Emulsion Fuel (e.g., Water-gasoline Emulsions, Etc.) Patents (Class 44/301)
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Patent number: 5885310Abstract: In the present invention, a solution of synthetic anionic surface active agents is at first prepared by mixing and homogenizing sodium polyoxyethylenealkylether sulfate and sodium alpha-olefin sulfonate (both are anionic surface active agents). Distillated water is added to this solution with mixing such that the mixture becomes a mousse-like emulsion that homogeneously contains a sufficient amount of air bubbles. A condensed emulsion fuel material is then produced by adding petroleum liquid fuel to the mousse-like emulsion with mixing. The concentrated emulsion fuel material and an emulsion fuel has an excellent chemical stability and does not separate to water and oil layers even after a long term storage. In addition, as it can be combusted at a high temperature boiler without requiring so much air, the emission of both soot (dust) and NOx are simultaneously reduced.Type: GrantFiled: December 11, 1997Date of Patent: March 23, 1999Assignees: Makoto Minamidate, Hisayoshi Tanaka, Yutaka HashimotoInventor: Makoto Minamidate
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Patent number: 5879419Abstract: The method for producing a superheavy oil emulsion fuel includes the steps of (a) adding to a superheavy oil 0.1 to 0.6 parts by weight of a nonionic surfactant having an HLB (hydrophilic-lipophilic balance) of 13 to 19, based on 100 parts by weight of the superheavy oil, and water, to prepare a homogeneous liquid mixture; and (b) mechanically mixing the homogeneous liquid mixture with a high shearing stress, to produce a superheavy oil emulsion fuel having a particle size distribution. In this method, a 10% cumulative particle size is from 1.5 to 8 .mu.m, a 50% cumulative particle size is from 11 to 30 .mu.m, and a 90% cumulative particle size is from 25 to 150 .mu.m, and coarse particles having particle sizes of 150 .mu.m or more occupy 3% by weight or less in the entire emulsion fuel, and the concentration of the superheavy oil is from 76.5 to 82.0% by weight.Type: GrantFiled: December 1, 1997Date of Patent: March 9, 1999Assignees: Kao Corporation, Mitsubishi Jukogyo Kabushiki KaishaInventors: Noboru Moriyama, Akio Hiraki, Toshimitsu Ichinose, Koichi Sakamoto
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Patent number: 5873916Abstract: A fuel emulsion blending system and method for operating the same is provided. The disclosed embodiments of the fuel emulsion blending system includes a plurality of fluid circuits, including a hydrocarbon circuit, a fuel emulsion additive circuit, a water circuit and an optional alcohol/methanol circuit. Each of the inlet circuits are adapted for receiving the identified ingredient from a suitable source which optionally may be included as part of the blending system. The disclosed blending system further includes a first blending station adapted to mix the hydrocarbon fuel and fuel emulsion additives and a second blending station adapted to mix the hydrocarbon fuel and additive mixture received from the first blending station together with the water received from the source of water. The disclosed blending system further includes an emulsification station downstream of the blending stations which is adapted to emulsify the mixture of hydrocarbon fuel, additives and water to yield a stable fuel emulsion.Type: GrantFiled: February 17, 1998Date of Patent: February 23, 1999Assignee: Caterpillar Inc.Inventors: Richard A. Cemenska, Gerald N. Coleman, Carlos H. Cortes, Ed Jakush, Ted. W. Scheuermann
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Patent number: 5863301Abstract: A heavy hydrocarbon, oil-in-water emulsion that has a relatively low viscosity for improved transport is disclosed. The emulsion is produced by combining the heavy hydrocarbon with an aqueous solution of emulsifier with agitation. The emulsifier has an HLB value of about 13 to about 16. The emulsifier can be anionic, nonionic, amphoteric, or a mixture thereof. Stirring is effected at medium shear values of about 0.1 sec.sup.-1 to about 20 sec.sup.-1 and at a mixer speed of 50 to 2000 rpm. The mixer imparts sufficient power and shear to the emulsion so that a mean oil droplet size of about 30 .mu.m is obtained.Type: GrantFiled: January 3, 1997Date of Patent: January 26, 1999Assignee: Empresa Colombiana de Petroleos ("ECOPETROL")Inventors: Jorge Luis Grosso, Martha Josefina Parra, Omar Caceres, Edelmira Afanador, Humberto Vidales, Fabio Enrique Hernandez, Rigoberto Barrero, Miguel Ruiz
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Patent number: 5856680Abstract: A petroleum derived oil is subjected to crude oil distillation or propane deasphalting to yield a viscous asphalt residue. The viscous asphalt residue is combined with an aqueous emulsifier comprising an EO-PO-EO block copolymer and passed through a mixer at 60.degree. C. to 70.degree. C. to form an emulsion. Criticality has been found in the amount of propylene oxide in the block copolymer and in the asphalt particle size. These emulsions are stable and can be transported by pumping through a pipeline. They are used as boiler fuel. They are also gasified with insufficient oxygen to produce synthesis gas.Type: GrantFiled: April 1, 1996Date of Patent: January 5, 1999Assignee: Texaco IncInventor: Shailaja Madhusudhan Shirodkar
