And Metal, Metal Oxide, Or Metal Hydroxide Patents (Class 502/182)
  • Patent number: 7790650
    Abstract: The present invention relates to catalysts comprising at least one support and at least one layer applied to said support, said layer containing a) 20 to 95% by weight of at least one aluminum, silicon, titanium or magnesium oxide compound or a silicon carbide or a carbon support or mixtures thereof, and b) 5 to 50% by weight of at least one nanocarbon. The catalysts can be used to produce unsaturated hydrocarbons by means of the oxidative dehydrogenation of alkylaromatics, alkenes and alkanes in the gas phase.
    Type: Grant
    Filed: July 13, 2005
    Date of Patent: September 7, 2010
    Assignee: NanoC Sdn. Bhd.
    Inventors: Robert Schlogl, Gerhard Mestl
  • Publication number: 20100222211
    Abstract: A method for producing nanoparticles on a substrate using a metal precursor in an ionic liquid and microwave heating is described. The composite compositions are useful as catalysts for chemical reactions, fuel cell, supercapacitor and battery components, and the like.
    Type: Application
    Filed: April 30, 2010
    Publication date: September 2, 2010
    Applicant: Board of Trustees of Michigan State University
    Inventors: Lawrence T. Drzal, In-Hwan Do, Hiroyuki Fukushima
  • Publication number: 20100213046
    Abstract: Nitrogen-doped titania nanotubes exhibiting catalytic activity on exposure to any one or more of ultraviolet, visible, and/or infrared radiation, or combinations thereof are disclosed. The nanotube arrays may be co-doped with one or more nonmetals and may further include co-catalyst nanoparticles. Also, methods are disclosed for use of nitrogen-doped titania nanotubes in catalytic conversion of carbon dioxide alone or in admixture with hydrogen-containing gases such as water vapor and/or other reactants as may be present or desirable into products such as hydrocarbons and hydrocarbon-containing products, hydrogen and hydrogen-containing products, carbon monoxide and other carbon-containing products, or combinations thereof.
    Type: Application
    Filed: January 5, 2010
    Publication date: August 26, 2010
    Applicant: The Penn State Research Foundation
    Inventors: Craig A. Grimes, Oomman K. Varghese, Maggie Paulose
  • Publication number: 20100215960
    Abstract: A hollow carbon sphere having a carbon shell and an inner core is disclosed. The hollow carbon sphere has a total volume that is equal to a volume of the carbon shell plus an inner free volume within the carbon shell. The inner free volume is at least 25% of the total volume. In some instances, a nominal diameter of the hollow carbon sphere is between 10 and 180 nanometers.
    Type: Application
    Filed: February 24, 2009
    Publication date: August 26, 2010
    Applicants: Toyota Motor Engineering & Manufacturing North America, Inc., Los Alamos National Lab
    Inventors: Claudia Luhrs, Jonathan Phillips, Monique N. Richard, Angela Michelle Knapp
  • Publication number: 20100216056
    Abstract: A non-noble metal based catalyst includes a compound represented by Formula 1: ZraMbOxNy??[Formula 1] where M is at least one element selected from Group 4 elements through Group 12 elements, a is a number in the range of about 1 to about 8, b is a number in the range of 1 to 8, x is a number in the range of about 0.2 to about 32, and y is a number in the range of about 0.2 to about 16. A fuel cell electrode and fuel cell may be formed using the non-noble metal based catalyst.
    Type: Application
    Filed: February 19, 2010
    Publication date: August 26, 2010
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Duckyoung YOO, Gang Liu, Huamin Zhang, Hong Jin, Ting Xu, Yuanwei Ma, Hexiang Zhong
  • Patent number: 7776782
    Abstract: A textured catalyst having a hydrothermally-stable support, a metal oxide and a catalyst component is described. Methods of conducting aqueous phase reactions that are catalyzed by a textured catalyst are also described. The invention also provides methods of making textured catalysts and methods of making chemical products using a textured catalyst.
    Type: Grant
    Filed: January 8, 2007
    Date of Patent: August 17, 2010
    Assignee: Battelle Memorial Institute
    Inventors: Todd Werpy, John G. Frye, Jr., Yong Wang, Alan H. Zacher
  • Patent number: 7771860
    Abstract: A fuel cell catalyst includes a carbon-containing core, and an active metal shell attached to the carbon core by an ionomer. The catalyst has a high catalyst utility, and facilitates a highly efficient and high power fuel cell. The ionomer is disposed between the active metal and the carbon core. The carbon core and the active metal are present in a mixing ratio ranging from 0.0001:99.9999 wt % to 0.05:99.95 wt %.
