Abstract: Embodiments include a gasification process where the carbon content of the residue from gasification of agricultural waste products and the fly ash content of the gaseous exhaust is controlled by regulated inflow of gasification-supporting air in a plurality of flow stream at different velocities to enhance fluidization of particulate feed in a bed being raked by a rotating sweep arm inducing radially outward movement of gasification residue into a collecting zone from which the residue enters a discharge duct. The particulate feed is dropped at a location in the gasification chamber above the bed in alignment with the inflow stream of maximum velocity.

Abstract: A fuel supply system for supplying pulverized feedstock to a gasifier includes a feedstock storage apparatus for storing pulverized feedstock. The feedstock storage apparatus operates at a first pressure. The fuel supply system also includes a mechanical conveyance apparatus linking the feedstock storage apparatus to a fuel distribution apparatus. The mechanical conveyance apparatus is operable to continuously convey the pulverized feedstock from the feedstock storage apparatus to the fuel distribution apparatus at a first flow rate. The fuel distribution apparatus operates at a second pressure that is greater than the first pressure. The fuel distribution apparatus includes at least one outlet communicably connected to at least one burner on the gasifier for transferring pulverized feedstock from the fuel distribution apparatus to the at least one burner.

Abstract: A reaction device can raise heat use efficiency. The reaction device includes a carbon monoxide remover removing carbon monoxide, and a vaporizer provided inside the carbon monoxide remover to vaporize fuel.

Abstract: An oxidative autothermal reformer including a reforming layer at least partially filled with a reforming catalyst for producing a reformed gas composed mainly of hydrogen through a reforming reaction by contacting a mixture of a hydrocarbon or an aliphatic alcohol and steam with the reforming catalyst; and an oxidative exothermic layer at least partially filled with an oxidation catalyst for generating heat by oxidizing a part of the reformed gas, in which the reforming layer is disposed at an upstream side of the oxidative exothermic layer; the reforming layer and the oxidative exothermic layer are in the form of a cylinder and have a triple circular tube structure formed by disposing an inner reforming layer, an oxidative exothermic layer and an outer reforming layer from the inside in a radial direction in this order; and at least a part of the reforming catalyst filled in the inner reforming layer and the outer reforming layer contains Ru metal.

Abstract: Systems and methods for producing hydrogen gas with a fuel processing system that includes a hydrogen-producing region that produces hydrogen gas from a feed stream and a heating assembly that consumes a fuel stream to produce a heated exhaust stream for heating the hydrogen-producing region. In some embodiments, the heating assembly heats the hydrogen-producing region to at least a minimum hydrogen-producing temperature. In some embodiments, the rate at which an air stream is delivered to the heating assembly is controlled to selectively increase or decrease the temperature of the heated exhaust stream. In some embodiments, the feed stream and the fuel stream both contain a carbon-containing feedstock and at least 25 wt % water. In some embodiments, the feed and fuel streams have the same composition.

Abstract: An improved multiple-tube catalytic reformer comprising a tubular body containing a radiator core having a plurality of longitudinal cells for low-pressure flow-through of combustion gases, the core being formed preferably either by winding of corrugated metal or as an extruded metal monolith. A plurality of reformer tubes, preferably non-cylindrical, containing hydrocarbon catalyst are arrayed in longitudinal openings within the radiator core and preferably are brazed thereto to maximize heat transfer from the radiator core to the reformer tubes. During manufacture, the metal radiator core is economically bored by laser cutting to form the openings to admit the reformer tubes for brazing. Preferably, the reformer tubes are numbered, sized, shaped, and arrayed to minimize the longest conduction path in the radiator core to the center of any reformer tube.

Abstract: A gasifier and gasifier system based on the gasifier, which contains as a major component, a novel feed system for feeding organic materials into the burn pile of the gasifier. The gasifier feed system is a horizontal auger driven feed system that feeds directly through a ceramic elbow into the furnace without having to auger the feed through significant vertical elevations.

Abstract: A device for generating gas by placing a liquid reactant in contact with a solid element, including: a liquid reactant tank, a reaction chamber configured to contain the solid element, an injector configured to inject the liquid reactant onto the solid element, and an outlet port configured to collect the gas generated in the reaction chamber, wherein the tank and the reaction chamber are separated in a sealed manner by a mobile wall, the mobile wall including an outlet port for collecting the gas generated in the reaction chamber, and wherein the injector passes through the mobile wall and configured to move into the solid element.

