Oxygen Is Ring Member Of The Hetero Ring Patents (Class 429/329)
  • Patent number: 7718322
    Abstract: Disclosed in an electrolyte for a rechargeable lithium battery, including a mixture of organic solvents including a cyclic solvent and a nitrile-based solvent represented by formula 1 and a lithium salt.
    Type: Grant
    Filed: August 20, 2004
    Date of Patent: May 18, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Yong-Beom Lee, Eui-Hwan Song, Kwang-Sup Kim, Tae-Shik Earmme, You-Mee Kim
  • Patent number: 7691537
    Abstract: An electrolyte for a lithium secondary battery and a lithium secondary battery having the electrolyte, the electrolyte including a lithium salt; a non-aqueous organic solvent including ?-butyrolactone; and succinic anhydride.
    Type: Grant
    Filed: July 7, 2006
    Date of Patent: April 6, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Cheonsoo Kim
  • Patent number: 7682754
    Abstract: The invention relates to the use of an amine oxide as an additive in a nonaqueous electrolytic solution. The electrolytic solution is suitable for use in electrochemical cells such as lithium batteries and lithium ion batteries. Batteries using this electrolyte solution have long life and high capacity retention.
    Type: Grant
    Filed: May 26, 2005
    Date of Patent: March 23, 2010
    Assignee: Novolyte Technologies, Inc.
    Inventors: Wu Xu, Zhongyi Deng, Vaikunth S. Prabhu, Pascal Bolomey
  • Publication number: 20100055574
    Abstract: A primary cell having an anode comprising lithium and a cathode comprising a metal doped iron sulfide and carbon particles. A cathode slurry is prepared comprising the metal doped iron sulfide powder, carbon, binder, and a liquid solvent. The mixture is coated onto a conductive substrate and solvent evaporated leaving a dry cathode coating on the substrate. The anode and cathode can be spirally wound with separator therebetween and inserted into the cell casing with electrolyte then added.
    Type: Application
    Filed: August 27, 2008
    Publication date: March 4, 2010
    Inventors: Zhiping Jiang, Rimma Sirontina, Nikolay Iltchev
  • Patent number: 7662519
    Abstract: The present invention provides a non-aqueous electrolyte secondary battery having excellent properties such as energy density and electromotive force and being excellent in cycle life, storage property and safety. In the present invention, the non-aqueous electrolyte secondary battery comprises a substance having a peak from 162.9 to 164.0 eV by XPS analysis on the anode surface.
    Type: Grant
    Filed: August 11, 2004
    Date of Patent: February 16, 2010
    Assignee: NEC Corporation
    Inventors: Yuki Kusachi, Koji Utsugi
  • Patent number: 7659037
    Abstract: Using a positive electrode active material including spinel type manganese oxide as the main constituent, a novel low cost and high output power flat type nonaqueous secondary cell for HEVs that has increased safety at overcharge, and superior storage properties and cycle life is provided. A flat type nonaqueous secondary cell that has increased safety and is superior in storage and cycle properties even though the cell is a laminate type cell which does not have a blocking mechanism can be obtained by blending the spinel type lithium manganese oxide of the positive electrode and 5 wt % to 40 wt % of layered type lithium manganese oxide, to suppress storage deterioration at a high temperature and to simultaneously achieve safety when overcharged, and further, by adding a Li compound having a structure as shown in Formula (1) structure, to suppress deterioration of a mixed positive electrode active material during a high temperature cycle.
    Type: Grant
    Filed: December 13, 2006
    Date of Patent: February 9, 2010
    Assignees: Hitachi, Ltd., Hitachi Vehicle Energy, Ltd.
    Inventors: Hiroshi Fukunaga, Youshin Yagi, Shuichi Wada, Kenji Hara, Kazushige Kohno, Hiroshi Haruna
  • Patent number: 7629081
    Abstract: A nonaqueous electrolyte secondary battery includes a case, a nonaqueous electrolyte provided in the case and containing a linear sulfite, a positive electrode provided in the case and capable of absorbing-releasing Li element or Li ions, and a negative electrode provided in the case and containing a lithium titanium oxide and a conductive agent that includes a carbonaceous material.
    Type: Grant
    Filed: March 24, 2005
    Date of Patent: December 8, 2009
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hiroki Inagaki, Yoshinao Tatebayashi, Norio Takami
  • Patent number: 7608364
    Abstract: This invention provides a lithium ion secondary battery comprising a cathode, an anode and an nonaqueous electrolytic solution in which an electrolyte is dissolved in a nonaqueous solvent, wherein the anode comprises a non-graphitizable carbon as an anode activator; and the nonaqueous electrolytic solution comprises at least one anode protecting component selected from the group consisting of sultones having a 5- to 7-membered cyclic sulfonate structure and their substituted derivatives as well as vinylene carbonates and their substituted derivatives.
