Co- Or Ni-base Component Next To Fe-base Component Patents (Class 428/679)
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Patent number: 12123274Abstract: An apparatus is disclosed as including a first material volume with at least a hardened portion and a second material volume that includes at least two layers. The first material volume is composed of at least a hardenable alloy of steel. The at least two layers is located adjacent to a first surface comprising the hardened portion of the first material volume. The at least two layers includes a first layer composed of at least a ductile low-carbon alloy of steel and a second layer composed of at least a cobalt-based hardfacing over the first layer. The apparatus is applicable in preparing shear ram blocks and shear ram blades to provide a hardened blade edge with an adjacent hardfacing surface.Type: GrantFiled: September 16, 2020Date of Patent: October 22, 2024Assignee: Hydril USA Distribution LLCInventors: Jamie Clay Gamble, Eric Larson, Brian Baker, Daya Singh, Joseph Incavo, William Miller, Melissa Newbury, Mark Reinmuller
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Patent number: 11401567Abstract: A manufacturing method of a steel sheet includes: a step of performing continuous casting of molten steel having a Si content of 0.4 mass % to 3.0 mass % to obtain a slab; a step of performing hot rolling of the slab to obtain a hot-rolled steel sheet; a step of performing cold rolling of the hot-rolled steel sheet to obtain a cold-rolled steel sheet; a step of performing cold-rolled sheet annealing of the cold-rolled steel sheet; a step of performing pickling after the cold-rolled sheet annealing; a step of performing water washing after the pickling; and a step of performing drying after the water washing. A dew point is set to ?35° C. or lower in the cold-rolled sheet annealing, an electrical conductivity of a rinse water to be used in the water washing is set to 5.0 mS/m or less, a water-washing time is set to 15 seconds or less in the water washing, and the drying is started within 60 seconds from an end of the water washing.Type: GrantFiled: March 24, 2017Date of Patent: August 2, 2022Assignee: NIPPON STEEL CORPORATIONInventors: Toyomitsu Nakamura, Kenichiro Matsumura
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Patent number: 11084252Abstract: A surface-treated steel sheet according to an aspect of the present invention includes: a steel sheet as a base metal and a coating layer, in which the coating layer includes a Ni—Co alloy coating layer, a Ni—Fe alloy layer, and a Ni layer, in the coating layer, a total adhesion amount of Co is 0.2 g/m2 to 2.3 g/m2, and a total adhesion amount of Ni is 8.9 g/m2 or more, the Ni layer has a thickness of 0.3 ?m to 3.0 ?m, an atomic concentration of Co on a surface of the Ni—Co alloy coating layer is 20 at % to 70 at %, and a Co concentration gradient y in the coating layer in a depth direction is 50 mass %/?m to 400 mass %/?m.Type: GrantFiled: March 1, 2018Date of Patent: August 10, 2021Assignee: NIPPON STEEL CORPORATIONInventors: Mamoru Saito, Takehiro Takahashi, Kiyokazu Ishizuka
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Patent number: 10941478Abstract: An arc wire spraying method includes conveying at least two wires out of respective lance nozzles of a wire conveying device by means of the wire conveying device, applying current to the two wires to form an arc for melting the ends of the two wires, and applying airflow to the arc in the direction transverse to the longitudinal direction of the wire conveying device by means of an airflow applying device so as to spray the melted wire material toward a surface to be sprayed. The airflow applying device rotationally applies the airflow around the longitudinal direction of the wire conveying device. Parameters for spraying are variably adjusted along the rotating direction of the airflow applying device. The airflow is rotationally applied at a varying rotating speed.Type: GrantFiled: June 20, 2017Date of Patent: March 9, 2021Assignee: BMW Brilliance Automotive Ltd.Inventors: Franz Schwarz, Stefan Wagner, Jingyuan Du
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Patent number: 10910607Abstract: There is provided a method for producing a surface-treated steel sheet for battery containers (1) comprising forming a dull or semi-bright nickel plating layer (12) on at least the surface to be the outside of a battery container in a steel sheet (11), wherein the nickel plating layer (12) is formed by performing plating treatment under a condition of a bath temperature of 70° C. or more.Type: GrantFiled: March 11, 2016Date of Patent: February 2, 2021Assignee: Toyo Kohan Co., Ltd.Inventors: Eiji Okamatsu, Yuji Nakano, Daisuke Matsushige
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Patent number: 9926629Abstract: A hot-gas conducting component for a flow machine has a nickel-base wrought alloy as structural material and a hot gas-side lining made from the group of iron-chromium-aluminum-yttrium alloys and a flow machine having a component of this type.Type: GrantFiled: October 7, 2008Date of Patent: March 27, 2018Assignee: MAN Diesel & Turbo SEInventors: Markus Beukenberg, Sharad Chandra, Norbert Czech, Roland Herzog
