Abstract: Olefins are oligomerized by bringing at least one C2 to C8-olefin into contact with a nickel-containing heterogeneous catalyst. The catalyst is conditioned before contact with the olefin by passing an inert gas flow over the same, until the inert gas flow has a water content of less than 1000 ppm. Selectivity for the production of higher oligomers, in particular trimers relative to the formation of dimers is increased by the pretreatment.

Abstract: The invention provides a process for the off site regeneration of a solid catalyst, comprising two consecutive steps: a first step of washing the catalyst using one or more fluid(s) in the supercritical state, so as to extract from the catalyst at least a portion of the hydrocarbons present at the surface of the latter, followed by a second step of combustion of at least a portion of the coke present at the surface of the said catalyst by a heat treatment of the latter in the presence of oxygen and at a temperature ranging from 300° C. to 600° C.

Abstract: Provided is a process for producing a regenerated hydrotreating catalyst by regenerating a spent hydrotreating catalyst in a prescribed temperature range, wherein the prescribed temperature range is a temperature range of T1?30° C. or more and T2+30° C. or less, as determined by subjecting the spent hydrotreating catalyst to a differential thermal analysis, converting a differential heat in a measuring temperature range of 100° C. or more and 600° C. or less to a difference in electromotive force, differentiating the converted value twice by temperature to provide a smallest extreme value and a second smallest extreme value, and representing a temperature corresponding to the extreme value on the lower-temperature side as T1 and a temperature corresponding to the extreme value on the higher-temperature side as T2.

Abstract: This invention relates to the field of Fischer-Tropsch catalysis, in particular to activation of a Fischer-Tropsch catalyst. More particularly the invention relates to a method of activating an iron based Fischer-Tropsch catalyst which includes iron in a positive oxidation state by contacting in a reactor said iron based catalyst with a reducing gas selected from the group consisting of CO and a combination of H2 and CO; at a temperature of at least 245° C. and below 280° C.; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.

Abstract: Treatment at elevated temperature and advantageously superatmospheric pressure with an inert gas, especially nitrogen, rejuvenates molecular sieve catalysts deactivated by use in liquid-phase or supercritical or dense-phase olefin oligomerization, or by use in aromatic alkylation.

Abstract: The invention concerns a process for regenerating a catalyst for the production of aromatic hydrocarbons or for reforming, comprising a step for combustion in a zone A comprising at least 2 beds A1 and A2, a step for oxychlorination in a zone B, and a step for calcining in a zone C. A portion of the effluent gas from the oxychlorination zone is recycled via at least one scrubbing section D to the inlet to beds A1 and A2. Further, a portion of the effluent gas from zone B is recycled to the combustion bed A2, passing via a blower but without passing via said scrubbing section D, and a portion is recycled to the inlet to zone B, passing via said blower but not via said scrubbing section. The invention also concerns the vessel in which said process is carried out.

Abstract: A process for regenerating a spent particulate wax-containing cobalt-based Fischer-Tropsch synthesis catalyst is provided. The process includes subjecting the spent wax-containing catalyst sequentially to a dewaxing treatment, an oxidation treatment and a reduction treatment. During the dewaxing treatment, the spent wax-containing catalyst is at least partially dewaxed, with dewaxed catalyst particles being produced. During the oxidation treatment, an oxygen-containing gas is passed through a bed of the dewaxed catalyst particles at an operating temperature T° C. where 150<T<450, and the operating temperature is controlled by removing heat from the catalyst particle bed using a cooling device, to obtain oxidized catalyst particles. During the reduction treatment, the oxidized catalyst particles are reduced, thereby regenerating the catalyst.

Abstract: Titanosilicate catalyst is used in the oxidation reactions such as allylchloride epoxidation, phenol hydroxylation, Cyclohexanone ammoximation. During the reaction the catalyst is deactivated which further decrease in the efficiency of the oxidation reactions. The present invention provides a method for an efficient regeneration of catalyst titanosilicate catalyst at low temperature below 100° C. using a gaseous mixture containing ozone, without isolating the catalyst from the reactor system.