    Type: Grant
    Filed: December 22, 2003
    Date of Patent: October 27, 2009
    Assignee: NEC Corporation
    Inventors: Junko Nishiyama, Tamaki Miura, Koji Utsugi
  • Publication number: 20090263727
    Abstract: A primary cell having an anode comprising lithium or lithium alloy and a cathode comprising iron disulfide (FeS2), iron sulfide (FeS) and carbon particles. The electrolyte comprises a lithium salt dissolved in a solvent mixture. A cathode slurry is prepared comprising iron disulfide (FeS2) powder, iron sulfide (FeS) powder, carbon, binder, and a liquid solvent. The mixture is coated onto a conductive substrate and solvent evaporated leaving a dry cathode coating on the substrate. The anode and cathode can be spirally wound with separator therebetween and inserted into the cell casing with electrolyte then added.
    Type: Application
    Filed: April 16, 2008
    Publication date: October 22, 2009
    Inventors: Barry D. Josephs, Michael Pozin, Zhiping Jiang, Maya Stevanovic, Fred J. Berkowitz, Yelena Kouznetsova, Steven J. Specht
  • Patent number: 7592101
    Abstract: A non-aqueous electrolyte primary battery including: a positive electrode including a fluorinated carbon; a negative electrode including a lithium metal; a non-aqueous electrolyte; and a separator, wherein the non-aqueous electrolyte includes a non-aqueous solvent and a solute dissolved therein, the non-aqueous solvent including ?-butyrolactone, and the separator includes a microporous membrane onto which a phosphoric acid ester is provided, the phosphoric acid ester being represented by the formula (1): where R1 is an alkyl group, R2 and R3 are each independently an alkylene group, and n is an integer.
    Type: Grant
    Filed: March 17, 2006
    Date of Patent: September 22, 2009
    Assignee: Panasonic Corporation
    Inventors: Shinichi Kawaguchi, Yukihiro Gotanda, Shinichiro Tahara
  • Patent number: 7592102
    Abstract: An electrolyte for a lithium ion secondary battery includes a non-aqueous organic solvent; lithium salt; and difluoro oxalato borate and fluoro ethylene carbonate (FEC). The capacity retention property and durability of a lithium ion secondary battery including the electrolyte is excellent even when the battery is left at a high temperature.
    Type: Grant
    Filed: October 23, 2008
    Date of Patent: September 22, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jinsung Kim, Narae Park, Jinhyunk Lim, Suhee Han, Jinburn Kim, Jungkang Oh
  • Patent number: 7582388
    Abstract: A non-aqueous solvent secondary battery with a high initial charge/discharge capacity and excellent charge/discharge characteristics at high temperature, having a positive electrode containing a positive electrode active material capable of reversibly occluding and releasing lithium, a negative electrode containing a negative electrode active material capable of reversibly occluding and releasing lithium and a non-aqueous solvent electrolyte containing (1) acrylic acid anhydride, and (2) an aromatic compound having at least one electron donating group, wherein the electron donating group comprises at least one member selected from any of the alkyl group, alkoxy group, alkylamino group and amine, provided that each of the alkyl group, alkoxy group and alkylamino group includes a halogen substituted group and a cycloaliphatic group.
    Type: Grant
    Filed: September 9, 2004
    Date of Patent: September 1, 2009
    Assignee: Sanyo Electric Co., Ltd.
    Inventor: Kentaro Takahashi
  • Patent number: 7579118
    Abstract: An organic electrolytic solution includes a lithium salt; an organic solvent including a high dielectric constant solvent and a low boiling point solvent; and an additive of a hetero ring compound including a cyano group and an alkenyl group as substituents. The organic electrolytic solution and the lithium battery employing the organic electrolytic solution suppress the reduction decomposition of a polar solvent to improve the capacity retention ratio of the battery. Thus, the charge/discharge efficiency and lifespan of the battery can be improved.
    Type: Grant
    Filed: June 21, 2006
    Date of Patent: August 25, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Seok-soo Lee, Han-su Kim, Young-gyoon Ryu, Boris Trofimov, Galing Myachina
  • Patent number: 7575833
    Abstract: The invention relates to a nonaqueous electrolyte which comprises a nonaqueous organic solvent and a lithium salt dissolved therein, wherein the nonaqueous organic solvent contains at least one compound selected from the group consisting of acid anhydrides and carbonic esters having an unsaturated bond, and at least one compound selected from the group consisting of sulfonic compounds and fluorine-containing aromatic compounds having 9 carbon atoms or less; and a lithium secondary battery employing the same.