Abstract: A method of gasification burner online feeding for a coal-water slurry gasifier, where a coal-water slurry line and an oxidizer line are both protected by shield gas. The method may realize online, pressurized and continuous feeding of the gasification burners which are fixed after they stalled for other reasons than their own, thus greatly reducing the probability of accidental shutdown of gasifiers and improving the reliability of long-term service of the multi-nozzle opposed gasifier.

Abstract: In a plate type reformer and a fuel cell system including the plate type reformer, the plate type reformer includes: a plate type combustion reactor including a distributing plate having a distributing chamber with a plurality of distributing holes adapted to supply an oxidizing agent, and a combustion plate having a combustion chamber with an oxidizing catalyst layer adapted to generate heat energy in response to the oxidizing agent supplied through the distributing holes of the distributing plate reacting with fuel; a plate type preheater including a channel adapted to introduce a mixed fuel of fuel and water is introduced, the plate type preheater adapted to preheat the mixed fuel with the heat energy generated in the plate type combustion reactor; and a plate type reforming reactor with a reforming catalyst layer adapted to generate hydrogen gas from the mixed fuel preheated by the plate type preheater, the plate type reforming reactor effecting a reforming reaction using the heat energy of the plate type

Abstract: A system for producing superior quality synthesis gas (“syngas”) consisting of a series of chambers in which the gasification stages of reaction, homogenization and activation occur. The first stage reaction stage agitates and combines the reactants, consisting primarily of organic matter, oxidizer and steam, to initiate gasification of the organic and volatile fraction and to transport the inorganic residue to continuous removal. In the homogenization chamber, turbulence is induced by injecting gaseous species. The gas mixture emerging from the homogenization chamber is accelerated via a third stage communicating duct and is introduced tangentially into the fourth stage activation chamber inducing a cyclonic motion wherein a high intensity radiant heat source is introduced along the central axis of the gas vortex.

Abstract: A method of operating a methanation reactor to reduce carbon monoxide concentration in a reformate stream in a fuel cell reformer. The reactor includes a flowpath with a noble metal catalyst supported by a ceramic support such that the reactor preferentially converts carbon monoxide via methanation over that of carbon dioxide. The reduced level of carbon monoxide present in the reformate stream after passing through the methanation reactor reduces the likelihood of poisoning of the catalyst used on the fuel cell anode.

Abstract: Hydrogen-processing assemblies, components of hydrogen-processing assemblies, and fuel-processing and fuel cell systems that include hydrogen-processing assemblies. The hydrogen-processing assemblies include a hydrogen-separation assembly positioned within the internal volume of an enclosure in a spaced relation to at least a portion of the internal perimeter of the body of the enclosure.

Abstract: An apparatus and method for processing waste material including organic waste and MSW comprises an elongate processing chamber (100) having a processing zone (200, 300) for processing waste at an elevated temperature; wherein the processing chamber (100) has: an inlet (210) for introducing said waste material; an outlet (504) for removal of processed solids; first means (206, 306) for introducing hot gasses into said chamber (100) at a radially outer region of said chamber; and extraction means (102) for extracting gas from a central region of said chamber (100).

Abstract: The present invention provides a cartridge for the generation of hydrogen. The cartridge includes a case, an igniter, and a structural component. The case defines an interior cavity and the igniter is positioned within the cavity. The structural component is also positioned within the cavity and is formed of a particulate embedded in a matrix and the particulate includes a metallic material. An oxidizing agent is positioned within the cavity. The structural component is configured such that the metallic material and the oxidizing agent react together to generate hydrogen after the igniter generates sufficient heat to remove the matrix from the structural component and to initiate the reaction between the metallic material and the oxidizing agent.

Abstract: A multiple adiabatic bed reforming apparatus and process involving stage-wise combustion and multiple reforming chambers. Co-flow and cross-flow occurs under laminar flow conditions. A reformer suitable for small scale production as well as large scale production. A passive stage-by-stage fuel distribution network suitable for low pressure fuel wherein the resistances in successive fuel distribution lines control the amount of fuel delivered to each combustion stage. Heat is captured from reforming syngas product to preheat gases before entering the reformer. Conditions that would produce unwanted coking or metal dusting are avoided or localized away from the heat exchangers to locations which can be cost effectively protected. A chemical reactor which has a core composed of a stack of metal plates that are diffusion bonded in face-to-face relationship.

