And Metal, Metal Oxide, Or Metal Hydroxide Patents (Class 502/182)
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Patent number: 12105024Abstract: A sensor for detecting an analyte can include a photoluminescent nanostructure embedded in a sensor porous planar substrate. The sensor porous planar substrate can be supported by a substrate porous planar substrate.Type: GrantFiled: November 6, 2019Date of Patent: October 1, 2024Assignee: Massachusetts Institute of TechnologyInventors: Michael Strano, Xun Gong, Daniel Salem
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Patent number: 12034151Abstract: Nanoporous carbon-based scaffolds or structures, and specifically carbon aerogels and their manufacture and use thereof are provided. Embodiments include a silicon-doped anode material for a lithium-ion battery, where the anode material includes beads of a polyimide-derived carbon aerogel. The carbon aerogel may further include silicon particles and accommodates expansion of the silicon particles during lithiation. The anode material provides optimal properties for use within the lithium-ion battery.Type: GrantFiled: August 23, 2021Date of Patent: July 9, 2024Assignee: Aspen Aerogels, Inc.Inventors: Nicholas A. Zafiropoulos, Roxana Trifu, Redouane Begag, Harris R. Miller, Wendell E. Rhine, Nicholas Leventis, George L. Gould, Alexei A. Erchak
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Patent number: 11996566Abstract: The invention provides noble metal-free electro-catalyst compositions for use in acidic media, e.g., acidic electrolyte. The noble metal-free electro-catalyst compositions include non-noble metal absent of noble metal. The non-noble metal is non-noble metal oxide, and typically in the form of any configuration of a solid or hollow nano-material, e.g., nano-particles, a nanocrystalline thin film, nanorods, nanoshells, nanoflakes, nanotubes, nanoplates, nanospheres and nanowhiskers or combinations of myriad nanoscale architecture embodiments. Optionally, the noble metal-free electro-catalyst compositions include dopant, such as, but not limited to halogen. Acidic media includes oxygen reduction reaction (ORR) in proton exchange membrane (PEM) fuel cells, and direct methanol fuel cells and oxygen evolution reaction (OER) in PEM-based water electrolysis and metal air batteries, and hydrogen generation from solar energy and electricity-driven water splitting.Type: GrantFiled: February 25, 2021Date of Patent: May 28, 2024Assignee: UNIVERSITY OF PITTSBURGH—OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATIONInventors: Prashant N. Kumta, Prasad P. Patel, Moni K. Datta, Oleg Velikokhatnyi, Prashanth J. Hanumantha, Ramalinga Kuruba, Shrinath Ghadge
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Patent number: 11932558Abstract: A piezoelectric polymer used as a piezocatalyst, and methods of manufacture and use therefor. A preferred piezoelectric polymer is poly(vinylidene difluoride) (PVDF) due to its piezoelectric response and good flexibility. The polymer can be doped with a metal, metal salt, metal carbonyl, metal oxide such as ZnO, Co2O3, or TiO2, or ion such as Cr3+, Co2+, or Zn2+. The dopant can be chosen so that when the polymer is PVDF the dopant increases the amount of ?-phase PVDF and/or ?-phase PVDF relative to ?-phase PVDF, thereby increasing the piezocatalytic response of the polymer. The compound to be decomposed can be adsorbed on the surface of the piezoelectric polymer. Applications include wastewater treatment, CO2 capture and reduction, hydroformylation, water splitting, and ammonia synthesis.Type: GrantFiled: March 2, 2021Date of Patent: March 19, 2024Assignee: University of Rhode Island Board of TrusteesInventors: William B. Euler, Angela Thach, Lasanthi Sumathirathne, Benjamin B. Cromwell, Mara Dubnicka
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Patent number: 11749810Abstract: A gas diffusion layer comprises a carbon sheet and a microporous layer disposed on at least one surface of the carbon sheet, and meeting the requirement “C is equal to or greater than 0”, wherein: C, referred to as “index for simultaneous realization of a required in-plane oxygen permeation coefficient and electrical resistance”, is calculated by subtracting the product of B multiplied by 60 from A and adding 310 to the difference, A, is the rate of oxygen permeation in an in-plane direction in a gas diffusion layer that occurs when a pressure of 0.5 MPa is applied in the through-plane direction to a surface of the gas diffusion layer to compress an arbitrarily selected region having a width of 10 mm and a depth of 3 mm in the gas diffusion layer, and B is the “electrical resistance” that occurs when the gas diffusion layer is compressed by applying a pressure of 2 MPa in the through-plane direction.Type: GrantFiled: June 28, 2019Date of Patent: September 5, 2023Assignee: TORAY INDUSTRIES, INC.Inventors: Umi Yamamoto, Masamichi Utsunomiya, Isamu Shigemoto, Yasuaki Tanimura