    Type: Grant
    Filed: April 13, 2007
    Date of Patent: August 18, 2009
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Minoru Kotato, Isao Konno, Shinichi Kinoshita
  • Patent number: 7572554
    Abstract: An electrolyte for a battery comprises a lithium organoborate salt in a lactone and a low viscosity solvent. The lithium organoborate salt may comprise LiBOB, or a mono[bidentate]borate salt. The lactone may comprise gamma butyrolactone. The low viscosity solvent may comprise a nitrile, an ether, a linear carbonate, or a linear ester. The electrolyte is suitable for use in lithium ion batteries having graphite negative electrodes. Batteries using this electrolyte have high conductivity, low polarization, and high discharge capacity.
    Type: Grant
    Filed: March 3, 2005
    Date of Patent: August 11, 2009
    Assignee: Quallion LLC
    Inventors: Tsuneaki Koike, Hiroyuki Yumoto, Hisashi Tsukamoto
  • Patent number: 7553588
    Abstract: An electrolyte for a lithium secondary battery includes lithium salts, a non-aqueous organic solvent, and additive compounds. The additive compounds added to the electrolyte of the present invention decompose earlier than the organic solvent to form a conductive polymer layer on the surface of a positive electrode, and prevent decomposition of the organic solvent. Accordingly, the electrolyte inhibits gas generation caused by decomposition of the organic solvent at initial charging, and thus reduces an increase of internal pressure and swelling during high temperature storage, and also improves safety of the battery during overcharge.
    Type: Grant
    Filed: September 10, 2003
    Date of Patent: June 30, 2009
    Assignees: Samsung SDI Co., Ltd., Cheil Industries Inc.
    Inventors: Jin-Hee Kim, Jin-Sung Kim, Sang-Moon Hwang, Meen-Seon Paik, Hak-Soo Kim
  • Patent number: 7553590
    Abstract: Disclosed is an additive for an electrochemical cell wherein the additive includes an N—O bond. The additive is most preferably included in a nonaqueous electrolyte of the cell. Also disclosed are cells and batteries including the additive, and methods of charging the batteries and cells. An electrochemical cell including the additive preferably has an anode that includes lithium and a cathode including an electroactive sulfur-containing material.
    Type: Grant
    Filed: April 7, 2008
    Date of Patent: June 30, 2009
    Assignee: Sion Power Corporation
    Inventor: Yuriy V. Mikhaylik
  • Publication number: 20090142670
    Abstract: Disclosed is an electrolytic solution including an organic solvent, a lithium salt, and an additive. The additive includes maleimide compound and vinylene carbonate. The maleimide compound can be maleimide, bismaleimide, polymaleimide, polybismaleimide, maleimide-bismaleimide copolymer, or combinations thereof. The lithium battery employing the described electrolytic solution has a higher capacity of confirmation, higher cycle efficiency, and longer operational lifespan.
    Type: Application
    Filed: February 25, 2008
    Publication date: June 4, 2009
    Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Fu-Ming Wang, Chang-Rung Yang, Jing-Pin Pan, Hung-Chun Wu
  • Publication number: 20090130566
    Abstract: A non-aqueous electrolyte secondary battery has a high initial capacity and excels in cycle characteristics and storage characteristics even when charged until the potential of the positive electrode active material exceeds as high as 4.3V versus lithium. The non-aqueous electrolyte of the secondary battery contains both 1,3-dioxane and a sulfonic acid ester compound.
    Type: Application
    Filed: November 14, 2008
    Publication date: May 21, 2009
    Applicants: SANYO ELECTRIC CO., LTD., UBE INDUSTRIES, LTD.
    Inventors: Masato IWANAGA, Noriko YAMASHITA, Koji ABE, Kazuhiro MIYOSHI
  • Patent number: 7524588
    Abstract: A nonaqueous secondary battery includes a negative electrode using a negative electrode active material containing a carbonaceous material; a positive electrode using a positive electrode active material capable of reversibly intercalating and deintercalating lithium; and a nonaqueous electrolyte. The nonaqueous electrolyte contains: (1) a vinyl ethylene carbonate derivative represented by Formula (I): wherein R1 to R6 independently represent a hydrogen atom or an alkyl group having a carbon number of 1 to 4; (2) a cyclic acid anhydride; and (3) at least one cyclic ether derivative selected from the group consisting of 1,3-dioxanes, 1,3-dioxolanes and derivatives thereof.
