Co- Or Ni-base Component Next To Fe-base Component Patents (Class 428/679)
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Patent number: 7163754Abstract: A sprocket has a base steel member including an outer toothed profile surface, at least a portion of the outer toothed profile surface having a wear and corrosion resistant coating disposed thereon; the coating comprising an alloy, the alloy comprising at least 60 weight % iron, cobalt, nickel, or alloys thereof. A method of producing a wear and corrosion resistant sprocket includes: (i) machining a base steel member to form an outer toothed profile surface thereon; (ii) applying a coating to at least a portion of the surface; and (iii) fusing the coating to the base steel member.Type: GrantFiled: October 23, 2003Date of Patent: January 16, 2007Assignee: Deere & CompanyInventors: Gopal S. Revankar, Timothy D. Wodrich, Todd B. Niemann
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Patent number: 7152526Abstract: Disclosed is a surface treated doctor blade in which the surface of at least the blade edge portion thereof consists of a surface treatment coating film composed of a first layer consisting of a specific nickel-based plating and a second layer provided thereon which has low surface energy, and in which preferably at least a part of the blade edge end portion of the blade base material is exposed. In the surface treated doctor blade of the present invention, it is possible to improve wear resistance of the blade edge end and to suppress generation of printing failures during continuous printing. Further, in the mode in which at least a part of the blade base material is exposed, it is possible to reduce running-in time for adjustment of contact of the blade edge with the cylinder after replacement of the doctor blade.Type: GrantFiled: January 28, 2002Date of Patent: December 26, 2006Assignee: Nihon New Chrome Co., Ltd.Inventors: Kazuya Urata, Naoyuki Oniwa, Kunio Tachibana
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Patent number: 7150922Abstract: A beta-phase nickel aluminide (NiAl) overlay coating (24) and method for modifying the grain structure of the coating (24) to improve its oxidation resistance. The coating (24) is deposited by a method that produces a grain structure characterized by grain boundaries (44) exposed at the outer coating surface (36). The grain boundaries (44) may also contain precipitates (40) as a result of the alloyed chemistry of the coating (24). During or after deposition, the overlay coating (24) is caused to form new grain boundaries (34) that, though open to the outer surface (36) of the coating (24), are free of precipitates or contain fewer precipitates (40) than the as-deposited grain boundaries (44). New grain boundaries (34) are preferably produced by causing the overlay coating (24) to recrystallize during coating deposition or after deposition as a result of a surface treatment followed by heat treatment.Type: GrantFiled: December 13, 2002Date of Patent: December 19, 2006Assignee: General Electric CompanyInventors: Irene Spitsberg, Joseph David Rigney, Ramgopal Darolia, Elissa Hae-Kyung Lee, Jeffrey Allan Pfaendtner
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Patent number: 7150939Abstract: A battery container having an inner surface provided with a nickel-phosphorous alloy layer, optionally provided with a nickel-cobalt alloy layer as the lower layer thereof. The outer surface of the battery container is preferably provided with a nickel-cobalt alloy layer. Batteries made using the battery containers of the present invention have excellent performance.Type: GrantFiled: December 5, 2002Date of Patent: December 19, 2006Assignee: Toyo Kohan Co., Ltd.Inventors: Hitoshi Ohmura, Tatsuo Tomomori, Hideo Ohmura, Keiji Yamane
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Patent number: 7147926Abstract: A multi-layer corrosion protection system and a method for applying the multi-layer corrosion protection system. The system comprises a corrosion-resistant layer plated onto a metallic substrate. The corrosion-resistant layer may be deposited using an autocatalytic (electroless) process. The corrosion-resistant layer may comprise phosphorous. The system comprises a stain-resistant layer deposited over the corrosion-resistant layer. The stain-resistant layer may be deposited using an autocatalytic (electroless) process. The stain-resistant layer may comprise nickel. The system may also comprise an inner layer plated onto the metallic substrate to prepare the metallic substrate for the application of the corrosion-resistant layer. The inner layer may comprise nickel and may be deposited using an autocatalytic (electroless) process.Type: GrantFiled: September 25, 2003Date of Patent: December 12, 2006Assignee: Reliance Electric Technologies, LLCInventors: James E. Mickelson, Alan M. Turza
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Patent number: 7094475Abstract: A gas turbine component consists of a superalloy base material with a single crystal structure and a protective MCrAlY-coating (6). The MCrAlY-coating (6) has a g/g? single crystal structure, which is epitaxial with the base material. It has be determined the critical factors for the successful epitaxial and crack-free growth of the MCrAlY-coating (6).Type: GrantFiled: September 6, 2002Date of Patent: August 22, 2006Assignee: Alstom Technology LTDInventors: Alexander Schnell, Cyrille Bezencon, Matthias Hoebel, Abdus Suttar Khan, Maxim Konter, Wilfried Kurz