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Patent number: 5851245Abstract: A method for producing a superheavy oil emulsion fuel comprising the steps of (i) preparing a liquid mixture comprising a superheavy oil, water, one or more nonionic surfactants having an HLB (hydrophilic-lipophilic balance) of 13 to 19, and optionally one or more stabilizers, and then agitating the resulting liquid mixture with a high shear rate of 1000/sec to 60000/sec, to give an oil-in-water (O/W) type emulsion fuel having a superheavy oil concentration of from 74 to 82% by weight; and (ii) adding at least one of ionic dispersants, and optionally water, to the emulsion fuel obtained in step (i), and then blending and agitating the resulting liquid mixture with a shear rate of 10/sec to 10000/sec, to give an oil-in-water (O/W) type emulsion fuel having a superheavy oil concentration of from 68 to 79% by weight. In step (i), the nonionic surfactants are contained in an amount of from 0.1 to 0.8% by weight of the emulsion fuel obtained in step (i), and the stabilizers are contained in an amount of from 0.Type: GrantFiled: May 23, 1997Date of Patent: December 22, 1998Assignees: Kao Corporation, Mitsubishi Heavy Industries, Ltd.Inventors: Noboru Moriyama, Akio Hiraki, Toshimitsu Ichinose, Koichi Sakamoto
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Patent number: 5834539Abstract: A multiple phase emulsion or gel including a water phase within at least one oil phase in which either or both of the phases contains one or more chemical moieties selected from a group consisting of organic compounds that have multiple hydroxide functionality, cholesterol, lecithin, multiple valent metal ions, saponified organic acids, unsaponified organic acids, saponified organic bases, unsaponified organic bases, nonionic surfactants and amphoteric compounds. The water and oil phase is also within a second water or oil phase in which the second water or oil phase is obtained by mixture of chemical moieties selected from a group consisting of organic acids, tall oil products, organic bases, phosphates, sulfates, nonionic chemicals, amphoterics and betaines.Type: GrantFiled: April 9, 1996Date of Patent: November 10, 1998Inventor: Dennis Krivohlavek
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Patent number: 5820640Abstract: A novel diesel engine fuel is in the form of a pyrolysis liquid-in-diesel oil microemulsion fuel comprising: (a) diesel oil in an amount sufficient to form a continuous phase in the composition; (b) a pyrolysis liquid forming a discontinuous phase in the composition, this pyrolysis liquid being a liquid obtained by rapid pyrolysis of biomass; and (c) at least one emulsifier selected from nonionic hydrophilic surfactants with HLB between 4 and 18, derived from fatty acids and polyoxyethylene glycol, or fatty acids, sorbitol and polyoxyethylene or polyethoxylated alcohols with long aliphatic chains. This fuel has excellent stability and physical properties similar to those of regular diesel fuel.Type: GrantFiled: July 9, 1997Date of Patent: October 13, 1998Assignee: Natural Resources CanadaInventors: Michio Ikura, Siamak Mirmiran, Maria Stanciulescu, Henry Sawatzky
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Patent number: 5807476Abstract: A method of removing hazardous sulfur compounds, such as hydrogen sulfide and sulfur dioxide, from sour crude oil and sour natural gas. An aqueous composition of an amine oxide surfactant, and preferably a mixture of an amine oxide surfactant and enzymes, is mixed with the sour crude oil or sour natural gas. The surfactant reacts with the hazardous sulfur compounds to eliminate the evolution of the compounds from the crude oil or gas and the enzymes act to catalyze the reaction.Type: GrantFiled: October 10, 1995Date of Patent: September 15, 1998Assignee: United Laboratories, Inc.Inventors: Bevan C. Collins, Pat A. Mestetsky, Nicholas J. Savaiano
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Patent number: 5800576Abstract: The present invention provides water cluster compositions characterized by high oxygen reactivity due to protruding, delocalized p.pi. orbitals. The invention also provides methods of producing the structures. The invention further provides methods of using the water clusters, for example in combustion, and compositions associated therewith.Type: GrantFiled: November 13, 1996Date of Patent: September 1, 1998Assignee: Quantum Energy Technologies CorporationInventors: Keith H. Johnson, Bin Zhang, Harry C. Clark