    Type: Grant
    Filed: June 12, 2007
    Date of Patent: August 10, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventor: In-Hyuk Son
  • Publication number: 20100192964
    Abstract: A low sidestream smoke cigarette comprises a conventional tobacco rod, and a combustible treatment paper having a sidestream smoke treatment composition. The treatment composition comprises in combination, an oxygen storage and donor metal oxide oxidation catalyst and an essentially non-combustible finely divided porous particulate adjunct for said catalyst.
    Type: Application
    Filed: April 13, 2010
    Publication date: August 5, 2010
    Applicant: Rothmans, Benson & Hedges, Inc.
    Inventors: Stanislav M. SNAIDR, E. Robert Becker
  • Patent number: 7767616
    Abstract: A catalyst for an electro-chemical oxygen reduction reaction (ORR) of a bundle of longitudinally aligned carbon nanotubes having a catalytically active transition metal incorporated longitudinally in said nanotubes. A method of making an electro-chemical catalyst for an oxygen reduction reaction (ORR) having a bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes, where a substrate is in a first reaction zone, and a combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into the first reaction zone which is maintained at a first reaction temperature for a time sufficient to vaporize material therein.
    Type: Grant
    Filed: March 3, 2006
    Date of Patent: August 3, 2010
    Assignee: UChicago Argonne, LLC
    Inventors: Di-Jia Liu, Junbing Yang, Xiaoping Wang
  • Patent number: 7767345
    Abstract: A lithium-air battery includes a lithium negative electrode, a positive electrode including a catalyst containing gold, and a non-aqueous electrolyte interposed between the positive electrode and the lithium negative electrode. The catalyst includes gold supported on a cerium-containing oxide, such as a cerium-zirconium compound oxide or a cerium-aluminum compound oxide. The amount of catalyst of the positive electrode is in the range of 0.01 to 50 weight percent relative to the total weight of the positive electrode.
    Type: Grant
    Filed: January 2, 2008
    Date of Patent: August 3, 2010
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Haruo Imagawa, Hideyuki Nakano, Hirozumi Azuma
  • Publication number: 20100190639
    Abstract: A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust.
    Type: Application
    Filed: January 27, 2010
    Publication date: July 29, 2010
    Inventors: Marcus A. Worsley, Thomas Yong-Jin Han, Joshua D. Kuntz, Octavio Cervantes, Alexander E. Gash, Theodore F. Baumann, Joe H. Satcher, JR.
  • Patent number: 7759277
    Abstract: The present invention provides a catalyst having high activity and excellent stability, a process for preparation of the catalyst, a membrane electrode assembly, and a fuel cell. The catalyst of the present invention comprises an electronically conductive support and catalyst fine particles. The catalyst fine particles are supported on the support and are represented by the formula (1): PtuRuxGeyTz (1). In the formula, u, x, y and z mean 30 to 60 atm %, 20 to 50 atm %, 0.5 to 20 atm % and 0.5 to 40 atm %, respectively. When the element represented by T is Al, Si, Ni, W, Mo, V or C, the content of the T-element's atoms connected with oxygen bonds is not more than four times as large as that of the T-element's atoms connected with metal bonds on the basis of X-ray photoelectron spectrum (XPS) analysis.
    Type: Grant
    Filed: March 19, 2009
    Date of Patent: July 20, 2010
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Taishi Fukazawa, Wu Mei, Yoshihiko Nakano, Tsuyoshi Kobayashi, Itsuko Mizutani, Hiroyasu Sumino
  • Patent number: 7749935
    Abstract: A catalyst carrier, being characterized in that a catalyst metal for promoting an oxidation-reduction reaction is carried on a vapor-grown carbon fiber having an average outer diameter of from 2 nm to 500 nm, which has been subjected to a crushing treatment so as to have a BET specific surface area of from 4 m2/g to 100 m2/g and an aspect ratio of from 1 to 200, and exhibiting high activity per unit amount of a catalyst metal, a low reaction resistance and an improved output density, and is useful for a fuel cell; a production method thereof and a fuel cell using the catalyst carrier.
    Type: Grant
    Filed: January 26, 2005
    Date of Patent: July 6, 2010
    Assignee: Showa Denko K.K.
    Inventors: Ken-ichiro Ota, Akimitsu Ishihara, Satoshi Iinou, Akinori Sudoh
  • Publication number: 20100167106
    Abstract: An ordered mesoporous carbon (OMC) composite catalyst includes an OMC; and metal particles and at least one component selected from a group consisting of nitrogen and sulfur included in the OMC. The ordered mesoporous carbon composite catalyst may be formed by impregnating an ordered mesoporous silica with a mixture of at least one selected from the group consisting of a nitrogen-containing carbon precursor, and a sulfur-containing carbon precursor, a metal precursor, and a solvent; drying and heat-treating the impregnated OMS; carbonizing the dried and heat-treated OMS to obtain a carbon-OMS composite; and removing the OMS from the carbon-OMS composite. A fuel cell may contain the OMC composite catalyst.