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Patent number: 11585546Abstract: An air conditioning device is disclosed. The present air conditioning device comprises: a photocatalytic filter including a space through which air can pass and having a transition metal oxide formed in a nanotube form on the surface thereof, the transition metal oxide removing gases included in the air and including at least one of TiO2, ZnO, NiO, and WO3; and a light source for emitting light to the photocatalytic filter.Type: GrantFiled: August 23, 2018Date of Patent: February 21, 2023Assignee: Samsung Electronics Co., Ltd.Inventors: Hee-jin Park, Jee-yeon Kim, Yong-won Jeong, Sae-mi Kim, Jeong-eun Lee
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Patent number: 11554363Abstract: Electrocatalysts composed of single atoms or metal clusters dispersed over porous carbon support were prepared by a lithium-melt method. The new catalysts demonstrated high selectivity, high Faradic efficiency and low overpotential toward to the electrocatalytic reduction of carbon dioxide to chemicals.Type: GrantFiled: September 1, 2020Date of Patent: January 17, 2023Assignee: UChicago Argonne, LLCInventors: Di-Jia Liu, Tao Xu, Haiping Xu
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Patent number: 11264624Abstract: An electrocatalyst material having improved stability to corrosion compared to existing conductive high surface area carbon and metal carbide support materials is disclosed. The electrocatalyst material comprises (i) metal carbide nanotubes and (ii) a metal or metal alloy deposited on the metal carbide nanotubes. The electrocatalyst material is suitable for oxidising hydrogen, reducing oxygen or evolving hydrogen.Type: GrantFiled: June 29, 2016Date of Patent: March 1, 2022Assignee: Universite MontpellierInventors: Sara Cavaliere, Jacques Roziere, Deborah Jones, Yannick Najm Nabil-Moreau
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Patent number: 11224866Abstract: The invention discloses a visible light responsive tricobalt tetraoxide dodecahedron/carbon nitride nanosheet composite and an application thereof in exhaust gas treatment. The preparation method of the composite comprises the following steps: with urea as a precursor, carrying out twice calcination to obtain carbon nitride nanosheet; dispersing the carbon nitride nanosheet into methanol, sequentially adding cobalt nitrate hexahydrate and 2-methylimidazole, and carrying out a reaction to obtain a carbon nitride nanosheet composite; and calcining the carbon nitride nanosheet composite in an air atmosphere at a low temperature to obtain the tricobalt tetraoxide dodecahedron/carbon nitride nanosheet composite.Type: GrantFiled: April 27, 2020Date of Patent: January 18, 2022Assignee: SOOCHOW UNIVERSITYInventors: Jianmei Lu, Dongyun Chen
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Patent number: 11141716Abstract: A metal/?-MoC1-x load-type single-atomic dispersion catalyst, a synthesis method therefor, and applications thereof. The catalyst uses ?-MoC1-x as carrier, and has metal that has the mass fraction ranging from 1-100% and that is dispersed on carrier ?-MoC1-x in the single atom form. The catalyst provided in the present application can be adapted to a wide alcohol/water proportion in hydrogen production based on aqueous-phase reforming of alcohols, outstanding hydrogen production performance can be obtained at a variety of proportions, and catalysis performance of the catalyst is much higher than that of metal loaded with an oxide carrier. Especially when the metal is Pt, catalysis performance of the catalyst provided in the present application in the hydrogen production based on aqueous-phase reforming of alcohols is much higher than that of a Pt/?-MoC1-x load-type catalyst on the ?-MoC1-x carrier on which Pt is disposed on a layer form in the prior art.Type: GrantFiled: June 21, 2017Date of Patent: October 12, 2021Assignee: Peking UniversityInventors: Ding Ma, Lili Lin, Siyu Yao
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Patent number: 11014084Abstract: The present invention provides a process for preparing a catalyst, wherein said process comprises:—(i) preparing a mixture of one or more aromatic alcohol monomers and/or non-aromatic monomers, solvent, polymerization catalyst, crosslinking agent, suspension stabilizing agent and one or more metal salts, under conditions sufficient to produce polymeric beads doped with one or more metals or salts thereof; (ii) carbonizing, activating and then reducing the polymeric beads produced in step (i) to produce metal nanoparticles-doped porous carbon beads; (iii) subjecting the metal nanoparticles-doped porous carbon beads produced in step (ii) to chemical vapour deposition in the presence of a carbon source to produce metal nanoparticles-doped porous carbon beads comprising carbon nanofibers; and (iv) doping the metal nanoparticles-doped porous carbon beads comprising carbon nanofibers produced in step (iii) with an oxidant; catalyst prepared by said process; and a process for treating waste water from an industrialType: GrantFiled: May 23, 2017Date of Patent: May 25, 2021Assignee: Shell Oil CompanyInventors: Kaushik Basak, Arian Van Mourik, Nishith Verma