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Patent number: 5792223Abstract: A stable hydrocarbon-in-water emulsion includes a hydrocarbon phase containing natural surfactant; a water phase having an electrolyte content greater than about 10 ppm (wt) and less than or equal to about 100 ppm (wt) with respect to the water phase; and a surfactant additive including an amine and an ethoxylated alcohol in amounts effective to activate the natural surfactant and stabilize the emulsion.Type: GrantFiled: March 21, 1997Date of Patent: August 11, 1998Assignee: Intevep, S.A.Inventors: Hercilio Rivas, Xiomara Gutierrez, Antonio E. Cardenas, Amanda Morles
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Patent number: 5779990Abstract: A method of and apparatus for manufacturing hydrous oil are provided low frequency and low voltage and current signals are applied to a water supply pipe system and a low frequency and low voltage and current signal is applied to an oil supply system. The water and oil mix with each other at a mixing point and a plurality of low frequency and low voltage and current signals are applied to a mixing supply system formed by joining the water supply pipe system and oil pipe system. The mixture of water and oil is subjected to emulsification in a heater-equipped emulsion tank and the emulsification is facilitated with the aid of air so as to produce the hydrous oil. After a low frequency and low voltage and current signal is applied to the hydrous oil, air is supplied to the hydrous oil in an aeration tank. Further, after a low frequency and low voltage current signal is applied to the hydrous oil, the hydrous oil is flowed in a storage tank.Type: GrantFiled: November 13, 1996Date of Patent: July 14, 1998Assignee: Yoshihiro IwataInventor: Yoshihiro Iwata
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Patent number: 5746783Abstract: A method and matter of composition for controlling NO.sub.x emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO.sub.x produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.Type: GrantFiled: November 8, 1995Date of Patent: May 5, 1998Assignee: Martin Marietta Energy Systems, Inc.Inventors: Alicia L. Compere, William L. Griffith, George F. Dorsey, Brian H. West
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Patent number: 5743922Abstract: An improved lubricity water and diesel fuel emulsion is presented. The emulsion is used as fuel for diesel engines, and includes a lubricity additive selected from the group consisting of dimer acids, trimer acids, phosphate esters, sulfurized castor oil, and mixtures thereof.Type: GrantFiled: March 21, 1994Date of Patent: April 28, 1998Assignee: Nalco Fuel TechInventors: Jeremy D. Peter-Hoblyn, James M. Valentine, Leonard Dubin
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Patent number: 5725609Abstract: A combustible fuel for diesel engines and a process for forming same in the form of a water in hydrocarbon emulsion wherein the mean water drop diameter is .ltoreq.4 .mu.m with a maximum diameter of .ltoreq.10 .mu.m.Type: GrantFiled: February 9, 1996Date of Patent: March 10, 1998Assignee: Intevep, S.A.Inventors: Hercilio Rivas, Gustavo A. Nunez, Tulio Colmenares, Manuel Chirinos
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Patent number: 5693106Abstract: Platinum group metal fuel additives are effective in fuel environments which make the exclusion of water impractical. The fuels additives comprise a platinum group metal compound and a water-functional composition selected from the group consisting of lipophilic emulsifiers, lipophilic organic compounds in which water is miscible and mixtures of these. The additives are preferably effective in fuel compositions having water contents of at least about 0.01% water by weight.Type: GrantFiled: January 13, 1995Date of Patent: December 2, 1997Assignee: Platinum Plus, Inc.Inventors: Jeremy D. Peter-Hoblyn, Barry N. Sprague, James M. Valentine
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Patent number: 5679236Abstract: A fuel mixture combusting virtually free of pollutants and, in addition, requiring only very small quantities of combustible hydrocarbons is produced by introducing liquid fuel, low-nitrogen air and water into a chamber (9) provided with at least one ultrasonic oscillator (7); by decomposing the fuel introduced and at least partially decomposing the water by cavitation; by dispersing the water and the air in the decomposed fuel; and by at least partially electrolytically decomposing the water. The fuel mixture has a foam-like consistency, is very easily combustible and can be stored for a longer time.Type: GrantFiled: February 1, 1996Date of Patent: October 21, 1997Assignee: PPV Verwaltungs AGInventor: Gunter Poschl
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Patent number: 5669938Abstract: A fuel composition which comprises a water-in-oil emulsion comprising a major proportion of a hydrocarbonaceous middle distillate fuel and about 1 to about 40 volume percent water, and an emission reducing amount of at least one fuel-soluble organic nitrate ignition improver such as 2-ethylhexyl nitrate provides important benefits for reduction of exhaust emissions from diesel engines.Type: GrantFiled: December 21, 1995Date of Patent: September 23, 1997Assignee: Ethyl CorporationInventor: Scott Daniel Schwab