    Type: Application
    Filed: December 31, 2009
    Publication date: July 1, 2010
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Chan-ho Pak, Hyuk Chang, Ji-Man Kim, Jeong-kuk Shon
  • Publication number: 20100167918
    Abstract: A catalyst for an electro-chemical oxygen reduction reaction (ORR) of a bundle of longitudinally aligned carbon nanotubes having a catalytically active transition metal incorporated longitudinally in said nanotubes. A method of making an electro-chemical catalyst for an oxygen reduction reaction (ORR) having a bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes, where a substrate is in a first reaction zone, and a combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into the first reaction zone which is maintained at a first reaction temperature for a time sufficient to vaporize material therein.
    Type: Application
    Filed: March 3, 2006
    Publication date: July 1, 2010
    Applicant: The University of Chicago
    Inventors: Di-Jia Liu, Junbing Yang, Xiaoping Wang
  • Publication number: 20100160155
    Abstract: A carbon nanotube film is disclosed which includes a plurality of macroscopically aligned carbon nanotubes, and a plurality of nanoparticles which are adhered to the surfaces of the carbon nanotubes. A method for constructing a carbon nanotube film is also disclosed. This method includes multiple steps. First, a plurality of macroscopically aligned carbon nanotubes are formed on a substrate. Next, a solution including a dispersion of nanoparticles in a solvent is applied onto the carbon nanotubes. Then, the solvent is evaporated so that the nanoparticles remain and are adhered to the carbon nanotubes.
    Type: Application
    Filed: December 22, 2008
    Publication date: June 24, 2010
    Inventor: Kangning Liang
  • Publication number: 20100152030
    Abstract: In one aspect, the present invention is directed to a coating composition. The coating composition comprises photocatalytic particles and an alkali metal silicate binder comprising a boric acid, borate, or combination thereof. In another aspect, the present invention is directed to a coated article. The coated article has a photocatalytic coating with improved durability on its external surface that is formed from the aforesaid coating composition.
    Type: Application
    Filed: December 17, 2007
    Publication date: June 17, 2010
    Inventors: Feng Bai, Rachael A.T. Gould, Mark T. Anderson
  • Patent number: 7736790
    Abstract: The present teachings are directed toward electrocatalyst compositions of platinum, tungsten and at least a third metal for use in fuel cells. The electrocatalyst composition is composed essentially of platinum present in an atomic percentage ranging between about 20 percent and about 55 percent, tungsten present in an atomic percentage ranging between about 30 percent and about 75 percent, and at least a third metal present in an atomic percentage ranging between about 1 percent and about 40 percent. The third metal can be at least one member selected from the group consisting of scandium, vanadium, chromium, manganese, iron, cobalt, copper, zinc, yttrium, niobium, molybdenum, cadmium, tin, hafnium, tantalum and rhenium; additional fourth and fifth metals can also be present.
    Type: Grant
    Filed: December 6, 2005
    Date of Patent: June 15, 2010
    Assignee: Honda Motor Co., Ltd.
    Inventors: Ting He, Eric Rolland Kreidler
  • Patent number: 7731867
    Abstract: The invention is directed to conductive polymer compositions, catalytic ink compositions (e.g., for use in screen-printing), electrodes produced by deposition of an ink composition, as well as methods of making, and methods of using such compositions and electrodes. An exemplary ink material comprises a metal catalyst (e.g., platinum black and/or platinum-on-carbon), graphite as a conducting material, a polymer binding material, and an organic solvent. In one aspect, the polymer binding material comprises a polymer binder blend comprising first and second polymers, wherein the first polymer has a glass transition temperature higher than the second polymer. In a second aspect, the polymer binding material comprises a hydrophilic acrylic polymer, copolymer, or terpolymer. The conductive polymer compositions of the present invention may be used, for example, to make electrochemical sensors. Such sensors may be used, for example, in a variety of devices to monitor analyte amount or concentrations in subjects.
    Type: Grant
    Filed: January 23, 2007
    Date of Patent: June 8, 2010
    Assignee: Animas Technologies, LLC
    Inventors: Huawen Li, Michael J. Tierney
  • Patent number: 7727927
    Abstract: Activation of a tungsten-containing catalyst using water in a PEM-type fuel cell is described as well as cathode operation of the tungsten-containing catalyst.
    Type: Grant
    Filed: October 4, 2005
    Date of Patent: June 1, 2010
    Assignee: Global Tungsten & Powders Corp.
