Inorganic Radiation Conductive Composition Patents (Class 430/84)
  • Patent number: 4572882
    Abstract: A photoconductive member is provided which comprises a substrate and a photoconductive light receiving layer made up of an amorphous material containing silicon atoms and germanium atoms, the light receiving layer containing nitrogen atoms and having a first layer region (1), a third layer region (3), and a second layer region (2) of nitrogen atom distribution concentrations C(1), C(3), and C(2), respectively, in the thickness direction, in that order from the substrate side to the opposite side, wherein C(3) is higher than any of C(2) and C(1) and one of C(1) and C(2) is not zero.
    Type: Grant
    Filed: September 6, 1984
    Date of Patent: February 25, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keishi Saitoh, Yukihiko Ohnuki, Shigeru Ohno
  • Patent number: 4572881
    Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.
    Type: Grant
    Filed: April 24, 1984
    Date of Patent: February 25, 1986
    Inventor: Shunpei Yamazaki
  • Patent number: 4571370
    Abstract: A photoconductive member comprises a substrate for photoconductive member and a light receiving layer provided on said substrate having a layer constitution in which a layer region (G) comprising an amorphous material containing germanium atoms and a layer region (S) exhibiting photoconductivity comprising an amorphous material containing silicon atoms are successively provided from the substrate side, said light receiving layer having a layer region (O) containing oxygen atoms, the depth profile of oxygen atoms in said layer region (O) being increased smoothly and continuously toward the upper end surface of the light receiving layer.
    Type: Grant
    Filed: August 13, 1984
    Date of Patent: February 18, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventor: Keishi Saitoh
  • Patent number: 4569892
    Abstract: A photoconductive member comprises a support for photoconductive member and a light-receiving layer provided on said support having a layer constitution in which a layer region (G) comprising an amorphous material containing germanium atoms and a layer region (S) exhibiting photoconductivity comprising an amorphous material containing silicon atoms are successively provided from the support side, said light-receiving layer having a first layer region (1), a third layer region (3) and a second layer region (2), each containing oxygen atoms, with the distribution concentrations in the layer thickness direction of C(1), C(3) and C(2), respectively, in the order mentioned from the support side, provided that when C(3) cannot be solely the maximum, and either one of C(1) and C(2) is 0, the other two are not 0 and not equal, or when C(3) is 0, the other two are not 0.
    Type: Grant
    Filed: August 17, 1984
    Date of Patent: February 11, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventor: Keishi Saitoh
  • Patent number: 4569895
    Abstract: An article having improved electrostatic charge transfer properties. The improvement in charge transfer properties results from subjecting a layer of photoconductive-insulative material or dielectric material on the charge donor or a layer of dielectric material on the charge receptor, or both layers, to plasma treatment process to provide an oxygen-enriched surface to the photoconductive-insulative layer and/or the dielectric layer.
    Type: Grant
    Filed: October 30, 1984
    Date of Patent: February 11, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Stephen J. Willett, Hsin H. Chou, Carol E. Hendrickson, William A. Hendrickson
  • Patent number: 4569894
    Abstract: A photoconductive member comprises a support and a light receiving layer comprising a first layer region comprising at least germanium atoms and being crystallized at least a portion thereof, a second region comprising an amorphous material comprising at least both of silicon atoms and germanium atoms and a third layer region comprising an amorphous material comprising at least silicon atoms, and exhibiting photoconductivity said layer regions being provided successively in this order from the said support side.
    Type: Grant
    Filed: January 11, 1984
    Date of Patent: February 11, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keishi Saitoh, Kozo Arao
  • Patent number: 4569893
    Abstract: A photoconductive member comprises a substrate for photoconductive member and a light receiving layer provided on said substrate having a layer consititution in which a first layer region (G) comprising an amorphous material containing germanium atoms and a second layer region (S) exhibiting photoconductivity comprising an amorphous material containing silicon atoms are successively provided from the substrate side, said light receiving layer containing oxygen atoms together with a substance for controlling conductivity (C) in a distributed state such that, in said light receiving layer, the maximum value C(PN).sub.max of the content of said substance (C) in the layer thickness direction exists within said second layer region (S) or at the interface with said first layer region (G) and, in said second layer region(S), said substance (C) is distributed in greater amount on the side of said substrate.