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Patent number: 5622920Abstract: A method for forming a stable emulsion of a viscous hydrocarbon in an aqueous buffer solution includes the steps of: providing a viscous hydrocarbon containing an inactive natural surfactant and having a salt content by weight of less than or equal to about 15 ppm and having a water content by weight of less than or equal to about 0.1%; forming a solution of a buffer additive in an aqueous solution to provide a basic aqueous buffer solution, the buffer additive being operative to extract and activate the inactive natural surfactant from the viscous hydrocarbon; and mixing the viscous hydrocarbon with the aqueous buffer solution at a rate sufficient to provide an emulsion of the viscous hydrocarbon in the aqueous buffer solution, whereby the buffer additive extracts the inactive natural surfactant from the viscous hydrocarbon into the aqueous buffer solution and activates the inactive natural surfactant so as to stabilize the emulsion. According to the invention, the buffer additive is a water soluble amine.Type: GrantFiled: March 13, 1995Date of Patent: April 22, 1997Assignee: Intevep, S.A.Inventors: Hercilio Rivas, Socrates Acevedo, Xiomara Gutierrez
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Patent number: 5603864Abstract: A method for forming a stable bimodal emulsion comprises admixing a viscous hydrocarbon with an aqueous buffer solution under controlled conditions so as to obtain a first monomodal emulsion having an average hydrocarbon droplet size of less than 5 microns. The monomodal emulsion is thereafter diluted with water and additional viscous hydrocarbon is admixed with the diluted monomodal emulsion under a second mixing energy sufficient to produce a bimodal emulsion wherein the average small hydrocarbon droplet size is less than or equal to 5 microns and the average large hydrocarbon droplet size is less than or equal to about 30 microns.Type: GrantFiled: December 13, 1994Date of Patent: February 18, 1997Assignee: Intevep, S.A.Inventors: Felix Silva, Hercilio Rivas, Gustavo Nunez, Dolores Pazos
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Patent number: 5584894Abstract: The present invention relates to a process for reducing nitrogen oxides emissions from a diesel engine, which comprises preparing an emulsion of water in diesel fuel which contains a catalytically effective amount of catalyst composition and a lubricity additive, and supplying said emulsion to a diesel engine for combusting therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.Type: GrantFiled: May 31, 1994Date of Patent: December 17, 1996Assignee: Platinum Plus, Inc.Inventors: Jeremy D. Peter-Hoblyn, James M. Valentine
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Patent number: 5556574Abstract: A method for forming a stable emulsion of a viscous hydrocarbon in an aqueous buffer solution includes the steps of: providing a viscous hydrocarbon containing an inactive natural surfactant and having a salt content by weight of less than or equal to about 15 ppm and having a water content by weight of less than or equal to about 0.1%; forming a solution of a buffer additive in an aqueous solution to provide a basic aqueous buffer solution, the buffer additive being operative to extract and activate the inactive natural surfactant from the viscous hydrocarbon; and mixing the viscous hydrocarbon with the aqueous buffer solution at a rate sufficient to provide an emulsion of the viscous hydrocarbon in the aqueous buffer solution, whereby the buffer additive extracts the inactive natural surfactant from the viscous hydrocarbon into the aqueous buffer solution and activates the inactive natural surfactant so as to stabilize the emulsion. According to the invention, the buffer additive is a water soluble amine.Type: GrantFiled: June 7, 1995Date of Patent: September 17, 1996Assignee: Intevep, S.A.Inventors: Hercilio Rivas, Socrates Acevedo, Xiomara Gutierrez
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Patent number: 5551956Abstract: A superheavy oil emulsion fuel having a low viscosity and a good long-term stability, which comprises, in a mixed and emulsified state, 100 parts by weight of a superheavy oil, 25 to 80 parts by weight of water and 0.02 to 5 parts by weight of a specific nonionic surfactant.A method for regenerating an oil-in-water superheavy oil emulsion fuel deteriorated to such a slight extent that the emulsion fuel can be pumped and handled as a fluid liquid to give an oil-in-water superheavy oil emulsion fuel having a good fluidity and a low unburned content, and a method for regenerating an oil-in-water superheavy oil emulsion fuel deteriorated to such a remarkable extent that the emulsion fuel has such a high viscosity that the pumping thereof is difficult and cannot be handled as a fluid liquid to give an oil-in-water superheavy oil emulsion fuel having a good fluidity and a low unburned content, wherein use is made of a specific nonionic surfactant.Type: GrantFiled: March 17, 1994Date of Patent: September 3, 1996Assignees: Kao Corporation, Mitsubishi Jukogyo Kabushiki KaishaInventors: Noboru Moriyama, Tsugitoshi Ogura, Akio Hiraki
