Abstract: A multi-chamber continuous tubular reactor for the transesterification of oil (e.g., waste cooking oil and the like) and methanol into glycol and fatty acid methyl (ethel) ester. The reactor includes a plurality of tubes, a plurality of fluidly coupled chambers, an inlet fluidly coupled to a first chamber of the plurality of chambers for receiving reactants, and an outlet fluidly coupled to a second chamber of the plurality of chambers for receiving products generated during a reaction within the plurality of chambers. At least one of the plurality of tubes is at least partially disposed within a lumen of another one of the plurality of tubes. The plurality of fluidly coupled chambers are defined, at least in part, by the plurality of tubes. The reactor is configured to generate a generally helical flow pattern through at least one of the plurality of chambers.

Abstract: This invention relates to a mineral oil containing hindered phenolic antioxidants with improved color stability. More particularly, it relates to non-coloring hindered phenolic blend that contains an oxygen scavenger, i.e., dibenzylhydroxyl amine (DBHA) as well as mineral oils containing such a blend.

Abstract: The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

Abstract: A process for producing mixed esters of fatty acids as biofuel or additive to a petroleum fuel for use in a compression ignition (CI) engine. The process preferably provides a partial transesterification of a mixture of fatty acid methyl esters with at least one alkyl alcohol containing 2 to 8 carbon atoms in the presence of a heterogeneous solid acid catalyst to produce a mixture of the fatty acid methyl esters and alkyl alcohol esters of the fatty acids.

Abstract: The invention relates to a diesel biofuel consisting of a mixture of naturally occurring fatty acid esters and containing an ester of ?-unsaturated acids having a chain with 11 or 13 carbon atoms or corresponding saturated acids. The invention also relates to a method for producing such a biofuel.

Abstract: A fuel composition having an enhanced thermal stability in a diesel fuel application is provided comprising a base fuel containing: (a) 90 to 50% by volume based on the base fuel, of a petroleum refined diesel fuel having sulfur level of less than 500 ppm, and boiling point within the range of about 150 to about 400° C.; (b) 5 to 25% by volume based on the base fuel, a Fischer-Tropsch derived gas oil; and (c) 5 to 25% by volume based on the base fuel, a fatty acid alkyl ester having C18:2 to C18:1 ratio of 1.5 to 2.8 wherein the alkyl group has a carbon number from 1 to 4.

Abstract: A process, adsorbent and apparatus for treating biofuel is disclosed.

Abstract: The present invention relates to a process for producing enzymes and single cell oil. The process comprises that microorganisms capable of producing both single cell oil and enzymes are cultivated under conditions suitable for single cell oil production and enzyme production in a single cell oil production process. A microorganism culture comprising single cell oil and enzymes is obtained and at least part of the microorganism culture, of the supernatant and/or microorganism cells separated from the microorganism culture, of protein fraction enriched from the supernatant, and/or of protein fraction obtained from the cells is used as an enzyme preparation or as a source of enzymes. Single cell oil is recovered from the microorganism cells and used as biofuel, component of biofuel or as a starting material for biofuel production. Enzymes produced according to the process are used in the same or in another industrial process.

Abstract: Fuels and other valuable compositions and compounds can be made from oil extracted from microbial biomass and from oil-bearing microbial biomass via hydroprocessing and/or other chemical treatments, including the alkaline hydrolysis of glycerolipids and fatty acid esters to fatty acid salts.

Abstract: Methods and system for obtaining long chain carbons that generally include forming a conversion mixture of an alcohol and a base, adding the conversion mixture to oil (such as petroleum based oil, crude oil, used oil, used motor oil, and new motor oil) to form a reaction mixture, adding a high nitrate compound the reaction mixture, and separating out the long chain carbons for use as an input by other processing such as pharmaceutical and/or additional petro-chemical processing. Additional cooling and/or filtering processes may be utilized to complete and/or optimize oil conversion.

Abstract: A method and system for providing direct conversion of algal biomass. Optionally, the method and system can be used to directly convert dry algal biomass to biodiesels under microwave irradiation by combining the reaction and combining steps. Alternatively, wet algae can be directly processed and converted to fatty acid methyl esters, which have the major components of biodiesels, by reacting with methanol at predetermined pressure and temperature ranges.