    Type: Grant
    Filed: August 27, 1984
    Date of Patent: February 11, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keishi Saitoh, Yukihiko Ohnuki, Shigeru Ohno
  • Patent number: 4568622
    Abstract: An electrophotographic photosensitive member has a conductive substrate, a first layer structure with a single layer made mainly of amorphous silicon formed on the substrate, and a second layer structure including multiple layers also mainly made of amorphous silicon layered in succession on the first layer structure. The plurality of second layers includes at least two high resistance layers having a relatively high resistance value and at least one low resistance layer having a relatively low resistance value compared to the high resistance value. The layers of the second layer structure are layered alternately on the first layer structure so that the first and last layers in the second layer structure are high resistance layers.
    Type: Grant
    Filed: June 15, 1984
    Date of Patent: February 4, 1986
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Koji Minami, Kazuyuki Goto, Hisao Haku, Takeo Fukatsu, Michitoshi Ohnishi, Yukinori Kuwano
  • Patent number: 4567127
    Abstract: A photoconductive member is provided which comprises a substrate and a light receiving layer having photoconductivity which comprises an amorphous material containing silicon atoms and germanium atoms, the distribution of germanium atoms therein being nonuniform in the layer thickness direction, and carbon atoms being contained in the light receiving layer.Said photoconductive member can further comprise thereon another layer which comprises amorphous material containing silicon atoms as a matrix and at least one kind of atoms selected from the group of nitrogen atoms and oxygen atoms.
    Type: Grant
    Filed: September 5, 1984
    Date of Patent: January 28, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keishi Saitoh, Yukihiko Ohnuki, Shigeru Ohno
  • Patent number: 4565731
    Abstract: An image-forming member for electro-photography has a photoconductive layer comprising a hydrogenated amorphous semiconductor composed of silicon and/or germanium as a matrix and at least one chemical modifier such as carbon, nitrogen and oxygen contained in the matrix.
    Type: Grant
    Filed: September 15, 1982
    Date of Patent: January 21, 1986
    Assignee: Canon Kabushiki Kaisha
    Inventors: Toshiyuki Komatsu, Yutaka Hirai, Katsumi Nakagawa, Tadaji Fukuda
  • Patent number: 4560634
    Abstract: An electrophotographic photosensitive member constituted of an electroconductive supporting substrate and a photoconductive layer provided on said substrate, said photoconductive layer being composed primarily of a microcrystalline silicon or a layered product of a microcrystalline silicon and an amorphous silicon.
    Type: Grant
    Filed: May 26, 1982
    Date of Patent: December 24, 1985
    Assignee: Tokyo Shibaura Denki Kabushiki Kaisha
    Inventors: Takeshi Matsuo, Yukio Suzuki
  • Patent number: 4557990
    Abstract: Image-forming member for electrophotography comprising a charge generation layer composed of hydrogenated amorphous silicon.
    Type: Grant
    Filed: December 23, 1983
    Date of Patent: December 10, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Katsumi Nakagawa, Toshiyuki Komatsu, Yutaka Hirai, Teruo Misumi, Tadaji Fukuda
  • Patent number: 4555462
    Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.
    Type: Grant
    Filed: July 21, 1983
    Date of Patent: November 26, 1985
    Inventor: Shunpei Yamazaki
  • Patent number: 4555465
    Abstract: A photoconductive member comprising a support and a light receiving layer provided on said support, having photoconductivity containing silicon atoms as a matrix and at least hydrogen atoms as constituent atom, said light receiving layer having a layer region with depth profile such that the content of hydrogen atoms contained therein is decreased in the direction of layer thickness toward both ends of said layer.
    Type: Grant
    Filed: December 16, 1983
    Date of Patent: November 26, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kyosuke Ogawa, Shigeru Shirai, Keishi Saitoh, Teruo Misumi, Junichiro Kanbe
  • Patent number: 4552824
    Abstract: A layer of amorphous silicon containing H, preferably 10-40 atomic % H, is used as a photoconductive layer for electrophotographic photosensitive member.