Abstract: The improvements proposed in this invention provide a reliable apparatus and method to gasify low rank coals in a class of pressurized circulating fluidized bed reactors termed “transport gasifier.” The embodiments overcome a number of operability and reliability problems with existing gasifiers. The systems and methods address issues related to distribution of gasification agent without the use of internals, management of heat release to avoid any agglomeration and clinker formation, specific design of bends to withstand the highly erosive environment due to high solid particles circulation rates, design of a standpipe cyclone to withstand high temperature gasification environment, compact design of seal-leg that can handle high mass solids flux, design of nozzles that eliminate plugging, uniform aeration of large diameter Standpipe, oxidant injection at the cyclone exits to effectively modulate gasifier exit temperature and reduction in overall height of the gasifier with a modified non-mechanical valve.

Abstract: An energy efficient, very flexible and safe feeding apparatus serves for creation of one or more plugs of compressible material for feeding into a gasifier, reactor or other combustion chamber. This apparatus includes a piston feeder with at least three pistons for pre-compressing and delivering compressible material towards a mouthpiece serving as a non-return valve and having an exit end facing a braking device with a friction member for regulating the final degree of compression of the material, and an opposing inlet end for at least partly compressed material. The inner diameter of at least an inlet section extending from the inlet end of the mouthpiece increases towards the first end, so that an angle between the inner wall of at least the inlet section and the longitudinal axis of the mouthpiece is larger than 0° but less than or equal to 3°.

Abstract: Systems and methods for producing synthetic natural gas are provided. The method can include gasifying a carbonaceous feedstock within a gasifier to provide a raw syngas. The raw syngas can be cooled to provide a cooled raw syngas. The cooled raw syngas can be processed in a purification system to provide treated syngas. The purification system can include a flash gas separator in fluid communication with the gasifier and a saturator. The treated syngas can be converted to synthetic natural gas to provide steam, a methanation condensate, and a synthetic natural gas. The methanation condensate can be introduced to the flash gas separator.

Abstract: A method for generating and purifying syngas and to an apparatus for generating and purifying syngas is presented.

Abstract: A method for producing high levels of methane based on a combination of steam hydrogasification and a shift reactor is provided. Hydrogen produced by the shift reactor can be recycled back into the steam hydrogasifier.

Abstract: A gas-generating apparatus (10) includes a reaction chamber (18) containing a solid fuel component (24) and a liquid fuel component (22) that is introduced into the reaction chamber by a fluid path, such as a tube, nozzle, or valve. The flow of the liquid fuel to the solid fuel is self-regulated. Other embodiments of the gas-generating apparatus are also disclosed.

Abstract: In a device for continuously conditioning fed-out natural gas prior to feeding the same to supply lines leading to consumers, comprising a mixing station for producing a burnable gas from natural gas and oxygen, a reactor container for a catalytic combustion of an introduced mixture of burnable gas and natural gas, at least one drying station that is connected downstream of an outlet of the reactor container and has at least one separator, particularly for water, and further comprising at least one expansion fitting for reducing the pressure, it is provided to dispose the reactor container and at least one separator chamber of the separator in an enclosed housing. A mixing chamber, into which a first feed line for fed-out cold natural gas opens, is disposed in the housing between the reactor container and the separator chamber. A transition is provided for the direct entry of the heated natural gas flowing out of the reactor container into the mixing chamber.

Abstract: Provided are a fluidized-bed combustion furnace 1, a separator 8 for separation into bed material 11 and an exhaust gas, a fluidized-bed gasification furnace 40 into which the bed material 11 is introduced through a downcomer 46 and into which raw material is introduced, a circulation passage for circulating char and the bed material 11 to the combustion furnace 1, a dispersion section 43 extending along a width of a bed-material-introduction-side wall 41 of the gasification furnace 40 to receive the bed material 11 from the downcomer, fluidizing-gas introduction means 47 for blowing fluidizing gas into the dispersion section 43 to fluidize the bed material 11 in the section 43, and a supply section 48 for supplying the bed material 11 in the dispersion section 43 to the fluidized-bed gasification furnace 40 substantially evenly throughout the width on the bed-material-introduction side.

Abstract: This invention relates to a hydrogen generator system for generating hydrogen from a water split reaction. The generator comprises a pressure container having a reactant water inlet, and a product hydrogen outlet. Pluralities of cells are vertically stacked inside the container; each cell contains a reactant compound comprising a mechanical mixture of metal and an anti-passivation material. The reactant compound produces hydrogen gas upon contact with water, and the cells are stacked such that water entering from the inlet can rise inside the container and sequentially activate each immersed cell to produce hydrogen gas.