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Patent number: 9502631Abstract: End-group components for superconducting accelerator cavity used in acceleration of charged particles are manufactured by subjecting pure niobium sheet materials to press forming composed mainly of flat-bottomed cylindrical drawing, preferably by simultaneously conducting control of slide velocity and/or its motion and control of tool die temperature and/or its distribution/gradient in the above press forming, further preferably by dynamically controlling blank holding force in accordance with the variation of flange area, flange thickness and deformed characteristics of niobium sheet materials during the press forming, more preferably by preparing an anisotropically shaped blank instead of a circular blank by use of servo press forming machine, servo-die cushion temperature control equipment, water-soluble solid coating type lubricant, and a tooling die.Type: GrantFiled: July 31, 2014Date of Patent: November 22, 2016Assignees: SHINOHARA PRESS SERVICE CO., LTD., INTER-UNIVERSITY RESEARCH INSTITUTE CORPORATIONInventors: Kiyohiko Nohara, Masayuki Shinohara, Nobuyuki Kawabata, Hideyoshi Nakamura, Hitoshi Hayano, Akira Yamamoto, Takayuki Saeki, Shigeki Kato, Masashi Yamanaka
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Patent number: 9489978Abstract: Provided is a method for surface-treating a metal component, whereby a pseudo-plated layer can be formed on a surface of a metal component, and quality equivalent to plating or other coating process can be obtained. The method includes a chemical polishing step scraping a surface of a base plate formed into a given shape through chemical polishing by 0.5 micrometer or more, and a heat treat pseudo-plating step forming a pseudo-plated layer on the surface through a heat treatment conducted by heating the base plate at a solution treatment temperature or above, for example, 850 degrees C. or above, preferably approximate 1040 degrees C., in a reducing atmosphere after the polishing step.Type: GrantFiled: June 1, 2012Date of Patent: November 8, 2016Assignee: NHK SPRING CO., LTD.Inventor: Tatsuji Tamura
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Patent number: 9404372Abstract: A Pt—Al—Hf/Zr aluminide coating that can be used as a bond coat for TBC and improve TBC spallation life in service at elevated temperatures is provided. The aluminide coating can include a metastable ternary or higher X—Pt/Pd—Ni phase where the phase and other elements in the alloy system are present in a NiAl ? phase of the coating. The metastable phase can be present and observable in the as-deposited condition of the bond coating; e.g. in an as-CVD deposited condition of the bond coating.Type: GrantFiled: October 31, 2012Date of Patent: August 2, 2016Assignee: Howmet CorporationInventor: Kenneth S. Murphy
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Patent number: 9284846Abstract: A Pt—Al—Hf/Zr aluminide coating that can be used as a bond coat for TBC and improve TBC spallation life in service at elevated temperatures is provided. The aluminide coating can include a metastable ternary or higher X—Pt/Pd—Ni phase where the phase and other elements in the alloy system are present in a NiAl ? phase of the coating. The metastable phase can be present and observable in the as-deposited condition of the bond coating; e.g. in an as-CVD deposited condition of the bond coating.Type: GrantFiled: May 18, 2010Date of Patent: March 15, 2016Assignee: Howmet CorporationInventor: Kenneth S. Murphy
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Publication number: 20150147590Abstract: A new Enhanced High Pressure Sintering (EHPS) method for making three-dimensional fully dense nanostructures and nano-heterostructures formed from nanoparticle powders, and three-dimensional fully dense nanostructures and nano-heterostructures formed using that method. A nanoparticle powder is placed into a reaction chamber and is treated at an elevated temperature under a gas flow to produce a cleaned powder. The cleaned powder is formed into a low density green compact which is then sintered at a temperature below conventional sintering temperatures to produce a fully dense bulk material having a retained nanostructure or nano-heterostructure corresponding to the nanostructure of the constituent nanoparticles. All steps are performed without exposing the nanoparticle powder to the ambient.Type: ApplicationFiled: November 14, 2014Publication date: May 28, 2015Applicant: The Government of the United States of America, as represented by the Secretary of the NavyInventors: Boris N. Feigelson, James A. Wollmershauser
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Patent number: 9040166Abstract: A hot-pressed member includes a steel sheet, a Ni-diffusion region present in a surface layer of the steel sheet, and an intermetallic compound layer and a ZnO layer which are provided in order on the Ni-diffusion region, the intermetallic compound layer corresponding to a ? phase present in a phase equilibrium diagram of a Zn—Ni alloy, wherein a spontaneous immersion potential indicated in a 0.5 M NaCl aqueous air-saturated solution at 25° C.±5° C. is ?600 to ?360 mV based on a standard hydrogen electrode.Type: GrantFiled: October 28, 2010Date of Patent: May 26, 2015Assignee: JFE STEEL CORPORATIONInventors: Hiroki Nakamaru, Seiji Nakajima, Tatsuya Miyoshi, Hiroyuki Masuoka, Shinji Ootsuka
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Patent number: 9012031Abstract: To provide a steel fuel conveying pipe which has high resistance to corrosive fuel and maintains reliability without damaging a direct-injection engine, and connects a high-pressure pump and a direct-injection rail with each other in a gasoline direct-injection engine system, and a fuel conveying pipe suitable as a bypass pipe for coupling direct-injection rails with each other in a V-type gasoline engine. A steel fuel conveying pipe for conveying gasoline is characterized in that a Ni-plated layer is provided on the whole inner circumferential face of the fuel conveying pipe, and an anti-rust film layer composed of a Zn-plated layer and a Zn-based alloy-plated layer is further provided on the Ni-plated layer at at least one end of the fuel conveying pipe.Type: GrantFiled: July 5, 2011Date of Patent: April 21, 2015Assignee: Usui Kokusai Sangyo Kaisha LimitedInventor: Kazuo Takagi