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Patent number: 10901565Abstract: A portable computer includes a display panel having a display surface and a touch panel. The touch panel is disposed on the display surface and comprises at least one transparent conductive layer. The transparent conductive layer includes a carbon nanotubes layer having a carbon nanotube film.Type: GrantFiled: August 27, 2015Date of Patent: January 26, 2021Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.Inventors: Kai-Li Jiang, Qun-Qing Li, Shou-Shan Fan
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Patent number: 10835889Abstract: A method for the preparation of zirconia-multi-walled carbon nanotube nanocomposite utilizing Pluronics as templating agents is described. An efficient method for producing hydrogen gas using the nanocomposite as a photocatalyst.Type: GrantFiled: August 3, 2020Date of Patent: November 17, 2020Assignee: King Abdulaziz UniversityInventors: Mohammad W. Kadi, Reda Mohamedy Mohamed Ouf
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Patent number: 10685844Abstract: Provided are a hardmask composition, a method of forming a pattern using the hardmask composition, and a hardmask formed using the hardmask composition. The hardmask composition includes a polar nonaqueous organic solvent and one of: i) a mixture of graphene quantum dots and at least one selected from a diene and a dienophile, ii) a Diels-Alder reaction product of the graphene quantum dots and the at least one selected from a diene and a dienophile, iii) a thermal treatment product of the Diels-Alder reaction product of graphene quantum dots and the at least one selected from a diene and a dienophile, or iv) a combination thereof.Type: GrantFiled: July 16, 2018Date of Patent: June 16, 2020Assignees: Samsung Electronics Co., Ltd., Research & Business Foundation, Sungkyunkwan UniversityInventors: Sangwon Kim, Changsik Song, Dongcheol Jeong, Minsu Seol, Hyeonjin Shin, Dongwook Lee, Taewoo Kim, Juhyen Lee, Hyejin Cho
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Patent number: 10533270Abstract: Consolidated carbon nanotube or graphene yarns and woven sheets are consolidated through the formation of a carbon hinder formed from the dehydration of sucrose. The resulting materials, on a macro-scale are lightweight and of a high specific modulus and/or strength. Sucrose is relatively inexpensive and readily available, and the process is therefore cost-effective.Type: GrantFiled: June 22, 2017Date of Patent: January 14, 2020Assignee: United States of America as represented by the Administrator of NASAInventors: Godfrey Sauti, Jae-Woo Kim, Emilie J. Siochi, Kristopher E. Wise
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Patent number: 10505201Abstract: The present subject matter relates generally to the derivatization of highly-aligned carbon nanotube sheet substrates with one or more transition metal centers and to uses of the resulting metal-derivatized CNT sheet substrates.Type: GrantFiled: February 5, 2015Date of Patent: December 10, 2019Assignee: North Carolina Agricultural and Technical State UniversityInventors: Yeoheung Yun, Youngmi Koo, Jagannathan Sankar
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Patent number: 9844762Abstract: Described here is a metal-carbon composite, comprising (a) a porous three-dimensional scaffold comprising one or more of carbon nanotubes, graphene and graphene oxide, and (b) metal nanoparticles disposed on said porous scaffold, wherein the metal-carbon composite has a density of 1 g/cm3 or less, and wherein the metal nanoparticles account for 1 wt. % or more of the metal-carbon composite. Also described are methods for making the metal-carbon composite.Type: GrantFiled: September 12, 2014Date of Patent: December 19, 2017Assignee: Lawrence Livermore National Security, LLCInventors: Marcus A. Worsley, Joe Satcher, Sergei Kucheyev, Supakit Charnvanichborikarn, Jeffrey Colvin, Thomas Felter, Sangil Kim, Matthew Merrill, Christine Orme
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Patent number: 9844222Abstract: A metal nanoparticles-doped porous carbon bead having an average size of about 0.4 millimeter (mm) to about 0.6 mm is provided. The metal nanoparticles-doped porous carbon bead is doped with silver, copper, or combinations thereof.Type: GrantFiled: August 19, 2014Date of Patent: December 19, 2017Assignee: INDIAN INSTITUTE OF TECHNOLOGY KANPURInventors: Nishith Verma, Ashutosh Sharma, Prateek Khare
