Fuel Cell With Solid Electrolyte Patents (Class 429/479)
  • Patent number: 10431839
    Abstract: A method of production of a channel member for fuel cell use comprising a step of obtaining a sheet-shaped first conductor part 11 containing a carbon material of at least one of carbon nanotubes, granular graphite, and carbon fibers and a first resin, a step of laying a sheet-shaped second conductor part 21 containing a carbon material and a second resin with a lower melting point than the first resin to form a sheet-shaped base part 13, a step of transferring a grooved surface 51 to a surface to form a grooved base part 16 provided with groove part 15, a step of laying a sheet-shaped third conductor part 31 containing a carbon material and a third resin with a lower melting point than the first resin, and a step of integrally joining the grooved base part and the third conductor part by hot melt bonding to cover the groove parts.
    Type: Grant
    Filed: November 2, 2015
    Date of Patent: October 1, 2019
    Assignee: FUTAMURA KAGAKU KABUSHIKI KAISHA
    Inventors: Takuzo Imaizumi, Naomi Goto, Naoki Shiba
  • Patent number: 10263272
    Abstract: A gas passage forming body for a fuel battery includes gas passages and water guide passages. A communication passage is arranged between one of the water guide passages and a gas passage that is adjacent to the water guide passage and is in communication with the adjacent gas passage and water guide passage to permit water to move therethrough. An aid portion is arranged at water drainage ends of two adjacent ones of the water guide passages and aids bonding of water drained from the water drainage ends of the two adjacent ones of the water guide passages. Thus, water drainage from the water guide passages of the gas passage forming body is improved, and water in the gas passages is reduced. As a result, the battery performance of the fuel battery is improved due to an improvement in gas diffusion.
    Type: Grant
    Filed: January 23, 2014
    Date of Patent: April 16, 2019
    Assignee: Toyota Shatai Kabushiki Kaisha
    Inventors: Keiji Hashimoto, Kousuke Kawajiri, Satoshi Futami
  • Patent number: 10020122
    Abstract: A symmetric hybrid supercapacitor has two internally hybridized electrodes having both faradic and capacitatively active materials. More specifically, the symmetric hybrid supercapacitor has a cathode and an anode. The cathode contains LiMnxFe1-xPO4. The LiMnxFe1-xPO4 is used as electrode material for the hybrid supercapacitor. The condition applies that 0.1<x<0.9.
    Type: Grant
    Filed: September 23, 2016
    Date of Patent: July 10, 2018
    Assignee: Robert Bosch GmbH
    Inventors: Severin Hahn, Elisabeth Buehler, Pallavi Verma
  • Patent number: 10006363
    Abstract: An electrical power system for an aircraft including a turbine engine coupled to the aircraft and providing propulsive thrust and emitting heat during operation to define a high temperature source, a cryogenic fuel system located within the aircraft and providing fuel for the turbine and emitting heat at a lower temperature than the heat from the turbine engine to define a low temperature source and an electrical power generator located on the aircraft and having a thermodynamic generator using the temperature difference to generate electrical power and a method for producing electric power.
    Type: Grant
    Filed: November 26, 2013
    Date of Patent: June 26, 2018
    Assignee: General Electric Company
    Inventors: Adon Delgado, Jr., Todd James Buchholz, Christopher Dale Mathias
  • Patent number: 9943841
    Abstract: A method to manufacture an ion exchange membrane involves treatment of the membrane in a strong base to strengthen the membrane, decrease the membrane solubility, and create linkages that can be detected by analysis using two-dimensional nuclear magnetic resonance (NMR).
    Type: Grant
    Filed: January 20, 2017
    Date of Patent: April 17, 2018
    Assignee: Dioxide Materials, Inc.
    Inventors: Richard I. Masel, Syed Dawar Sajjad, Mark J. Pellerite
  • Patent number: 9914649
    Abstract: A composition of matter is disclosed which is a perovskite having a composition A2?xA?xB2?yB?yO6??, where A is a praseodymium (Pr) element at the A-site of the perovskite, A? is a strontium (Sr) element at the A-site of the perovskite, B is a cobalt (Co) element at the B-site of the perovskite, and B? is a manganese (Mn) element at the B-site of the perovskite, and where 0<x ?1 and 0<y<2. Also disclosed is an electrode material Conformally coated with the composition of matter. Also disclosed are methods of producing the composition of matter and conformally coating the electrode material. Also disclosed an electrode is conformally coated with a praseodymium strontium manganese perovskite and a method for the coating.
    Type: Grant
    Filed: May 8, 2015
    Date of Patent: March 13, 2018
    Assignee: Georgia Tech Research Corporation
    Inventors: Dong Ding, Meilin Liu
  • Patent number: 9911982
    Abstract: A method for making a fibrous layer for fuel cell applications includes a step of combining a perfluorocyclobutyl-containing resin with a water soluble carrier resin to form a resinous mixture. The resinous mixture is then shaped to form a shaped resinous mixture. The shaped resinous mixture includes perfluorocyclobutyl-containing structures within the carrier resin. The shaped resinous mixture is contacted (i.e., washed) with water to separate the perfluorocyclobutyl-containing structures from the carrier resin. Optional protogenic groups and then a catalyst are added to the perfluorocyclobutyl-containing structures.