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Patent number: 9011785Abstract: A high-temperature-resistant component for an exhaust-gas treatment unit, an exhaust-gas treatment unit and a method for producing such a unit, include providing the component or the exhaust-gas treatment unit with a surface layer intended to prevent the formation of chromium carbide bridges during a brazing process for producing the exhaust-gas treatment unit.Type: GrantFiled: December 3, 2012Date of Patent: April 21, 2015Assignee: EMITEC Gesellschaft fuer Emissionstechnologies mbHInventor: Dieter Lutz
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Patent number: 9005767Abstract: A billet includes a solid steel body and an alloy cladding. The cladding may include a square tube in which the body is inserted with an interface at which the cladding becomes bonded to the body when the billet is heated and rolled or otherwise worked into a ferrous product. At least one element composed of a mass of finely divided scavenging aluminum, titanium or magnesium, is placed in the tube adjacent the body and separate from the interface. The elements are advantageously compressed into briquettes which scavenge oxygen from residual air at the interface to prevent oxidation of the cladding at the interface. The tube may be closed to prevent gases outside the billet from penetrating to the interface. Alternatively, reliance may be placed on the briquettes to scavenge oxygen from the residual air and also from atmospheric air and furnace gases before they can penetrate to the interface.Type: GrantFiled: October 19, 2010Date of Patent: April 14, 2015Assignee: Cladinox International LimitedInventor: Antonino Giorgio Cacace
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Patent number: 8993118Abstract: According to the present invention, a steel sheet for a container excellent in corrosion resistance, adhesion, and weldability is provided, which includes a steel sheet; a Ni plating layer which is formed on a surface of the steel sheet in an amount of plating deposition containing a Ni amount of 0.3 to 3 g/m2 and contains Co in the range of 0.1 to 100 ppm; and a chromate coating layer which is formed on a surface of the Ni plating layer in an amount of coating deposition containing a converted Cr amount of 1 to 40 mg/m2.Type: GrantFiled: March 24, 2011Date of Patent: March 31, 2015Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Shigeru Hirano, Makoto Kawabata
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Patent number: 8974865Abstract: A component and a method of processing a component are disclosed. The method includes providing a base metal having a feature, removing the feature to form a processed region, applying a first layer to the processed region, and applying a second layer to the first layer. The base metal, the first layer, and the second layer each have predetermined thermal expansion coefficients, yield strengths, and elongations. The processed component includes the first layer applied to a processed region of the base metal and a second layer applied to the first layer.Type: GrantFiled: February 23, 2011Date of Patent: March 10, 2015Assignee: General Electric CompanyInventors: Dechao Lin, Yan Cui, Srikanth Chandrudu Kottilingam, Ganjiang Feng
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Publication number: 20140377586Abstract: The present invention resides in an assembly comprising a first steel component that is joined to a second steel component by a weld joint formed in a hybrid welding process, whereby at least one of the first and second steel components comprises a through-hardened bearing steel. In the hybrid welding process, base material of the first and second steel components is melted and a moulten filler material comprising at least 90% Nickel is added. The weld joint is formed after solidification of the moulten base material and of the moulten filler material. According to the invention, the weld joint comprises a central solidified portion and a peripheral solidified portion, whereby the central solidified portion comprises at least 80% filler material and the peripheral solidified portion comprises no more than 20% filler material.Type: ApplicationFiled: January 25, 2013Publication date: December 25, 2014Applicant: Aktiebolaget SKFInventor: John Van De Sanden
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Patent number: 8911880Abstract: A turbine rotor which is composed by connecting Ni-based alloy and heat resisting steel such as 12-Cr steel by welding to be able to ensure strength of welded parts and can be used under steam conditions of 700° C. class and method of manufacturing the rotor are also provided. The rotor of the rotating machine into which working fluid of 650° C. or higher is introduced, the rotor being composed of a plurality of members connected by welding such that material of each member is different in accordance with temperature of working fluid which flows contacting the members, wherein the first member(s) is formed from Ni-based alloy having mean linear expansion coefficient of 12.4×10?6/° C.˜14.5×10?6/° C., preferably 14.0×10?6/° C. or smaller within a temperature range from a room temperature to 700° C. and second member(s) is formed from high-chrome steels, and the rotor is composed such that the first member(s) formed from Ni-base alloy is located in a portion which contact to the working fluid of 650° C.Type: GrantFiled: June 11, 2009Date of Patent: December 16, 2014Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Shin Nishimoto, Takashi Nakano, Yoshinori Tanaka, Tatsuaki Fujikawa, Kenji Kawasaki, Yoshikuni Kadoya, Ryuichi Yamamoto, Yuichi Hirakawa, Takashi Shige