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Patent number: 9825182Abstract: A method includes growing a graphene layer on a metal layer, intercalating a first material between the metal layer and the graphene layer by heating the first material at a first pressure and a first temperature, and intercalating a second material between the metal layer and the graphene layer by heating the second material at a second pressure different from the first pressure and a second temperature different from the first temperature. Accordingly, the first material and the second material are chemically bonded to each other to form an insulating layer, and the insulating layer may be between the metal layer and the graphene layer.Type: GrantFiled: February 23, 2016Date of Patent: November 21, 2017Assignee: Samsung Electronics Co., Ltd.Inventors: Insu Jeon, Jiyeon Ku, Hyowon Kim
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Patent number: 9803910Abstract: A refrigerator includes a main body having a storage room formed therein, a door that opens and closes the storage room, a filter module, and a cool air circulation fan that circulates cool air through the filter module. The filter module includes a metal photocatalyst filter and a UV LED module for radiating UV rays to the metal photocatalyst filter. The metal photocatalyst filter has photocatalysts made of one of ZnTiO2, CuTiO2, AgTiO2 or FeTiO2 coated on a filter base. The filter module may allow the entire storage room to be uniformly subject to antibiosis and sterilization at a relatively low cost.Type: GrantFiled: February 10, 2014Date of Patent: October 31, 2017Assignee: LG ELECTRONICS, INC.Inventors: Eunjeong Kim, Yuri Choi, Myungsuk Lee, Jeongyon Kim
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Patent number: 9776173Abstract: The present specification relates to a hollow metal nanoparticle. Specifically, the present specification relates to a hollow metal nanoparticle having a cavity.Type: GrantFiled: June 3, 2014Date of Patent: October 3, 2017Assignee: LG CHEM, LTD.Inventors: Kwanghyun Kim, Gyo Hyun Hwang, Sang Hoon Kim, Jun Yeon Cho
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Patent number: 9669388Abstract: Disclosed are hierarchically porous carbon materials with a plurality of discreet nanoparticles dispersed on their carbon phase. The materials possess a continuous network of pores that spans the porous material, permitting the flow of fluids into and through the material. The porous materials can be used as heterogeneous catalysts.Type: GrantFiled: December 8, 2015Date of Patent: June 6, 2017Assignee: The Board Trustees of The University of AlabamaInventors: Martin G. Bakker, Franchessa Maddox Sayler, Kevin Shaughnessy
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Patent number: 9650531Abstract: In accordance with one embodiment, an ink composition for inkjet recording comprises a pigment, a pigment dispersant, water, a water-soluble solvent, a wettability enhancer including 2,5,8,11-tetramethyl-6-dodecyne-5,8-diol, and an aqueous resin emulsion.Type: GrantFiled: November 24, 2014Date of Patent: May 16, 2017Assignee: TOSHIBA TEC KABUSHIKI KAISHAInventors: Hiroshi Kiyomoto, Takaya Kitawaki
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Patent number: 9114387Abstract: The present subject matter provides a method of preparing a multicomponent metal-hybrid nanocomposite using co-gasification, in which a multicomponent metal-hybrid nanocomposite can be prepared by a one-step process without using a complicated process including the steps of supporting-drying-calcining-annealing and the like at the time of preparing a conventional alloy catalyst, and provides a multicomponent metal-hybrid nanocomposite prepared by the method. The method is advantageous in that a multicomponent metal-hybrid nanocomposite can be synthesized by a simple process of simultaneously gasifying two kinds of metal precursors, and in that an additional post-treatment process is not required.Type: GrantFiled: July 17, 2013Date of Patent: August 25, 2015Assignee: KOREA INSTITUTE OF ENERGY RESEARCHInventors: Hee-Yeon Kim, Seok-yong Hong, Kwang-Sup Song, Hong-Soo Kim
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Patent number: 9056782Abstract: Disclosed is a method for preparing a platinum-manganese dioxide/carbon complex for a positive-electrode material of a lithium-air battery. More specifically, a manganese dioxide/carbon complex is prepared by dispersing carbon in a manganese dioxide precursor solution and applying microwaves, filtering and drying to the resulting solution. Next a platinum-manganese dioxide/carbon complex is prepared by dispersing the manganese dioxide/carbon complex in ethylene glycol, adding a platinum precursor and applying microwaves to the resulting solution. The platinum-manganese dioxide/carbon complex synthesized according to the present invention exhibits lower overvoltage and higher current density in oxygen reduction and oxidation reactions as compared to either a manganese dioxide/carbon complex or a platinum/carbon complex.Type: GrantFiled: October 14, 2011Date of Patent: June 16, 2015Assignees: Hyundai Motor Company, Inha-Industry Partnership InstituteInventors: Ho Taek Lee, Kyoung Han Ryu, Yongsug Tak, Sung-Hyeon Baeck, Jinsub Choi, Jin Yong Shim