    Inventor: Joel B. Christian
  • Patent number: 7718155
    Abstract: Methods for manufacturing carbon nanostructures include: 1) forming a plurality of catalytic templating particles using a plurality of dispersing agent molecules; 2) forming an intermediate carbon nanostructure by polymerizing a carbon precursor in the presence of the plurality of templating nanoparticles; 3) carbonizing the intermediate carbon nanostructure to form a composite nanostructure; and 4) removing the templating nanoparticles from the composite nanostructure to yield the carbon nanostructures. The carbon nanostructures are well-suited for use as a catalyst support. The carbon nanostructures exhibit high surface area, high porosity, and high graphitization. Carbon nanostructures according to the invention can be used as a substitute for more expensive and likely more fragile carbon nanotubes.
    Type: Grant
    Filed: October 5, 2006
    Date of Patent: May 18, 2010
    Assignee: Headwaters Technology Innovation, LLC
    Inventors: Cheng Zhang, Martin Fransson, Changkun Liu, Bing Zhou
  • Patent number: 7718156
    Abstract: Carbon nanostructures are formed from a carbon precursor and catalytic templating nanoparticles. Methods for manufacturing carbon nanostructures generally include (1) forming a precursor mixture that includes a carbon precursor and a plurality of catalytic templating particles, (2) carbonizing the precursor mixture to form an intermediate carbon material including carbon nanostructures, amorphous carbon, and catalytic metal, (3) purifying the intermediate carbon material by removing at least a portion of the amorphous carbon and optionally at least a portion of the catalytic metal, and (4) heat treating the purified intermediate carbon material and/or treating the purified intermediate carbon material with a base to remove functional groups on the surface thereof. The removal of functional groups increases the graphitic content of the carbon nanomaterial and decreases its hydrophilicity.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: May 18, 2010
    Assignee: Headwaters Technology Innovation, LLC
    Inventors: Cheng Zhang, Martin Fransson, Bing Zhou
  • Patent number: 7713910
    Abstract: The present invention provides a method for manufacture of supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method is based on the use of polyol solvents as reaction medium and comprises of a two-step reduction process in the presence of a support material. In the first step, the first metal (M1=transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (M2=noble metal; e.g. Pt, Pd, Au and mixtures thereof) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300° C. Due to this two-step method, an uniform reduction occurs, resulting in noble metal based catalysts with a high degree of alloying and a small crystallite size of less than 3 nm. Due to the high degree of alloying, the lattice constants are lowered.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: May 11, 2010
    Assignee: Umicore AG & Co KG
    Inventors: Dan V. Goia, Marco Lopez, Tapan Kumar Sau, Mihaela-Ortansa Jitianu
  • Patent number: 7713899
    Abstract: Compositions and methods for the manufacture of electrodes for fuel cells. The compositions and methods are particularly useful for the manufacture of anodes and cathodes for proton exchange membrane fuel cells, particularly direct methanol fuel cells. The methods can utilize direct-write tools to deposit ink compositions and form functional layers of a membrane electrode assembly having controlled properties and enhanced performance.
    Type: Grant
    Filed: July 3, 2006
    Date of Patent: May 11, 2010
    Assignee: Cabot Corporation
    Inventors: Mark J. Hampden-Smith, Toivo T. Kodas, Paolina Atanassova, Rimple Bhatia, Ross A. Miesem, Paul Napolitano, Gordon L. Rice
  • Patent number: 7704913
    Abstract: A visible-light-responsive three-dimensional fine cell-structured photocatalytic filter in accordance with the present invention includes a sponge-like porous structure (B) containing an anatase-type titanium oxide coating formed on a surface of a sponge-like porous structural body (A) which has a porosity of 85 vol % or more.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: April 27, 2010
    Assignee: National Institute of Advanced Industrial Science and Technology
    Inventors: Eiji Tani, Kunio Kimura
  • Publication number: 20100099551
    Abstract: A carbon nanohorn (CNH) is oxidized to make an opening in the side of the CNH. A substance to be included, e.g., a metal, is introduced through the opening. The inclusion substance is moved to a tip part of the carbon nanohorn through heat treatment in vacuum or an inert gas. The CNH is further heat treated in an atmosphere containing oxygen in a low concentration to remove the carbon layer in the tip through catalysis of the inclusion substance. This exposes the inclusion substance. If the inclusion substance is a metal which is not moved to a tip part by the heat treatment in vacuum or an inert gas, the carbon part surrounding the fine catalyst particle is specifically burned by a heat treatment in an low oxygen concentration atmosphere, while utilizing the catalysis. Thus, the fine catalyst particle is fixed to the tip part of the CNH.