Abstract: The invention concerns a process for regenerating a catalyst for the production of aromatic hydrocarbons or for reforming. Said process comprises a step for combustion in a zone A comprising at least 2 beds A1 and A2, a step for oxychlorination in a zone B, and a step for calcining in a zone C. A portion of the effluent gas from the oxychlorination zone is recycled via at least one scrubbing section D to the inlet to beds A1 and A2. Further, a portion of the effluent gas from zone B is recycled, passing via a blower and without passing via said scrubbing section D, to the combustion bed A2.

Abstract: The present invention relates to a continuous catalyst regeneration device comprising at least one burning zone formed by at least one annular combustion zone (3), centered along a longitudinal axis (A), in which the catalyst circulates, an inlet conduit of the catalyst (4) and an outlet conduit of the catalyst (4?), an external zone (11) for circulation of a combustive gas disposed around the annular combustion zone (3) and an internal circulation zone (15) disposed inside the annular combustion zone (3), wherein the burning zone is divided into sectors (14) by hermetic longitudinal plates (10) disposed radially relative to the longitudinal axis (A) of the regenerator. The invention also relates to the process using this device.

Abstract: An apparatus and method for vaporizing and transporting an alkali metal salt is shown. The apparatus has a first conduit capable of transporting an alkali metal salt solution and a second conduit in fluid communication with the first conduit, the second conduit capable of transporting steam so that the alkali metal salt is dissipated into the steam forming a solution that can be transported, such as to a remote reaction zone. The solution can be transported via a third conduit that is capable of being heated by a heat source. The method can be used to add a promoter to a dehydrogenation catalyst during a dehydrogenation reaction.

Abstract: A method for manufacturing a catalyst, which comprises regenerating a catalyst comprising a CHA zeolite as an active ingredient and having an ethylene conversion lowered through reaction of producing propylene by bringing into contact with ethylene in a vapor phase, by bringing the catalyst into contact with a gas which does not comprise oxygen and comprises hydrogen having a hydrogen partial pressure of 0.01 MPa or more as an absolute pressure thereof.

Abstract: Provided is a practical method for dry-separating arsenic compounds from a used NOx removal catalyst contaminated with arsenic. The method for removing arsenic compounds comprises heat-treating a NOx removal catalyst contaminated with arsenic compounds at a predetermined temperature in a reducing atmosphere while exposing the catalyst to hydrocarbon compounds (except CH4) or oxygen-containing carbon compound.

Abstract: This disclosure relates to a method for rejuvenating a catalyst, comprising contacting the catalyst with a gaseous feedstock at rejuvenation conditions for at least one hour to form a rejuvenated catalyst and a gaseous product, wherein the catalyst comprises at least 10 wt. % of a molecular sieve, wherein the catalyst prior to the contacting step comprises from 0.001 wt. % to 45 wt. % of hydrocarbons and 0.001 to 10 wt.

Abstract: The present invention relates to new processes for regenerating oxidized interstitial metal hydride containing catalysts prior to the use of such catalysts in a hydroprocessing process. Interstitial metal hydride containing catalysts are easily oxidized in the environment and once oxidized, the hydroprocessing activity of the interstitial metal hydrides is most often severely diminished and this lost activity due to oxidization of the iMeH is not susceptible to recovery under hydroprocessing conditions. As a result, these catalysts in the present art require considerable special handling in inert environments all through processes from fabrication, shipping, loading, use, and maintenance of the catalyst systems to protect the activity of the interstitial metal hydride components.

Abstract: An apparatus is disclosed. The apparatus comprises a lean-burn internal combustion engine, engine management means and an exhaust system for treating exhaust gas of the engine. The exhaust system comprises a first oxidation catalyst disposed on a first honeycomb monolith substrate. The first oxidation catalyst comprises platinum supported on a first metal oxide support comprising at least one reducible oxide, and is substantially free of alkali metals and alkaline earth metals. The engine management means is arranged, when in use, intermittently to modulate the lambda composition of the exhaust gas entering the first oxidation catalyst to a rich lambda composition.