    Type: Grant
    Filed: October 16, 2015
    Date of Patent: March 6, 2018
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: James Mitchell, Timothy J. Fuller, Lijun Zou
  • Patent number: 9899687
    Abstract: The present invention discloses a process for the synthesis of nitrogen-doped carbon electrocatalyst with good electrochemical stability and fuel tolerance for oxygen reduction reaction (ORR) by pyrolysis of protein-rich pulse flour cooked with SiO2 nanoparticles.
    Type: Grant
    Filed: September 2, 2014
    Date of Patent: February 20, 2018
    Assignee: COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH
    Inventors: Rohan Gokhale, Sreekuttan Maraveedu Unni, Kurungot Sreekumar, Satishchandra Balkrishna Ogale
  • Patent number: 9849450
    Abstract: An anion-conducting polymeric membrane comprises a terpolymer of styrene, vinylbenzyl-Rs and vinylbenzyl-Rx. Rs is a positively charged cyclic amine group. Rx is at least one constituent selected from the group consisting Cl, OH and a reaction product between an OH or Cl and a species other than a simple amine or a cyclic amine. The total weight of the vinylbenzyl-Rx groups is greater than 0.3% of the total weight of the membrane. In a preferred embodiment, the membrane is a Helper Membrane that increases the faradaic efficiency of an electrochemical cell into which the membrane is incorporated, and also allows product formation at lower voltages than in cells without the Helper Membrane.
    Type: Grant
    Filed: January 6, 2017
    Date of Patent: December 26, 2017
    Assignee: Dioxide Materials, Inc.
    Inventors: Richard I. Masel, Syed Dawar Sajjad, Yan Gao, Zengcai Liu, Qingmei Chen
  • Patent number: 9806346
    Abstract: Disclosed is a homogeneous catalyst having a single phase of Perovskite oxide, wherein at least one doping element is substituted at site A, site B or sites A and B in ABO3 Perovskite type oxide so that the wettability with a liquid molten carbonate electrolyte may be decreased. The catalyst may have high catalytic activity, inhibit catalyst poisoning caused by creepage and evaporation of a liquid molten carbonate electrolyte, maintain high reaction activity for a long time, provide high methane conversion, and allow production of synthetic gas having a high proportion of hydrogen.
    Type: Grant
    Filed: July 6, 2015
    Date of Patent: October 31, 2017
    Assignee: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Sung Pil Yoon, Hyoung-Juhn Kim, Chang Won Yoon, Seong Cheol Jang, Sun-Hee Choi, Jonghee Han, Hyung Chul Ham
  • Patent number: 9779884
    Abstract: Capacitors having electrodes made of interconnected corrugated carbon-based networks (ICCNs) are disclosed. The ICCN electrodes have properties that include high surface area and high electrical conductivity. Moreover, the electrodes are fabricated into an interdigital planar geometry with dimensions that range down to a sub-micron scale. As such, micro-supercapacitors employing ICCN electrodes are fabricated on flexible substrates for realizing flexible electronics and on-chip applications that can be integrated with micro-electromechanical systems (MEMS) technology and complementary metal oxide semiconductor technology in a single chip. In addition, capacitors fabricated of ICCN electrodes that sandwich an ion porous separator realize relatively thin and flexible supercapacitors that provide compact and lightweight yet high density energy storage for scalable applications.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: October 3, 2017
    Assignee: The Regents of the University of California
    Inventors: Maher F. El-Kady, Veronica A. Strong, Richard B. Kaner
  • Patent number: 9646820
    Abstract: The present disclosure relates to the deposition of conductive titanium oxide films by atomic layer deposition processes. Amorphous doped titanium oxide films are deposited by ALD processes comprising titanium oxide deposition cycles and dopant oxide deposition cycles and are subsequently annealed to produce a conductive crystalline anatase film. Doped titanium oxide films may also be deposited by first depositing a doped titanium nitride thin film by ALD processes comprising titanium nitride deposition cycles and dopant nitride deposition cycles and subsequently oxidizing the nitride film to form a doped titanium oxide film. The doped titanium oxide films may be used, for example, in capacitor structures.
    Type: Grant
    Filed: December 15, 2014
    Date of Patent: May 9, 2017
    Assignee: ASM INTERNATIONAL N.V.
    Inventors: Viljami Pore, Mikko Ritala, Markku Leskela
  • Patent number: 9640825
    Abstract: A fuel cell includes an anode, a solid electrolyte layer, a barrier layer, and a cathode. The anode includes a transition metal and an oxygen ion conductive material. In the interface region within 3 micrometers from the interface with the solid electrolyte layer of the anode after reduction, the content rate of silicon is less than or equal to 200 ppm, the content rate of phosphorous is less than or equal to 50 ppm, the content rate of chromium is less than or equal to 100 ppm, the content rate of boron is less than or equal to 100 ppm, and the content rate of sulfur is less than or equal to 100 ppm.