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Patent number: 7087316Abstract: A low-expansion unit includes a plate member and an iron-nickel layer. Upper and lower surface layers of the plate member each have the iron-nickel layer thereon and/or therein. While the plate member has a relatively large thermal expansion coefficient, the iron-nickel layers, which are formed on and/or in the upper and lower surface layers of the plate member, have a relatively small thermal expansion coefficient. Therefore, thermal expansion coefficient of the low-expansion unit is as a whole restrained to a relatively small value. Also, the plate member includes pure iron whose thermal conductivity is relatively high. Meanwhile, the iron-nickel layers, which are formed on the plate member, are relatively thin. Therefore, the low-expansion unit has a relatively large thermal conductivity in a direction of thickness thereof.Type: GrantFiled: September 3, 2003Date of Patent: August 8, 2006Assignee: Kabushiki Kaisha Toyota JidoshokkiInventors: Takashi Yoshida, Kyoichi Kinoshita, Katsufumi Tanaka, Tomohei Sugiyama, Hidehiro Kudo, Eiji Kono
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Patent number: 7067201Abstract: A method of reducing stress and wear on one or more components in a keel joint assembly in which a cobalt-based, wear resistant alloy coating is applied to the surfaces of one or more components. The use of the coating reduces stress and wear and achieves improved corrosion, galling, erosion and abrasion resistance as compared to other currently known and applied methods. In the present invention, the coating would preferably would be applied to the surfaces of the mating components of the keel joint.Type: GrantFiled: September 29, 2004Date of Patent: June 27, 2006Assignee: Vetco Gray Inc.Inventors: Fife B. Ellis, Kim H. Phan, Eric J. Schultz
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Patent number: 7060366Abstract: A coated article has a metallic substrate with a substrate composition, and a metallic coating overlying and contacting the metallic substrate. The metallic coating has a metallic-coating composition different from the substrate composition. A protective coating overlies and contacts the metallic coating. The protective coating includes a chromium aluminide layer overlying and contacting the metallic coating, and optionally a thermal barrier coating overlying and contacting the chromium aluminide layer. This structure may be used to restore a key dimension of an article that has previously been in service and to protect the article as well.Type: GrantFiled: February 19, 2003Date of Patent: June 13, 2006Assignee: General Electric CompanyInventors: Bhupendra Kumar Gupta, Wayne Ray Grady, Lyle Timothy Rasch, Thomas Joseph Kelly, Nripendra Nath Das
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Patent number: 7052782Abstract: A high-temperature protection layer contains (% by weight) 23 to 27% Cr, 4 to 7% Al, 0.1 to 3% Si, 0.1 to 3% Ta, 0.2 to 2% Y, 0.001 to 0.01% B, 0.001 to 0.01% Mg and 0.001 to 0.01% Ca, remainder Ni and inevitable impurities. Optionally, the Al content is in a range from over 5 up to 6% by weight.Type: GrantFiled: July 19, 2004Date of Patent: May 30, 2006Assignee: ALSTOM Technology Ltd.Inventors: Hans-Peter Bossmann, Dietrich Eckardt, Klaus Erich Schneider, Christoph Toennes
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Patent number: 7041383Abstract: This invention provides a thermal barrier ceramic coating for application to a metallic article, with the ceramic coating having a formula of NdxZr1-xOy with Z dissolved in, where 0<x<0.5 and 1.75<y<2 and wherein Z is an oxide of a metal selected from the group consisting of Y, Mg, Ca, Hf and mixtures thereof. In one embodiment Nd is added at a level up to 7 mole %. In another embodiment Z is yttrium and is added at a level of at least 6 wt %.Type: GrantFiled: May 3, 2004Date of Patent: May 9, 2006Assignee: Chromalloy Gas Turbine CorporationInventors: Yourong Liu, Paul Lawton
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Patent number: 7014923Abstract: A gas turbine component consists of a superalloy base material with a single crystal structure and a protective MCrAlY-coating. The MCrAlY-coating the MCrAlY has a ?/?-phase and single crystal structure, which is epitaxial with the base material.Type: GrantFiled: September 6, 2002Date of Patent: March 21, 2006Assignee: Alstom Technology LTDInventors: Alexander Schnell, Cyrille Bezencon, Matthias Hoebel, Abdus Suttar Khan, Maxim Konter, Wilfried Kurz
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Patent number: 7001674Abstract: An exposure method for preventing accumulation of process error for substrates processed by an apparatus designed for multiprocessing and producing high quality semiconductor chips. A semiconductor integrated circuit production line polishes wafers of individual lots at a first processing system and second processing system of a CMP system two at a time. Wafer processing information indicating at which processing system of the first processing system and second processing system each wafer has been processed is transmitted through a communication line to a later processing apparatus including an exposure apparatus. The wafers of a lot loaded in the exposure apparatus are allocated to a plurality of processing systems of the exposure apparatus so that wafers processed by the same processing system are processed by the same processing system among the two processing systems of the exposure apparatus and are exposed at those processing systems.Type: GrantFiled: May 7, 2003Date of Patent: February 21, 2006Assignee: Nikon CorporationInventor: Nobuyuki Irie