Abstract: A configuration is provided for a deposition device using the catalytic CVD method which reduces problems associated with extension of the catalyst and is superior in terms of running costs and productivity. The configuration provides a chamber 1 able to maintain reduced interior pressure; a source gas introducing route 32, 33a for introducing source gas into the chamber; a catalyst 4 of tantalum wire having a boride layer on the surface and provided inside the chamber 1 so as to allow the source gas introduced via the source gas introducing route to come into contact with the surface of the catalyst; a gas introducing route 36, 33b for introducing boron-containing gas to the chamber 1 for the reformation of the boride layer on the surface of the catalyst 4; and a power supply unit 5 for applying energy to the catalyst 4 to maintain the catalyst at a predetermined temperature.

Abstract: The present invention relates to a method of regenerating a ruthenium catalyst for the hydrogenation of phthalates, which comprises flushing the catalyst with inert gas in a regeneration step until the original activity or part of the original activity has been attained.

Abstract: One exemplary embodiment can be a process for mixing catalyst in a regenerator. The process can include providing a first stream of catalyst, a second stream of catalyst mixed with the first stream of catalyst, and an oxygen-containing gas to a chamber via a distributor of the regenerator. Generally, the chamber imparts a swirl to at least one of the oxygen-containing gas, the first catalyst, and the second catalyst for regenerating the catalyst.

Abstract: Disclosed is a catalyst distributor and process for mixing spent catalyst and recycled regenerated catalyst in a regenerator vessel. Mixing is conducted in a confined space to which catalyst is delivered from catalyst conduits protruding through the wall of the regenerator.

Abstract: A method for producing a regenerated Fischer-Tropsch synthesis catalyst obtained by regenerating a spent catalyst used in a Fischer-Tropsch synthesis reaction, comprising a steaming step of bringing the above spent catalyst into contact with a mixed gas comprising 1 to 30% by volume of steam and an inert gas at a pressure of atmospheric pressure to 5 MPa and a temperature of 150 to 350° C., the above spent catalyst being a spent catalyst in which cobalt and/or ruthenium is supported on a carrier comprising silica with an average pore diameter measured by a nitrogen adsorption method of 4 to 25 nm, and of which activity represented by an initial carbon monoxide conversion is 40 to 95%, based on the activity of a corresponding unused catalyst.

Abstract: A method for producing an activated Fischer-Tropsch synthesis catalyst comprising a hydrogen reduction step of subjecting a catalyst comprising 3 parts by mass to 50 parts by mass, as a metal atom, of a cobalt compound and/or a ruthenium compound, based on 100 parts by mass of a carrier containing a porous inorganic oxide, supported on the carrier, to reduction in a gas containing molecular hydrogen at a temperature of 300° C. to 600° C.; and a CO reduction step of subjecting the catalyst to reduction in a gas containing carbon monoxide and containing no molecular hydrogen at a temperature of 200° C. to 400° C.

Abstract: A process for a continuous regeneration of a catalyst wherein the regeneration section includes at least two separate zones. The regeneration includes an upper combustion zone, and an lower combustion zone, where the process utilizes at least two independent regeneration gas loops for control of the amount of oxygen to regenerate the catalyst. The upper combustion zone can be divided into multiple zones, and the combustion zone can be divided into multiple zones.

Abstract: The present disclosure relates to facilities, systems, methods and/or catalysts for use in chemical production. In particular, the disclosure provides innovations relating to dehydration of multihydric compounds such as glycerol to form acrolein. Some of these innovations include continuous reaction systems as well as system parameters that allow for long term production.

Abstract: A method of preparing a spray dried catalyst by combining spray dried catalyst particles with wax so the spray dried catalyst particles are coated with wax, yielding wax coated catalyst particles, and shaping the wax coated catalyst to provide shaped wax coated catalyst. A method of activating Fischer-Tropsch catalyst particles containing oxides by contacting the catalyst particles with a reducing gas in an activation vessel to produce an activated catalyst, wherein contacting is performed in the absence of a liquid medium under activation conditions. A system for activating a Fischer-Tropsch catalyst containing an activation reactor configured to introduce an activation gas to a fixed or fluidized bed of the Fischer-Tropsch catalyst in the absence of a liquid medium and at least one separation device configured to separate a gas stream comprising entrained catalyst fines having an average particle size below a desired cutoff size from the activation reactor.