Abstract: A hydrogen generator (101) is provided which comprises a third chamber (109) containing a catalyst (121), a first chamber (103) containing a fluid, a second chamber (105) containing a material that reacts with the fluid in the presence of the catalyst to generate hydrogen gas, and a valve (111) movable from a first position in which the flow of fluid along a pathway including the first, second and third chambers is enabled, to a second position in which the flow of fluid along the pathway is prevented.

Abstract: A method of and an apparatus for gasifying carbonaceous material, the apparatus including a gasification reactor, to which oxygen-containing primary gas and secondary gasification gas are introduced, whereby a portion of the material to be gasified is gasified to product gas, residual carbon contained in the fly ash extracted from the product gas is combusted in a cyclone combustor, and the exhaust gas from the cyclone combustor is guided to above the bottom level of the gasification reactor to act as secondary gasification gas.

Abstract: A down-draft fixed bed gasifier is disclosed that produced clean producer or synthesis gas. The gasifier can be installed at a stationary location or can be scaled down to enable placing the gasifier on a trailer that can be moved to the site of biomass generation. The gasifier is vertically oriented and generally cylindrical, and the design allows for a continual input of feedstock into the gasifier with less clogging and without lowering the gas pressure inside the gasifier. The design incorporates an internal catalyst to clean tars from the produced gas, and uses heat from the combustion chamber of the gasifier to heat the catalyst. The flow of air may be either positive flow or negative flow.

Abstract: A continuous pyrolysis system, comprising a reactor with a charge port, a discharge port and a first gas outlet and a first axial transporting structure installed therein; a hest-source generator for supplying heat necessary for carrying out a pyrolysis reaction in the reactor; a solid-product reformer for performing a reforming process for the solid product of the pyrolysis reaction, with a first solid product inlet, a first solid product outlet and a second gas outlet, and a second axial transporting structure installed therein, wherein the first solid product inlet is communicated with the discharge port of the reactor; and a gas-barrier component for preventing the gas product of the pyrolysis reaction from entering the solid product reformer and transporting the solid product of the pyrolysis reaction into the solid-product reformer, wherein the gas barrier component is installed in a channel communicating the first solid product inlet and the discharge port of the reactor.

Abstract: The inventive stage system for producing hydrogen consists of at least two upstream/downstream stages, respectively, each of which comprises, optionally, a catalytic reactor (C1 to C5) followed by a separator comprising a space (E1 to E4) for circulation of a gaseous mixture contacting at least one oxygen extracting membrane and a hydrogen collecting space, wherein the reactor (C1) of the upstream stage is connected to a reaction gaseous mixture source, the circulation stage (E1) of the upstream stage separator is connected to the reactor (C2) of the downstream stage and the spaces for extracting/collecting oxygen from two separators are connected to a hydrogen collecting circuit (TC, 8) which is common for two stages.

Abstract: A reformer for a fuel cell system includes at least one reaction substrate having a channel for allowing fuel to flow on a surface thereof; and a close contact assembly closely contacted with a surface of the reaction substrate to form a passage by the channel, wherein the reaction substrate includes aluminum.

Abstract: A steam generator used to contain and cool the synthesis gas produced by coal gasification processes employs radiant and convection surfaces, and an integral gasifier, in a specific arrangement to achieve a cost-effective, compact design.

Abstract: A system for removing sulfur from a continuous reformate stream feeding a fuel cell stack. First and second sulfur traps are disposed in parallel between a hydrocarbon reformer and the fuel cell stack. The ends of the sulfur traps are connected to conventional four-way valves such that either trap may be selected for trapping sulfur from the reformate stream, while the other trap is undergoing regeneration by backflushing the accumulated adsorbed sulfur deposits. Thus, the sulfur traps may be used and stripped alternately, permitting continuous supply of desulfurized reformate to the fuel cell assembly. In a currently preferred embodiment, the hot cathode air exhaust is used to assist in stripping the out-of-service trap. In an alternative embodiment, two reformers are provided and the reformers are alternately regenerated along with their respective traps.

Abstract: The present invention is a natural gas steam reforming method for generating an output gas mixture of carbon dioxide and hydrogen, including the following steps. (1) Combusting a portion of the natural gas with an oxidizing agent to generate heat, superheated steam, and a gas mixture of carbon dioxide, carbon monoxide, and hydrogen. (2) Steam reforming the gas mixture with additional superheated steam under steam-rich conditions to transform a remaining portion of the natural gas into carbon dioxide, carbon monoxide, and hydrogen. (3) Water-gas-shifting any residual carbon monoxide into additional carbon dioxide and additional hydrogen by utilizing a water-gas-shift catalyst downstream of the steam reforming step, thereby producing an effluent gas mixture that is predominantly carbon dioxide and hydrogen.