    Type: Grant
    Filed: March 18, 2015
    Date of Patent: May 2, 2017
    Assignee: NGK INSULATORS, LTD.
    Inventors: Yohei Miura, Makoto Ohmori, Ayano Kobayashi, Takafumi Terahai
  • Patent number: 9570757
    Abstract: Provided is a fuel cell catalyst layer which has a catalytic performance equivalent to or higher than fuel cell catalyst layers containing platinum alone and which is inexpensive. The fuel cell catalyst layer of the present invention includes a metal oxycarbonitride-containing layer (I) and a platinum-containing layer (II). It is preferable that the mass ratio per unit area of the metal oxycarbonitride in the layer (I) to platinum in the layer (II) (metal oxycarbonitride/platinum) is 2 to 500. It is preferable that the mass per unit area of platinum in the layer (II) is 0.005 to 0.2 mg/cm2.
    Type: Grant
    Filed: September 9, 2011
    Date of Patent: February 14, 2017
    Assignee: SHOWA DENKO K.K.
    Inventors: Yasuaki Wakizaka, Ryuji Monden, Takuya Imai, Hiroshi Nakajima
  • Patent number: 9496561
    Abstract: Provided is an electrode catalyst that can exhibit sufficient performance, is suitable for mass production, and is suitable for reducing production costs, even when containing a relatively high concentration of chlorine. The electrode catalyst has a core-shell structure including a support; a core part that is formed on the support; and a shell part that is formed so as to cover at least one portion of the surface of the core part. The electrode catalyst concurrently fulfills conditions expressed by the following formulae (1) and (2): (X1/M)?1.2 . . . (1) (X2/M)?47.0 . . . (2) (in the formula (1) and the formula (2), M represents an amount of substance (number of atoms) of one or more constituent metal elements of the shell part, X1 represents an amount of substance (number of atoms) of bromine (Br), and X2 represents an amount of substance (number of atoms) of chlorine (Cl)).
    Type: Grant
    Filed: March 27, 2015
    Date of Patent: November 15, 2016
    Assignee: N.E. CHEMCAT CORPORATION
    Inventors: Kiyotaka Nagamori, Tomoteru Mizusaki, Yoko Nakamura, Takuya Tsubaki, Hiroshi Igarashi, Yasuhiro Seki
  • Patent number: 9461313
    Abstract: Provided is an electrode catalyst that can exhibit sufficient performance, is suitable for mass production, and is suitable for reducing production costs, even when containing a relatively high concentration of chlorine. The electrode catalyst has a core-shell structure including a support; a core part that is formed on the support; and a shell part that is formed so as to cover at least one portion of the surface of the core part. The electrode catalyst concurrently fulfills conditions expressed by the following formulae (1) and (2): (X1/M)?1.2 . . . (1) (X2/M)?47.0 . . . (2) (in the formula (1) and the formula (2), M represents an amount of substance (number of atoms) of one or more constituent metal elements of the shell part, X1 represents an amount of substance (number of atoms) of bromine (Br), and X2 represents an amount of substance (number of atoms) of chlorine (Cl)).
    Type: Grant
    Filed: March 27, 2015
    Date of Patent: October 4, 2016
    Assignee: N.E. CHEMCAT CORPORATION
    Inventors: Kiyotaka Nagamori, Tomoteru Mizusaki, Yoko Nakamura, Takuya Tsubaki, Hiroshi Igarashi, Yasuhiro Seki
  • Patent number: 9350035
    Abstract: Crosslinked polymers are produced by polymerizing a styrene-based comonomer with a bifunctional styrenated crosslinkable monomer comprising the following straight chain formula: CH2?CH—C6H4—CH2—(OCH2CH2)n—O—CH2—C6H4—CH?CH2. The styrenated crosslinkable monomer can be produced from a two arm polyethylene glycol having a molecular weight between 200 g/mol and 35,000 g/mol. The styrenated crosslinkable monomer can also be produced from a two arm polyethylene oxide having a molecular weight between 100 kg/mol and 800 kg/mol. The styrenated crosslinkable monomer can also be produced from a four arm polyethylene glycol. Polymer electrolyte membranes are produced from the crosslinked polymers.
    Type: Grant
    Filed: July 30, 2014
    Date of Patent: May 24, 2016
    Assignee: NISSAN NORTH AMERICA, INC.
    Inventor: Rameshwar Yadav
  • Patent number: 9276294
    Abstract: A method of making a molten sodium battery is disclosed. A first metallic interconnect frame having a first interconnect vent hole is provided. A second metallic interconnect frame having a second interconnect vent hole is also provided. An electrolyte plate having a cathode vent hole and an anode vent hole is interposed between the metallic interconnect frames. The metallic interconnect frames and the electrolyte plate are sealed thereby forming gaseous communication between an anode chamber through the anode vent hole and gaseous communication between a cathode chamber through the cathode vent hole.
