Abstract: The present application is directed to carbon materials comprising an electrochemical modifier. The carbon materials find utility in any number of electrical devices, for example, in lead acid batteries. Methods for making the disclosed carbon materials are also disclosed.

Abstract: A lithium-ion secondary battery allowed to improve cycle characteristics and initial charge-discharge characteristics is provided. The lithium-ion secondary battery includes a cathode; an anode; and an electrolytic solution. The anode includes an anode active material layer including a plurality of anode active material particles. The anode active material particles each include a core section and a coating section applied to a part or a whole of a surface of the core section, and the core section includes a silicon-based material (SiOx: 0?x<0.5) and the coating section includes an amorphous or low-crystalline silicon-based material (SiOy: 0.5?y?1.8).

Abstract: A rechargeable battery is provided such that the positive electrode comprises lead dioxide, the negative electrode zinc, iron, lead or cadmium, and the electrolyte is alkaline. Upon discharge, the lead dioxide is reduced to lead oxide, the metal is oxidized to an oxide, and the electrolyte remains unchanged. The reactions are reversed when the battery is charged.

Abstract: A nonaqueous electrolyte secondary battery including: an electrode group which includes a positive electrode containing lithium-containing composite oxide, a negative electrode capable of inserting and extracting lithium ions, and a porous insulator interposed between the positive electrode and the negative electrode, and is sealed in a battery case together with a nonaqueous electrolyte, wherein the porous insulator has a Gurley number of 100 sec/100 ml to 1000 sec/100 ml, both inclusive, and an average pore diameter of 0.05 ?m to 0.15 ?m, both inclusive.

Abstract: A method and apparatus for continuously casting lead alloy strip on a casting surface on substantially the upper half of a rotatable casting drum from a pool of molten lead alloy at a high speed comprising imparting a coarse texture to the casting surface, providing a tundish containing a pool of the molten lead alloy at a predetermined temperature adjacent a substantially vertical upwardly-moving portion of said casting drum, the tundish having a graphite lip insert having an open front defined by a lip insert floor and opposed sidewalls cooperating with and commencing at a substantially vertical portion of the casting surface to contain said molten lead alloy in the lip insert, controlling the height of the surface level and temperature of the molten lead alloy in the lip insert, moving the casting surface upwardly through the pool of molten lead alloy by rotating said drum for depositing the lead alloy thereon, cooling the casting surface of the drum to solidify a strip of the lead alloy on substantially t

Abstract: A lead-acid battery comprising: at least one lead-based negative electrode; at least one lead dioxide-based positive electrode; at least one capacitor electrode; and electrolyte in contact with the electrodes; wherein a battery part is formed by the lead based negative electrode and the lead dioxide-based positive electrode; and an asymmetric capacitor part is formed by the capacitor electrode and one electrode selected from the lead based negative electrode and the lead-dioxide based positive electrode; and wherein all negative electrodes are connected to a negative busbar, and all positive electrodes are connected to a positive busbar. The capacitor electrode may be a capacitor negative electrode comprising carbon and an additive mixture selected from oxides, hydroxides or sulfates of lead, zinc, cadmium, silver and bismuth, or a capacitor negative electrode comprising carbon, red lead, antimony in oxide, hydroxide or sulfate form, and optionally other additives.

Abstract: Capacitor pastes for flooded deep discharge lead-acid batteries include lead oxide, a carbon additive, and an aqueous acid. The capacitor paste contains lead and carbon in a lead to carbon mass ratio of about 5:1 to 82:1. Hybrid negative plates for flooded deep discharge lead-acid batteries can be made using such pastes in combination with traditional pastes. The hybrid negative plates include a capacitor paste on a bottom portion of the plate, and a traditional paste on the remainder of the plate. Batteries using the capacitor paste and hybrid plates exhibit improved performance over batteries with conventional plates and pastes and require less overcharge to prevent electrolyte stratification.

