-coated aluminum carrier sheet from the copper-clad laminate.

Abstract: A copper foil for a printed circuit comprising a copper layer having the bonding surface coated with a tin layer and having said tin layer coated with a vanadium-containing zinc layer which optionally may be given a chromic acid treatment. The invention also provides a method for producing said copper foil.

Abstract: Novel micro-throwing alloy undercoatings, multi-layer coatings containing a novel micro-throwing alloy undercoating and method of improving the corrosion resistance of ferrous metal articles are provided in accordance with the invention. The novel micro-throwing alloy undercoatings are applied as an initial layer over ferrous metal and comprise a layer of alloy having micro-throwing power, such as nickel-cadmium, nickel-zinc, iron-cadmium, iron-zinc, cobalt-cadmium, cobalt-zinc or a ternary or quaternary alloy containing iron, nickel or cobalt in combination with cadmium or zinc. The method comprises application, preferably by electroplating, of a layer of novel micro-throwing alloy undercoating directly over ferrous metal, optionally followed by one or more layers of metallic or organic coatings which further contribute to improved corrosion resistance.

Abstract: Markedly superior corrosion protective properties are imparted to metal-bearing surfaces at substantially reduced costs by depositing upon said surfaces one or more superimposed coatings containing zinc alloying elements located intermediate the metal-bearing surfaces and a sacrificial layer of generally pure zinc. In this manner penetration of rust inducing substances into the metal bearing surfaces is effectively precluded under substantially all environmental conditions normally encountered.

Abstract: A process, article produced therefrom, and compositions are described for the reception of electroless plating onto a substrate of a non-catalytic metal or non-catalytic alloy. The process comprises contacting the surface of the non-catalytic substrate with a promotor composition containing ions selected from the group of nickel, cobalt, iron, and mixtures thereof and a suitable reducing agent, and thereafter contacting the treated surface with an electroless plating bath comprising hypophosphite for metallic build-up.

Abstract: An improved wire with an excellent adhesion with rubber is disclosed for reinforcing rubber goods, made by a diffusion process wherein oxides formed on the surface of plated metal during diffusion are removed before drawing.

Abstract: A method of increasing the rate of formation of zinc-iron alloy when hot-dip galvanizing a ferrous metal strip to effect complete alloying of the hot-dip zinc coating on at least one side of the strip, wherein a clean ferrous metal strip is provided on at least one lateral surface of the strip with a coating of metallic copper and heating the strip in a non-oxidizing atmosphere to a temperature sufficient to diffuse a portion of the copper coating into the ferrous metal strip (i.e. heating to a temperature between about 724.degree. C. and about 927.degree. C.)and thereafter hot-dip galvanizing the strip. With a very thin hot-dip zinc coating (i.e. having a thickness less than 0.1 mil) no further heating of the strip is necessary in order to provide on at least the one lateral surface a zinc-iron alloy diffusion coating free of unalloyed metallic zinc.

Abstract: A method of plating a metallic substrate by coating said substrate with a specific metallic system; plating at least one metal onto the coating; and heating the coated and plated metallic substrate to a temperature that effects a bonding of said metallic substrate to said coating and the plated metal. The method is utilized to plate metals onto metal substrates; including substrates such as aluminum and zinc.

Abstract: Markedly superior corrosion protective properties are imparted to metal-bearing surfaces at substantially reduced costs by depositing upon said surfaces one or more superimposed coatings containing zinc alloying elements located intermediate the metal-bearing surfaces and a sacrificial layer of generally pure zinc. In this manner penetration of rust inducing substances into the metal bearing surfaces is effectively precluded under substantially all environmental conditions normally encountered.

Abstract: A dry process high sensitivity imaging film includes a solid, high optical density and substantially opaque film of dispersion imaging material deposited on a substrate. The film of dispersion imaging material comprises a plurality of separate layers of different and substantially mutually insoluble metal components having relatively high melting points and relatively low melting point eutectics, and interfaces between said layers having relatively low melting points.

Abstract: A multi-layer plating and method for improving the corrosion resistance of ferrous metal articles, such as steel fasteners, are provided in accordance with the invention. The multi-layer plating comprises, in sequence over a ferrous metal substrate, a layer of an alloy which has micro-throwing power, such as nickel-cadmium, nickel-zinc, iron-cadmium, iron-zinc, cobalt-cadmium, or cobalt-zinc, a layer of cadmium, cadmium-tin alloy, a dual layer of cadmium and tin, zinc or zinc alloy, a layer of copper, a layer of nickel, and a layer of chromium or a metallic chromium substitute. The method comprises plating, and preferably electroplating, the aforementioned layers of alloy and metals over an article having a ferrous metal substrate to obtain improved corrosion resistance.