Abstract: The present invention is directed toward compositions suitable for use as dielectric fluids, lubricant fluids and biodiesel fluids. Compositions described herein are obtained from a saturated, unsaturated or combinations of both monol, diol, triol or polyol acyl ester based fluid and/or a non-ester based fluid and 2,4,6-tris(di-C1-C6-alkylaminomethyl) phenol and/or the carboxylic acid salt of 2,4,6-tris(di-C1-C6-alkylaminomethyl) phenol. These compositions demonstrate improved oxidative stability and/or hydrolytic stability at higher use temperatures.

Abstract: A system includes a biodiesel production system and an advanced process controller configured to implement a model predictive control algorithm to control one or more aspects of the biodiesel production system.

Abstract: Ketene chemistry and hydrogenation reactions are used to synthesize fuels and chemicals. Ketene from acetic acid is hydrogenated to form fuels and chemicals; acetic acid can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc. In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass.

Abstract: This invention relates to alternative diesel fuels with improved cold flow properties. The alternative fuel may be a biodiesel which typically comprises fatty acid methyl or ethyl esters; or a diesel fuel blend including diesel fuel derived from a Fischer-Tropsch (FT) reaction and possibly comprising or containing crude-derived diesel fuel and biodiesel. The cold flow properties are improved by adding a higher alcohol component which is not a naturally occurring component of the biodiesel, nor the diesel fuel.

Abstract: The invention relates to a diesel biofuel consisting of a mixture of naturally occurring fatty acid esters and containing an ester of ?-unsaturated acids having a chain with 11 or 13 carbon atoms or corresponding saturated acids. The invention also relates to a method for producing such a biofuel.

Abstract: Processes for thermal conversion of biomass are provided. The processes involve upgrading the pyrolysis vapor from a pyrolysis reactor. The steps include thermally converting a biomass feedstock in a pyrolysis reactor, recovering a pyrolysis vapor from the reactor, passing the pyrolysis vapor in contact with an acid catalyst in the presence of alcohol, and converting the resulting upgraded pyrolysis vapor into a liquid product. The resulting biooil liquid product is more refined, and the overall processes offer economic and energy efficiency.

Abstract: The present invention relates to a method for producing biodiesel comprising a step of generating fatty acid alkyl ester and glycerol by a transesterification of animal and vegetable oils and fats and fatty acid alcohols in the presence of porous materials. The method is characterized by a high response speed and high FAME conversion, and can be performed in a consecutive process. Further, according to the method, a high-purity fatty acid alkyl ester and glycol can be produced irrespective of the content of free fatty acids (FFAs). Further, since the method does not use a catalyst, the total processing time and cost can be reduced, and the method is environmentally friendly.

Abstract: A power generation system, which includes a source of a seed oil, a source of alcohol, and a reactor in communication with the source of seed oil and the source of alcohol. The reactor produces a biofuel product. The system has a power source that operates on a biofuel energy source to produce heated exhaust and is in communication with the reactor to utilize a portion of the biofuel product as its biofuel energy source. The system has a heat transfer mechanism that transfers heat from the exhaust manifold to the reactor. The power source also converts mechanical power into electrical power. Also disclosed is a system that involves extraction of oil from an oilseed product. A method of extracting oil from an oilseed product, a method of making a transesterified seed oil, and a method of making a biofuel are also disclosed, as are products obtained thereby.

Abstract: A liquid fuel composition containing (a) a diesel base fuel suitable for use in an internal combustion engine; and (b) one or more organic sunscreen compounds. The liquid fuel composition of the present invention provides benefits in terms of power output of a diesel engine, and modifying the ignition delay and/or modifying the burn period and/or increasing the cetane number of the liquid fuel composition.

Abstract: A method for producing biodiesel includes feeding methanol into a tank and heating methanol to a temperature above a critical temperature of methanol to obtain a supercritical methanol. A reactive matrix is fed into the tank. The reactive matrix includes acetic acid and a material oil. A molar ratio of acetic acid to the material oil is in a range from 1:1 to 5:1. A molar ratio of methanol to the material oil is in a range from 20:1 to 90:1. A supercritical carbon dioxide is fed into the tank. A total pressure of the supercritical methanol and the supercritical carbon dioxide is higher than 10 MPa. The supercritical methanol, the material oil, acetic acid, and the supercritical carbon dioxide react with each other in the tank at 240-500° C. and 8.1-50 MPa for 0.1-1.5 hours to obtain biodiesel.