    Type: Grant
    Filed: April 17, 2007
    Date of Patent: April 28, 2009
    Assignee: Sanyo Electric C.o., Ltd.
    Inventor: Kentaro Takahashi
  • Patent number: 7524579
    Abstract: A method for enhancing the performance characteristics of a battery through the use of the electrolyte composition comprised of a non-aqueous solvent, and a salt mixture. The salt mixture includes an alkali metal electrolyte salt and an additive salt having an anion of a mixed anhydride of oxalic acid and boric acid. Specific additive salts include lithium bis(oxalato) borate and lithium oxalyldifluoroborate. Particular electrolyte salts comprise LiPF6 and LiBF4. The additive salt is present in an amount of 0.1-60 mole percent of the total of the additive salt and electrolyte salt content of the electrolyte.
    Type: Grant
    Filed: December 21, 2006
    Date of Patent: April 28, 2009
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: T. Richard Jow, Shengshui Zhang, Kang Xu
  • Patent number: 7514182
    Abstract: An organic electrolytic solution and a rechargeable lithium battery comprising the same is provided. The organic electrolytic solution contains a lithium salt and an organic solvent mixture. The organic solvent mixture is comprised of a solvent with high permittivity, a solvent with a low boiling point, and a cyclic organic compound having at least an oxy-carbonyl group and having a ring structure of 6 units or more. The organic electrolytic solution helps to increase reduction decomposition stability in the lithium battery using the same. As a result, the irreversible capacity of the lithium battery at a first cycle decreases and charge/discharge efficiency and lifespan of the lithium battery increases. In addition, the battery thickness is maintained within a specific range at room temperature after formation and standard charging, which improves the reliability of the lithium battery.
    Type: Grant
    Filed: February 3, 2005
    Date of Patent: April 7, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Han-Su Kim, Jin-Sung Kim, Myung-Dong Cho, Hyo-Sug Lee, Dong-Min Im
  • Patent number: 7507503
    Abstract: The present invention relates to non-aqueous electrolytes having electrode stabilizing additives, stabilized electrodes, and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, and an electrode stabilizing additive. In some embodiments the additives include a substituted or unsubstituted cyclic or spirocyclic hydrocarbon containing at least one oxygen atom and at least one alkenyl or alkynyl group. When used in electrochemical devices with, e.g., lithium manganese oxide spinel electrodes or olivine or carbon-coated olivine electrodes, the new electrolytes provide batteries with improved calendar and cycle life.
    Type: Grant
    Filed: December 8, 2005
    Date of Patent: March 24, 2009
    Assignee: U Chicago Argonne LLC
    Inventors: Khalil Amine, Jun Liu, Donald R. Vissers, Wenquan Lu
  • Patent number: 7504181
    Abstract: Disclosed is a nonaqueous liquid electrolyte comprising a nonaqueous solvent, an electrolyte dissolved in the nonaqueous solvent and a macromolecular material added to the nonaqueous solvent. The nonaqueous liquid electrolyte is a fluid having a viscosity at 20° C. of 7 cP to 30,000 cP. The nonaqueous liquid electrolyte suppresses leakage, ensures high discharge characteristics, reduces the unevenness of liquid electrolyte, and lessens the change of electrodes and the change in battery resistivity.
    Type: Grant
    Filed: May 15, 2007
    Date of Patent: March 17, 2009
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Tatsuoki Kohno, Norio Takami
  • Publication number: 20090053612
    Abstract: A battery capable of improving battery characteristics is provided. The battery includes a cathode, an anode and an electrolytic solution, and a separator arranged between the cathode and the anode is impregnated with the electrolytic solution. The solvent of the electrolytic solution includes a sulfone compound having a sulfonyl fluoride type structure in which a sulfonyl group and a fluorine group are bonded together, and at least one kind selected from the group consisting of a chain carbonate which includes a halogen and a cyclic carbonate which includes a halogen.
    Type: Application
    Filed: July 31, 2008
    Publication date: February 26, 2009
    Applicant: SONY CORPORATION
    Inventors: Masayuki Ihara, Hiroyuki Yamaguchi, Tadahiko Kubota
  • Patent number: 7491471
    Abstract: An electrolyte for a lithium secondary battery which has a non-aqueous organic solvent including a ?-butyrolactone and optionally a cyclic carbonate, an ester compound having an electron withdrawing group, and at least two salts. The lithium secondary battery including the electrolyte has good safety and good storage characteristics at high temperature.