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Publication number: 20140342187Abstract: The present disclosure is related to a component. The component may include a cast iron base and an intermediate layer covering a least a portion of the cast iron base. The intermediate layer may include aluminum and at least one of nickel, cobalt, chromium, silicon, or iron. The component may also include an outer layer covering the intermediate layer. The outer layer may include steel.Type: ApplicationFiled: May 14, 2013Publication date: November 20, 2014Applicant: Caterpillar Inc.Inventor: Robert Eugene Sharp
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Patent number: 8883318Abstract: An aluminum bonding alloy is an Ni—Mg alloy for bonding aluminum and a non-aluminum metal selected from steel, copper, nickel or titanium. The Ni—Mg alloy consists essentially of 0.08-0.90 mass % Mg, and the balance of Ni and inevitable impurities. A clad material includes a non-aluminum metal layer made of the non-aluminum metal and a bonding alloy layer made of the aluminum bonding alloy. The non-aluminum metal layer and the bonding alloy layer are bonded together by pressure welding and diffusion bonding.Type: GrantFiled: October 25, 2010Date of Patent: November 11, 2014Assignee: Neomax Materials Co., Ltd.Inventors: Shinji Yamamoto, Masaaki Ishio
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Patent number: 8846211Abstract: A strip product consists of a metallic substrate, such as stainless steel, and a coating, which in turn comprises at least one metallic layer and one reactive layer. The coated strip product is produced by providing the different layers, preferably by coating, and thereafter oxidizing the coating to accomplish a conductive surface layer comprising perovskite and/or spinel structure.Type: GrantFiled: November 21, 2005Date of Patent: September 30, 2014Assignee: Sandvik Intellectual Property ABInventors: Mikael Schuisky, Finn Petersen, Niels Christiansen, Joergen Gutzon Larsen, Soeren Linderoth, Lars Mikkelsen
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Publication number: 20140227553Abstract: Disclosed are a preparation method of a steel product capable of local reinforcement using laser heat treatment, and a heat hardened steel used in the method. According to the present invention, the preparation method of a steel part comprises the following steps: (a) preparing a material comprising 0.1-0.5 wt % of C, 0.1-0.5 wt % of Si, 0.5-3.0 wt % of Mn, 0.1 wt % or less of P, 0.05 wt % or less of S, 0.01-1.0 wt % of Cr, 0.1 wt % or less of Al, 0.2 wt % or less of Ti, 0.0005-0.08 wt % of B, and the balance of Fe and inevitable impurities; (b) preparing a formed product by forming the material into a predetermined shape; and (c) locally reinforcing the high strength portion by carrying out laser heat treatment on a portion requiring high strength at the formed product.Type: ApplicationFiled: October 17, 2011Publication date: August 14, 2014Applicant: HYUNDAI HYSCOInventors: Hee-Joong Im, Seung-Man Nam, Bo-Ryong Lee, Kyung-Bo Kim, Youn-Il Jung
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Patent number: 8795846Abstract: Provided is a Ni-plated steel sheet having excellent press formability. An Fe—Ni diffusion layer and a softened Ni layer formed on the Fe—Ni diffusion layer are formed on a surface of a steel sheet corresponding to an outer surface of a battery can, a semi-bright Ni plating layer is formed on the softened Ni layer, a Ni coating weight of the Fe—Ni diffusion layer and the softened Ni layer formed on the Fe—Ni diffusion layer is set smaller than a Ni coating weight of the semi-bright Ni plating layer, and average roughness Ra of the semi-bright Ni plating layer measured by a traceable roughness gauge is 1.0 ?m or more and 2.0 ?m or less, and a maximum height Ry of the semi-bright Ni plating layer measured by the traceable roughness gauge is 5 ?m or more and 20 ?m or less.Type: GrantFiled: August 24, 2010Date of Patent: August 5, 2014Assignee: Toyo Kohan Co., Ltd.Inventors: Hideyuki Minagi, Eiji Okamatsu
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Patent number: 8790789Abstract: Disclosed herein is an erosion and corrosion resistant coating comprising a metallic binder, a plurality of hard particles, and a plurality of sacrificial particles. Also disclosed is a method of improving erosion and corrosion resistance of a metal component comprising disposing on a surface of the metal component the foregoing erosion and corrosion resistant coating comprising, and a metal component comprising a metal component surface and the foregoing erosion and corrosion resistant coating comprising a first surface and a second surface opposite the first surface, wherein the first surface is disposed on the metal component surface.Type: GrantFiled: May 29, 2008Date of Patent: July 29, 2014Assignee: General Electric CompanyInventors: Thodla Ramgopal, Krishnamurthy Anand, David Vincent Bucci, Nitin Jayaprakash, Jane Marie Lipkin, Tamara Jean Muth, Surinder Singh Pabla, Vinod Kumar Pareek, Guru Prasad Sundararajan
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Patent number: 8753754Abstract: The present invention provides a steel sheet for a can exhibiting excellent corrosion resistance, adhesive properties, and weldability, including a steel sheet, an Ni—Cu alloy plating layer formed on at least one surface of the steel sheet; and a chromate film layer formed on a surface of the Ni—Cu alloy plating layer, in which the Ni—Cu alloy plating layer has Ni attached thereto in an amount of from 0.30 g/m2 to 3.0 g/m2, and Cu contained therein in an amount of from 0.5 mass % to 20 mass %; and the chromate film layer has Cr attached thereto in an amount of from 1.0 mg/m2 to 40 mg/m2 in equivalent units of Cr.Type: GrantFiled: August 15, 2011Date of Patent: June 17, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Shigeru Hirano, Makoto Kawabata