    Type: Application
    Filed: January 16, 2008
    Publication date: April 22, 2010
    Applicant: NEC CORPORATION
    Inventors: Ryota Yuge, Masako Yodasaka, Sumio Iijima
  • Patent number: 7700518
    Abstract: The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.
    Type: Grant
    Filed: September 20, 2005
    Date of Patent: April 20, 2010
    Assignee: Battelle Memorial Institute
    Inventors: Yong Wang, David P. Vanderwiel, Anna Lee Y. Tonkovich, Yufei Gao, Eddie G. Baker
  • Publication number: 20100094070
    Abstract: Bimetallic, supported catalysts for production of 1-hexene from ethylene are manufactured by impregnating a porous, solid support material with at least one catalytic chromium compound and at least one catalytic tantalum compound. The bimetallic, supported catalysts have high catalytic turnover, high selectivity for 1-hexene production, a low tendency for metals to leach from the catalysts during manufacturing and use compared to catalysts manufactured using known techniques. Moreover, the catalysts can be reused in multiple synthesis runs. High turnover, high selectivity, and reusability improve yields and reduce the costs associated with producing 1-hexene from ethylene, while the absence of metal leaching reduces the potential environmental impacts of using toxic metal catalysts (e.g., chromium).
    Type: Application
    Filed: October 15, 2008
    Publication date: April 15, 2010
    Applicant: HEADWATERS TECHNOLOGY INNOVATION, LLC
    Inventors: He Qiu, Bing Zhou
  • Patent number: 7696121
    Abstract: The invention provides an electrode comprising an electrically conductive material having a surface capable of producing surface enhanced Raman scattering of incident light from an adsorbate material adsorbed on the surface of the electrode. The adsorbate is substantially reducible and not substantially oxidizable. The surface of the electrode can be microroughened and include, for example, a plurality of adatoms or clusters of adatoms of a metallic material. The adatoms or clusters of adatoms form sites for photocatalysis of electroreduction when the electrode is irradiated with a light source. The invention also includes a method for making the electrode, and a method of generating electricity using the electrode. In accordance with a further aspect of the invention, a fuel cell is provided including the electrode of the invention.
    Type: Grant
    Filed: March 30, 2006
    Date of Patent: April 13, 2010
    Assignee: Fordham University
    Inventor: John J. McMahon
  • Patent number: 7687427
    Abstract: The present invention discloses a novel process for the fabrication of a class of conductive supported electrocatalysts based on transition metals. The electrocatalysts are formed by pyrolysis of an organometallic polymer complex precursor which is the reaction product of transition metal salts and a templating polymer. The electrocatalysts has enhanced catalytic activity, and are useful in the preparation of supercapacitor and fuel cell electrodes, auto-thermal fuel reformer catalysts, oxygen and hydrogen sensors, zinc-air battery electrode and oxidation catalysts.
    Type: Grant
    Filed: June 13, 2006
    Date of Patent: March 30, 2010
    Assignee: Enerage, Inc.
    Inventor: Mark Y. Wu
  • Patent number: 7687424
    Abstract: The invention provides an electrode comprising an electrically conductive material having a surface capable of producing surface enhanced Raman scattering of incident light from a complex adsorbed at the surface of the electrode, the complex including the electrically conductive material combined with a second material that is substantially reducible and not substantially oxidizable. The surface of the electrode can be microroughened. The invention also includes a method for making various embodiments of the electrode, and a method of generating electricity using the electrode. In accordance with a further aspect of the invention, a fuel cell is provided including the electrode of the invention.
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: March 30, 2010
    Assignee: Fordham University
    Inventor: John J. McMahon
  • Publication number: 20100075835
    Abstract: A nanocarbon aggregate including a graphite aggregate including a graphene sheet having a petal shape and a nanohorn. The petal-shaped graphite aggregate achieves a reduction in the particulate size and a higher dispersibility by allowing the edge of the petal shape to locally absorb a metal, a metal complex and a metal oxide. The nanocarbon aggregate is used for a catalyst support.
    Type: Application
    Filed: January 29, 2008
    Publication date: March 25, 2010
    Applicant: NEC CORPORATION
    Inventors: Ryota Yuge, Masako Yudasaka, Sumio Iijima
  • Patent number: 7670582
    Abstract: Provided are a mesoporous carbon and a method of preparing the same, where the mesoporous carbon is prepared using phenanthrene as a carbon source and a mesoporous silica as a template. The mesoporous carbon has a significantly low plane resistance, which can be obtained without sacrificing other physical properties, and thus obtains a high conductivity and effectively transfers electrical energy. Accordingly, a fuel cell electrode or a fuel cell which is produced using the mesoporous carbon as a conductive material has high efficiency. Furthermore, the mesoporous carbon may be used in various electrochemical devices as a conductive material.