    Type: Grant
    Filed: January 28, 1985
    Date of Patent: November 12, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yutaka Hirai, Toshiyuki Komatsu, Katsumi Nakagawa, Teruo Misumi, Tadaji Fukuda
  • Patent number: 4551405
    Abstract: Image-forming member for electrophotography comprising a charge generation layer composed of hydrogenated amorphous silicon.
    Type: Grant
    Filed: December 23, 1983
    Date of Patent: November 5, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Katsumi Nakagawa, Toshiyuki Komatsu, Yutaka Hirai, Teruo Misumi, Tadaji Fukuda
  • Patent number: 4547448
    Abstract: A photoconductive member comprises a support for a photoconductive member; a first amorphous layer comprising an amorphous material containing silicon atoms as a matrix and exhibiting photoconductivity, said first amorphous layer having a first layer region containing oxygen atoms as constituent atoms in a distribution state which is ununiform and continuous in the direction of layer thickness and a second layer region containing atoms belonging to the group III of the periodic table as constituent atoms in a distribution state which is continuous in the direction of layer thickness, said first layer region existing internally beneath the surface of said first amorphous layer; and a second amorphous layer comprising an amorphous material represented by any of the following formulae:Si.sub.a C.sub.1-a (0.4<a<1) (1)(Si.sub.b C.sub.1-b).sub.c H.sub.1-c (0.5<b<1, 0.6.ltoreq.c<1) (2)(Si.sub.d C.sub.1-d).sub.e X.sub.1-e (0.47<d<1, 0.8.ltoreq.e<1) (3)(Si.sub.f C.sub.1-f).sub.g (H+X).sub.
    Type: Grant
    Filed: July 6, 1984
    Date of Patent: October 15, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shigeru Shirai, Kyosuke Ogawa, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato, Teruo Misumi
  • Patent number: 4543314
    Abstract: A process for the preparation of an electrostatographic photosensitive device comprising combining a sodium additive comprising sodium carbonate, sodium bicarbonate, sodium selenite, sodium hydroxide or mixtures thereof with trigonal selenium particles, an organic resin binder and a solvent for the binder to form a milling mixture, milling the milling mixture to form a uniform dispersion, applying the dispersion to a substrate in an even layer and drying the layer.
    Type: Grant
    Filed: December 1, 1983
    Date of Patent: September 24, 1985
    Assignee: Xerox Corporation
    Inventor: Kenneth H. Maxwell, deceased
  • Patent number: 4540652
    Abstract: A material consists of an electrically conducting support and a dielectric layer containing in % by weight: 17-80 of a polymeric binder and 20-83 of a finely divided mixed pyrogenic silicon and titanium oxide containing between 10 and 50% by weight of titanium.
    Type: Grant
    Filed: May 24, 1984
    Date of Patent: September 10, 1985
    Inventors: Alexei A. Chuiko, Anatoly V. Morev, Alexandr S. Golovkov, Valentin A. Smirnov, Evgeny F. Voronin, Raisa A. Evlakhova, Galina Y. Guba, Iolita R. Slushnene, Arunas V. Pasvyanskas, Roman V. Sushko
  • Patent number: 4536459
    Abstract: A photoconductive member, comprises a support for a photoconductive member, a first amorphous layer exhibiting photoconductivity comprising an amorphous material containing silicon atoms as a martix, said first amorphous layer having a first layer region containing oxygen atoms in a distribution which is continuous and ununiform in the direction of layer thickness and a second layer region containing atoms belonging to the group III of the periodic table as constituent atoms in a distribution which is continuous and ununiform in the direction of layer thickness, and a second amorphous layer comprising an amorphous material represented by any of the following formulae:Si.sub.a C.sub.1-a (0.4<a<1) (1)(Si.sub.b C.sub.1-b).sub.c H.sub.1-c (0.5<b<1, 0.6.ltoreq.c<1) (2)(Si.sub.d C.sub.1-d).sub.e X.sub.1-e (0.47<d<1, 0.8.ltoreq.e<1) (3)(Si.sub.f C.sub.1-f).sub.g (H+X).sub.1-g (0.47<f<1, 0.8.ltoreq.g<1) (4)(wherein X represents a halogen atom).