Abstract: A hybrid supercapacitor energy storage device includes at least one lead electrode, at least one carbon electrode, a separator, a casing, and an acid electrolyte. The lead electrode is enveloped in a common glass mat separator known in the lead-acid battery industry. The carbon electrode comprises a highly conductive current collector which is a sheet or other metal material sandwiched between two sheets of electronically conductive shield material. Activated carbon is manufactured using a binder such as polyethylene or PTFE adhered to and in electrical contact with the shield material of the current collector.

Abstract: The object of the present invention is to improve the short-term discharge power after the thermal cycles, as the object of the improvement of the characteristics of the lead acid battery. An electrode for a lead acid battery comprising an electrode active material layer comprising a lead containing material, a porous carbon material and a binder, and a current collector, wherein when a weight of lead atom is A and a weight of porous carbon material is B, B/(A+B)×100 satisfies 1.0 to 90%; and said binder is a crystalline polymer having a melting temperature of 40° C. or less or amorphous polymer, is used.

Abstract: A process is provided to produce non-aqueous electrolytic solution for use in batteries having low acid content and low water content. The invention involves removing acids and water from non-aqueous electrolytic solutions typically found in lithium or lithium-ion batteries by using nitrogen-containing compounds such as triazines. After treatment by a triazine such as melamine, the concentrations of acids and water in the electrolytic solutions are substantially decreased. The present invention provides a process to prepare extremely pure electrolytic solutions having low (<20 ppm) concentrations of both water and acids.

Abstract: Provided is a lead-based alloy for a lead-acid battery, comprising not less than 0.02% and less than 0.05% by weight of calcium, not less than 0.4% and not more than 2.5% by weight of tin, not less than 0.005% and not more than 0.04% by weight of aluminum, not less than 0.002% and not more than 0.014% by weight of barium, and the balance of lead and unavoidable impurities.

Abstract: Disclosed herein is a unit cell for a lithium ion secondary battery, which includes an electrode laminate formed in such a manner that a plurality of unit structures are stacked, each of which includes and least one electrode and at least one separation layer; and at least one conductive sheet layer located between certain layers in the electrode laminate and electrically connected to an electrode lead. The conductive sheet layer of the unit cell for the lithium ion secondary battery rapidly conducts current to the outside or generates heat in quantity smaller than the quantity of heat generated in positive and negative electrodes when short-circuit occurs due to a physical or electrical impact applied to the battery. Accordingly, it is possible to reduce the risk of firing or explosion due to the physical or electrical impact to improve the safety of the lithium ion secondary battery.

Abstract: The invention provides an electrochemical cell which includes a first electrode and a second electrode which is a counter electrode to said first electrode, and an electrolyte material interposed there between. The first electrode includes an alkali metal phosphorous compound doped with an element having a valence state greater than that of the alkali metal.

Abstract: A battery, comprising a case, an electrode assembly within the case, wherein the electrode assembly includes a positive electrode and a negative electrode, and positive and negative conductors electrically connected to the positive and negative electrodes, respectively, at a substantially similar point on the respective electrode assembly such that current flows in opposite directions through the positive and negative electrodes. The positive and negative conductors are closely routed so as to be aligned and in close proximity. As a result, magnetic fields generated by the positive and negative electrodes and the positive and negative conductors are substantially cancelled.

Abstract: A stacked energy storage device (ESD) has at least two cell segments arranged in a stack. Each cell segment may have a first electrode unit having a first active material electrode, a second electrode unit having a second active material electrode, and an electrolyte layer between the active material electrodes. The ESD includes at least two sub-stacks, where the elements of each respective sub-stack are electrically coupled in series with other elements of the sub-stack. The sub-stacks may be placed in a single stack, and the sub-stacks may be electrically coupled in parallel, in series, or both, with other sub-stacks to create an ESD with a particular voltage and current capacity. The entire stack may be contained by a single pair of end caps.

Abstract: The invention relates to a metal-containing, hydrogen-storing material which contains a catalyst for the purpose of hydration or dehydration, said catalyst being a metal carbonate. The method for producing such a metal-containing, hydrogen-storing material is characterized by subjecting the metal-containing material and/or the catalyst in the form of a metal carbonate to a mechanical milling process.

Abstract: The present invention relates to a negative active material for a rechargeable lithium battery, a method of manufacturing the negative active material, and a rechargeable lithium battery including the negative active material.