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Patent number: 6986951Abstract: The present invention relates to a cobalt-based alloy for the coating of organs subject to erosion by liquid comprising chromium 28–32% by weight, tungsten 6–8% by weight, silicon 0.1–2% by weight, carbon 1.2–1.7% by weight, nickel 3–6% by weight, molybdenum 1–3%, cobalt the complement to 100%. The invention also relates to an application method of the alloy on organs subject to erosion by liquid, in particular vapour turbine blades, to reduce the metal erosion rate following impact with liquids.Type: GrantFiled: September 25, 2003Date of Patent: January 17, 2006Assignee: Nuovo Pignone Holdings S.p.A.Inventor: Massimo Giannozzi
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Patent number: 6984458Abstract: The present invention relates to a method for treating organs subject to erosion by liquids, in particular vapour turbine components, which contemplates laser plating with a cobalt-based alloy comprising chromium from 28 to 32% by weight; tungsten from 5 to 7% by weight; silicon from 0.1 to 2% by weight; carbon from 1.2 to 1.7% by weight; nickel from 0.5 to 3% by weight; iron from 0.01 to 1% by weight; manganese from 0.01 to 1% by weight; molybdenum from 0.2 to 1% by weight; possible impurities or other elements from 0 to 0.5% by weight and cobalt the complement to 100%.Type: GrantFiled: October 31, 2003Date of Patent: January 10, 2006Assignee: Nuovo Pignone Holding S.p.A.Inventor: Massimo Giannozzi
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Patent number: 6979498Abstract: A strengthened bond coat for improving the adherence of a thermal barrier coating to an underlying metal substrate to resist spallation without degrading oxidation resistance of the bond coat. The bond coat comprises a bond coating material selected from the group consisting of overlay alloy coating materials, aluminide diffusion coating materials and combinations thereof. Particles comprising a substantially insoluble bond coat strengthening compound and having a relatively fine particle size of about 2 microns or less are dispersed within at least the upper portion of the bond coat in an amount sufficient to impart strengthening to the bond coat, and thus limit ratcheting or rumpling thereof.Type: GrantFiled: November 25, 2003Date of Patent: December 27, 2005Assignee: General Electric CompanyInventors: Ramgopal Darolia, Joseph David Rigney, Gillion Herman Marijnissen, Eric Richard Irma Carolus Vergeldt, Annejan Bernard Kloosterman
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Patent number: 6964818Abstract: A coated article includes formed of an alloy having a composition including nickel and aluminum, and a protective coating overlying and contacting the substrate. The protective coating is a mixture of a quasicrystalline metallic phase, and a non-quasicrystalline metallic phase comprising nickel and aluminum. The aluminum is present in an amount of from about 3 to about 35 percent by weight of the non-quasicrystalline metallic phase.Type: GrantFiled: April 16, 2003Date of Patent: November 15, 2005Assignee: General Electric CompanyInventor: Ramgopal Darolia
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Patent number: 6924045Abstract: It is disclosed a bond or overlay MCrAlY-coating for the use within a high temperature environment for the protection of the base alloy of turbine blades and vanes. The MCrAlY-coating having a ? or ?/??-structure comprises a dispersion of ?-NiAl and/or ?/?-MCrAlY particles. This provides a reservoir of aluminum reservoir to coatings wherein the reservoir replenish the aluminum lost due to oxidation and interdiffusion during service. The ?-NiAl and/or ?/?-MCrAlY is the aluminum reservoir and is applied by mixing appropriate powders with ? or ?/?? powders.Type: GrantFiled: May 3, 2002Date of Patent: August 2, 2005Assignee: ALSTOM Technology LTDInventors: Abdus S. Khan, Maxime Konter, Robert Schmees
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Patent number: 6921582Abstract: An article is described, which includes a metal-based substrate and an oxidation-resistant coating bonded to the substrate by a bonding agent, such as a braze material The oxidation-resistant coating material is often an aluminide- or MCrAlX-type coating, and can be one which contains relatively high amounts of aluminum. The coating is often very smooth, for maximum aerodynamic efficiency. The oxidation-resistant coating can be applied and bonded to the substrate by a variety of methods, using slurries, braze tapes, or metal foils. Coating repair methods are also described.Type: GrantFiled: December 23, 2002Date of Patent: July 26, 2005Assignee: General Electric CompanyInventor: Wayne Charles Hasz