    Type: Grant
    Filed: July 15, 2004
    Date of Patent: February 17, 2009
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Takitaro Yamaguchi, Ryuichi Shimizu, Hyun-Jei Chung, Cheol-Soo Jung, Hyeong-Gon Noh, Eui-Hwan Song, Joong-Hun Kim
  • Patent number: 7438991
    Abstract: The invention provides a non-aqueous electrolyte secondary cell that has high capacity and excels in cycle characteristics. The non-aqueous electrolyte secondary cell functions stably at a high potential of from 4.4 to 4.6 V with respect to lithium and inhibits the decomposition of the electrolytic solution at high potential. This is accomplished as follows. The non-aqueous electrolyte secondary cell has a positive electrode having a positive electrode active material; a negative electrode having a negative electrode active material; and a non-aqueous electrolyte having a non-aqueous solvent and electrolytic salt. The positive electrode active material has: lithium cobalt compound oxide having added therein at least zirconium and magnesium; and lithium-nickel-manganese compound oxide having a layered structure. The positive electrode active material has a potential of from 4.4 to 4.6 V with respect to lithium. The non-aqueous solvent contains diethyl carbonate of 10 vol. % or higher at 25° C.
    Type: Grant
    Filed: November 29, 2005
    Date of Patent: October 21, 2008
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Nobumichi Nishida, Hidetoshi Inoue
  • Publication number: 20080193835
    Abstract: Disclosed is an additive for an electrochemical cell wherein the additive includes an N—O bond. The additive is most preferably included in a nonaqueous electrolyte of the cell. Also disclosed are cells and batteries including the additive, and methods of charging the batteries and cells. An electrochemical cell including the additive preferably has an anode that includes lithium and a cathode including an electroactive sulfur-containing material.
    Type: Application
    Filed: April 18, 2008
    Publication date: August 14, 2008
    Inventor: Yuriy V. Mikhaylik
  • Publication number: 20080193854
    Abstract: An electrolytic solution capable of improving battery characteristics even at high temperature, and a battery using the electrolytic solution are provided. A separator is impregnated with an electrolytic solution. The electrolyic solution includes a cyclic imide salt such as 1,1,2,2,3,3-hexafluoropropane-1,3-disulfonimide lithium and a light metal salt such as difluoro[oxalato-O,O?] lithium borate or bis[oxalato-O,O?] lithium borate. Thereby, the decomposition reaction of the electrolytic solution can be prevented even at high temperature, and the battery characteristics can be improved.
    Type: Application
    Filed: March 12, 2007
    Publication date: August 14, 2008
    Inventors: Akira Yamaguchi, Atsumichi Kawashima, Masayuki Ihara, Hiroshi Horiuchi, Hiroyuki Yamaguchi, Tadahiko Kubota, Kumiko Takagi
  • Publication number: 20080187840
    Abstract: Disclosed is an additive for an electrochemical cell wherein the additive includes an N—O bond. The additive is most preferably included in a nonaqueous electrolyte of the cell. Also disclosed are cells and batteries including the additive, and methods of charging the batteries and cells. An electrochemical cell including the additive preferably has an anode that includes lithium and a cathode including an electroactive sulfur-containing material.
    Type: Application
    Filed: April 7, 2008
    Publication date: August 7, 2008
    Inventor: Yuriy V. Mikhaylik
  • Patent number: 7402260
    Abstract: A non-aqueous mixture solvent for a non-aqueous electrolytic solution to be used for electrochemical energy devices, which contains an aprotic solvent, and a fluorinated ketone of the formula: (wherein Rf1 and Rf2 each independently represents a fluorinated aliphatic group, or Rf1 and Rf2 together form a cyclic group, Q represents a fluorinated or non-fluorinated alkylene group or a bond, and n represents 0 or 1), and an electrolytic solution containing the mixture solvent.
    Type: Grant
    Filed: March 22, 2005
    Date of Patent: July 22, 2008
    Assignee: 3M Innovative Properties Company
    Inventors: Haruki Segawa, Hideto Yanome
  • Patent number: 7399554
    Abstract: A hybrid rechargeable lithium battery, which includes a plurality of high power rechargeable cells, having nano-particles therein, and high energy density rechargeable cells, with the high energy cells recharging the high power cells. The battery preferably includes a low volt parallel charger to simultaneously and individually charge both the high power and high energy cells, through a protective device. All cells are then discharged in series at high voltage, and are individually protected from over discharge. A rechargeable battery having both high power and high energy density cells is thus provided.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: July 15, 2008
    Inventor: Joseph B. Kejha
  • Publication number: 20080166637
    Abstract: A nonaqueous electrolyte battery includes a positive electrode, a negative electrode and a nonaqueous electrolyte. The negative electrode contains a titanium-containing oxide. The nonaqueous electrolyte contains a compound having a functional group represented by the formula (1) below and a sultone having an unsaturated hydrocarbon group. [Chem.