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Patent number: 5535708Abstract: The present invention relates to a process for reducing nitrogen oxides emissions from a diesel engine, which comprises preparing an emulsion of an aqueous urea solution in diesel fuel, and supplying said emulsion to a diesel engine for combusting therein, whereby combustion of the emulsion leads to a reduction in the nitrogen oxides emissions from the diesel engine when compared with combustion of diesel fuel alone.Type: GrantFiled: October 31, 1994Date of Patent: July 16, 1996Assignee: Platinum Plus, Inc.Inventor: James M. Valentine
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Patent number: 5513584Abstract: A process for the in-situ production of an effluent sorbent-oxide aerosol during the combustion of a hydrocarbon containing fuel whereby the effluents are removed from the resultant gaseous hydrocarbon stream comprises admixing an aqueous solution of the sorbent with the fuel, atomizing and combusting the mixture under controlled conditions so as to generate the effluent sorbent-oxide aerosol.Type: GrantFiled: March 26, 1990Date of Patent: May 7, 1996Assignee: Intevep, S.A.Inventors: Domingo Rodriguez, Jose Carrazza
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Patent number: 5505877Abstract: A multiple phase emulsion or gel including a water phase within at least one oil phase in which either or both of the phases contains one or more chemical moieties selected from a group consisting of organic compounds that have multiple hydroxide functionality, cholesterol, lecithin, multiple valent metal ions, saponified organic acids, unsaponified organic acids, saponified organic bases, unsaponified organic bases, nonionic surfactants and amphoteric compounds. The water and oil phase is also within a second water or oil phase in which the second water or oil phase is obtained by mixture of chemical moieties selected from a group consisting of organic acids, tall oil products, organic bases, phosphates, sulfates, nonionic chemicals, amphoterics and betaines.Type: GrantFiled: May 26, 1993Date of Patent: April 9, 1996Inventor: Dennis Krivohlavek
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Patent number: 5505876Abstract: A low viscosity, non-aging hydrocarbon in water emulsion formed from a viscous hydrocarbon comprises from about 70 to 80%/wt. oil, from about 20 to 30%/wt. water, from about 0.1 to 5.0%/wt. of an emulsifying agent, and an average oil droplet size of greater than or equal to 15 microns wherein the emulsion is characterized by a viscosity of less or equal to 1500 centipoise at 80.degree. F. and substantial non-aging over time wherein the change in viscosity of the emulsion is less than 100 centipoise per month.Type: GrantFiled: June 14, 1994Date of Patent: April 9, 1996Assignee: IntevepInventors: Hercilio Rivas, Maria L. Ventresca, Gerardo Sanchez
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Patent number: 5503772Abstract: A stable, low viscosity bimodal oil in water emulsion having an emulsifier, a continuous water phase and a discontinuous oil phase having an oil:water ratio of from about 70:30 to about 85:15 by weight, the discontinuous oil phase being characterized by two distinct oil droplet sizes D.sub.L and D.sub.S wherein D.sub.L is about 10 to 40 microns and D.sub.S is less than or equal to 5 microns, the ratio of D.sub.L /D.sub.S is greater than or equal to 4 and about 45 to 85% by weight of the oil is in oil droplet size D.sub.L.Type: GrantFiled: March 1, 1995Date of Patent: April 2, 1996Assignee: Intevep, S.A.Inventors: Hercilio Rivas, Gustavo Nunez, Gerardo Sanchez
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Patent number: 5499587Abstract: A process for the in-situ production of an effluent sorbent-oxide aerosol with promoter during the combustion of a hydrocarbon containing fuel whereby the effluents are removed from the resultant gaseous hydrocarbon stream comprises admixing an aqueous solution of the sorbent and promoter with the fuel, atomizing and combusting the mixture under controlled conditions so as to generate the effluent sorbent-oxide aerosol.Type: GrantFiled: February 19, 1991Date of Patent: March 19, 1996Assignee: Intevep, S.A.Inventors: Domingo Rodriquez, Roy Payne, Cebers Gomez, Jose Carrazza, John Kramlich
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Patent number: 5480583Abstract: A method for forming a stable emulsion of a viscous hydrocarbon in an aqueous buffer solution includes the steps of: providing a viscous hydrocarbon containing an inactive natural surfactant and having a salt content by weight of less than or equal to about 15 ppm and having a water content by weight of less than or equal to about 0.1%; forming a solution of a buffer additive in an aqueous solution to provide a basic aqueous buffer solution, the buffer additive being operative to extract and activate the inactive natural surfactant from the viscous hydrocarbon; and mixing the viscous hydrocarbon with the aqueous buffer solution at a rate sufficient to provide an emulsion of the viscous hydrocarbon in the aqueous buffer solution, whereby the buffer additive extracts the inactive natural surfactant from the viscous hydrocarbon into the aqueous buffer solution and activates the inactive natural surfactant so as to stabilize the emulsion. According to the invention, the buffer additive is a water soluble amine.Type: GrantFiled: January 4, 1993Date of Patent: January 2, 1996Assignee: Intevep, S.A.Inventors: Hercilio Rivas, Socrates Acevedo, Xiomara Gutierrez