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Publication number: 20150147262Abstract: The present invention relates to metal catalyst particles for carbon nanotube synthesis, comprising carbon-containing regions on their surfaces.Type: ApplicationFiled: June 20, 2013Publication date: May 28, 2015Inventors: Suguru Noda, Zhongming Chen, Dong Young Kim, Shunsuke Ueda, Eisuke Haba
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Publication number: 20150140333Abstract: Porous and/or curved nanofiber bearing substrate materials are provided having enhanced surface area for a variety of applications including as electrical substrates, semipermeable membranes and barriers, structural lattices for tissue culturing and for composite materials, production of long unbranched nanofibers, and the like. A method of producing nanofibers is disclosed including providing a plurality of microparticles or nanoparticles such as carbon black particles having a catalyst material deposited thereon, and synthesizing a plurality of nanofibers from the catalyst material on the microparticles or nanoparticles. Compositions including carbon black particles having nanowires deposited thereon are further disclosed.Type: ApplicationFiled: October 3, 2014Publication date: May 21, 2015Inventor: Chunming NIU
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Publication number: 20150140474Abstract: The present invention provides a method for producing metal-supported carbon, which includes supporting metal microparticles on the surface of carbon black, by a liquid-phase reduction method, in a thin film fluid formed between processing surfaces arranged to be opposite to each other so as to be able to approach to and separate from each other, at least one of which rotates relative to the other, as well as a method for producing crystals comprising fullerene molecules and fullerene nanowhisker/nanofiber nanotubes, which includes uniformly stirring and mixing a solution containing a first solvent having fullerene dissolved therein, and a second solvent in which fullerene is less soluble than in the first solvent, in a thin film fluid formed between processing surfaces arranged to be opposite to each other so as to be able to approach to and separate from each other, at least one of which rotates relative to the other.Type: ApplicationFiled: January 29, 2015Publication date: May 21, 2015Applicant: M. TECHNIQUE CO., LTD.Inventor: Masakazu ENOMURA
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Publication number: 20150133291Abstract: Catalyst support materials that are coated with a thin carbon over-layer and methods for making the same are shown and described. In general, a supporting oxide material, which may or may not have a catalytic material already deposited on the surface, is coated with a thin carbon layer.Type: ApplicationFiled: March 15, 2013Publication date: May 14, 2015Applicant: STC.UNMInventors: Abhaya Datye, Hien Pham
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Publication number: 20150132669Abstract: The present invention relates to a process for producing carbon-supported manganese oxide catalysts, to carbon-supported manganese oxide catalysts obtainable or obtained by the process according to the invention, to gas diffusion electrodes comprising said carbon-supported manganese oxide catalysts and to electrochemical cells comprising said gas diffusion electrodes.Type: ApplicationFiled: April 30, 2013Publication date: May 14, 2015Applicant: BASF SEInventors: Arnd Garsuch, Hubert Gasteiger, Cueneyt Kavakli
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Publication number: 20150118477Abstract: Disclosed herein is a fungicide, including: a porous carbon material; and a silver member adhered to the porous carbon material, wherein a value of a specific surface area based on a nitrogen BET, namely Brunauer, Emmett, and Teller method is equal to or larger than 10 m2/g, and a volume of a fine pore based on a BJH, namely Barrett, Joyner, and Halenda method and an MP, namely Micro Pore method is equal to or larger than 0.1 cm3/g.Type: ApplicationFiled: January 7, 2015Publication date: April 30, 2015Applicant: Sony CorporationInventors: Hironori Iida, Shun Yamanoi, Machiko Minatoya, Seiichiro Tabata, Shinichiro Yamada