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Publication number: 20140162087Abstract: The invention relates to a method for enhancing a metallic coating on a steel strip or steel plate, the coating being melted by heating to a temperature above the melting temperature of the material of the coating, the heating taking place by irradiation of the surface of the coating with electromagnetic radiation having a high power density over a limited irradiation time of not more than 10 ?s, and the mandated irradiation time and the energy density introduced into the coating by the electromagnetic radiation being selected such that the coating melts completely over its entire thickness down to the boundary layer with the steel strip, thereby forming a thin alloy layer at the boundary layer between the coating and the steel strip.Type: ApplicationFiled: January 2, 2012Publication date: June 12, 2014Applicant: THYSSENKRUPP RASSELSTEIN GMBHInventors: Winfried Hoehn, Helmut Oberhoffer, Benjamin Johannes Liebscher, Reiner Sauer
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Patent number: 8748008Abstract: A fired heater tube that is resistant to corrosion and fouling is disclosed. The fired heater tube comprises an advantageous high performance coated material composition resistant to corrosion and fouling comprises: (PQR), wherein P is an oxide layer at the surface of (PQR), Q is a coating metal layer interposed between P and R, and R is a base metal layer, wherein P is substantially comprised of alumina, chromia, silica, mullite, spinels, and mixtures thereof, Q comprises Cr, and at least one element selected from the group consisting of Ni, Al, Si, Mn, Fe, Co, B, C, N, P, Ga, Ge, As, In, Sn, Sb, Pb, Sc, La, Y, Ce, Ti, Zr, Hf, V, Nb, Ta, Mo, W, Re, Ru, Rh, Ir, Pd, Pt, Cu, Ag, Au and mixtures thereof, and R is selected from the group consisting of low chromium steels, ferritic stainless steels, austenetic stainless steels, duplex stainless steels, Inconel alloys, Incoloy alloys, Fe—Ni based alloys, Ni-based alloys and Co-based alloys.Type: GrantFiled: June 8, 2009Date of Patent: June 10, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: ChangMin Chun, Mark A Greaney, Ian A Cody, F. Pierce Hubbard, Jr., David Samuel Deutsch
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Patent number: 8734961Abstract: A Ni-plated steel sheet is provided in which the occurrence of scratches at the time of forming a battery can is suppressed. Also provided is a method which includes a step where a surface of a steel sheet is plated with Ni in a Ni adhesion amount of 0.3-2 ?m, a step where the Ni-plated steel sheet is heated to 600-800° C. to form an Fe?Ni diffusion layer as an outermost surface layer, and a step where the steel sheet is rolled by temper rolling so as to adjust the Fe?Ni diffusion layer so that the steel sheet has the surface roughness Ra of 0.9-2.0 ?m and the surface roughness Ry of 4.0-15 ?m. A Ni-plated steel sheet which includes an Fe?Ni diffusion layer as an outermost surface layer and in which the diffusion layer has the surface roughness Ra of 0.9-2.0 ?m and the surface roughness Ry of 4.0-15 ?m and the diffusion layer has such an Fe/Ni ratio that the Fe accounts for 20-50% in Auger analysis is subjected to drawing using a water-soluble liquid which contains water-soluble emersion as a press lubricant.Type: GrantFiled: May 31, 2010Date of Patent: May 27, 2014Assignee: Toyo Kohan Co., Ltd.Inventors: Shinichi Takematsu, Eiji Okamatsu, Hideyuki Minagi
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Publication number: 20140120372Abstract: A method is for plating metal or alloy blanks. The method includes heating the metal or alloy blanks at a recrystallization temperature sufficient to soften the steel for minting; plating the softened metal or alloy blanks with one or more layers of metal or alloy; and heating the plated blanks at a temperature sufficient to reduce plating stresses but below the recrystallization temperature of the outermost plating layer.Type: ApplicationFiled: June 12, 2012Publication date: May 1, 2014Applicant: MONNAIE ROYALE CANADIENNE/ROYAL CANADIAN MINTInventors: Hieu Cong Truong, Toan Dinh Nguyen, Dennis Herman Weber
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Patent number: 8697250Abstract: A composition based on a novel MCrAlY formulation is provided for the production of protective coatings. The specific combination of the constituents of the MCrAlY formulation advantageously allows significantly high loadings of ceramic (metal oxide) while still retaining the ability to selectively oxidize aluminum to form alumina scale, a property previously not attainable with conventional MCrAlY materials when loaded with ceramics at levels of 15-45 weight percent. The alumina scale in combination with the modified MCrAlY formulation act as a barrier to specific detrimental oxide formations. The compositions of the present invention can act as protective coatings for a wide array of applications.Type: GrantFiled: February 14, 2013Date of Patent: April 15, 2014Assignee: Praxair S.T. Technology, Inc.Inventor: William Jarosinski