    Type: Grant
    Filed: March 11, 1983
    Date of Patent: August 20, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Teruo Misumi, Kyosuke Ogawa, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato, Shigeru Shirai
  • Patent number: 4532198
    Abstract: A photoconductive member is provided, which comprises a support for photoconductive member and a light receiving layer with a layer constitution, comprising a first layer region containing at least germanium atoms of which at least a portion is crystallized, a second region comprising an amorphous material containing at least silicon atoms and germanium atoms, a third layer region comprising an amorphous material containing at least silicon atoms and exhibiting photoconductivity, and a fourth layer region comprising an amorphous material containing silicon atoms and carbon atoms, provided successively in the order mentioned from the said support side.
    Type: Grant
    Filed: May 7, 1984
    Date of Patent: July 30, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keishi Saitoh, Kozo Arao
  • Patent number: 4529679
    Abstract: A photoconductive member comprises a substrate and a light receiving layer having photoconductive provided on said support, comprising silicon atoms as a matrix and at least halogen atoms as constituent atoms said light receiving layer having a depth profile with respect to the layer thickness direction such that the concentration of halogen atoms contained therein is increased from the said substrate side toward the surface side of the photoconductive member.
    Type: Grant
    Filed: December 22, 1983
    Date of Patent: July 16, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kyosuke Ogawa, Shigeru Shirai, Keishi Saitoh, Teruo Misumi, Junichiro Kanbe
  • Patent number: 4525442
    Abstract: A photoconductive member comprises a photoconductive layer constituted of an amorphous material containing at least one of hydrogen atoms and halogen atoms in a matrix of silicon atoms and an amorphous layer constituted of an amorphous material containing at least one of hydrogen atoms and halogen atoms in a matrix of boron atoms.
    Type: Grant
    Filed: July 16, 1984
    Date of Patent: June 25, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shigeru Shirai, Junichiro Kanbe, Tadaji Fukuda
  • Patent number: 4518670
    Abstract: Disclosed is a multilayered electrophotographic recording material comprising a charge transfer layer and a charge generating layer on a substrate. The layers are comprised of essentially amorphous silicon. At least 1 atomic percent of nitrogen is present in the charge transfer layer.
    Type: Grant
    Filed: June 3, 1983
    Date of Patent: May 21, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Masatoshi Matsuzaki, Toshinori Yamazaki, Hiroyuki Nomori
  • Patent number: 4518671
    Abstract: An electrophotographic photosensitive member has a selenium type photoconductive layer containing 8000 ppm or less oxygen based on selenium. The member is free from a fatigue due to repeated use.
    Type: Grant
    Filed: September 19, 1983
    Date of Patent: May 21, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Teruo Misumi, Yoichi Osato
  • Patent number: 4514483
    Abstract: The present invention provides a method for preparing a selenium type electrophotographic element comprising the steps of processing the surface of an electrically conductive substrate which has a metal surface by vibrating and sliding a grindstone until a predetermined surface-roughness is obtained and thereafter vapordepositing thereon selenium, selenium alloy or selenium compound in a usual manner.
    Type: Grant
    Filed: March 30, 1983
    Date of Patent: April 30, 1985
    Assignee: Ricoh Co., Ltd.
    Inventors: Tadashi Matsuura, Yasuo Kadomatsu
  • Patent number: 4513072
    Abstract: An electrophotographic recording material comprises a conductive substrate, a first photoconductive selenium layer containing halogen disposed on the substrate, and a second photoconductive selenium layer containing arsenic disposed on the second photo conductive layer. The first photo conductive layer disposed on the substrate additionally contains arsenic.