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Patent number: 9018127Abstract: A reduced metallic catalyst or pre-activated catalyst is formed by contacting a precursor catalyst or a reduced metallic catalyst with a modifier solution in the presence of a source of hydrogen and heat treating the precursor catalyst or the reduced metallic catalyst at super-atmospheric pressure to obtain the reduced metallic catalyst from the precursor catalyst or the pre-activated catalyst from the reduced metallic catalyst. A method of hydrogenating a hydrogenatable precursor includes providing a reduced metallic catalyst or the pre-activated catalyst prepared with modifier buffer and contacting the reduced metallic catalyst or pre-activated catalyst with the hydrogenatable precursor in the presence of hydrogen and, optionally, in the presence of a modifier solution.Type: GrantFiled: January 8, 2013Date of Patent: April 28, 2015Assignee: BioAmber International S.a.r.l.Inventors: Setrak K. Tanielyan, Robert L. Augustine, Leo E. Manzer, James F. White, Ramesh D. Bhagat, Balaraju Miryala
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Patent number: 8999876Abstract: Catalyst compositions comprising molybdenum, sulfur and an alkali metal ion supported on a nanofibrous, mesoporous carbon molecular sieve are useful for converting syngas to higher alcohols. The compositions are produced via impregnation and may enhance selectivity to ethanol in particular.Type: GrantFiled: December 1, 2011Date of Patent: April 7, 2015Assignee: Georgia Tech Research CorporationInventors: Christopher W. Jones, Pradeep K. Agrawal, Tien Thao Nguyen
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Publication number: 20150093685Abstract: An oxygen reduction reaction catalyst and method for making the catalyst includes a graphitized carbon substrate with an amorphous metal oxide layer overlying the surface of the substrate. The amorphous metal oxide layer has a worm-like structure. A catalyst overlies the metal oxide layer.Type: ApplicationFiled: October 2, 2013Publication date: April 2, 2015Applicant: Ford Global Technologies, LLCInventors: Jun Yang, Patrick Pietrasz, Chunchuan Xu, Shinichi Hirano
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Publication number: 20150093294Abstract: In various implementations, a filter may include a substrate and manganese oxide coupled to the substrate. The filter may at least remove particles and/or chemicals from a gaseous stream. In some implementations, the filter may be capable of degrading at least one of formaldehyde or ozone present in a gaseous stream.Type: ApplicationFiled: September 26, 2014Publication date: April 2, 2015Inventors: Sanjeev Hingorani, Henry Greist
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Patent number: 8993471Abstract: In one aspect, the present invention is directed to a coating composition. The coating composition comprises photocatalytic particles and an alkali metal silicate binder comprising a boric acid, borate, or combination thereof. In another aspect, the present invention is directed to a coated article. The coated article has a photocatalytic coating with improved durability on its external surface that is formed from the aforesaid coating composition.Type: GrantFiled: December 17, 2007Date of Patent: March 31, 2015Assignee: 3M Innovative Properties CompanyInventors: Feng Bai, Rachael A. T. Gould, Mark T. Anderson
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Patent number: 8993164Abstract: A support for carrying a catalyst is obtained by carbonizing raw materials containing a nitrogen-containing organic substance and a metal. The support for carrying a catalyst may have a peak at a diffraction angle of around 26° in an X-ray diffraction pattern, the peak including 20 to 45% of a graphite-like structure component and 55 to 80% of an amorphous component. In addition, the support for carrying a catalyst may have an intensity ratio of a band at 1,360 cm?1 to a band at 1,580 cm?1 (I1,360/I1,580) in a Raman spectrum of 0.3 or more and 1.0 or less. In addition, the support for carrying a catalyst may be obtained by carbonizing the raw materials to obtain a carbonized material, subjecting the carbonized material to a metal removal treatment, and subjecting the resultant to a heat treatment.Type: GrantFiled: December 3, 2010Date of Patent: March 31, 2015Assignees: Nisshinbo Holdings Inc., National University Corporation Gunma UniversityInventors: Erina Matsuzaka, Takeaki Kishimoto, Jun-ichi Ozaki
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Patent number: 8993472Abstract: Layered catalyst structures for fuel cells, particularly for a Proton Exchange Membrane Fuel Cell (PEMFC), are produced by a reactive spray deposition technology process. The catalyst layers so produced contain particles sized between 1 and 15 nm and clusters of such particles of a catalyst selected from the group consisting of platinum, platinum alloys with transition metals, mixtures thereof and non-noble metals. The catalyst layers without an electrically conducting supporting medium exhibit dendritic microstructure, providing high electrochemically active surface area and electron conductivity at ultra-low catalyst loading. The catalyst layers deposited on an electrically conducting medium, such as carbon, exhibit three-dimensional functional grading, which provides efficient utilization as a catalyst, high PEMFC performance at the low catalyst loading, and minimized limitations caused by reactant diffusion and activation. The catalytic layers may be produced by a single-run deposition method.Type: GrantFiled: November 6, 2009Date of Patent: March 31, 2015Assignee: National Research Council of CanadaInventors: Justin Roller, Radenka Maric, Khalid Fatih, Roberto Neagu