    Type: Application
    Filed: December 27, 2007
    Publication date: July 10, 2008
    Inventors: Hiroki INAGAKI, Yumi Fujita, Norio Takami
  • Publication number: 20080153006
    Abstract: A non-aqueous electrolyte for a lithium battery includes a non-aqueous organic solvent, the organic solvent including one or more of a carbonate-based solvent, an ester-based solvent, an ether-based solvent, and/or a ketone-based solvent, a lithium salt, and a hexafluoroacetylacetone in an amount of about 0.02 parts by weight to about 10 parts by weight, based on 100 parts by weight of the non-aqueous organic solvent.
    Type: Application
    Filed: December 17, 2007
    Publication date: June 26, 2008
    Inventors: Jung Kang Oh, Young Jai Cho, Ho Seok Yang, Kab Youl Lee
  • Patent number: 7384708
    Abstract: A non-aqueous electrolyte battery of the present invention includes a non-aqueous electrolyte containing a lithium salt, a cyclic sultone derivative, and an acid anhydride, wherein the non-aqueous electrolyte contains the cyclic sultone derivative in an amount of 0.3 to 3% by mass and the non-aqueous electrolyte contains the acid anhydride in an amount of 0.3 to 3% by mass. Furthermore, the non-aqueous electrolyte battery includes at least one selected from a cyclic sultone derivative and an acid anhydride, and an electrolyte salt. The electrolyte salt contains lithium salt A and lithium salt B. The lithium salt A is at least one selected from LiBF4, LiPF6, LiAsF6, and LiSbF6, and the lithium salt B is a lithium salt other than the lithium salt A. The electrolyte contains the lithium salt A in an amount of 2 mol % or more.
    Type: Grant
    Filed: January 13, 2006
    Date of Patent: June 10, 2008
    Assignee: Hitachi Maxell, Ltd.
    Inventors: Tetsuo Kawai, Atsushi Yamano, Noriyuki Yabushita, Tadashi Sakata, Hideki Nishihama
  • Patent number: 7378190
    Abstract: Storage performance in a charged state is improved with a non-aqueous electrolyte secondary battery using gamma-butyrolactone as a solvent. A non-aqueous electrolyte secondary battery includes a positive electrode (2) containing a positive electrode active material including a lithium-containing transition metal oxide; a negative electrode (1) containing a negative electrode active material capable of intercalating and deintercalating lithium; and a non-aqueous electrolyte including a solute and a solvent; wherein the solvent contains 50 volume % or more of gamma-butyrolactone with respect to the total volume of the solvent, and the positive electrode active material contains a phosphate salt M1PO4, where M1 is a metal element capable of having a valency of 3.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: May 27, 2008
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Atsushi Yanai, Yoshinori Kida, Toshiyuki Nohma
  • Patent number: 7358012
    Abstract: Disclosed is an electrochemical cell comprising a lithium anode and a sulfur-containing cathode and a non-aqueous electrolyte. The cell exhibits high utilization of the electroactive sulfur-containing material of the cathode and a high charge-discharge efficiency.
    Type: Grant
    Filed: January 6, 2004
    Date of Patent: April 15, 2008
    Assignee: Sion Power Corporation
    Inventor: Yuriy V. Mikhaylik
  • Patent number: 7354680
    Abstract: Disclosed is an additive for an electrochemical cell wherein the additive includes an N—O bond. The additive is most preferably included in a nonaqueous electrolyte of the cell. Also disclosed are cells and batteries including the additive, and methods of charging the batteries and cells. An electrochemical cell including the additive preferably has an anode that includes lithium and a cathode including an electroactive sulfur-containing material.
    Type: Grant
    Filed: January 6, 2004
    Date of Patent: April 8, 2008
    Assignee: Sion Power Corporation
    Inventor: Yuriy V. Mikhaylik
  • Publication number: 20080026290
    Abstract: A battery includes an anode including an alkali metal as the active material, a cathode having, for example, iron disulfide as the active material, and an electrolyte including an organic solvent and an aluminum salt selected from the group consisting of aluminum iodide and aluminum tri(sec-butoxide).