Abstract: This invention relates to a hydrocarbon synthesis process. More particularly, but not exclusively, this invention relates to a Fischer Tropsch Process employing an activated catalyst and to the use of such an activated catalyst, wherein the Fischer Tropsch Process conditions favor the attainment of a low acid selectivity. More particularly the invention relates to a three-phase low temperature Fischer Tropsch (LTFT) process wherein a feed of H2 and CO are converted to hydrocarbons and possible oxygenates thereof by contacting the H2 and CO in the presence of an iron-based Fischer Tropsch catalyst in a reaction zone, wherein the molar ratio of H2:CO in the feed is from 0.5 and less than 1.

Abstract: An apparatus and process are presented for drying a catalyst in a reactor-regenerator system. The process includes a continuous operating system with catalyst circulating between a reactor and regenerator, and the catalyst is dried before returning the catalyst to the reactor. The process uses air that is split between the drying stage and the combustion stage without adding equipment outside of the regenerator, minimizing energy, capital cost, and space requirements.

Abstract: This invention relates to a Fischer Tropsch process using a catalyst activated in accordance with the invention. More particularly the invention relates to a three phase Low Temperature Fischer Tropsch process wherein CO and H2 are converted to hydrocarbons and possibly oxygenates thereof by contacting syngas including CO and H2 in the presence of an iron based Fischer Tropsch catalyst, wherein the ratio of H2:CO in the feed is between 2.5 and 1, and wherein the iron based Fischer Tropsch catalyst is activated according to the steps of: (a) providing an iron catalyst including iron in a positive oxidation state; and (b) contacting the iron catalyst in a reactor with a reducing gas selected from CO and a combination of H2 and CO; at a temperature of at least 245° C. and below 280° C.; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.

Abstract: A process for the regeneration of deactivated catalyst from a Fischer-Tropsch synthesis reactor, the catalyst being a supported cobalt catalyst. The process comprises the following steps: a withdrawal step, in which a portion of deactivated catalyst together with liquid hydrocarbon is withdrawn from the reactor; a concentration step, in which the concentration of the catalyst in the liquid hydrocarbon is increased; a calcination step, in which the deactivated catalyst composition is subjected to an oxidising gas to oxidise carbonaceous material contained in the deactivated catalyst in to gaseous oxides of the components of the carbonaceous material; and a reactivation step, in which the deactivated catalyst composition is reactivated to produced a regenerated catalyst.

Abstract: Apparatuses and processes are provided for stripping gaseous hydrocarbons from particulate material. One process comprises the step of contacting particles containing hydrocarbons with a stripping vapor in countercurrent flow to remove at least a portion of the hydrocarbons with the stripping vapor to form stripped particles. Contacting the particles includes advancing the particles down a sloping element of a structured packing toward a reinforcing rod that is disposed along a lower channel portion of the sloping element. The particles are advanced over the reinforcing rod. The particles are contacted with the stripping vapor that is rising up adjacent to the lower channel portion.

Abstract: Apparatuses and processes are provided for stripping gaseous hydrocarbons from particulate material. One process comprises the step of contacting particles that contain hydrocarbons with a stripping vapor in countercurrent flow to remove at least a portion of the hydrocarbons with the stripping vapor to form stripped particles. Contacting the particles includes advancing the particles down a sloping element of a structured packing toward a reinforcing rod that is disposed adjacent to a lower section of the sloping element. The particles are advanced down through an opening formed in the sloping element proximate the reinforcing rod. The particles are contacted with the stripping vapor that is rising up through the opening.

Abstract: Apparatuses and processes are provided for stripping gaseous hydrocarbons from particulate material. One process comprises the step of contacting particles containing hydrocarbons with a stripping vapor in countercurrent flow to remove at least a portion of the hydrocarbons with the stripping vapor to form stripped particles. Contacting the particles includes advancing the particles down a sloping element of a structured packing toward a lower section of the sloping element. The particles are passed through a drainage gap formed between a pair of reinforcing rod sections that are disposed adjacent to the lower section of the sloping element. The particles are contacted with the stripping vapor that is rising up adjacent to the drainage gap.