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Patent number: 6908693Abstract: A Sn-based metal-coated steel strip excellent in appearance comprises a Ni-based metal (such as Ni, a Ni—Sn alloy, a Ni—Zn alloy, a Ni—Fe alloy and a Ni—Co alloy) preplating layer and a Sn-based metal (such as a Sn—Zn alloy) coating formed thereon, and is characterized in that a Ni emission intensity line and an Fe emission intensity line obtained by glow discharge spectroscopy of the surface of the coated steel strip satisfy a relationship of the formula: T1?T2 wherein T1 is a sputtering time at the peak of a Ni emission intensity line, and T2 is a sputtering time at the inflection point of an Fe emission intensity line, or a relationship of the formulas: T1?T2, and 1?T1/T2?1.Type: GrantFiled: July 9, 2003Date of Patent: June 21, 2005Assignee: Nippon Steel CorporationInventors: Seiji Sugiyama, Teruaki Izaki, Masao Kurosaki, Yasuto Goto, Yusho Oyama, Tomohide Kamiyama
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Patent number: 6905783Abstract: Steel sheet for porcelain enameling having excellent workability yet capable of providing an enamel layer having excellent adhesion with the steel sheet on direct-on enameling once and still free of black specks defects, a method for producing the same, as well as a porcelain enamel product and the method for producing the same are provided, in which low carbon Al-killed steel sheet, high oxygen steel sheet, Ti-added steel sheet, Nb-added steel sheet, Ti—Nb-added steel sheet or B-added steel sheet is used. A steel sheet for porcelain enameling is produced by applying Ni—Mo alloy plating to the low carbon Al-killed steel sheet, high oxygen steel sheet, Ti-added steel sheet, Nb-added steel sheet, Ti—Nb-added steel sheet or B-added steel sheet having specified components and composition ratio, and after performing heat treatment thereto to control the content of Ni, Mo, and Fe that are present on the surface of the steel sheet in a predetermined range, porcelain enamel is applied and fired.Type: GrantFiled: December 17, 2001Date of Patent: June 14, 2005Assignees: Ferro Enamels (Japan) Limited, Toyo Kohan Co., Ltd.Inventors: Fumiaki Sato, Toshihira Hamada, Shuzo Oda, Yoshihiro Jono, Takahiro Hayashida, Junichi Fujimoto, Masao Komai
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Patent number: 6896978Abstract: In the joint construction of cobalt-based alloy, a cobalt-based alloy layer 1, in which granular or massive eutectic carbide 2 disperses, is joined to a metal of a base metal 37 via an insert metal layer 36. For the joint construction of cobalt-based alloy, liquid phase diffusion bonding is performed at a temperature of 1100° C. for a retention time of 1 hour with an insert metal with a thickness of about 40 ?m being interposed between the base metal, which is S45C carbon steel, and a cobalt-based alloy material which has granular or massive eutectic carbide with a grain size not larger than 30 ?m in a matrix of cast structure and contains 1.03 wt % C, 29.73 wt % Cr, 3.86 wt % W, 2.59 wt % Ni, 2.67 wt % Fe, 0.59 wt % Si, and 0.07 wt % Mo, the balance substantially being Co. The cobalt-based alloy layer 1 after bonding contains granular or massive eutectic carbide.Type: GrantFiled: February 27, 2002Date of Patent: May 24, 2005Assignee: Hitachi, Ltd.Inventors: Yoshihisa Kiyotoki, Mitsuo Chigasaki, Shizuo Matsushita, Jiro Kuniya, Takahiko Kato, Yoshiteru Chiba
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Patent number: 6890667Abstract: A magnetic recording medium having a soft magnetic underlayer structure that includes two soft underlayers is presented. A thick first soft underlayer, disposed on the medium substrate, is made of material which provides a low magnitude of magnetization saturation (Bsat) and high permeability. The first soft underlayer can be formed by plating or high-rate sputtering. The second soft underlayer, which has a lesser thickness than the first soft underlayer, is made of a material which provides a relatively high magnitude of Bsat and low permeability. The second soft underlayer can be formed by low-rate sputtering. The first soft under layer can be isolated from other layers in the medium by an exchange isolation layer. The second soft underlayer can be exchange coupled to a radial exchange pin layer disposed on the exchange isolation layer.Type: GrantFiled: October 28, 2002Date of Patent: May 10, 2005Assignee: Maxtor CorporationInventors: Bruce Lairson, Mourad Benakli
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Patent number: 6886327Abstract: A multi-layered component, such as a rocket engine combustion chamber, includes NiAl or NiAl-based alloy as a structural layer on the “hot” side of the component. A second structural layer is formed of material selected from Ni-based superalloys, Co-based alloys, Fe-based alloys, Cu, and Cu-based alloys. The second material is more ductile than the NiAl and imparts increased toughness to the component. The second material is selected to enhance one or more predetermined physical properties of the component. Additional structural layers may be included with the additional material(s) being selected for their impact on physical properties of the component.Type: GrantFiled: July 22, 2003Date of Patent: May 3, 2005Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Michael V. Nathal, John Gayda, Ronald D. Noebe