    Type: Application
    Filed: July 27, 2006
    Publication date: January 31, 2008
    Inventors: Zhiping Jiang, William L. Bowden, Leslie J. Pinnell, Michael Pozin, Nikolai N. Issaev
  • Publication number: 20080026296
    Abstract: A battery includes an anode having a lithium alloy as the active material, a cathode having, for example, iron disulfide as the active material, and an electrolyte containing a sulfolane and 1,2-dimethoxyethane.
    Type: Application
    Filed: July 27, 2006
    Publication date: January 31, 2008
    Inventors: William L. Bowden, Todd E. Bofinger, David Leigh DeMuth, Rimma A. Sirotina
  • Patent number: 7316868
    Abstract: Disclosed is an electrolyte for an electrochemical cell wherein the electrolyte includes a solvent mixture comprising a dioxolane and one or more of 1,2-dialkoxyalkanes of 5 or 6 carbon atoms and/or 1,3-dialkoxyalkanes of 5 or 6 carbon atoms. Also disclosed are cells and batteries including the electrolyte. An electrochemical cell including the electrolyte preferably has an anode that includes lithium and a cathode including an electroactive sulfur-containing material.
    Type: Grant
    Filed: February 11, 2004
    Date of Patent: January 8, 2008
    Assignee: Sion Power Corporation
    Inventor: Alexander Gorkovenko
  • Patent number: 7312001
    Abstract: A non-aqueous electrolytic solution and a lithium battery employing the same are provided. The non-aqueous electrolyte solution that contains a substituted or unsubstituted acetate can effectively stabilize lithium metal and improve the conductivity of lithium ions.
    Type: Grant
    Filed: September 25, 2003
    Date of Patent: December 25, 2007
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Ju-yup Kim, Myung-dong Cho, Young-gyoon Ryu
  • Publication number: 20070281217
    Abstract: An electrolyte and battery using same is provided. The electrolyte comprising at least one of a compound represented by Formula 1, wherein, R1, P2, R3, and R4 represent a hydrogen group, or a methyl group and an ethyl group; X, Y, and Z represent sulfur (S) or oxygen (O) or Formula 2, wherein, R1 and R2 represent a hydrogen group, a halogen group, or a methyl group and an ethyl group, or groups in which a part of hydrogen thereof is substituted by a halogen group; X, Y, and Z represent sulfur (S) or oxygen (O), which can retain chemical stability at high temperatures. Use of the electrolyte allows a battery to have excellent characteristics in a hot environment.
    Type: Application
    Filed: June 4, 2007
    Publication date: December 6, 2007
    Applicant: SONY CORPORATION
    Inventors: Masayuki IHARA, Hiroyuki YAMAGUCHI, Tadahiko KUBOTA
  • Publication number: 20070275306
    Abstract: Organic electrolytic solutions and lithium batteries using the organic electrolytic solutions are provided. One organic electrolytic solution includes a lithium salt, a mixed organic solvent consisting of a high-dielectric constant solvent and a low-boiling point solvent, and a compound represented by Formula 1 or 2 as an additive. The organic electrolytic solution and the lithium battery using the organic electrolytic solution may inhibit the reductive cleavage reaction of a polar solvent, thereby increasing capacity retention of the battery, and improving charge-discharge efficiency and battery lifetime.
    Type: Application
    Filed: January 12, 2007
    Publication date: November 29, 2007
    Inventors: Seok-soo Lee, Young-gyoon Ryu, Han-su Kim
  • Patent number: 7297447
    Abstract: A non-aqueous electrolyte battery of the present invention includes a non-aqueous electrolyte containing a lithium salt, a cyclic sultone derivative, and an acid anhydride, wherein the non-aqueous electrolyte contains the cyclic sultone derivative in an amount of 0.3 to 3% by mass and the non-aqueous electrolyte contains the acid anhydride in an amount of 0.3 to 3% by mass. Furthermore, the non-aqueous electrolyte battery includes at least one selected from a cyclic sultone derivative and an acid anhydride, and an electrolyte salt. The electrolyte salt contains lithium salt A and lithium salt B. The lithium salt A is at least one selected from LiBF4, LiPF6, LiAsF6, and LiSbF6, and the lithium salt B is a lithium salt other than the lithium salt A. The electrolyte contains the lithium salt A in an amount of 2 mol % or more.
    Type: Grant
    Filed: December 10, 2002
    Date of Patent: November 20, 2007
    Assignee: Hitachi Maxell, Ltd.