Abstract: A method of forming battery grids or plates that includes the step of mechanically reshaping or refinishing battery grid wires to improve adhesion between the battery paste and the grid wires. The method is particularly useful in improving the paste adhesion to battery grids formed by a continuous battery grid making process (such as strip expansion, strip stamping, continuous casting) that produces grid wires and nodes with smooth surfaces and a rectangular cross-section. In a preferred version of the method, the grid wires of battery grids produced by a stamping process are deformed such that the grid wires have a cross-section other than the rectangular cross-section produced by the stamping process. The method increases the cycle life of a battery.

Abstract: A process for producing high purity lead oxide from impure lead compounds particularly from waste lead battery paste which includes an oxidation-reduction step. The process results in a reduction of impure lead compounds to the +2 valence state and metal particle contaminants are oxidized to the +2 state.

Abstract: A non-aqueous electrolyte secondary battery that can restrict lowering of battery performance during battery preservation is provided. A negative electrode that a negative electrode mixture including graphite is applied on a rolled copper foil and a positive electrode that a positive electrode mixture including lithium manganate is applied on an aluminum foil are used. An oxide in which one element selected from Al, Si, Ti, V, Cr, Fe, Ni, Cu, Zn, Zr, Mo, W, Pb and dissimilar to elements constituting the lithium manganate is oxidized is intermixed with the lithium manganate. An intermixture amount of the oxide is set such that a molar number of the dissimilar element contained in one gram of the positive electrode active material to a molar number of lithium contained in one gram of the positive electrode active material is not more than 5/1000. Charge transfer is restricted by the oxide during battery preservation.

Abstract: A composite electrode includes an active component directly bonded to a current collector. The direct bonding provides a low resistance contact between the current collector and the active material. The active component can be provided as fibres of silicon. The fibres can be free or attached to a support.

Abstract: Disclosed is a compound represented by the following formula 1. A lithium secondary battery using the same compound as electrode active material, preferably as cathode active material, is also disclosed. LiMP1-xAxO4??[Formula 1] wherein M is a transition metal, A is an element having an oxidation number of +4 or less and 0<x<1. The electrode active material comprising a compound represented by the formula of LiMP1-xAxO4 shows excellent conductivity and charge/discharge capacity compared to LiMPO4.

Abstract: A lead-acid battery comprising:—at least one negative electrode comprising lead-based battery electrode material and at least one region of capacitor material overlying the lead-based battery electrode material, each electrode being in electrical connection to an outer terminal of the battery, and—at least one positive lead-dioxide based battery electrode, each positive electrode being in electrical connection to a second outer terminal of the battery,—separator interleaving the facing electrodes;—electrolyte filling at least the space of the electrodes and separators wherein the capacitor material overlying the lead-based battery electrode material comprises 20-65% by weight of a high electrical conductivity carbonaceous material, 30-70% of a high specific surface area carbonaceous material, at least 0.1% lead and binder.

Abstract: The present invention provides a lithium ion battery that exhibits a significantly improved specific capacity and much longer charge-discharge cycle life. In one preferred embodiment, the battery comprises an anode active material that has been prelithiated and pre-pulverized. This anode may be prepared with a method that comprises (a) providing an anode active material (preferably in the form of fine powder or thin film); (b) intercalating or absorbing a desired amount of lithium into the anode active material to produce a prelithiated anode active material; (c) comminuting the prelithiated anode active material into fine particles with an average size less than 10 ?m (preferably <1 ?m and most preferably <200 nm); and (d) combining multiple fine particles of the prelithiated anode active material with a conductive additive and/or a binder material to form the anode. Preferably, the prelithiated particles are protected by a lithium ion-conducting matrix or coating material.

Abstract: The invention provides an electrochemical cell which includes a first electrode and a second electrode which is a counter electrode to said first electrode, and an electrolyte material interposed there between. The first electrode includes an alkali metal phosphorous compound doped with an element having a valence state greater than that of the alkali metal.