    Type: Grant
    Filed: September 27, 2011
    Date of Patent: March 1, 2016
    Assignee: BATTELLE MEMORIAL INSTITUTE
    Inventors: John P. Lemmon, Kerry D. Meinhardt
  • Patent number: 9243012
    Abstract: A phosphorous containing benzoxazine-based monomer, or a polymer thereof.
    Type: Grant
    Filed: May 23, 2012
    Date of Patent: January 26, 2016
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Seongwoo Choi, Jungock Park, Wonmok Lee
  • Patent number: 9059470
    Abstract: A cathode for a fuel cell includes a gas diffusion layer contacting with a separator having a channel and a catalyst layer interposed between the gas diffusion layer and an electrolyte membrane. The catalyst layer of the cathode has two portions with different water-repelling properties, and a portion of the catalyst layer that does not face a channel has a higher water-repelling property than a portion that faces a channel. This cathode controls a water-repelling property of the catalyst layer differently according to locations, so it is possible to keep an amount of moisture in an electrode in a suitable way and to restrain generation of flooding, thereby improving the performance of the cell.
    Type: Grant
    Filed: May 9, 2013
    Date of Patent: June 16, 2015
    Assignee: LG CHEM, LTD.
    Inventors: Hyuk Kim, Won-Ho Lee, Chang-Song Lee, Seong-Uk Jeong, Sang-Hyun Lee
  • Patent number: 9029042
    Abstract: This invention provides a redox fuel cell comprising an anode and a cathode separated by an ion selective polymer electrolyte membrane; means for supplying a fuel to the anode region of the cell; means for supplying an oxidant to the cathode region of the cell; means for providing an electrical circuit between the anode and the cathode; a non-volatile catholyte solution flowing fluid communication with the cathode, the catholyte solution comprising a polyoxometallate redox couple being at least partially reduced at the cathode in operation of the cell, and at least partially re-generated by reaction with the oxidant after such reduction at the cathode, the catholyte solution comprising at least one counterion for the polyoxometallate redox couple wherein the at least one counterion comprises one or more divalent ions.
    Type: Grant
    Filed: September 24, 2008
    Date of Patent: May 12, 2015
    Assignee: Acal Energy Limited
    Inventors: Andrew Martin Creeth, Andrew Robert Potter, Kathryn Knuckey
  • Patent number: 9029041
    Abstract: To an internal vessel that houses cells of a solid oxide fuel cell, an external vessel is further disposed. In the internal vessel, a plurality of planar cells is disposed vertically with a gap between the cells, a mixed gas of a fuel and air is descended from top down through the gap having a predetermined width between the cells, and, at a bottom portion of the housing space, the mixed gas is burned to generate electricity.
    Type: Grant
    Filed: May 22, 2007
    Date of Patent: May 12, 2015
    Assignee: Shinko Electric Industries Co., Ltd.
    Inventors: Michio Horiuchi, Yasue Tokutake, Shigeaki Suganuma, Jun Yoshiike, Fumimasa Katagiri
  • Publication number: 20150125780
    Abstract: A sealant for forming a seal between at least two solid oxide fuel cell components wherein the sealant comprises a glass material comprising B2O3 as a principal glass former, BaO, and other components and wherein the glass material is substantially alkali-free and contains less than 30% crystalline material.
    Type: Application
    Filed: July 23, 2013
    Publication date: May 7, 2015
    Applicants: THE CURATORS OF THE UNIVERSITY OF MISSOURI, MO-SCI CORPORATION
    Inventors: Cheol Woon Kim, Richard K. Brow
  • Publication number: 20150125718
    Abstract: An electric field activated fuel cell. Electrodes have sharp tips and are subjected to electric fields to generate ions. Ion conductive media may include polar solvents, liquid electrolytes, solid electrolytes and nonpolar solvent with phase transfer catalysts. Charge leaks preferentially from sharp electrode surface tips. Ionized fluid atoms and molecules migrate across the ion conductive media, leading to reaction completion and newly formed products.
    Type: Application
    Filed: November 6, 2013
    Publication date: May 7, 2015
    Inventor: Mark Minto
  • Patent number: 9023547
    Abstract: A separator of a fuel cell includes a sandwiching section, first and second bridges connected to the sandwiching section, a fuel gas supply section connected to the first bridge and an oxygen-containing gas supply section connected to the second bridge. The sandwiching section sandwiches an electrolyte electrode assembly, and has a fuel gas channel and an oxygen-containing gas channel separately. In the sandwiching section, a plurality of first projections are arranged in a zigzag pattern in a direction in which the first bridge extends, and the first projections at least protrude toward the fuel gas channel to contact an anode.
    Type: Grant
    Filed: May 8, 2009
    Date of Patent: May 5, 2015
    Assignee: Honda Motor Co., Ltd.