    Type: Grant
    Filed: September 7, 1982
    Date of Patent: April 23, 1985
    Assignee: Licentia Patent-Verwaltungs-GmbH
    Inventors: Hartmut Dulken, Karlheinz Kassel, Wolfgang Mows, Hubert Walsdorfer
  • Patent number: 4510224
    Abstract: A photoreceptor comprising a photoconductive layer composed of hydrogenated and/or fluorinated amorphous silicon, a surface modifying layer formed on the above photoconductive layer and composed of hydrogenated and/or fluorinated amorphous silicon carbide and a charge transport layer formed below the above photoconductive layer and composed of hydrogenated and/or fluorinated amorphous silicon carbide wherein the thickness "t" of the above surface modifying layer is selected in a range 400 .ANG..ltoreq.t<2,000 .ANG..
    Type: Grant
    Filed: May 3, 1983
    Date of Patent: April 9, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshinori Yamazaki, Hiroyuki Nomori, Masatoshi Matsuzaki, Tetsuo Shima, Isao Myokan
  • Patent number: 4507375
    Abstract: A layer of amorphous silicon containing H, preferably 10-40 atomic %H, is used as a photoconductive layer for electrophotographic photosensitive member.
    Type: Grant
    Filed: February 17, 1984
    Date of Patent: March 26, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yutaka Hirai, Toshiyuki Komatsu, Katsumi Nakagawa, Teruo Misumi, Tadaji Fukuda
  • Patent number: 4501807
    Abstract: A photoconductive member comprising a support for photoconductive member and an amorphous layer exhibiting photoconductivity comprising an amorphous material containing silicon atoms as a matrix is characterized in that said amorphous layer has a first layer region containing, as constituent atoms, oxygen atoms in a distribution which is nonuniform and continuous in the direction of the layer thickness and a second layer region containing, as constituent atoms, the atoms (A) belonging to group III or group V of the periodic table in a distribution which is continuous in the direction of the layer thickness, said second layer existing internally beneath the surface of said amorphous layer.
    Type: Grant
    Filed: March 8, 1983
    Date of Patent: February 26, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shigeru Shirai, Kyosuke Ogawa, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato, Teruo Misumi
  • Patent number: 4495262
    Abstract: Disclosed is a photosensitive member, or an electrophotographic photosensitive member, characterised by having a photoconductive layer comprising at least one of an amorphous hydrogenated and/or fluorinated silicon germanium and an amorphous hydrogenated and/or fluorinated silicon germanium carbide, a first amorphous hydrogenated and/or fluorinated silicon carbide layer formed on the photoconductive layer and a second amorphous hydrogenated and/or fluorinated silicon carbide layer formed beneath said photoconductive layer.
    Type: Grant
    Filed: April 28, 1983
    Date of Patent: January 22, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Masatoshi Matsuzaki, Toshinori Yamazaki, Isao Myokan, Tetsuo Shima, Hiroyuki Nomori
  • Patent number: 4490450
    Abstract: A photoconductive member comprises a support for a photoconductive member and an amorphous layer having a layer constitution comprising a first layer region comprising an amorphous material containing silicon atoms and germanium atoms and a second layer region comprising an amorphous material containing silicon atoms and exhibiting photoconductivity, said first and second layer regions being provided successively from the side of said support.
    Type: Grant
    Filed: March 28, 1983
    Date of Patent: December 25, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Isamu Shimizu, Kozo Arao, Eiichi Inoue
  • Patent number: 4490454
    Abstract: A photoconductive member comprises a support for photoconductive member and an amorphous layer comprising an amorphous material containing silicon atoms as a matrix and exhibiting photoconductivity, said amorphous layer having a first layer region containing, as constituent atoms, oxygen atoms and a second layer region containing, as constituent atoms, the atoms belonging to the group V of the periodic table in a distribution which is continuous in the direction of the layer thickness and more enriched toward the side of said support.