Abstract: A process is described for generating hydrogen through the oxidation of fuels that contain chemically bound hydrogen, in particular hydrocarbons, having the following process steps: a) introducing the fuel (1) as well as the oxidation agent (2) into a reactor (3) having a porous material (4?) that is embodied in such a way that flame propagation in a direction opposite the direction of flow is prevented, and b) reacting the fuel with the oxidation agent in partial oxidation so that hydrogen is obtained in gaseous form. In addition, an apparatus for generating hydrogen that has a reactor that contains a porous material (4, 4?), and the reactor (3) is embodied as a tubular reactor that has a central chamber (5) to introduce the fuel and the oxidation agent that extends in the axial direction and is delimited radially toward the outside by a first wall that has porous material (4), and the first wall is delimited radially toward the outside by a second wall that contains the porous material (4?).

Abstract: A controller for a reformer that: changes the supply quantity of at least either one of combustible gas and combustion oxidizing gas supplied to a combustion section; detects a change which is caused in the combustion state of the combustion section as a result of a change of the supply quantity; and checks the combustion state which arose at the combustion section before the change based on the previously detected detection result. Thus, a gone-out state of the combustion section can be reliably judged with a low cost device, and the combustion state of the combustion section in the reformer of a fuel cell system can be adjusted to an optimum combustion state.

Abstract: A reformer burner that includes a fuel supply tube through which a fuel is supplied and a fuel supply chamber that surrounds the fuel supply tube and has a plurality of atomizing holes to atomize a fuel into a combustion chamber of a reformer.

Abstract: To provide a method and an apparatus for reforming a hydrocarbon with a prolonged life of an oxygen-permeable membrane and a high recovery rate. The oxygen-permeable membrane absorbs the free energy change, ?G, of a partial oxidation reforming reaction and then converts it into work for oxygen isolation and Joule heat, Q. Here, as seen in Table 1 and FIG. 1, ?G of the partial oxidation reforming reaction is approximately ten times larger than ?H, and further increases as the temperature increases. The generated Joule heat, Q, has to be removed at a high efficiency, and this removal process is achieved by returning a portion of the Joule heat to the system as the entropy change, T?S, of the partial oxidation reaction itself and by steam reforming using the total energy change, ?H.

Abstract: A compact hydrogen generator for use with fuel cells and other applications includes a hydrogen membrane reactor having a combustion chamber and a reaction chamber. The two chambers are have a fluid connection and a heat exchange relationship with one another. The hydrogen generation apparatus also includes a fuel supply, a fuel supply line for transporting fuel from the fuel supply to the reaction chamber, an oxygen supply, an oxygen supply line for transporting oxygen from the oxygen supply to the combustion chamber, as well as a tail gas supply line for transporting tail gas supply line for transporting tail gases from the reaction chamber, a combustion by-product line for transporting combustion by-products for the combustion chamber, and a reaction product line for transporting hydrogen from the reaction chamber.

Abstract: The present invention is natural gas steam reforming apparatus for generating an output gas mixture of carbon dioxide and hydrogen. The apparatus is made from two enclosures. A first enclosure contains a source of water, superheated steam, and channels, located within a lower portion of the first enclosure, which contain a water-gas-shift catalyst for converting CO into CO2 and H2. The heat from hot gas flowing through the channels is released into the first enclosure to boil the water to generate the superheated steam. A second enclosure, contained within an upper portion of the first enclosure, includes a steam inlet for receiving the superheated steam from the first enclosure; a combustion chamber; and a reformation chamber. The combustion chamber is used for combusting a portion of the natural gas to generate additional steam, heat, and a hot gas mixture of CO2, CO, and H2.

Abstract: Fuel processors, methods of using fuel processors, and the like, are disclosed.

Abstract: Method and apparatus for generating a low tar, renewable fuel gas from biomass and using it in other energy conversion devices, many of which were designed for use with gaseous and liquid fossil fuels. An automated, downdraft gasifier incorporates extensive air injection into the char bed to maintain the conditions that promote the destruction of residual tars. The resulting fuel gas and entrained char and ash are cooled in a special heat exchanger, and then continuously cleaned in a filter prior to usage in standalone as well as networked power systems.