    Inventors: Tetsuo Kawai, Atsushi Yamano, Noriyuki Yabushita, Tadashi Sakata, Hideki Nishihama
  • Patent number: 7294436
    Abstract: In order to manufacture a lithium secondary battery having excellent performances in safety under overcharge condition, cycle property, electric capacity, and storage endurance, 0.1 wt. % to 10 wt. % of a tert-alkylbenzene compound is favorably incorporated into a non-aqueous electrolytic solution comprising a non-aqueous solvent and an electrolyte, preferably in combination with 0.1 wt. % to 1.5 wt. % of a biphenyl compound.
    Type: Grant
    Filed: January 24, 2002
    Date of Patent: November 13, 2007
    Assignee: Ube Industries, Ltd.
    Inventors: Koji Abe, Yasuo Matsumori
  • Patent number: 7285362
    Abstract: An ion transporting solvent maintains very low vapor pressure, contains flame retarding elements, and is nontoxic. The solvent in combination with common battery electrolyte salts can be used to replace the current carbonate electrolyte solution, creating a safer battery. It can also be used in combination with polymer gels or solid polymer electrolytes to produce polymer batteries with enhanced conductivity characteristics. The solvents may comprise a class of cyclic and acyclic low molecular weight phosphazenes compounds, comprising repeating phosphorus and nitrogen units forming a core backbone and ion-carrying pendent groups bound to the phosphorus. In preferred embodiments, the cyclic phosphazene comprises at least 3 phosphorus and nitrogen units, and the pendent groups are polyethers, polythioethers, polyether/polythioethers or any combination thereof, and/or other groups preferably comprising other atoms from Group 6B of the periodic table of elements.
    Type: Grant
    Filed: May 17, 2004
    Date of Patent: October 23, 2007
    Assignee: Battelle Energy Alliance, LLC
    Inventors: Mason K. Harrup, Joseph R. Delmastro, Frederick F. Stewart, Thomas A. Luther
  • Patent number: 7285361
    Abstract: A non-aqueous secondary battery includes a positive electrode, a negative electrode, and a non-aqueous electrolyte solution where the non-aqueous electrolyte solution contains a compound A in which a halogen group is bonded to a benzene ring and a compound B oxidized at a potential lower than that of the compound A, and the compound B is at least one selected from an aromatic compound and a heterocyclic compound. Thus, a non-aqueous secondary battery having excellent overcharging safety and being capable of ensuring storage reliability with less generation of gas during storage at a high temperature can be provided.
    Type: Grant
    Filed: April 6, 2006
    Date of Patent: October 23, 2007
    Assignee: Hitachi Maxell, Ltd.
    Inventors: Fusaji Kita, Hideo Sakata, Haruki Kamizori
  • Publication number: 20070243471
    Abstract: A nonaqueous secondary battery includes a negative electrode using a negative electrode active material containing a carbonaceous material; a positive electrode using a positive electrode active material capable of reversibly intercalating and deintercalating lithium; and a nonaqueous electrolyte. The nonaqueous electrolyte contains: (1) a vinyl ethylene carbonate derivative represented by Formula (I): wherein R1 to R6 independently represent a hydrogen atom or an alkyl group having a carbon number of 1 to 4; (2) a cyclic acid anhydride; and (3) at least one cyclic ether derivative selected from the group consisting of 1,3-dioxanes, 1,3-dioxolanes and derivatives thereof.
    Type: Application
    Filed: April 17, 2007
    Publication date: October 18, 2007
    Applicant: SANYO ELECTRIC CO., LTD.
    Inventor: Kentaro Takahashi
  • Patent number: 7282304
    Abstract: A non-aqueous electrolyte battery of the present invention includes a non-aqueous electrolyte containing a lithium salt, a cyclic sultone derivative, and an acid anhydride, wherein the non-aqueous electrolyte contains the cyclic sultone derivative in an amount of 0.3 to 3% by mass and the non-aqueous electrolyte contains the acid anhydride in an amount of 0.3 to 3% by mass. Furthermore, the non-aqueous electrolyte battery includes at least one selected from a cyclic sultone derivative and an acid anhydride, and an electrolyte salt. The electrolyte salt contains lithium salt A and lithium salt B. The lithium salt A is at least one selected from LiBF4, LiPF6, LiAsF6, and LiSbF6, and the lithium salt B is a lithium salt other than the lithium salt A. The electrolyte contains the lithium salt A in an amount of 2 mol % or more.
    Type: Grant
    Filed: February 14, 2006
    Date of Patent: October 16, 2007
    Assignee: Hitachi Maxell, Ltd.
    Inventors: Tetsuo Kawai, Atsushi Yamano, Noriyuki Yabushita, Tadashi Sakata, Hideki Nishihama