Abstract: A liquid fuel composition containing (a) a gasoline base fuel suitable for use in an internal combustion engine; and (b) one or more organic sunscreen compounds. The liquid fuel composition of the present invention provides benefits in terms of improved acceleration and/or power output of an internal combustion engine fuelled by said fuel as well as an increase in flame speed.

Abstract: A process for producing biodiesel from natural oils and/or fats, a low molecular weight C1-C6 alcohol and catalyst is described. The process preferably uses vegetable oils and is specifically configured for producing biodiesel from castor oil.

Abstract: An unleaded gasoline composition comprising: (i) a gasoline base fuel; and (ii) component A, wherein component A is an alkyl alkenoate compound, or a mixture of alkyl alkenoate compounds, selected from compounds of formula I: wherein R1 is a linear alkenyl group containing 3 to 5 carbon atoms, optionally substituted by a methyl group, and R2 is a linear or branched alkyl group containing 1 to 6 carbon atoms. The gasoline composition of the present invention exhibits good lubricity. The gasoline composition of the invention in another aspect provides increased sensitivity.

Abstract: A diesel fuel formulation containing a triethoxypropane and a palm oil methyl ester (POME), and a diesel fuel supplement containing a premix of a triethoxypropane and a POME is disclosed. The triethoxypropane may be 1,2,3-triethoxypropane or 1,1,3-triethoxypropane.

Abstract: The invention relates to methods and compositions for attaining acceptably low uptake of zinc and copper metals in a renewable component of a distillate boiling range fuel composition. The method can advantageously comprise the steps of providing the renewable component comprising blending a tallow ester feed and at least one of soybean oil ester feed and palm oil ester feed, such that the tallow ester feed comprises from about 35 vol % to about 90 vol % of the renewable component, and exposing the renewable component blend to a source of zinc or copper under conditions sufficient for copper and/or zinc to leach into the renewable component, but only to an acceptably low level.

Abstract: An improved, environmentally friendly lighter fluid composition made from renewable resources is described that includes n-butanol and biodiesel. This lighter fluid has reduced VOCs compared to a petroleum-based lighter fluid. The fuel sources such as charcoal ignited with the lighter fluid composition maintain desirable temperature profiles. Food cooked using the lighter fluid composition as the ignition source have improved taste characteristics due to reduced VOCs. Methods of using the lighter fluid compositions are also described.

Abstract: Methods, systems, and devices are disclosed for producing, storing and using alcohol fuels. In one aspect of the disclosed technology, a method to provide a fuel for an engine includes mixing an alcohol with water to produce a wet alcohol, adding a fuel constituent in the wet alcohol to form a liquid fuel, the fuel constituent being soluble in the wet alcohol, and converting, in a container having an interior formed of an armored material, the liquid fuel into a gaseous fuel substance using at least one of heat energy or electrical energy to pressurize the liquid fuel, the gaseous fuel substance exhibiting a higher pressure and lower density than that of the liquid fuel.

Abstract: A methodology for separation and subsequent handling of FAME fractions of biodiesel, comprising of the steps, providing a biodiesel containing several different FAME fractions mixed together, the biodiesel being at a first temperature wherein at the first temperature none of the FAME fractions of the biodiesel have crystallized; bringing the biodiesel to a first crystallizing temperature, wherein when the biodiesel reaches the first crystallizing temperature, a first FAME fraction remains in a non-crystallized, liquid phase while the remaining FAME fractions crystallize; and separating the liquid first FAME fraction from the remaining crystallized FAME fractions.

Abstract: The present invention relates to a composition comprising a) a substance selected from the group of astaxanthinmonoalkanoylesters, astaxanthindialkanoylesters, isozeaxanthin, isozeaxanthinmonoalkanoylesters, isozeaxanthindialkanoylesters and mixtures thereof; and b) a substance selected from the group of alkyl nitrates, nitrooxy esters of alkoxy substituted aliphatic alcohols and organic peroxides; as well as to a change in oxidation reactions of hydrocarbons, especially fuels, admixed to these compositions. The invention also relates to a composition comprising a) a compound selected from the group consisting of astaxanthinmonoalkanoylesters, astaxanthindialkanoylesters, iso-zeaxanthin, iso-zeaxanthinmonoalkanoylesters, iso-zeaxanthindialkanoylesters and mixtures thereof; and c) a fuel.