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Patent number: 6869690Abstract: The present invention relates to a zinc-diffused nickel alloy coating for corrosion and heat protection and to a method for forming such a coating. The coating method broadly comprises the steps of forming a plain nickel or nickel alloy coating layer on a substrate, applying a layer of zinc over the nickel or nickel alloy coating layer, and thermally diffusing the zinc into the nickel alloy coating layer. The coating method may further comprise immersing the coated substrate in a phosphated trivalent chromium conversion solution either before or after the diffusing step. The substrate may be a component used in a gas turbine engine, which component is formed from a steel material.Type: GrantFiled: May 19, 2004Date of Patent: March 22, 2005Assignee: United Technologies CorporationInventors: Henry M. Hodgens, Thomas R. Hanlon
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Patent number: 6863995Abstract: A method for using a novel ternary nickel-gold-phosphorus brazing alloy for joining nickel-based components together and the assembly so formed.Type: GrantFiled: May 16, 2003Date of Patent: March 8, 2005Assignee: Praxair S.T. Technology, Inc.Inventor: Thomas A. Sandin
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Patent number: 6858322Abstract: A corrosion-resistant coated brass metal coated with a corrosion resistant alloy. The corrosion resistant alloy is a tin metal alloy or a tin and zinc metal alloy. The corrosion resistant metal alloy may also include one or more metal additives to improve the coating process and/or to alter the properties of the tin and zinc metal alloy.Type: GrantFiled: May 9, 2003Date of Patent: February 22, 2005Assignee: The Louis Berkman CompanyInventors: Jay F. Carey, II, Mehrooz Zamanzadeh, Nicholas R. Hesske
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Patent number: 6855437Abstract: The subject of the invention is a layer system for the decorative coating of galvanizable work pieces. In order to have a layer system which meets strict requirements with regard to corrosion resistance and which, at the same time, has a high abrasion resistance and, in addition, provides a high degree of freedom with regard to decorative coloration, the invention proposes a layer system which is formed by galvanic deposition and comprises a base coat consisting of at least one bright layer and one discontinuous chrome layer as well as a cover coat of mechanically resistant materials deposited by the PVD process.Type: GrantFiled: January 26, 2001Date of Patent: February 15, 2005Assignee: Enthone Inc.Inventors: Hiltrud Tolls, Elmar Tolls
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Patent number: 6844086Abstract: A coated superalloy article is prepared by furnishing a nickel-base superalloy article substrate having a rhenium content of not less than about 4.0 percent by weight, and thereafter depositing an aluminum-containing coating onto a surface of the article substrate. The aluminum-containing coating includes an additive zone having an average aluminum content of not greater than about 27 percent by weight, and a diffusion zone of interdiffusion with the article substrate. A ratio of a thickness of the additive zone to a thickness of the diffusion zone is not greater than about 3:1, and is preferably about 1:1.Type: GrantFiled: February 8, 2002Date of Patent: January 18, 2005Assignee: General Electric CompanyInventors: Theodore Robert Grossman, Ronald Gustav Rajala, Dwayne Edward Burnett, William Scott Walston, Wendy Howard Murpjy
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Patent number: 6841264Abstract: The invention relates to a doctor or coater blade (1) of steel, having a nickel coating comprising abrasion resistant particles, said coating being constituted by an electrolytic nickel layer comprising abrasion resistant particles. The coating preferably comprises at least two electrolytic nickel layers having different composition, and may be formed differently in different sections of the blade. The invention also relates to a continuous process for electrolytic nickel coating in at least one electrolytic cell holding an electrolyte liquid comprising at least one nickel salt, and in at least one of these cells also comprising abrasion resistant particles.Type: GrantFiled: November 29, 2001Date of Patent: January 11, 2005Assignee: Swedev AktiebolagInventors: Allan Lunnerfjord, Roland Sundberg, Jan-Åke Gavén
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Patent number: 6835467Abstract: Disclosed are a structure of multi-layered clad plates and sheets for corrosion resistance and a fabricating method thereof. Provided are clad plates and sheets for corrosion resistance in which Ni, Co, Ti, Nb, V, and Zr having an excellent corrosion resistance, or an alloy thereof are bonded to cheap Fe, Cu, or an alloy thereof. Chemical compositions of the clad metals and structures of the clad plates and sheets are easily modified with service conditions of the clad plates and sheets. Also, this invention provides a more cost-effective method based on a resistance seam welding process for fabricating the corrosion-resistant clad plates and sheets.Type: GrantFiled: January 16, 2003Date of Patent: December 28, 2004Assignee: Korea Institute of Science and TechnologyInventors: Jung Mann Doh, Ji Young Byun, Kyu Won Cho, Ju Yong Jung