Abstract: Electrochemical energy sources based on solid-state electrolytes are known in the art. These (planar) energy sources, or ‘solid-state batteries’, efficiently convert chemical energy into electrical energy and can be used as the power sources for portable electronics. The invention relates to an improved electrochemical energy source. The invention also relates to an electronic device provided with such an electrochemical energy source.

Abstract: A mixed positive electrode active material is used. The mixed positive electrode active material is obtained by mixing a layered oxide whose initial charge-discharge efficiency when lithium metal is used for a counter electrode is less than 100% (hereinafter referred to as a first layered oxide) and a layered oxide whose initial charge-discharge efficiency is 100% or more (hereinafter referred to as a second layered oxide). Examples of the first layered oxide include Li1+aMnxCoyNizO2. A sodium oxide such as LiANaBMnXCoYNiZO2 other than a layered compound from which lithium is previously extracted by acid treatment or the like can be used as the second layered oxide whose initial charge-discharge efficiency is 100% or more. A layered oxide obtained by replacing (ion exchange) sodium in the foregoing LiANaBMnXCoYNiZO2 with lithium can be also used as the second layered oxide.

Abstract: The invention relates to an electrochemical energy source, comprising a substrate, and at least one cell deposited onto said substrate. The invention also relates to an electronic device, said device comprising at least one electrochemical energy source according to invention, and at least one electronic component electrically connected to said electrochemical energy source.

Abstract: The invention relates to the use of an amine oxide as an additive in a nonaqueous electrolytic solution. The electrolytic solution is suitable for use in electrochemical cells such as lithium batteries and lithium ion batteries. Batteries using this electrolyte solution have long life and high capacity retention.

Abstract: An object of the present invention is to take fundamental measures against the phenomenon that the positive current collector of a lead-acid battery elongates due to corrosion, in consideration of a mechanism, and to inhibit corrosion elongation. A current collector is prepared by the steps of: mixing a lead oxide of pinning compounds for inhibiting recrystallization with the atomized powder of lead or a lead alloy; and then powder-rolling the mixture. A lead-acid battery is composed with the use of the current collector.

Abstract: An electrode plate (44) for a lead-acid battery (10) is disclosed. The electrode plate includes a current-collecting first layer (48). In addition, the electrode plate also includes a second layer (50) comprising flexible graphite sheeting (52) and configured to distribute thermal energy within the electrode plate. Further, the electrode plate includes a third layer (48, 62), wherein the second layer is disposed between the current-collecting first layer and the third layer.

Abstract: Multi-component intermetallic negative electrodes prepared by electrochemical deposition for non-aqueous lithium cells and batteries are disclosed. More specifically, the invention relates to composite intermetallic electrodes comprising two or more compounds containing metallic or metaloid_elements, at least one element of which can react with lithium to form binary, ternary, quaternary or higher order compounds, these compounds being in combination with one or more other metals that are essentially inactive toward lithium and act predominantly, but not necessarily exclusively, to the electronic conductivity of, and as current collection agent for, the electrode. The invention relates more specifically to negative electrode materials that provide an operating potential between 0.05 and 2.0 V vs. metallic lithium.

Abstract: The invention relates to an electrochemical energy source, comprising a substrate and at least one electrochemical cell deposited onto said substrate, wherein the cell comprises an anodic electrode, a cathodic electrode and an electrolyte separating said anodic electrode and said cathodic electrode and wherein the cathodic electrode comprises at least one non-oxidic composition, said composition comprising active species. The invention disclosed in this document describes how a battery, consisting of a lithium alloy anodic electrode and a cathodic electrode made of this different class of materials mentioned above, might be a suitable alternative for a battery stack comprising conventionally used materials, especially in applications in which a high current capability is essential.

Abstract: A process for producing lightweight materials for a battery comprises lightweight polymer substrate coated with dispersions of nano particles, conductive matrixes and active material.