    Type: Grant
    Filed: May 16, 2006
    Date of Patent: March 2, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Chan-ho Pak, Sang-hoon Joo, Hyuk Chang, Ji-man Kim, Hyung-ik Lee
  • Patent number: 7670985
    Abstract: The invention provides an activated carbon supported cobalt based catalyst for directly converting of synthesis gas to mixed linear alpha-alcohols and paraffins, comprising cobalt, an activated carbon carrier, a metal promoter which is at least one selected from the group consisting of a zirconium component, a lanthanum component, a cerium component, a chromium component, a vanadium component, a titanium component, a manganese component, a rhenium component, a potassium component, a ruthenium component, a magnesium component and a mixture thereof, wherein the cobalt and the promoter are deposited on the activated carbon carrier or substantially uniformly dispersed therein, and the metal promoter is present in the form of a metal, an oxide or a combination thereof.
    Type: Grant
    Filed: August 9, 2007
    Date of Patent: March 2, 2010
    Assignees: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, CNOOC New Energy Investment Co., Ltd.
    Inventors: Yunjie Ding, Hejun Zhu, Tao Wang, Guiping Jiao, Yuan Lv
  • Publication number: 20100048387
    Abstract: Provided are an electrocatalyst for a fuel cell having a large amount of catalyst metal particles supported on a carbon support and maintaining a high-dispersity state and a method of preparing the same. The electrocatalyst is characterized by being composed of catalyst metal particles having a secondary structure composed of at least one kind of primary metal particles having a particle diameter of 0.1 to 1.5 nm, or the catalyst metal particles having a core-shell structure of which the core is composed of metal particles having a particle diameter of 2.0 nm or less, and carbon particles. The method of preparing the electrocatalyst, including a first loading step for producing the core of catalyst metal particles wherein distances between the particles are controlled to 2.0 nm or less on a support and a second loading step for growing the catalyst metal particles, enables the amount of metal loaded on the support to increase without causing aggregation of the catalyst metal particles in the end.
    Type: Application
    Filed: November 8, 2006
    Publication date: February 25, 2010
    Applicant: Shin-Etsu Chemical Co., Ltd.
    Inventors: Shuguo Zhang, Shinsuke Ohyagi
  • Patent number: 7666812
    Abstract: An improved gas diffusion electrode composed of a perovskite-type oxide dispersed in a mixture of carbon black and a hydrophobic binder polymer. An improved catalyst for use in the electrochemical reduction of oxygen comprising a perovskite-type compound having alpha and beta sites, and having a greater molar ratio of cations at the beta site. A particularly good reduction catalyst is a neodymium calcium manganite. An improved method of dispersing the catalysts with carbon in a reaction layer of the electrode improves performance of the electrode and the oxygen reduction process. This is provided by adding carbon black to an aqueous solution of metal salts before it is heated to a gel and then to a char and then calcined. Optionally, a quantity of the desired oxide catalyst can be premixed with a portion the carbon before adding the carbon to an aqueous solution of the metal salts to be heated.
    Type: Grant
    Filed: August 10, 2007
    Date of Patent: February 23, 2010
    Assignee: Ceramatec, Inc.
    Inventors: John Howard Gordon, Hachiya Toshinori, Shekar Balagopal, Sai Bhavaraju
  • Patent number: 7662741
    Abstract: The present invention relates to a process for the preparation of highly active silver deposited on carbon covered alumina catalyst, in controlling the microorganism in water.
    Type: Grant
    Filed: March 31, 2006
    Date of Patent: February 16, 2010
    Assignee: Council of Scientific and Industrial Research
    Inventors: Kamaraju Sheetha Rama Rao, Bussi David Raju, Aytam Hari Padmasri, Sivakumar Vasireddy, Naga Ratnakar Adapa, Seetharamulu Podila, Shashikala Veldurthi, Mallanna Nagaraja Bhari, Sanapureddy Sreevardhan Reddy, Ponnapalli Nageswara Sarma, Katuri Krishna Prasad, Reddy Venkata Mohan Srinivasula
  • Patent number: 7662740
    Abstract: A fuel cell catalyst comprising platinum, chromium, and copper, nickel or a combination thereof. In one or more embodiments, the concentration of platinum is less than 50 atomic percent, and/or the concentration of chromium is less than 30 atomic percent, and/or the concentration of copper, nickel, or a combination thereof is at least 35 atomic percent.