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Patent number: 6824668Abstract: Disclosed is a method of electroplating a Ni—Fe—P alloy using a sulfamate solution and, in particular, a method of electroplating a Ni—Fe—P alloy using a plating solution containing nickel sulfamate, iron sulfamate, phosphorous acid, and a buffer agent. The method is advantageous in that a residual stress of a deposited layer is very low and has stable mechanical properties, and excellent thermal and corrosion resistance because the deposited layer is obtained by electroplating the Ni—Fe—P alloy using the sulfamate solution useful in a high rate plating process. Furthermore, the method can be applied to various parent metals such as stainless steel, Inconel and iron alloys, and to various fields because the chemical compositions of the deposited layer are readily controlled by varying the concentration of the plating solution.Type: GrantFiled: November 13, 2002Date of Patent: November 30, 2004Assignees: Korea Atomic Energy Research Institute, Korea Hydro & Nuclear Power Co., Ltd.Inventors: Joung Soo Kim, Yun Soo Lim, Seong Sik Hwang, Moohong Seo
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Patent number: 6818322Abstract: The present invention provides a surface treated steel sheet for electronic components which does not include lead, which is a hazardous substance with environmental impact, and, in particular, satisfies the solder wettability after retort treatment, a rust-proof property and a whisker-proof property simultaneously. More specifically, the present invention is a surface treated steel sheet with less environmental impact for electronic components excellent in solder wettability, a rust-proof property and a whisker-proof property and having an Sn—Zn alloy layer which is formed by plating Sn and Zn on a steel sheet or a Ni plated steel sheet and then applying thermal diffusion treatment, or by plating Sn—Zn alloy on a steel sheet or a Ni plated steel sheet, characterized in that the amount of said Sn—Zn alloy layer is not less than 3 g/m2, the Zn/Sn ratio (in weight ratio) is 0.01 to 10, more preferably 0.01 to 0.Type: GrantFiled: August 21, 2003Date of Patent: November 16, 2004Assignee: Nippon Steel CorporationInventors: Ryoichi Yoshihara, Tokitsugu Shirakawa, Yasuhiko Miura
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Patent number: 6818321Abstract: A high-temperature strength member comprises a substrate of Ni-based single crystal alloy or a Ni-based unidirectional solidified alloy and a coating of a B-containing alloy having a specified B content formed on the surface thereof by a spraying process or a vapor deposition process.Type: GrantFiled: October 25, 2002Date of Patent: November 16, 2004Assignee: Tocalo Co., Ltd.Inventors: Masakazu Okazaki, Yoshio Harada, Tatsuo Suidzu
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Patent number: 6815089Abstract: The invention relates to structural components for the boiler zone of power plants or refuse incineration plants, especially tubes or nests of tubes, fin and diaphragm walls, that consist of steel or steel alloys, and is characterized by a continuous closed outer nickel or nickel alloy layer galvanically deposited having a layer thickness of approximately 1 to 5 mm, preferably 1 to 2.5 mm.Type: GrantFiled: August 20, 2003Date of Patent: November 9, 2004Assignee: BBP Service GmbHInventor: Johann Wilhelm Ansey
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Patent number: 6811894Abstract: A nickel base single crystal compliant layer on a ceramic blade has the capability to sustain high stresses and high operating temperature. Layers of nickel and platinum bonded on a single crystal superalloy over a sputtered gold-chromium layer support the high stress levels at elevated temperature without extrusion of the soft platinum or nickel layer and without destruction of an NiO compliant surface. The compliant layers have survived stress and temperature conditions without failure to the ceramic blade and the system can be stressed/heated and unloaded/cooled repeatedly without damage to the ceramic blades. A single crystal nickel base superalloy (i.e., SC180) has high strength properties at elevated temperature. Thin layers of chromium followed by gold are e-beam evaporated on one side of a polished surface of the alloy. Pure nickel is electroplated over this e-beam gold-chromium layer. Platinum is either electroplated or plated electrolessly over the nickel layer.Type: GrantFiled: June 6, 2003Date of Patent: November 2, 2004Assignee: Honeywell International, Inc.Inventors: Dave Narasimhan, Alexander S. Kozlov, Margaret Eagan, Milton Ortiz
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Publication number: 20040209106Abstract: A peelable composite foil includes a metallic carrier foil, a first barrier layer on one side of the metallic carrier and a second metallic layer on the first barrier layer. The second metallic layer includes a combination of a metal selected from the group including zinc, molybdenum, antimony and tungsten, and an electrodeposited, ultra-thin metal foil on the second metallic layer.Type: ApplicationFiled: January 16, 2004Publication date: October 21, 2004Inventors: Raymond Gales, Michel Streel, Rene Lanners