    Type: Grant
    Filed: March 14, 1983
    Date of Patent: December 25, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Teruo Misumi, Kyosuke Ogawa, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato, Shigeru Shirai
  • Patent number: 4486521
    Abstract: A photoconductive member comprises a support for a photoconductive member and an amorphous layer containing an amorphous material comprising silicon atom as a matrix and having photoconductivity, said amorphous layer comprising a first layer region containing oxygen atom as a constituent atom, the oxygen atom being distributed continuously in the direction of the layer thickness and enriched at the support side, and a second layer region containing an atom of the group III of the periodic table as a constituent atom, said first layer region being internally present at the support side in the amorphous layer, and the layer thickness T.sub.B of said second layer region and a layer thickness T resulted from subtracting T.sub.B from the layer thickness of the amorphous layer satisfying the relation, T.sub.B /T.ltoreq.1.
    Type: Grant
    Filed: March 14, 1983
    Date of Patent: December 4, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Teruo Misumi, Kyosuke Ogawa, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato, Shigeru Shirai
  • Patent number: 4483911
    Abstract: A photoconductive member comprises a support and an amorphous layer comprising a first layer region and a second layer region, the first layer region having photoconductivity comprising an amorphous material which comprises silicon atoms as a matrix and at least one member selected from hydrogen atoms and halogen atoms as a constituent, the first layer region having a layer region (I) containing an impurity controlling the electroconductivity type at the support side, and the second layer region comprising an amorphous material comprising at least both silicon and carbon as constituents.
    Type: Grant
    Filed: December 17, 1982
    Date of Patent: November 20, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kyosuke Ogawa, Shigeru Shirai, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato
  • Patent number: 4482619
    Abstract: An x-ray electro-photographic recording material is formed of a photo-conductive layer (1) comprised of a selenium-arsenic alloy and positioned on a transparent electrode layer (4), which is positioned on a further layer (3) comprised of an x-ray luminophore and positioned on a reflective surface (2a) of a film carrier layer (2). In usage, with a positive corona charge on the free photo-conductive layer surface (1a) before x-ray exposure, the luminophore-containing layer (3), during x-ray exposure, converts a component (5) of the x-ray radiation (.gamma.) not absorbed by the photo-conductive layer (1) into visible luminescent light (6) which effects an increase of sensitivity in the photo-conductive layer (1). This recording material can be used in x-ray photograph devices.
    Type: Grant
    Filed: May 12, 1983
    Date of Patent: November 13, 1984
    Assignee: Siemens Aktiengesellschaft
    Inventor: Eberhard Bayer
  • Patent number: 4476209
    Abstract: An electrophotographic photoreceptor comprising a conductive layer and a photosensitive layer of vapor-deposited selenium-antimony alloy film formed thereon is disclosed. The photosensitive layer has an average antimony concentration of 5 to 21 wt % and the center layer thereof except for the skin layer on either side has a change in antimony concentration within 2 wt % in any region that is 1000 deep .ANG. from the surface of the skin layer.
    Type: Grant
    Filed: September 16, 1982
    Date of Patent: October 9, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hiroyuki Moriguchi, Takeo Shimura, Tadashi Kaneko, Hiroyuki Nomori, Akira Nishiwaki
  • Patent number: 4471042
    Abstract: An image-forming member for electrophotography has a photoconductive layer comprising a hydrogenated amorphous semiconductor composed of silicon and/or germanium as a matrix and at least one chemical modifier such as carbon, nitrogen and oxygen contained in the matrix.
    Type: Grant
    Filed: May 4, 1979
    Date of Patent: September 11, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Toshiyuki Komatsu, Yutaka Hirai, Katsumi Nakagawa, Tadaji Fukuda
  • Patent number: 4468443
    Abstract: A process for producing a photoconductive member, which comprises forming a photoconductive layer on a substrate for formation of a photoconductive layer by introducing starting substances for formation of a photoconductive layer under gaseous state into a deposition chamber maintained under a desired reduced pressure and exciting discharging under the gas atmosphere of said starting substances is characterized in that said starting substances are constituted of at least one substance selected from the first group consisting of substances(O) containing oxygen atoms as constituent atom, substances(N) containing nitrogen atoms as constituent atom and substances(C) containing carbon atoms as constituent atom, and at least two compounds selected from the second group consisting of the compounds of the formula:Si.sub.n H.sub.2n+2 (A)wherein n is a positive integer and the compounds of the formula:Si.sub.m H.sub.l X.sub.