Abstract: A panel for selectively absorbing solar energy comprising an aluminum substrate, a layer of zinc thereon, a layer of nickel over the zinc layer and an outer layer of solar energy absorbing nickel oxide or a copper substrate with a layer of nickel thereon and a layer of solar energy absorbing nickel oxide distal from the copper substrate. A method for making aforesaid panels is disclosed.

Abstract: A method whereby a surface of chromium metal electrodeposited on a zinc substrate from a trivalent chromium electrolyte is treated by contacting the surface with an aqueous solution at a pH of from 5 to 12 and containing a dissolved metal salt of a weak acid which does not form a soluble complex with zinc. Preferred salts are carbonates, phosphates and silicates of an alkali metal, e.g. sodium or potassium. Also disclosed is the product of said process comprising an article having a zinc substrate, a microporous electrodeposited chromium coating from 0.025 to 2.5 microns in thickness on said substrate, and a water-insoluble basic salt of zinc within the micropores.

Abstract: A novel fastening means of a highly corrosion resistant nature and presenting a bright chrome-like outer appearance.

Abstract: A magnetic recording film having high magnetic remanence and unusually good square loop characteristics at thicknesses of between one and five microinches can be deposited directly on non-magnetic electroless nickel from an electroless bath containing cobalt ions, citrate ions, hypophosphite ions, phosphate ions and, if desired, nickel ions. The electroless bath may also contain an ethanolamine, or mixture thereof, as a wetting agent and brightener. The coercive force of the magnetic recording film can be selected to lie between 300 and 1,000 oersteds by adjusting the pH of the bath. Thicker structures with good square loop characteristics and high coercive force can be prepared by the successive plating of two or more magnetic thin films separated by thin films of non-magnetic nickel-phosphorus.

Abstract: An improvement in a process for making a rubber adherable wire, wherein a steel wire is plated with brass and then drawn through dies to reach the desired diameter, comprises coating the brass plated wire with 5.times.10.sup.-5 to 50.times.10.sup.-5 milligrams of zinc per square millimeter of coating surface prior to drawing. The product made by the process is useful for reinforcing rubber articles such as tires.

Abstract: Delamination of plating on aluminum, for example tin plating, is avoided by providing an intermediate alloy coating on the aluminum prior to its passage through a bath of molten tin or a tin alloy. The coating is applied by passing cleansed aluminum through to the plating thereof with a primary protective metal. The intermediate alloy coating alloy contains zinc, bismuth, cadmium, tin and lead.

Abstract: Improved electrical contact materials and a method for manufacturing same are disclosed. The improved materials comprise mechanically elongated billets composed of at least a first metal and the oxide of a second metal. The billets include a plurality of alternating substantially coaxial zones of metal-metal oxide and zones devoid of the metal oxide. The zones devoid of the metal oxide serve as slip zones and render the contact material readily formable into any desired electrical contact shape.

Abstract: A wear-resistant article comprises a zinc base metal having a substantially continuous, hard chromium skin layer on at least one surface thereof and a chromium-enriched subsurface layer of the zinc base metal situated immediately below the chromium skin layer. The chromium-enriched subsurface layer has a gradually decreasing chromium content in a direction inwardly away from the skin layer and is at least as thick as the skin layer. The wear-resistant article of this invention is produced by direct electrodeposition of chromium onto the zinc base metal from a self-regulating bath under controlled conditions.

Abstract: A method of plating a metallic substrate by coating said substrate with a specific metallic system; plating at least one metal onto the coating; and heating the coated and plated metallic substrate to a temperature that effects a bonding of said metallic substrate to said coating and the plated metal. The method is utilized to plate metals onto metal substrates; including substrates such as aluminum and zinc.

Abstract: A novel fastening means of a highly corrosion resistant nature and presenting a bright chrome-like outer appearance.

Abstract: The present invention relates to a method of treatment on the surface of copperfoil mainly used for printed circuits. More particularly, it relates to a method of electrodeposition of a binary alloy consisting of zinc and tin as a barrier layer against copper migration into an adhesive substrate during subsequent heat press lamination, while a binary alloy on copperfoil is converted to ternary alloy defusing into copper by heat press lamination resulting in a layer of Cu-Zn-Sn, ternary alloy. This layer prevents spottings on the etched surfaces and provides high resistance to hydrochloric acid, and better adhesion than hitherto used alloys.