    Inventors: Hiroki Homma, Tsutomu Takahashi, Tetsuya Ogawa
  • Patent number: 9023555
    Abstract: A monolithic fuel cell device is provided by forming anode and cathode layers by dispensing paste of anode or cathode material around pluralities of spaced-apart removable physical structures to at least partially surround the structures with the anode or cathode material and then drying the paste. An electrolyte layer is provided in a multi-layer stack between the cathode layer and the anode layer thereby forming an active cell portion. The multi-layer stack is laminated, and then the physical structures are pulled out to reveal spaced-apart active passages formed through each of the anode layer and cathode layer. Finally, the laminated stack is sintered to form an active cell comprising the spaced apart active passages embedded in and supported by the sintered anode material and sintered cathode material.
    Type: Grant
    Filed: February 21, 2013
    Date of Patent: May 5, 2015
    Inventors: Alan Devoe, Lambert Devoe
  • Publication number: 20150111126
    Abstract: The high current density performance of solid polymer electrolyte fuel cells using certain alloy catalyst compositions can be improved via appropriate treatment of the catalyst composition with a fluoro-phosphonic acid compound. In particular, fuel cells employing carbon supported Pt—Co cathode catalyst compositions with relatively high Co content benefit by treating the catalyst composition with 2-(perfluorohexyl) ethyl phosphonic acid.
    Type: Application
    Filed: October 10, 2014
    Publication date: April 23, 2015
    Inventors: Rajesh Bashyam, Prasanna Mani
  • Publication number: 20150111125
    Abstract: Alignment features and methods for their use are disclosed for purposes of aligning adjacent bipolar plates, and also optionally the membrane electrode assemblies as well as the plates making up the bipolar plates, during assembly of solid polymer electrolyte fuel cell stacks. The alignment features are located within common datum openings and advantageously can be in-plane with the bipolar plates. This provides for improved alignment and manufacturability.
    Type: Application
    Filed: October 16, 2014
    Publication date: April 23, 2015
    Inventor: Simon Farrington
  • Patent number: 9005844
    Abstract: On each of upper and lower surfaces of a flat-plate-like support substrate having a longitudinal direction and having fuel gas flow channels formed therein, a plurality of power-generating elements A connected electrically in series are disposed at predetermined intervals along the longitudinal direction. On each of the upper and lower surfaces of the support substrate, a plurality of recesses are formed at predetermined intervals along the longitudinal direction. Each of the recesses is a rectangular-parallelepiped-like depression defined by four side walls arranged in a circumferentially closed manner and a bottom wall. That is, in the support substrate, frames are formed to surround the respective recesses. Fuel electrodes of the power-generating elements A are embedded in the respective recesses.
    Type: Grant
    Filed: July 8, 2011
    Date of Patent: April 14, 2015
    Assignee: NGK Insulators, Ltd.
    Inventors: Makoto Ohmori, Takashi Ryu, Toshiaki Kuno, Tadashi Otagiri
  • Patent number: 9006300
    Abstract: A method for the production of a mechanically stabilized polyazole polymer membrane or film having the following steps: a) providing a membrane or film containing i.) a polyazole with at least one amino group in a repeating unit except the ones obtained by reacting aromatic and/or heteroaromatic diaminocarboxylic acids, ii.) at least one strong acid and iii.) at least one stabilizing reagent, the total content of stabilizing reagents in the membrane or film being within the range of from 0.01 to 30% by weight, b) performing the stabilization reaction in the membrane, immediately or in a subsequent processing step of the membrane, c) optionally doping the membrane obtained in accordance with step b) with a strong acid or concentrating the present strong acid by removal of present water, wherein the stabilizing reagent contains at least one oxazine-based compound and wherein the polyazole polymer has at least 1.8 dl/g intrinsic viscosity.
    Type: Grant
    Filed: November 12, 2010
    Date of Patent: April 14, 2015
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Oliver Gronwald, Jörg Belack, Jochen Baurmeister, Thomas Justus Schmidt, Seongwoo Choi, Jung Ock Park, Woo Sung Jeon, Jung Seok Yi
  • Patent number: 9005835
    Abstract: This disclosure related to polymer electrolyte member fuel cells and components thereof.
    Type: Grant
    Filed: June 22, 2009
    Date of Patent: April 14, 2015
    Assignee: Nuvera Fuel Cells, Inc.
    Inventors: Scott C. Blanchet, Amedeo Conti, James C. Cross, III
  • Patent number: 9005842
    Abstract: Proton exchange membrane compositions having high proton conductivity are provided. The proton exchange membrane composition includes a hyper-branched polymer, wherein the hyper-branched polymer has a DB (degree of branching) of more than 0.5. A polymer with high ion conductivity is distributed uniformly over the hyper-branched polymer, wherein the hyper-branched polymer has a weight ratio equal to or more than 5 wt %, based on the solid content of the proton exchange membrane composition.
    Type: Grant
    Filed: August 24, 2009
    Date of Patent: April 14, 2015
    Assignee: Industrial Technology Research Institute
    Inventors: Tsung-Hsiung Wang, Jing-Pin Pan, Wen-Chin Lee, Yueh-Wei Lin, Ya-Tin Hsu, Chung-Liang Chang, Chih-Jer Shih
  • Publication number: 20150093683
    Abstract: A fuel cell includes a chromium-containing metal support, a ceramic electrode layer on the metal support and an electroconductive ceramic layer between the chromium-containing metal support and the ceramic electrode layer. The electroconductive ceramic layer includes a ceramic material selected from lanthanum-doped strontium titanate and perovskite oxides.