Abstract: Hydrogen generation materials are a complex hydride which generates hydrogen upon hydrolysis, and an aqueous solution comprising water for causing the hydrolysis, and an accelerator dissolved therein for accelerating a hydrogen generation reaction. A method of hydrogen generation by a hydrogen generator comprises a first step S1 of detecting that the internal pressure of a reactor is lower than a reference pressure, and supplying the aqueous accelerator solution to the reactor; a second step S2 of dissolving the complex hydride in the aqueous accelerator solution to cause a hydrogen generation reaction; and a third step S3 of detecting that the internal pressure of the reactor is higher than the reference pressure, and stopping the supply of the aqueous accelerator solution, and repeats the flow from the first step S1 to the third step S3.

Abstract: The present disclosure is directed to generating hydrogen using thermal energy. In some implementations, a method includes concentrating solar energy on an absorption element to heat the absorption element to about 2,000° C. or greater. The absorption element is in thermal contact with a reservoir of water. The water is at a pressure of, for example, approximately 760 Torr or less, and at least a portion of the water disassociates based on heat from the absorption element. The hydrogen and the oxygen are rapidly cooled to substantially avoid recombination. After cooling, the hydrogen gas and oxygen gas are pressurized and then separated using a size-selective membrane.

Abstract: A hydrogen supplying apparatus equipped with a hydrogen separation membrane and a catalyst plate, which is made by forming a catalyst layer on a metal plate, wherein the metal material of the membrane is different in hardness from that of the catalyst plate. A method of producing the hydrogen supplying apparatus, which comprises: bonding a catalyst plate and a hydrogen separation membrane to each other, by friction-stir welding, wherein a welding tool is pressed towards only one of the membrane and catalyst plate, forming a reaction layer between the membrane and the catalyst plate by the frictional heat, and forming ripples in the welded interface.

Abstract: A gas-generating apparatus (10) includes a reaction chamber (18) containing a solid fuel component (24) and a liquid fuel component (22) that is introduced into the reaction chamber by a fluid path, such as a tube, nozzle, or valve. The flow of the liquid fuel to the solid fuel is self-regulated. Other embodiments of the gas-generating apparatus are also disclosed.

Abstract: A fuel reforming apparatus is provided such that an assembled unit of a reformer 1 with its associated instruments (a water vaporizer 2, primary fuel gasifier 3, desulfurizer 4, low-temperature shift converter 5 and selective oxidation CO remover 6) is covered with and enclosed by a vacuum heat insulating vessel 15 with inner and outer cylinders 15a and 15b and a vacuum heat insulating layer 15c between them. No heat insulating material such as ceramic fiber is required to be charged between the instruments and thus the heat insulating layer may be reduced in volume.

Abstract: A reformer for a fuel cell including: at least one reaction plate in which a channel is formed on a surface thereof; a cover plate disposed on the surface of the reaction plate; a bonding part which is formed between the reaction plate and the cover plate and which integrally fixes the reaction plate and the cover plate to each other; and a heat processing part which is formed outside the channel and which reduces a contact area between the reaction plate and the cover plate and controls thermal energy supplied to the reaction plate.

Abstract: A hydrogen generating material reacts with water to produce hydrogen and includes at least one metal material selected from the group consisting of aluminum, magnesium, and their alloys. The metal material includes particles with a particle size of 60 ?m or less in a proportion of 80 wt % or more. The hydrogen generating material can produce hydrogen easily and efficiently at low temperatures. A hydrogen generator can be made portable by using the hydrogen generating material. Moreover, the use of the hydrogen generating material as a hydrogen fuel source can reduce the size of a fuel cell and improve the electrical efficiency.

Abstract: A reformer having a combustion unit including a combustion part to burn air and fuel, a combustion gas distributor to distribute the burned combustion gas, and first and second combustion gas passages to guide the distributed combustion gas into an outlet. A fuel-converting catalytic reaction unit includes two reforming reaction parts preparing a reforming reaction reformate, each having a reforming catalyst to reform feed and water supplied from a feed/water inlet, and a water gas shift reaction part preparing a water gas shift reformate, between the two reforming reaction parts to decrease a concentration of carbon monoxide in the reforming reacting reformate. The two units are structured as six cylindrical pipes to realize optimal heat exchange efficiency, and preferential oxidation reactor is provided between first air fuel preheating passages in the combustion part to decrease the concentration of carbon monoxide in the water gas shift reformate to a predetermined level or lower.