Abstract: A method for regenerating at least one impurity-adsorbing sorbent bed includes passing impurity-containing fluid through the impurity-adsorbing bed. The impurity-adsorbing sorbent bed adsorbs an impurity in the impurity-containing fluid to produce a purified fluid. A portion of the purified fluid is sent back through the impurity-adsorbing sorbent bed that contains the adsorbed impurity. The impurity-adsorbing sorbent bed is exposed to microwave energy to desorb the impurity adsorbed on the impurity-adsorbing sorbent bed.

Abstract: Systems that facilitate operating proton exchange membrane (PEM) fuel cells are provided. The systems employ a fuel supply component that supplies fuel to the proton exchange membrane fuel cell; and a regeneration component that provides a reducing agent comprising a mixture of hydrogen and nitrogen, or a reducing plasma to a cathode catalyst of the proton exchange membrane fuel cell to reduce the cathode catalyst.

Abstract: Processes are disclosure which comprise alternately contacting an oxygen-carrying catalyst with a reducing substance, or a lower partial pressure of an oxidizing gas, and then with the oxidizing gas or a higher partial pressure of the oxidizing gas, whereby the catalyst is alternately reduced and then regenerated to an oxygenated state. In certain embodiments, the oxygen-carrying catalyst comprises at least one metal oxide-containing material containing a composition having the following formulas: (a) CexByB?zB?O?, wherein B=Ba, Sr, Ca, or Zr; B?=Mn, Co, and/or Fe; B?=Cu; 0.01<x<0.99; 0<y<0.6; 0<z<0.5; (b) Ce1-x-yNixByO2-*, wherein B=Zr, Ba, Ca, La, or K; 0.02<x<0.1; 0<y<0.1; and 0.02<*<0.15; and 1<?<2.2 and (c) coal ash either as a catalyst material itself or as a support for said unary or binary metal oxides.

Abstract: An exhaust gas purifying filter, a system for regenerating a particulate filter, and a method therefore are disclosed. An exhaust gas purifying filter may include: an ammonia storage catalyst unit adapted to absorb ammonia contained in the exhaust gas when a temperature of the ammonia storage catalyst unit is lower than a predetermined temperature, release the absorbed ammonia when the temperature of the ammonia storage catalyst unit is higher than or equal to the predetermined temperature, and generate nitrogen oxide from the released ammonia; and a particulate filter adapted to trap particulate matter contained in the exhaust gas and regenerate the trapped particulate matter by using the nitrogen oxide generated from the ammonia storage catalyst unit.

Abstract: One exemplary embodiment can be a process for regenerating catalyst in a fluid catalytic cracking unit. Generally, the process includes providing a feed to a riser of a reaction vessel, and providing a stream to a distributor positioned within a void proximate to an inlet receiving unregenerated catalyst in a regenerator. The feed can include at least one of a gas oil, a vacuum gas oil, an atmospheric gas oil, a coker gas oil, a hydrotreated gas oil, a hydrocracker unconverted oil, and an atmospheric residue.

Abstract: The method includes a pretreatment step during an operation of a boiler in which in a predetermined period of time before shutdown of the boiler, a part of combustion gas that has bypassed an economizer provided in a flue gas duct for flue gas from the boiler is supplied to an upstream of a NOx removal device having a NOx removal catalyst and mixed with the combustion flue gas from the economizer to generate mixed gas having a predetermined temperature equal to or higher than 360° C. (360° C. to 450° C.), the mixed gas is introduced into the NOx removal catalyst, thereby decomposing VOSO4 adhering to and accumulating on the NOx removal catalyst into V2O5.

Abstract: One exemplary embodiment can be an apparatus for treating a hydrocarbon stream having one or more compounds with a boiling point of about 140° to about 450° C. The apparatus can include an extraction zone and a regeneration zone. The extraction zone can include at least one settler. Each settler can have a height and a length. Typically the length is greater than the height. Also, the settler can form a boot, which can be adapted to receive a feed at one end. The regeneration zone may include a regenerator for an ionic liquid. The regenerator can include a column adapted to provide a regenerated ionic liquid to the extraction zone.