    Type: Grant
    Filed: March 4, 1982
    Date of Patent: August 28, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Isamu Shimizu, Kyosuke Ogawa, Eiichi Inoue, Junichiro Kanbe
  • Patent number: 4465750
    Abstract: A photoconductive member comprises a support and an amorphous layer compsed of a first layer region composed of a photoconductive amorphous silicon containing p- or n-type impurity distributed nonuniformly and continuously in the layer thickness direction, and a second layer region composed of Si.sub.a C.sub.1-a (0.4<a<1), [Si.sub.b C.sub.1-b ].sub.c H.sub.1-c (0.5<b<1, 0.6.ltoreq.c<1), [Si.sub.d C.sub.1-d ].sub.e X.sub.1-e (0.47<d<1, 0.8.ltoreq.e<1, X: halogen) or [Si.sub.f C.sub.1-f ].sub.g (H+X).sub.1-g (0.47<f<1, 0.8.ltoreq.g<1, X: halogen].
    Type: Grant
    Filed: December 13, 1982
    Date of Patent: August 14, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kyosuke Ogawa, Shigeru Shirai, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato
  • Patent number: 4464451
    Abstract: An electrophotographic image-forming member comprises a substrate for electrophotography and an amorphous layer which is laid on said substrate and constituted of silicon atoms as matrix containing at least one of hydrogen atom and halogen atom and exhibits photoconductivity, said substrate being constituted of aluminum oxide containing chemi-structurally water at least on the surface thereof, and said amorphous layer having a layer region containing at least one member selected from the group consisting of oxygen atom, nitrogen atom and carbon atom in at least a part thereof, the content of said member in said layer region being distributed unevenly in the direction of the thickness of said layer.
    Type: Grant
    Filed: January 29, 1982
    Date of Patent: August 7, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shigeru Shirai, Junichiro Kanbe, Tadaji Fukuda
  • Patent number: 4460670
    Abstract: A photoconductive member comprises a support for a photoconductive member and an amorphous layer having photoconductivity constituted of an amorphous material comprising silicon atoms as a matrix, said amorphous layer having a first layer region containing at least one kind of atoms selected from the group consisting of oxygen atoms, carbon atoms and nitrogen atoms as constituent atoms in a distribution which is ununiform and continuous in the direction of layer thickness and a second layer region containing atoms of an element belonging to the group III of the periodic table as constituent atoms in a distribution which is ununiform and continuous in the direction of layer thickness.
    Type: Grant
    Filed: November 19, 1982
    Date of Patent: July 17, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kyosuke Ogawa, Shigeru Shirai, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato
  • Patent number: 4460669
    Abstract: A photoconductive member comprises a support for a photoconductive member and an amorphous layer having photoconductivity constituted of an amorphous material comprising silicon atoms as a matrix, said amorphous layer having a first layer region containing as the constituent atom at least one kind of atoms selected from the group consisting of oxygen atoms, carbon atoms and nitrogen atoms in a distribution state which is ununiform and continuous in the direction of layer thickness and a second layer region containing atoms belonging to the group III of the periodic table as constituent atoms in a distribution state which is ununiform and continuous in the direction of layer thickness, said first layer region existing internally below the surface of said amorphous layer.
    Type: Grant
    Filed: November 22, 1982
    Date of Patent: July 17, 1984
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kyosuke Ogawa, Shigeru Shirai, Junichiro Kanbe, Keishi Saitoh, Yoichi Osato
  • Patent number: 4439508
    Abstract: An electrophotographic recording material including a photoconductor made of a selenium compound applied as a layer on an electrically conductive substrate. The photoconductor includes a compound of arsenic, selenium and tellurium of the formula As.sub.2 Se.sub.3-x Te.sub.x, where 0<x<3.