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Patent number: 5478365Abstract: Disclosed is a combustible heavy hydrocarbon-in-water emulsion comprising: a. a nitrogen base neutralized phosphate-ester emulsifier in about 0.2 to about 1.0 wt. % amount; b. a water-soluble emulsion stabilizer comprising a high molecular weight water-soluble thickener in about 0.02 to about 0.2 wt. % amount; c. water in about 25 to 50 wt. % amount; and d. a high-softening point hydrocarbon material in an amount to make 100 wt. % emulsion wherein said hydrocarbon material is present in said emulsion in the form of substantially spherical particles having a median diameter in the range of 1 to 30 microns. Also disclosed and claimed is a combustible slurry fuel made from said emulsion which contains carbonaceous solids, particularly petroleum coke. The process for making the emulsion and slurry fuel is also disclosed and claimed.Type: GrantFiled: February 15, 1991Date of Patent: December 26, 1995Assignee: Chevron U.S.A. Inc.Inventors: Manuch Nikanjam, Charles T. Buse, David A. Kohler, John W. Muzatko
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Patent number: 5478366Abstract: A pumpable slurry for recovering fuel value from lignin by mixing the lignin with water, fuel oil and a dispersing agent to form a stable thixotropic or near Newtonian portable slurry by coordinating the amounts of lignin, water and fuel oil to produce a substantially slurry suitable for use as a liquid fuel having a viscosity after stirring of 100 to 1,000 mPa.s.Type: GrantFiled: September 28, 1994Date of Patent: December 26, 1995Assignee: The University of British ColumbiaInventors: Khay C. Teo, Alan P. Watkinson
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Patent number: 5445656Abstract: The present invention relates to a fuel for reducing the noxiousness of exhaust gases, particularly for internal-combustion engines. The fuel has the peculiarity of comprising a mixture of a combustible fuel with 10 to 42% water by weight with respect to the combustible fuel, with the addition of a lubricating antifreeze activator in an amount comprised between 0.5 and 2% by weight of the amount of combustible fuel. The mixture is atomized and stabilized by means of a turbine transducer which provides an electro-magneto-mechanical action, subjecting the mixture, in succession, to positive-pressure actions alternated with negative-pressure actions at high frequency.Type: GrantFiled: September 16, 1993Date of Patent: August 29, 1995Inventor: Ernesto Marelli
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Patent number: 5419852Abstract: A stable, low viscosity bimodal oil in water emulsion having an emulsifier, a continuous water phase and a discontinuous oil phase having an oil:water ratio of from about 70:30 to about 85:15 by weight, the discontinuous oil phase being characterized by two distinct oil droplet sizes D.sub.L and D.sub.S wherein D.sub.L is about 10 to 40 microns and D.sub.S is less than or equal to 5 microns, the ratio of D.sub.L /D.sub.S is greater than or equal to 4 and about 45 to 85% by weight of the oil is in oil droplet size D.sub.L.Type: GrantFiled: December 2, 1991Date of Patent: May 30, 1995Assignee: Intevep, S.A.Inventors: Hercilio Rivas, Gustavo Nunez, Gerardo Sanchez
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Patent number: 5411558Abstract: An oil-in-water type heavy oil emulsion fuel having a specific and broad particle size distribution which has a viscosity close to that of water, can be sufficiently atomized at a temperature of room temperature to 90.degree. C., is excellent in the handleability and fluidity, despite a very high heavy oil concentration, and has a very excellent stability such that neither precipitation nor increase in the viscosity occurs even after storage for a long period of time is prepared according to the present invention. Oil-in-water type heavy oil emulsion fuel according to the present invention can be used as a substitute fuel for heavy fuel oil without modification of the boilers. Further, the combustion efficiency of the heavy oil emulsion fuel according to the present invention is high and it is possible to reduce the amount of nitrogen oxides and sulfur oxides after combustion.Type: GrantFiled: August 26, 1993Date of Patent: May 2, 1995Assignees: Kao Corporation, Nippon Oil Company, LimitedInventors: Takao Taniguchi, Masanori Iizuka, Kazuo Isobe, Sayuri Tamaki, Shinichi Satake, Tadakazu Yamashita