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Publication number: 20150087498Abstract: Microwave irradiation is used to synthesize graphene and metallic nanocatalysts supported on graphene either by solid or solution phase. In solid phase methods, no solvents or additional reducing agents are required so the methods are “environmentally friendly” and economical, and the graphene and nanocatalysts are substantially free of residual contaminants. Recyclable, high efficiency Pd nanocatalysts are prepared by these methods.Type: ApplicationFiled: September 29, 2014Publication date: March 26, 2015Applicant: Virginia Commonwealth UniversityInventors: M. Samy El-Shall, Victor Abdelsayed, Hassan M. A. Hassan, Abd El Rahman S. Khder, Khaled M. AbouZeid, Qilin Dai, Parichehr Afshani, Frank Gupton, Ali R. Siamaki, Zeid Abdullah M. Alothman, Hamad Zaid Alkhathlan
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Publication number: 20150087502Abstract: The invention relates to a method of preparing a catalytic composition comprising at least one non-noble metal from group VIII and at least one metal from group VIB of the periodic table. The invention also relates to the catalytic composition thus produced, which has a high specific activity in reactions involving the hydroprocessing of light and intermediate fractions, preferably in reactions involving the hydrotreatment of hydrocarbon streams, including hydrodesulphurisation (HDS), hydrodenitrogenation (HDN) and hydro-dearomatisation (HDA).Type: ApplicationFiled: December 4, 2014Publication date: March 26, 2015Inventors: Jose Antonio TOLEDO ANTONIO, Miguel PEREZ LUNA, Maria Antonia CORTES JACOME, Jose ESCOBAR AGUILAR, Maria de Lourdes MOSQUEIRA MONDRAGON, Carlos ANGELES CHAVEZ, Esteban LOPEZ SALINAS, Victor PEREZ MORENO, Gerardo FERRAT TORRES, Rodolfo Juventino MORA VALLEJO, Marcelo LOZADA Y CASSOU
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Patent number: 8987164Abstract: A semiconductor of which a substance such as a semiconductor photocatalyst is uniformly coated on the surface thereof with a graphitic carbon film and a method of fabricating the same are disclosed. According to the inventive method, a graphitic carbon film having a thickness of 1 nm or less is uniformly formed on the surface of the semiconductor by performing hydrothermal synthesis and pyrolysis on glucose, so as to keep the original structure crystallinity of the semiconductor photocatalyst to be a support of the carbon film.Type: GrantFiled: December 7, 2012Date of Patent: March 24, 2015Assignee: Korea Advanced Institute of Science and TechnologyInventors: Jeung-Ku Kang, Dong-Ki Lee, Kyu-Sung Han, Weon-Ho Shin, Jung-Woo Lee, Jung-Hoon Choi, Kyung-Min Choi, Yeob Lee
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Patent number: 8986502Abstract: A photodegradable paper including cellulose fibers and, if applicable, fillers, additives and/or other kind of fibers is described. Also described, is a paper particularly in the field of packaging, tissue papers or cigarettes.Type: GrantFiled: February 10, 2011Date of Patent: March 24, 2015Assignee: Solvay Acetow GmbHInventors: Dirk Hölter, Wolfgang Koppe
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Publication number: 20150068916Abstract: The catalyst for electrochemical dechlorination of hydrocarbons, such as chlorobenzenes, is a d-block transition metal supported by rice husk ash (RHA), preferably rice husk ash-supported platinum or titanium. The catalysts are prepared from rice husk ash by the sol-gel method. In order to dechlorinate chlorinated organic compounds, such as 1,4-dichlorobenzene, 1,2-dichlorobenzene, 1,3-dichlorobenzene, and 1,2,4-trichlorobenzene, a capillary microreactor is at least partially filled with the d-block transition metal supported by rice husk ash catalyst, a buffer solution having a pH preferably between 7 and 10, and the chlorinated organic compound. An electrical potential of approximately 3 kV is then applied across the capillary microreactor to initiate the dechlorination reaction.Type: ApplicationFiled: September 11, 2013Publication date: March 12, 2015Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALSInventors: CHANBASHA BASHEER, ABDULELAH AHMED ALI THABET
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Publication number: 20150065333Abstract: The present disclosure relates to a catalyst for a metal air battery or fuel cell comprising a mixed metal oxide consisting of at least one lanthanide element and at least two different transition metal elements. The catalyst may further comprise a conducting additive. The present disclosure further provides an air electrode, metal air battery or fuel cell comprising the disclosed catalyst, and methods for forming the disclosed catalyst.Type: ApplicationFiled: September 2, 2014Publication date: March 5, 2015Inventors: Xiaoming Ge, Zhao Lin Liu, Fu Wei Thomas Goh, Yun Zong, Bing Li, Jie Zhang, T.S. Andy Hor