    Type: Grant
    Filed: June 3, 2004
    Date of Patent: February 16, 2010
    Assignees: Symyx Technologies, Inc., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Konstantinos Chondroudis, Alexander Gorer, Martin Devenney, Ting He, Hiroyuki Oyanagi, Daniel M. Giaquinta, Kenta Urata, Hiroichi Fukuda, Qun Fan, Peter Strasser, Keith James Cendak, Jennifer N. Cendak, legal representative
  • Publication number: 20100036138
    Abstract: An object of the present invention is to provide a catalyst exhibiting excellent performance particularly in partial oxidation reaction. Another object is to provide a method for efficiently producing carboxylic acid or carboxylic anhydride through vapor-phase partial oxidation of an organic compound by use of an oxygen-containing gas in the presence of the catalyst. The catalyst contains (1) diamond; (2) at least one species selected from among Group 5 transition element oxides, collectively called oxide A; and (3) at least one species selected from among Group 4 transition element oxides, collectively called oxide B. The method for producing a carboxylic acid or a carboxylic anhydride includes subjecting an organic compound to vapor phase partial oxidation by use of an oxygen-containing gas in the presence of the catalyst, wherein the organic compound is an aromatic compound having one or more substituents in a molecule thereof, the substituents each including a carbon atom bonded to an aromatic ring.
    Type: Application
    Filed: June 18, 2009
    Publication date: February 11, 2010
    Applicant: Mitsubishi Gas Chemical Company, Inc.
    Inventor: Atsushi OKAMOTO
  • Publication number: 20100035750
    Abstract: A method of preparing carbon-coated metal oxide nano-particles and carbon-coated metal oxide nano-particles prepared with the same method are described. The method includes the following steps at least. A precursor of a polymer is polymerized on metal oxide nano-particles to form polymer-coated metal oxide nano-particles. Then, pyrolysis is conducted to carbonize the polymer coated on the metal oxide nano-particles, so as to form carbon-coated metal oxide nano-particles.
    Type: Application
    Filed: October 27, 2008
    Publication date: February 11, 2010
    Applicant: National Tsing Hua University
    Inventors: Chia-Min Yang, Yu-Chuan Hsu, Huang-Ching Lin, Yi-Ting Liao, Chien-Wei Lue
  • Patent number: 7659224
    Abstract: Although nanoparticles capable of providing an extremely large active surface area have highly marked advantages, when a PEFC electrode utilizing nanoparticles is used for a prolonged period of time, the catalyst nanoparticles on carrier of the PEFC electrode because of the nano-size thereof migrate and aggregate together to result in a rapid loss of activity. Thus, there is a demand for inhibition of the above aggregation so as to prevent any drop of catalytic activity. According to the present invention the aggregation of nanoparticles can be inhibited by catalyst nanoparticles containing Pt wherein a porous matter containing an inorganic oxide is disposed on the surface of the catalyst nanoparticles. When use is made of nanoparticles whose surface has undergone specific modification, excellent activity can be realized. Therefore, there are provided surface-modified nanoparticles and catalyst and further a PEFC electrode utilizing these nanoparticles.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: February 9, 2010
    Assignee: Hitachi, Ltd.
    Inventors: Yuzuru Shimazaki, Yoshio Kobayashi, Mikio Konno
  • Patent number: 7659225
    Abstract: Disclosed is a catalyst composite containing a metal catalyst and a specifically defined carbon support containing a carbonaceous material. For example, the carbon support may have a total pore surface area of about 800 m2/g or more and about 2,000 m2/g or less where about 20% or less of the total pore surface area is micro pore surface area. Alternatively the carbon support may have a total pore volume of at least about 0.75 cc/g where about 15% or less of the total pore volume is micro pore volume. Alternatively, the carbon support may have a phosphorus content of about 0.75% by weight or less. Also disclosed are methods of making and using the catalyst composite.
    Type: Grant
    Filed: June 3, 2005
    Date of Patent: February 9, 2010
    Assignee: BASF Catalysts LLC
    Inventors: Jian Ping Chen, Charles R. Penquite, Deepak S. Thakur
  • Publication number: 20100021794
    Abstract: Disclosed is a method for fabricating a carbon material, by which carbon fibers or carbon tubes, particularly branched carbon fibers or carbon tubes, are obtained via a so-called self-growing process without using external carbon sources. The carbon material obtained by the method has a large specific surface area and further includes a metal catalyst, and thus may be used in cell materials for a fuel cell or secondary battery, hydrogen storage devices, capacitors, solar cells, display panel or the like.