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Patent number: 6803135Abstract: This invention provides a thermal barrier ceramic coating for application to a metallic article, with the ceramic coating having a formula of RexZr1−xOy wherein Re is a rare earth element selected from the group consisting of Ce, Pr, Nd, Pm, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb and Lu where O<X<0.5 and 1.75<Y<2. A preferred embodiment is wherein Re is Nd.Type: GrantFiled: February 24, 2003Date of Patent: October 12, 2004Assignee: Chromalloy Gas Turbine CorporationInventors: Yourong Liu, Paul Lawton
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Publication number: 20040197594Abstract: A steel material that has on its surface a non-hexavalent-chromium type corrosion-resistant coating film formed by a composite of a metal layer and a resin layer. The steel material having or not having a copper layer is formed with 1) a Zn and/or Zn-based alloy layer, 2) a Zn/Ni alloy layer which is on this Zn and/or Zn-based alloy layer, 3) a de-Zn layer which is on the Zn/Ni alloy layer and is obtained by chemically treating the surface of the Zn/Ni alloy layer, and 4) at least one resin covering layer which is on this de-Zn layer, which are successively formed to make a corrosion-resistant coating film, the corrosion-resistant coating film, which is superior in adhesion between the metal layer and resin layer, being obtained by way of taking into account the use of a trivalent chromium type chromate layer instead of a hexavalent chromium type chromate layer (which is a substance that places a burden on the environment).Type: ApplicationFiled: February 11, 2004Publication date: October 7, 2004Inventors: Kazuo Suzuki, Iyoshi Watanabe
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Patent number: 6800376Abstract: A method is provided for refurbishing a service operated metallic coating on a substrate alloy, the coating including at least within a coating outer surface at least one oxide chemically grown from at least one coating element, for example Al, and chemically bonded with the coating outer surface as a result of thermal exposure during service operation. Growth of the oxide has depleted at least a portion of the coating element from the coating. The method comprises removing the oxide from the coating outer surface while substantially retaining the metallic coating, thereby exposing in the coating outer surface at least one surface void that had been occupied by the oxide. The retained metallic coating is mechanically worked, substantially without removal of the retained coating, to close the void, providing a treated metallic coating surface over which a refurbishing coating is applied.Type: GrantFiled: September 30, 2002Date of Patent: October 5, 2004Assignee: General Electric CompanyInventors: Bhupendra Kumar Gupta, Nripendra Nath Das, Lyle Timothy Rasch, Jeffrey Allen Conner, Michael James Weimer
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Patent number: 6797406Abstract: The present invention relates to a color cathode ray tube provided with a pressed-type shadow mask. As material for constituting the shadow mask 6, a single plate body made of a composite gradient alloy plate consisting of three layers 6A, 6B, 6C or more in which an alloy element has the concentration gradient which is continuously changed from one surface to the other surface is used. The present invention can realize a pressed mask having a large radius of curvature by self-correcting the thermal deformation such as a doming or the like.Type: GrantFiled: June 5, 2002Date of Patent: September 28, 2004Assignee: Hitachi, Ltd.Inventors: Noriharu Matsudate, Nobuhiko Hosotani
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Patent number: 6780524Abstract: Disclosed is a spin-valve sensor disposed between first and second gap layers and formed of one or more in-situ oxidized films. The improved spin valve sensor helps eliminate electrical shorting between the spin-valve sensor and shield layers. A fabrication method of the gap layers comprises repeatedly depositing a metallic films on a wafer in a DC-magnetron sputtering module of a sputtering system, and then transferring the wafer in a vacuum to an oxidation module where in-situ oxidation is conducted. This deposition/in-situ oxidation process is repeated until a designed thicknesses of gap layers is attained. Smaller, more sensitive spin-valve sensors may be sandwiched between thinner gap layers formed of in-situ oxidized films, thus allowing for greater recording data densities in disk drive systems.Type: GrantFiled: February 4, 2002Date of Patent: August 24, 2004Assignee: Hitachi Global Storage Technologies Netherlands B.V.Inventors: Tsann Lin, Daniele Mauri
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Publication number: 20040151941Abstract: A separator plate for the production of printed circuit board components by pressing individual layers, which separator plate includes a metallic core layer and a coating on at least one side of the core layer, wherein the coating on the core layer, which is made of a comparatively well heat-conductive metal, is comprised of an outer metal layer applied to the core layer by cold-plating and made of a metal having a comparatively high surface hardness.Type: ApplicationFiled: July 25, 2003Publication date: August 5, 2004Applicant: C2C TECHNOLOGIE FUR LEITERPLATTEN GMBHInventor: Ernst D. Backhaus