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Publication number: 20150064608Abstract: A catalyst consisting of structurally ordered mesoporous carbon containing a transition metal and a method for preparing the same are provided. The method for preparing the catalyst includes forming a mixture of a carbon precursor and structurally ordered mesoporous silica, carbonizing the mixture to form a composite, and removing mesoporous silica from the composite.Type: ApplicationFiled: October 18, 2013Publication date: March 5, 2015Applicant: UNIST Academy-Industry Research CorporationInventors: Sang Hoon JOO, Jae Yeong Cheon
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Patent number: 8969236Abstract: A preferred embodiment of the process involves a generate a catalyst that comprises molybdenum carbide nickel material. Steps may involve heating a surface that comprises molybdenum oxide and a nickel salt while passing thereover a gaseous mixture that comprises a reductant and a carburizer. In certain embodiments, the reductant and the carburizer may both be carbon monoxide, or both be a saturated hydrocarbon. In others, the reductant may be carbon monoxide and the carburizer may be a saturated hydrocarbon.Type: GrantFiled: November 1, 2011Date of Patent: March 3, 2015Assignee: University of Wyoming Research CorporationInventors: Vijay K. Sethi, Yulong Zhang
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Patent number: 8951931Abstract: The noble metal fine particle supported catalyst of the present invention includes a substrate, and a porous membrane formed on the substrate. The porous membrane contains support particles, noble metal fine particles, and an inorganic binder. In the porous membrane, the noble metal fine particles are supported on surfaces of the support particles, and the support particles form secondary particles each having a porous structure. The porous membrane is formed by binding, with the inorganic binder, the secondary particles formed of the support particles so that a gap is present at least partly between the secondary particles adjacent to each other.Type: GrantFiled: February 28, 2011Date of Patent: February 10, 2015Assignee: Nippon Sheet Glass Company, LimitedInventors: Ryohei Ogawa, Kiyoshi Miyashita
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Patent number: 8946111Abstract: Permeable composite fibrous catalytic sheets comprised of at least three distinct solid phases. A first solid phase is a 3-dimensional porous network of a non-conductive porous ceramic material. A second solid phase is an electrically conductive phase comprised of randomly oriented electrically conductive fibers. A third phase is comprised of catalytic particles dispersed on said 3-dimensional porous network, said conductive fibers, or both. A fourth phase can be present, which fourth phase is comprised one or more conductive species or one or more non conductive species embedded in said first solid phase.Type: GrantFiled: November 18, 2012Date of Patent: February 3, 2015Inventor: Juzer Jangbarwala
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Publication number: 20150030968Abstract: The present invention relates to an aerogel based on doped graphene, a method for producing said aerogel and the use of said aerogel, for example, as an electrode or a catalyst. Furthermore, the present invention relates to electrodes, all solid-state supercapacitors (ASSS) or catalysts based on said aerogel. The present invention also relates to doped graphene, which can be obtained as an intermediate in the production of the aerogel based on doped graphene using graphene oxide as starting material.Type: ApplicationFiled: February 26, 2013Publication date: January 29, 2015Applicants: BASF SE, Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.Inventors: Matthias Georg Schwab, Klaus Muellen, Xinliang Feng, Zhong-Shuai Wu
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Publication number: 20150031528Abstract: The present invention relates to a process for producing a carbon substrate loaded with metal oxides, in particular a carbon material which contains metal oxide nanoparticles and is preferably suitable for use in a catalyst and/or as a catalyst, wherein, in a first process step, nanoparticles of metal oxides are introduced into a matrix based on at least one organic polymer, in particular are dispersed therein, and, in a second process step, the polymer matrix containing the nanoparticles is subsequently carbonised to carbon, optionally followed by a third process step of activation.Type: ApplicationFiled: September 29, 2014Publication date: January 29, 2015Inventors: Christof Schulz, Hartmut Wiggers