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Patent number: 8663816Abstract: A hot-pressed member includes a steel sheet, a Ni-diffusion region present in a surface layer of the steel sheet, and an intermetallic compound layer and a ZnO layer which are provided in order on the Ni-diffusion region, the intermetallic compound layer corresponding to a ? phase present in a phase equilibrium diagram of a Zn—Ni alloy, wherein a spontaneous immersion potential indicated in a 0.5 M NaCl aqueous air-saturated solution at 25° C.±5° C. is ?600 to ?360 mV based on a standard hydrogen electrode.Type: GrantFiled: October 28, 2010Date of Patent: March 4, 2014Assignee: JFE Steel CorporationInventors: Hiroki Nakamaru, Seiji Nakajima, Tatsuya Miyoshi, Hiroyuki Masuoka, Shinji Ootsuka
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Patent number: 8663819Abstract: Free standing articles or articles at least partially coated with substantially porosity free, fine-grained and/or amorphous Co-bearing metallic materials optionally containing solid particulates dispersed therein, are disclosed. The electrodeposited metallic layers and/or patches comprising Co provide, enhance or restore strength, wear and/or lubricity of substrates without reducing the fatigue performance compared to either uncoated or equivalent thickness chromium coated substrate. The fine-grained and/or amorphous metallic coatings comprising Co are particularly suited for articles exposed to thermal cycling, fatigue and other stresses and/or in applications requiring anti-microbial properties.Type: GrantFiled: November 9, 2012Date of Patent: March 4, 2014Assignee: Integran Technologies, Inc.Inventors: Francisco Gonzalez, Diana Facchini, Jonathan McCrea, Mike Uetz, Gino Palumbo, Klaus Tomantschger
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Publication number: 20140037986Abstract: A brazing filler metal powder is provided for brazing thin stainless steel parts together with reduced erosion. The brazing filler metal powder is formed by processing first metal particles, which typically comprise a nickel-based alloy including chromium, phosphorous, silicon, to a particle size of not greater than 0.0098 inch; providing second metal particles, typically consisting of copper, molybdenum, or cobalt; combining the first metal particles with the second metal particles by mixing and/or, milling, or sintering; and processing the combined composition to a particle size of not greater than 0.0098 inch. The first and second metal particles are less than fully alloyed together and are distinct from one another. A preferred composition of the brazing filler metal powder is 26.1 wt. % chromium, 5.4 wt. % phosphorous, 5.9 wt. % silicon, 10.0 wt. % cobalt, and a balance essentially of nickel.Type: ApplicationFiled: August 1, 2013Publication date: February 6, 2014Inventors: Michael Weinstein, Eric Krosche, Lydia W. Lee, Christopher Jacob Skinner
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Patent number: 8637164Abstract: A silver-coated composite material for movable contact parts, which has: an underlying layer composed of any one of nickel, cobalt, a nickel alloy, and a cobalt alloy at least provided on a part of the surface of a stainless steel substrate; an intermediate layer composed of copper or a copper alloy provided thereon; and a silver or silver alloy layer provided thereon as an outermost layer, wherein a thickness of the intermediate layer is 0.05 to 0.3 ?m, and wherein an average grain size of the silver or silver alloy provided as the outermost layer is 0.5 to 5.0 ?m.Type: GrantFiled: August 10, 2012Date of Patent: January 28, 2014Assignee: Furukawa Electric Co., Ltd.Inventors: Yoshiaki Kobayashi, Satoru Zama, Satoshi Suzuki, Masato Ohno
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Patent number: 8637166Abstract: Provided are strain hardened high strength nickel based alloy welds that yield improved properties and performance in joining high strength metals. The advantageous weldments include two or more segments of ferrous or non-ferrous components, and fusion welds, friction stir welds, electron beam welds, laser beam welds, or a combination thereof bonding adjacent segments of the components together, wherein the welds comprise a strain hardened nickel based alloy weld metal composition including greater than or equal to 10 wt % Mo based on the total weight of the nickel based alloy weld metal composition. Also provided are methods for forming the welds from the nickel based alloy weld compositions. The strain hardened high strength nickel based alloy welds are useful in the oil, gas and petrochemical industry in applications for natural gas transportation and storage, oil and gas well completion and production, and oil and gas refinery and chemical plants.Type: GrantFiled: December 16, 2008Date of Patent: January 28, 2014Assignee: Exxonmobil Research and Engineering CompanyInventors: Raghavan Ayer, Neeraj Srinivas Thirumalai, Hyun-Woo Jin, Daniel B. Lillig, Douglas Paul Fairchild, Steven Jeffrey Ford
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Publication number: 20130316191Abstract: A welding structure (30A) includes a welding layer (60A) which is configured of a first built-up layer (33) which is formed of low-alloy steel or carbon steel having a carbon content of less than low-alloy steel and which is formed on a base metal (31), a second built-up layer (34) which is formed of a 600-type nickel-based alloy and which is formed on the first built-up layer (33) and a third built-up layer (35) which is formed of a 690-type nickel-based alloy and which is formed on the second built-up layer (34).Type: ApplicationFiled: January 27, 2012Publication date: November 28, 2013Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Kenji Kawasaki, Masahiko Toyoda, Hiroshi Kanasaki, Tomoyuki Inoue, Takafumi Hiro, Seiichi Kawaguchi, Kosuke Kitamura, Tomohisa Ota, Nobutaka Nakajima