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Publication number: 20040146739Abstract: The invention relates to a method for coating a seal surface (1) used at an oil refinery by a coating layer (4) of a nickel-based material. In the method according to the invention, the coating layer (4) is formed using a laser coating method. The invention also relates to a seal surface (1) for use at an oil refinery and having a coating layer (4) of a nickel-based material applied theron. In a seal surface (1) according to the invention, the coating layer (4) is formed using a laser coating method.Type: ApplicationFiled: February 10, 2004Publication date: July 29, 2004Inventors: Tapani Karhinen, Jari Lyytinen
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Patent number: 6764779Abstract: This invention provides a metallic article with a metallic substrate having a thermal barrier ceramic coating on its surface, the ceramic coating comprising a plurality of first layers of about 6 to 8 wt % yttria stabilized zirconia alternating with a plurality of second layers of about 18 to 22 wt % yttria stabilized zirconia. The alternating layers can be distinct layers or gradient layers.Type: GrantFiled: February 24, 2003Date of Patent: July 20, 2004Assignee: Chromalloy Gas Turbine CorporationInventors: Yourong Liu, Paul Lawton
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Publication number: 20040137261Abstract: The invention relates to a doctor or coater blade (1) of steel, having a nickel coating comprising abrasion resistant particles, said coating being constituted by an electrolytic nickel layer comprising abrasion resistant particles. The coating preferably comprises at least two electrolytic nickel layers having different composition, and may be formed differently in different sections of the blade. The invention also relates to a continuous process for electrolytic nickel coating in at least one electrolytic cell holding an electrolyte liquid comprising at least one nickel salt, and in at least one of these cells also comprising abrasion resistant particles.Type: ApplicationFiled: January 13, 2004Publication date: July 15, 2004Inventors: Allan Lunnerfjord, Roland Sundberg, Jan-Ake Gaven
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Patent number: 6756134Abstract: The present invention relates to a zinc-diffused nickel alloy coating for corrosion and heat protection and to a method for forming such a coating. The coating method broadly comprises the steps of forming a plain nickel or nickel alloy coating layer on a substrate, applying a layer of zinc over the nickel or nickel alloy coating layer, and thermally diffusing the zinc into the nickel alloy coating layer. The coating method may further comprise immersing the coated substrate in a phosphated trivalent chromium conversion solution either before or after the diffusing step. The substrate may be a component used in a gas turbine engine, which component is formed from a steel material.Type: GrantFiled: September 23, 2002Date of Patent: June 29, 2004Assignee: United Technologies CorporationInventors: Henry M. Hodgens, Thomas R. Hanlon, Promila Bhatia
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Patent number: 6749952Abstract: The tin-plated steel sheet includes a base steel sheet; a tin plating layer coating approximately more than 97.0% of the base steel sheet; and a chemical conversion coating having approximately 0.5 to 100 mg/m2 phosphorus and approximately 0.1 to 250 mg/m2 silicon formed on the tin plating layer and an unplated region corresponding to approximately less than 3.0%. The tin-plated steel sheet does not contain chromium which is harmful to the environment but has superior overcoat adhesion property, discoloration resistance, and rust resistance.Type: GrantFiled: March 15, 2002Date of Patent: June 15, 2004Assignee: JFE Steel CorporationInventors: Tomofumi Shigekuni, Hisatada Nakakoji, Chiaki Kato
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Patent number: 6730413Abstract: A thermal insulating ceramic layer for use on metal alloy components exposed to hostile thermal and chemical environment, such as a gas turbine engine used to generate electricity. The preferred thermal barrier layer is formed using dense vertical cracking and formed of zirconia that is partially stabilized by yttria in a preferred amount of less than 4 weight percent and about 1 weight percent Hafnia. The ceramic layer is optimized to protect the underlying superalloy component from erosion, chipping, and handling, while reducing the cost of the protective layer. An alternative method of preparing the thermal barrier coating uses electron beam physical vapor deposition.Type: GrantFiled: July 31, 2001Date of Patent: May 4, 2004Assignee: General Electric CompanyInventors: Jon C. Schaeffer, Robert W. Bruce
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Publication number: 20040076850Abstract: The invention relates to structural components for the boiler zone of power plants or refuse incineration plants, especially tubes or nests of tubes, fin and diaphragm walls, that consist of steel or steel alloys, and is characterized by a continuous closed outer nickel or nickel alloy layer galvanically deposited having a layer thickness of approximately 1 to 5 mm, preferably 1 to 2.5 mm.Type: ApplicationFiled: August 20, 2003Publication date: April 22, 2004Inventor: Johann Wilhelm Ansey