    Type: Application
    Filed: May 5, 2014
    Publication date: April 2, 2015
    Inventors: Jean Yamanis, Tianli Zhu, Neal Magdefrau, Mark A. Hermann
  • Patent number: 8993193
    Abstract: New proton conducting membranes are made of perfluorosulfonic acid polymers films that have been treated by exposing them to a chlorosulfonating agent. The membranes are used as a proton exchange membrane in PEM fuel cells operating at temperatures above 95° C., or at low relative humidity. In various embodiments, the treated films have superior physical properties such as tensile strength, when compared to an untreated film. In some embodiments, the ion exchange capacity (IEC) of the treated films is increased.
    Type: Grant
    Filed: August 5, 2005
    Date of Patent: March 31, 2015
    Assignee: GM Global Technology Operations LLC
    Inventors: Timothy J. Fuller, Beba T. Dobulis
  • Patent number: 8986894
    Abstract: A solid electrolyte including a layered metal oxide represented by the formula (1), (La1-xAx)(Sr1-yBy)3(Co1-zCz)3O10-???(1) [wherein A represents a rare earth element other than La; B represents Mg, Ca, or Ba; C represents Ti, V, Cr, or Mn; 0?x<1, 0?y<1, 0?z<1; and ? represents an oxygen deficiency amount].
    Type: Grant
    Filed: February 7, 2012
    Date of Patent: March 24, 2015
    Assignees: Toyota Jidosha Kabushiki Kaisha, National University Corporation Hokkaido University
    Inventors: Haruyuki Nakanishi, Tatsuya Takeguchi, Hiroki Takahashi, Ayaka Nakamura, Saburo Hosokawa
  • Patent number: 8974983
    Abstract: An electrical conductive member includes: an electrical conductive structure including: a substrate; an electrical conductive carbon layer provided on at least one surface of the substrate and containing electrical conductive carbon; and a middle layer interposed between the substrate and the electrical conductive carbon layer. An intensity ratio R (ID/IG) of a D-band peak intensity (ID) to a G-band peak intensity (IG) measured by a Raman scattering spectroscopic analysis in the electrical conductive carbon layer is between 1.4 and 1.9.
    Type: Grant
    Filed: October 20, 2009
    Date of Patent: March 10, 2015
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Tomokatsu Himeno, Atsushi Miyazawa, Motoki Yaginuma, Keisuke Yamamoto, Keiji Okada, Tsutomu Yamazaki, Yasuhiro Numao, Toshihiko Tsuda
  • Patent number: 8968956
    Abstract: A repeat unit for a fuel cell stack, the repeat unit having: a conductive interconnect plate; an electrolyte-supported fuel cell, wherein a dense sealing perimeter extends around the entire perimeter of the fuel cell; a cathode gasket adjacent the cathode side of the fuel cell; and an anode gasket adjacent the anode side of the fuel cell. First and second air manifolding ports, and first and second fuel manifolding ports are provided in each of the interconnect plate, dense sealing perimeter of the fuel cell, cathode gasket and anode gasket. An SOFC stack having an aligned stack of a plurality of repeat units is also provided, as well as an SOFC stack configured for cascade fuel flow.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: March 3, 2015
    Assignee: NexTech Materials, Ltd
    Inventors: Michael J. Day, Scott L. Swartz, Gene B. Arkenberg, Chad T. Sellers
  • Patent number: 8968959
    Abstract: In a method for fabrication of an electrochemical energy converter, cermet composition layers (2A), (2B) are applied on both sides of a central ceramic plate (1), channels (3A), (3B) are made in the cermet composition layers (2A), (2B), then the channels (3A), (3B) on both sides of the plate are covered with cermet composition layers (4A), (4B). Afterwards, both sides of the ceramic structure are overlaid with conductive structures (5A), (5B) and then with subsequent layers of the cermet composition (6A), (6B) containing nickel, then both sides of the ceramic structure are overlaid with: layers constituting the solid electrolyte (7A), (7B), layers constituting electrodes (8A), (8B) and contact layers (9A), (9B).
    Type: Grant
    Filed: July 12, 2010
    Date of Patent: March 3, 2015
    Assignee: Akademia Gorniczo-Hutnicza Im. Stanislawa Staszica
    Inventors: Zbigniew Magonski, Barbara Dziurdzia
  • Patent number: 8956780
    Abstract: A solid oxide fuel cell has a stack structure in which sheet bodies and separators for separating air and fuel gas are stacked in alternating layers. Each of the sheet bodies includes an electrolyte layer, a fuel electrode layer formed on the upper surface of the electrolyte layer, and an air electrode layer formed on the lower surface of the electrolyte layer, wherein these layers are stacked and fired in such a manner that the electrolyte layer is sandwiched between the fuel electrode layer and the air electrode layer. The thickness of the electrolyte layer is 0.3 ?m or more and 5 ?m or less, and the electrolyte layer is composed of a single particle of YSZ in the thickness direction. Thus, the electrolyte layer is extremely thin, and further, the grain boundary in the thickness direction is small. Accordingly, the IR loss (electric resistance) of the electrolyte layer can remarkably be reduced.