Abstract: An apparatus for efficiently removing the exuded substance and/or the attached substance on the surface of a catalyst (catalyst surface substance) from the catalyst is provided. The apparatus comprising a main body, the apparatus for removing a catalyst surface substance present on a surface of a catalyst from the catalyst by bringing a gas flow into contact with the catalyst housed in the main body, wherein a gas flow length in a flow direction of the gas flow is 55 mm or more, and an average flow velocity of the gas flow is 80 m/s or more and 500 m/s or less in terms of a linear velocity at 15° C. and 1 atm.

Abstract: An improved spent catalyst regenerator which contains sub-troughs branching off from the main trough, distribution troughs which extend outward from the sides of the main trough and the sub-troughs, and downflow tubes extending downward from the bottom of the main trough and sub-troughs.

Abstract: A thermal evaporation apparatus for depositing of a material on a substrate is described. The apparatus can comprise material storage means; heating means to generate a vapour of the material in the material storage means; vapour outlet means comprising a vapour receiving pipe having vapour outlet passages, and emission reducing means arranged such that an external surface of the vapour outlet means directed to said substrate exhibits low emission. Also the use of the apparatus, and a method of depositing a material onto a substrate by thermal evaporation are described.

Abstract: A process for catalyst regeneration is presented. The process regenerates a catalyst in a paraffin dehydrogenation process, where the reaction is endothermic. The regeneration process provides the heat for the process through heating the catalyst and removes the need for a charge heater to the dehydrogenation reactor, which in turn eliminates high temperature thermal residence time which eliminates thermal cracking of the feed and improves the overall product selectivity. In addition, plot area, equipment costs and operating complexity are reduced.

Abstract: The present disclosure relates to methods for treating an SCR catalyst or components of an SCR system having a decreased NOx potential efficiency as a result of particulate pluggage in the system or in one or more channels in the SCR catalyst which renders at least a portion of the catalytic active areas inaccessible for the flue gas. The methods include removal of the particulates and plug(s) using a blasting stream of a pressurized carrier gas having a particulate blasting medium directed at the SCR catalyst or component of an SCR system.

Abstract: A method and a device for the regeneration of a particle filter, especially a diesel particle filter, arranged in the exhaust gas train of an internal combustion engine, wherein an exhaust gas stream to be cleaned is supplied to the at least one particle filter. The exhaust gas stream supplied to the at least one particle filter is a raw exhaust gas stream of the internal combustion engine, into which, during regeneration mode, a heated exhaust gas stream at a higher temperature than the raw exhaust gas stream is mixed at a point upstream of the particle filter under the control of at least one open-loop and/or closed-loop control device, which actuates a throttle device and/or shut-off device in accordance with predetermined regeneration parameters.

Abstract: A process for regenerating a catalyst bed deactivated in the course of a heterogeneously catalyzed partial dehydrogenation of a hydrocarbon, in which a gas comprising molecular oxygen is conducted at elevated temperature through the deactivated catalyst bed and, in the course of the regeneration, the content of molecular oxygen in the regeneration gas is increased repeatedly and the increase in the carbon oxide content of the regeneration gas as it flows through the deactivated catalyst bed is restricted to values of ?5% by volume.

Abstract: One exemplary embodiment can be a process for desorbing an adsorbent bed. The process can include passing a desorbent stream through the adsorbent bed to remove at least one of a nitrile compound and an oxygenate compound. Generally, the desorbent stream after desorbing is combined with a feed stream for an alkylation zone after a selective hydrogenation zone.

Abstract: A method includes contacting a catalyst including a metal having an average particle size of approximately one nanometer or greater with SO2; and reducing the average particle size of the metal.

Abstract: An exhaust treatment method is provided. Method of increasing activation of NOx reduction catalyst using two or more reductant is discussed. The NOx catalyst is disposed to receive both the exhaust stream and reductant stream. The sensor is disposed to sense a system parameter related to carbon loading of the catalyst and produce a signal corresponding to the system parameter. The controller is disposed to receive the signal and to control dosing of the reductant stream based at least in part on the signal. The method includes sensing a system parameter related to carbon loading of a catalyst, producing a signal corresponding to the system parameter and sending the signal to a controller; and controlling a dosing of a reductant stream based at least in part on the signal.

Abstract: Disclosed is a catalyst distributor and process for spreading catalyst over a regenerator vessel. Nozzles disposed angular to a header of the distributor spread catalyst throughout a full cross section of the catalyst bed.