Abstract: There is disclosed a fuel composition comprising (a) a major amount of a middle distillate fuel comprising from about 0.5% to about 30% by weight fatty acid methyl esters, relative to the total amount of the fuel composition; and (b) a minor amount of an additive composition comprising an antioxidant system comprising at least one cyclic amine antioxidant and at least one phenolic antioxidant, and at least one ashless dispersant, wherein said fuel composition demonstrates reduced sediment formation as compared to a fuel composition devoid of the additive composition, and methods of use thereof.

Abstract: A process for preparing biodiesel having improved filterability characteristics including inducing transesterification of a triglyceride feedstock with cavitation to form an intermediate reaction product. Glycerol by product is separated from the intermediate reaction product before finishing the transesterification reaction in a pressurized reaction tank to yield a biodiesel reaction product. The biodiesel reaction product can be further purified by removing glycerol.

Abstract: The instant invention pertains to new biodiesels which may be blended with petrodiesel. The biodiesels may comprise a fatty acid C1-C2 alkyl ester and a fatty acid branched C3-C4 alkyl ester. Blends of the novel biodiesel and petrodiesel often exhibit advantageous cloud point properties.

Abstract: A diesel fuel formulation with improved lubricity is provided containing (i) a fatty alcohol ester, (ii) an acid-based lubricity additive and (iii) an additional diesel fuel component. The ester (i) has the formula R1-C(O)—O—R2, in which R1 is for example either hydrogen or methyl and R2 is for example a C6 to C14 alkyl group.

Abstract: Compositions of oxygenated gasolines are disclosed that have reduced vapor pressure compared to those containing a single oxygenate and no RVP reducing compound. Such compositions can be formed at a refinery or at a terminal. Methods of reducing vapor pressure of an oxygenated gasoline are disclosed and methods of reducing vapor pressure constraints upon a refinery in the production of oxygenated gasoline are disclosed. Fundamental properties of RVP reducing compounds are disclosed including IR spectrum analysis. Processes and methods for blending and distributing these fuels are also disclosed.

Abstract: The process of this invention removes impurities from transesterification products comprising primarily fatty acid alkyl esters (FAAE) that are being processed for final fuel products, such as biodiesel. The inventive process is catalytic, and the resulting ester is suitable for use as biodiesel. Metal oxide and mixed metal oxide catalysts are particularly suitable. The invention is particularly suitable for treating fatty acid alkyl ester compositions comprising impurities such as glycerin, sterol glycosides, and/or triglyceride, diglyceride and/or monoglyceride. The invention is particularly useful in treating FAAE transesterification products made using homogeneous alkali catalysts. The treated ester exhibits improved performance under cold weather conditions, which can be measured by methods such as ASTM 7501 Cold Soak Filtration Test (CSFT).

Abstract: The invention provides methods of manufacturing biodiesel and other oil-based compounds using glycerol and combinations of glycerol and other feedstocks as an energy source in fermentation of oil-bearing microorganisms. Methods disclosed herein include processes for manufacturing high nutrition edible oils from non-food feedstock materials such as waste products from industrial waste transesterification processes. Also included are methods of increasing oil yields by temporally separating glycerol and other feedstocks during cultivation processes. Also provided herein are oil-bearing microbes containing exogenous oil production genes and methods of cultivating such microbes on glycerol and other feedstocks.

Abstract: A method of manufacturing a biodiesel fuel that comprises mixing a co-solvent, a first reactant and a second reactant together in a mixing chamber to form a homogeneous solution. The first reactant and the second reactant are substantially immiscible with each other in the absence of the co-solvent. The first reactant is one of an alcohol or an oil, and the second reactant is the other of the oil or the alcohol. Method also comprises transferring the homogeneous solution into a transesterification reaction vessel.

Abstract: A method of producing a biodiesel from a wet biomass is provided. The method includes providing the wet biomass that includes water and biomass solids. The method also includes heating the wet biomass at a first temperature and a first pressure for a time period ranging from 10 to 480 minutes to form an aqueous solution and a solid agglomerate containing a hydrolyzed lipid component. The method also includes step of transesterifying the hydrolyzed lipid component to form biodiesel.

Abstract: A fuel composition for a homogenous charge compression ignition engine includes a combination of a gasoline fuel and a diesel fuel, the combination having a derived cetane number of from about 19.9 to 45 as determined in accordance with ASTM method D6890. A method for making the fuel composition provides for blending presently available gasoline fuel and diesel fuel together in a ratio to obtain the desired fuel composition.