Abstract: This invention provides a nanocomposite-based lithium battery electrode comprising: (a) A porous aggregate of electrically conductive nano-filaments that are substantially interconnected, intersected, physically contacted, or chemically bonded to form a three-dimensional network of electron-conducting paths, wherein the nano-filaments have a diameter or thickness less than 1 ?m (preferably less than 500 nm); and (b) Sub-micron or nanometer-scale electro-active particles that are bonded to a surface of the nano-filaments with a conductive binder material, wherein the particles comprise an electro-active material capable of absorbing and desorbing lithium ions and wherein the electro-active material content is no less than 25% by weight based on the total weight of the particles, the binder material, and the filaments. Preferably, these electro-active particles are coated with a thin carbon layer. This electrode can be an anode or a cathode.

Abstract: A lithium secondary battery includes a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material, a separator separating the positive electrode from the negative electrode, and an electrolyte. The negative electrode active material includes a graphite core particle, at least one metal particle located on the graphite core particle, and a polymer film coating the graphite core particle and the at least one metal particle. The polymer includes a polyimide- or polyacrylate-based polymer.

Abstract: An alkaline electrochemical cell having an anode containing zinc and a cathode that includes a catalyst and an iodate is disclosed. The catalyst catalyzes the reduction of the iodate when the cell is discharged thereby enabling the cell to be used in devices that have a functional endpoint of 1.0V or higher. Preferred catalysts include platinum and palladium. Suitable iodates include copper iodate, strontium iodate and lead iodate.

Abstract: A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

Abstract: A storage battery is provided comprising appositive electrode of lead, a negative electrode of mercury, and an electrolyte consisting of an aqueous solution of a salt of an alkali metal. Upon charging the battery, lead is converted to lead dioxide and the alkali metal forms the amalgam with the mercury. During discharge, the lead dioxide is reduced to the plumbous state and the alkali metal is oxidized to the positive ion and goes into solution. The mercury is immobilized in one of several alternative ways.

Abstract: The invention relates to an electrochemical energy source, comprising: a substrate, and at least one stack deposited onto said substrate, the stack comprising: an anode, a cathode, and an intermediate solid-state electrolyte separating said anode and said cathode; and at least one electron-conductive barrier layer being deposited between the substrate and the anode, which barrier layer is adapted to at least substantially preclude diffusion of active species of the stack into said substrate. The invention further relates to a method for manufacturing such an electrochemical energy source, comprising the steps of: A) depositing at least one electron-conductive barrier layer onto the substrate, and B) depositing at least one stack of an anode, an solid-state electrolyte, and a cathode successively onto said electron-conductive barrier layer.

Abstract: A nonaqueous electrolyte secondary battery with excellent charging/discharging cycle characteristics is provided, more specifically a nonaqueous electrolyte secondary battery in which deterioration of the conductivity of a negative electrode due to charging/discharging cycle is suppressed and a method for manufacturing the same are provided. The nonaqueous electrolyte secondary battery includes: a positive electrode and a negative electrode that are capable of reversibly absorbing and desorbing Li ions; and a nonaqueous electrolyte having lithium ion conductivity. The negative electrode includes a collector and active material particles that are disposed on a surface of the collector. The active material particles include Si and at least one element R selected from the group consisting of Sn, In, Ga, Pb and Bi. Metallic bond including the element R is formed between the active material particles.

Abstract: A lead acid battery of the present invention has: an electrode plate pack including a plurality of negative electrode plates which each comprise a negative electrode grid having a tab and a negative electrode active material layer retained by the negative electrode grid, a plurality of positive electrode plates which each comprise a positive electrode grid having a tab and a positive electrode active material layer retained by the positive electrode grid, and a plurality of separators separating the positive and negative electrode plates; a positive electrode connecting member connected to each positive electrode plate of the electrode plate pack; and a negative electrode connecting member connected to each negative electrode plate of the electrode plate pack. The positive electrode grid has a lead alloy layer including 0.01 to 0.

Abstract: A current collector plate (20) for an energy storage device includes a first current collector (11) and a bonding layer (22) connected to the first current collector. At least one current carrier (31) is disposed at least partially between the first current collector and the bonding layer.

Abstract: In a positive electrode current collector for a lead-acid battery including a coating of tin dioxide formed on the surface of a current collector substrate of titanium or a titanium alloy, the half width of a peak with the maximum intensity among peaks of tin dioxide in the x-ray diffraction pattern of the positive electrode current collector for a lead-acid battery is 1° or lower.