    Type: Grant
    Filed: January 8, 2009
    Date of Patent: February 17, 2015
    Assignee: NGK Insulators, Ltd.
    Inventors: Makoto Ohmori, Natsumi Shimogawa, Toshiyuki Nakamura, Tsutomu Nanataki
  • Patent number: 8956777
    Abstract: The multi-section cathode air heat exchanger (102) includes at least a first heat exchanger section (104), and a fixed contact oxidation catalyzed section (126) secured adjacent each other in a stack association. Cool cathode inlet air flows through cool air channels (110) of the at least first (104) and oxidation catalyzed sections (126). Hot anode exhaust flows through hot air channels (124) of the oxidation catalyzed section (126) and is combusted therein. The combusted anode exhaust then flows through hot air channels (112) of the first section (104) of the cathode air heat exchanger (102). The cool and hot air channels (110, 112) are secured in direct heat exchange relationship with each other so that temperatures of the heat exchanger (102) do not exceed 800° C. to minimize requirements for using expensive, high-temperature alloys.
    Type: Grant
    Filed: January 7, 2013
    Date of Patent: February 17, 2015
    Assignee: Ballard Power Systems Inc.
    Inventors: Kazuo Saito, Yao Lin
  • Patent number: 8951605
    Abstract: The current invention provides a fabrication method for large surface area, pinhole-free, ultra thin ion conducting membranes using atomic layer deposition on inexpensive sacrificial substrates to make cost effective, high performance fuel cells or electrolyzers. The resultant membrane electrode assembly (MEA) enables significant reduction in resistive losses as well as lowering of the operating temperature of the fuel cell. The invention further provides a method to deposit 3-dimensional surface conformal films that may have compositional grading for superior performance. In addition, the invention provides decoration and modification of electrode surfaces for enhanced catalytic activity and reduced polarization losses. The method of the current invention enables the MEA structure to be fabricated from the anode side up or the cathode side up, each with or without an incorporated anode current collector or cathode current collector, respectively.
    Type: Grant
    Filed: October 28, 2009
    Date of Patent: February 10, 2015
    Assignee: The Board of Trustees of the Leland Stanford Junior University
    Inventors: Friedrich B. Prinz, Turgut M. Gür
  • Patent number: 8945782
    Abstract: The present invention provides a method of producing a multilayer barrier structure in a solid oxide cell stack, comprising the steps of: —providing a metal interconnect; —applying a first metal oxide layer on said metal interconnect; —applying a second metal oxide layer on top of said first metal oxide layer; —applying a third metal oxide layer on top of said second metal oxide layer; —forming a solid oxide cell stack comprising said metal interconnect having said metal oxide layers thereon; and —reacting the metal oxide in said first metal oxide layer with the metal of said metal interconnect during the SOC-stack initialization, and a solid oxide stack comprising an anode contact layer and support structure, an anode layer, an electrolyte layer, a cathode layer, a cathode contact layer, a metallic interconnect, and a multilayer barrier structure which is obtainable by the above method and through an initialization step, which is carried out under controlled conditions for atmosphere composition and current
    Type: Grant
    Filed: November 13, 2007
    Date of Patent: February 3, 2015
    Assignees: Technical University of Denmark, Topsoe Fuel Cell A/S
    Inventors: Karsten Agersted Nielsen, Søren Linderoth, Peter Vang Hendriksen, Åsa Persson, Lars Mikkelsen, Niels Christiansen, Jørgen Gutzon Larsen
  • Patent number: 8940461
    Abstract: A method of coating carbon based electrodes and thick electrodes without mud-cracking is described. The electrode ink is deposited on a decal substrate, and transferred to a hot press before the electrode ink is completely dried. The partially dried electrode ink is hot pressed to the membrane to form a membrane electrode assembly. A membrane electrode assembly including a polymer membrane; and a pair of crack-free electrode layers on opposite sides of the polymer membrane, each of the pair of electrode layers having a thickness of at least about 50 ?m is also described.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: January 27, 2015
    Assignee: GM Global Technology Operations LLC
    Inventors: Junliang Zhang, Matthew Dioguardi, Frederick T. Wagner
  • Patent number: 8940449
    Abstract: A fuel cell including an electrolyte film, a catalyst layer, two diffusion layers, a fuel supply layer, an oxygen supply layer, a water-absorbing layer, and a collector. The fuel cell has an opening at least in a part of a side surface parallel to a proton conduction direction of the electrolyte film among side surfaces of the fuel cell. The water-absorbing layer is present between the oxygen supply layer and the collector. An end portion of the water-absorbing layer is present on one of a plane including the opening and an opposite side of the fuel cell with the plane including the opening being a reference. A fuel cell system having a fuel cell stack including the fuel cells. The fuel cell has a high water discharging ability and is capable of maintaining stable high generation efficiency and providing a high output even while being small-sized and light-weight.