Abstract: A process for producing mixed esters of fatty acids as biofuel or additive to a petroleum fuel for use in a compression ignition (CI) engine. The process preferably provides a partial transesterification of a mixture of fatty acid methyl esters with at least one alkyl alcohol containing 2 to 8 carbon atoms in the presence of a heterogeneous solid acid catalyst to produce a mixture of the fatty acid methyl esters and alkyl alcohol esters of the fatty acids.

Abstract: A fuel composition comprising: a diesel base fuel; from 1 to 10% v/v of a fatty acid alkyl ester; and more than 10% v/v of an ether component, the ether component comprising one or more ether compounds having in the range of from 8 to 12 carbon atoms and selected from compounds of formula I R1—O—R2??(I) wherein R1 and R2 are independently primary or secondary alkyl.

Abstract: A diesel fuel formulation is provided containing (i) a fatty acid alkyl ester (FAAE), in particular a fatty acid methyl ester (FAME), (ii) diethyl carbonate (DEC) and (iii) an additional diesel fuel component. Also provided is a diesel fuel supplement containing a FAAE and DEC. The inclusion of DEC, in a FAAE or in a diesel fuel formulation containing a FAAE, increase the stability of one or more glycerides present in the FAAE, and/or reduce the concentration of a stability-enhancing additive in the FAAE or fuel formulation, and/or reduce the amount of glyceride precipitates in the FAAE or fuel formulation. The glycerides are in particular saturated monoglycerides.

Abstract: This invention provides stabilized biodiesels comprising (1) biodiesel, such as fatty acid methyl ester (FAME), (2) mono- or bis-hindered phenolic derived from 2,6-di-tert-butylphenol, and (3) N,N-di-substituted para-phenylene diamine. Also methods of stabilizing biodiesel are provided involving adding (2) and (3) to (1).

Abstract: Disclosed are biodiesel fuels with improved oxidative stability. Disclosed are biodiesel fuels which comprise two or more antioxidants which increase the oxidative stability of the biodiesel fuel.

Abstract: When producing biodiesel from fats, oils or split fatty acids rich in steryl glycosides, the light phase rich in fatty acid alkyl esters, which is obtained from the transesterification or esterification, is washed with water in a washing column, wherein the suspension layer formed is treated by stirring. In this way, the steryl glycosides are transferred into the light phase of the wash. In a subsequent treatment of the light washer phase with water in an intensive mixer, compact steryl glycoside/fatty acid alkyl ester/water agglomerates are obtained, which can easily be separated by means of centrifugation. From the light phase of centrifugation, on-spec biodiesel is obtained upon further processing by drying and/or filtration. This process is suitable for processing fats, oils or split fatty acids with a high content of steryl glycosides and avoids the use of auxiliary substances foreign to the process. It is characterized by simplicity of equipment and a low demand for energy.

Abstract: The present invention describes a composition comprising at least one antioxidant and at least one ethylene vinyl acetate copolymer comprising units being derived from at least one alkyl (meth)acrylate having 1 to 30 carbon atoms in the alkyl residue. The composition is useful as cold flow improver and oxidation stabilizer in fossil fuel oil and or biodiesel fuel oil.

Abstract: The present invention relates to a process and apparatus for the production of diesel fuel from feedstocks containing fatty acids, glycerated fatty acids, and glycerin by catalytic and/or non-catalytic pyrolysis followed by esterification. Specifically, the present invention relates to the production of Renewable Diesel having low glycerin, water, and sulfur content.

Abstract: A process for production of biofuels from algae can include cultivating an oil-producing algae, extracting the algal oil, and converting the algal oil to form biodiesel. Extracting the algal oil from the oil-producing algae can include biologically rupturing cell wall and oil vesicles of the oil-producing algae using at least one enzyme such as a cellulose or glycoproteinase, a structured enzyme system such as a cellulosome, a virus, or combination of these materials.

Abstract: The process described in the instant invention has the steps of dissolving the lipid-containing biomass in an ionic liquid, whereby a lipid phase and a hydrophilic phase are formed. The lipid phase contains primarily triglycerides, which can be converted to biodiesel by transesterification to, e.g., methyl esters. The hydrophilic phase comprises dissolved biopolymers, such as cellulose, hemicellulose, and protein. The biopolymers are converted in situ to compounds that are insoluble in the molten inorganic salt hydrate. The molten inorganic salt hydrates regenerated by removing insolubles, such as lignin, ash from the biomass, and water.