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Patent number: 5401341Abstract: This invention relates to water-in-oil emulsion explosives in which an oxidizing material is contained in the discontinuous water phase, and the continuous oil phase acts as a carbonaceous fuel. More particularly, this invention relates to such explosives in which polyfunctional carboxylic acids, sulfonic acids, or phosphorous-containing acids, soluble in the oil phase, are caused to cross-link using an inorganic cross-linker, thereby causing the viscosity of the emulsion to increase.Type: GrantFiled: January 19, 1994Date of Patent: March 28, 1995Assignee: The Lubrizol CorporationInventors: John W. Forsberg, Nils O. Pearson
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Patent number: 5380343Abstract: Improved microemulsion fuels are prepared from about 70-99% alcohol-fatty acid esters, about 1-30% alcohol and less than 1% alkali metal soap.Type: GrantFiled: February 1, 1993Date of Patent: January 10, 1995Inventor: Herbert F. Hunter
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Patent number: 5372613Abstract: New and improved (1) hydrocarbon, per se (nonhydrosol), fuels and compositions plus, additionally, new and improved (2) hydrosol (water/hydrocarbon) fuels and fuel compositions made possible by the development and use of novel additives thereto and additive packages therefor including, for example; (1) improved hydrocarbon fuel compositions, per se, comprising a hydrocarbon fuel including from about 67% to 97.Type: GrantFiled: April 19, 1993Date of Patent: December 13, 1994Inventor: Kenneth Mekonen
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Patent number: 5360458Abstract: This invention provides for water-oil emulsions comprising water, oil and a minor emulsifying amount of the reaction product of: (A) at least one saturated or unsaturated aliphatic monocarboxylic acid of about 12 to about 24 carbon atoms; (B) at least one acid of the general formula C.sub.19 H.sub.n COOH, wherein n is a number in the range of about 27 to about 31, and having a phenathrene nucleus; and (C) at least one amine. In one hydroxy embodiment, the oil employed in these emulsions can be any oil, the water content of these emulsions being up to about 30% by weight. In a preferred embodiment, the oil employed is crude oil. These emulsions can be facilitatingly pumped through a conduit even when the oil employed is a viscous crude oil. These emulsions are useful as a combustible fuel when the water content is below about 30% by weight.Type: GrantFiled: June 19, 1991Date of Patent: November 1, 1994Assignee: The Lubrizol CorporationInventors: John W. Forsberg, Richard W. Jahnke
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Patent number: 5344306Abstract: The invention presented relates to a process for reducing nitrogen oxides emissions from a gas turbine. The process involves forming an emulsion of water and fuel oil and simultaneously combusting the thusly formed emulsion with natural gas in a gas turbine.Type: GrantFiled: August 28, 1991Date of Patent: September 6, 1994Assignee: Nalco Fuel TechInventors: Donald T. Brown, Alexander S. Dainoff
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Patent number: 5338485Abstract: Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups are disclosed, which are prepared by transesterification of polyacrylate alkyl esters, the alkyl groups of which have 1 to 4 carbon atoms and which were obtained by free radical polymerization, wherein the transesterification is carried out with a mixture of selected alcohols and polyoxyalkylene monools. Compared to products obtained by copolymerization, the transesterification products are largely free of undesirable low molecular weight components, have a narrow molecular weight distribution and exhibit excellent surfactant properties. They are useful especially as W/O emulsifiers for natural and synthetic oils.Type: GrantFiled: February 27, 1992Date of Patent: August 16, 1994Assignee: The Goldschmidt AGInventors: Jurgen Fock, Eberhard Esselborn, Dietmar Schaefer
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Patent number: 5288295Abstract: A fuel comprised of liquid and solid refinery waste streams is described. The fuel is a blend of a heavy paraffinic oil, an emulsified waste oil, water and solids. The fuel is blended both to achieve a viscosity which enables the fuel to be pumped, and to obtain the required fuel value for burning in a cement kiln while simultaneously having a high solids content. The amount of the heavy paraffinic oil present in the final fuel is related to the ambient temperature at which the fuel is to be pumped, stored and consumed. Typically, the higher the ambient temperature the more heavy paraffinic oil that can be used in the fuel blend.Type: GrantFiled: February 8, 1993Date of Patent: February 22, 1994Assignee: Romic Chemical CorporationInventors: Ron Hypes, Peter Morton