Abstract: This invention provides a mixed nano-filament composition for use as an electrochemical cell electrode. The composition comprises: (a) an aggregate of nanometer-scaled, electrically conductive filaments that are substantially interconnected, intersected, or percolated to form a porous, electrically conductive filament network, wherein the filaments have a length and a diameter or thickness with the diameter/thickness less than 500 nm (preferably <100 nm) and a length-to-diameter or length-to-thickness aspect ratio greater than 10; and (b) Multiple nanometer-scaled, electro-active filaments comprising an electro-active material capable of absorbing and desorbing lithium ions wherein the electro-active filaments have a diameter or thickness less than 500 nm (preferably <100 nm). The electro-active filaments (e.g., nanowires) and the electrically conductive filaments (e.g.

Abstract: An object of the present invention is to take fundamental measures against the phenomenon that the positive current collector of a lead-acid battery elongates due to corrosion, in consideration of a mechanism, and to inhibit corrosion elongation. A current collector is prepared by the steps of: mixing a lead oxide of pinning compounds for inhibiting recrystallization with the atomized powder of lead or a lead alloy; and then powder-rolling the mixture. A lead-acid battery is composed with the use of the current collector.

Abstract: This invention provides a hybrid nano-filament composition for use as an electrochemical cell electrode. The composition comprises: (a) an aggregate of nanometer-scaled, electrically conductive filaments that are substantially interconnected, intersected, or percolated to form a porous, electrically conductive filament network comprising substantially interconnected pores, wherein the filaments have an elongate dimension and a first transverse dimension with the first transverse dimension being less than 500 nm (preferably less than 100 nm) and an aspect ratio of the elongate dimension to the first transverse dimension greater than 10; and (b) micron- or nanometer-scaled coating that is deposited on a surface of the filaments, wherein the coating comprises an anode active material capable of absorbing and desorbing lithium ions and the coating has a thickness less than 20 ?m (preferably less than 1 ?m). Also provided is a lithium ion battery comprising such an electrode as an anode.

Abstract: The invention relates to an electrochemical energy source comprising at least one assembly of: a first electrode, a second electrode, and an intermediate solid-state electrolyte separating said first electrode and said second electrode. The invention also relates to an electronic module provided with such an electrochemical energy source. The invention further relates to an electronic device provided with such an electrochemical energy source. Moreover, the invention relates to a method of manufacturing of such an electrochemical energy source.

Abstract: An electrode material for an anode of a rechargeable lithium battery, containing a particulate comprising an amorphous Sn.A.X alloy with a substantially non-stoichiometric ratio composition. For said formula Sn.A.X , A indicates at least one kind of an element selected from a group consisting of transition metal elements, X indicates at least one kind of an element selected from a group consisting of O, F, N, Mg, Ba, Sr, Ca, La, Ce, Si, Ge, C, P, B, Pb, Bi, Sb, Al, Ga, In, Tl, Zn, Be, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, As, Se, Te, Li and S, where the element X is not always necessary to be contained. The content of the constituent element Sn of the amorphous Sn.A.X alloy is Sn/(Sn+A+X)=20 to 80 atomic %.

Abstract: A positive-electrode active material for a lithium-ion secondary battery has an average composition expressed by the following formula (1): LixCo1?y?zMyCezOb?aXa ??(1) wherein M represents at least one element selected from the group consisting of boron B, magnesium Mg, aluminum Al, silicon Si, phosphorous P, sulfur S, titanium Ti, chromium Cr, manganese Mn, iron Fe, cobalt Co, nickel Ni, copper Cu, zinc Zn, gallium Ga, yttrium Y, zirconium Zr, molybdenum Mo, silver Ag, tungsten W, indium In, tin Sn, lead Pb, and antimony Sb, X represents a halogen element, and x, y, z, a, and b satisfy 0.2<x?1.2, 0?y?0.1, 0.5<z?5.0, 1.8?b?2.2, and 0?a?1.0, respectively, and the concentration of cerium Ce is higher in the vicinity of the surface than in the inside.