    Type: Grant
    Filed: February 1, 2007
    Date of Patent: January 27, 2015
    Assignee: Canon Kabushiki Kaisha
    Inventors: Atsuhito Yoshizawa, Kentaro Nagai
  • Patent number: 8940451
    Abstract: A planar high temperature fuel cell, a use and a method of manufacture are discloses. The planar high-temperature fuel cell with includes a layer structure. The layer structure includes a cathode layer, an anode layer and a solid electrolyte layer disposed between the cathode layer and the anode layer. Each of the layers are planar. A porous metal structure is used as the support for the layer structure and is also planar.
    Type: Grant
    Filed: September 24, 2009
    Date of Patent: January 27, 2015
    Assignee: Siemens Aktiengesellschaft
    Inventors: Robert Fleck, Horst Greiner, Alessandro Zampieri
  • Patent number: 8940455
    Abstract: A fuel cell is provided that includes an anode, a cathode, a solid electrolyte layer, a barrier layer, and a buffer layer. The solid electrolyte layer includes zirconium and is provided between the anode and the cathode. The barrier layer includes cerium and is provided between the solid electrolyte layer and the cathode, with the barrier layer having pores. The buffer layer includes zirconium and cerium and is provided between the barrier layer and the solid electrolyte layer. The barrier layer has a first barrier layer provided near to the buffer layer with a first pore ratio and a second barrier layer provided between the first barrier layer and the cathode with a second pore ratio. The first pore ratio of the first barrier layer is larger than the second pore ratio of the second barrier layer.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: January 27, 2015
    Assignee: NGK Insulators, Ltd.
    Inventors: Ayano Kobayashi, Shinji Fujisaki, Makoto Ohmori
  • Patent number: 8932780
    Abstract: An example fuel cell assembly may include a proton exchange membrane (or membrane electrode assembly) that has a first major surface and a second major surface. An anode electrode, which may include a patterned metal layer with a plurality of apertures extending through the patterned metal layer, may also be provided. An anode gas diffusion layer secured to an anode adhesive frame may be situated between the anode electrode and the first major surface of the proton exchange membrane. A cathode electrode may, in some instances, include a patterned metal layer with a plurality of apertures extending through the patterned metal layer. A cathode gas diffusion layer secured to a cathode adhesive frame may be situated between the cathode electrode and the second major surface of the proton exchange membrane. In some instances a fuel cell assembly may be flexible so that the fuel cell assembly can be rolled into a rolled configuration that defines an inner cavity with open ends.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: January 13, 2015
    Assignee: Honeywell International Inc.
    Inventor: Steven J. Eickhoff
  • Publication number: 20150004521
    Abstract: A mold for forming a porous article can include a first material having a first thermal conductivity and a second material having a second thermal conductivity different from the first thermal conductivity. The first material may be at least partially embedded within the second material and configured to create regions of different thermal conductivity in the body, such as configured to create distinct nucleation regions within a material formed within the mold. A method for forming a porous article can include providing a slurry within a mold and freeze-casting the slurry to form a porous article having a burst-like distribution of porosity. A porous article according to embodiments herein can include a burst-like distribution of porosity.
    Type: Application
    Filed: June 23, 2014
    Publication date: January 1, 2015
    Inventors: Satyalakshmi K. Ramesh, Chuanping Li, Paul Braun, Michael J. Ferrecchia, John D. Pietras, Brian P. Feldman, James A. Salvatore
  • Patent number: 8921007
    Abstract: A bonding layer, disposed between an interconnect layer and an electrode layer of a solid oxide fuel cell article, may be formed from a yttria stabilized zirconia (YSZ) powder having a monomodal particle size distribution (PSD) with a d50 that is greater than about 1 ?m and a d90 that is greater than about 2 ?m.
    Type: Grant
    Filed: November 14, 2012
    Date of Patent: December 30, 2014
    Assignee: Saint-Gobain Ceramics & Plastics, Inc.
    Inventors: Guangyong Lin, Yeshwanth Narendar, John D. Pietras, Qiang Zhao, Robert J. Sliwoski, Caroline Levy, Samuel S. Marlin, Aravind Mohanram
  • Publication number: 20140377681
    Abstract: The invention describes an air-breathing fuel cell for the oxidation of ions with air or oxygen, having an anode half cell and a cathode half cell. A first ion-conducting membrane and a second ion-conducting membrane is introduced between the half cells, and the second ion-conducting membrane is coated at least in regions on the side orientated towards the cathode half cell with a catalyst for the reduction of oxygen. According to the invention, the air-breathing fuel cell is characterised in that an oxidation zone for the oxidation of ions with negative standard electrode potential is provided between the ion-conducting membranes.
    Type: Application
    Filed: July 13, 2012
    Publication date: December 25, 2014
    Applicant: Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.V.
    Inventors: Jens Noack, Thomas Berger, Jens Tübke, Karsten Pinkwart