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Patent number: 5284492Abstract: An improved lubricity water and fuel oil emulsion is presented. The emulsion is used as fuel for an electric power generating turbine, and includes a lubricity additive selected from the group consisting of dimer acids, trimer acids, phosphate esters, sulfurized castor oil, and mixtures thereof. Also included is a method for improving the combustion efficiency of a turbine, using the inventive additives.Type: GrantFiled: October 8, 1992Date of Patent: February 8, 1994Assignee: Nalco Fuel TechInventor: Leonard Dubin
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Patent number: 5283001Abstract: A process for preparing a water continuous emulsion from heavy crude fraction. A process for preparing a double emulsion.Type: GrantFiled: April 18, 1991Date of Patent: February 1, 1994Assignee: Canadian Occidental Petroleum Ltd.Inventors: Armand A. Gregoli, Daniel P. Rimmer, John A. Hamshar
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Patent number: 5263848Abstract: A process for preparing an oil-in-aqueous phase emulsion and removing contaminants from a contaminated hydrocarbon. The process comprises mixing a contaminated hydrocarbon with a reactant and an emulsifying composition. Contaminants are removed from the contaminated hydrocarbon either during the mixing, after the mixing, or during the combustion of the mixture, or after combustion of the mixture such as from combustion flue gases.Type: GrantFiled: February 16, 1989Date of Patent: November 23, 1993Assignee: Canadian Occidental Petroleum, Ltd.Inventors: Armand A. Gregoli, Andrew M. Olah, John A. Hamshar, Daniel P. Rimmer
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Patent number: 5244475Abstract: An emulsion composition with a polymerizing and/or crosslinking agent and method for its use in improving the manufacturing, packaging, transporting, storage placement and blasting characteristics of explosives containing an emulsion. More specifically, compositions and methods directed to controlling the rheology of an emulsion or explosive containing an emulsion by polymerizing and/or crosslinking the continuous phase of the emulsion by employing hydroxy-terminated polybutadiene and polymerizing agents and/or maleic anhydride adducted polybutadiene and crosslinking agents, but without compromising the integrity of the explosive reaction.Explosive materials comprised of a water-in-oil emulsion containing a continuous carbonaceous fuel phase at least partially polymerized and/or crosslinked.Type: GrantFiled: December 4, 1990Date of Patent: September 14, 1993Assignee: Mining Services International CorporationInventors: C. Mick Lownds, Steven C. Grow
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Patent number: 5196129Abstract: Stable, single-phased solutions of water-in-oil microemulsions which contain microorganisms and/or parts thereof are described. They are obtained by adding to crude oil and/or at least one product of the refining of same an aqueous concentrated solution of microorganisms and/or parts thereof, in such a way that said aqueous solution is solubilized in crude oil or the refined product and that the blend thus obtained has the form of a stable, single-phased solution.Type: GrantFiled: July 10, 1990Date of Patent: March 23, 1993Assignee: Eniricerche S.p.A.Inventor: Pier L. Luisi
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Patent number: 5133898Abstract: Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups are disclosed, which are prepared by transesterification of polyacrylate alkyl esters, the alkyl groups of which have 1 to 4 carbon atoms and which were obtained by free radical polymerization, wherein the transesterification is carried out with a mixture of selected alcohols and polyoxyalkylene monools. Compared to products obtained by copolymerization, the transesterification products are largely free of undesirable low molecular weight components, have a narrow molecular weight distribution and exhibit excellent surfactant properties. They are useful especially as W/O emulsifiers for natural and synthetic oils.Type: GrantFiled: January 29, 1990Date of Patent: July 28, 1992Assignee: Th. Goldschmidt AGInventors: Jurgen Fock, Eberhard Esselborn, Dietmar Schaefer
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Patent number: 5110443Abstract: A process for converting heavy hydrocarbons into lighter hydrocarbons. The process comprises forming an oil-in-aqueous phase emulsion and feeding the formed emulsion into an ultrasonic reactor wherein heavy hydrocarbons are converted into lighter hydrocarbons.Type: GrantFiled: April 18, 1989Date of Patent: May 5, 1992Assignee: Canadian Occidental Petroleum Ltd.Inventors: Armand A. Gregoli, Andrew M. Olah, John A. Hamshar, Daniel P. Rimmer
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Patent number: 5104418Abstract: A hybrid diesel fuel composition in the form of a microemulsion stable with time over a wide temperature range comprises a diesel fuel, water, a glycolipid surfactant and an aliphatic alcohol co-surfactant.Type: GrantFiled: May 25, 1990Date of Patent: April 14, 1992Assignee: Eniricerche S.p.A.Inventors: Calogero Genova, Irena Blute, Rosario Pappa