    Type: Grant
    Filed: June 3, 1981
    Date of Patent: March 27, 1984
    Assignee: Licentia Patent-Verwaltungs-GmbH
    Inventors: Manfred Lutz, Bernd Reimer
  • Patent number: 4430405
    Abstract: A xeroradiographic material comprising a substrate at least one surface of which is electrically conductive, and an X-ray sensitive layer provided on the conductive surface of the substrate and essentially consisting of an organic binder, .gamma.-form crystal grains of a bismuth oxide-based compound oxide and n-type semiconductor grains dispersed in the organic binder. The material is made by dispersing these grains in an organic binder solution, applying the dispersion onto the conductive surface of the substrate, drying the coat of the dispersion at a temperature in a range not lower than the boiling point of the solvent but below the softening point of the organic binder to form an X-ray sensitive layer, and heat-treating the X-ray sensitive layer at a temperature in a range not lower than the softening point of the organic binder but below the temperature at which the organic binder begins decomposing.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: February 7, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Ono, Hiroshi Sunagawa
  • Patent number: 4423129
    Abstract: An electrophotographic photosensitive member is characterized by having a layer which contains at least one hydrazone compound represented by the following formula (1) or (2): ##STR1## wherein R.sub.11 represents substituted or unsubstituted naphthyl; R.sub.12 represents substituted or unsubstituted alkyl, substituted or unsubstituted aralkyl, or substituted or unsubstituted aryl; R.sub.13 represents hydrogen, alkyl, or alkoxy; R.sub.14 and R.sub.15 each represent substituted or unsubstituted alkyl, substituted or unsubstituted aralkyl, or substituted or unsubstituted aryl; n is 0 or 1; when n=1, R.sub.14 and R.sub.15, together with the nitrogen which links them, may complete a cyclic amino group; X represents a group necessary for completing a benzene ring or naphthalene ring; R.sub.21 and R.sub.22 each represent hydrogen, halogen, alkyl, alkoxy or disalkylamino; and R.sub.23, R.sub.24, R.sub.25, R.sub.26 and R.sub.
    Type: Grant
    Filed: November 30, 1981
    Date of Patent: December 27, 1983
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshio Takasu, Kiyoshi Sakai, Minoru Mabuchi, Shozo Ishikawa, Katsunori Watanabe
  • Patent number: 4423133
    Abstract: A photoconductive layer comprises a support and an amorphous layer. The amorphous layer is photoconductive, comprises silicon as matrix and hydrogen and/or halogen, and has a layer region containing group III atoms which is distributed such that the distribution is continuous in the direction of layer thickness and said atoms are more enriched on the aforesaid support side than on the opposite side to the aforesaid support side in said layer.
    Type: Grant
    Filed: November 10, 1982
    Date of Patent: December 27, 1983
    Assignee: Canon Kabushiki Kaisha
    Inventors: Junichiro Kanbe, Shigeru Shirai, Kyosuke Ogawa, Keishi Saitoh, Yoichi Osato
  • Patent number: 4421838
    Abstract: A photoconductive element comprising elemental selenium dispersed in an insulating polymer is prepared by reducing an inorganic selenium compound in the presence of the insulating polymer. The invention also provide a process for preparing an electrophotosensitive material having a photoconductive layer in which reduction of the inorganic selenium compound is performed in a layer coated on a conductive support.
    Type: Grant
    Filed: April 20, 1981
    Date of Patent: December 20, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Takeda, Mitsuharu Nirasawa, Masayoshi Nagata
  • Patent number: 4420546
    Abstract: An electrophotographic image forming member having on a substrate a photoconductive layer constructed by laminating a crystalline silicon layer and an amorphous silicon layer.
    Type: Grant
    Filed: August 20, 1981
    Date of Patent: December 13, 1983
    Assignee: Canon Kabushiki Kaisha
    Inventors: Junichiro Kanbe, Tadaji Fukuda
  • Patent number: 4418132
    Abstract: A printing member for electrostatic photocopying, comprises a substrate having a conductive surface and a photoelectric-sensitive, electrically chargeable layer deposited on the conductive surface of the substrate. The electrically chargeable layer has a non-single crystal semiconductor layer having a built-in-potential, or the non-single crystal semiconductor layer and an insulating or semi-insulating layer.
    Type: Grant
    Filed: June 23, 1981
    Date of Patent: November 29, 1983
    Inventor: Shunpei Yamazaki