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Patent number: 8568901Abstract: An alloy for use as a welding overlay for boiler tubes in a low NOx coal-fired boiler comprising in % by weight: 36 to 43% Cr, 0.2 to 5.0% Fe, 0-2.0% Nb, 0-1% Mo, 0.3 to 1% Ti, 0.5 to 2% Al, 0.005 to 0.05% C, 0.005 to 0.020% (Mg+Ca), 0-1% Mn, 0-0.5% Si, less than 0.01% S, balance substantially Ni and trace additions and impurities. The alloy provides exceptional coal ash corrosion resistance in low partial pressures of oxygen. The alloy also increases in hardness and in thermal conductivity at service temperature over time. The increased hardness improves erosion resistance of the tubes while the increased thermal conductivity improves the thermal efficiency of the boiler and its power generation capabilities.Type: GrantFiled: November 19, 2007Date of Patent: October 29, 2013Assignee: Huntington Alloys CorporationInventors: Samuel D. Kiser, Brian A. Baker
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Patent number: 8545994Abstract: An article includes an electrodeposited metallic material including Co with a minimum content of 75% by weight. The metallic material has a microstructure which is fine-grained with an average grain size between 2 and 5,000 nm and/or an amorphous microstructure. The metallic material forms at least part of an exposed surface of the article. The metallic material has an inherent contact angle for water of less than 90 degrees at room temperature when measured on a smooth exposed surface portion of the metallic material which has a maximum surface roughness Ra of 0.25 microns. The metallic material has an exposed patterned surface portion having surface structures having a height of between at least 5 microns to about 100 microns incorporated therein to increase the contact angle for water at room temperature of the exposed patterned surface portion to over 100 degrees.Type: GrantFiled: May 24, 2010Date of Patent: October 1, 2013Assignee: Integran Technologies Inc.Inventors: Diana Facchini, Francisco Gonzalez, Jonathan McCrea, Mike Uetz, Gino Palumbo, Klaus Tomantschger, Nandakumar Nagarajan, Jared J. Victor, Uwe Erb
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Patent number: 8512874Abstract: A coating and process for depositing the coating on a substrate. The coating is a nickel aluminide overlay coating of predominantly the beta (NiAl) and gamma-prime (Ni3Al) intermetallic phases, and is suitable for use as an environmental coating and as a bond coat for a thermal barrier coating (TBC). The coating can be formed by depositing nickel and aluminum in appropriate amounts to yield the desired beta+gamma prime phase content. Alternatively, nickel and aluminum can be deposited so that the aluminum content of the coating exceeds the appropriate amount to yield the desired beta+gamma prime phase content, after which the coating is heat treated to diffuse the excess aluminum from the coating into the substrate to yield the desired beta+gamma prime phase content.Type: GrantFiled: June 4, 2007Date of Patent: August 20, 2013Assignee: General Electric CompanyInventors: Ramgopal Darolia, Joseph David Rigney, Gillion Herman Marijnissen, Eric Richard Irma Carolus Vergeldt, Annejan Bernard Kloosterman
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Publication number: 20130189541Abstract: A composite material includes a clad material including a base material that includes an iron-chromium alloy and vibration-damping layers that are provided on both surfaces of the base material and include a metal to suppress a vibration.Type: ApplicationFiled: January 16, 2013Publication date: July 25, 2013Applicant: HITACHI CABLE, LTD.Inventor: HITACHI CABLE, LTD.
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Patent number: 8445117Abstract: The present invention discloses corrosion and wear-resistant claddings comprising hard particles and an alloying addition dispersed in a nickel-based alloy matrix. The alloying addition comprises at least one of molybdenum or copper. The cladding does not include cobalt-bonded tungsten carbide particles.Type: GrantFiled: September 28, 2010Date of Patent: May 21, 2013Assignee: Kennametal Inc.Inventor: Hongbo Ding
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Patent number: 8426033Abstract: Provided are precipitation hardened high strength nickel based alloy welds that yield improved properties and performance in joining high strength metals. The advantageous weldments include two or more segments of ferrous or non-ferrous components, and fusion welds, friction stir welds, electron beam welds, laser beam welds, or a combination thereof bonding adjacent segments of the components together, wherein the welds comprise a precipitation hardened nickel based alloy weld metal composition including greater than or equal to 1.4 wt % of combined aluminum and titanium based on the total weight of the nickel based alloy weld metal composition. Also provided are methods for forming the welds from the nickel based alloy weld compositions, wherein the precipitation hardening occurs in the as-welded condition. The nickel based welds do not require a separate heat treatment step after welding to produce advantageous strength properties.Type: GrantFiled: December 16, 2008Date of Patent: April 23, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Raghavan Ayer, Neeraj Srinivas Thirumalai, Hyun-Woo Jin, Daniel B. Lillig, Douglas Paul Fairchild, Steven Jeffrey Ford
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Publication number: 20130095003Abstract: A high-temperature-resistant component for an exhaust-gas treatment unit, an exhaust-gas treatment unit and a method for producing such a unit, include providing the component or the exhaust-gas treatment unit with a surface layer intended to prevent the formation of chromium carbide bridges during a brazing process for producing the exhaust-gas treatment unit.Type: ApplicationFiled: December 3, 2012Publication date: April 18, 2013Applicant: EMITEC GESELLSCHAFT FUER EMISSIONSTECHNOLOGIE MBHInventor: Amitec Gesellschaft Fuer Emissionstechnologie