    Type: Application
    Filed: July 21, 2009
    Publication date: January 28, 2010
    Applicant: KOREA INSTITUTE OF SCIENCE AND TECHOLOGY
    Inventors: Soo-Kil KIM, Heung Yong Ha, Han-ik Joh, Seong Mu Jo, Suk-Woo Nam, In Hwan Oh, Tae Hoon Lim, Seong Ahn Hong, Sung-Yeon Jang
  • Patent number: 7648938
    Abstract: The present invention provides a metal nanocolloidal liquid characterized by containing a dispersion medium and nanocolloidal metal particles, and containing substantially no protective colloid-forming agent; and a method for producing a metal-on-carrier, characterized by including causing nanocolloidal metal particles to be carried on a carrier by use of the metal nanocolloidal liquid. According to the production method, nanocolloidal metal particles can be efficiently caused to be carried on a carrier, and a metal-on-carrier which is useful in a variety of fields can be industrially advantageously produced.
    Type: Grant
    Filed: December 15, 2004
    Date of Patent: January 19, 2010
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Kiyoshi Miyashita, Masamichi Kezuka, Tetsuro Yoshii, Ryohei Ogawa, Akihiro Hishinuma, Tsutomu Sakai, Toyo Yano
  • Publication number: 20100004119
    Abstract: Sorbents comprising activated carbon particles, sulfur, and metal catalyst. The sorbents may be used, for example, for the removal of a contaminant, such as mercury, from a fluid stream.
    Type: Application
    Filed: July 3, 2008
    Publication date: January 7, 2010
    Inventors: Kishor Purushottam Gadkaree, Anbo Liu
  • Publication number: 20100004121
    Abstract: The present invention is related to a short carbon nanotube for a catalyst support. In particular, the short carbon nanotube may be opened at both ends, a length of less than about 300 nm, and an aspect ratio in the range of about 1 to about 15. The short carbon nanotube has a broad surface area and better electric conductivity and is opened at both ends, thereby impregnating a metallic catalyst into the inner side of the carbon nanotube. Also, a catalyst impregnated carbon nanotube has a broad effective specific surface area, and thus, has an improved efficiency of catalyst utilization, can reduce an amount of the catalyst used and can efficiently diffuse a fuel. Accordingly, when catalyst impregnated carbon nanotube is used in a fuel cell, etc., improvements can be made in the pricing, power density of an electrode, and energy density of a fuel cell.
    Type: Application
    Filed: January 6, 2005
    Publication date: January 7, 2010
    Inventors: Hyuk Chang, Chan-ho Pak, Jian Nong Wang
  • Patent number: 7642212
    Abstract: Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at a low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with the stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks.
    Type: Grant
    Filed: April 16, 2008
    Date of Patent: January 5, 2010
    Assignee: Advanced Refining Technologies LLC
    Inventor: Darryl P. Klein
  • Patent number: 7638455
    Abstract: A process for the preparation of a catalyst, which process comprises the steps of: i) mixing an alumina precursor with combustible carbon-containing fibers with a diameter in the range of from 0.5 to 5 ?m and a length of no greater than 100 ?m in an amount in the range of from 20 to 40 wt % based on the total dry mixture; ii) adding nitric acid and water to form an extrudable mass; iii) extruding the mixture to form shaped particles; iv) drying the shaped particles; v) heating the particles in an atmosphere comprising no more than 5 vol % oxygen at a temperature in the range of from 350 to 600° C.; and vi) then heating the particles in a gas mixture comprising at least 12 vol % oxygen at a temperature in the range of from 450 to 600° C.
    Type: Grant
    Filed: March 8, 2007
    Date of Patent: December 29, 2009
    Assignee: Shell Oil Company
    Inventors: Peter Birke, Frank Heinz Goerlitz, Wigbert Gerhard Himmel, Jürgen Hunold, Hans-Heino John
  • Patent number: 7629285
    Abstract: A process for synthesis of a catalyst is provided. The process includes providing a carbon precursor material, oxidizing the carbon precursor material whereby an oxygen functional group is introduced into the carbon precursor material, and adding a nitrogen functional group into the oxidized carbon precursor material.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: December 8, 2009
    Assignee: University of South Carolina
    Inventors: Branko N. Popov, Jog-Won Lee, Nalini P. Subramanian, Swaminatha P. Kumaraguru, Hector R. Colon-Mercado, Vijayadurga Nallathambi, Xuguang Li, Gang Wu
  • Patent number: 7625832
    Abstract: A catalyst for the hydroprocessing of organic compounds, composed of an interstitial metal hydride having a reaction surface at which monatomic hydrogen is available. The activity of the catalyst is maximized by avoiding surface oxide formation. Transition metals and lanthanide metals compose the compound from which the interstitial metal hydride is formed. The catalyst's capabilities can be further enhanced using radio frequency (RF) or microwave energy.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: December 1, 2009
    Assignee: Carnegie Mellon University
    Inventors: David A. Purta, Marc A. Portnoff, Faiz Pourarian, Margaret A. Nasta, Jingfeng Zhang