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Publication number: 20130089751Abstract: The present invention provides a steel sheet for a container including a cold-rolled steel sheet and a composite film formed on the cold-rolled steel sheet through an electrolysis process in a solution containing: at least one metal ion of an Sn ion, an Fe ion, and an Ni ion; Zr ion; a nitric acid ion: and an ammonium ion, in which the composite film contains at least one element of: Zr of 0.1 to 100 mg/m2 in equivalent units of metal Zr; Sn of 0.3 to 20 g/m2 in equivalent units of metal Sn; Fe of 5 to 2000 mg/m2 in equivalent units of metal Fe; and Ni of 5 to 2000 mg/m2 in equivalent units of metal Ni.Type: ApplicationFiled: June 28, 2011Publication date: April 11, 2013Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Shigeru Hirano, Akira Tachiki, Hirokazu Yokoya, Morio Yanagihara, Makoto Kawabata
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Patent number: 8387228Abstract: A method for producing a single-clad or multiple-clad product includes providing a welded assembly comprising a cladding material disposed on a substrate material. Both the substrate material and the cladding material are individually selected alloys. At least a first edge of the cladding material of the welded assembly does not extend to a first edge of the substrate material and thereby provides a margin between the first edges. A material that is an alloy having hot strength greater than the cladding material is within the margin and adjacent the first edge of the cladding material. The welded assembly is hot rolled to provide a hot rolled band, and the material within the margin inhibits the cladding material from spreading beyond the edge of the substrate material during the hot rolling. In certain embodiments of the methods, the substrate material is stainless steel and the cladding material is nickel or a nickel alloy.Type: GrantFiled: June 10, 2004Date of Patent: March 5, 2013Assignee: ATI Properties, Inc.Inventors: David S. Bergstrom, Kris J. Schott, Mark A. Tarhay
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Patent number: 8389126Abstract: A structural component suitable for use as refinery and/or petrochemical process equipment and piping is provided. The structural component has improved corrosion, abrasion, environmental degradation resistance, and fire resistant properties with a substrate coated with a surface-treated amorphous metal layer. The surface of the structural component is surface treated with an energy source to cause a diffusion of at least a portion of the amorphous metal layer and at least a portion of the substrate, forming a diffusion layer disposed on a substrate. The diffusion layer has a negative hardness profile with the hardness increasing from the diffusion surface in contact with the substrate to the surface away from the substrate.Type: GrantFiled: April 28, 2010Date of Patent: March 5, 2013Assignee: Chevron U.S.A. Inc.Inventors: Grzegorz Jan Kusinski, Jan H. Kusinski
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Publication number: 20130052481Abstract: A body comprising a steel substrate and a hard face structure fused to the steel substrate, the hard face structure comprising a core region and an intermediate region, the intermediate region at least partially enclosing the core region and comprising at least about 0.Type: ApplicationFiled: April 7, 2011Publication date: February 28, 2013Applicant: ELEMENT SIX GMBHInventors: Igor Yuri Konyashin, Bernd Heinrich Ries, Frank Friedrich Lachmann
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Publication number: 20130052482Abstract: Free standing articles or articles at least partially coated with substantially porosity free, fine-grained and/or amorphous Co-bearing metallic materials optionally containing solid particulates dispersed therein, are disclosed. The electrodeposited metallic layers and/or patches comprising Co provide, enhance or restore strength, wear and/or lubricity of substrates without reducing the fatigue performance. The fine-grained and/or amorphous metallic coatings comprising Co are particularly suited for articles exposed to thermal cycling, fatigue and other stresses and/or in applications requiring anti-microbial properties.Type: ApplicationFiled: October 31, 2012Publication date: February 28, 2013Applicant: INTEGRAN TECHNOLOGIES, INC.Inventor: INTEGRAN TECHNOLOGIES, INC.
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Publication number: 20130034745Abstract: The present invention provides a steel sheet for a container including: a plated layer containing an adhesion amount of 300 to 1000 mg/m2 of nickel, provided on at least one surface of a steel sheet as metal Ni; and a chemical conversion treatment film formed on the steel sheet by performing immersion or a cathodic electrolytic treatment with a solution containing Zr ions, F ions, and phosphate ions, wherein a metal Zr adhesion amount of the chemical conversion treatment film is 1.0 to 50 mg/m2, an amount of 0.5 to 25 mg/m2 of a phosphate compound is contained in terms of P amount, and an F-atom number density measured by XPS analysis of a plane of 2 nm and a plane of 4 nm in a depth direction obtained by a sputtering treatment is equal to or less than 2 at %.Type: ApplicationFiled: March 22, 2011Publication date: February 7, 2013Applicant: NIPPON STEEL CORPORATIONInventors: Akira Tachiki, Shigeru Hirano, Hirokazu Yokoya, Masakazu Noda, Hiroshi Nishida, Kazushige Hasegawa